WO2015096834A1

WO2015096834A1 - Agent and method for the temporary shaping of keratin fibers

Info

Publication number: WO2015096834A1
Application number: PCT/DE2014/200535
Authority: WO
Inventors: Jisook Baek; Anna Henschel
Original assignee: Henkel Ag & Co. Kgaa
Priority date: 2013-12-23
Filing date: 2014-10-08
Publication date: 2015-07-02
Also published as: DE102013227119A1

Abstract

The invention relates to pulverulent cosmetic compositions containing: a) between 10 and 30 wt.-% hydrophobic metal oxide powder; b) between 40 and 89 wt.-% polar solvent; and c) between 0.001 and 8.0 wt.-% dye. Said compositions are particularly suitable for the shaping and scenting of keratin fibers and provide shine, texture and silkiness.

Description

"Means and Method of Temporarily Deforming Keratinous Fibers"

The application relates to the technical field of temporary deformation keratinhaltiger fibers, especially human hair.

Styling agents for the deformation of keratin-containing fibers have long been known and find use in various embodiments for the construction, for refreshing and for fixing hairstyles, which can be obtained in many hair types only using firming agents. Both hair treatment products, which serve a permanent, as well as those that serve a temporary shaping of the hair, play an important role. Temporary shapes, which should give a good grip, without affecting the healthy appearance of the hair, such as their gloss, can be achieved for example by hair sprays, hair waxes, hair gels, hair drier, etc.

Corresponding temporary shaping agents usually contain synthetic polymers as the shaping component. Preparations containing a polymer can be applied to the hair by means of propellants or by a pumping mechanism. Hair gels and hair waxes, however, are usually not applied directly to the hair, but distributed by means of a comb or hands in the hair.

Known forms of temporary styling agents often can not be dosed with satisfactory accuracy. For example, hair gels, hair creams and hair waxes are difficult to disperse once they are applied to the hair.

Hair sprays can be distributed more evenly over the hair. However, since the user has no ability to visually detect the total amount of styling agent applied, there is a risk that more styling agent will be applied to the hair than would actually be required.

Powdered cosmetics are known and have been used for some time in the field of skin treatment for example. Typical examples include make-up powder or eye shadow. In order to achieve the powdery consistency, the use of a powdery carrier material is required. As a suitable carrier material may be used, for example, a metal oxide such as silicon dioxide. Hydrophoborated metal oxide or silicon dioxide is of particular interest. This can be obtained, for example, starting from fumed silica, which is commercially available in various specifications. On the surface, untreated fumed silica carries silanol and siloxane groups. As a result, it has a high affinity for water, ie it is hydrophilic. By reaction with suitable organic Silicon compounds can chemically bind alkylsilyl groups on the surface of the fumed silica. This results in modified silica powder, which are no longer wetted by water, ie have the hydrophobic properties. These hydrophobicized silica are suitable for the production of so-called dry water, in which the water droplets are prevented from re-merging. The resulting powdery solids may have water content of up to 95%. Under mechanical stress, for example rubbing on the skin, the trapped water is released again.

Cosmetic or pharmaceutical liquefiable powder compositions are described, for example, in European Patent EP 1 235 554 B1.

International application WO 03/037287 A1 discloses the use of granules based on pyrogenic silicon dioxide in cosmetic compositions. The specific granules can be silanized, i. be hydrophobic and are suitable for the preparation of cosmetic compositions of any consistency, such as liquids, foams, sprays or powders.

The international application WO 2007/05151 1 A1 describes the use of a pulverulent composition containing 50 to 95 wt .-% of an aqueous solvent, hydrophobized silica powder and at least in the aqueous solvent located film-forming and / or setting polymer for the temporary deformation of keratinous fibers. The German patent application DE102008057261 A1 has powdered compositions which are used for the temporary forming of hair for very strong hold the fixed hairstyle.

Although the powdered hair cosmetics of the prior art have now been acceptable for hair shaping hold and are characterized by a good metering. However, the result achieved with these agents in terms of the parameters of natural gloss as well as the elasticity and the hold is in need of improvement as well as their applicability, for example by hand and hair. At the same time remain visible in the application of the previously known powdered hair cosmetics due to the sometimes difficult application to the naked eye visible product particles on the hair and disturb the appearance.

Object of the present invention was therefore to provide storage-stable powdered hair treatment compositions for temporary shaping available that can be precisely and easily dose and apply, bring no adverse effects on the appearance of the hairstyle by visible product residues, the hair does not stick to the hair give a fuller and natural feel and natural shine. The durability of the styling result should not be affected.

It has been found that powdery cosmetic compositions based on a polyol-emulsifier mixture solve the aforementioned object. A first subject of the present application are powdered cosmetic compositions containing

a) 10 to 30 wt .-% hydrophobized metal oxide powder

b) 40 to 89 wt .-% polar solvent

c) from 0.001 to 8.0% by weight of colorant.

The pulverulent compositions according to the invention are preferably in the form of core-shell particles whose shell contains particles of at least one hydrophobized metal oxide powder and whose liquid core contains organic polyol and optionally water.

According to the invention, particles are particles which are present as grains (see DIN 66160: 1992-09) of solids.

For the purposes of the invention, powders are compositions whose particles are freely free-flowing under their own weight (see DIN EN ISO 6186: 1998-08).

The pulverulent compositions according to the invention are characterized in that the liquid core is released from the core-shell particle by mechanical loading of the core-shell particles, in particular by friction and / or pressure, and thereby the powdered composition becomes a liquid forms. It is thus a powdered powder-to-liquid composition. The pulverulent compositions according to the invention can be metered very easily. They can also be very evenly distributed in the hair, since the liquid core is released only under mechanical stress at the site of action and targeted wetting of the hair fibers is possible. The powder can therefore be first carefully distributed in the hair and only then be subjected to mechanical stress, for example, by targeted massaging the powder into the hair. As a result, the styling effect is only deployed directly on the desired hair part.

The powdered compositions used contain hydrophobized metal oxide. Preferred compositions are characterized in that they contain the hydrophobized metal oxide powder in amounts of from 10 to 25, preferably from 12 to 22,% by weight, based on their total weight. The optimum amount depends primarily on the hydrophobicity of the silica powder used. The more hydrophobic the silica powder is, the less of it is needed to obtain a stable, powdered product. The nature of the hydrophobicized metal oxide is not limited in principle, as long as it is ensured that the intense mixing with the liquid, aqueous phase results in a powdery product. For the purposes of the invention, hydrophobed are to be understood as meaning those metal oxides which have been modified at least on the surface of the particles in such a way that the modified particle is wetted less by water than the unmodified particle. In particular, silanized, hydrophobized metal oxides are preferred. As reagent for the silanization of the metal oxide, according to the invention, at least one member of the group which is formed, from silanes, halosilanes, alkoxysilanes and silazanes is preferably suitable. Preferred hydrophobized metal oxides of the hydrophobized metal oxide powder are selected according to the invention from at least one member of the group formed from hydrophobized silicates, hydrophobicized aluminum silicates, hydrophobized titanium dioxide and hydrophobized silica. Hydrophoborated silicates have proved particularly suitable for the preparation of the cosmetic compositions according to the invention, with fumed silica aftertreated by silanization or by reaction with polydimethylsiloxane having particular advantages.

The powdered compositions used preferably contain hydrophobized silica. The nature of the hydrophobicized silica is not limited in principle, as long as it is ensured that the intensive mixing with the polyol b), the copolymer c) and optionally other ingredients, a powdered product is formed.

The pulverulent composition according to the invention particularly preferably contains as hydrophobized metal oxide powder at least silanized, hydrophobized silicon dioxide.

As a reagent for silanizing the silicon dioxide, at least one member of the group which is formed from silanes, halosilanes, alkoxysilanes and silazanes is preferably suitable according to the invention.

Preferred representatives of the group of silanes are hexa (C 1 -C 20) alkyldisilanes, in particular hexamethyldisilane.

When a halosilane is used as the silylating agent, as the preferred halosilane, at least one compound selected from the group consisting of the compounds is selected

[(C 1 -C 20) alkyl] z ^< SiX (4-z ^< )

X ₃ Si [(CH ₂ ) n R]

X ₂ [(C ₁ -C 20) alkyl] Si (CH ₂ ) n R

[(C 1 -C 20) alkyl] (y ^< ₊ i) [R- (CH 2) n] (2-y) SiX

wherein X represents a chlorine, bromine or iodine atom,

z 'is a number 1, 2 or 3,

y 'is a number 0, 1 or 2

n is an integer from 1 to 20 and

R stands for a rest

(C 1 -C 10) alkyl, aryl, (C 1 -C 6) perfluoroalkyl, -NH ₂ , -N ₃ , -SCN, -CH = CH ₂ ,

-0 (0) CC (CH ₃ ) = CH ₂ , -OCH ₂ -CH = CH ₂ ,

-NHC (0) -NC (0) - (CH ₂ ) s

I i

-NH-C (O) O-Me, -NH-C (O) O-Et, -NH- (CH ₂ ) 3-Si (O (C 1 -C ₆ ) alkyl) 3.

When an alkoxysilane is used as the silylating agent, as the preferred alkoxysilane, at least one compound selected from the group consisting of the compounds is selected

[(C ₁ -C ₂₀ ) alkylO] z Si (C ₁ -C ₂₀ ) alkyl (4-z)

[(C 1 -C ₂₀ ) alkylO] z Si [(CH ₂ ) n R] ₍ 4-z)

[(C 1 -C ₂₀ ) alkylO] ₂ [(C 1 -C ₂₀ ) alkyl] Si (CH ₂ ) n R

[(Ci-C ₂ o) alkylO] _[(Ci-C20) alkyl] ₂ Si (CH ₂₎ n

[(C 1 -C ₂₀ ) alkylO] [(C 1 -C ₂₀ ) alkyl] Si [(CH ₂ ) n R] ₂

(Ci-C ₂ oAlkyl) ₃ SiO-C (CH 3) = N-Si (Ci-C ₂ o) Alkyl3,

wherein

n is an integer from 1 to 20 and

z is a number 1, 2, or 3

R stands for a rest

(C 1 -C ₂₀ ) alkyl, aryl, (C 1 -C 6) perfluoroalkyl, -NH ₂ , -N ₃ , -SCN, -CH = CH ₂ ,

-0 (0) CC (CH ₃ ) = CH ₂ , -OCH ₂ -CH = CH ₂ ,

-NHC (O) -NC (0) - (CH ₂ ) ₅

I i

-NH-C (O) O-Me, -NH-C (O) O-Et, -NH- (CH ₂ ) ₃ -Si (O (C 1 -C ₆ ) alkyl) ₃ .

As a preferred silazane is at least one compound from the class of disilazanes, in particular at least one compound of disilazanes of the formula

R ' ₂ R "Si-NH-SiR' ₂ R"

selected in which

R 'is a (Ci-C ₂ o) alkyl group and

R "represents a (C ₁ -C 20) alkyl group or a vinyl group, a particularly preferred silazane being hexamethyldisilazane.

All of the abovementioned alkyl groups, whether (C ₁ -C 6) -alkyl, (C ₁ -C 10) -alkyl or (C ₁ -C 20) -alkyl, may be both cyclic and linear or branched. Examples of usable according to the invention Alkyl groups are methyl, ethyl, n-propyl, isopropyl, n-butyl, cyclopentyl, cyclohexyl, n-decyl,

Lauryl, myristyl, cetyl, stearyl, isostearyl and behenyl.

An example of an aryl group according to the invention is the phenyl group.

Examples of a (Ci-C6) perfluoroalkyl group according to the invention are trifluoromethyl, perfluoroethyl, perfluoropropyl and perfluorohexyl.

Preference is given to using hydrophobized silicon dioxides which are obtained by silanization of fumed silica.

Silanized hydrophobized silicas are particularly preferably selected from at least one compound of the group formed from trimethylsilylate-coated silica, dimethylsilylate-coated silica, octylsilylate-coated silica.

Preference is given to using hydrophobicized silicas obtained by silanization of fumed silica.

A variety of suitable hydrophobized silicas are commercially available. Examples include Aerosil® R104 V, Aerosil® R106, Aerosil® R202, Aerosil® R805, Aerosil® R812, Aerosil® R812S, Aerosil® R972 and Aerosil® R8200, all Degussa, as well as HDK® H2000, HDK® H2050 and HDK® H3004 , all Wacker, called.

Particular preference is given to using the hydrophobized silicas available under the names Aerosil® R202, Aerosil® R812S or Aerosil® R972. Very particular preference is given to using the silica with the INCI name Silica Silyiate, which is marketed by Degussa under the name Aerosil® R812S.

Preferred compositions according to the invention are therefore characterized in that they contain as hydrophobized metal oxide powder a hydrophobized silicate, preferably a polydimethylsiloxane aftertreated fumed silica. Corresponding metal oxides with the INCI name "Silica Dimethicone Silyiate" are sold, for example, by Evonik under the trade name Aersoil® R202.

The particle diameter of the primary particles of preferred hydrophobized metal oxides is preferably less than 5 μm, particularly preferably less than 1 μm, and in particular between 1 and 50 nm. Preference is furthermore given to those hydrophobicized silicon dioxides which have a BET specific surface area of between 10 and 400 m ² / g, preferably between 40 and 300 m ² / g and in particular between 80 and 150 m ² / g.

The pulverulent compositions according to the invention contain as the second essential constituent a polar solvent. Preferred compositions contain the polar solvent based on their total weight in amounts of from 42 to 88% by weight, preferably from 45 to 87% by weight.

As a polar solvent Einzelsubtanzen or mixtures of substances can be used. Preferred polar solvents besides water are the polyols.

Preferred agents according to the invention are characterized in that they contain less than four, preferably one to three, but in particular only one polyol. Polyols from the group of glycerol, 1,2-ethanediol, polyethylene glycols with MW> 400 are particularly suitable for the preparation of cosmetic compositions. Propanediol, butanediol, in particular 1,3-butanediol, hexanediol, especially hexane-1,6-diol, sorbitol, threitol, erythritol, Arabitol, altritol, ribitol, xylitol, galactitol, mannitol, iditol and panthenol. Particularly suitable organic polyols are glycerol, sorbitol and panthenol. These polyols can be converted into a powder form by comparatively small amounts of hydrophobized metal oxide powder, generally containing less than 10% by weight of metal oxide powder (based on the total weight of the pulverulent, chemical composition). Preferred compositions according to the invention are therefore characterized in that they contain as organic polyol at least one compound from the group of glycerol, sorbitol and panthenol, preferably glycerol.

In summary, those compositions are preferred which contain as polar solvent b) at least one solvent from the group consisting of water and glycerol, preferably water.

The proportion by weight of the polar solvent in general and of the polyol in particular may vary within wide limits.

Particular preference is given to compositions according to the invention which contain primarily or exclusively water as the polar solvent. Corresponding preferred compositions are characterized in that they are based on their total weight - 60 to 88 wt .-%, preferably 65 to 87 wt .-% water and

less than 10% by weight, preferably less than 5% by weight, preferably less than 1% by weight, of glycerol.

In compositions according to the invention having a low polyol content, it is preferred to add a further polar solvent to the compositions in the balance, wherein the addition of water is particularly preferred. Preferred compositions are therefore characterized by being based on their total weight

- 12 to 30 wt .-%, preferably 15 to 25 wt .-% of organic polyol b) and

- 40 to 75 wt .-%, preferably 50 to 70 wt .-% water.

When using a large proportion by weight of the polyol, the addition of further polar solvent, in particular the addition of water, is dispensed with as far as possible. Corresponding compositions preferred according to the invention are characterized in that they are based on their total weight

- 60 to 88 wt .-%, preferably 65 to 87 wt .-% organic polyol b) and

less than 10% by weight, preferably less than 5% by weight, preferably less than 1% by weight of water.

The addition of the polyol improves the mechanical properties of compositions according to the invention during storage and application and has advantageous cosmetic effects.

As a third essential, the composition according to the invention contains from 0.001 to 8.0% by weight of dye and / or pigment. Dyes in the context of the invention are in the polar solvent b), especially in water, soluble colorants, while as pigments such colorants are referred to, which are insoluble in the polar solvent b), in particular water.

Suitable dyes are inorganic and organic coloring substances. The dyes are preferably water-soluble.

In a particular embodiment, the composition of the invention contains at least one dye from the group of substantive dyes. Direct dyes can be subdivided into anionic, cationic and nonionic substantive dyes. The substantive dyes are preferably selected from the Nitrophenylendiaminen, the Nitroaminophenolen, the azo dyes, the anthraquinones or the indophenols and their physiologically acceptable salts.

2,4-dinitro-1-naphthol-7-sulfonic acid disodium salt (Cl 10,316, Acid Yellow 1, Food Yellow No. 1), 2- (indan-1, 3-dione-2) are particularly suitable as anionic substantive dyes. yl) quinoline-x, x-sulfonic acid (mixture of mono- and disulfonic acid) (Cl 47.005, D & C Yellow No. 10, Food Yellow No. 13, Acid Yellow 3, Yellow 10), 5-hydroxy-1 - (4- sulfophenyl) -4 - [(4-sulfophenyl) azo] pyrazole-3-carboxylic acid trisodium salt (Cl 19, 140; Food Yellow No. 4; Acid Yellow 23), 3 - [(4-phenylamino) phenyl] azobenzenesulfonic acid sodium salt ( Cl 13.065; Ki406; Acid Yellow 36), 4 - [(2-hydroxynaphth-1-yl) azo] -benzenesulfonic acid, sodium salt (Cl 15.510, Acid Orange 7), 6-hydroxy-5 - [(4-sulfonaphth-1 -yl) azo] -2,4-naphthalenedisulfonic acid trisodium salt (Cl 16,255; Ponceau 4R; Acid Red 18), 8-amino-1-hydroxy-2- (phenylazo) -3,6-naphthalenedisulfonic acid disodium salt (Cl 17,200; Acid Red 33; Red 33), N- [6- (diethylamino) -9- (2,4-disulfophenyl) -3H-xanthen-3-ylidene] -N-ethylethanammonium hydroxide, inner salt, sodium salt (C.I. 45.100; Acid Red 52), 2 ', 4', 5 ', 7'-tetrabromo-4,5,6,7-tetrachloro-3', 6'-dihydroxyspiro [isobenzofuran-1 (3H), 9 '[9H] xanthene ] -3-one disodium salt (Cl 45.410; Acid Red 92), 3-hydroxy-4 - [(4-methyl-2-sulfonphenyl) azo] -2-naphthalenecarboxylic acid calcium salt (Cl 15.850: 1, Pigment Red 57: 1), 1, 4-bis [(2-sulfo-4-methylphenyl) amino] -9,10-anthraquinone disodium salt (Cl 61, 570; Acid Green 25), bis [4- (dimethylamino) phenyl] - ( 3,7-disulfo-2-hydroxynaphth-1-yl) carbenium inner salt, sodium salt (CI 44.090, Food Green No. 4, Acid Green 50), N- [4 - [(2,4-disulfophenyl) [4 [ethyl (phenylmethyl) amino) phenyl] methylene] -2,5-cyclohexadiene-1-ylidene] -N-ethylbenzenemethanamine hydroxide, inner salt, sodium salt (CI 42.080, Acid Blue 7), (2-sulfophenyl) di [ 4- (ethyl ((4-sulfophenyl) methyl) amino) phenyl] -carbenium disodium salt betaine (CI 42.090, Acid Blue 9, FD & C Blue No. 1), 1-amino-4- (cyclohexylamino) -9,10- anthraquinone-2-sulfonic acid, sodium salt (Cl 62045; Acid Blue 62), 1-hydroxy-4 - [(4-methyl-2-sulfoph enyl) amino] - 9,10-anthraquinone sodium salt (C.I. 60.730; D & C Violet No. 2; Acid Violet 43), 5-amino-4-hydroxy-6 - [(4-nitrophenyl) -azo] -3- (phenylazo) -2,7-naphthalenedisulfonic acid disodium salt (Cl 20,470, Acid Black 1), 3 -Hydroxy-4 - [(2-hydroxynaphth-1-yl) azo] -7-nitro-1-naphthalenesulfonic acid chromic complex (3: 2) (Cl 15,711; Acid Black 52), 3 ', 3 ", 4 , 5,5 ', 5 ", 6,7-Octabromphenolsulfon- phthalein (tetrabromophenol blue).

Preferred anionic substantive dyes are those having the international designations or trade names Acid Yellow 1, Acid Yellow 10, Acid Yellow 23, Acid Yellow 36, Acid Orange 7, Acid Red 33, Acid Red 52, Pigment Red 57: 1, Acid Blue 7 , Acid Green 50, Acid Violet 43, Acid Black 1 and Acid Black 52 known compounds. Suitable cationic substantive dyes are, in particular, di [4- (diethylamino) phenyl] [4- (ethylamino) naphthyl] carbenium chloride (CI 42,595, Basic Blue 7), di [4- (dimethylamino) phenyl] [4- (phenylamino ) naphthyl] carbenium chloride (Cl 44.045; Basic Blue 26), 8-amino-2-bromo-5-hydroxy-4-imino-6 - [(3- (trimethylammonio) phenyl) amino] -1 (4H) - naphthalene chloride (Cl 56.059, Basic Blue No. 99), tri (4-amino-3-methylphenyl) carbenium chloride (Cl 42.520, Basic Violet 2), di (4-aminophenyl) (4-amino-3-methylphenyl ) carbenium chloride (Cl 42.510 Basic Violet 14), 1 - [(4-aminophenyl) azo] -7- (trimethylammonio) -2-naphthol chloride (Cl 12.250, Basic Brown 16), 1 - [(4-amino-3 -nitrophenyl) azo] -7- (trimethylammonio) -2-naphthol chloride (Cl 12,251, Basic Brown 17),

3- [(4-Amino-2,5-dimethoxyphenyl) azo] -N, N, N-trimethylbenzylaminium chloride (Cl 12,605, Basic Orange 69), 2 - [((4-dimethylamino) phenyl) azo] -1 , 3-dimethyl-1H-imidazolium chloride (Basic Red 51), 2-hydroxy-1 - [(2-methoxyphenyl) azo] -7- (trimethylammonio) -naphthalene chloride (Cl 12.245, Basic Red 76), 2- [4-Aminophenyl] azo] -1,3-dimethyl-1 H -imidazolium chloride (Basic Orange 31), 3-methyl-1-phenyl-4 - [(3- (trimethylammonio) phenyl) azo] -pyrazole 5-on chloride (Cl 12,719, Basic Yellow 57), 1-methyl-4 - ((methylphenylhydrazono) methyl) pyridinium methylsulfate (Basic Yellow 87), 1- (2-morpholiniumpropylamino) -4-hydroxy-9, 10-anthraquinone methylsulfate, 4-formyl-1-methylquinolonium p-toluenesulfonate and substantive dyes containing a heterocycle having at least one quaternary nitrogen atom.

Suitable nonionic substantive dyes are in particular nonionic nitro and quinone dyes and neutral azo dyes.

Particularly suitable blue nitro dyes are 1,4-bis [(2-hydroxyethyl) amino] -2-nitrobenzene (HC Violet BS), 1- (2-hydroxyethyl) amino-2-nitro-4- [di (2-hydroxyethyl) amino] benzene (HC Blue 2),

4- [di (2-hydroxyethyl) amino] -1 - [(2-methoxyethyl) amino] -2-nitrobenzene (HC Blue 11), 4- [ethyl- (2-hydroxyethyl) amino] -1 - [( 2-hydroxyethyl) amino] -2-nitrobenzene hydrochloride (HC Blue 12), 1- (2-hydroxyethyl) amino-2-nitro-4-N-ethyl-N- (2-hydroxyethyl) aminobenzene (HC Blue 15) , 1-Amino-3-methyl-4 - [(2-hydroxyethyl) amino] -6-nitrobenzene (HC Violet 1), 1- (3-hydroxypropylamino) -4- [di (2-hydroxyethyl) amino] -2 nitrobenzene (HC Violet 2).

Suitable red nitro dyes are in particular 1-amino-4 - [(2-hydroxyethyl) amino] -2-nitrobenzene (HC Red 7), 2-amino-4,6-dinitrophenol (pikramic acid) and their salts, 1, 4-diamino -2-nitrobenzene (Cl 76.070), 4-amino-2-nitro-diphenylamine (HC Red 1), 1-amino-4- [di (2-hydroxyethyl) amino] -2-nitrobenzene hydrochloride (HC Red 13) , 1-Amino-4 - [(2-hydroxyethyl) amino] -

5-chloro-2-nitrobenzene, 4-amino-1 - [(2-hydroxyethyl) amino] -2-nitrobenzene (HC Red 3), 4 - [(2-hydroxyethyl) amino] -3-nitrotoluene, 4- Amino-3-nitrophenol, 4 - [(2-hydroxyethyl) amino] -3-nitrophenol, 4 - [(2-nitrophenyl) amino] phenol (HC Orange 1), 1 - [(2-aminoethyl) amino] - 4- (2- hydroxyethoxy) -2-nitrobenzene (HC Orange 2), 1-amino-5-chloro-4 - [(2,3-dihydroxypropyl) amino] -2-nitrobenzene (HC Red 10), 5-chloro-1, 4- [di (2,3-dihydroxypropyl) amino] -2-nitrobenzene (HC Red 1 1), 2- [(2-hydroxyethyl) amino] -4,6-dinitrophenol and its salts, 4-ethylamino-3-nitrobenzoic acid, 2- [(4-Amino-2-nitrophenyl) amino] benzoic acid, 2-chloro-6-ethylamino-4-nitrophenol, 2-amino-6-chloro-4-nitrophenol, 4 - [(3-hydroxypropyl) amino ] -3-nitrophenol (HC Red BN), 1, 2,3,4-tetrahydro-6-nitroquinoxaline, 6-hydroxy-5 - ((2-methoxy-5-methyl-4-sulfophenyl) azo) - 2- naphthalenesulfonic acid (Curry Red).

Particularly suitable yellow nitro dyes are 1,2-diamino-4-nitrobenzene (Cl 76.020), 1 - [(2-hydroxyethyl) amino] -2-nitrobenzene (HC Yellow 2), 1- (2-hydroxyethoxy) -2- [ (2-hydroxyethyl) amino] -5-nitrobenzene (HC Yellow 4), 1-amino-2 - [(2-hydroxyethyl) amino] -5-nitrobenzene (HC Yellow 5), 4- [(2,3-dihydroxypropyl ) -amino] -3-nitro-1-trifluoromethylbenzene (HC Yellow 6), 2 - [(2-hydroxyethyl) amino] -1-methoxy-5-nitrobenzene, 2-amino-4-nitrophenol, 1 - (2-Hydroxyethoxy) -3-methylamino-4-nitrobenzene, 2,3- (dihydroxypropoxy) -3-methylamino-4-nitrobenzene, 3 - [(2-aminoethyl) amino] -1-methoxy-4-nitrobenzene hydrochloride (HC Yellow 9), 1-chloro-2,4-bis [(2-hydroxyethyl) amino] -5-nitrobenzene (HC Yellow 10), 2 - [(2-hydroxyethyl) amino] -5-nitrophenol (HC Yellow 1 1), 1 - [(2'-ureidoethyl) amino] -4-nitrobenzene, 1-amino-4 - [(2-aminoethyl) amino] -5-methyl-2-nitrobenzene, 4 - [(2-hydroxyethyl ) amino] -3-nitro-1-methylbenzene, 1-chloro-4 - [(2-hydroxyethyl) amino] -3-nitrobenzene (HC Yellow 12), 4 - [(2-hydroxyethyl) amino] -3- nitro-1-trifluoromethylbenzene (HC Yellow 13).

Suitable quinone dyes are, in particular, 1 - [(2-hydroxyethyl) amino] -4-methylamino-9,10-anthraquinone (Cl 61, 505, Disperse Blue 3), mixtures of 1,4-bis [(2-hydroxyethyl) amino] anthra-9,10-quinone with 1 - [(2-hydroxyethyl) amino] -4 - [(3-hydroxypropyl) amino] anthra-9,10-quinone and 1,4-bis [(3-hydroxypropyl) amino] anthra-9,10-quinone (Disperse Blue 377), 1,4-diamino-9,10-anthraquinone (Cl 61, 100, Disperse Violet 1), 1-amino-4- (methylamino) -9,10-anthraquinone (Cl 61, 105, Disperse Violet 4, Solvent Violet No. 12), 2-hydroxy-1,4-naphthoquinone (Lawsone, Cl 75,480, Natural Orange 6), 1,4-bis [(2,3-dihydroxypropyl) amino] -9,10-anthracenedione (HC Blue 14).

Suitable neutral azo dyes are, in particular, 1- [di (2-hydroxyethyl) amino] -3-methyl-4 - [(4-nitrophenyl) azo] benzene (Cl 11, 210, Disperse Red 17), 1- [di ( 2-hydroxyethyl) amino] -4 - [(4-nitrophenyl) azo] benzene (Disperse Black 9), 4 - [(4-aminophenyl) azo] -1- [di (2-hydroxyethyl) amino] -3- methylbenzene (HC Yellow 7), 2,6-diamino-3 - [(pyridin-3-yl) azo] -pyridine, 4 - [(4-nitrophenyl) azo] aniline (Cl 11, 005, Disperse Orange 3) ,

Other preferred dyes are selected from the group cationic (basic) dyes, preferably Basic Blue 6, Cl-No. 51, 175; Basic Blue 7, Cl-No. 42.595; Basic Blue 9, Cl-No. 52.015; Basic Blue 26, Cl-No. 44.045; Basic Blue 41, Cl-No. 1 1, 154; Basic Blue 99, Cl-No. 56.059; Basic Brown 4, Cl-No. 21, 010; Basic Brown 16, Cl-No. 12.250; Basic Brown 17, Cl-No. 12,251; Basic Green 1, Cl-No. 42.040; Basic Orange 31; Basic Red 2, Cl-No. 50.240; Basic Red 22, Cl-No. 11, 055; Basic Red 46; Basic Red 51; Basic Red 76, Cl-No. 12.245; Basic Violet 1, Cl-No. 42.535; Basic Violet 2; Basic Violet 3, Cl-No. 42.555; Basic Violet 10, Cl-No. 45.170; Basic Violet 14, Cl- No. 42.510; Basic Yellow 57, Cl-No. 12.719; Basic Yellow 87 and / or

the anionic (acidic) dyes, and / or the nonionic dyes, preferably Acid Black 1, C.l. 20.470; Acid Black 52; Acid Blue 7; Acid Blue 9, C.I. 42.090; Acid Blue 74, C.I. 73.015, Acid Red 18, C.I. 16.255; Acid Red 23; Acid Red 27, C.I. 16.185; Acid Red 33; Acid Red 52; Acid Red 87, C.I. 45,380; Acid Red 92, C.I. 45,410; Acid Orange 3; Acid Orange 7; Acid Violet 43, C.I. 60.730; Acid Yellow 1, C.I. 10.316; Acid Yellow 10; Acid Yellow 23, C.I. 19,140; Acid Yellow 3, C.I. 47.005; Acid Yellow 36; D & C Brown no. 1, C.I. 20.170 (Acid Orange 24); D & C Green no. 5, C.I. 61, 570 (Acid Green G); D & C Orange No. 4, C.I. 15.510 (Acid Orange II); D & C Orange No. 10, C.I. 45.425: 1 (Solvent Red 73); D & C Orange No. 1 1, C.I. 45.425 (Acid Red 95); D & C Red No. 21, C.I. 45.380: 2 (Solvent Red 43); D & C Red No. 27, C.I. 45.410: 1 (Solvent Red 48); D & C Red No. 33, C.I. 17,200 (Acid Red 2A, Acid Red B); D & C Yellow No. 7, C.I. 45.350: 1 (Solvent Yellow 94); D & C Yellow No. 8, C.I. 45,350 (Acid Yellow 73); FD & C Red No. 4, C.I. 14,700 (Food Red 4); FD & C Yellow No. 6, C.I. 15,985 (Food Yellow 3); Food Green 3; Pigment Red 57-1; Disperse Black 9; Disperse Blue 1; Disperse Blue 3; Disperse Violet 1; Disperse Violet 4; HC Orange 1; HC Red 1; HC Red 3; HC Red 13; HC Yellow 2; HC Yellow 4; Na-Pikramat; 1, 4-bis (2'-hydroxyethyl) amino-2-nitro-p-phenylenediamine; HC Yellow 5; HC Blue 2; HC Blue 12; 4-amino-3-nitrophenol; HC Yellow 6; HC Yellow 12; 2-nitro-1- (2'-hydroxyethyl) amino-4-methyl benzene; 2-nitro-4-amino-diphenylamine-2-carboxylic acid; 2-amino-6-chloro-4-nitrophenol; HC Red BN; 6-nitro-1,2,3,4-tetranitroquinoxaline; o-nitro-p-phenylenediamine; p-nitro-m-phenylenediamine; HC Red B 54; HC Red 10; HC Red 1 1; HC Red 13; 2- (2'-hydroxyethyl) amino-1-hydroxy-4,6-dinitrobenzene; 4-ethylamino-3-nitrobenzoic acid; 2-chloro-6-ethylamino-4-nitrophenol; 2-hydroxy-1, 4-naphthoquinone; amine-1-propene (4-amino-2-nitrophenyl); isatin; N-methylylisatin; HC Violet 1; HC Violet 2; 4-nitrophenyl aminoethylharnstoff.

Preferred compositions are characterized in that the colorant c) is selected from the group of the dyes, preferably the water-soluble dyes, wherein the Weight fraction of the colorant c) in the total weight of the composition 0.001 to 1, 0 wt%, preferably 0.001 to 0.8 wt .-% and in particular 0.001 to 0.5 wt .-% is.

Particularly preferred compositions contain, based on their total weight

From 60 to 88% by weight, preferably from 65 to 87% by weight, of organic polyol b), preferably glycerol;

less than 10% by weight, preferably less than 5% by weight, preferably less than 1% by weight of water;

- 0.001 to 1, 0 wt .-%, preferably 0.001 to 0.8 wt .-% and in particular 0.001 to 0.5 wt .-% dye.

A second group of preferred coloring substances form the preferably water-insoluble pigments. In one preferred embodiment of the invention, the inorganic or organic pigment is selected from the group consisting of mineral pigments, metal pigments, pearlescent pigments, organic colored pigments and carbon blacks. If the pigments are metal oxides, these metal oxides are different from the hydrophobized metal oxide powder a).

Inorganic pigments include naturally occurring and obtainable by mechanical treatment and synthetic pigments.

Mineral pigments or natural inorganic pigments contain predominantly sulfides and oxides. Preferred natural pigments are ocher (Fe (OOH), Pigment Yellow 43), calcined Siena (Fe203, Pigment Red 102), Umbra (Fe2Ü3 ΧΜΠΟΣ, Pigment Brown 7: x), Vermilion (β-HgS, PR 106), Lapis Lazuli ( Ultramarine, Na 6 Al 16 Si 6024 ^■ Na 2 S _n ; Pigment Blue 29), azurite (basic copper carbonate, Cu 3 [OH / CO 3] 2, PB 30), green earth (FeO-containing silicate, Pigment Green 23), malachite (Cu ₂ [(OH) ₂ , C0 ₃ ]) and carbon black (carbon (graphite), Pigment Black 9).

One group of particularly preferred pigments are the coloring synthetic iron oxides. Particularly preferred representatives of this class of substances are Pigment Black 11 (Cl No 77499), Pigment Brown 6 (Cl No 77491), Pigment Red 101 (Cl No 77491), Pigment Yellow 42 (Cl No 77492), and mixtures of these pigments.

Synthetic inorganic pigments are obtained in particular by chemical and / or physical conversion (digestion, precipitation, annealing). These include in particular: - white pigments (titanium dioxide (TiO ₂ ), Pigment White PW 6, zinc sulfide (ZnS), PW 7, zinc oxide (ZnO), PW 4; Antimony white (Sb ₂ 0 ₃ ), PW 11; Lithopone (ZnS / BaS0 ₄ ), PW 5; Lead white (2PbC0 ₃ ^■ Pb (OH) ₂ ), PW 1),

subordinate white fillers (calcium carbonate, PW 18, talc, PW 26 and barium sulfate, PW 21);

Black pigments (manganese black, spinel black and carbon blacks (graphite carbon);

Luster pigments (absorption pigments, metal pigments or metallic effect pigments and pearlescent pigments) and

- inorganic colored pigments (iron oxide pigments, iron blue pigments, ultramarine pigments and less suitable due to their toxicological properties lead chromate pigments, chromium oxide pigments, cadmium pigments and bismuth vanadate pigments).

Pearlescent pigments are luster pigments that consist of several layers of different refractive indices. Pearlescent pigments which are preferred according to the invention are magnesium stearate, zinc stearate and lithium stearate or ethylene glycol distearate or polyethylene terephthalate and also pearlescent pigments which consist essentially of mica, titanium dioxide (titanium dioxide mica), bis-chloride chloride oxide or guanine and, moreover, with colored oxide layers (eg iron oxides or chromium oxides). can be covered.

Pearlescent pigments based on mica and on mica / metal oxide are, according to the invention, particularly preferred pearlescent pigments. Mica belongs to the layered silicates. The most important representatives of these silicates are muscovite, phlogopite, paragonite, biotite, lepidolite and margarite. To produce the pearlescent pigments in conjunction with metal oxides, the mica, predominantly muscovite or phlogopite, is coated with a metal oxide. Suitable metal oxides include Ti0 ₂ , Cr ₂ 0 ₃ and Fe ₂ 0 ₃ . By appropriate coating, interference pigments and color luster pigments are obtained as pearlescent pigments preferred according to the invention. In addition to a glittering optical effect, these pearlescent pigment types also have color effects. Furthermore, the pearlescent pigments which can be used according to the invention may additionally contain a color pigment which does not derive from a metal oxide.

Very particularly preferred pearlescent pigments are marketed by Merck under the trade names Colorona ^®, wherein the pigments Colorona ^® red-brown (47-57 wt.% Muscovite mica (KH ₂ (AISi0 ₄₎ 3), 43-50 . wt% Fe ₂ 0 ₃ (INCI: Iran Oxides CI 77491), <3% by weight T1O2. (INCI: Titanium Dioxide CI 77891)., Colorona® ^® Black Star Blue (39-47 wt% muscovite mica (KH ₂ ₍₄ AISi0 ) 3), 53-61 wt% of Fe ₃ 0 ₄ (INCI:.. Iron oxide Cl 77499)), Colorona ^® Fine Siena (35-45% by weight of muscovite mica (KH ₂ (AISi0 ₄₎ _3), 55-65 Wt.% Fe ₂ O ₃ (INCI: Iron Oxides Cl 77491)), . Colorona ^® Aborigine Amber weight (50-62% muscovite mica (KH ₂ (AISi0 ₄₎ 3), 36-44 wt% of Fe ₃ 0 ₄ (INCI:. Iron oxide Cl 77499), 2-6% by weight Ti0 _2. (INCI: Titanium Dioxide CI 77891).), Colorona ^® Patagonian Purple (. 42-54% by weight of muscovite mica (KH ₂ (AISi0 ₄₎ 3), 26-32 wt% Fe ₂ 0 ₃ (INCI: Iron oxide Cl 77491 ), 18-22% by weight of T1O2 (INCI:. Titanium Dioxide CI 77891), 2-4% by weight Prussian blue (INCI:. Ferric ferrocyanide Cl 77510)), Colorona ^® Chameleon (40-50% by weight of muscovite mica (KH. ₂ (AISi0 ₄ ) 3), 50-60% by weight Fe ₂ O ₃ (INCI: Iron Oxides Cl 77491)) and Silk ^® Mica (> 98% by weight Muscovit Mica (KH ₂ (AISi0) ₃ )).

As metal pigments or metallic effect pigments, powdery metals or metal alloys are referred to. Particularly advantageous according to the invention are aluminum pigments (aluminum bronze) and brass pigments (so-called gold bronzes), ie copper / aluminum alloys or copper / zinc alloys, the term "bronze" in this context not being seen in the narrow chemical sense. Exemplary metal pigments are

Aluminum bronzes (AI, color silver);

Gold bronzes (Cu, Cu-Al or Cu-Zn alloy, natural shades)

(Cu, color copper)

(90% Cu - 10% Zn; pale gold)

(85% Cu - 15% Zn, rich pale gold)

(70% Cu - 30% Zn; real gold)

Silver bronzes (Cu-Zn-Ni, silver)

Fire-colored bronzes (oxidized Cu-Zn, tarnishing colors such as Citron, fire red, sea green)

Patent bronzes (Cu-Zn (Ni) + dyes, various colors)

Organic pigments which are suitable according to the invention are, in particular, synthetic organic pigments. Natural organic pigments are preferably present in the composition according to the invention in combination with other pigments. Natural organic pigments include gummi, indigo and chlorophyll.

However, particularly preferred according to the invention are synthetic organic pigments. These include in particular azo pigments and polycyclic pigments.

Preferred azo pigments are monoazo yellow pigments, BONS (β (beta) -locene / α-naphthol carboxylic acid) pigments, β-naphthol pigments, naphthol AS pigments, benzimidazolone pigments, pyrazoloquinazolone pigments, diaryl yellow pigments , Bisacetessigsäurearylamid pigments, disazopyrazolone pigments and disazo condensation pigments. Suitable yellow pigments are monoazo yellow pigments prepared from substituted anilines as a diazo component and methylene-active compounds, such as acetoacetic arylamides or substituted pyrazolones, as a coupling component. The color palette ranges from the greenish to the reddish yellow; for pyrazolones to orange shades (monoazo orange pigments or monoazopyrazolone pigments). These include the preferred PY 1, PY 74 and PY 97.

Preferred β-naphthol pigments are PO 2, PO 5, PO 17, PO 17: 1, PR 1 (para-red), PR 3 (toluidine red), PR 4, PR 6, PR 50: 1, PR 51, PR 53 A , PR 53, PR 68, PR 49: 1 and PR 49: 2.

Preferred BONS (β (beta) -locene / -o-naphtholcarboxylic acid) pigments are PR 48: 1, PR 48: 2, PR 48: 3, PR 48: 4, PR 48: 5, PR 52: 1, PR 52 : 2, PR 57, PR 57: 1, PR 58: 2, PR 58: 4, PR 64, PR 64: 1. Particularly preferred is PR 48: 1 and PR 52: 1 and in particular PR 57 and PR 57: 1 (PR 57: 1 stands for the Ca ²⁺ salt of PR 57).

Preferred naphthol AS pigments are PO 38, PO 74, PR 2, PR 5, PR 14, PR 112, PR 146, PR 147, PR 170, PR 184, PR 187, PR 188, PR 210 and PR 253.

Preferred benzimidazolone pigments are PY 151, PY 175, PO 36, PO 60, PR 175, PR 176, PR 185, PR 208, PV 32 and PBr 25.

Preferred pyrazoloquinazolone pigments are PO 67 and PR 251.

Among the azo pigments, yellow pigments according to the invention are especially suitable diaryl yellow pigments. Preferred diaryl yellow pigments are PY (Pigment Yellow) 12, PY 13, PY 14, PY 17, PY 55, PY 63, PY 63, PY 81, PY 83, PY 87, PY 90, PY 106, PY 113, PY 114, PY 121, PY 124, PY 126, PY 127, PY 136, PY 152, PY 170, PY 171, PY 172, PY 174, PY 176, PY 188 and PO (Pigment Orange) 15, PO 16 and PO 44. Particularly preferred are PY 12 and PY 13.

Preferred disazopyrazolone pigments are PO 13, PO 34, PR 37, PR 38, PR 11 1.

Preferred disazo condensation pigments are PY 93, PY 94, PY 95, PY 128, PO 31, PR 144, PR 166, PR 221, PR 242, PR 262, PBr 23, PBr 41 and PBr 42.

Polycyclic pigments in the context of the invention are all organic non-azo pigments which have at least one aromatic or heteroaromatic ring system. For more detailed characterization, a further subdivision of the class of polycyclic pigments is common. The expert knows

a) highly polycyclic pigments, such as phthalocyanine pigments, quinacridone pigments, triarylmethane pigments, triphenylmethane pigments, dye salts with complex anions and dioxazine pigments;

b) non-azo pigments such as metal complex pigments, azomethine pigments, bis (azomethine) pigments, isoindolinone pigments, isoindoline pigments, quinophthalone pigments, diketopyrrolopyrrole pigments and aniline black;

c) vat dye-derived pigments such as perylene pigments, naphthalenetetracarboxylic acid pigments, thioindigo pigments, anthraquinone pigments, aminoanthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments and anthanthrone pigments ,

According to the invention suitable polycyclic pigments are the so-called phthalocyanine pigments. These are porphyrin metal complexes. Particularly advantageous according to the invention are the copper phthalocyanine pigments which exist in various colors and modifications. According to the color, a distinction is made between phthalo blue and phthalo green grades, the green color usually being produced by additional halogenation of the porphyrin ring. In addition, cobalt or aluminum-containing complexes can be used. Phthalocyanines which are preferred according to the invention are, however, the copper phthalocyanine pigments, in particular the phthalo blue pigments PB 15 (C 32 H ₆ CuN ₈ ), PB: 1, PB 15: 2, PB 15: 3 and PB 15: 4, the respective numbers being different Modification and / or a different halogenation content in the porphyrin, as well as the phthalo-green pigments PG 17 (C32HCI15CUN8) and PG 36 ^ BreChoCuNs).

Further pigments which are advantageous according to the invention are the so-called pigment blacks (carbon blacks, also carbon pigments). These are finely divided carbon blacks which are used as black pigments and for UV stabilization. Pigment blacks are extremely resistant to chemicals and are characterized by high lightfastness and weathering resistance. Due to the very high color depth and color strength and other specific properties, pigment blacks are the preferred black pigments (Pigment Black PBI 7) according to the invention.

In a further embodiment, compositions according to the invention are characterized in that the inorganic or organic pigment is selected from the group consisting of Pigment Yellow 12 and 13 (PY 12 / PY 13), Pigment Red 57 (PR 57), pigment Blue 15 (PB 15), Pigment Black 7 (PBI 7), Pigment White 6 (PW 6), aluminum and brass pigments.

Preferred compositions are characterized in that the colorant c) is selected from the group of water-insoluble pigments wherein the proportion by weight of the colorant c) in the total weight of the composition 0.1 to 8.0 wt .-%, preferably 0.2 to 6.0 Wt .-% and in particular 0.5 to 5.0 wt .-% is.

In compositions according to the invention having a low polyol content, it is preferred to add a further polar solvent to the compositions in the balance, wherein the addition of water is particularly preferred. Preferred compositions contain, based on their total weight

- 12 to 30 wt .-%, preferably 15 to 25 wt .-% organic polyol b), preferably glycerol and

- 40 to 75 wt .-%, preferably 50 to 70 wt .-% water

- 0.1 to 8.0 wt .-%, preferably 0.2 to 6.0 wt .-% and in particular 0.5 to 5.0 wt .-% water-insoluble pigment.

An optional constituent of compositions according to the invention are copolymers d) which are obtained by polymerization of the monomers N-tert-octylacrylamide, acrylic acid and tert-butylaminoethylmethacrylic acid. Preferred copolymers d) consist of at least 90% by weight, preferably at least 95% by weight and in particular at least 97% by weight, of the monomers N-tert-octylacrylamide, acrylic acid and tert-butylaminoethyl methacrylic acid. Particularly preferred copolymers d) were obtained exclusively from the monomers N-tert-octylacrylamide, acrylic acid and tert-butylaminoethylmethacrylic acid.

The copolymers d) described above (for example, under the name Amphomer ^® INCI name: distributed Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer) from the company National Starch.

Preferred compositions according to the invention are characterized in that the weight fraction of the copolymer d) in the total weight of the composition is 0.01 to 15% by weight, preferably 0.02 to 12% by weight, preferably 0.03 to 8.0% by weight. % and in particular from 0.05 to 1, 0 wt .-% is. In summary, those compositions are preferred which, based on their total weight, 0.01 to 15 wt .-%, preferably 0.02 to 12 wt .-%, preferably 0.03 to 8.0 wt .-% and in particular of 0 , 05 to 1, 0 wt .-% of at least one copolymer d) from the monomers

b1) N-tert-octylacrylamide

b2) acrylic acid

b3) tert-butylaminoethylmethacrylic acid

b4) and optionally other monomers

contain.

The composition of some preferred cosmetic agents can be found in the following tables (data in% by weight based on the total weight of the cosmetic agent, unless stated otherwise).

Formula 11 Formula 12 Formula 13 Formula 14 Formula 15

Silica silylates 10 to 30 10 to 25 10 to 25 12 to 22 12 to 22

Gylcerin 40 to 89 42 to 88 42 to 88 45 to 87 45 to 87

Dye 0.001 to 0.001 to 0.001 to 0.001 to 0.001 to

8.0 1, 0 0.8 0.5 0.5

Optional Additives add 100 add 100 add 100 add 100 add 100 Formula 16 Formula 17 Formula 18 Formula 19 Formula 20

Silica dimethicone silylates 10 to 30 10 to 25 10 to 25 12 to 22 12 to 22 polar solvent 40 to 89 42 to 88 42 to 88 45 to 87 45 to 87

Dye 0.001 to 0.001 to 0.001 to 0.001 to 0.001 to

8.0 1, 0 0.8 0.5 0.5

Optional Additives add 100 add 100 add 100 add 100 add 100

Formula 31 Formula 32 Formula 33 Formula 34 Formula 35

Silica silylates 10 to 30 10 to 25 10 to 25 12 to 22 12 to 22 polar solvent 40 to 89 42 to 88 42 to 88 45 to 87 45 to 87

Dye 0.001 to 0.001 to 0.001 to 0.001 to 0.001 to

8.0 1, 0 0.8 0.5 0.5

Copoylmer c) 0.01 to 15 0.02 to 12 0.03 to 8.0 0.05 to 1.0, 0.05 to 1.0

Optional Additives add 100 add 100 add 100 add 100 add 100 Formula 36 Formula 37 Formula 38 Formula 39 Formula 40

Silica silylates 10 to 30 10 to 25 10 to 25 12 to 22 12 to 22

Glycerol 40 to 89 42 to 88 42 to 88 45 to 87 45 to 87

Dye 0.001 to 0.001 to 0.001 to 0.001 to 0.001 to

8.0 1, 0 0.8 0.5 0.5

Copoylmer c) 0.01 to 15 0.02 to 12 0.03 to 8.0 0.05 to 1.0, 0.05 to 1.0

Optional Additives add 100 add 100 add 100 add 100 add 100

Formula 51 Formula 52 Formula 53 Formula 54 Formula 55

Hydrophobicized 10 to 30 10 to 25 10 to 25 12 to 22 12 to 22 metal oxide powder

polar solvent 40 to 89 42 to 88 42 to 88 45 to 87 45 to 87

Pigment 0.001 to 8.0 0.1 to 8.0 0.2 to 6.0 0.2 to 6.0 0.5 to 5.0 optional additives add 100 add 100 add 100 add 100 add 100 Formula 56 Formula 57 Formula 58 Formula 59 Formula 60

Pigment 0.001 to 8.0 0.1 to 8.0 0.2 to 6.0 0.2 to 6.0 0.5 to 5.0

Optional Additives add 100 add 100 add 100 add 100 add 100

Formula 76 Formula 77 Formula 78 Formula 79 Formula 80

Hydrophobicized 10 to 30 10 to 25 10 to 25 12 to 22 12 to 22 metal oxide powder

polar solvent 40 to 89 42 to 88 42 to 88 45 to 87 45 to 87

Pigment 0.001 to 8.0 0.1 to 8.0 0.2 to 6.0 0.2 to 6.0 0.5 to 5.0

Copoylmer c) 0.01 to 15 0.02 to 12 0.03 to 8.0 0.05 to 1.0, 0.05 to 1.0

Optional Additives add 100 add 100 add 100 add 100 add 100 Formula 81 Formula 82 Formula 83 Formula 84 Formula 85

Pigment 0.001 to 8.0 0.1 to 8.0 0.2 to 6.0 0.2 to 6.0 0.5 to 5.0

Copoylmer c) 0.01 to 15 0.02 to 12 0.03 to 8.0 0.05 to 1.0, 0.05 to 1.0

Optional Additives add 100 add 100 add 100 add 100 add 100

The cosmetic compositions of the invention may contain other auxiliaries, care agents and additives. The proportion by weight of the further constituents contained in the powdery compositions according to the invention in addition to the components a) to c), in particular the further auxiliaries, care agents and additives contained in these compositions, in the total weight of the pulverulent compositions according to the invention is preferably less than 10 wt .-%, preferably less than 5.0 wt .-%, more preferably less than 2.0 wt .-% and in particular less than 1, 0 wt .-%. The proportion by weight of these auxiliaries, care agents and additives in the total weight of the cosmetic compositions according to the invention can be, for example, from 0.001 to 2% by weight, in particular from 0.01 to 0.5% by weight.

The pulverulent compositions according to the invention can be formulated in arbitrary containers, as long as it is ensured that the mechanical loading of the powder during the removal of the composition does not lead to liquefaction. Suitable, for example, crucibles, bottles or tetra packs, the container can be configured for example with a bulk and metering device.

A further subject of the present application is the use of a cosmetic composition according to the invention for the temporary deformation of keratin-containing fibers, in particular human hair. When using the powdery composition for the temporary deformation of keratinous fibers, preferably the desired amount of the pulverulent composition is first removed from the container. The composition can be applied directly to the keratinic fiber to be treated or, for example, to the hand. In the first case, the applied powder directly on the keratin fiber can be subjected to a mechanical load, for example by means of the hands, whereby the liquid, aqueous phase is released directly on the fiber. If the powdered composition is first given to the hand, then it can first be carefully distributed in the hair and then again be subjected to greater mechanical stress, for example by targeted massaging the powder into the hair. This releases the liquid, aqueous phase on the hair.

It is of course also possible to rub the powdery composition already on hand and only apply the resulting liquid or paste-like agent to the keratinic fiber. However, this procedure is not preferred because it dispenses with a substantial advantage of the powdery consistency of the styling agent, namely the good spreadability. Of course, the powdered composition can also be applied with an aid, such as a brush, a sponge, a cloth, a brush or a comb.

A further subject of the present application is a method for the temporary deformation of keratin-containing fibers, in particular human hair, in which the keratinic fibers are acted upon by a cosmetic composition according to the invention and temporarily fixed in their form, characterized in that from the cosmetic Composition before, during or after application to the keratinic fibers by the action of a force a plastically deformable mass is formed.

Claims

claims

1 . Powdered cosmetic compositions containing

a) 10 to 30 wt .-% hydrophobized metal oxide powder

b) 40 to 89 wt .-% polar solvent

c) from 0.001 to 8.0% by weight of colorant.

2. Composition according to claim 1, characterized in that it contains the hydrophobized metal oxide powder based on their total weight in amounts of from 10 to 25, preferably from 12 to 22 wt .-%.

3. Composition according to one of the preceding claims, characterized in that it contains as hydrophobized metal oxide powder obtained by silanization of fumed silica hydrophobic silicate.

4. Composition according to one of the preceding claims, characterized in that they contain based on their total weight 42 to 88 wt .-%, preferably from 45 to 87 wt .-% polar solvent b).

5. Composition according to one of the preceding claims, characterized in that they contain as polar solvent b) at least one solvent from the group consisting of water and glycerol, preferably water.

6. Composition according to one of the preceding claims, characterized in that they, based on their total weight

- 60 to 88 wt .-%, preferably 65 to 87 wt .-% water and

7. Composition according to one of the preceding claims, characterized in that they, based on their total weight

- 12 to 30 wt .-%, preferably 15 to 25 wt .-% organic polyol, preferably glycerol and

- 40 to 75 wt .-%, preferably 50 to 70 wt .-% water.

8. Composition according to one of the preceding claims, characterized in that they, based on their total weight

- 60 to 88 wt .-%, preferably 65 to 87 wt .-% organic polyol, preferably glycerol and

9. Composition according to one of the preceding claims, characterized in that the colorant c) is selected from the group of water-soluble dyes, wherein the proportion by weight of the colorant c) in the total weight of the composition 0.001 to 1, 0% by weight, preferably 0.001 to 0.8 wt .-% and in particular 0.001 to 0.5 wt .-% is.

10. The composition according to any one of the preceding claims, characterized in that the colorant c) is selected from the group of water-insoluble pigments wherein the weight proportion of the colorant c) in the total weight of the composition 0.1 to 8.0 wt .-%, preferably 0 , 2 to 6.0 wt .-% and in particular 0.5 to 5.0 wt .-% is.

1 1. Composition according to one of the preceding claims, characterized in that it, based on their total weight, 0.01 to 15 wt .-%, preferably 0.02 to 12 wt .-%, preferably 0.03 to 8.0 Wt .-% and in particular from 0.05 to 1, 0 wt .-% of at least one copolymer of the monomers

b1) N-tert-octylacrylamide

b2) acrylic acid

b3) tert-butylaminoethylmethacrylic acid

b4) and optionally other monomers

contain.

12. Use of a cosmetic composition according to one of the preceding claims for the temporary deformation of keratin-containing fibers, in particular human hair.

13. A process for the temporary deformation of keratin fibers, in particular human hair, in which the keratin fibers are applied with a cosmetic composition according to one of claims 1 to 11 and temporarily fixed in their shape, characterized in that from the cosmetic composition before, during or after application to the keratinic fibers by the action of a force a plastically deformable mass is formed.