WO2015083508A1 - Coal deactivation processing device - Google Patents

Coal deactivation processing device Download PDF

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Publication number
WO2015083508A1
WO2015083508A1 PCT/JP2014/079915 JP2014079915W WO2015083508A1 WO 2015083508 A1 WO2015083508 A1 WO 2015083508A1 JP 2014079915 W JP2014079915 W JP 2014079915W WO 2015083508 A1 WO2015083508 A1 WO 2015083508A1
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WO
WIPO (PCT)
Prior art keywords
coal
feed pipe
protrusion
rotary kiln
main body
Prior art date
Application number
PCT/JP2014/079915
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French (fr)
Japanese (ja)
Inventor
慶一 中川
大本 節男
Original Assignee
三菱重工業株式会社
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Filing date
Publication date
Application filed by 三菱重工業株式会社 filed Critical 三菱重工業株式会社
Priority to DE112014005551.4T priority Critical patent/DE112014005551T5/en
Priority to AU2014358470A priority patent/AU2014358470B2/en
Priority to CN201480064758.XA priority patent/CN105793657B/en
Priority to US15/037,807 priority patent/US20160289582A1/en
Publication of WO2015083508A1 publication Critical patent/WO2015083508A1/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/04Raw material of mineral origin to be used; Pretreatment thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/02Treating solid fuels to improve their combustion by chemical means
    • C10L9/06Treating solid fuels to improve their combustion by chemical means by oxidation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/08Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B7/00Rotary-drum furnaces, i.e. horizontal or slightly inclined
    • F27B7/06Rotary-drum furnaces, i.e. horizontal or slightly inclined adapted for treating the charge in vacuum or special atmosphere
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B7/00Rotary-drum furnaces, i.e. horizontal or slightly inclined
    • F27B7/20Details, accessories, or equipment peculiar to rotary-drum furnaces
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/06Heat exchange, direct or indirect
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/14Injection, e.g. in a reactor or a fuel stream during fuel production
    • C10L2290/145Injection, e.g. in a reactor or a fuel stream during fuel production of air
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/56Specific details of the apparatus for preparation or upgrading of a fuel

Definitions

  • the present invention relates to a coal deactivation treatment apparatus that performs deactivation treatment of coal with a treatment gas containing oxygen.
  • Low-grade coal with high water content such as lignite and sub-bituminous coal has a low calorific value per unit weight, so it is dried and dry-distilled by heating, and in a low-oxygen atmosphere. By reforming so as to reduce the oxidation reaction activity, the reformed coal has an increased calorific value per unit weight while preventing spontaneous ignition.
  • a coal inactivation treatment apparatus for inactivating dry distillation coal obtained by drying or carbonizing the above-described low-grade coal As a coal inactivation treatment apparatus for inactivating dry distillation coal obtained by drying or carbonizing the above-described low-grade coal, a rotary kiln to which dry distillation coal and process gas are supplied is provided, and the periphery thereof is provided in the rotary kiln.
  • An apparatus having a plurality of feed pipes adjacent to each other in the direction through which cooling water flows is being studied.
  • the above-described coal inactivation treatment apparatus rotates the rotary kiln and rotates the rotary kiln main body while cooling the dry-distilled coal with cooling water flowing through the feed pipe by rotating the rotary kiln and the plurality of feed pipes. While stirring, a plurality of feed pipes pass through a coal bed in which dry-distilled coal accumulates in a rotary kiln, lift the dry-distilled coal above the coal bed surface, and drop from above to the coal bed surface By stirring the carbonized carbon, the carbonized coal is inactivated by the processing gas. The agitation is repeated while the carbonized coal moves from the base end side to the tip end side of the rotary kiln, and the carbonized coal is gradually pulverized.
  • the present invention has been made to solve the above-described problems, and can efficiently adsorb oxygen onto the surface of coal while preventing spontaneous combustion of coal. It aims at providing the coal inactivation processing apparatus which can be performed.
  • the coal inactivation processing apparatus for solving the above-described problem is a coal inactivation processing apparatus that inactivates coal with a processing gas containing oxygen, in which the coal and the processing gas are contained inside.
  • a kiln main body provided rotatably and provided rotatably with the kiln main body and extending in the longitudinal direction of the kiln main body, and a feed pipe through which cooling water flows.
  • the coal inactivation processing apparatus according to the second invention that solves the above-described problem is the coal inactivation processing apparatus according to the first invention described above, wherein the protrusion is a radial section of the feed pipe. It is characterized in that it has a V-shape and the apex of the protrusion coincides with the locus of the central axis of the feed pipe.
  • a coal inactivation processing apparatus that solves the above-described problem is the coal inactivation processing apparatus according to the first or second aspect of the invention described above, wherein the protrusion is formed of the protrusion.
  • a coal inactivation processing apparatus that solves the above-described problem is the coal inactivation processing apparatus according to any one of the first to third aspects of the invention described above, and is the apex of the protrusion. And the center axis of the feed pipe is not more than twice the radius of the feed pipe.
  • the outer periphery of the feed pipe is provided with a hat-shaped projection provided so as to project in the rotation direction of the feed pipe, and the feed pipe and the projection are
  • the kiln body is arranged to pass through a coal layer in which the coal is deposited in the kiln body, while cooling the coal with cooling water circulating in the feed pipe, While stirring the coal by rotation, a predetermined amount of coal is lifted above the surface of the coal bed in the kiln body by the feed pipe and the protrusion, and dropped from above to stir the coal.
  • the contact opportunity can be made suitable. Thereby, adsorption
  • the overall length of the kiln main body can be shortened compared to the case where no protrusion is provided on the feed pipe, and the apparatus can be downsized.
  • a coal deactivation treatment apparatus 100 that deactivates dry-distilled coal 1 has a hopper 101 that receives dry-distilled coal 1, and a base end side that communicates with a delivery port of the hopper 101. And a screw feeder 102 that is a rotary conveying means that rotates and conveys the coal 1 in the hopper 101 from one end side (base end side) to the other end side (tip end side).
  • the distal end side of the screw feeder 102 communicates with the proximal end side of a cylindrical rotary kiln main body (kiln main body) 103.
  • the base end side of the rotary kiln main body 103 is in communication with the base end side casing 111 via the sealing device 108.
  • a gas receiving port 111 a for introducing the processing gas 13 is provided at the upper part of the base end side casing 111.
  • the gas inlet 111a is connected to the distal end side of the processing gas supply pipe 121 that supplies the processing gas 13.
  • a blower 127 and a heating device 128 are provided in the middle of the processing gas supply pipe 121.
  • the distal end side of the air supply pipe 122 that supplies the air 11 and the distal end side of the nitrogen supply pipe 123 that supplies the nitrogen gas 12 are connected to the proximal end side of the processing gas supply pipe 121.
  • the base end side of the air supply pipe 122 is open to the atmosphere.
  • the base end side of the nitrogen supply pipe 123 is connected to a nitrogen supply source 124 such as a nitrogen gas tank.
  • flow control valves 125 and 126 are provided, respectively.
  • the distal end side of the rotary kiln main body 103 communicates with the distal end side casing 112 via seal devices 109a and 109b.
  • a gas discharge port 112 a for discharging the used processing gas 14 is provided in the upper part of the front end side casing 112.
  • the base end side of the processing gas discharge pipe 131 that discharges the used processing gas 14 is connected to the gas discharge port 112a.
  • a temperature sensor 131 a is provided in the middle of the processing gas discharge pipe 131.
  • a shooter 112b that drops and discharges the deactivated coal (modified coal) 3 is provided at the lower portion of the front end side casing 112.
  • An annular ridge 104 is provided on the distal end side and the proximal end side of the outer peripheral portion of the rotary kiln main body 103, and the ridge 104 is supported by a roller 105.
  • a gear 106 that meshes with the gear 107 a of the driving electric motor 107 is provided on the outer peripheral portion of the rotary kiln main body 103. Therefore, when the gear 107a of the driving motor 107 is rotated, the rotary kiln main body 103 is rotated.
  • the coal inactivation processing apparatus 100 described above further includes a cooling device 140.
  • the cooling device 140 includes a bearing 145 fixed to the side wall portion 103 a on the distal end side of the rotary kiln main body 103.
  • the cooling device 140 includes a cooling water supply header 141 that is provided on the bearing 145 and to which the cooling water 21 is supplied from outside the system.
  • a plurality of, for example, eight (see FIG. 2) feed pipes 142 (for example, double pipes) for feeding the coolant 21 are connected to the coolant feed header 141.
  • the cooling device 140 includes a cooling water discharge header 146 that discharges the used cooling water 22 circulated through the supply pipe 142 to the outside of the system.
  • the plurality of feed pipes 142 are arranged in the rotary kiln main body 103 adjacent to each other at equal intervals in the circumferential direction of the rotary kiln main body 103.
  • the plurality of feed pipes 142 is a coal layer formed by depositing coal 2 even when the filling rate of coal 2 into the rotary kiln body 103 is, for example, 10% to 15% when the rotary kiln body 103 rotates. It arrange
  • the plurality of feed pipes 142 extend in the rotary kiln main body 103 in parallel to the central axis C1 of the rotary kiln main body 103, and extend from the distal end side to the proximal end side of the rotary kiln main body 103. .
  • the temperature is adjusted so that the coal 2 does not spontaneously ignite by the cooling water 21 flowing in the feed pipe 142. Is done.
  • the plurality of feed pipes 142 are disposed so as to penetrate the side wall 103a of the rotary kiln main body 103.
  • the plurality of feed pipes 142 are supported by support tools (not shown) arranged at a plurality of locations in the longitudinal direction. As a result, the plurality of feed pipes 142 rotate around the central axis C ⁇ b> 1 of the rotary kiln body 103 together with the rotary kiln body 103 as the rotary kiln body 103 rotates.
  • A indicates the rotational direction of the rotary kiln body 103.
  • L1 indicates a trajectory through which the central axis C2 of the plurality of supply pipes 142 passes, and L2 indicates a tangent to the trajectory L1.
  • L3 indicates a bisector of a protrusion 143 to be described later.
  • L4 and L5 indicate tangent lines of the feed pipe 142 passing through the apex 143c of the protrusion 143.
  • L11 indicates an auxiliary line passing through the contact point P1 between the feed pipe 142 and the tangent line L5 and the contact point P2 between the feed pipe 142 and the tangent line L4.
  • L12 and L13 indicate auxiliary lines passing through the central axis C2 of the feed pipe 142 and the contacts P1 and P2, respectively.
  • is an acute angle formed by the bisector L3 and the tangent line L5 (inner plane portion 143a of the hat), and indicates the angle (hat angle) of the protrusion, and ⁇ is formed by the bisector L3 and the auxiliary line L12. It shows an acute angle.
  • represents an acute angle formed by the tangent line L5 and the auxiliary line L11.
  • auxiliary lines L11, L12, and L13 form an isosceles triangle having the central axis C2 as an apex, and the auxiliary line L12 and the tangent line L5 form a right angle. Therefore, the angle ⁇ is the same size as the angle ⁇ .
  • the feed pipe 142 has a perfect circle in its radial cross section.
  • a protrusion 143 having a hat shape is provided on the outer peripheral portion of the feed pipe 142 so as to project in the rotation direction A of the feed pipe 142. More specifically, the protrusion 143 has a V shape in the radial cross section of the feed pipe 142. Similar to the feed pipe 142, the protrusion 143 is configured so that when the rotary kiln main body 103 rotates, even if the filling rate of the coal 2 into the rotary kiln main body 103 is, for example, 10% to 15%, It is arranged at a position that passes through the coal bed that is deposited.
  • the protruding portion 143 includes an inner flat surface portion 143a positioned on the central axis C1 side of the rotary kiln main body 103 and an outer flat surface portion 143b positioned on the outer peripheral surface side of the rotary kiln main body 103.
  • the distal end side of the inner plane portion 143a and the outer plane portion 143b is connected.
  • the apex 143c of the protrusion 143 is positioned at a position that coincides with the locus of the central axis C2 of the feed pipe 142.
  • the amount of coal lifted above the coal bed surface 2a by the feed pipe 142 and the protrusion 143 can be reduced as compared with the case where there is no hat-shaped protrusion, so that a suitable state can be obtained.
  • the contact opportunity between the coal 2 and the processing gas 13 by stirring is in a suitable state, and the efficiency of the inactivation processing of the coal 2 can be improved.
  • the inner plane portion 143a and the outer plane portion 143b are arranged symmetrically on a plane passing through the tip portion 143c of the protrusion 143 and the central axis C2. That is, the protrusion 143 has a shape that is plane-symmetric. Further, a corner portion ⁇ formed by a straight line L11 connecting the intersections P2, P1 of the two tangents L4, L5 of the feed pipe 142 passing through the apex 143c of the projection 143 and the feed pipe 142 and one of the tangent lines L5. However, it is larger than the angle of repose.
  • the distance D2 between the tip 143c of the protrusion 143 and the central axis C2 of the feed pipe 142 is preferably less than or equal to twice the radius of the feed pipe 142, and more preferably less than or equal to one. This is because when the distance D2 exceeds the upper limit value, the heat transfer area between the cooling water 21 and the coal 2 in the feed pipe 142 decreases, the heat exchange rate decreases, and the rotary kiln main body 103 This is because a large number of space portions are formed between the projection 143 and the feed pipe 142, and the amount of treated coal is reduced.
  • feed pipe 142 and the protrusion 143 it is possible to use one made of a material having no reactivity with the coal 2 and having heat resistance, for example, steel.
  • the radius r2 of the feed pipe 142 and the distance D1 between the central axis C1 of the rotary kiln main body 103 and the central axis C2 of the feed pipe 142 are expressed by the following relational expression (1 ) Is more preferable.
  • the distance D3 between the adjacent feed pipes 142 and 142 satisfies the following expression (2).
  • the nitrogen supply source 124, the base end side casing 111, the gas receiving port 111a, and the like constitute processing gas supply means.
  • the cooling water feed header 141, the feed pipe 142, the projection 143, the bearing 145, the cooling water discharge header 146, and the like constitute the cooling device 140 that forms a cooling means.
  • the ridge 104, the roller 105, the gear 106, the drive motor 107, the gear 107a, and the like constitute a rotating means.
  • the hopper 101, the screw feeder 102, and the like constitute coal supply means.
  • the shooter 112b and the like of the front end side casing 112 constitute coal discharging means.
  • the front end side casing 112, the gas discharge port 112a, the processing gas discharge pipe 131, and the like constitute processing gas discharge means.
  • Each means, the rotary kiln main body 103, the sealing devices 108, 109a, 109b, etc. constitute the coal inactivation processing device 100.
  • the coal 1 When the coal 1 is supplied to the hopper 101, the coal 1 is conveyed into the rotary kiln main body 103 by the screw feeder 102.
  • the air 11 and the nitrogen gas 12 are supplied to the processing gas supply pipe 121 via the air supply pipe 122 and the nitrogen supply pipe 123 by controlling the opening degree of the flow rate adjusting valves 125 and 126. Supplied.
  • the air 11 and the nitrogen gas 12 are mixed to become the processing gas 13 (for example, the oxygen concentration is about 5 to 10%).
  • the processing gas 13 is heated by the heating device 128 based on the temperature data of the used processing gas 14 obtained by the temperature sensor 131a, and adjusted to be 40 ° C. to 200 ° C. in the rotary kiln main body 103.
  • a gas supply pipe 121 supplies the rotary kiln main body 103 through the gas receiving port 111a.
  • the rotary kiln main body 103 rotates when the gear 107 a of the driving motor 107 rotates and is transmitted via the gear 106.
  • the coal 2 conveyed into the rotary kiln main body 103 moves from the proximal end side to the distal end side of the rotary kiln main body 103 while being stirred.
  • the coal 2 in the rotary kiln main body 103 adsorbs the oxygen of the processing gas 13 supplied into the rotary kiln main body 103.
  • the inactivated coal (reformed coal) 3 is obtained by oxygen adsorption, and is carried out of the system via the shooter 112b.
  • the coal 2 in the rotary kiln main body 103 generates heat by adsorbing oxygen in the processing gas 13, the coal 2 is adjusted to a temperature at which the coal 2 does not spontaneously ignite by the cooling water 21 flowing through the feed pipe 142.
  • the used processing gas (about 50 ° C. to 70 ° C.) 14 used for the inactivation processing of the coal 2 in the rotary kiln main body 103 circulates in the same direction as the transport direction of the coal 2, and the rotary kiln main body 103
  • the gas flows from the gas discharge port 112 a of the front end side casing 112 provided on the front end side to the process gas discharge pipe 131 and is discharged out of the system through the process gas discharge pipe 131.
  • the rotary kiln main body 103 rotates with the rotary kiln main body 103 around the central axis C ⁇ b> 1 of the rotary kiln main body 103, and the rotary kiln main body 103 rotates.
  • a plurality of feed pipes 142 are provided in the rotary kiln body 103 so as to pass through the coal bed formed by depositing the coal 2 supplied into the main body 103, and the projections 143 are provided on the feed pipes 142.
  • it operates as follows.
  • the outer periphery of the feed pipe 142 includes the protrusion 143 provided to project in the rotation direction A of the feed pipe 142, and the feed pipe 142 and the protrusion 143 are arranged so as to pass through a coal bed in which the coal 2 is deposited in the rotary kiln main body 103 when the rotary kiln main body 103 rotates, and thereby circulate in the feed pipe 142.
  • the coal 2 While the coal 2 is being cooled by the cooling water 21 to be stirred, the coal 2 is agitated by the rotation of the rotary kiln main body 103, and a predetermined amount of the coal 2 is fed into the coal layer in the rotary kiln main body 103 by the feed pipe 142 and the protrusion 143.
  • the coal 2 is stirred by being lifted upward from the surface 2a and dropped from above, and the contact opportunity between the coal 2 and the processing gas 13 can be made suitable. Thereby, adsorption
  • the overall length of the rotary kiln main body 103 can be shortened compared to the case where no hat-shaped protrusion is provided on the feed pipe, and the apparatus can be downsized.
  • the shape of the protrusion 143 provided in each of the plurality of supply pipes 142 is not limited to one type, and may be two or more types.
  • the coal inactivation processing apparatus 100 including the eight supply pipes 142 has been described.
  • the number of the supply pipes is not limited to eight, and seven or less or nine or more supply pipes are used. It is also possible to provide a coal inactivation treatment apparatus.
  • 1,2,3 coal 11 air, 12 nitrogen gas, 13,14 treatment gas, 21,22 cooling water, 100 coal deactivation treatment device, 101 hopper, 102 screw feeder, 103 rotary kiln body (kiln body), 104 ridges, 105 rollers, 106 gears, 107 driving motors, 107a gears, 108 sealing devices, 109a and 109b sealing devices, 111 proximal casings, 111a gas inlets, 112 distal casings, 112a gas outlets, 112b shooter, 121 processing gas supply pipe, 122 air supply pipe, 123 nitrogen supply pipe, 124 nitrogen supply source, 125, 126 flow control valve, 127 blower, 128 heating device, 131 processing gas discharge pipe, 131a temperature sensor, 140 cooling Equipment, 141 Cooling water feed header, 142 Feed pipe, 143 Protrusion, 143a Inner plane, 143b Outer plane, 143c Apex, 145 bearing, 146 Coolant discharge header, A Rotary direction of rotary kiln

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  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Geology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
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  • Combustion & Propulsion (AREA)
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  • Thermal Sciences (AREA)
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  • Muffle Furnaces And Rotary Kilns (AREA)
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Abstract

The present invention makes it possible to prevent the spontaneous combustion of coal while causing oxygen to be adsorbed to the surface of the coal in an efficient manner. A coal deactivation processing device is provided with: a rotary kiln body (103) that is capable of rotation and into which coal and a processing gas are supplied; a feed pipe (142) that is provided so as to be capable of rotating together with the rotary kiln body (103), that extends along the lengthwise direction of the rotary kiln body (103), and within which a coolant flows; and a hat (143) that is provided to the outer circumferential section of the feed pipe (142) so as to protrude toward the rotation direction of the feed pipe (142). The feed pipe (142) and the hat (143) are arranged so as to pass through a coal layer resulting from the accumulation of coal (2) within the rotary kiln body (103) when the rotary kiln body (103) rotates.

Description

石炭不活性化処理装置Coal deactivation processing equipment
 本発明は、酸素を含有する処理ガスで石炭の不活性化処理を行う石炭不活性化処理装置に関する。 The present invention relates to a coal deactivation treatment apparatus that performs deactivation treatment of coal with a treatment gas containing oxygen.
 褐炭や亜瀝青炭などのような水分含有量の多い低品位炭(低質炭)は、単位重量当たりの発熱量が低いため、加熱されることにより、乾燥や乾留されると共に、低酸素雰囲気中で酸化反応活性を低下させるように改質されることにより、自然発火を防止されつつ単位重量当たりの発熱量を高めた改質石炭としている。 Low-grade coal (low-quality coal) with high water content such as lignite and sub-bituminous coal has a low calorific value per unit weight, so it is dried and dry-distilled by heating, and in a low-oxygen atmosphere. By reforming so as to reduce the oxidation reaction activity, the reformed coal has an increased calorific value per unit weight while preventing spontaneous ignition.
特開2007-237011号公報JP 2007-237011 A 国際公開第95/13868号パンフレットInternational Publication No. 95/13868 Pamphlet
 上述した低品位炭が乾燥や乾留されてなる乾留炭を不活性化する石炭不活性化処理装置として、乾留炭および処理ガスが供給されるロータリキルンを備えると共に、当該ロータリキルン内にてその周方向で隣接し、冷却水が流通する送給管を複数備えた装置が検討されている。 As a coal inactivation treatment apparatus for inactivating dry distillation coal obtained by drying or carbonizing the above-described low-grade coal, a rotary kiln to which dry distillation coal and process gas are supplied is provided, and the periphery thereof is provided in the rotary kiln. An apparatus having a plurality of feed pipes adjacent to each other in the direction through which cooling water flows is being studied.
 上述した石炭不活性化処理装置は、ロータリキルンおよび複数の送給管が回転されることで、送給管内を流通する冷却水により乾留炭を冷却しつつ、ロータリキルン本体の回転により乾留炭を撹拌すると共に、複数の送給管がロータリキルン内にて乾留炭が堆積してなる石炭層内を通過し当該乾留炭を石炭層表面よりも上方へ持ち上げ上方から石炭層表面に落下することでも乾留炭を撹拌することで、処理ガスにより乾留炭を不活性化処理している。前記撹拌が前記ロータリキルンの基端側から先端側へ前記乾留炭が移動していく間で繰り返し行われており、前記乾留炭が徐々に粉化することになる。 The above-described coal inactivation treatment apparatus rotates the rotary kiln and rotates the rotary kiln main body while cooling the dry-distilled coal with cooling water flowing through the feed pipe by rotating the rotary kiln and the plurality of feed pipes. While stirring, a plurality of feed pipes pass through a coal bed in which dry-distilled coal accumulates in a rotary kiln, lift the dry-distilled coal above the coal bed surface, and drop from above to the coal bed surface By stirring the carbonized carbon, the carbonized coal is inactivated by the processing gas. The agitation is repeated while the carbonized coal moves from the base end side to the tip end side of the rotary kiln, and the carbonized coal is gradually pulverized.
 前記石炭不活性化処理装置では、前記送給管の管径が大きいと、当該送給管の大きさに応じて当該送給管に乗る乾留炭の量が多くなることから、前記乾留炭の粉化が進行しすぎてしまい、粉化した前記乾留炭がロータリキルン内に供給される処理ガスに同伴し、当該処理ガスと共に系外へ排出され、不活性化処理された石炭の歩留まりを低下させてしまう可能性があった。他方、前記送給管の管径が小さいと、この大きさに応じて当該送給管に乗る乾留炭の量が少なくなることから、前記乾留炭と前記処理ガスとの接触効率が低下してしまい、前記乾留炭の不活性化処理を効率良く行うことができない可能性があった。 In the coal deactivation processing apparatus, when the pipe diameter of the feed pipe is large, the amount of dry-distilled coal that rides on the feed pipe increases according to the size of the feed pipe. The pulverization progresses too much, and the pulverized dry-distilled coal accompanies the processing gas supplied into the rotary kiln and is discharged out of the system together with the processing gas, reducing the yield of the deactivated coal. There was a possibility of letting it. On the other hand, when the pipe diameter of the feed pipe is small, the amount of dry-distilled coal that rides on the feed pipe is reduced according to the size, so that the contact efficiency between the dry-distilled coal and the processing gas decreases. Therefore, there is a possibility that the inactivation treatment of the carbonized coal cannot be performed efficiently.
 このようなことから、本発明は、前述した課題を解決するために為されたものであって、石炭の自然発火の防止を図りつつ、石炭の表面への酸素の吸着を効率良く行うことができる石炭不活性化処理装置を提供することを目的としている。 Therefore, the present invention has been made to solve the above-described problems, and can efficiently adsorb oxygen onto the surface of coal while preventing spontaneous combustion of coal. It aims at providing the coal inactivation processing apparatus which can be performed.
 上述した課題を解決する第1の発明に係る石炭不活性化処理装置は、酸素を含有する処理ガスで石炭の不活性化を行う石炭不活性化処理装置において、前記石炭および前記処理ガスが内部に供給され、回転可能に設けられたキルン本体と、前記キルン本体と共に回転可能に設けられると共に、前記キルン本体の長手方向に延在して設けられ、内部を冷却水が流通する送給管と、前記送給管の外周部に当該送給管の回転方向へ突出して設けられ当該送給管の径断面にてハット形をなす突起部とを備え、前記送給管および前記突起部は、前記キルン本体が回転したときに当該キルン本体内にて前記石炭が堆積してなる石炭層を通過するように配置されることを特徴とする。 The coal inactivation processing apparatus according to the first invention for solving the above-described problem is a coal inactivation processing apparatus that inactivates coal with a processing gas containing oxygen, in which the coal and the processing gas are contained inside. A kiln main body provided rotatably and provided rotatably with the kiln main body and extending in the longitudinal direction of the kiln main body, and a feed pipe through which cooling water flows. A projecting portion that protrudes in the rotation direction of the feed pipe and forms a hat shape in a radial cross section of the feed pipe, and the feed pipe and the projecting portion are provided on the outer periphery of the feed pipe, When the kiln main body rotates, the kiln main body is disposed so as to pass through a coal bed in which the coal is deposited.
 上述した課題を解決する第2の発明に係る石炭不活性化処理装置は、前述した第1の発明に係る石炭不活性化処理装置であって、前記突起部は、前記送給管の径断面にてV字状をなし、前記突起部の頂点は、前記送給管の中心軸の軌跡と一致することを特徴とする。 The coal inactivation processing apparatus according to the second invention that solves the above-described problem is the coal inactivation processing apparatus according to the first invention described above, wherein the protrusion is a radial section of the feed pipe. It is characterized in that it has a V-shape and the apex of the protrusion coincides with the locus of the central axis of the feed pipe.
 上述した課題を解決する第3の発明に係る石炭不活性化処理装置は、前述した第1または第2の発明に係る石炭不活性化処理装置であって、前記突起部は、当該突起部の頂点および前記送給管の中心軸を通る面で対称となる形状であり、前記突起部の頂点を通る前記送給管の二つの接線の当該送給管との交点同士を結ぶ直線と、前記接線の一方とでなす角部が、安息角よりも大きいことを特徴とする。 A coal inactivation processing apparatus according to a third aspect of the present invention that solves the above-described problem is the coal inactivation processing apparatus according to the first or second aspect of the invention described above, wherein the protrusion is formed of the protrusion. A shape that is symmetric with respect to a vertex and a plane that passes through the central axis of the feed pipe, and a straight line that connects the intersections of the two tangents of the feed pipe that pass through the top of the protrusion with the feed pipe, and The corner formed by one of the tangent lines is larger than the angle of repose.
 上述した課題を解決する第4の発明に係る石炭不活性化処理装置は、前述した第1乃至第3の何れか一つの発明に係る石炭不活性化処理装置であって、前記突起部の頂点と前記送給管の中心軸との距離は、前記送給管の半径の2倍以下であることを特徴とする。 A coal inactivation processing apparatus according to a fourth aspect of the present invention that solves the above-described problem is the coal inactivation processing apparatus according to any one of the first to third aspects of the invention described above, and is the apex of the protrusion. And the center axis of the feed pipe is not more than twice the radius of the feed pipe.
 本発明に係る石炭不活性化処理装置によれば、送給管の外周部に当該送給管の回転方向へ突出して設けられたハット形をなす突起部を備え、送給管および突起部が、キルン本体が回転したときにキルン本体内にて石炭が堆積してなる石炭層を通過するように配置されることで、送給管内を流通する冷却水により石炭を冷却しつつ、キルン本体の回転により石炭を撹拌すると共に、送給管および突起部により所定の量の石炭をキルン本体内の石炭層表面よりも上方に持ち上げ上方より落下させて石炭を撹拌して、当該石炭と処理ガスとの接触機会を適した状態にすることができる。これにより、石炭の自然発火の防止を図りつつ、石炭の表面への酸素の吸着を効率良く行うことができる。さらに、送給管に突起部を設けていない場合と比べて、キルン本体の全長を短くすることができ、装置の小型化を図ることができる。 According to the coal deactivation processing apparatus according to the present invention, the outer periphery of the feed pipe is provided with a hat-shaped projection provided so as to project in the rotation direction of the feed pipe, and the feed pipe and the projection are The kiln body is arranged to pass through a coal layer in which the coal is deposited in the kiln body, while cooling the coal with cooling water circulating in the feed pipe, While stirring the coal by rotation, a predetermined amount of coal is lifted above the surface of the coal bed in the kiln body by the feed pipe and the protrusion, and dropped from above to stir the coal. The contact opportunity can be made suitable. Thereby, adsorption | suction of oxygen to the surface of coal can be performed efficiently, aiming at prevention of spontaneous combustion of coal. Furthermore, the overall length of the kiln main body can be shortened compared to the case where no protrusion is provided on the feed pipe, and the apparatus can be downsized.
本発明に係る石炭不活性化処理装置の一実施形態の概略構成図である。It is a schematic block diagram of one Embodiment of the coal inactivation processing apparatus which concerns on this invention. 図1におけるII-II矢視断面を拡大した図である。It is the figure which expanded the II-II arrow cross section in FIG. 前記石炭不活性化処理装置が具備する送給管の拡大図である。It is an enlarged view of the feed pipe which the said coal inactivation processing apparatus comprises.
 本発明に係る石炭不活性化処理装置の一実施形態を図面に基づいて説明するが、本発明は、図面に基づいて説明する以下の実施形態のみに限定されるものではない。 Although one embodiment of the coal inactivation processing apparatus according to the present invention will be described with reference to the drawings, the present invention is not limited to only the following embodiments described with reference to the drawings.
 本発明に係る石炭不活性化処理装置の一実施形態を図1~図3に基づいて説明する。 An embodiment of a coal inactivation processing apparatus according to the present invention will be described with reference to FIGS.
 図1に示すように、乾留された石炭1を不活性化処理する石炭不活性化処理装置100は、乾留された石炭1を受け入れるホッパ101と、ホッパ101の送出口に基端側が連絡して設けられ、前記ホッパ101内の前記石炭1を回転して一端側(基端側)から他端側(先端側)へ搬送する回転式搬送手段であるスクリューフィーダ102とを備える。 As shown in FIG. 1, a coal deactivation treatment apparatus 100 that deactivates dry-distilled coal 1 has a hopper 101 that receives dry-distilled coal 1, and a base end side that communicates with a delivery port of the hopper 101. And a screw feeder 102 that is a rotary conveying means that rotates and conveys the coal 1 in the hopper 101 from one end side (base end side) to the other end side (tip end side).
 スクリューフィーダ102の先端側は、円筒状をなすロータリキルン本体(キルン本体)103の基端側に連絡している。ロータリキルン本体103の基端側は、シール装置108を介して基端側ケーシング111と連絡している。基端側ケーシング111の上部には処理ガス13を導入するガス受入口111aが設けられる。ガス受入口111aは、処理ガス13を供給する処理ガス供給管121の先端側が接続している。処理ガス供給管121の途中には、ブロア127および加熱装置128が設けられている。 The distal end side of the screw feeder 102 communicates with the proximal end side of a cylindrical rotary kiln main body (kiln main body) 103. The base end side of the rotary kiln main body 103 is in communication with the base end side casing 111 via the sealing device 108. A gas receiving port 111 a for introducing the processing gas 13 is provided at the upper part of the base end side casing 111. The gas inlet 111a is connected to the distal end side of the processing gas supply pipe 121 that supplies the processing gas 13. A blower 127 and a heating device 128 are provided in the middle of the processing gas supply pipe 121.
 処理ガス供給管121の基端側には、空気11を供給する空気供給管122の先端側と、窒素ガス12を供給する窒素供給管123の先端側とが接続している。空気供給管122の基端側は大気開放されている。窒素供給管123の基端側は、窒素ガスタンクなどのような窒素供給源124と接続している。空気供給管122および窒素供給管123の途中には、流量調整弁125,126がそれぞれ設けられている。 The distal end side of the air supply pipe 122 that supplies the air 11 and the distal end side of the nitrogen supply pipe 123 that supplies the nitrogen gas 12 are connected to the proximal end side of the processing gas supply pipe 121. The base end side of the air supply pipe 122 is open to the atmosphere. The base end side of the nitrogen supply pipe 123 is connected to a nitrogen supply source 124 such as a nitrogen gas tank. In the middle of the air supply pipe 122 and the nitrogen supply pipe 123, flow control valves 125 and 126 are provided, respectively.
 ロータリキルン本体103の先端側は、シール装置109a,109bを介して先端側ケーシング112と連絡している。先端側ケーシング112の上部には使用済みの処理ガス14を排出するガス排出口112aが設けられる。ガス排出口112aは、使用済みの処理ガス14を排出する処理ガス排出管131の基端側が接続している。処理ガス排出管131の途中に温度センサ131aが設けられている。先端側ケーシング112の下部に不活性化処理済みの石炭(改質炭)3を落下排出するシュータ112bが設けられる。 The distal end side of the rotary kiln main body 103 communicates with the distal end side casing 112 via seal devices 109a and 109b. A gas discharge port 112 a for discharging the used processing gas 14 is provided in the upper part of the front end side casing 112. The base end side of the processing gas discharge pipe 131 that discharges the used processing gas 14 is connected to the gas discharge port 112a. A temperature sensor 131 a is provided in the middle of the processing gas discharge pipe 131. A shooter 112b that drops and discharges the deactivated coal (modified coal) 3 is provided at the lower portion of the front end side casing 112.
 ロータリキルン本体103の外周部における先端側および基端側に環状の突条部104が設けられ、突条部104がローラ105により支持されている。ロータリキルン本体103の外周部には、駆動用電動機107のギア107aに噛み合うギア106が設けられる。よって、駆動用電動機107のギア107aが回転することにより、ロータリキルン本体103が回転することになる。 An annular ridge 104 is provided on the distal end side and the proximal end side of the outer peripheral portion of the rotary kiln main body 103, and the ridge 104 is supported by a roller 105. A gear 106 that meshes with the gear 107 a of the driving electric motor 107 is provided on the outer peripheral portion of the rotary kiln main body 103. Therefore, when the gear 107a of the driving motor 107 is rotated, the rotary kiln main body 103 is rotated.
 上述した石炭不活性化処理装置100は、冷却装置140をさらに備える。冷却装置140は、ロータリキルン本体103の先端側の側壁部103aに固定されるベアリング145を備える。冷却装置140は、ベアリング145に設けられ、系外から冷却水21が送給される冷却水送給ヘッダ141を備える。冷却水送給ヘッダ141には、冷却水21を送給する送給管142(例えば、二重管)が複数、例えば8本(図2参照)接続している。冷却装置140は、送給管142を流通した使用済みの冷却水22を系外へ排出する冷却水排出ヘッダ146を備える。 The coal inactivation processing apparatus 100 described above further includes a cooling device 140. The cooling device 140 includes a bearing 145 fixed to the side wall portion 103 a on the distal end side of the rotary kiln main body 103. The cooling device 140 includes a cooling water supply header 141 that is provided on the bearing 145 and to which the cooling water 21 is supplied from outside the system. A plurality of, for example, eight (see FIG. 2) feed pipes 142 (for example, double pipes) for feeding the coolant 21 are connected to the coolant feed header 141. The cooling device 140 includes a cooling water discharge header 146 that discharges the used cooling water 22 circulated through the supply pipe 142 to the outside of the system.
 複数の送給管142は、図1および図2に示すように、ロータリキルン本体103内にて、ロータリキルン本体103の周方向で等間隔に隣接して配置される。複数の送給管142は、ロータリキルン本体103が回転したときに、石炭2のロータリキルン本体103内への充填率が例えば10%~15%であっても石炭2が堆積してなる石炭層内を通過する位置に配置されると共に、その中心軸C2とロータリキルン本体103の中心軸C1との距離D1が同一となるように配置される。複数の送給管142は、ロータリキルン本体103内にて、ロータリキルン本体103の中心軸C1と平行に延在し、ロータリキルン本体103の先端側から基端側に亘って延在している。これにより、ロータリキルン本体103内部に供給される処理ガス13により石炭2が不活性化処理される領域においては、送給管142内を流通する冷却水21によって石炭2が自然発火しない温度に調整される。 As shown in FIGS. 1 and 2, the plurality of feed pipes 142 are arranged in the rotary kiln main body 103 adjacent to each other at equal intervals in the circumferential direction of the rotary kiln main body 103. The plurality of feed pipes 142 is a coal layer formed by depositing coal 2 even when the filling rate of coal 2 into the rotary kiln body 103 is, for example, 10% to 15% when the rotary kiln body 103 rotates. It arrange | positions so that the distance D1 of the center axis | shaft C2 and the center axis | shaft C1 of the rotary kiln main body 103 may become the same. The plurality of feed pipes 142 extend in the rotary kiln main body 103 in parallel to the central axis C1 of the rotary kiln main body 103, and extend from the distal end side to the proximal end side of the rotary kiln main body 103. . Thereby, in the region where the coal 2 is inactivated by the processing gas 13 supplied into the rotary kiln main body 103, the temperature is adjusted so that the coal 2 does not spontaneously ignite by the cooling water 21 flowing in the feed pipe 142. Is done.
 複数の送給管142は、ロータリキルン本体103の側壁部103aを貫通して配置される。複数の送給管142は、その長手方向の複数箇所に配置された支持具(図示せず)により支持されている。これにより、複数の送給管142は、ロータリキルン本体103の回転に伴い、当該ロータリキルン本体103と共に当該ロータリキルン本体103の中心軸C1を中心として回転することになる。 The plurality of feed pipes 142 are disposed so as to penetrate the side wall 103a of the rotary kiln main body 103. The plurality of feed pipes 142 are supported by support tools (not shown) arranged at a plurality of locations in the longitudinal direction. As a result, the plurality of feed pipes 142 rotate around the central axis C <b> 1 of the rotary kiln body 103 together with the rotary kiln body 103 as the rotary kiln body 103 rotates.
 ここで、上述した送給管142の諸元について、図2および図3を参照して説明する。
 図2において、Aはロータリキルン本体103の回転方向を示している。L1は、複数の送給管142の中心軸C2が通る軌跡を示し、L2は、前記軌跡L1の接線を示している。図2および図3において、L3は、後述する突起部143の二等分線を示している。図3において、L4,L5は、突起部143の頂点143cを通る送給管142の接線を示している。L11は、送給管142と接線L5の接点P1と、送給管142と接線L4の接点P2を通る補助線を示している。L12,L13は、送給管142の中心軸C2と接点P1,P2を通る補助線をそれぞれ示している。αは、二等分線L3と接線L5(ハットの内側平面部143a)でなす鋭角であり、突起部の角度(ハット角)を示し、βは二等分線L3と補助線L12とでなす鋭角を示している。θは接線L5と補助線L11でなす鋭角を示している。なお、補助線L11,L12,L13が中心軸C2を頂点とする二等辺三角形をなし、補助線L12と接線L5とで直角をなすことから、角βは、角θと同じ大きさとなる。
Here, the specifications of the feeding pipe 142 described above will be described with reference to FIGS.
In FIG. 2, A indicates the rotational direction of the rotary kiln body 103. L1 indicates a trajectory through which the central axis C2 of the plurality of supply pipes 142 passes, and L2 indicates a tangent to the trajectory L1. 2 and 3, L3 indicates a bisector of a protrusion 143 to be described later. In FIG. 3, L4 and L5 indicate tangent lines of the feed pipe 142 passing through the apex 143c of the protrusion 143. L11 indicates an auxiliary line passing through the contact point P1 between the feed pipe 142 and the tangent line L5 and the contact point P2 between the feed pipe 142 and the tangent line L4. L12 and L13 indicate auxiliary lines passing through the central axis C2 of the feed pipe 142 and the contacts P1 and P2, respectively. α is an acute angle formed by the bisector L3 and the tangent line L5 (inner plane portion 143a of the hat), and indicates the angle (hat angle) of the protrusion, and β is formed by the bisector L3 and the auxiliary line L12. It shows an acute angle. θ represents an acute angle formed by the tangent line L5 and the auxiliary line L11. The auxiliary lines L11, L12, and L13 form an isosceles triangle having the central axis C2 as an apex, and the auxiliary line L12 and the tangent line L5 form a right angle. Therefore, the angle β is the same size as the angle θ.
 図2および図3に示すように、送給管142は、その径方向断面にて真円をなしている。送給管142の外周部には、当該送給管142の回転方向Aへ突出するハット形をなす突起部143が設けられる。より具体的には、突起部143は、送給管142の径断面にてV字状をなしている。前記突起部143は、送給管142と同様に、ロータリキルン本体103が回転したときに、石炭2のロータリキルン本体103内への充填率が例えば10%~15%であっても石炭2が堆積してなる石炭層内を通過する位置に配置される。 As shown in FIG. 2 and FIG. 3, the feed pipe 142 has a perfect circle in its radial cross section. A protrusion 143 having a hat shape is provided on the outer peripheral portion of the feed pipe 142 so as to project in the rotation direction A of the feed pipe 142. More specifically, the protrusion 143 has a V shape in the radial cross section of the feed pipe 142. Similar to the feed pipe 142, the protrusion 143 is configured so that when the rotary kiln main body 103 rotates, even if the filling rate of the coal 2 into the rotary kiln main body 103 is, for example, 10% to 15%, It is arranged at a position that passes through the coal bed that is deposited.
 突起部143は、ロータリキルン本体103の中心軸C1側に位置づけられる内側平面部143aと、ロータリキルン本体103の外周面側に位置づけられる外側平面部143bとを備える。内側平面部143aと外側平面部143bは、先端側が接続している。突起部143の頂点143cは、送給管142の中心軸C2の軌跡と一致する位置に位置づけられる。これにより、送給管142および突起部143によって石炭層表面2aより上方に持ち上げられる石炭量をハット形の突起部が無い場合と比べて減らして、適した状態にすることができ、石炭2の撹拌による当該石炭2と処理ガス13との接触機会が適した状態になり、石炭2の不活性化処理の効率化を図ることができる。 The protruding portion 143 includes an inner flat surface portion 143a positioned on the central axis C1 side of the rotary kiln main body 103 and an outer flat surface portion 143b positioned on the outer peripheral surface side of the rotary kiln main body 103. The distal end side of the inner plane portion 143a and the outer plane portion 143b is connected. The apex 143c of the protrusion 143 is positioned at a position that coincides with the locus of the central axis C2 of the feed pipe 142. As a result, the amount of coal lifted above the coal bed surface 2a by the feed pipe 142 and the protrusion 143 can be reduced as compared with the case where there is no hat-shaped protrusion, so that a suitable state can be obtained. The contact opportunity between the coal 2 and the processing gas 13 by stirring is in a suitable state, and the efficiency of the inactivation processing of the coal 2 can be improved.
 内側平面部143aと外側平面部143bは、突起部143の先端部143cと中心軸C2を通る面で対称に配置される。つまり、突起部143は、面対称となる形状である。また、突起部143の頂点143cを通る送給管142の二つの接線L4,L5の当該送給管142との交点P2,P1同士を結ぶ直線L11と、接線L5の一方とでなす角部θが、安息角よりも大きくなっている。これは、前記角部θが安息角より小さいと前記突起部143に石炭2が乗る量が多くなり、当該石炭2の粉化を促進して、不活性化処理された石炭3の歩留まりを低下させてしまうことになるからである。 The inner plane portion 143a and the outer plane portion 143b are arranged symmetrically on a plane passing through the tip portion 143c of the protrusion 143 and the central axis C2. That is, the protrusion 143 has a shape that is plane-symmetric. Further, a corner portion θ formed by a straight line L11 connecting the intersections P2, P1 of the two tangents L4, L5 of the feed pipe 142 passing through the apex 143c of the projection 143 and the feed pipe 142 and one of the tangent lines L5. However, it is larger than the angle of repose. This is because if the corner portion θ is smaller than the angle of repose, the amount of coal 2 on the protrusion 143 increases, promoting the pulverization of the coal 2 and reducing the yield of the deactivated coal 3. It is because it will let you.
 前記突起部143の先端部143cと送給管142の中心軸C2との距離D2は、前記送給管142の半径の2倍以下であることが好ましく、1倍以下であるとより好ましい。これは、前記距離D2が前記上限値を上回ると、送給管142内の冷却水21と石炭2との伝熱面積が減少し、熱交換率が低下するとともに、ロータリキルン本体103内にて突起部143と送給管142との間にできる空間部が多数生じ、処理石炭量が低下してしまうからである。 The distance D2 between the tip 143c of the protrusion 143 and the central axis C2 of the feed pipe 142 is preferably less than or equal to twice the radius of the feed pipe 142, and more preferably less than or equal to one. This is because when the distance D2 exceeds the upper limit value, the heat transfer area between the cooling water 21 and the coal 2 in the feed pipe 142 decreases, the heat exchange rate decreases, and the rotary kiln main body 103 This is because a large number of space portions are formed between the projection 143 and the feed pipe 142, and the amount of treated coal is reduced.
 なお、送給管142および突起部143として、石炭2との反応性がなく、耐熱性のある材料で作製されたもの、例えば鋼鉄製のものを用いることが可能である。 In addition, as the feed pipe 142 and the protrusion 143, it is possible to use one made of a material having no reactivity with the coal 2 and having heat resistance, for example, steel.
 さらに、上述した石炭不活性化処理装置100において、送給管142の半径r2と、ロータリキルン本体103の中心軸C1と送給管142の中心軸C2の距離D1とが以下の関係式(1)を満たすとより好ましい。 Further, in the above-described coal deactivation processing apparatus 100, the radius r2 of the feed pipe 142 and the distance D1 between the central axis C1 of the rotary kiln main body 103 and the central axis C2 of the feed pipe 142 are expressed by the following relational expression (1 ) Is more preferable.
 1/50D1<r2<1/10D1              ・・・(1) 1 / 50D1 <r2 <1 / 10D1 ... (1)
 送給管142の半径r2が1/10D1(D1の10分の1)以上である場合には、ロータリキルン本体103内の石炭層の厚みに対して、送給管142の管径が大きすぎ、石炭2の流動が大きくなるため、石炭2の粉化を促進してしまう。他方、送給管142の半径r2が1/50D1(D1の50分の1)以下である場合には、送給管142が細く、石炭2層に送給管142を多く設置しないと、熱交換できなくなり、設備コスト増となるだけではなく、送給管142への冷却水21の供給水圧が高くなり、より多くの動力を消費してしまう。よって、上述の(1)式を満たすことにより、石炭2の粉化を抑制し、設備コスト増および動力消費増を抑制することができる。 When the radius r2 of the feed pipe 142 is 1 / 10D1 (1/10 of D1) or more, the pipe diameter of the feed pipe 142 is too large with respect to the thickness of the coal layer in the rotary kiln body 103. Since the flow of coal 2 becomes large, pulverization of coal 2 will be promoted. On the other hand, when the radius r2 of the feed pipe 142 is 1/50 D1 (1/50 of D1) or less, the feed pipe 142 is thin, and if many feed pipes 142 are not installed in the two layers of coal, It becomes impossible to exchange, and not only the equipment cost increases, but also the supply water pressure of the cooling water 21 to the feed pipe 142 becomes high, and more power is consumed. Therefore, by satisfy | filling above-mentioned (1) Formula, pulverization of the coal 2 can be suppressed and an increase in equipment cost and an increase in power consumption can be suppressed.
 また、上述した石炭不活性化処理装置100において、隣接する送給管142,142間の距離D3は以下の(2)式を満足するとより好ましい。 In the above-described coal deactivation processing apparatus 100, it is more preferable that the distance D3 between the adjacent feed pipes 142 and 142 satisfies the following expression (2).
 2r2<D3<6r2  ・・・(2) 2r2 <D3 <6r2 ... (2)
 隣接する送給管142,142間の距離D3が2r2(送給管142の半径r2の2倍)以下である場合には、隣接する送給管142,142が近すぎて、石炭2が隣接する送給管142,142の間でブリッジしてしまう。他方、隣接する送給管142,142間の距離D3が6r2(送給管142の半径r2の6倍)以上である場合には、送給管142内の冷却水21と石炭2との伝熱面積が減少することから、石炭2の冷却伝熱面積を確保できなくなってしまう。よって、上述の(2)式を満たすことにより、隣接する送給管142,142の間でのブリッジの発生を抑制することができ、送給管142内の冷却水21による石炭2の冷却伝熱面積を確保することができる。 When the distance D3 between the adjacent feed pipes 142 and 142 is 2r2 (twice the radius r2 of the feed pipe 142), the adjacent feed pipes 142 and 142 are too close and the coal 2 is adjacent. Bridge between the feeding pipes 142 and 142. On the other hand, when the distance D3 between the adjacent feed pipes 142, 142 is 6r2 (6 times the radius r2 of the feed pipe 142) or more, the transmission between the cooling water 21 in the feed pipe 142 and the coal 2 is performed. Since the heat area decreases, the cooling heat transfer area of the coal 2 cannot be secured. Therefore, by satisfying the above equation (2), it is possible to suppress the occurrence of a bridge between the adjacent feed pipes 142 and 142, and the cooling transmission of the coal 2 by the cooling water 21 in the feed pipe 142. A heat area can be secured.
 このような本実施形態においては、前記処理ガス供給管121、前記加熱装置128、前記ブロア127、前記空気供給管122、前記流量調整弁125、前記窒素供給管123、前記流量調整弁126、前記窒素供給源124、前記基端側ケーシング111、前記ガス受入口111aなどが処理ガス供給手段を構成している。前記冷却水送給ヘッダ141、前記送給管142、前記突起部143、前記ベアリング145、前記冷却水排出ヘッダ146などが冷却手段をなす前記冷却装置140を構成している。前記突条部104、前記ローラ105、前記ギア106、前記駆動用電動機107、前記ギア107aなどが回転手段を構成している。前記ホッパ101、前記スクリューフィーダ102などが石炭供給手段を構成している。前記先端側ケーシング112の前記シュータ112bなどが石炭排出手段を構成している。前記先端側ケーシング112、前記ガス排出口112a、前記処理ガス排出管131などが処理ガス排出手段を構成している。前記各手段、前記ロータリキルン本体103、前記シール装置108,109a,109bなどが前記石炭不活性化処理装置100を構成している。 In this embodiment, the processing gas supply pipe 121, the heating device 128, the blower 127, the air supply pipe 122, the flow rate adjustment valve 125, the nitrogen supply pipe 123, the flow rate adjustment valve 126, The nitrogen supply source 124, the base end side casing 111, the gas receiving port 111a, and the like constitute processing gas supply means. The cooling water feed header 141, the feed pipe 142, the projection 143, the bearing 145, the cooling water discharge header 146, and the like constitute the cooling device 140 that forms a cooling means. The ridge 104, the roller 105, the gear 106, the drive motor 107, the gear 107a, and the like constitute a rotating means. The hopper 101, the screw feeder 102, and the like constitute coal supply means. The shooter 112b and the like of the front end side casing 112 constitute coal discharging means. The front end side casing 112, the gas discharge port 112a, the processing gas discharge pipe 131, and the like constitute processing gas discharge means. Each means, the rotary kiln main body 103, the sealing devices 108, 109a, 109b, etc. constitute the coal inactivation processing device 100.
 次に、上述した石炭不活性化処理装置100の中心となる作動を説明する。 Next, the operation that is the center of the above-described coal deactivation processing apparatus 100 will be described.
 前記石炭1がホッパ101に供給されると、スクリューフィーダ102により、ロータリキルン本体103内に搬送される。他方、ブロア127の作動を制御する一方、流量調整弁125,126の開度を制御することにより空気供給管122および窒素供給管123を介して処理ガス供給管121に空気11および窒素ガス12が供給される。これにより、空気11および窒素ガス12が混合して処理ガス13(例えば、酸素濃度が約5~10%程度)となる。処理ガス13は、温度センサ131aにより得られた使用済みの処理ガス14の温度データに基づき加熱装置128により加熱されてロータリキルン本体103内にて40℃~200℃となるように調整され、処理ガス供給管121によりガス受入口111aを介してロータリキルン本体103内に供給される。 When the coal 1 is supplied to the hopper 101, the coal 1 is conveyed into the rotary kiln main body 103 by the screw feeder 102. On the other hand, while controlling the operation of the blower 127, the air 11 and the nitrogen gas 12 are supplied to the processing gas supply pipe 121 via the air supply pipe 122 and the nitrogen supply pipe 123 by controlling the opening degree of the flow rate adjusting valves 125 and 126. Supplied. As a result, the air 11 and the nitrogen gas 12 are mixed to become the processing gas 13 (for example, the oxygen concentration is about 5 to 10%). The processing gas 13 is heated by the heating device 128 based on the temperature data of the used processing gas 14 obtained by the temperature sensor 131a, and adjusted to be 40 ° C. to 200 ° C. in the rotary kiln main body 103. A gas supply pipe 121 supplies the rotary kiln main body 103 through the gas receiving port 111a.
 ロータリキルン本体103は、駆動用電動機107のギア107aが回転し、ギア106を介して伝達することにより回転する。ロータリキルン本体103の回転に伴って、ロータリキルン本体103内に搬送された石炭2は、撹拌されながら当該ロータリキルン本体103の基端側から先端側へ移動することになる。このとき、ロータリキルン本体103内の石炭2は、ロータリキルン本体103内部に供給された処理ガス13の酸素を吸着することになる。このように酸素吸着することにより不活性化処理された石炭(改質炭)3となり、シュータ112bを介して系外へ搬出される。ロータリキルン本体103内の石炭2は、処理ガス13の酸素を吸着して発熱するものの、送給管142内を流通する冷却水21によって、石炭2が自然発火しない温度に調整される。 The rotary kiln main body 103 rotates when the gear 107 a of the driving motor 107 rotates and is transmitted via the gear 106. As the rotary kiln main body 103 rotates, the coal 2 conveyed into the rotary kiln main body 103 moves from the proximal end side to the distal end side of the rotary kiln main body 103 while being stirred. At this time, the coal 2 in the rotary kiln main body 103 adsorbs the oxygen of the processing gas 13 supplied into the rotary kiln main body 103. In this way, the inactivated coal (reformed coal) 3 is obtained by oxygen adsorption, and is carried out of the system via the shooter 112b. Although the coal 2 in the rotary kiln main body 103 generates heat by adsorbing oxygen in the processing gas 13, the coal 2 is adjusted to a temperature at which the coal 2 does not spontaneously ignite by the cooling water 21 flowing through the feed pipe 142.
 ロータリキルン本体103内で石炭2の不活性化処理に使用された使用済みの処理ガス(約50℃~70℃)14は、石炭2の搬送方向と同じ方向に流通し、ロータリキルン本体103の先端側に設けられた先端側ケーシング112のガス排出口112aから処理ガス排出管131へ流通し、当該処理ガス排出管131を介して系外へ排出される。 The used processing gas (about 50 ° C. to 70 ° C.) 14 used for the inactivation processing of the coal 2 in the rotary kiln main body 103 circulates in the same direction as the transport direction of the coal 2, and the rotary kiln main body 103 The gas flows from the gas discharge port 112 a of the front end side casing 112 provided on the front end side to the process gas discharge pipe 131 and is discharged out of the system through the process gas discharge pipe 131.
 ここで、上述した石炭不活性化処理装置100においては、前記ロータリキルン本体103の回転に伴い、当該ロータリキルン本体103と共に、当該ロータリキルン本体103の中心軸C1を中心として回転し、当該ロータリキルン本体103内へ供給された石炭2が堆積してなる石炭層内を通過するように複数の送給管142が当該ロータリキルン本体103内に設けられ、各送給管142に突起部143が上述した諸元で設けられたことから、さらに、以下のように作動する。 Here, in the above-described coal deactivation processing apparatus 100, the rotary kiln main body 103 rotates with the rotary kiln main body 103 around the central axis C <b> 1 of the rotary kiln main body 103, and the rotary kiln main body 103 rotates. A plurality of feed pipes 142 are provided in the rotary kiln body 103 so as to pass through the coal bed formed by depositing the coal 2 supplied into the main body 103, and the projections 143 are provided on the feed pipes 142. In addition, it operates as follows.
 つまり、本実施形態では、複数の送給管142が、ロータリキルン本体103の回転に伴い、ロータリキルン本体103の中心軸C1を中心として回転移動し、石炭層を通過したときに、送給管142および突起部143により石炭2を石炭層表面2aより上方に持ち上げることになる。このとき、送給管142に突起部143を設けたことで、送給管142の安息角で持ち上げられるよりも少ない量の石炭2を前記石炭層表面2aよりも上方に持ち上げることになる。よって、突起部143を設けることで、石炭2の撹拌しすぎによる石炭2の粉化を抑制することができる。 That is, in this embodiment, when the plurality of feed pipes 142 rotate around the central axis C1 of the rotary kiln main body 103 as the rotary kiln main body 103 rotates and pass through the coal bed, The coal 2 is lifted above the coal bed surface 2a by the 142 and the protrusions 143. At this time, by providing the projecting portion 143 on the feed pipe 142, a smaller amount of coal 2 is lifted above the coal bed surface 2a than is lifted at the angle of repose of the feed pipe 142. Therefore, by providing the protrusion 143, pulverization of the coal 2 due to excessive stirring of the coal 2 can be suppressed.
 したがって、本実施形態に係る石炭不活性化処理装置100によれば、送給管142の外周部に当該送給管142の回転方向Aへ突出して設けられた突起部143を備え、送給管142および突起部143が、ロータリキルン本体103が回転したときにロータリキルン本体103内にて石炭2が堆積してなる石炭層を通過するように配置されることで、送給管142内を流通する冷却水21により石炭2を冷却しつつ、ロータリキルン本体103の回転により石炭2を撹拌すると共に、送給管142および突起部143により所定の量の石炭2をロータリキルン本体103内の石炭層表面2aよりも上方に持ち上げ上方より落下させて石炭2を撹拌して、当該石炭2と処理ガス13との接触機会を適した状態にすることができる。これにより、石炭2の自然発火の防止を図りつつ、石炭2の表面への酸素の吸着を効率良く行うことができる。さらに、送給管にハット形の突起部を設けていない場合と比べて、ロータリキルン本体103の全長を短くすることができ、装置の小型化を図ることができる。 Therefore, according to the coal deactivation processing apparatus 100 according to the present embodiment, the outer periphery of the feed pipe 142 includes the protrusion 143 provided to project in the rotation direction A of the feed pipe 142, and the feed pipe 142 and the protrusion 143 are arranged so as to pass through a coal bed in which the coal 2 is deposited in the rotary kiln main body 103 when the rotary kiln main body 103 rotates, and thereby circulate in the feed pipe 142. While the coal 2 is being cooled by the cooling water 21 to be stirred, the coal 2 is agitated by the rotation of the rotary kiln main body 103, and a predetermined amount of the coal 2 is fed into the coal layer in the rotary kiln main body 103 by the feed pipe 142 and the protrusion 143. The coal 2 is stirred by being lifted upward from the surface 2a and dropped from above, and the contact opportunity between the coal 2 and the processing gas 13 can be made suitable. Thereby, adsorption | suction of oxygen to the surface of coal 2 can be performed efficiently, aiming at prevention of spontaneous ignition of coal 2. Furthermore, the overall length of the rotary kiln main body 103 can be shortened compared to the case where no hat-shaped protrusion is provided on the feed pipe, and the apparatus can be downsized.
 [他の実施形態]
 なお、複数の送給管142のそれぞれに設けられた突起部143の形状は1種類に限らず、2種類以上とすることも可能である。
[Other Embodiments]
Note that the shape of the protrusion 143 provided in each of the plurality of supply pipes 142 is not limited to one type, and may be two or more types.
 上記では、8本の送給管142を備える石炭不活性化処理装置100を用いて説明したが、送給管の数量は8本に限らず、7本以下や9本以上の送給管を備える石炭不活性化処理装置とすることも可能である。 In the above description, the coal inactivation processing apparatus 100 including the eight supply pipes 142 has been described. However, the number of the supply pipes is not limited to eight, and seven or less or nine or more supply pipes are used. It is also possible to provide a coal inactivation treatment apparatus.
1,2,3 石炭、11 空気、12 窒素ガス、13,14 処理ガス、21,22 冷却水、100 石炭不活性化処理装置、101 ホッパ、102 スクリューフィーダ、103 ロータリキルン本体(キルン本体)      、104 突条部、105 ローラ、106 ギア、107 駆動用電動機、107a ギア、108 シール装置、109a,109b シール装置、111 基端側ケーシング、111a ガス受入口、112 先端側ケーシング、112a ガス排出口、112b シュータ、121 処理ガス供給管、122 空気供給管、123 窒素供給管、124 窒素供給源、125,126 流量調整弁、127 ブロア、128 加熱装置、131 処理ガス排出管、131a 温度センサ、140 冷却装置、141 冷却水送給ヘッダ、142 送給管、143 突起部、143a 内側平面部、143b 外側平面部、143c 頂点、145 ベアリング、146 冷却水排出ヘッダ、A ロータリキルン本体の回転方向、C1 ロータリキルン本体の中心軸、C2 送給管の中心軸、D1 ロータリキルン本体の中心軸と送給管の中心軸との間の距離、D2 突起部の頂点と送給管の中心軸との間の距離、D3 隣接する送給管間の距離、L1 送給管の中心軸の軌跡、L2 送給管の中心軸の軌跡の接線、L3 突起部の二等分線、L4,L5 突起部の頂点を通る送給管の接線、L11 補助線、L12 点P1と送給管の中心軸C2を通る線、L13 点P2と送給管の中心軸C2を通る線、P1,P2 接点、r1 ロータリキルン本体の半径、r2 送給管の半径、α 突起部の角度(ハット角)、θ 線L5と線L11のなす角、β 線L3と線L12のなす角 1,2,3 coal, 11 air, 12 nitrogen gas, 13,14 treatment gas, 21,22 cooling water, 100 coal deactivation treatment device, 101 hopper, 102 screw feeder, 103 rotary kiln body (kiln body), 104 ridges, 105 rollers, 106 gears, 107 driving motors, 107a gears, 108 sealing devices, 109a and 109b sealing devices, 111 proximal casings, 111a gas inlets, 112 distal casings, 112a gas outlets, 112b shooter, 121 processing gas supply pipe, 122 air supply pipe, 123 nitrogen supply pipe, 124 nitrogen supply source, 125, 126 flow control valve, 127 blower, 128 heating device, 131 processing gas discharge pipe, 131a temperature sensor, 140 cooling Equipment, 141 Cooling water feed header, 142 Feed pipe, 143 Protrusion, 143a Inner plane, 143b Outer plane, 143c Apex, 145 bearing, 146 Coolant discharge header, A Rotary direction of rotary kiln body, C1 rotary Kiln body center axis, C2 feed pipe center axis, D1 distance between rotary kiln body center axis and feed pipe center axis, D2 between top of projection and feed pipe center axis Distance, D3 Distance between adjacent feeding pipes, L1 Trajectory of the central axis of the feeding pipe, L2 Tangent line of the central axis of the feeding pipe, L3 bisector, L4, L5 L1, auxiliary line, L12, line passing through point P1 and the central axis C2 of the feed pipe, L13, line passing through point P2 and the central axis C2 of the feed pipe, P1, P2 contact point, r1 rotor Radius of kiln body, the radius of r2 delivery line, the angle of α projections (hat angle), the angle of θ line L5 and line L11, the angle of β line L3 and the line L12

Claims (4)

  1.  酸素を含有する処理ガスで石炭の不活性化を行う石炭不活性化処理装置において、
     前記石炭および前記処理ガスが内部に供給され、回転可能に設けられたキルン本体と、
     前記キルン本体と共に回転可能に設けられると共に、前記キルン本体の長手方向に延在して設けられ、内部を冷却水が流通する送給管と、
     前記送給管の外周部に当該送給管の回転方向へ突出して設けられ当該送給管の径断面にてハット形をなす突起部とを備え、
     前記送給管および前記突起部は、前記キルン本体が回転したときに当該キルン本体内にて前記石炭が堆積してなる石炭層を通過するように配置される
    ことを特徴とする石炭不活性化処理装置。
    In a coal inactivation treatment apparatus that inactivates coal with a treatment gas containing oxygen,
    The coal and the processing gas are supplied to the inside, and a kiln main body provided rotatably,
    A feed pipe that is rotatably provided with the kiln body, is provided extending in the longitudinal direction of the kiln body, and in which cooling water flows.
    A protrusion that is provided on the outer periphery of the feed pipe so as to protrude in the rotation direction of the feed pipe and has a hat shape in the radial cross section of the feed pipe;
    The coal inactivation is characterized in that the feed pipe and the protrusion are arranged so as to pass through a coal layer in which the coal is deposited in the kiln body when the kiln body rotates. Processing equipment.
  2.  請求項1に記載された石炭不活性化処理装置であって、
     前記突起部は、前記送給管の径断面にてV字状をなし、
     前記突起部の頂点は、前記送給管の中心軸の軌跡と一致する
    ことを特徴とする石炭不活性化処理装置。
    A coal inactivation processing apparatus according to claim 1,
    The protrusion is V-shaped in the radial cross section of the feed pipe,
    The coal inactivation processing apparatus according to claim 1, wherein a vertex of the protrusion coincides with a locus of a central axis of the feed pipe.
  3.  請求項1または請求項2に記載された石炭不活性化処理装置であって、
     前記突起部は、当該突起部の頂点および前記送給管の中心軸を通る面で対称となる形状であり、
     前記突起部の頂点を通る前記送給管の二つの接線の当該送給管との交点同士を結ぶ直線と、前記接線の一方とでなす角部が、安息角よりも大きい
    ことを特徴とする石炭不活性化処理装置。
    A coal inactivation treatment apparatus according to claim 1 or claim 2,
    The protrusion is symmetrical in a plane passing through the apex of the protrusion and the central axis of the feed pipe,
    A corner formed by a straight line connecting the intersections of the two tangents of the feed pipe passing through the apex of the protrusion and the feed pipe and one of the tangents is larger than a repose angle. Coal deactivation processing equipment.
  4.  請求項1乃至請求項3の何れか一項に記載された石炭不活性化処理装置であって、
     前記突起部の頂点と前記送給管の中心軸との距離は、前記送給管の半径の2倍以下である
    ことを特徴とする石炭不活性化処理装置。
    A coal inactivation treatment apparatus according to any one of claims 1 to 3,
    The coal inactivation processing apparatus characterized in that a distance between the apex of the protrusion and the central axis of the feed pipe is not more than twice the radius of the feed pipe.
PCT/JP2014/079915 2013-12-06 2014-11-12 Coal deactivation processing device WO2015083508A1 (en)

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CN201480064758.XA CN105793657B (en) 2013-12-06 2014-11-12 Coal deactivates processing unit
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