WO2015083355A1 - Reconstituted milk having favorable taste, flavor, and emulsion stability, and method for producing same - Google Patents

Reconstituted milk having favorable taste, flavor, and emulsion stability, and method for producing same Download PDF

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Publication number
WO2015083355A1
WO2015083355A1 PCT/JP2014/005972 JP2014005972W WO2015083355A1 WO 2015083355 A1 WO2015083355 A1 WO 2015083355A1 JP 2014005972 W JP2014005972 W JP 2014005972W WO 2015083355 A1 WO2015083355 A1 WO 2015083355A1
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Prior art keywords
milk
fat
oil
emulsion
reduced
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PCT/JP2014/005972
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French (fr)
Japanese (ja)
Inventor
愛 佐藤
七洋 今田
英樹 小泉
桂二 出内
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キリン株式会社
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Priority to JP2015551383A priority Critical patent/JP6199989B2/en
Publication of WO2015083355A1 publication Critical patent/WO2015083355A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/15Reconstituted or recombined milk products containing neither non-milk fat nor non-milk proteins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C11/00Milk substitutes, e.g. coffee whitener compositions
    • A23C11/02Milk substitutes, e.g. coffee whitener compositions containing at least one non-milk component as source of fats or proteins
    • A23C11/04Milk substitutes, e.g. coffee whitener compositions containing at least one non-milk component as source of fats or proteins containing non-milk fats but no non-milk proteins

Definitions

  • the present invention is a method for producing reduced milk having a fresh milk-like taste and flavor and good emulsification stability, and in particular, reduced using a non-fat milk solid content raw material such as skim milk powder and a fat and oil raw material.
  • a non-fat milk solid content raw material such as skim milk powder and a fat and oil raw material.
  • the present invention relates to a method for producing reduced milk excellent in emulsification stability by improving the reduced emulsion stability of reduced milk that is caused when a raw material is used as a raw material.
  • the present invention also relates to processed milk, milk beverage or milk-containing beverage using reduced milk having excellent taste, flavor and emulsion stability, and a method for producing the same.
  • Reduced milk is generally defined as “a food made from milk and water added and has similar components to the components of city milk” (“Ministerial Ordinance on Component Standards for Milk and Dairy Products” (Hereinafter referred to as “Ministerial Ordinance of Milk”) ”), and milk raw materials such as powdered milk, concentrated milk, cream and butter obtained by processing raw milk and milk are used as the main raw materials in the form of drinking milk. Examples include processed milk and milk beverages whose fat content is increased or decreased compared with milk, and milk beverages added with calcium, iron, and the like.
  • Non-Patent Document 1 improvement of its flavor is an issue.
  • powdered milk materials such as milk powder, cream powder, and whey powder are widely used because they can be stored for a long period of time and are relatively inexpensive.
  • the powdered processed product of such a milk raw material not only reduces the milk flavor originally possessed by the milk raw material in the processing process such as concentration, drying, and sterilization, but also generates a strange odor other than the milk flavor, Even when water-solubilized again, there is a problem in that a sufficient milk flavor is not exhibited and a strange odor generally expressed as a powdery odor is generated (Japanese Patent Laid-Open No. 6-319448: Patent Document 1).
  • Japanese Patent Laid-Open No. 6-319448: Patent Document 1 Japanese Patent Laid-Open No. 6-319448
  • Patent Document 4 discloses that creaming does not cause long-term storage in processed milk for 3 months or more.
  • Patent Document 5 a method of containing fat globules obtained by emulsifying a fat and oil component contained in the processed milk with a complex composed of an organic acid monoglyceride and milk protein JP-A-2004-267223 (Patent Document 5) discloses a clouding point of 90 ° C. or higher in order to obtain a milk beverage capable of maintaining long-term emulsification stability even after UHT sterilization.
  • a method of containing a polyglycerol fatty acid ester is disclosed.
  • the addition of the taste-improving substance as described above has a problem in that lack of refreshing feeling due to a taste or thickening occurs, and the method of adding an emulsifier also has a problem of a taste due to the addition of the emulsifier.
  • Patent Document 6 discloses that a part of milk fat is separated by centrifugation to adjust the milk fat content of raw milk, and then processed with a reverse osmosis (RO) membrane.
  • Patent Document 7 discloses a method of concentrating milk fat and non-fat milk solids to increase protein content and calcium content and obtaining processed milk with excellent flavor.
  • a method for producing a beverage or food containing milk or a milk component free from light-induced off-flavour by heating a beverage or food containing a milk component at 140 ° C.
  • Liquid raw materials are used for the preparation of the processed milk.
  • liquid raw materials such as raw milk, milk and processed raw milk membranes generally have a problem of poor storage stability as raw materials.
  • even the method of performing a severe heat treatment as shown in the document has a problem that the natural taste of milk is denatured.
  • Patent Document 8 discloses a first milk raw material liquid mainly composed of non-fat milk solids such as nonfat concentrated milk and a milk fat content as a main component.
  • Two milk raw material liquids are separately heat-sterilized, homogenized, and cooled, and then mixed.
  • This method improves the conventional method of heat sterilization and cooling after mixing milk raw materials, and mixes milk raw materials by mixing them after heat sterilization treatment of milk raw materials separately, cooling and mixing
  • the purpose is to produce processed milk with a flavor similar to that of fresh milk by suppressing the off-flavors and off-flavors generated by heat sterilization.
  • JP-A-6-319448 Japanese Patent Laid-Open No. 2006-180792. JP 2002-335903 A. JP 2004-267147 A. JP 2004-267223 A. JP 2002-51699 A. JP 2002-262769 A. JP 2011-24508 A. Japanese National Patent Publication No. 11-505121. JP2011-152107A.
  • An object of the present invention is to provide a reduced milk having a fresh milk-like taste and flavor and good emulsification stability, in particular, a non-fat milk solid content raw material such as skim milk powder, and an oil and fat content raw material.
  • the reduced milk produced by reducing the odor and odor of the produced reduced milk can be used to produce reduced milk having a fresh milk-like taste and flavor, and the absence of powder such as skim milk powder.
  • An object of the present invention is to provide a method for producing reduced milk excellent in emulsification stability by improving the reduced emulsification stability of reduced milk caused when using a raw material of solid milk fat as a raw material.
  • this invention is providing the processed milk, milk drink, or milk-containing drink using the reduced milk excellent in this taste, flavor, and emulsion stability, and its manufacturing method.
  • the present inventors have made a reduced milk produced using a non-fat milk solid material such as skim milk powder in a method for producing reduced milk using a non-fat milk solid raw material and an oil / fat raw material.
  • a first milk raw material liquid mainly composed of non-fat milk solids such as nonfat concentrated milk and a milk fat content as a main component in the method of Japanese Patent Application Laid-Open No. 2011-24508 (Patent Document 8), a first milk raw material liquid mainly composed of non-fat milk solids such as nonfat concentrated milk and a milk fat content as a main component.
  • the method for producing reduced milk using the second milk raw material liquid by adopting a method of separately heat sterilizing the milk raw material, suppressing the off-flavors and off-flavors generated by heat sterilization, A process for producing processed milk having a flavor close to that of fresh milk has been adopted.
  • this method is applied when using a non-fat milk solid content raw material such as skim milk powder, there is a problem that it is difficult to prepare reduced milk with good emulsification stability.
  • the non-fat milk solid solution and the fat and oil emulsion were separately heat-sterilized. Later, by adopting the method of mixing, the non-fat milk solid solution and the fat and oil emulsion are heated and sterilized in a mixed state. While obtaining taste and flavor, in the homogenization treatment, the heat-sterilized non-fat milk solid solution and the fat / oil emulsion are mixed and subjected to a homogenization treatment at a temperature equal to or higher than the freezing point of the fat / oil. Thus, it was possible to obtain good emulsion stability.
  • a non-fat milk solid material and an oily fat raw material used as raw materials as a raw material particularly preferably used, a powdered milk raw material such as skim milk powder is used as a non-fat milk solid raw material.
  • the oil / fat raw material include animal fats and oils and vegetable oils, and examples of animal fats include milk fats such as butter.
  • a temperature equal to or higher than the freezing point of fats and oils can be adopted as the temperature at which the homogenization treatment is performed.
  • Examples of such homogenization treatment temperature include a temperature of 30 to 70 ° C.
  • reduced milk is produced by mixing a non-fat milk solid solution and an oil and fat emulsion, and the non-fat milk solid solution and the fat and oil emulsion are mixed.
  • the mixing ratio is adjusted so that the fat concentration is higher than 1.5% and lower than 6.0%, and the solid content of non-fat milk is higher than 5.0% and lower than 14.0%. Can do.
  • the mixed non-fat milk solid solution and the fat / oil emulsion are subjected to a homogenization treatment at a temperature equal to or higher than the freezing point of the fat / oil, and excellent in taste, flavor and emulsion stability.
  • the method for producing reduced milk excellent in taste, flavor and emulsion stability according to [1] above, wherein the non-fat milk solid content raw material is a powdered milk raw material [3] The method for producing reduced milk excellent in taste, flavor and emulsion stability according to the above [1] or [2], wherein the fat is animal fat or vegetable fat or oil, [4] The method for producing reduced milk excellent in taste, flavor and emulsion stability according to [3] above, wherein the animal fat is milk fat; [5] Production of reduced milk excellent in taste, flavor and emulsion stability according to any one of [1] to [4] above, wherein the temperature at which the homogenization treatment is performed is 30 to 70 ° C.
  • the mixing ratio of the non-fat milk solid solution and the fat / fat emulsion is such that the oil / fat concentration is higher than 1.5% and less than 6.0%, and the non-fat milk solids concentration is higher than 5.0%. From the method for producing reduced milk excellent in taste, flavor and emulsion stability according to any one of the above [1] to [5], characterized by being adjusted so as to be high and less than 14.0% Obviously.
  • the present invention comprises [7] reduced milk produced by the production method according to any one of [1] to [6] and having excellent taste, flavor and emulsion stability.
  • the present invention provides [8] a method for producing processed milk, a milk beverage or a milk-containing beverage, wherein the reduced milk according to [7] is used as all or part of the raw material, and [9] It consists of the processed milk, milk drink, or milk-containing drink manufactured by the manufacturing method of the processed milk, milk drink, or milk-containing drink as described in [8].
  • the present invention provides reduced milk having a fresh milk-like taste and flavor and good emulsification stability.
  • reduced milk using non-fat milk solid ingredients such as skim milk powder and oil and fat ingredients, reducing the off-flavors and off-flavors of the produced reduced milk, the fresh milk-like taste
  • non-fat milk solid content raw materials such as skim milk powder as a raw material
  • a method for producing reduced milk is provided.
  • the fresh milk-like taste and flavor of the present invention and reduced milk excellent in emulsification stability can be suitably used as a milk raw material for preparing processed milk, milk drinks and milk-containing drinks.
  • FIG. 1 is a diagram showing a preparation process of reduced milk Example 1 in an example of the present invention.
  • FIG. 2 is a diagram showing the preparation process of reduced milk comparative example 1 in the examples of the present invention.
  • FIG. 3 is a diagram showing a preparation process of reduced milk comparative example 2 in the examples of the present invention.
  • FIG. 4 is a diagram showing a preparation process of reduced milk comparative example 3 in the example of the present invention.
  • FIG. 5 is a diagram showing the preparation process of reduced milk example 2 in the example of the present invention.
  • FIG. 6 is a diagram showing a preparation process of reduced milk comparative example 4 in the examples of the present invention.
  • FIG. 7 is a diagram showing the preparation process of reduced milk Example 3 in the Example of the present invention.
  • FIG. 1 is a diagram showing a preparation process of reduced milk Example 1 in an example of the present invention.
  • FIG. 2 is a diagram showing the preparation process of reduced milk comparative example 1 in the examples of the present invention.
  • FIG. 3 is
  • FIG. 8 is a diagram showing a preparation process of reduced milk example 4 in the example of the present invention.
  • FIG. 9 is a diagram illustrating a preparation process of reduced milk comparative example 5 in the example of the present invention.
  • FIG. 10 is a diagram illustrating a preparation process of reduced milk comparative example 6 in the example of the present invention.
  • the present invention provides a method for producing reduced milk using a non-fat milk solid raw material and an oily fat raw material, (1) a step of preparing a non-fat milk solid solution containing the non-fat milk solid raw material, and ( 2) Separately from the step (1), a step of preparing an oil / fat emulsion containing an oil / fat component, and (3) a non-fat milk solid prepared in the steps (1) and (2) A step of heat-sterilizing the separated solution and the fat and oil emulsion, and (4) a step of cooling and mixing the heat-sterilized nonfat milk solid solution and the fat and oil emulsion, and (5) And a step of homogenizing the mixed non-fat milk solid solution and the fat and oil emulsion at a temperature equal to or higher than the freezing point of the fat and oil, and a method for producing reduced milk excellent in taste, flavor and emulsion stability , And also expressed as “Method for producing reduced milk of the present invention”).
  • the non-fat milk solid content solution and the fat and oil emulsion are reduced in taste and off-flavor in the reduced milk when heat-sterilized in a mixed state.
  • Reduced milk is defined as drinking milk produced by reducing dairy products produced using raw milk or milk as raw materials, and beverages to which raw materials other than milk raw materials are added as necessary. “Reduced milk” is a concept that includes all of “processed milk” and “milk drink” in “Departmental Decree of Milk”.
  • raw milk refers to milk of cows that have been milked
  • milk refers to milk of cows that have been sterilized for drinking or processing.
  • airy products used as a raw material for reduced milk include those classified as “dairy products” in the “Ministry Ordinance of Milk, etc.”.
  • skim milk powder whole milk powder, concentrated milk, skim concentrated milk , Cream powder, cream, butter, butter oil, concentrated whey, whey powder, protein concentrated whey powder, buttermilk powder, sweetened powdered milk, prepared powdered milk and the like.
  • the present invention is directed to reduced milk using a non-fat milk solid raw material in the form of skim milk powder and an oily fat raw material and a method for producing the reduced milk in the above-mentioned “reduced milk”, and more preferably.
  • reduced milk excellent in taste and flavor means reducing off-flavor (powder odor), off-flavor in reduced milk produced by a general production method using a milk raw material such as skim milk powder, This means reduced milk with a taste and flavor that is similar to fresh milk. More specifically, the same amount and amount of raw material are used to produce the same amount of reduced milk. Compared to the case of manufacturing with a process that includes heat and sterilization treatment in a state where solids and fats and oils are mixed), the off-flavour (powder smell) and off-taste are reduced, and the taste like fresh milk, Contains reduced milk with improved flavor.
  • “reduced milk with improved emulsification stability” or “reduced milk with excellent emulsification stability” means a general production method (especially none) using a powdered milk raw material such as skim milk powder.
  • the reduced milk is produced by a method including a step of mixing the nonfat milk solid solution and the fat emulsion solution after homogenization.
  • a step of preparing a non-fat milk solid content solution containing a non-fat milk solid content raw material (1) a step of preparing a non-fat milk solid content solution containing a non-fat milk solid content raw material, and (2) separately from the step (1) above, A step of preparing an oil / fat emulsion containing an oil / fat raw material, and (3) heat-sterilization treatment of the non-fat milk solid solution and the oil / fat emulsion prepared in steps (1) and (2), respectively.
  • the reduced milk is produced by a production process comprising the step of homogenizing the liquid at a temperature equal to or higher than the freezing point of the fat.
  • the treatment conditions used in the production of reduced milk can be used as the treatment conditions in each step.
  • Non-fat milk solid content materials used in the method for producing reduced milk of the present invention include skim milk powder, whole powdered milk, sweetened powdered milk, prepared powdered milk, skim concentrated milk, milk protein powder, milk protein concentrate, and the like.
  • the effect of the present invention (the effect of reducing off-flavors and off-flavors that are problematic in reduced milk, and reduced emulsification stability, which is particularly problematic in reduced milk using a non-fat milk solid content raw material such as skim milk powder) From the viewpoint of enjoying more improvement effect), powdered milk raw materials such as skim milk powder, whole milk powder, sweetened powder milk, prepared milk powder, milk protein powder, milk protein concentrate, and the like are preferable, and skim milk powder is more preferable among them.
  • the use ratio of the non-fat milk solid content raw material of the powder is preferably 25% or more, preferably 50% or more, of the non-fat milk solid content in the non-fat milk solid solution in the present invention.
  • 1 type may be sufficient as the nonfat milk solid content raw material to be used, and 2 or more types may be sufficient as it.
  • the “preparing step” of the non-fat milk solid content solution containing the non-fat milk solid content material is obtained by dissolving the non-fat milk solid content material in water or hot water.
  • non-fat milk solids are already dissolved in water or hot water (such as skim milk powder already dissolved in water or hot water, skim concentrated milk, etc.) Can be used as a non-fat milk solid content solution in the present invention, or water or hot water and / or non-fat milk solid content raw material, etc. Further, it may be added to prepare a nonfat milk solid solution.
  • the concentration of the non-fat milk solid content and the oil / fat content (preferably milk fat content) in the non-fat milk solid solution is, for example, preferably within the range of 5 to 50% of the non-fat milk solid content in the liquid.
  • No special equipment is required for the dissolution, and it can be carried out with an ordinary agitator such as a turbine type or chi-type.
  • Examples of the fats and oils used in the method for producing reduced milk of the present invention include edible fats and oils such as animal fats and vegetable fats, and the animal fats are derived from milk of mammals (preferably cows). Milk fat, beef tallow, pork tallow, fish oil, chicken oil, etc., among which milk-derived milk fat is mentioned as a particularly preferred example, and vegetable oils include rice oil, sesame oil, coconut oil, palm oil, Corn oil, rapeseed oil, soybean oil, olive oil, sunflower oil, cottonseed oil and the like can be mentioned, and examples of fats and oils that may contain animal fats include margarine, shortening, fat spread and the like.
  • edible fats and oils such as animal fats and vegetable fats
  • the animal fats are derived from milk of mammals (preferably cows). Milk fat, beef tallow, pork tallow, fish oil, chicken oil, etc., among which milk-derived milk fat is mentioned as a particularly preferred example
  • vegetable oils include rice oil, sesame oil, coconut oil, palm
  • milk fat ingredients containing a large amount of milk fat such as butter, cream, butter oil, butter milk powder, cream powder, etc.
  • a raw material for milk fat such as cream.
  • 1 type may be sufficient as the fats and oils raw material to be used, and 2 or more types may be sufficient as it.
  • oil and fat raw materials particularly milk fat raw materials
  • creams that have already been emulsified oil-in-water emulsification
  • fat and oil raw materials such as butter, butter oil, butter milk powder and cream powder that are not emulsified are preferably mentioned, and when the fat and oil raw materials are milk fat raw materials, Of these, butter is more preferable.
  • the use ratio of the oil / fat raw material (particularly the milk / fat raw material) not emulsified (oil-in-water emulsion) is preferably 25% or more of the oil / fat in the oil / fat emulsion in the present invention. More preferably, it can be 50% or more.
  • the fat / oil raw material in the step of preparing the fat / oil emulsion containing the fat / oil raw material, the fat / oil raw material, if necessary, a substance having an emulsifying action such as a food emulsifier and / or water.
  • oil and fat ingredient to be used can already be used as an oil and fat emulsion (the oil and fat ingredient is already emulsified, for example, like a cream (Such as when oil-in-water emulsification is performed)) use the oil / fat raw material as it is as the oil / fat emulsion in the present invention, or use water or hot water and / or oil / fat raw material as the oil / fat raw material. Is added to prepare an oil and fat emulsion.
  • the concentration of oil and fat and non-fat milk solid content in the oil and fat emulsion is, for example, in the range where the total concentration of oil and fat (preferably milk fat) in the oil and fat emulsion is 3 to 50%, preferably 5
  • the concentration is within the range of ⁇ 30%, and the concentration of the non-fat milk solid content is 10% or less, preferably 5% or less, more preferably 1% or less.
  • the prepared non-fat milk solid solution and the oil / fat emulsion are respectively heat sterilized in the heat sterilization treatment step.
  • the heat sterilization method include UHT method, LTLT method, and HTST method.
  • Particularly preferable heat sterilization methods include heat sterilization by the UHT method.
  • the temperature is usually 120 to 150 ° C. for 1 second to 5 seconds (for example, 130 ° C. for 2 seconds), in the LTLT method, at 63 ° C. for 30 minutes, and in the HTST method, 72 Conditions can be used at ⁇ 75 ° C. for 15 seconds or equivalent effects. You may hold warming before heat sterilization.
  • the condition for maintaining the heating may be a condition that is usually used, and is selected according to the heat sterilization method. In the case of performing heat sterilization by the UHT method, it can be kept warm at about 70 to 85 ° C.
  • the nonfat milk solid solution and the milk fat emulsion that have been heat sterilized in the heat sterilization treatment step are each cooled and mixed.
  • the non-fat milk solid solution and the oil / fat emulsion emulsified by heat sterilization in the heat sterilization treatment step are cooled and subjected to a step of mixing both liquids.
  • the mixing ratio of the non-fat milk solid solution and the oil / fat emulsion is such that the oil / fat content (preferably milk fat content) of the reduced milk is higher than 1.5% and less than 6.0%, and the non-fat milk solid content. It is preferable to adjust so that the concentration is higher than 5.0% and lower than 14.0%.
  • the mixed non-fat milk solid solution and fat / oil emulsion are subjected to a homogenization process at a temperature equal to or higher than the freezing point of the fat.
  • the freezing point of fats and oils in the manufacturing method of reduced milk of this invention can be suitably specified according to the kind of fats and oils in the raw material of fats and oils used for this manufacturing method. Examples of the freezing point of various fats and oils are: “20 to 40 ° C.” for milk fat, “45 to 48 ° C.” for beef tallow, “28 to 48 ° C.” for pork fat, and “ ⁇ 10 to ⁇ 5” for rice oil. °C ”, sesame oil is“ ⁇ 6 to ⁇ 3 ° C.
  • the temperature of the freezing point of a certain fat or oil has a range, the temperature of the lower limit value of the freezing point temperature range may be the freezing point in the present invention, but the temperature in the center of the temperature range may be the freezing point in the present invention.
  • the upper limit temperature of the temperature range is more preferably the freezing point in the present invention.
  • the “temperature above the freezing point of the fat” in the present invention is not particularly limited as long as it is a temperature equal to or higher than the freezing point of the fat, but is 5 ° C. or more, preferably 10 ° C. from the lower limit, the center, or the upper limit temperature of the freezing point of the fat.
  • a temperature higher than 15 ° C., more preferably higher than 15 ° C., and even more preferably higher than 20 ° C., and a temperature within the range of 10 ° C. to 70 ° C. can be preferably mentioned.
  • Examples of the “temperature above the freezing point of fats and oils” include a temperature of 30 ° C. or higher, preferably 30 to 70 ° C., more preferably 50 to 70 ° C., and still more preferably 50 to 60 ° C.
  • the homogenization of the mixed nonfat milk solid solution and the oily fat emulsion can be performed using a homogenizer such as a high-pressure homogenizer.
  • the pressure at the time of homogenization is not particularly limited, and may be, for example, a pressure of 10 MPa or more and less than 50 MPa, a pressure of 15 MPa or more and 40 MPa or less, and 15 MPa or more used in a normal production process of milk or reduced milk. Although it can also be performed at a pressure of 25 MPa or less, a homogenization pressure higher than usual can be employed from the viewpoint of obtaining reduced milk that is superior in taste, flavor and emulsion stability.
  • reduced milk with improved taste, flavor and emulsion stability produced by the method for producing reduced milk of the present invention as all or part of the raw material, processed as an excellent reduced milk food material It can be used for the production of milk, milk drinks and milk-containing drinks.
  • the “processed milk, milk beverage, milk-containing beverage” is classified into health food, functional food, food for specified health use, dietary supplement, food with a disease risk reduction label, or food for the sick. Included beverages are also included.
  • “contained processed milk” using the reduced milk of the present invention cannot contain anything other than non-fat milk solids, milk fat, and water, and water. It is preferable not to include ingredients other than milk raw materials and water.
  • optional ingredients can be used as the milk raw material and raw materials other than water.
  • food materials such as coffee, tea, fruit juice, vegetable juice, natural products such as plants and extracts, purified products, concentrates, processed products, sweeteners, nutritional supplements, pH adjusters, Additives such as emulsifiers, thickeners, fragrances, foaming agents, and antifoaming agents may be mentioned.
  • the “milk beverage” and the “milk beverage” are not particularly distinguished as long as they are beverages containing the reduced milk in the present invention.
  • beverages containing the reduced milk in the present invention for example, milk tea, milk coffee, milk cocoa , Coffee milk, fruit milk, strawberry milk, sour milk drink and the like.
  • skim milk powder manufactured by Fontera
  • non-fat milk solid content material in the following examples of reduced milk and comparative examples, skim milk powder (manufactured by Fontera) was used as the non-fat milk solid content material.
  • butter that is animal fat is used (manufactured by Fontera Co., Ltd.).
  • Rice oil which is a vegetable oil, was used. The components of the aforementioned skim milk powder and butter are as shown in Table 1.
  • the tube-type heat exchange UHT sterilizer is used for the sterilization of the non-fat milk solid solution and the oil / fat emulsion in preparing the reduced milk examples and comparative examples described later, and Izumi is used for the homogenization.
  • a high-pressure homogenizer manufactured by Food Machinery was used.
  • Example 1 According to the process shown in FIG. 1, reduced milk Example 1 was prepared. Specifically, it was prepared by the following method. 688.8 g of skim milk powder was dissolved in hot water at 55 to 65 ° C. to obtain 4000 g of a non-fat milk solid content solution (16.6% non-fat milk solid content, 0.17% milk fat content). In addition, 352 g of butter that was heated to 55 to 65 ° C. and melted was added little by little to a solution of emulsifier P-1670 (manufactured by Mitsubishi Chemical Foods) having a temperature of 55 to 65 ° C.
  • emulsifier P-1670 manufactured by Mitsubishi Chemical Foods
  • Example 1 In order to evaluate the flavor and emulsion stability of Example 1 above, the following Comparative Examples 1 to 3 were prepared.
  • reduced milk comparative example 1 was prepared. Specifically, it was prepared by the following method. The non-fat milk solid solution and the oil / fat emulsion were prepared under the same conditions as in Example 1. The non-fat milk solid solution and the fat / oil emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, both liquids were separately cooled to a liquid temperature of 60 ° C., immediately homogenized at a pressure of 20 MPa, and then cooled separately to 10 ° C. Reduced milk comparative example 1 was prepared by mixing 500 g of a cooled non-fat milk solid solution and 500 g of a cooled oil / fat emulsion.
  • reduced milk comparative example 2 was prepared. Specifically, it was prepared by the following method. The non-fat milk solid solution and the oil / fat emulsion were prepared under the same conditions as in Example 1. After 2000 g of the non-fat milk solid solution and the oil / fat emulsion were mixed, the mixture was sterilized by heating at 130 ° C. for 2 seconds. Thereafter, the mixture was cooled to a liquid temperature of 60 ° C., immediately homogenized at a pressure of 20 MPa, and then cooled to 10 ° C. to prepare reduced milk comparative example 2.
  • reduced milk comparative example 3 was prepared. Specifically, it was prepared by the following method. 344.4 g of skim milk powder was added to 3200 g of hot water at 55 to 65 ° C. and stirred and dissolved. To the solution, 176 g of butter melted by heating to 55 to 65 ° C. was added little by little, then stirred at high speed for 5 minutes, and hot water was added to make up to 4000 g. This liquid containing non-fat milk solids and emulsified oils and fats (milk fats) is sterilized by heating at 130 ° C. for 2 seconds, then cooled to 60 ° C. and immediately homogenized at a pressure of 20 MPa. Turned into. After the homogenization treatment, the mixture was cooled to 10 ° C. to prepare reduced milk comparative example 3.
  • ⁇ Factor sensory evaluation method> Sensory evaluation of the flavor of the reduced milk produced in the above Examples and Comparative Examples was performed. The evaluation was carried out by 5 trained sensory panelists who have a habit of drinking commercially available reduced milk and milk. Each method for producing reduced milk was turned down to perform sensory evaluation, and evaluation was performed according to the criteria in Table 2.
  • ⁇ Emulsification stability evaluation method 10 ml of each reduced milk was applied to a sample tube having a height of 140 mm and a diameter of 10 mm, sealed, and stored in a 5 ° C. environment. The number of days from the start of storage until oil-water separation was first observed was measured and evaluated as an index of the emulsion stability of the reduced milk.
  • Table 3 shows the results of sensory evaluation and emulsion stability evaluation performed on each reduced milk of Example 1 and Comparative Examples 1 to 3.
  • Example 1 Compared with Comparative Examples 2 and 3 in which the non-fat milk solid solution and the fat emulsion were mixed and then heat-sterilized, the non-fat milk solid solution and the fat emulsion were separately heat-sterilized.
  • Example 1 and Comparative Example 1 were evaluated as having a better flavor. From these results, it was confirmed that reduced milk with better flavor can be produced by separately heat-sterilizing the non-fat milk solid solution and the fat and oil emulsion.
  • Example 2 and Comparative Example 4 were prepared in order to examine the influence of the temperature of the mixed solution in the homogenization treatment performed after mixing the non-fat milk solid solution and the fat and oil emulsion.
  • Example 2 According to the process shown in FIG. 5, reduced milk Example 2 was prepared. Specifically, it was prepared by the following method. The non-fat milk solid solution and the oil / fat emulsion were prepared under the same conditions as in Example 1. The non-fat milk solid solution and the fat / oil emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, 1000 g of both liquids cooled separately to a liquid temperature of 60 ° C. were mixed and the mixed liquid was cooled to 30 ° C., and then immediately homogenized at a pressure of 20 MPa. After the homogenization treatment, the reduced milk Example 2 was prepared by cooling to 10 ° C.
  • reduced milk comparative example 4 was prepared. Specifically, it was prepared by the following method.
  • the non-fat milk solid solution and the oil / fat emulsion were prepared under the same conditions as in Example 1.
  • the non-fat milk solid solution and the fat / oil emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, 1000 g of both liquids cooled separately to a liquid temperature of 60 ° C. were mixed, and the mixed liquid was cooled to 10 ° C., and then immediately homogenized at a pressure of 20 MPa. After the homogenization treatment, the mixture was cooled to 10 ° C. to prepare reduced milk comparative example 4.
  • the preparation method of Comparative Example 4 differs from the preparation method of Example 2 only in that the cooling temperature after mixing both solutions is not 30 ° C. but 10 ° C.
  • Example 2 and Comparative Example 4 Results of sensory evaluation and emulsion stability evaluation of Example 2 and Comparative Example 4> About each reduced milk of said Example 2 and Comparative Example 4, the sensory evaluation of flavor and evaluation of the emulsion stability were performed. Each evaluation was performed by the method described above. Table 4 shows the results of sensory evaluation and emulsion stability evaluation for Example 2 and Comparative Example 4.
  • Example 2 in which the nonfat milk solid solution after sterilization was mixed with the oil and fat emulsion and the mixture was cooled to a liquid temperature of 30 ° C. and then homogenized, had a good flavor. Also, the emulsion stability was good, and no oil-water separation was observed for 22 days from the start of storage.
  • Comparative Example 4 in which the non-fat milk solid solution after sterilization and the fat / oil emulsion were mixed and the mixture was cooled to a liquid temperature of 10 ° C. and then homogenized was very poor in emulsion stability. Oil-water separation was observed in only one day from the start of storage.
  • the difference between the preparation method of Example 2 and the preparation method of Comparative Example 4 is that the cooling temperature after mixing both solutions is 30 ° C. (Example 2) or 10 ° C. (Comparative Example 4). It is only what. It is known that the butter used as the fat and oil raw material in the fat and oil emulsion has a freezing point of around 30 ° C., and if the temperature is 30 ° C. or higher, 90% or more is in a liquid fat state. . From the experimental results using Example 2 and Comparative Example 4, the homogenization treatment performed after mixing the non-fat milk solid solution and the fat and oil emulsion was conducted from the freezing point of butter as the fat and oil raw material in the fat and oil emulsion.
  • Example 3 Reduced milk Example 3 was prepared according to the process shown in FIG. Specifically, it was prepared by the following method.
  • the non-fat milk solid solution was prepared under the same conditions as in Example 1.
  • 292 g of rice oil heated to 55 to 65 ° C. was added little by little to the emulsifier P-1670 solution having a liquid temperature of 55 to 65 ° C., then stirred at high speed for 5 minutes, and hot water was added to make 4000 g.
  • an oil / fat emulsion vegetable oil / fat emulsion
  • fat / oil content 7.3%, P-1670 2000 ppm was obtained.
  • the non-fat milk solid solution and the fat / oil emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, 1000 g of both liquids cooled to a liquid temperature of 50 ° C. were mixed as they were separately, and the mixed liquid was immediately homogenized at a pressure of 20 MPa, and then cooled to 10 ° C. to prepare reduced milk Example 3.
  • Example 4 Reduced milk Example 4 was prepared according to the process shown in FIG. Specifically, it was prepared by the following method.
  • the non-fat milk solid solution was prepared under the same conditions as in Example 1, and the vegetable oil / fat emulsion was prepared under the same conditions as in Example 3.
  • the non-fat milk solid solution and the vegetable oil / fat emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, 1000 g of both liquids cooled to a liquid temperature of 50 ° C. were mixed separately and the mixed liquid was cooled to 10 ° C., and then immediately homogenized at a pressure of 20 MPa. After the homogenization treatment, the reduced milk Example 4 was prepared by cooling to 10 ° C.
  • Reduced milk comparative example 5 was prepared according to the process shown in FIG. Specifically, it was prepared by the following method.
  • the non-fat milk solid solution was prepared under the same conditions as in Example 1, and the vegetable oil / fat emulsion was prepared under the same conditions as in Example 3.
  • the non-fat milk solid solution and the vegetable oil / fat emulsion were mixed in an amount of 2000 g, and the mixture was sterilized by heating at 130 ° C. for 2 seconds. Thereafter, the liquid mixture was cooled to a liquid temperature of 50 ° C. and immediately homogenized at a pressure of 20 MPa, and then cooled to 10 ° C. to prepare reduced milk comparative example 5.
  • Reduced milk comparative example 6 was prepared according to the process shown in FIG. Specifically, it was prepared by the following method.
  • the non-fat milk solid solution was prepared under the same conditions as in Example 1, and the vegetable oil / fat emulsion was prepared under the same conditions as in Example 3.
  • the non-fat milk solid solution and the vegetable oil / fat emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, both liquids were separately cooled to a liquid temperature of 50 ° C., immediately homogenized at a pressure of 20 MPa, and then cooled separately to 10 ° C.
  • Reduced milk comparative example 6 was prepared by mixing 500 g of the cooled non-fat milk solid solution and 500 g of the cooled vegetable oil emulsion.
  • Example 3 in which the non-fat milk solid solution and the vegetable oil / fat emulsion were separately sterilized by heating and mixed, and the mixture was homogenized had little off-flavor and good flavor. Also, the emulsion stability was good, and no oil-water separation was observed for 22 days from the start of storage.
  • Comparative Example 5 in which heat-sterilization was performed after mixing the non-fat milk solid solution and the vegetable oil / fat emulsion, had a strong off-flavor and poor flavor. Further, Comparative Example 6 mixed after homogenizing each of the non-fat milk solid solution and the vegetable oil / fat emulsion was very poor in emulsion stability, and oil-water separation was observed in only one day from the start of storage. It was.
  • Example 4 in which the non-fat milk solid solution and the vegetable oil / fat emulsion were separately sterilized by heating and mixed, and the mixture was homogenized at a temperature of 10 ° C. was also carried out. Like Example 3, the flavor was good and the emulsion stability was good. It is known that the freezing point of rice oil used as an oil / fat raw material for vegetable oil / fat emulsion is lower than the freezing point of animal fats such as butter and is -5 to -10 ° C. Even at a liquid temperature of °C, it corresponds to a liquid temperature higher than the freezing point of rice oil, and it is considered that sufficient homogenization treatment was performed.
  • the non-fat milk solid solution and the oil / fat emulsion (animal oil / fat emulsion or vegetable) It is shown that the homogenization treatment performed after mixing with the oil / fat emulsion) needs to be performed at a temperature higher than the freezing point of the animal oil / vegetable oil / vegetable oil / fat as the oil / fat raw material of the oil / fat emulsion. It was.
  • the present invention provides reduced milk having a fresh milk-like taste and flavor and good emulsification stability.
  • reduced milk using non-fat milk solid ingredients such as skim milk powder and oil and fat ingredients, reducing the off-flavors and off-flavors of the produced reduced milk, the fresh milk-like taste
  • non-fat milk solid content raw materials such as skim milk powder as a raw material
  • a method for producing reduced milk is provided.
  • the fresh milk-like taste and flavor of the present invention and reduced milk excellent in emulsification stability can be suitably used as a milk raw material for preparing processed milk, milk drinks and milk-containing drinks.

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Abstract

The problem addressed by the present invention is to provide a method for producing reconstituted milk having improved flavor and emulsion stability, and in particular to provide a reconstituted milk that has superior emulsion stability by means of ameliorating the reduced emulsion stability of reconstituted milks, and having a fresh taste/flavor like that of cow milk by reducing off-tastes and off-odors of the reconstituted milk produced in a method for producing reconstituted milk using an oil/fat content starting material and a non-fat milk solid content such as powdered skim milk. In the present invention, reconstituted milk is produced having superior emulsion stability and a taste/flavor like that of fresh cow milk by means of separately performing (1) a step for preparing a non-fat milk solid component solution containing a non-fat milk solid content starting material, heat sterilizing the non-fat milk solid content solution, and cooling the result, and (2) a step for preparing an oil/fat emulsion containing the oil/fat content starting material, and heat sterilizing and cooling the result, and then (3) mixing the non-fat milk solid component solution and the oil/fat emulsion and performing a homogenization process on the mixture of the non-fat milk solid component solution and the oil/fat emulsion at a temperature that is at least the congealing point of the oil/fat.

Description

味覚、風味及び乳化安定性の良好な還元乳、及びその製造方法Reduced milk with good taste, flavor and emulsion stability, and production method thereof
 本発明は、新鮮な牛乳様の味覚、風味を有し、乳化安定性の良好な還元乳の製造方法、特に、脱脂粉乳等の無脂乳固形分原料と、油脂分原料とを用いて還元乳を製造する方法において、製造した還元乳が有する異味、異臭を低減することにより、新鮮な牛乳様の味覚、風味を有する還元乳を製造すると共に、脱脂粉乳等の粉体の無脂乳固形分原料を原料として用いる場合に招来する還元乳の低下した乳化安定性を改善して、乳化安定性に優れた還元乳を製造する方法に関する。また、本発明は、該味覚、風味及び乳化安定性に優れた還元乳を用いた加工乳、乳飲料又は乳入り飲料、及びその製造方法に関する。 The present invention is a method for producing reduced milk having a fresh milk-like taste and flavor and good emulsification stability, and in particular, reduced using a non-fat milk solid content raw material such as skim milk powder and a fat and oil raw material. In the method for producing milk, by reducing the off-taste and off-flavor of the produced reduced milk, reduced milk having a fresh milk-like taste and flavor is produced, and non-fat milk solids such as skim milk powder are produced. The present invention relates to a method for producing reduced milk excellent in emulsification stability by improving the reduced emulsion stability of reduced milk that is caused when a raw material is used as a raw material. The present invention also relates to processed milk, milk beverage or milk-containing beverage using reduced milk having excellent taste, flavor and emulsion stability, and a method for producing the same.
 還元乳とは、一般に「乳を原料とした食品に水を加えたものであって市乳の成分と類似成分をもつものをいう」と定義され(「乳及び乳製品の成分規格等に関する省令(以下「乳等省令」という。)」)、生乳や牛乳を加工して得られる粉乳、濃縮乳、クリーム、バター等の乳原料を主要な原料として飲用乳の形態にしたものである。例としては、脂肪分を牛乳と比較して増減させた加工乳や乳飲料、カルシウムや鉄分などを添加した乳飲料などが挙げられる。これらの牛乳を模した還元乳は、例えば、脱脂粉乳や脱脂濃縮乳などの無脂乳固形分を多く含む乳原料と、バターやクリームなどの乳脂肪分を多く含む乳原料とを含む乳原料液を用いて、牛乳の製造と同様の設備を用いて、混合、殺菌、冷却、均質化等の製造工程を経て製造されている。 Reduced milk is generally defined as “a food made from milk and water added and has similar components to the components of city milk” (“Ministerial Ordinance on Component Standards for Milk and Dairy Products” (Hereinafter referred to as “Ministerial Ordinance of Milk”) ”), and milk raw materials such as powdered milk, concentrated milk, cream and butter obtained by processing raw milk and milk are used as the main raw materials in the form of drinking milk. Examples include processed milk and milk beverages whose fat content is increased or decreased compared with milk, and milk beverages added with calcium, iron, and the like. Reduced milk imitating these milks is, for example, a milk raw material containing a high amount of non-fat milk solids such as nonfat dry milk and nonfat concentrated milk, and a high milk raw material containing a large amount of milk fat such as butter and cream. Using the same equipment as the milk production, the liquid is produced through production steps such as mixing, sterilization, cooling, and homogenization.
 しかしながら、一般的に還元乳は牛乳と比較して「粉っぽい」、「舌や喉に被膜感が残る」、「生乳の風味が損なわれていてナチュラル感に欠ける」とされており(「日本味と匂学会誌」、vol.14、No.3、PP.471-474、2007年12月。)(非特許文献1)、その風味の改善が課題となっている。還元乳の原料の中でも、粉乳、クリームパウダー、ホエイパウダー等の粉体の乳原料は、長期保存が可能で、比較的安価であることから、広く使用されている。しかしながら、このような乳原料の粉末加工品は、濃縮、乾燥、殺菌等の加工処理過程で本来乳原料が持っていた乳風味が低減されるのみならず、乳風味以外の異臭が発生し、再度水溶性化しても充分な乳風味を呈さず、一般的に粉臭などと表現される異臭が生じるといった問題があった(特開平6-319448号公報:特許文献1)。特に、還元乳の製造に粉乳を用いる場合には、全脂粉乳を用いる場合と、脱脂粉乳とバターのような乳脂肪を用いる場合とがあり、例えば、脱脂粉乳を用いる場合、新鮮な牛乳のような味覚、風味の還元乳を調製することが難しいという面があるだけでなく、調製した還元乳の乳化安定性を得ることが難しいという問題がある。 However, in general, reduced milk is said to be “powder-like” compared to cow's milk, “a filmy feeling remains on the tongue and throat”, and “natural milk flavor is impaired and lacks a natural feeling” (“ Journal of Japanese Society of Taste and Smell ”, vol.14, No.3, PP.471-474, December 2007.) (Non-Patent Document 1), improvement of its flavor is an issue. Among the raw materials of reduced milk, powdered milk materials such as milk powder, cream powder, and whey powder are widely used because they can be stored for a long period of time and are relatively inexpensive. However, the powdered processed product of such a milk raw material not only reduces the milk flavor originally possessed by the milk raw material in the processing process such as concentration, drying, and sterilization, but also generates a strange odor other than the milk flavor, Even when water-solubilized again, there is a problem in that a sufficient milk flavor is not exhibited and a strange odor generally expressed as a powdery odor is generated (Japanese Patent Laid-Open No. 6-319448: Patent Document 1). In particular, when using powdered milk for the production of reduced milk, there are cases where whole milk powder is used and milk fat such as skim milk powder and butter is used. For example, when skim milk powder is used, There is a problem that it is difficult to prepare reduced milk having such a taste and flavor, and it is difficult to obtain emulsion stability of the prepared reduced milk.
 還元乳の製造に際して、その風味を向上するための技術、及び、その乳化安定性を高めるための技術として各種のものが開示されている。還元乳の風味を向上させるための技術として、例えば、特開2006-180792号公報(特許文献2)には、呈味改良剤として寒天分子をゲル化能以下の流動体として存在するように添加することで、コク味や、エグ味等の呈味を改良した加工乳及び乳飲料が開示されている。特開2002-335903号公報(特許文献3)には、乳類を含む飲食物に、味質改善剤として、セロビオース、ソホロース、ラミナリビオース、ゲンチオビオース等のβ-グルコオリゴ糖を添加することで、喉越しや、舌の上、喉、口に残る被膜感や臭さが改善された加工乳等が開示されている。 Various techniques have been disclosed as techniques for improving the flavor and techniques for improving the emulsion stability in the production of reduced milk. As a technique for improving the flavor of reduced milk, for example, Japanese Patent Application Laid-Open No. 2006-180792 (Patent Document 2) adds agar molecules as a taste improver so as to exist as a fluid having a gelling ability or less. Thus, processed milk and milk beverages with improved taste such as richness and taste are disclosed. JP 2002-335903 A (Patent Document 3) adds a β-glucooligosaccharide such as cellobiose, sophorose, laminaribiose, gentiobiose, etc. as a taste improver to foods and drinks including milk, Disclosed is a processed milk with improved feeling and odor remaining over the throat, on the tongue, on the throat and in the mouth.
 還元乳の乳化安定性を向上させるための技術としては、例えば、特開2004-267147号公報(特許文献4)には、加工乳における長期保存に対して、クリーミングを生ぜず、3ヶ月以上の長期安定な乳化状態の保持と、風味を保持した加工乳を提供するために、加工乳中に含まれる油脂成分を有機酸モノグリセリドと乳蛋白質からなる複合体により乳化した脂肪球を含有させる方法が、特開2004-267223号公報(特許文献5)には、UHT殺菌を施しても、長期間の乳化安定性を保持することができる乳飲料とするために、曇点が90℃以上であるポリグリセリン脂肪酸エステルを含有させる方法が開示されている。しかしながら、上記のような呈味改善物質の添加は、異味や増粘による清涼感の欠如が生じるという問題があり、また乳化剤を添加する方法も、乳化剤の添加による異味が問題となる。 As a technique for improving the emulsification stability of reduced milk, for example, JP-A-2004-267147 (Patent Document 4) discloses that creaming does not cause long-term storage in processed milk for 3 months or more. In order to provide a long-term stable emulsified state and processed milk having a flavor, a method of containing fat globules obtained by emulsifying a fat and oil component contained in the processed milk with a complex composed of an organic acid monoglyceride and milk protein JP-A-2004-267223 (Patent Document 5) discloses a clouding point of 90 ° C. or higher in order to obtain a milk beverage capable of maintaining long-term emulsification stability even after UHT sterilization. A method of containing a polyglycerol fatty acid ester is disclosed. However, the addition of the taste-improving substance as described above has a problem in that lack of refreshing feeling due to a taste or thickening occurs, and the method of adding an emulsifier also has a problem of a taste due to the addition of the emulsifier.
 また、加工乳等の風味や味覚の改善に、物理的処理を用いる方法が知られている。例えば、特開2002-51699号公報(特許文献6)には、遠心分離により乳脂肪分の一部を分離して生乳の乳脂肪分を調整した後、逆浸透(RO)膜で処理して、乳脂肪分及び無脂乳固形分を濃縮し、蛋白質分及びカルシウム分を高め、風味の優れた加工乳を得る方法が、特開2002-262769号公報(特許文献7)には、牛乳又は乳成分を含む飲料又は食品を、140℃で30~120秒間の加熱処理を行うことにより、光誘導によるオフフレーバーの発生のない牛乳又は乳成分を含有した飲料又は食品を製造する方法が開示されている。該加工乳の調製には液体の原料が用いられているが、生乳や牛乳、生乳膜処理物のような液体の原料は、一般的に原料としての保存安定性が悪いという問題がある上に、該文献に示されたような過酷な加熱処理を施す方法によっても、乳の自然な味覚が変性してしまうという問題がある。 Also, a method using physical treatment is known for improving the flavor and taste of processed milk. For example, Japanese Patent Laid-Open No. 2002-51699 (Patent Document 6) discloses that a part of milk fat is separated by centrifugation to adjust the milk fat content of raw milk, and then processed with a reverse osmosis (RO) membrane. JP-A-2002-262769 (Patent Document 7) discloses a method of concentrating milk fat and non-fat milk solids to increase protein content and calcium content and obtaining processed milk with excellent flavor. Disclosed is a method for producing a beverage or food containing milk or a milk component free from light-induced off-flavour by heating a beverage or food containing a milk component at 140 ° C. for 30 to 120 seconds. ing. Liquid raw materials are used for the preparation of the processed milk. However, liquid raw materials such as raw milk, milk and processed raw milk membranes generally have a problem of poor storage stability as raw materials. However, even the method of performing a severe heat treatment as shown in the document has a problem that the natural taste of milk is denatured.
 例えば、脱脂粉乳や脱脂濃縮乳などの無脂乳固形分を多く含む乳原料を用いた還元乳の製造には、該乳原料と、バターやクリームなどの乳脂肪分を多く含む乳原料とを、牛乳製造と同様の設備を用いて、乳原料の混合、殺菌、冷却、均質化処理という工程が採られている。該還元乳の製造における工程を工夫して、還元乳の味覚や風味を改善する方法が開示されている。例えば、特開2011-24508号公報(特許文献8)には、脱脂濃縮乳のような無脂乳固形分を主成分とする第1の乳原料液と、乳脂肪分を主成分とする第2の乳原料液を、それぞれ別々に加熱殺菌、均質化、冷却処理をした後、混合する方法が開示されている。この方法は、乳原料を混合した後に、加熱殺菌、冷却する従来の方法を改良して、乳原料を別々に加熱殺菌処理し、冷却した後、混合する方法とすることにより、乳原料を混合した後に加熱殺菌することにより発生する、異味、異臭を抑制して、新鮮な牛乳の風味に近い風味を付与した加工乳の製造を目的としたものである。 For example, in the production of reduced milk using a milk raw material containing a large amount of non-fat milk solids such as nonfat dry milk and defatted concentrated milk, the milk raw material and a milk raw material containing a large amount of milk fat such as butter and cream are used. Using the same equipment as milk production, the steps of mixing, sterilizing, cooling and homogenizing milk raw materials are taken. A method for improving the taste and flavor of reduced milk by devising a process in the production of the reduced milk is disclosed. For example, Japanese Patent Application Laid-Open No. 2011-24508 (Patent Document 8) discloses a first milk raw material liquid mainly composed of non-fat milk solids such as nonfat concentrated milk and a milk fat content as a main component. Two milk raw material liquids are separately heat-sterilized, homogenized, and cooled, and then mixed. This method improves the conventional method of heat sterilization and cooling after mixing milk raw materials, and mixes milk raw materials by mixing them after heat sterilization treatment of milk raw materials separately, cooling and mixing The purpose is to produce processed milk with a flavor similar to that of fresh milk by suppressing the off-flavors and off-flavors generated by heat sterilization.
 また、特表平11-505121号公報(特許文献9)には、全乳をクリームの流れと脱脂乳の流れに分離し、脱脂乳の流れを微細濾過器に通して、その微細濾過器から残留物の流れと透過液の流れを得、該透過液の流れを熱処理に付し、その後に脱脂乳の透過液の流れを高温処理されたクリーム製品の一部の流れと所望とされる量で混合する方法が開示されている。該開示の方法では、分離されたクリームの流れと脱脂乳の流れについて、それぞれ別個に加熱処理が施されている。 In Japanese Patent Publication No. 11-505121 (Patent Document 9), whole milk is separated into a flow of cream and a flow of skim milk, and the flow of skim milk is passed through a fine filter, A residue flow and a permeate flow are obtained, the permeate flow is subjected to a heat treatment, and then the skim milk permeate flow is subjected to a portion of the hot-treated cream product and the desired amount. Is disclosed. In the disclosed method, the separated cream flow and skim milk flow are separately heated.
 また、特開2011-152107号公報(特許文献10)には、ホエイ固形分、無脂乳固形分及び水を含む乳製品製造用組成物において、乳脂肪分の含有率、ホエイ固形分の含有率を調整することによって、ホエイタンパク質を含有する原料を用いた場合であっても、加熱殺菌時に凝集が生じ難く、熱安定性に優れている乳製品製造用組成物を製造する方法が開示されている。該乳製品製造用組成物の製造においては、クリーム等の乳脂肪分を別途加熱殺菌して、ホエイタンパク質の加熱凝固しない温度で混合することによって、ホエイタンパク質を強化した、乳脂肪分0.5%以上の乳製品を製造することができることが示されている。 Japanese Patent Application Laid-Open No. 2011-152107 (Patent Document 10) discloses a composition for producing dairy products containing whey solids, non-fat milk solids and water, and the content of milk fat and the content of whey solids. By adjusting the rate, there is disclosed a method for producing a composition for producing dairy products that is less likely to agglomerate during heat sterilization and has excellent thermal stability even when a raw material containing whey protein is used. ing. In the production of the composition for dairy product production, milk fat content such as cream is sterilized by heating and mixed at a temperature at which the whey protein is not heated and coagulated, thereby strengthening whey protein. It has been shown that more than% dairy products can be produced.
 上記のように、還元乳の製造において、その風味を向上するための技術、及び、その乳化安定性を高めるための技術として各種の方法が開示されており、該開示の方法には、脱脂濃縮乳などの無脂乳固形分や、ホエイ固形分を含む乳原料を用いた還元乳の製造工程において、乳原料の混合、殺菌、冷却、均質化処理という工程を工夫して、還元乳の味覚や風味を改善する方法も開示されている。しかし、該開示の方法を、脱脂粉乳等の粉体の無脂乳固形分原料を用いる場合に適用しても、乳化安定性にすぐれた還元乳を調製することが難しいという問題がある。 As described above, in the production of reduced milk, various methods are disclosed as a technique for improving the flavor and a technique for improving the emulsification stability, and the disclosed method includes defatted concentration. In the production process of reduced milk using non-fat milk solids such as milk and milk ingredients containing whey solids, the process of mixing, sterilizing, cooling, and homogenizing the milk ingredients is devised to provide a taste of reduced milk A method for improving the taste and flavor is also disclosed. However, there is a problem that it is difficult to prepare reduced milk having excellent emulsification stability even when the disclosed method is applied when using a non-fat milk solid content raw material such as skim milk powder.
特開平6-319448号公報。JP-A-6-319448. 特開2006-180792号公報。Japanese Patent Laid-Open No. 2006-180792. 特開2002-335903号公報。JP 2002-335903 A. 特開2004-267147号公報。JP 2004-267147 A. 特開2004-267223号公報。JP 2004-267223 A. 特開2002-51699号公報。JP 2002-51699 A. 特開2002-262769号公報。JP 2002-262769 A. 特開2011-24508号公報。JP 2011-24508 A. 特表平11-505121号公報。Japanese National Patent Publication No. 11-505121. 特開2011-152107号公報。JP2011-152107A.
 本発明の課題は、新鮮な牛乳様の味覚、風味を有し、乳化安定性の良好な還元乳を提供すること、特に、脱脂粉乳等の無脂乳固形分原料と、油脂分原料とを用いて還元乳を製造する方法において、製造した還元乳が有する異味、異臭を低減することにより、新鮮な牛乳様の味覚、風味を有する還元乳を製造すると共に、脱脂粉乳等の粉体の無脂乳固形分原料を原料として用いる場合に招来する還元乳の低下した乳化安定性を改善して、乳化安定性に優れた還元乳を製造する方法を提供することある。更に、本発明は、該味覚、風味及び乳化安定性に優れた還元乳を用いた加工乳、乳飲料又は乳入り飲料、及びその製造方法を提供することにある。 An object of the present invention is to provide a reduced milk having a fresh milk-like taste and flavor and good emulsification stability, in particular, a non-fat milk solid content raw material such as skim milk powder, and an oil and fat content raw material. In the method for producing reduced milk, the reduced milk produced by reducing the odor and odor of the produced reduced milk can be used to produce reduced milk having a fresh milk-like taste and flavor, and the absence of powder such as skim milk powder. An object of the present invention is to provide a method for producing reduced milk excellent in emulsification stability by improving the reduced emulsification stability of reduced milk caused when using a raw material of solid milk fat as a raw material. Furthermore, this invention is providing the processed milk, milk drink, or milk-containing drink using the reduced milk excellent in this taste, flavor, and emulsion stability, and its manufacturing method.
 本発明者らは、上記課題を解決すべく、無脂乳固形分原料及び油脂分原料を用いた還元乳の製造方法において、脱脂粉乳等の無脂乳固形分原料を用いて製造した還元乳が有する異臭、異味を低減すると共に、該還元乳の低下した乳化安定性を改善して、味覚、風味及び乳化安定性に優れた還元乳を製造する方法について鋭意検討する中で、(1)脱脂粉乳などの無脂乳固形分原料を水又は湯に溶解し、該無脂乳固形分溶解液を加熱殺菌し、冷却する工程と、(2)バター等の動物性脂肪やコメ油等の植物性油脂などの油脂分原料を乳化して油脂分乳化液を調製し、加熱殺菌処理し、冷却する工程をそれぞれ別個に行い、(3)該無脂乳固形分溶解液及び油脂分乳化液を混合した後、該無脂乳固形分溶解液と油脂分乳化液の混合液を油脂の凝固点以上の温度で均質化処理を行うことにより、無脂乳固形分溶解液及び油脂分乳化液(特に乳脂肪分乳化液)を混合状態で加熱殺菌処理した場合の還元乳の異味、異臭を低減すると共に、また、無脂乳固形分溶解液と油脂分乳化液(特に乳脂肪分乳化液)を別個に均質化処理した場合に発生する乳化安定性の悪さを顕著に改善して、新鮮な牛乳のような味覚、風味を有するとともに、乳化安定性に優れた還元乳を製造することができることを見出し、本発明を完成するに至った。 In order to solve the above-mentioned problems, the present inventors have made a reduced milk produced using a non-fat milk solid material such as skim milk powder in a method for producing reduced milk using a non-fat milk solid raw material and an oil / fat raw material. In the course of diligently studying a method for producing reduced milk with excellent taste, flavor and emulsification stability by reducing the reduced odor and taste of the reduced milk and improving the reduced emulsion stability of the reduced milk, (1) A step of dissolving a non-fat milk solid content raw material such as skim milk powder in water or hot water, sterilizing and cooling the non-fat milk solid solution, and (2) animal fat such as butter or rice oil Oil and fat raw materials such as vegetable oil and fat are emulsified to prepare an oil and fat emulsion, heat sterilized, and cooled separately. (3) The non-fat milk solid solution and the oil and fat emulsion After mixing the non-fat milk solid solution and the fat emulsion emulsion, By performing homogenization at a temperature above the point, the non-fat milk solid solution and the oil / fat emulsion (particularly the milk / fat emulsion) are heat-sterilized in the mixed state to reduce the taste and smell of the reduced milk. In addition to reducing the non-fat milk solid solution and the fat and oil emulsion (particularly the milk fat emulsion), the poor emulsion stability that occurs when homogenized separately is significantly improved. It has been found that reduced milk having a taste and flavor similar to natural milk and excellent in emulsion stability can be produced, and the present invention has been completed.
 すなわち、本発明は、無脂乳固形分原料及び油脂分原料を用いた還元乳の製造方法において、(1)無脂乳固形分原料を含む無脂乳固形分溶解液を調製する工程、及び、(2)上記(1)の工程とは別個に、油脂分原料を含む油脂分乳化液を調製する工程、及び、(3)上記(1)及び(2)の工程で調製された無脂乳固形分溶解液及び油脂分乳化液をそれぞれ加熱殺菌処理する工程、及び、(4)加熱殺菌処理した無脂乳固形分溶解液及び油脂分乳化液を冷却し、混合する工程、及び、(5)混合した無脂乳固形分溶解液及び油脂分乳化液を油脂の凝固点以上の温度で均質化処理を行う工程、とを有する、味覚、風味及び乳化安定性に優れた還元乳の製造方法からなる。 That is, the present invention provides a method for producing reduced milk using a nonfat milk solid material and an oily fat material, (1) a step of preparing a nonfat milk solid solution containing the nonfat milk solid material, and (2) Separately from the step (1), a step of preparing an oil / fat emulsion containing an oil / fat raw material, and (3) non-fat prepared in the steps (1) and (2) A step of heat sterilizing each of the milk solid solution and the fat emulsion, and (4) a step of cooling and mixing the heat-sterilized non-fat milk solid solution and the fat emulsion, and ( 5) A process for homogenizing the mixed non-fat milk solid solution and the oil / fat emulsion at a temperature equal to or higher than the freezing point of the oil / fat, and a method for producing reduced milk excellent in taste, flavor and emulsion stability. Consists of.
 還元乳の製造に粉乳を用いる場合には、全脂粉乳を用いる場合と、脱脂粉乳とバターのような乳脂肪を用いる場合などがある。例えば、脱脂粉乳や脱脂濃縮乳などの無脂乳固形分を多く含む乳原料を用いる還元乳の製造には、一般に、該乳原料と、バターやクリームなどの乳脂肪分を多く含む乳原料とを、混合した後、殺菌処理を行い、冷却、均質化処理を行うという工程が採られているが、かかる一般的な製法においては、新鮮な牛乳のような味覚、風味の還元乳を調製することが難しいという問題があるだけでなく、調製した還元乳の乳化安定性を得ることが難しいという問題がある。その理由は、粉乳、クリームパウダー、ホエイパウダー等の粉体の乳原料を用いて還元乳の製造を行う場合、乳原料を粉末加工する過程で本来乳原料が持っていた乳風味が低減されるのみならず、乳風味以外の異臭が発生し、再度水溶性化しても充分な乳風味を呈さず、一般的に粉臭などと表現される異臭が生じるといった理由がある。また、還元乳の製造において、脱脂粉乳や脱脂濃縮乳などの無脂乳固形分を多く含む乳原料と、バターやクリームなどの乳脂肪分を多く含む乳原料とを混合した状態で、加熱処理を行うと、異味、異臭を発生して、新鮮な牛乳のような味覚、風味の還元乳を製造することが難しいという理由もある。 In the case of using powdered milk for the production of reduced milk, there are a case where whole milk powder is used and a case where milk fat such as skim milk and butter is used. For example, in the production of reduced milk using a milk material containing a large amount of non-fat milk solids such as skim milk powder and skim concentrated milk, generally the milk material and a milk material containing a large amount of milk fat such as butter and cream Are mixed, then sterilized, cooled, and homogenized. In such a general production method, reduced milk with a taste and flavor like fresh milk is prepared. There is a problem that it is difficult to obtain the emulsion stability of the prepared reduced milk. The reason for this is that when producing reduced milk using powdered milk ingredients such as powdered milk, cream powder, and whey powder, the milk flavor that the milk ingredients originally had in the process of powder processing of the milk ingredients is reduced. Besides, there is a reason that an unpleasant odor other than the milk flavor is generated, and even if it is made water-soluble again, it does not exhibit a sufficient milk flavor, and an unpleasant odor generally expressed as a powdery odor is generated. In the production of reduced milk, heat treatment is performed in a state where milk raw materials containing a large amount of non-fat milk solids such as skim milk powder and defatted concentrated milk are mixed with milk raw materials containing a large amount of milk fat such as butter and cream. When it is performed, there is also a reason that it is difficult to produce reduced milk having a taste and flavor like fresh milk by generating off-flavors and off-flavors.
 そこで、特開2011-24508号公報(特許文献8)の方法では、脱脂濃縮乳のような無脂乳固形分を主成分とする第1の乳原料液と、乳脂肪分を主成分とする第2の乳原料液とを用いた還元乳の製造方法において、該乳原料を別々に加熱殺菌処理する方法を採用することにより、加熱殺菌することにより発生する、異味、異臭を抑制して、新鮮な牛乳の風味に近い風味を付与した加工乳の製造方法が採られている。しかし、該方法を、脱脂粉乳等の粉体の無脂乳固形分原料を用いる場合に適用すると、乳化安定性の良好な還元乳を調製することが難しいという問題がある。 Therefore, in the method of Japanese Patent Application Laid-Open No. 2011-24508 (Patent Document 8), a first milk raw material liquid mainly composed of non-fat milk solids such as nonfat concentrated milk and a milk fat content as a main component. In the method for producing reduced milk using the second milk raw material liquid, by adopting a method of separately heat sterilizing the milk raw material, suppressing the off-flavors and off-flavors generated by heat sterilization, A process for producing processed milk having a flavor close to that of fresh milk has been adopted. However, when this method is applied when using a non-fat milk solid content raw material such as skim milk powder, there is a problem that it is difficult to prepare reduced milk with good emulsification stability.
 上記問題点を解消するために、本発明においては、該問題を解決するために鋭意検討した結果、無脂乳固形分溶解液と、油脂分乳化液とを、それぞれ別個に、加熱殺菌処理した後に、混合するという方法を採ることにより、無脂乳固形分溶解液と、油脂分乳化液とを混合状態で加熱殺菌することにより発生する、異味、異臭を抑制して新鮮な牛乳のような味覚、風味を得る一方、均質化処理においては、加熱殺菌した無脂乳固形分溶解液と、油脂分乳化液とを混合状態で、かつ、油脂の凝固点以上の温度で均質化処理を行うことにより、良好な乳化安定性を得ることに成功した。 In order to solve the above problems, in the present invention, as a result of intensive studies to solve the problem, the non-fat milk solid solution and the fat and oil emulsion were separately heat-sterilized. Later, by adopting the method of mixing, the non-fat milk solid solution and the fat and oil emulsion are heated and sterilized in a mixed state. While obtaining taste and flavor, in the homogenization treatment, the heat-sterilized non-fat milk solid solution and the fat / oil emulsion are mixed and subjected to a homogenization treatment at a temperature equal to or higher than the freezing point of the fat / oil. Thus, it was possible to obtain good emulsion stability.
 本発明の還元乳の製造方法において、原料として用いられる無脂乳固形分原料及び油脂分原料としては、特に好ましく用いられる原料として、無脂乳固形分原料として脱脂粉乳等の粉体乳原料を挙げることができ、油脂分原料として、動物性油脂又は植物性油脂を、動物性油脂としてバター等の乳脂肪を挙げることができる。 In the method for producing reduced milk of the present invention, as a non-fat milk solid material and an oily fat raw material used as raw materials, as a raw material particularly preferably used, a powdered milk raw material such as skim milk powder is used as a non-fat milk solid raw material. Examples of the oil / fat raw material include animal fats and oils and vegetable oils, and examples of animal fats include milk fats such as butter.
 本発明の還元乳の製造方法において、均質化処理を行う温度として、油脂の凝固点以上の温度を採用することができる。かかる均質化処理温度としては、30~70℃の温度を挙げることができる。 In the method for producing reduced milk of the present invention, a temperature equal to or higher than the freezing point of fats and oils can be adopted as the temperature at which the homogenization treatment is performed. Examples of such homogenization treatment temperature include a temperature of 30 to 70 ° C.
 本発明の還元乳の製造方法においては、無脂乳固形分溶解液と、油脂分乳化液を混合して還元乳の製造が行われるが、該無脂乳固形分溶解液及び油脂分乳化液の混合比は、油脂分濃度が1.5%より高く且つ6.0%未満、且つ無脂乳固形分濃度が5.0%より高く且つ14.0%未満となるように、調整することができる。 In the method for producing reduced milk of the present invention, reduced milk is produced by mixing a non-fat milk solid solution and an oil and fat emulsion, and the non-fat milk solid solution and the fat and oil emulsion are mixed. The mixing ratio is adjusted so that the fat concentration is higher than 1.5% and lower than 6.0%, and the solid content of non-fat milk is higher than 5.0% and lower than 14.0%. Can do.
 本発明は、本発明の還元乳の製造方法によって製造された味覚、風味及び乳化安定性に優れた還元乳自体の発明を包含する。また、本発明は、本発明の還元乳の製造方法によって製造された還元乳を原料の全部又は一部として用いる加工乳、乳飲料又は乳入り飲料の製造方法の発明を包含する。更に、本発明は、本発明の還元乳の製造方法によって製造された還元乳を原料の全部又は一部として用いて調製された加工乳、乳飲料又は乳入り飲料自体の発明を包含する。 The present invention includes the invention of reduced milk itself, which is produced by the method for producing reduced milk of the present invention and has excellent taste, flavor and emulsion stability. Moreover, this invention includes invention of the manufacturing method of processed milk, milk drink, or milk-containing drink which uses the reduced milk manufactured by the manufacturing method of the reduced milk of this invention as all or one part of a raw material. Furthermore, this invention includes invention of the processed milk, milk drink, or milk-containing drink itself prepared using the reduced milk manufactured by the manufacturing method of the reduced milk of this invention as all or one part of a raw material.
 すなわち、具体的には本発明は、
[1]無脂乳固形分原料及び油脂分原料を用いた還元乳の製造方法において、
(1)無脂乳固形分原料を含む無脂乳固形分溶解液を調製する工程、
(2)(1)の工程とは別個に、油脂分原料を含む油脂分乳化液を調製する工程、
(3)(1)及び(2)の工程で調製された無脂乳固形分溶解液及び油脂分乳化液をそれぞれ加熱殺菌処理する工程、
(4)加熱殺菌処理した無脂乳固形分溶解液及び油脂分乳化液を冷却し、混合する工程、
(5)混合した無脂乳固形分溶解液及び油脂分乳化液を油脂の凝固点以上の温度で均質化処理を行う工程、とを有することを特徴とする味覚、風味及び乳化安定性に優れた還元乳の製造方法や、
[2]無脂乳固形分原料が粉体乳原料であることを特徴とする上記[1]に記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法や、
[3]油脂が動物性油脂又は植物性油脂であることを特徴とする上記[1]又は[2]に記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法や、
[4]動物性油脂が乳脂肪であることを特徴とする上記[3]に記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法や、
[5]均質化処理を行う温度が、30~70℃であることを特徴とする上記[1]~[4]のいずれかに記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法や、
[6]無脂乳固形分溶解液及び油脂分乳化液の混合比は、油脂分濃度が1.5%より高く且つ6.0%未満、且つ無脂乳固形分濃度が5.0%より高く且つ14.0%未満となるように、調整されることを特徴とする上記[1]~[5]のいずれかに記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法からなる。
Specifically, the present invention specifically relates to
[1] In a method for producing reduced milk using a non-fat milk solids raw material and an oily fat raw material,
(1) a step of preparing a non-fat milk solid solution containing a non-fat milk solid material,
(2) Separately from the step of (1), a step of preparing an oil / fat emulsion containing the oil / fat raw material,
(3) A step of heat sterilizing each of the nonfat milk solid solution and the fat emulsion prepared in the steps (1) and (2),
(4) A step of cooling and mixing the heat-sterilized non-fat milk solid solution and the fat / oil emulsion.
(5) The mixed non-fat milk solid solution and the fat / oil emulsion are subjected to a homogenization treatment at a temperature equal to or higher than the freezing point of the fat / oil, and excellent in taste, flavor and emulsion stability. How to make reduced milk,
[2] The method for producing reduced milk excellent in taste, flavor and emulsion stability according to [1] above, wherein the non-fat milk solid content raw material is a powdered milk raw material,
[3] The method for producing reduced milk excellent in taste, flavor and emulsion stability according to the above [1] or [2], wherein the fat is animal fat or vegetable fat or oil,
[4] The method for producing reduced milk excellent in taste, flavor and emulsion stability according to [3] above, wherein the animal fat is milk fat;
[5] Production of reduced milk excellent in taste, flavor and emulsion stability according to any one of [1] to [4] above, wherein the temperature at which the homogenization treatment is performed is 30 to 70 ° C. How,
[6] The mixing ratio of the non-fat milk solid solution and the fat / fat emulsion is such that the oil / fat concentration is higher than 1.5% and less than 6.0%, and the non-fat milk solids concentration is higher than 5.0%. From the method for producing reduced milk excellent in taste, flavor and emulsion stability according to any one of the above [1] to [5], characterized by being adjusted so as to be high and less than 14.0% Become.
 また、本発明は、[7]上記[1]~[6]のいずれかに記載の製造方法によって製造された味覚、風味及び乳化安定性に優れた還元乳からなる。 Moreover, the present invention comprises [7] reduced milk produced by the production method according to any one of [1] to [6] and having excellent taste, flavor and emulsion stability.
 さらに、本発明は、[8]上記[7]に記載の還元乳を原料の全部又は一部として用いることを特徴とする加工乳、乳飲料又は乳入り飲料の製造方法や、[9]上記[8]に記載の加工乳、乳飲料又は乳入り飲料の製造方法により製造された加工乳、乳飲料又は乳入り飲料からなる。 Furthermore, the present invention provides [8] a method for producing processed milk, a milk beverage or a milk-containing beverage, wherein the reduced milk according to [7] is used as all or part of the raw material, and [9] It consists of the processed milk, milk drink, or milk-containing drink manufactured by the manufacturing method of the processed milk, milk drink, or milk-containing drink as described in [8].
 本発明は、新鮮な牛乳様の味覚、風味を有し、乳化安定性の良好な還元乳を提供する。特に、脱脂粉乳等の無脂乳固形分原料と、油脂分原料とを用いて還元乳を製造する場合において、製造した還元乳が有する異味、異臭を低減することにより、新鮮な牛乳様の味覚、風味を有する還元乳を製造すると共に、脱脂粉乳等の粉体の無脂乳固形分原料を原料として用いる場合に招来する還元乳の低下した乳化安定性を改善して、乳化安定性に優れた還元乳を製造する方法を提供する。本発明の新鮮な牛乳様の味覚、風味と、乳化安定性に優れた還元乳は、加工乳、乳飲料及び乳入り飲料を調製するための乳原料として、好適に用いることができる。 The present invention provides reduced milk having a fresh milk-like taste and flavor and good emulsification stability. In particular, when producing reduced milk using non-fat milk solid ingredients such as skim milk powder and oil and fat ingredients, reducing the off-flavors and off-flavors of the produced reduced milk, the fresh milk-like taste In addition to producing reduced milk with a flavor, it improves the reduced emulsion stability of reduced milk caused when using non-fat milk solid content raw materials such as skim milk powder as a raw material, and is excellent in emulsion stability A method for producing reduced milk is provided. The fresh milk-like taste and flavor of the present invention and reduced milk excellent in emulsification stability can be suitably used as a milk raw material for preparing processed milk, milk drinks and milk-containing drinks.
図1は、本発明の実施例における還元乳実施例1の調製工程を示す図である。FIG. 1 is a diagram showing a preparation process of reduced milk Example 1 in an example of the present invention. 図2は、本発明の実施例における還元乳比較例1の調製工程を示す図である。FIG. 2 is a diagram showing the preparation process of reduced milk comparative example 1 in the examples of the present invention. 図3は、本発明の実施例における還元乳比較例2の調製工程を示す図である。FIG. 3 is a diagram showing a preparation process of reduced milk comparative example 2 in the examples of the present invention. 図4は、本発明の実施例における還元乳比較例3の調製工程を示す図である。FIG. 4 is a diagram showing a preparation process of reduced milk comparative example 3 in the example of the present invention. 図5は、本発明の実施例における還元乳実施例2の調製工程を示す図である。FIG. 5 is a diagram showing the preparation process of reduced milk example 2 in the example of the present invention. 図6は、本発明の実施例における還元乳比較例4の調製工程を示す図である。FIG. 6 is a diagram showing a preparation process of reduced milk comparative example 4 in the examples of the present invention. 図7は、本発明の実施例における還元乳実施例3の調製工程を示す図である。FIG. 7 is a diagram showing the preparation process of reduced milk Example 3 in the Example of the present invention. 図8は、本発明の実施例における還元乳実施例4の調製工程を示す図である。FIG. 8 is a diagram showing a preparation process of reduced milk example 4 in the example of the present invention. 図9は、本発明の実施例における還元乳比較例5の調製工程を示す図である。FIG. 9 is a diagram illustrating a preparation process of reduced milk comparative example 5 in the example of the present invention. 図10は、本発明の実施例における還元乳比較例6の調製工程を示す図である。FIG. 10 is a diagram illustrating a preparation process of reduced milk comparative example 6 in the example of the present invention.
 本発明は、無脂乳固形分原料及び油脂分原料を用いた還元乳の製造方法において、(1)無脂乳固形分原料を含む無脂乳固形分溶解液を調製する工程、及び、(2)上記(1)の工程とは別個に、油脂分原料を含む油脂分乳化液を調製する工程、及び、(3)上記(1)及び(2)の工程で調製された無脂乳固形分溶解液及び油脂分乳化液をそれぞれ加熱殺菌処理する工程、及び、(4)加熱殺菌処理した無脂乳固形分溶解液及び油脂分乳化液を冷却し、混合する工程、及び、(5)混合した無脂乳固形分溶解液及び油脂分乳化液を油脂の凝固点以上の温度で均質化処理を行う工程、とを有する、味覚、風味及び乳化安定性に優れた還元乳の製造方法(以下、「本発明の還元乳の製造方法」とも表示する。)からなる。該製造方法により、無脂乳固形分溶解液及び油脂分乳化液を混合状態で加熱殺菌処理した場合の還元乳の異味、異臭を低減すると共に、また、無脂乳固形分溶解液と油脂分乳化液を別個に均質化処理した場合に発生する乳化安定性の悪さを顕著に改善して、新鮮な牛乳のような味覚、風味を有するとともに、乳化安定性に優れた還元乳を製造することからなる。 The present invention provides a method for producing reduced milk using a non-fat milk solid raw material and an oily fat raw material, (1) a step of preparing a non-fat milk solid solution containing the non-fat milk solid raw material, and ( 2) Separately from the step (1), a step of preparing an oil / fat emulsion containing an oil / fat component, and (3) a non-fat milk solid prepared in the steps (1) and (2) A step of heat-sterilizing the separated solution and the fat and oil emulsion, and (4) a step of cooling and mixing the heat-sterilized nonfat milk solid solution and the fat and oil emulsion, and (5) And a step of homogenizing the mixed non-fat milk solid solution and the fat and oil emulsion at a temperature equal to or higher than the freezing point of the fat and oil, and a method for producing reduced milk excellent in taste, flavor and emulsion stability , And also expressed as “Method for producing reduced milk of the present invention”). According to the production method, the non-fat milk solid content solution and the fat and oil emulsion are reduced in taste and off-flavor in the reduced milk when heat-sterilized in a mixed state. Producing reduced milk that has significantly improved emulsification stability that occurs when the emulsion is homogenized separately, and has a taste and flavor similar to fresh milk and excellent emulsification stability. Consists of.
 「還元乳」とは、生乳や牛乳を原料として製造された乳製品を還元して製造される飲用乳、及びこれに必要に応じて乳原料以外の原料を添加した飲料と定義されている。「還元乳」は、「乳等省令」における「加工乳」のすべて、及び「乳飲料」の一部を含む概念である。ここで、「生乳」とは、搾乳したままの牛の乳のことをいい、「牛乳」とは、生乳を飲用又は加工用に殺菌を施した牛の乳のことをいう。また、還元乳の原料として用いられる「乳製品」とは、「乳等省令」において乳製品と分類されているものを含み、具体的には、脱脂粉乳、全粉乳、濃縮乳、脱脂濃縮乳、クリームパウダー、クリーム、バター、バターオイル、濃縮ホエイ、ホエイパウダー、タンパク質濃縮ホエイパウダー、バターミルクパウダー、加糖粉乳、調製粉乳などが挙げられる。本発明は、上記「還元乳」において、脱脂粉乳のような粉体の無脂乳固形分原料と、油脂分原料とを用いた還元乳及び該還元乳の製造方法を対象とし、より好適には、油脂分原料として、バターのような乳脂肪分原料を用いた還元乳及び該還元乳の製造方法を対象とする。 “Reduced milk” is defined as drinking milk produced by reducing dairy products produced using raw milk or milk as raw materials, and beverages to which raw materials other than milk raw materials are added as necessary. “Reduced milk” is a concept that includes all of “processed milk” and “milk drink” in “Departmental Decree of Milk”. Here, “raw milk” refers to milk of cows that have been milked, and “milk” refers to milk of cows that have been sterilized for drinking or processing. In addition, “dairy products” used as a raw material for reduced milk include those classified as “dairy products” in the “Ministry Ordinance of Milk, etc.”. Specifically, skim milk powder, whole milk powder, concentrated milk, skim concentrated milk , Cream powder, cream, butter, butter oil, concentrated whey, whey powder, protein concentrated whey powder, buttermilk powder, sweetened powdered milk, prepared powdered milk and the like. The present invention is directed to reduced milk using a non-fat milk solid raw material in the form of skim milk powder and an oily fat raw material and a method for producing the reduced milk in the above-mentioned “reduced milk”, and more preferably. Is intended for reduced milk using a milk fat raw material such as butter as a fat and oil raw material and a method for producing the reduced milk.
 また、本発明において「味覚、風味に優れた還元乳」とは、脱脂粉乳等の乳原料を用いて一般的な製法により製造した還元乳が有する異臭(粉臭)、異味を低減して、新鮮な牛乳のような味覚、風味に改善された還元乳を意味し、より具体的には、同種、同量の原料を用いて同量の還元乳を一般的な製法(特に、無脂乳固形分と油脂分が混合された状態で加熱殺菌処理する工程を含む製法)で製造した場合と比較して、異臭(粉臭)、異味が低減されており、新鮮な牛乳のような味覚、風味に改善された還元乳が含まれる。また、本発明において「乳化安定性が改善された還元乳」或いは「乳化安定性に優れた還元乳」とは、脱脂粉乳等の粉体の乳原料を用いて一般的な製法(特に、無脂乳固形分溶解液と油脂分乳化液の加熱殺菌処理は別々であるものの、均質化処理後に無脂乳固形分溶解液と油脂分乳化液を混合する工程を含む製法)により還元乳を製造する場合に招来する乳化安定性の低下が改善され、乳化安定性に優れた還元乳を意味し、より具体的には、同種、同量の原料を用いて同量の還元乳を一般的な製法で製造した場合と比較して、乳化安定性の低下が改善され、乳化安定性に優れた還元乳が含まれる。 Further, in the present invention, "reduced milk excellent in taste and flavor" means reducing off-flavor (powder odor), off-flavor in reduced milk produced by a general production method using a milk raw material such as skim milk powder, This means reduced milk with a taste and flavor that is similar to fresh milk. More specifically, the same amount and amount of raw material are used to produce the same amount of reduced milk. Compared to the case of manufacturing with a process that includes heat and sterilization treatment in a state where solids and fats and oils are mixed), the off-flavour (powder smell) and off-taste are reduced, and the taste like fresh milk, Contains reduced milk with improved flavor. In the present invention, “reduced milk with improved emulsification stability” or “reduced milk with excellent emulsification stability” means a general production method (especially none) using a powdered milk raw material such as skim milk powder. Although the heat sterilization treatment of the fat milk solid solution and the fat emulsion solution is separate, the reduced milk is produced by a method including a step of mixing the nonfat milk solid solution and the fat emulsion solution after homogenization. This means reduced milk with improved emulsion stability and superior emulsion stability. More specifically, the same amount of reduced milk using the same amount and the same amount of raw material is generally used. Compared with the case where it is manufactured by the production method, a reduction in emulsion stability is improved, and reduced milk excellent in emulsion stability is included.
 本発明の還元乳の製造方法においては、(1)無脂乳固形分原料を含む無脂乳固形分溶解液を調製する工程、及び、(2)上記(1)の工程とは別個に、油脂分原料を含む油脂分乳化液を調製する工程、及び、(3)上記(1)及び(2)の工程で調製された無脂乳固形分溶解液及び油脂分乳化液をそれぞれ加熱殺菌処理する工程、及び、(4)加熱殺菌処理した無脂乳固形分溶解液及び油脂分乳化液を冷却し、混合する工程、及び、(5)混合した無脂乳固形分溶解液及び油脂分乳化液を油脂の凝固点以上の温度で均質化処理を行う工程、とを有する製造工程により、還元乳の製造が行われる。本発明における還元乳の製造方法において、各工程の順序、組合せの点を除いて、各工程における処理条件等は、通常、還元乳の製造において用いられている処理条件を用いることができる。 In the method for producing reduced milk of the present invention, (1) a step of preparing a non-fat milk solid content solution containing a non-fat milk solid content raw material, and (2) separately from the step (1) above, A step of preparing an oil / fat emulsion containing an oil / fat raw material, and (3) heat-sterilization treatment of the non-fat milk solid solution and the oil / fat emulsion prepared in steps (1) and (2), respectively. And (4) a step of cooling and mixing the heat-sterilized non-fat milk solid solution and the fat and oil emulsion, and (5) a mixed non-fat milk solid solution and the fat and oil emulsification. The reduced milk is produced by a production process comprising the step of homogenizing the liquid at a temperature equal to or higher than the freezing point of the fat. In the method for producing reduced milk in the present invention, except for the order and combination of the steps, the treatment conditions used in the production of reduced milk can be used as the treatment conditions in each step.
 本発明の還元乳の製造方法に用いられる無脂乳固形分原料としては、脱脂粉乳、全粉乳、加糖粉乳、調製粉乳、脱脂濃縮乳、乳タンパク質パウダー、乳タンパク質濃縮物などが挙げられるが、本発明の効果(還元乳で問題となる異味、異臭を低減する効果や、脱脂粉乳等の粉体の無脂乳固形分原料を用いた還元乳で特に問題となる、低下した乳化安定性を改善する効果)をより多く享受する観点から、脱脂粉乳、全粉乳、加糖粉乳、調製粉乳、乳タンパク質パウダー、乳タンパク質濃縮物等の粉体の乳原料が好ましく挙げられ、中でも脱脂粉乳がより好ましく挙げられる。かかる粉体の無脂乳固形分原料の使用割合としては、本発明における無脂乳固形分溶解液における無脂乳固形分のうち、25%以上、好ましくは50%以上とすることが好ましい。なお、用いる無脂乳固形分原料は1種であってもよいし、2種以上であってもよい。 Non-fat milk solid content materials used in the method for producing reduced milk of the present invention include skim milk powder, whole powdered milk, sweetened powdered milk, prepared powdered milk, skim concentrated milk, milk protein powder, milk protein concentrate, and the like. The effect of the present invention (the effect of reducing off-flavors and off-flavors that are problematic in reduced milk, and reduced emulsification stability, which is particularly problematic in reduced milk using a non-fat milk solid content raw material such as skim milk powder) From the viewpoint of enjoying more improvement effect), powdered milk raw materials such as skim milk powder, whole milk powder, sweetened powder milk, prepared milk powder, milk protein powder, milk protein concentrate, and the like are preferable, and skim milk powder is more preferable among them. Can be mentioned. The use ratio of the non-fat milk solid content raw material of the powder is preferably 25% or more, preferably 50% or more, of the non-fat milk solid content in the non-fat milk solid solution in the present invention. In addition, 1 type may be sufficient as the nonfat milk solid content raw material to be used, and 2 or more types may be sufficient as it.
 本発明の還元乳の製造方法における、無脂乳固形分原料を含む無脂乳固形分溶解液を「調製する工程」には、無脂乳固形分原料を水または湯に溶解し、無脂乳固形分溶解液を調製することのほか、無脂乳固形分原料が水または湯に既に溶解しているもの(脱脂粉乳が水または湯に既に溶解しているものや、脱脂濃縮乳など)をそのまま本発明における無脂乳固形分溶解液として用いることや、無脂乳固形分原料が水または湯に既に溶解しているものに、水若しくは湯及び/又は無脂乳固形分原料等をさらに添加して無脂乳固形分溶解液を調製することなどが含まれる。無脂乳固形分溶解液における無脂乳固形分や油脂分(好ましくは乳脂肪分)の濃度としては、例えば、液中の無脂乳固形分の濃度が5~50%の範囲内、好ましくは8~40%の範囲内であって、かつ、油脂分(好ましくは乳脂肪分)の合計濃度が2%以下、好ましくは1%以下、より好ましくは0.5%以下である液体を挙げることができる。溶解には、特殊な機器は必要なく、通常のタービン型・カイ型等の攪拌機で行うことができる。 In the method for producing reduced milk of the present invention, the “preparing step” of the non-fat milk solid content solution containing the non-fat milk solid content material is obtained by dissolving the non-fat milk solid content material in water or hot water. In addition to preparing a milk solids solution, non-fat milk solids are already dissolved in water or hot water (such as skim milk powder already dissolved in water or hot water, skim concentrated milk, etc.) Can be used as a non-fat milk solid content solution in the present invention, or water or hot water and / or non-fat milk solid content raw material, etc. Further, it may be added to prepare a nonfat milk solid solution. The concentration of the non-fat milk solid content and the oil / fat content (preferably milk fat content) in the non-fat milk solid solution is, for example, preferably within the range of 5 to 50% of the non-fat milk solid content in the liquid. Is a liquid having a total concentration of oil and fat (preferably milk fat) of 2% or less, preferably 1% or less, more preferably 0.5% or less. be able to. No special equipment is required for the dissolution, and it can be carried out with an ordinary agitator such as a turbine type or chi-type.
 本発明の還元乳の製造方法に用いられる油脂分原料としては、動物性油脂及び植物性油脂のような食用油脂が挙げられ、該動物性油脂としては、哺乳動物(好ましくは牛)の乳由来の乳脂肪、牛脂、豚脂、魚油、鶏油等が挙げられ、中でも、牛乳由来の乳脂肪が特に好ましい例として挙げられ、植物性油脂としては、コメ油、ゴマ油、ヤシ油、パーム油、コーン油、菜種油、大豆油、オリーブ油、ヒマワリ油、綿実油等が挙げられ、また、動物性油脂を原料に含む場合がある油脂として、マーガリン、ショートニング、ファットスプレッド等が挙げられる。上記乳脂肪としては、バター、クリーム、バターオイル、バターミルクパウダー、クリームパウダーなど、乳脂肪分を多く含む乳脂肪分原料を用いることができ、特に、得られる還元乳の風味面から、バター、クリームのような乳脂肪分原料を用いることが好ましい。なお、用いる油脂分原料は1種であってもよいし、2種以上であってもよい。また、低下した乳化安定性を改善するという本発明の効果をより多く享受する観点から、既に乳化(水中油滴型乳化)がなされているクリームなどの油脂分原料(特に乳脂肪分原料)よりも、そのような乳化がなされていないバター、バターオイル、バターミルクパウダー、クリームパウダーなどの油脂分原料(特に乳脂肪分原料)が好ましく挙げられ、油脂分原料が乳脂肪分原料である場合は、これらの中でもバターがより好ましく挙げられる。このような、乳化(水中油滴型乳化)がなされていない油脂分原料(特に乳脂肪分原料)の使用割合としては、本発明における油脂分乳化液における油脂分のうち、好ましくは25%以上、より好ましくは50%以上とすることができる。 Examples of the fats and oils used in the method for producing reduced milk of the present invention include edible fats and oils such as animal fats and vegetable fats, and the animal fats are derived from milk of mammals (preferably cows). Milk fat, beef tallow, pork tallow, fish oil, chicken oil, etc., among which milk-derived milk fat is mentioned as a particularly preferred example, and vegetable oils include rice oil, sesame oil, coconut oil, palm oil, Corn oil, rapeseed oil, soybean oil, olive oil, sunflower oil, cottonseed oil and the like can be mentioned, and examples of fats and oils that may contain animal fats include margarine, shortening, fat spread and the like. As the milk fat, milk fat ingredients containing a large amount of milk fat, such as butter, cream, butter oil, butter milk powder, cream powder, etc., can be used. It is preferable to use a raw material for milk fat such as cream. In addition, 1 type may be sufficient as the fats and oils raw material to be used, and 2 or more types may be sufficient as it. In addition, from the viewpoint of more enjoying the effect of the present invention to improve the reduced emulsification stability, from oil and fat raw materials (particularly milk fat raw materials) such as creams that have already been emulsified (oil-in-water emulsification). However, fat and oil raw materials (particularly milk fat raw materials) such as butter, butter oil, butter milk powder and cream powder that are not emulsified are preferably mentioned, and when the fat and oil raw materials are milk fat raw materials, Of these, butter is more preferable. The use ratio of the oil / fat raw material (particularly the milk / fat raw material) not emulsified (oil-in-water emulsion) is preferably 25% or more of the oil / fat in the oil / fat emulsion in the present invention. More preferably, it can be 50% or more.
 本発明の還元乳の製造方法における、油脂分原料を含む油脂分乳化液を調製する工程には、油脂分原料に、必要に応じて、食品用乳化剤等の乳化作用を有する物質及び/又は水若しくは湯などを添加し、攪拌するなどして油脂分乳化液を調製することのほか、用いる油脂分原料が既に油脂分乳化液として用い得る場合(油脂分原料が、例えばクリームのように既に乳化(水中油滴型乳化)がなされている場合など)は、かかる油脂分原料をそのまま本発明における油脂分乳化液として用いること、あるいは、かかる油脂分原料に水若しくは湯及び/又は油脂分原料等をさらに添加して油脂分乳化液を調製することなどが含まれている。油脂分乳化液における油脂分や無脂乳固形分の濃度としては、例えば、油脂分乳化液中の油脂分(好ましくは乳脂肪分)の合計濃度が3~50%の範囲内、好ましくは5~30%の範囲内であって、かつ、無脂乳固形分の濃度が10%以下、好ましくは5%以下、より好ましくは1%以下である濃度を挙げることができる。 In the method for preparing the reduced milk of the present invention, in the step of preparing the fat / oil emulsion containing the fat / oil raw material, the fat / oil raw material, if necessary, a substance having an emulsifying action such as a food emulsifier and / or water. Alternatively, in addition to preparing an oil and fat emulsion by adding hot water and stirring, etc., and when the oil and fat ingredient to be used can already be used as an oil and fat emulsion (the oil and fat ingredient is already emulsified, for example, like a cream (Such as when oil-in-water emulsification is performed)) use the oil / fat raw material as it is as the oil / fat emulsion in the present invention, or use water or hot water and / or oil / fat raw material as the oil / fat raw material. Is added to prepare an oil and fat emulsion. The concentration of oil and fat and non-fat milk solid content in the oil and fat emulsion is, for example, in the range where the total concentration of oil and fat (preferably milk fat) in the oil and fat emulsion is 3 to 50%, preferably 5 The concentration is within the range of ˜30%, and the concentration of the non-fat milk solid content is 10% or less, preferably 5% or less, more preferably 1% or less.
 本発明の還元乳の製造方法においては、それぞれ調製された無脂乳固形分溶解液及び油脂分乳化液を、加熱殺菌処理工程においてそれぞれ加熱殺菌する。該加熱殺菌の方法は、UHT法、LTLT法、HTST法を挙げることができる。特に、好ましい加熱殺菌の方法として、UHT法による加熱殺菌を挙げることができる。UHT法を用いることで、製造した還元乳の賞味期限までの期間を十分に長くすることが可能となる。UHT法を用いる場合は、直接加熱法及び間接加熱法のいずれをも用いることができる。 In the method for producing reduced milk of the present invention, the prepared non-fat milk solid solution and the oil / fat emulsion are respectively heat sterilized in the heat sterilization treatment step. Examples of the heat sterilization method include UHT method, LTLT method, and HTST method. Particularly preferable heat sterilization methods include heat sterilization by the UHT method. By using the UHT method, it is possible to sufficiently lengthen the period until the expiration date of the produced reduced milk. When the UHT method is used, either a direct heating method or an indirect heating method can be used.
 それぞれの加熱殺菌方法における加熱条件としては、UHT法では、通常120~150℃で1秒間以上5秒間以内(例えば130℃2秒間)、LTLT法では、63℃で30分間、HTST法では、72~75℃で15秒間又は同等の効果が得られる条件を使用することができる。加熱殺菌の前に加温保持を行ってもよい。加温保持の条件は、通常用いられている条件であれば良く、加熱殺菌方法に応じて選択される。UHT法による加熱殺菌を行う場合には、通常70~85℃程度で加温保持することができる。 As heating conditions in each heat sterilization method, in the UHT method, the temperature is usually 120 to 150 ° C. for 1 second to 5 seconds (for example, 130 ° C. for 2 seconds), in the LTLT method, at 63 ° C. for 30 minutes, and in the HTST method, 72 Conditions can be used at ˜75 ° C. for 15 seconds or equivalent effects. You may hold warming before heat sterilization. The condition for maintaining the heating may be a condition that is usually used, and is selected according to the heat sterilization method. In the case of performing heat sterilization by the UHT method, it can be kept warm at about 70 to 85 ° C.
 本発明の還元乳の製造方法においては、それぞれ加熱殺菌処理工程において加熱殺菌を行った無脂乳固形分溶解液及び乳脂肪分乳化液を冷却し、両液を混合する工程に付す。 In the method for producing reduced milk of the present invention, the nonfat milk solid solution and the milk fat emulsion that have been heat sterilized in the heat sterilization treatment step are each cooled and mixed.
 本発明の還元乳の製造方法においては、加熱殺菌処理工程において加熱殺菌を行った無脂乳固形分溶解液及び油脂分乳化液を冷却し、両液を混合する工程に付す。無脂乳固形分溶解液及び油脂分乳化液の混合比は、還元乳の油脂分(好ましくは乳脂肪分)濃度が1.5%より高く且つ6.0%未満、且つ無脂乳固形分濃度が5.0%より高く且つ14.0%未満となるように、調整することが好ましい。 In the method for producing reduced milk of the present invention, the non-fat milk solid solution and the oil / fat emulsion emulsified by heat sterilization in the heat sterilization treatment step are cooled and subjected to a step of mixing both liquids. The mixing ratio of the non-fat milk solid solution and the oil / fat emulsion is such that the oil / fat content (preferably milk fat content) of the reduced milk is higher than 1.5% and less than 6.0%, and the non-fat milk solid content. It is preferable to adjust so that the concentration is higher than 5.0% and lower than 14.0%.
 本発明の還元乳の製造方法においては、混合した無脂乳固形分溶解液及び油脂分乳化液を、油脂の凝固点以上の温度で、均質化処理を行う工程に付す。本発明の還元乳の製造方法における油脂の凝固点は、該製造方法に用いる油脂分原料中の油脂の種類に応じて適宜特定することができる。各種の油脂の凝固点を例示すると、乳脂肪は「20~40℃」程度、牛脂は「45~48℃」程度、豚脂は「28~48℃」程度、コメ油は「-10~-5℃」程度、ゴマ油は「-6~-3℃」程度、ヤシ油は「14~25℃」程度、パーム油は「27~50℃」程度、コーン油は「10~15℃」程度、菜種油は「-12~0℃」程度、大豆油は「-8~-7℃」程度、オリーブ油は「0~6℃」程度、ヒマワリ油は「-18~-16℃」程度、綿実油は「-6~4℃」程度である。なお、ある油脂の凝固点の温度に幅がある場合、その凝固点の温度範囲の下限値の温度を本発明における凝固点としてもよいが、該温度範囲の中央の温度を本発明における凝固点とすることが好ましく、該温度範囲の上限の温度を本発明における凝固点とすることがより好ましい。本発明における「油脂の凝固点以上の温度」としては、油脂の凝固点以上の温度であれば特に制限されないが、油脂の凝固点の温度範囲の下限又は中央又は上限の温度より5℃以上、好ましくは10℃以上、より好ましくは15℃以上、さらに好ましくは20℃以上高い温度であって、かつ、10℃~70℃の範囲内の温度を好ましく挙げることができ、油脂として乳脂肪を用いる場合の好ましい「油脂の凝固点以上の温度」として例えば、30℃以上、好ましくは30~70℃、より好ましくは50~70℃、さらに好ましくは50~60℃の温度を挙げることができる。  In the method for producing reduced milk of the present invention, the mixed non-fat milk solid solution and fat / oil emulsion are subjected to a homogenization process at a temperature equal to or higher than the freezing point of the fat. The freezing point of fats and oils in the manufacturing method of reduced milk of this invention can be suitably specified according to the kind of fats and oils in the raw material of fats and oils used for this manufacturing method. Examples of the freezing point of various fats and oils are: “20 to 40 ° C.” for milk fat, “45 to 48 ° C.” for beef tallow, “28 to 48 ° C.” for pork fat, and “−10 to −5” for rice oil. ℃ ”, sesame oil is“ −6 to −3 ° C. ”, palm oil is“ 14-25 ° C. ”, palm oil is“ 27-50 ° C. ”, corn oil is“ 10-15 ° C. ”, rapeseed oil Is about -12 to 0 ° C, soy oil is about -8 to -7 ° C, olive oil is about 0 to 6 ° C, sunflower oil is about -18 to -16 ° C, and cottonseed oil is about- It is about “6-4 ° C.”. If the temperature of the freezing point of a certain fat or oil has a range, the temperature of the lower limit value of the freezing point temperature range may be the freezing point in the present invention, but the temperature in the center of the temperature range may be the freezing point in the present invention. Preferably, the upper limit temperature of the temperature range is more preferably the freezing point in the present invention. The “temperature above the freezing point of the fat” in the present invention is not particularly limited as long as it is a temperature equal to or higher than the freezing point of the fat, but is 5 ° C. or more, preferably 10 ° C. from the lower limit, the center, or the upper limit temperature of the freezing point of the fat. A temperature higher than 15 ° C., more preferably higher than 15 ° C., and even more preferably higher than 20 ° C., and a temperature within the range of 10 ° C. to 70 ° C. can be preferably mentioned. Examples of the “temperature above the freezing point of fats and oils” include a temperature of 30 ° C. or higher, preferably 30 to 70 ° C., more preferably 50 to 70 ° C., and still more preferably 50 to 60 ° C.
 混合した無脂乳固形分溶解液及び油脂分乳化液の均質化は、高圧ホモジナイザーなどの均質機を用いて行うことができる。均質化する際の圧力は、特に制限されず、例えば10MPa以上50MPa未満の圧力や、15MPa以上40MPa以下の圧力であってもよく、また、通常の牛乳や還元乳の製造工程に用いられる15MPa以上25MPa以下の圧力で行うこともできるが、味覚、風味及び乳化安定性により優れた還元乳を得る観点から、通常より高い均質化圧力を採用することもできる。 The homogenization of the mixed nonfat milk solid solution and the oily fat emulsion can be performed using a homogenizer such as a high-pressure homogenizer. The pressure at the time of homogenization is not particularly limited, and may be, for example, a pressure of 10 MPa or more and less than 50 MPa, a pressure of 15 MPa or more and 40 MPa or less, and 15 MPa or more used in a normal production process of milk or reduced milk. Although it can also be performed at a pressure of 25 MPa or less, a homogenization pressure higher than usual can be employed from the viewpoint of obtaining reduced milk that is superior in taste, flavor and emulsion stability.
 本発明においては、本発明の還元乳の製造方法により製造される味覚、風味及び乳化安定性の改善された還元乳を原料の全部又は一部として用いて、優れた還元乳食品材料として、加工乳、乳飲料、乳入り飲料の製造に用いることができる。該「加工乳、乳飲料、乳入り飲料」には、健康食品、機能性食品、特定保健用食品、栄養補助食品、疾病リスク低減表示を付した食品、又は病者用食品のような分類に包含される飲料も含まれる。 In the present invention, using reduced milk with improved taste, flavor and emulsion stability produced by the method for producing reduced milk of the present invention as all or part of the raw material, processed as an excellent reduced milk food material, It can be used for the production of milk, milk drinks and milk-containing drinks. The “processed milk, milk beverage, milk-containing beverage” is classified into health food, functional food, food for specified health use, dietary supplement, food with a disease risk reduction label, or food for the sick. Included beverages are also included.
 本発明の還元乳を使用して、「容器詰の加工乳」を製造する場合は、無脂乳固形分や乳脂肪等の乳原料と、水以外を含めることはできないため、還元乳製造原料には乳原料と水以外の成分を含めないことが好ましい。他方、本発明の還元乳を使用して、「容器詰の乳飲料、乳入り飲料」を製造する場合は、乳原料と、水以外の原料として任意成分を用いることができる。任意成分としては、例えば、コーヒー、茶、果汁、野菜汁などの食品素材、植物等の天然物やその抽出物、精製物、濃縮物、加工物、甘味料、栄養補助剤、pH調整剤、乳化剤、増粘剤、香料、起泡剤、消泡剤等の添加物が挙げられる。本発明において、「乳入り飲料」及び「乳飲料」には、本発明における還元乳を含んでいる飲料である限り、特に区別なく用いられ、例えば、乳入り紅茶、乳入りコーヒー、乳入りココア、コーヒー牛乳、フルーツ牛乳、イチゴ牛乳、酸乳飲料などを挙げることができる。 When producing “contained processed milk” using the reduced milk of the present invention, it cannot contain anything other than non-fat milk solids, milk fat, and water, and water. It is preferable not to include ingredients other than milk raw materials and water. On the other hand, when the reduced milk of the present invention is used to produce a “packaged milk beverage, milk-containing beverage”, optional ingredients can be used as the milk raw material and raw materials other than water. As optional ingredients, for example, food materials such as coffee, tea, fruit juice, vegetable juice, natural products such as plants and extracts, purified products, concentrates, processed products, sweeteners, nutritional supplements, pH adjusters, Additives such as emulsifiers, thickeners, fragrances, foaming agents, and antifoaming agents may be mentioned. In the present invention, the “milk beverage” and the “milk beverage” are not particularly distinguished as long as they are beverages containing the reduced milk in the present invention. For example, milk tea, milk coffee, milk cocoa , Coffee milk, fruit milk, strawberry milk, sour milk drink and the like.
 以下、実施例を挙げて、本発明を具体的に説明するが、本発明はこれらによってなんら限定されるものではない。 Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited thereto.
 後述の還元乳実施例及び比較例においては、無脂乳固形分原料としていずれも脱脂粉乳(フォンテラ社製)を用いた。また、油脂分原料としては、実施例1~2及び比較例1~4においては、動物性油脂であるバター(フォンテラ社製)を用い、実施例3~4及び比較例5~6においては、植物性油脂であるコメ油を用いた。前述の脱脂粉乳及びバターの成分は、表1に示すとおりである。 In the following examples of reduced milk and comparative examples, skim milk powder (manufactured by Fontera) was used as the non-fat milk solid content material. In addition, as the fat and oil raw material, in Examples 1 and 2 and Comparative Examples 1 to 4, butter that is animal fat is used (manufactured by Fontera Co., Ltd.). In Examples 3 to 4 and Comparative Examples 5 to 6, Rice oil, which is a vegetable oil, was used. The components of the aforementioned skim milk powder and butter are as shown in Table 1.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 後述の還元乳実施例及び比較例を調製する際の、無脂乳固形分溶解液や油脂分乳化液の殺菌処理には、チューブ式熱交換方式のUHT殺菌装置を、均質化処理にはイズミフードマシナリ社製の高圧ホモジナイザーを用いた。 The tube-type heat exchange UHT sterilizer is used for the sterilization of the non-fat milk solid solution and the oil / fat emulsion in preparing the reduced milk examples and comparative examples described later, and Izumi is used for the homogenization. A high-pressure homogenizer manufactured by Food Machinery was used.
 [実施例1]
 図1に示す工程に従い、還元乳実施例1を調製した。具体的には以下のような方法で調製した。脱脂粉乳688.8gを55~65℃の湯に溶解させて、無脂乳固形分溶解液4000g(無脂乳固形分16.6%、乳脂肪分0.17%)を得た。また、55~65℃の液温の乳化剤P-1670(三菱化学フーズ社製)溶解液に、55~65℃に加温して融解させたバター352gを少しずつ添加した後、5分間高速で攪拌し、湯を添加して4000gにメスアップすることで、油脂分乳化液(動物性油脂分乳化液)(乳脂肪分7.3%、無脂乳固形分0.14%、P-1670 2000ppm)を得た。無脂乳固形分溶解液と油脂分乳化液は、それぞれ別々に、130℃で2秒間加熱殺菌した。その後、別々のまま液温60℃まで冷却した両液を1000gずつ混合し、混合液をすみやかに20MPaの圧力で均質化した後、10℃まで冷却して還元乳実施例1(乳脂肪分3.74%、無脂乳固形分8.37%)を調製した。
[Example 1]
According to the process shown in FIG. 1, reduced milk Example 1 was prepared. Specifically, it was prepared by the following method. 688.8 g of skim milk powder was dissolved in hot water at 55 to 65 ° C. to obtain 4000 g of a non-fat milk solid content solution (16.6% non-fat milk solid content, 0.17% milk fat content). In addition, 352 g of butter that was heated to 55 to 65 ° C. and melted was added little by little to a solution of emulsifier P-1670 (manufactured by Mitsubishi Chemical Foods) having a temperature of 55 to 65 ° C. Stirring, adding hot water to make up to 4000 g, oil emulsion (animal oil emulsion) (milk fat content 7.3%, non-fat milk solid content 0.14%, P-1670 2000 ppm). The non-fat milk solid solution and the fat / oil emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, 1000 g of both liquids cooled to a liquid temperature of 60 ° C. were mixed separately, and the mixed liquid was immediately homogenized at a pressure of 20 MPa, then cooled to 10 ° C. and reduced milk Example 1 (milk fat content 3 0.74%, non-fat milk solids 8.37%).
 上記の実施例1の風味及び乳化安定性を評価するために、以下の比較例1~3を調製した。 In order to evaluate the flavor and emulsion stability of Example 1 above, the following Comparative Examples 1 to 3 were prepared.
 [比較例1]
 図2に示す工程に従い、還元乳比較例1を調製した。具体的には以下のような方法で調製した。無脂乳固形分溶解液及び油脂分乳化液は実施例1と同じ条件で調製した。無脂乳固形分溶解液と油脂分乳化液は、それぞれ別々に、130℃で2秒間加熱殺菌した。その後、両液をそれぞれ別々に液温60℃まで冷却し、すみやかに20MPaの圧力でそれぞれを均質化した後、別々のまま10℃まで冷却した。冷却した無脂乳固形分溶解液500gと、冷却した油脂分乳化液500gを混合して還元乳比較例1を調製した。
[Comparative Example 1]
According to the process shown in FIG. 2, reduced milk comparative example 1 was prepared. Specifically, it was prepared by the following method. The non-fat milk solid solution and the oil / fat emulsion were prepared under the same conditions as in Example 1. The non-fat milk solid solution and the fat / oil emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, both liquids were separately cooled to a liquid temperature of 60 ° C., immediately homogenized at a pressure of 20 MPa, and then cooled separately to 10 ° C. Reduced milk comparative example 1 was prepared by mixing 500 g of a cooled non-fat milk solid solution and 500 g of a cooled oil / fat emulsion.
 [比較例2]
 図3に示す工程に従い、還元乳比較例2を調製した。具体的には以下のような方法で調製した。無脂乳固形分溶解液及び油脂分乳化液は実施例1と同じ条件で調製した。無脂乳固形分溶解液と油脂分乳化液を2000gずつ混合した後、混合液を130℃で2秒間加熱殺菌した。その後、混合液を液温60℃まで冷却し、すみやかに20MPaの圧力で均質化した後、10℃まで冷却して還元乳比較例2を調製した。
[Comparative Example 2]
According to the process shown in FIG. 3, reduced milk comparative example 2 was prepared. Specifically, it was prepared by the following method. The non-fat milk solid solution and the oil / fat emulsion were prepared under the same conditions as in Example 1. After 2000 g of the non-fat milk solid solution and the oil / fat emulsion were mixed, the mixture was sterilized by heating at 130 ° C. for 2 seconds. Thereafter, the mixture was cooled to a liquid temperature of 60 ° C., immediately homogenized at a pressure of 20 MPa, and then cooled to 10 ° C. to prepare reduced milk comparative example 2.
 [比較例3]
 図4に示す工程に従い、還元乳比較例3を調製した。具体的には以下のような方法で調製した。脱脂粉乳344.4gを55~65℃の湯3200gに添加して攪拌・溶解した。その溶液に55~65℃に加温して融解させたバター176gを少しずつ添加した後、5分間高速攪拌し、湯を添加して4000gにメスアップした。無脂乳固形分と乳化された油脂分(乳脂肪分)とが含まれているこの液体を130℃で2秒間加熱殺菌した後、液温60℃まで冷却し、すみやかに20MPaの圧力で均質化した。均質化処理後、10℃まで冷却して還元乳比較例3を調製した。
[Comparative Example 3]
According to the process shown in FIG. 4, reduced milk comparative example 3 was prepared. Specifically, it was prepared by the following method. 344.4 g of skim milk powder was added to 3200 g of hot water at 55 to 65 ° C. and stirred and dissolved. To the solution, 176 g of butter melted by heating to 55 to 65 ° C. was added little by little, then stirred at high speed for 5 minutes, and hot water was added to make up to 4000 g. This liquid containing non-fat milk solids and emulsified oils and fats (milk fats) is sterilized by heating at 130 ° C. for 2 seconds, then cooled to 60 ° C. and immediately homogenized at a pressure of 20 MPa. Turned into. After the homogenization treatment, the mixture was cooled to 10 ° C. to prepare reduced milk comparative example 3.
 <風味の官能評価方法>
 上記の実施例及び比較例で製造した還元乳の風味の官能評価を行った。評価は、市販の還元乳及び牛乳の飲用習慣のある、訓練された官能パネラー5名により実施した。それぞれの還元乳の製造方法は伏せて官能評価を実施し、表2の基準に従って評価を行った。
<Factor sensory evaluation method>
Sensory evaluation of the flavor of the reduced milk produced in the above Examples and Comparative Examples was performed. The evaluation was carried out by 5 trained sensory panelists who have a habit of drinking commercially available reduced milk and milk. Each method for producing reduced milk was turned down to perform sensory evaluation, and evaluation was performed according to the criteria in Table 2.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 また、上記の実施例1及び比較例1~3の各還元乳の乳化安定性について、以下の方法により評価を行った。 Further, the emulsion stability of each of the reduced milks of Example 1 and Comparative Examples 1 to 3 was evaluated by the following method.
 <乳化安定性評価方法>
 各還元乳10mlを、高さ140mmで直径10mmのサンプル管にアプライして密封し、5℃の環境下で静置保存した。保存開始から、油水分離が初めて観察されるまでの日数を測定し、還元乳の乳化安定性の指標として評価した。
<Emulsification stability evaluation method>
10 ml of each reduced milk was applied to a sample tube having a height of 140 mm and a diameter of 10 mm, sealed, and stored in a 5 ° C. environment. The number of days from the start of storage until oil-water separation was first observed was measured and evaluated as an index of the emulsion stability of the reduced milk.
 <実施例1及び比較例1~3の官能評価及び乳化安定性評価の結果>
 実施例1及び比較例1~3の各還元乳について行った官能評価の結果と乳化安定性評価の結果を表3に示す。
<Results of sensory evaluation and emulsion stability evaluation of Example 1 and Comparative Examples 1 to 3>
Table 3 shows the results of sensory evaluation and emulsion stability evaluation performed on each reduced milk of Example 1 and Comparative Examples 1 to 3.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 無脂乳固形分溶解液と油脂分乳化液を混合した後で加熱殺菌を行った比較例2及び3と比較して、無脂乳固形分溶解液と油脂分乳化液を別々に加熱殺菌した実施例1及び比較例1のほうが、より良好な風味を有していると評価された。これらの結果から、無脂乳固形分溶解液と、油脂分乳化液を、別々に加熱殺菌する事で、風味のより良好な還元乳を製造できる事が確認された。 Compared with Comparative Examples 2 and 3 in which the non-fat milk solid solution and the fat emulsion were mixed and then heat-sterilized, the non-fat milk solid solution and the fat emulsion were separately heat-sterilized. Example 1 and Comparative Example 1 were evaluated as having a better flavor. From these results, it was confirmed that reduced milk with better flavor can be produced by separately heat-sterilizing the non-fat milk solid solution and the fat and oil emulsion.
 また、無脂乳固形分溶解液と油脂分乳化液を、それぞれ均質化した後で両液を混合した比較例1の乳化安定性は悪く、保存開始からわずか2日で油水分離が観察された。一方、無脂乳固形分溶解液と油脂分乳化液を混合した後で均質化処理を行った、実施例1の乳化安定性は良好で、保存開始から22日間油水分離が観察されなかった。油滴を微細にする均質化処理工程は、還元乳の乳化安定性を向上させるのに必須の工程であるが、無脂乳固形分溶解液と油脂分乳化液を、それぞれ均質化した後で混合するのではなく、混合させた後で均質化する事で、還元乳の乳化安定性を顕著に向上させることが可能である事が、これらの結果により示された。 Moreover, the emulsification stability of Comparative Example 1 in which the non-fat milk solid solution and the oil / fat emulsion were homogenized and then mixed together was poor, and oil-water separation was observed in only 2 days from the start of storage. . On the other hand, the non-fat milk solid content solution and the fat / oil emulsion were mixed and then homogenized, and the emulsion stability of Example 1 was good, and no oil / water separation was observed for 22 days from the start of storage. The homogenization process to make the oil droplets fine is an essential process for improving the emulsion stability of the reduced milk, but after homogenizing the non-fat milk solid solution and the oil / fat emulsion, respectively. These results indicate that the emulsification stability of the reduced milk can be remarkably improved by homogenization after mixing rather than mixing.
 次に無脂乳固形分溶解液と油脂分乳化液を混合させた後に行う均質化処理における、混合液の温度による影響を検討するため、実施例2及び比較例4を調製した。 Next, Example 2 and Comparative Example 4 were prepared in order to examine the influence of the temperature of the mixed solution in the homogenization treatment performed after mixing the non-fat milk solid solution and the fat and oil emulsion.
 [実施例2]
 図5に示す工程に従い、還元乳実施例2を調製した。具体的には以下のような方法で調製した。無脂乳固形分溶解液及び油脂分乳化液は実施例1と同じ条件で調製した。無脂乳固形分溶解液と油脂分乳化液は、それぞれ別々に、130℃で2秒間加熱殺菌した。その後、別々のまま液温60℃まで冷却した両液を1000gずつ混合し、混合液を30℃まで冷却した後、すみやかに20MPaの圧力で均質化した。均質化処理後、10℃まで冷却して還元乳実施例2を調製した。
[Example 2]
According to the process shown in FIG. 5, reduced milk Example 2 was prepared. Specifically, it was prepared by the following method. The non-fat milk solid solution and the oil / fat emulsion were prepared under the same conditions as in Example 1. The non-fat milk solid solution and the fat / oil emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, 1000 g of both liquids cooled separately to a liquid temperature of 60 ° C. were mixed and the mixed liquid was cooled to 30 ° C., and then immediately homogenized at a pressure of 20 MPa. After the homogenization treatment, the reduced milk Example 2 was prepared by cooling to 10 ° C.
 [比較例4]
 図6に示す工程に従い、還元乳比較例4を調製した。具体的には以下のような方法で調製した。無脂乳固形分溶解液及び油脂分乳化液は実施例1と同じ条件で調製した。無脂乳固形分溶解液と油脂分乳化液は、それぞれ別々に、130℃で2秒間加熱殺菌した。その後、別々のまま液温60℃まで冷却した両液を1000gずつ混合し、混合液を10℃まで冷却した後、すみやかに20MPaの圧力で均質化した。均質化処理後、10℃まで冷却して還元乳比較例4を調製した。なお、比較例4の調製法は、両液を混合した後の冷却温度が30℃ではなく、10℃である点のみが、実施例2の調製法と異なっている。
[Comparative Example 4]
According to the process shown in FIG. 6, reduced milk comparative example 4 was prepared. Specifically, it was prepared by the following method. The non-fat milk solid solution and the oil / fat emulsion were prepared under the same conditions as in Example 1. The non-fat milk solid solution and the fat / oil emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, 1000 g of both liquids cooled separately to a liquid temperature of 60 ° C. were mixed, and the mixed liquid was cooled to 10 ° C., and then immediately homogenized at a pressure of 20 MPa. After the homogenization treatment, the mixture was cooled to 10 ° C. to prepare reduced milk comparative example 4. The preparation method of Comparative Example 4 differs from the preparation method of Example 2 only in that the cooling temperature after mixing both solutions is not 30 ° C. but 10 ° C.
 <実施例2及び比較例4の官能評価及び乳化安定性評価の結果>
 上記の実施例2及び比較例4の各還元乳について、風味の官能評価及び乳化安定性の評価を行った。各評価は、前述の方法で行った。実施例2及び比較例4についての官能評価の結果と乳化安定性評価の結果を表4に示す。
<Results of sensory evaluation and emulsion stability evaluation of Example 2 and Comparative Example 4>
About each reduced milk of said Example 2 and Comparative Example 4, the sensory evaluation of flavor and evaluation of the emulsion stability were performed. Each evaluation was performed by the method described above. Table 4 shows the results of sensory evaluation and emulsion stability evaluation for Example 2 and Comparative Example 4.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
 殺菌後の無脂乳固形分溶解液と油脂分乳化液を混合し、混合液を液温30℃まで冷却した後で均質化処理した実施例2は、良好な風味を有していた。また、乳化安定性も良好で、保存開始から22日間油水分離が観察されなかった。一方、殺菌後の無脂乳固形分溶解液と油脂分乳化液を混合し、混合液を液温10℃まで冷却した後で均質化処理した比較例4は、乳化安定性が非常に悪く、保存開始からわずか1日で油水分離が観察された。前述したように、実施例2の調製法と比較例4の調製法の相違は、両液を混合した後の冷却温度が30℃(実施例2)であるか、10℃(比較例4)であるかのみである。油脂分乳化液における油脂分原料として使用しているバターは、凝固点が30℃前後とされており、30℃以上の温度であれば90%以上が液体脂の状態となる事が知られている。実施例2及び比較例4を用いた実験結果から、無脂乳固形分溶解液と油脂分乳化液を混合した後に行う均質化処理を、油脂分乳化液における油脂分原料であるバターの凝固点よりも低い液温で行うと十分な均質化処理を行うことができず、かかる均質化処理は、油脂分乳化液における油脂分原料であるバターの凝固点以上の液温で行う事が必要であることが示された。 Example 2 in which the nonfat milk solid solution after sterilization was mixed with the oil and fat emulsion and the mixture was cooled to a liquid temperature of 30 ° C. and then homogenized, had a good flavor. Also, the emulsion stability was good, and no oil-water separation was observed for 22 days from the start of storage. On the other hand, Comparative Example 4 in which the non-fat milk solid solution after sterilization and the fat / oil emulsion were mixed and the mixture was cooled to a liquid temperature of 10 ° C. and then homogenized was very poor in emulsion stability. Oil-water separation was observed in only one day from the start of storage. As described above, the difference between the preparation method of Example 2 and the preparation method of Comparative Example 4 is that the cooling temperature after mixing both solutions is 30 ° C. (Example 2) or 10 ° C. (Comparative Example 4). It is only what. It is known that the butter used as the fat and oil raw material in the fat and oil emulsion has a freezing point of around 30 ° C., and if the temperature is 30 ° C. or higher, 90% or more is in a liquid fat state. . From the experimental results using Example 2 and Comparative Example 4, the homogenization treatment performed after mixing the non-fat milk solid solution and the fat and oil emulsion was conducted from the freezing point of butter as the fat and oil raw material in the fat and oil emulsion. However, if it is performed at a low liquid temperature, sufficient homogenization cannot be performed, and such homogenization must be performed at a liquid temperature equal to or higher than the freezing point of butter which is a raw material for fats and oils in an oil and fat emulsion. It has been shown.
 次に、バターを油脂分原料とする油脂分乳化液(動物性油脂分乳化液)の代わりに、植物油脂を油脂分原料とした植物性油脂分乳化液を用いて、実施例3~4及び比較例5~6を調製した。 Next, instead of the fat and oil emulsion using butter as the fat and oil raw material (animal fat and oil emulsion), using the vegetable fat and oil emulsion using the vegetable fat and oil as the fat and oil raw material, Examples 3 to 4 and Comparative Examples 5-6 were prepared.
 [実施例3]
 図7に示す工程に従い、還元乳実施例3を調製した。具体的には以下のような方法で調製した。無脂乳固形分溶解液は実施例1と同じ条件で調製した。また、55~65℃の液温の乳化剤P-1670溶解液に、55~65℃に加温したコメ油292gを少しずつ添加した後、5分間高速で攪拌し、湯を添加して4000gにメスアップすることで、油脂分乳化液(植物性油脂分乳化液)(油脂分7.3%、P-1670 2000ppm)を得た。無脂乳固形分溶解液と油脂分乳化液は、それぞれ別々に、130℃で2秒間加熱殺菌した。その後、別々のまま液温50℃まで冷却した両液を1000gずつ混合し、混合液をすみやかに20MPaの圧力で均質化した後、10℃まで冷却して還元乳実施例3を調製した。
[Example 3]
Reduced milk Example 3 was prepared according to the process shown in FIG. Specifically, it was prepared by the following method. The non-fat milk solid solution was prepared under the same conditions as in Example 1. In addition, 292 g of rice oil heated to 55 to 65 ° C. was added little by little to the emulsifier P-1670 solution having a liquid temperature of 55 to 65 ° C., then stirred at high speed for 5 minutes, and hot water was added to make 4000 g. By increasing the volume, an oil / fat emulsion (vegetable oil / fat emulsion) (fat / oil content 7.3%, P-1670 2000 ppm) was obtained. The non-fat milk solid solution and the fat / oil emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, 1000 g of both liquids cooled to a liquid temperature of 50 ° C. were mixed as they were separately, and the mixed liquid was immediately homogenized at a pressure of 20 MPa, and then cooled to 10 ° C. to prepare reduced milk Example 3.
 [実施例4]
 図8に示す工程に従い、還元乳実施例4を調製した。具体的には以下のような方法で調製した。無脂乳固形分溶解液は実施例1と同じ条件で調製し、植物性油脂分乳化液は実施例3と同じ条件で調製した。無脂乳固形分溶解液と植物性油脂分乳化液は、それぞれ別々に、130℃で2秒間加熱殺菌した。その後、別々のまま液温50℃まで冷却した両液を1000gずつ混合し、混合液を10℃まで冷却した後、すみやかに20MPaの圧力で均質化した。均質化処理後、10℃まで冷却して還元乳実施例4を調製した。
[Example 4]
Reduced milk Example 4 was prepared according to the process shown in FIG. Specifically, it was prepared by the following method. The non-fat milk solid solution was prepared under the same conditions as in Example 1, and the vegetable oil / fat emulsion was prepared under the same conditions as in Example 3. The non-fat milk solid solution and the vegetable oil / fat emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, 1000 g of both liquids cooled to a liquid temperature of 50 ° C. were mixed separately and the mixed liquid was cooled to 10 ° C., and then immediately homogenized at a pressure of 20 MPa. After the homogenization treatment, the reduced milk Example 4 was prepared by cooling to 10 ° C.
 [比較例5]
 図9に示す工程に従い、還元乳比較例5を調製した。具体的には以下のような方法で調製した。無脂乳固形分溶解液は実施例1と同じ条件で調製し、植物性油脂分乳化液は実施例3と同じ条件で調製した。無脂乳固形分溶解液と植物性油脂分乳化液を2000gずつ混合した後、混合液を130℃で2秒間加熱殺菌した。その後、混合液を液温50℃まで冷却し、すみやかに20MPaの圧力で均質化した後、10℃まで冷却して還元乳比較例5を調製した。
[Comparative Example 5]
Reduced milk comparative example 5 was prepared according to the process shown in FIG. Specifically, it was prepared by the following method. The non-fat milk solid solution was prepared under the same conditions as in Example 1, and the vegetable oil / fat emulsion was prepared under the same conditions as in Example 3. The non-fat milk solid solution and the vegetable oil / fat emulsion were mixed in an amount of 2000 g, and the mixture was sterilized by heating at 130 ° C. for 2 seconds. Thereafter, the liquid mixture was cooled to a liquid temperature of 50 ° C. and immediately homogenized at a pressure of 20 MPa, and then cooled to 10 ° C. to prepare reduced milk comparative example 5.
 [比較例6]
 図10に示す工程に従い、還元乳比較例6を調製した。具体的には以下のような方法で調製した。無脂乳固形分溶解液は実施例1と同じ条件で調製し、植物性油脂分乳化液は実施例3と同じ条件で調製した。無脂乳固形分溶解液と植物性油脂分乳化液は、それぞれ別々に、130℃で2秒間加熱殺菌した。その後、両液をそれぞれ別々に液温50℃まで冷却し、すみやかに20MPaの圧力でそれぞれを均質化した後、別々のまま10℃まで冷却した。冷却した無脂乳固形分溶解液500gと、冷却した植物性油脂分乳化液500gを混合して還元乳比較例6を調製した。
[Comparative Example 6]
Reduced milk comparative example 6 was prepared according to the process shown in FIG. Specifically, it was prepared by the following method. The non-fat milk solid solution was prepared under the same conditions as in Example 1, and the vegetable oil / fat emulsion was prepared under the same conditions as in Example 3. The non-fat milk solid solution and the vegetable oil / fat emulsion were sterilized by heating at 130 ° C. for 2 seconds, respectively. Thereafter, both liquids were separately cooled to a liquid temperature of 50 ° C., immediately homogenized at a pressure of 20 MPa, and then cooled separately to 10 ° C. Reduced milk comparative example 6 was prepared by mixing 500 g of the cooled non-fat milk solid solution and 500 g of the cooled vegetable oil emulsion.
 上記の実施例3~4及び比較例5~6の各還元乳について、風味の官能評価及び乳化安定性の評価を行った。各評価は、前述の方法で行った。実施例3~4及び比較例5~6についての官能評価の結果と乳化安定性評価の結果を表5に示す。 For each of the reduced milks of Examples 3 to 4 and Comparative Examples 5 to 6, the taste sensory evaluation and the emulsion stability were evaluated. Each evaluation was performed by the method described above. Table 5 shows the results of sensory evaluation and emulsion stability evaluation for Examples 3 to 4 and Comparative Examples 5 to 6.
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
 無脂乳固形分溶解液と植物性油脂分乳化液を別々に加熱殺菌した後で混合し、混合液の均質化処理を行った実施例3は異臭が少なく、良好な風味であった。また、乳化安定性も良好で、保存開始から22日間油水分離が観察されなかった。一方、無脂乳固形分溶解液と植物性油脂分乳化液を混合した後で加熱殺菌を行った比較例5は、異臭が強く風味が悪かった。また、無脂乳固形分溶解液と植物性油脂分乳化液をそれぞれ均質化処理した後で混合した比較例6は、極めて乳化安定性が悪く、保存開始からわずか1日で油水分離が観察された。これらの結果から、バターの代わりに植物性油脂を用いて還元乳を調製する場合においても、無脂乳固形分溶解液と植物性油脂分乳化液を別々に殺菌し、殺菌後の両液を混合した後で均質化処理を行う製法を用いる事で、風味と乳化安定性が良好な還元乳が製造可能である事が示された。 Example 3 in which the non-fat milk solid solution and the vegetable oil / fat emulsion were separately sterilized by heating and mixed, and the mixture was homogenized had little off-flavor and good flavor. Also, the emulsion stability was good, and no oil-water separation was observed for 22 days from the start of storage. On the other hand, Comparative Example 5 in which heat-sterilization was performed after mixing the non-fat milk solid solution and the vegetable oil / fat emulsion, had a strong off-flavor and poor flavor. Further, Comparative Example 6 mixed after homogenizing each of the non-fat milk solid solution and the vegetable oil / fat emulsion was very poor in emulsion stability, and oil-water separation was observed in only one day from the start of storage. It was. From these results, even when preparing reduced milk using vegetable oils and fats instead of butter, sterilize the non-fat milk solids solution and the vegetable oil and fat emulsions separately, It was shown that reduced milk with good flavor and emulsion stability can be produced by using a method of homogenization after mixing.
 また、無脂乳固形分溶解液と植物性油脂分乳化液を別々に加熱殺菌した後で混合し、混合液の液温が10℃の状態で均質化処理を行った実施例4も、実施例3と同様に良好な風味であり、乳化安定性も良好であった。植物性油脂分乳化液の油脂分原料として使用しているコメ油の凝固点は、バター等の動物性脂肪の凝固点よりも低く、-5~-10℃である事が知られているところ、10℃という液温でも、コメ油の凝固点よりも高い液温に相当し、十分な均質化処理が行われたと考えられる。 In addition, Example 4 in which the non-fat milk solid solution and the vegetable oil / fat emulsion were separately sterilized by heating and mixed, and the mixture was homogenized at a temperature of 10 ° C. was also carried out. Like Example 3, the flavor was good and the emulsion stability was good. It is known that the freezing point of rice oil used as an oil / fat raw material for vegetable oil / fat emulsion is lower than the freezing point of animal fats such as butter and is -5 to -10 ° C. Even at a liquid temperature of ℃, it corresponds to a liquid temperature higher than the freezing point of rice oil, and it is considered that sufficient homogenization treatment was performed.
 実施例3及び4の実験結果を、前述の実施例2及び比較例4の実験結果と併せ考慮すると、無脂乳固形分溶解液と、油脂分乳化液(動物性油脂分乳化液又は植物性油脂分乳化液)とを混合した後に行う均質化処理は、油脂分乳化液の油脂分原料である動物性油脂や植物性油脂の凝固点以上の液温で行う事が必要であることが示された。 When the experimental results of Examples 3 and 4 are considered together with the experimental results of Example 2 and Comparative Example 4 described above, the non-fat milk solid solution and the oil / fat emulsion (animal oil / fat emulsion or vegetable) It is shown that the homogenization treatment performed after mixing with the oil / fat emulsion) needs to be performed at a temperature higher than the freezing point of the animal oil / vegetable oil / vegetable oil / fat as the oil / fat raw material of the oil / fat emulsion. It was.
 本発明は、新鮮な牛乳様の味覚、風味を有し、乳化安定性の良好な還元乳を提供する。特に、脱脂粉乳等の無脂乳固形分原料と、油脂分原料とを用いて還元乳を製造する場合において、製造した還元乳が有する異味、異臭を低減することにより、新鮮な牛乳様の味覚、風味を有する還元乳を製造すると共に、脱脂粉乳等の粉体の無脂乳固形分原料を原料として用いる場合に招来する還元乳の低下した乳化安定性を改善して、乳化安定性に優れた還元乳を製造する方法を提供する。本発明の新鮮な牛乳様の味覚、風味と、乳化安定性に優れた還元乳は、加工乳、乳飲料及び乳入り飲料を調製するための乳原料として、好適に用いることができる。 The present invention provides reduced milk having a fresh milk-like taste and flavor and good emulsification stability. In particular, when producing reduced milk using non-fat milk solid ingredients such as skim milk powder and oil and fat ingredients, reducing the off-flavors and off-flavors of the produced reduced milk, the fresh milk-like taste In addition to producing reduced milk with a flavor, it improves the reduced emulsion stability of reduced milk caused when using non-fat milk solid content raw materials such as skim milk powder as a raw material, and is excellent in emulsion stability A method for producing reduced milk is provided. The fresh milk-like taste and flavor of the present invention and reduced milk excellent in emulsification stability can be suitably used as a milk raw material for preparing processed milk, milk drinks and milk-containing drinks.

Claims (9)

  1.  無脂乳固形分原料及び油脂分原料を用いた還元乳の製造方法において、
    (1)無脂乳固形分原料を含む無脂乳固形分溶解液を調製する工程、
    (2)(1)の工程とは別個に、油脂分原料を含む油脂分乳化液を調製する工程、
    (3)(1)及び(2)の工程で調製された無脂乳固形分溶解液及び油脂分乳化液をそれぞれ加熱殺菌処理する工程、
    (4)加熱殺菌処理した無脂乳固形分溶解液及び油脂分乳化液を冷却し、混合する工程、
    (5)混合した無脂乳固形分溶解液及び油脂分乳化液を油脂の凝固点以上の温度で均質化処理を行う工程、とを有することを特徴とする味覚、風味及び乳化安定性に優れた還元乳の製造方法。
    In the method for producing reduced milk using the non-fat milk solid raw material and the fat and oil raw material,
    (1) a step of preparing a non-fat milk solid solution containing a non-fat milk solid material,
    (2) Separately from the step of (1), a step of preparing an oil / fat emulsion containing the oil / fat raw material,
    (3) A step of heat sterilizing each of the nonfat milk solid solution and the fat emulsion prepared in the steps (1) and (2),
    (4) A step of cooling and mixing the heat-sterilized non-fat milk solid solution and the fat / oil emulsion.
    (5) The mixed non-fat milk solid solution and the fat / oil emulsion are subjected to a homogenization treatment at a temperature equal to or higher than the freezing point of the fat / oil, and excellent in taste, flavor and emulsion stability. A method for producing reduced milk.
  2.  無脂乳固形分原料が粉体乳原料であることを特徴とする請求項1に記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法。 The method for producing reduced milk with excellent taste, flavor and emulsion stability according to claim 1, wherein the non-fat milk solid content raw material is a powdered milk raw material.
  3.  油脂が動物性油脂又は植物性油脂であることを特徴とする請求項1又は2に記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法。 The method for producing reduced milk excellent in taste, flavor and emulsion stability according to claim 1 or 2, wherein the fat is animal fat or vegetable fat.
  4.  動物性油脂が乳脂肪であることを特徴とする請求項3に記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法。 The method for producing reduced milk with excellent taste, flavor and emulsion stability according to claim 3, wherein the animal fat is milk fat.
  5.  均質化処理を行う温度が、30~70℃であることを特徴とする請求項1~4のいずれかに記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法。 The method for producing reduced milk excellent in taste, flavor and emulsion stability according to any one of claims 1 to 4, wherein the temperature at which homogenization is performed is 30 to 70 ° C.
  6.  無脂乳固形分溶解液及び油脂分乳化液の混合比は、油脂分濃度が1.5%より高く且つ6.0%未満、且つ無脂乳固形分濃度が5.0%より高く且つ14.0%未満となるように、調整されることを特徴とする請求項1~5のいずれかに記載の味覚、風味及び乳化安定性に優れた還元乳の製造方法。 The mixing ratio of the non-fat milk solid solution and the oil / fat emulsion is such that the oil / fat concentration is higher than 1.5% and lower than 6.0%, and the non-fat milk solid content concentration is higher than 5.0% and 14 The method for producing reduced milk excellent in taste, flavor and emulsion stability according to any one of claims 1 to 5, wherein the content is adjusted to be less than 0.0%.
  7.  請求項1~6のいずれかに記載の製造方法によって製造された味覚、風味及び乳化安定性に優れた還元乳。 Reduced milk excellent in taste, flavor and emulsion stability produced by the production method according to any one of claims 1 to 6.
  8.  請求項7に記載の還元乳を原料の全部又は一部として用いることを特徴とする加工乳、乳飲料又は乳入り飲料の製造方法。 A method for producing processed milk, a milk beverage or a milk-containing beverage, wherein the reduced milk according to claim 7 is used as all or part of a raw material.
  9.  請求項8に記載の加工乳、乳飲料又は乳入り飲料の製造方法により製造された加工乳、乳飲料又は乳入り飲料。 Processed milk, milk beverage or milk-containing beverage produced by the method for producing processed milk, milk beverage or milk-containing beverage according to claim 8.
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