WO2015110096A8 - Method of preparation of a soluble block copolymer of styrene and olefines, and use thereof - Google Patents

Method of preparation of a soluble block copolymer of styrene and olefines, and use thereof Download PDF

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Publication number
WO2015110096A8
WO2015110096A8 PCT/CZ2015/000004 CZ2015000004W WO2015110096A8 WO 2015110096 A8 WO2015110096 A8 WO 2015110096A8 CZ 2015000004 W CZ2015000004 W CZ 2015000004W WO 2015110096 A8 WO2015110096 A8 WO 2015110096A8
Authority
WO
WIPO (PCT)
Prior art keywords
styrene
preparation
block
c4alkylene
block copolymer
Prior art date
Application number
PCT/CZ2015/000004
Other languages
French (fr)
Other versions
WO2015110096A1 (en
Inventor
Jan Zitka
Jan Schauer
Miroslav Bleha
Karel BOUZEK
Martin PAIDAR
Jaromir HNAT
Original Assignee
Ustav Makromolekularni Chemie Av Cr, V. V. I.
Vysoka Skola Chemicko-Technologicka V Praze
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ustav Makromolekularni Chemie Av Cr, V. V. I., Vysoka Skola Chemicko-Technologicka V Praze filed Critical Ustav Makromolekularni Chemie Av Cr, V. V. I.
Publication of WO2015110096A1 publication Critical patent/WO2015110096A1/en
Publication of WO2015110096A8 publication Critical patent/WO2015110096A8/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/24—Haloalkylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/28—Polymers of vinyl aromatic compounds
    • B01D71/281—Polystyrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/80—Block polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/12—Ion-exchange processes in general; Apparatus therefor characterised by the use of ion-exchange material in the form of ribbons, filaments, fibres or sheets, e.g. membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/26—Polyalkenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/28—Polymers of vinyl aromatic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B01J35/59—Membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/08—Copolymers of styrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The present invention relates to the method of preparation of a soluble block copolymer poly(styrene-block-C2-C4alkylene-stat-C2-C4alkylene-block-styrene) chloromethylated into a chloromethylation degree higher than 35 %. The principle of this method lies in a reaction of the starting block copolymer poly(styrene-block-C2-C4alkylene-stat-C2-C4alkylene-block-styrene) with dimethoxymethane, a chlorinating agent, and ZnCl2 catalyst, preferably at the temperature in the range of from 10 °C to 65 °C, with no direct use of chloroalkyl ethers and with no side cross-linking reaction. The invention further describes the use of this method for the preparation of homogeneous or microheterogeneous anion-exchange membranes, particularly by chloromethylated solution casting, its reaction with trialkylamine or trialkylphosphine, and their use for electrode impregnation in electrochemical devices, as catalyst carriers, for preparation of ion-exchange membranes and binders in electrochemical devices, ion-exchange applications and catalytic systems.
PCT/CZ2015/000004 2014-01-24 2015-01-19 Method of preparation of a soluble block copolymer of styrene and olefines, and use thereof WO2015110096A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CZPV2014-56 2014-01-24
CZ2014-56A CZ201456A3 (en) 2014-01-24 2014-01-24 Process for preparing soluble block copolymer of styrene and olefins as well as use thereof

Publications (2)

Publication Number Publication Date
WO2015110096A1 WO2015110096A1 (en) 2015-07-30
WO2015110096A8 true WO2015110096A8 (en) 2015-09-11

Family

ID=52598538

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CZ2015/000004 WO2015110096A1 (en) 2014-01-24 2015-01-19 Method of preparation of a soluble block copolymer of styrene and olefines, and use thereof

Country Status (2)

Country Link
CZ (1) CZ201456A3 (en)
WO (1) WO2015110096A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ2020481A3 (en) 2020-09-01 2022-01-12 Ústav makromolekulární chemie AV ČR, v. v. i. Process for preparing a block copolymer
CZ309781B6 (en) 2022-06-03 2023-10-04 Ústav makromolekulární chemie AV ČR, v. v. i. An anion-exchange material based on block polymer of styrene and olefins

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1002121B (en) * 1973-11-29 1976-05-20 Montedison Spa PROCEDURE FOR THE CHLOROMETHYLATION OF COPOLYMERS STYRENE DIVINYL BENZENE
CS266062B1 (en) * 1988-01-18 1989-11-14 Jerabek Karel Method of polymere carrier production for peptides synthesis
US5629386A (en) * 1995-05-25 1997-05-13 Bayer Rubber Inc. Halomethylation of polymer
ATE381584T1 (en) * 2004-08-09 2008-01-15 Stichting Energie PROTON CONDUCTING COPOLYMERS
WO2008149950A1 (en) * 2007-06-05 2008-12-11 Tokuyama Corporation Hydrocarbon elastomer capable of oh type anion exchange, use thereof, and process for producing the same
WO2010038306A1 (en) * 2008-10-03 2010-04-08 日本化薬株式会社 Polyethersulfone polymer electrolyte, solid polymer electrolyte membrane, fuel cell, and method for production of the polyethersulfone polymer electrolyte

Also Published As

Publication number Publication date
CZ305138B6 (en) 2015-05-13
WO2015110096A1 (en) 2015-07-30
CZ201456A3 (en) 2015-05-13

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