WO2015142330A1 - Appareil et procédé mettant en oeuvre un chauffage par micro-ondes d'un fluide hydrocarboné dans une cavité de résonance - Google Patents

Appareil et procédé mettant en oeuvre un chauffage par micro-ondes d'un fluide hydrocarboné dans une cavité de résonance Download PDF

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Publication number
WO2015142330A1
WO2015142330A1 PCT/US2014/031251 US2014031251W WO2015142330A1 WO 2015142330 A1 WO2015142330 A1 WO 2015142330A1 US 2014031251 W US2014031251 W US 2014031251W WO 2015142330 A1 WO2015142330 A1 WO 2015142330A1
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WO
WIPO (PCT)
Prior art keywords
resonant cavity
microwave radiation
resonant
pipe
hydrocarbon fluid
Prior art date
Application number
PCT/US2014/031251
Other languages
English (en)
Inventor
Wai-Ming Tam
Original Assignee
Schlumberger Canada Limited
Services Petroliers Schlumberger
Schlumberger Holdings Limited
Schlumberger Technology B.V.
Prad Research And Development Limited
Schlumberger Technology Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schlumberger Canada Limited, Services Petroliers Schlumberger, Schlumberger Holdings Limited, Schlumberger Technology B.V., Prad Research And Development Limited, Schlumberger Technology Corporation filed Critical Schlumberger Canada Limited
Priority to PCT/US2014/031251 priority Critical patent/WO2015142330A1/fr
Publication of WO2015142330A1 publication Critical patent/WO2015142330A1/fr

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G15/00Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs
    • C10G15/08Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs by electric means or by electromagnetic or mechanical vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122Incoherent waves
    • B01J19/126Microwaves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
    • C10G32/02Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by electric or magnetic means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00054Controlling or regulating the heat exchange system
    • B01J2219/00056Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00058Temperature measurement
    • B01J2219/00063Temperature measurement of the reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/0015Controlling the temperature by thermal insulation means
    • B01J2219/00155Controlling the temperature by thermal insulation means using insulating materials or refractories
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00193Sensing a parameter
    • B01J2219/00195Sensing a parameter of the reaction system
    • B01J2219/002Sensing a parameter of the reaction system inside the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00222Control algorithm taking actions
    • B01J2219/00227Control algorithm taking actions modifying the operating conditions
    • B01J2219/00238Control algorithm taking actions modifying the operating conditions of the heat exchange system
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1209Features relating to the reactor or vessel
    • B01J2219/1212Arrangements of the reactor or the reactors
    • B01J2219/1215Single reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1209Features relating to the reactor or vessel
    • B01J2219/1221Features relating to the reactor or vessel the reactor per se
    • B01J2219/1224Form of the reactor
    • B01J2219/1227Reactors comprising tubes with open ends
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1209Features relating to the reactor or vessel
    • B01J2219/1221Features relating to the reactor or vessel the reactor per se
    • B01J2219/1242Materials of construction
    • B01J2219/1245Parts of the reactor being microwave absorbing, dielectric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1248Features relating to the microwave cavity
    • B01J2219/1266Microwave deflecting parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1248Features relating to the microwave cavity
    • B01J2219/1269Microwave guides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1248Features relating to the microwave cavity
    • B01J2219/1272Materials of construction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1275Controlling the microwave irradiation variables
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1287Features relating to the microwave source
    • B01J2219/129Arrangements thereof
    • B01J2219/1293Single source

Abstract

L'invention concerne un appareil pour le chauffage par des micro-ondes d'un fluide hydrocarboné dans une cavité de résonance, où le fluide hydrocarboné est chargé dans un tuyau qui s'étend au travers de la cavité de résonance entre une entrée et une sortie, un point central étant situé au centre entre celles-ci. La cavité de résonance concentre le rayonnement de micro-ondes sur une zone localisée occupée par le tuyau de telle sorte que la distribution de la densité de puissance le long de la longueur du tuyau présente un pic situé au niveau d'un point décalé du point central, entre le point central et la sortie. Dans un autre aspect, la cavité de résonance peut présenter un volume variable qui fait résonner le rayonnement de micro-ondes à des fréquences de résonance différentes. L'appareil peut être configuré pour chauffer un fluide hydrocarboné à une température de réaction appropriée à la viscoréduction du fluide hydrocarboné. La température de réaction peut se situer dans la plage de 350°C à 500°C, qui est appropriée pour la viscoréduction d'huile lourde.
PCT/US2014/031251 2014-03-19 2014-03-19 Appareil et procédé mettant en oeuvre un chauffage par micro-ondes d'un fluide hydrocarboné dans une cavité de résonance WO2015142330A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/US2014/031251 WO2015142330A1 (fr) 2014-03-19 2014-03-19 Appareil et procédé mettant en oeuvre un chauffage par micro-ondes d'un fluide hydrocarboné dans une cavité de résonance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2014/031251 WO2015142330A1 (fr) 2014-03-19 2014-03-19 Appareil et procédé mettant en oeuvre un chauffage par micro-ondes d'un fluide hydrocarboné dans une cavité de résonance

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WO2015142330A1 true WO2015142330A1 (fr) 2015-09-24

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10669814B2 (en) 2017-08-08 2020-06-02 Saudi Arabian Oil Company In-situ heating fluids with electromagnetic radiation
US11187044B2 (en) 2019-12-10 2021-11-30 Saudi Arabian Oil Company Production cavern
US11438976B2 (en) 2020-02-04 2022-09-06 Qwave Solutions, Inc. Apparatuses, systems, and methods for heating with electromagnetic waves
US11460330B2 (en) 2020-07-06 2022-10-04 Saudi Arabian Oil Company Reducing noise in a vortex flow meter
CN115444954A (zh) * 2022-09-22 2022-12-09 四川大学 一种电磁场分布调节装置、微波加热装置以及加热方法
EP3953992A4 (fr) * 2019-04-05 2022-12-14 Pyrowave Inc. Coupleur pour systèmes de pyrolyse à micro-ondes
CN115639222A (zh) * 2022-12-22 2023-01-24 河北科技大学 变频微波和uv协同处理有机污染物评价方法及评价装置
US11619097B2 (en) 2021-05-24 2023-04-04 Saudi Arabian Oil Company System and method for laser downhole extended sensing
US11725504B2 (en) 2021-05-24 2023-08-15 Saudi Arabian Oil Company Contactless real-time 3D mapping of surface equipment

Citations (6)

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US4067683A (en) * 1976-06-14 1978-01-10 Frank T. Sullivan, Inc. Method and apparatus for controlling fluency of high viscosity hydrocarbon fluids
US6077400A (en) * 1997-09-23 2000-06-20 Imperial Petroleum Recovery Corp. Radio frequency microwave energy method to break oil and water emulsions
US20040134126A1 (en) * 2001-04-27 2004-07-15 Vizoso Ricardo Blach Method for plasma-catalytic conversion of fuels that can be used in an internal combustion engine or a gas turbine into a synthetic gas and the plasma-catalytic converter used for same
US20060054281A1 (en) * 2004-09-10 2006-03-16 Pingree Richard E Jr Hydrocarbon dielectric heat transfer fluids for microwave plasma generators
US20090078559A1 (en) * 2007-09-21 2009-03-26 Proudkii Vassilli P Method and apparatus for multiple resonant structure process and reaction chamber
US20130277045A1 (en) * 2012-04-19 2013-10-24 Harris Corporation Method of heating a hydrocarbon resource including lowering a settable frequency based upon impedance

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4067683A (en) * 1976-06-14 1978-01-10 Frank T. Sullivan, Inc. Method and apparatus for controlling fluency of high viscosity hydrocarbon fluids
US6077400A (en) * 1997-09-23 2000-06-20 Imperial Petroleum Recovery Corp. Radio frequency microwave energy method to break oil and water emulsions
US20040134126A1 (en) * 2001-04-27 2004-07-15 Vizoso Ricardo Blach Method for plasma-catalytic conversion of fuels that can be used in an internal combustion engine or a gas turbine into a synthetic gas and the plasma-catalytic converter used for same
US20060054281A1 (en) * 2004-09-10 2006-03-16 Pingree Richard E Jr Hydrocarbon dielectric heat transfer fluids for microwave plasma generators
US20090078559A1 (en) * 2007-09-21 2009-03-26 Proudkii Vassilli P Method and apparatus for multiple resonant structure process and reaction chamber
US20130277045A1 (en) * 2012-04-19 2013-10-24 Harris Corporation Method of heating a hydrocarbon resource including lowering a settable frequency based upon impedance

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10830017B2 (en) 2017-08-08 2020-11-10 Saudi Arabian Oil Company In-situ heating fluids with electromagnetic radiation
US11401782B2 (en) 2017-08-08 2022-08-02 Saudi Arabian Oil Company In-situ heating fluids with electromagnetic radiation
US10669814B2 (en) 2017-08-08 2020-06-02 Saudi Arabian Oil Company In-situ heating fluids with electromagnetic radiation
EP3953992A4 (fr) * 2019-04-05 2022-12-14 Pyrowave Inc. Coupleur pour systèmes de pyrolyse à micro-ondes
US11187044B2 (en) 2019-12-10 2021-11-30 Saudi Arabian Oil Company Production cavern
US11438976B2 (en) 2020-02-04 2022-09-06 Qwave Solutions, Inc. Apparatuses, systems, and methods for heating with electromagnetic waves
US11460330B2 (en) 2020-07-06 2022-10-04 Saudi Arabian Oil Company Reducing noise in a vortex flow meter
US11619097B2 (en) 2021-05-24 2023-04-04 Saudi Arabian Oil Company System and method for laser downhole extended sensing
US11725504B2 (en) 2021-05-24 2023-08-15 Saudi Arabian Oil Company Contactless real-time 3D mapping of surface equipment
CN115444954A (zh) * 2022-09-22 2022-12-09 四川大学 一种电磁场分布调节装置、微波加热装置以及加热方法
CN115444954B (zh) * 2022-09-22 2023-10-13 四川大学 一种电磁场分布调节装置、微波加热装置以及加热方法
CN115639222B (zh) * 2022-12-22 2023-03-31 河北科技大学 变频微波和uv协同处理有机污染物评价方法及评价装置
CN115639222A (zh) * 2022-12-22 2023-01-24 河北科技大学 变频微波和uv协同处理有机污染物评价方法及评价装置

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