WO2015072888A1 - Structure de mur réfractaire entièrement en verre - Google Patents

Structure de mur réfractaire entièrement en verre Download PDF

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Publication number
WO2015072888A1
WO2015072888A1 PCT/RU2014/000599 RU2014000599W WO2015072888A1 WO 2015072888 A1 WO2015072888 A1 WO 2015072888A1 RU 2014000599 W RU2014000599 W RU 2014000599W WO 2015072888 A1 WO2015072888 A1 WO 2015072888A1
Authority
WO
WIPO (PCT)
Prior art keywords
fire
glass
resistant
wall structure
panels
Prior art date
Application number
PCT/RU2014/000599
Other languages
English (en)
Russian (ru)
Inventor
Анатолий Евгеньевич ГАЛАШИН
Юрий Леонидович КУЗНЕЦОВ
Ольга Григорьевна КАСИМОВА
Галина Валентиновна НОВОСЕЛОВА
Original Assignee
Анатолий Евгеньевич ГАЛАШИН
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Анатолий Евгеньевич ГАЛАШИН filed Critical Анатолий Евгеньевич ГАЛАШИН
Publication of WO2015072888A1 publication Critical patent/WO2015072888A1/fr

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/54Slab-like translucent elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/069Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of intumescent material
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/02Wings made completely of glass
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/54Fixing of glass panes or like plates
    • E06B3/5436Fixing of glass panes or like plates involving holes or indentations in the pane
    • E06B3/5445Support arms engaging the holes or indentations
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B5/00Doors, windows, or like closures for special purposes; Border constructions therefor
    • E06B5/10Doors, windows, or like closures for special purposes; Border constructions therefor for protection against air-raid or other war-like action; for other protective purposes
    • E06B5/16Fireproof doors or similar closures; Adaptations of fixed constructions therefor
    • E06B5/161Profile members therefor
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B5/00Doors, windows, or like closures for special purposes; Border constructions therefor
    • E06B5/10Doors, windows, or like closures for special purposes; Border constructions therefor for protection against air-raid or other war-like action; for other protective purposes
    • E06B5/16Fireproof doors or similar closures; Adaptations of fixed constructions therefor
    • E06B5/164Sealing arrangements between the door or window and its frame, e.g. intumescent seals specially adapted therefor
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B5/00Doors, windows, or like closures for special purposes; Border constructions therefor
    • E06B5/10Doors, windows, or like closures for special purposes; Border constructions therefor for protection against air-raid or other war-like action; for other protective purposes
    • E06B5/16Fireproof doors or similar closures; Adaptations of fixed constructions therefor
    • E06B5/165Fireproof windows

Definitions

  • the present invention relates to the field of building materials and products, namely to fire-resistant fire-resistant translucent wall structures designed to prevent the spread of smoke and fire in the event of a fire outside the insulated compartment.
  • the main distinguishing feature of this design is that it can be made all-glass, only of glass panels without additional frames and profiles.
  • fire barriers are used in all buildings under construction and reconstructed for various purposes to provide fire protection.
  • Known fire design (EP, N ° l 194673, IPC: E06B5 / 16, publ. 10/29/2003), consisting of at least two transparent fire-resistant glass plates, which are laterally connected to each other through an elastic separation element, equipped with a sealing layer.
  • the plates are multilayer and consist of glasses with fire layers located between them. These fire layers do not reach the edges of the glass and are equipped with perimeter gaskets.
  • the fire wall is well-known (RU, .257449, IPC: ⁇ 04 ⁇ 1 / 94, published July 27, 2005), designed to prevent the spread of fire outside the compartment insulated by it, which is a modular design and made of separate sections consisting of profiles, connected around the perimeter in the frame, and which simultaneously separate two spaced apart glass. Glass reaches the outer edge of the profiles. The frame is hidden by an enamel coating applied to the respective sections of the glass. These individual sections are made with the possibility of their connection with each other by connecting elements with a gasket of fire laminates
  • This design is quite difficult to manufacture, it is not all-glass, since the sections contain profiles in addition to glasses, and there is a frame along the perimeter of the structure, which, although hidden by an enamel coating, significantly degrades the aesthetic perception of this design.
  • Known fire-resistant glass partition (US, N ° 5380569, IPC: E06VZ / 24, publ. 10/01/1995), formed of laminated fire-resistant glass and having attachments. The edges of the glass are inserted into the profile of elastic material and between the profile and the edge of the glass is a material that foams under the influence of high temperature.
  • This fire-resistant glass partition is quite simple to install, but it is not all-glass, because it contains profiles for attaching laminated fire-prevention glass, which does not meet the current requirements of architectonics.
  • Fire-prevention glazing is known (EP, ⁇ ° 1820931, IPC: ⁇ 06 ⁇ 5 / 16, published on 08/22/2007), which contains at least two transparent double-glazed windows, which are laterally aligned with one another and the other lateral edges fixed on a building element.
  • Each double-glazed window consists of two parallel glasses fixed at a mutual distance, between which there is a fire protection agent in the form of a gel. The glasses are held at a mutual distance by means of distance elements and a polyurethane joint.
  • a fire-retardant silicone mass In a two-millimeter seam between the edges of the double-glazed windows.
  • a fire-retardant ceramic tape In the same edge zone between the spacer elements.
  • a fire wall was selected to prevent the spread of fire outside the compartment insulated by it (RU, 2257449, IPC: ⁇ 04 ⁇ 1 / 94, published July 27, 2005), which contains a modular design and is made of separate sections consisting of profiles connected around the perimeter in the frame, and which simultaneously separate two spaced apart glass. Glass reaches the outer edge of the profiles. The frame is hidden by an enamel coating applied to the respective sections of the glass. These individual sections are made with the possibility of their connection with each other by connecting elements with a gasket of fire laminates.
  • This fire-resistant glass partition is quite simple to install, but it is not all-glass, because it contains profiles for fastening laminated fire-resistant glass, which does not meet the modern requirements of architectonics.
  • the basis of the claimed invention is the task of creating a fireproof translucent wall structure without framing frames, that is, an all-glass structure that would have modern architectonics while ensuring high strength and fire protective properties.
  • each of the fire-resistant glass panels contains at least one fastener made with the possibility of connecting fire-resistant glass panels to each other, fixing them in a wall opening, as well as with the possibility of installing various fittings on them, and at least one mounting element made with the possibility of installing a fastening element therein, wherein each fire-resistant glass panel has a layered structure comprising layers of glass and layers of a fire composition located between layers of fire-prevention glass.
  • at least one mounting element was made in the form of a through hole in the fire-resistant glass panel, and was equipped with a sleeve installed in this hole.
  • At least one mounting element was made in the form of a connecting element glued to the fire-resistant glass panel.
  • the fire-resistant all-glass wall structure contains an independent supporting metal or glass structure for fixing the wall structure in the wall opening, while the fire-resistant glass panels are fixed in an independent supporting metal structure using fasteners installed in the mounting elements.
  • a profile element is installed that covers the end of the fire-resistant glass panel.
  • the profile element was made T-shaped, U-shaped or H-shaped.
  • the profile element was made of a material selected from the group consisting of metal, thermosetting plastic or rubber, wood, or other thermosetting material.
  • each of the fire-resistant glass panels contains at least one of the ends of the layer in the form of a self-adhesive tape of various composite materials. It is advisable that in a fire-resistant all-glass wall structure, at least one of the ends of each of the fire-resistant glass panels has at least one recess filled with sealant.
  • each of the fire-resistant glass panels as a sealant contain a curable material selected from the group consisting of silicone, polyurethane, polysulfide.
  • each of the fire-resistant glass panels contains a layer in the form of a tape placed in a recess on the sealant.
  • the layer in the form of a tape was made of thermosetting material.
  • each of the fire-resistant glass panels contains as layers of glass layers selected from the group consisting of layers of sheet non-tempered glass, tempered glass, silicate glass, borosilicate glass, ceramic glass, organic glass, as well as various combinations of these layers .
  • each of the fire-resistant glass panels as layers of the fire-resistant composition contains a foaming and / or coking composition.
  • each of the fire-resistant glass panels contains at least one layer of adhesive reinforcing composition located between the layers of glass.
  • At least one of the fire-resistant glass panels is made in the form of a glass door, fastened with hinges to the adjacent previous fire-resistant glass panel, while the hinges were installed in the mounting elements of this fire-resistant previous glass panels.
  • the glass door be installed in a door frame made of a metal, wooden or other profile.
  • the glass door has a handle fixed to the door using mounting elements.
  • the glass door has a lock secured with mounting elements.
  • the glass door has thermal locks that fix the door leaf in case of fire, fixed with fasteners in the mounting elements.
  • the glass door had thermal locks that fix the door leaf in case of fire, fixed in the cutouts of fire-resistant glass panels.
  • the glass door had thermal locks that fix the door leaf in case of fire, fixed in the cutouts of fire-resistant glass panels.
  • the glass door had a closer fixed with fasteners in the cutouts of the fire-resistant glass panels. It is desirable that in the fire-resistant all-glass wall construction the glass door had a closer fixed with fasteners in the mounting elements.
  • this design has high fire protective properties.
  • Figure 1 shows a General view of a fire-resistant all-glass wall structure with a glass door, according to the invention.
  • FIG. 2 shows a cross-section through a fire-resistant glass panel with a sealant layer and a tape of thermoset material according to the invention.
  • FIG. 3 shows a cross-section through a fire-resistant glass panel with a sealant layer and a profile element according to the invention.
  • FIG. 4 shows a section AA of the fastening option for fire-resistant glass panels in a metal structure according to the invention.
  • FIG. 5 shows a section B-B of an embodiment for mounting a lock on a fire-resistant glass panel according to the invention.
  • FIG. 6 shows a section G-D of a variant of joining fire-resistant glass panels to each other according to the invention.
  • FIG. 7 shows a view B of a lock fastening in a cutout of a fire-resistant glass panel according to the invention.
  • FIG. 8 shows a section DD of fastening fire-resistant glass panels to each other using mounting elements in the form of through holes and fasteners in the form of spiders, according to the invention.
  • FIG. 9 shows a section DD of fastening fire-resistant glass panels to each other by means of glued mounting elements and fasteners in the form of spiders according to the invention.
  • Fire-resistant all-glass wall structure in the form of a partition 1, according to the claimed invention, consists of fire-resistant glass panels 2 ( Figure 1).
  • the fire-resistant glass panels 2 are fastened together and also fixed in the wall opening with the help of mounting elements 3, into which fasteners 4 are installed for connecting the fire-resistant glass panels 2 to each other and fixing them in the wall opening, as well as for installing them on different fittings.
  • the fire-resistant all-glass wall structure according to the claimed invention, the mounting elements 3 are made in the form of through holes 5 in the fire-resistant glass panels 2, and are equipped with bushings 6 installed in these through holes 5 (Figs. 1, 4-5).
  • various designs of spiders 7 are used, which are installed in the mounting elements 3 in the form of through holes 5. Using spiders 7 they fasten fire-resistant glass panels 2 together, and also fasten the fire-resistant all-glass wall structure in view of the partition 1 in the wall opening (Fig. 8-9).
  • the mounting elements 3, according to the claimed invention can be made in the form of a connecting element 3 glued to the fire-resistant glass panel 2, into which the fastening element 4 is installed (Fig. 9).
  • the fire-resistant all-glass wall structure in the form of a partition 1, according to the claimed invention, can also have an independent supporting metal or glass structure 8, made of profiles or frames, for fixing the wall structure in a wall opening, while the fire-resistant glass panels 2 are fixed in an independent supporting metal or glass structure 8 using fasteners 4 installed in the mounting elements 3.
  • each of the fire-resistant glass panels 2 is a layered structure in which layers of the fire-resistant composition 10 and layers of the adhesive reinforcing composition 11 are placed between the layers of glass 9 (FIGS. 2, 3).
  • a profile element 12 is installed that covers the ends of the layers of glass 9 with layers of the fire-resistant composition 10 and layers of adhesive reinforcing composition 1 1.
  • the profile element 12 can be made T-shaped, U-shaped, or H - shaped from thermosetting plastic or rubber, wood, or other thermosetting material.
  • the ends of the fire-resistant glass panels 2 can also be closed using self-adhesive tape 13 of various composite materials.
  • sealant 15 for example, of silicone, polyurethane, polysulfide.
  • sealant 15 may be located tape 13 of thermosetting material.
  • sealant 15 a self-hardening substance can be used, in particular silicone, polyurethane, polysulfide (Figs. 2-3).
  • the layers of glass 9 can be used layers of sheet tempered glass, tempered glass, silicate glass, borosilicate glass, glass ceramics, organic glass, or various combinations of these layers.
  • an expandable and / or coking composition may be used as layers of the fire fighting composition 10.
  • the fire-resistant all-glass wall structure according to the claimed invention may have a glass door 16 made of one fire-resistant glass panel 2 (single-leaf door), or of two fire-resistant glass panels 2 (double-leaf door).
  • the glass door 16 is fixed by means of hinges 17 to the adjacent pre-existing fire-resistant glass panel 2, while the hinges 17 are installed in the mounting elements 3 of this fire-resistant glass panel 2 ( Figure 1).
  • Glass door 16 can be installed in a door frame made of metal, wood or other profile.
  • the glass door 16 may have a handle 18 fixed to this door with mounting elements 3, in which fasteners 4 are installed, and a lock 19, fixed, for example, with mounting elements 3 in the cutouts 20 of fire-resistant glass panels 2 (Fig. 7 )
  • the glass door 16 may also have thermal locks securing the door leaf in case of fire, secured, for example, with fasteners 4 in the mounting elements 3 in the cutouts 20 of the fire-resistant glass panels 2.
  • the glass door 16 may also have a closer 21 fixed both with fasteners 4 in the cutouts 20 of the fire-resistant glass panels 2 and with fasteners 4 in the mounting elements 3.
  • the foaming and / or coking fire composition 10 in the fire-resistant glass panels 2 provides impermeability to heat and flame.
  • the presence in the fireproof glass panels 2 of the adhesive reinforcing composition 1 1 provides increased strength of these panels.
  • Thermoset material expands under the action of high temperatures and provides reliable isolation of the room from smoke and fire during fire.
  • Fire-resistant glass panels 2 can be made, according to the claimed invention, in various ways.
  • the following methods can be used to make fire-resistant glass panels 2.
  • a laminated glass panel 2 is formed, choosing the layers of glass 9 required for fire resistance, the layers of the fire-resistant composition 10, and the layers of the adhesive reinforcing composition 1 1.
  • fire-resistant glass 9 of a larger length and / or width is selected and glued with a photocurable adhesive hardening composition 1 1 to the formed fire-resistant glass panels 2 from their outer sides, while receiving fire-resistant glass panels 2 with a recess 14 formed at its ends (edges).
  • the recess 14 can be partially filled with sealant 15, and partially with tape 13 or profile element 12, which is configured to completely close the ends (edges).
  • Fire-resistant glass panels 2 are formed from the layers of glass 9 required for fire resistance, the layers of the fire-resistant composition 10 and the adhesive hardening composition 1 1. After that, at least one end of the fire-resistant glass panels 2 is treated with a special tool, such as a grinding disk, to obtain a radial recesses 14. Then, the resulting recess 14 can be partially filled with sealant 15, and partially with tape 13 or profile element 12, which is configured to completely close the ends (edges).
  • the proposed fire-resistant all-glass wall construction fully meets its purpose, is durable, transparent, all-glass, reliably seals the room from smoke and fire in case of fire.

Landscapes

  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Architecture (AREA)
  • Building Environments (AREA)
  • Securing Of Glass Panes Or The Like (AREA)
  • Special Wing (AREA)

Abstract

L'invention concerne une structure de mur réfractaire entièrement en verre se présentant sous forme d'une cloison (1) fixée à une embrasure de mure, laquelle comprend des panneaux en verre réfractaires (2) fixés les uns aux autres. Chacun des panneaux en verre réfractaires (2) comprend au moins un élément de fixation (4) permettant de connecter les panneaux en verre réfractaires (2) les uns aux autres, de les fixer dans l'embrasure du mur et d'installer sur ces derniers divers accessoires, et comprend également au moins un élément de montage (3) dans lequel peut être disposé un élément de fixation (4). Chaque panneau de verre réfractaire possède une structure stratifiée comprenant des couches de verre (9) et des couches d'une composition anti-incendie (10) disposées entre les couches de verre (9).
PCT/RU2014/000599 2013-11-15 2014-08-11 Structure de mur réfractaire entièrement en verre WO2015072888A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2013150761/12A RU2013150761A (ru) 2013-11-15 2013-11-15 Огнестойкая цельностеклянная стеновая конструкция
RU2013150761 2013-11-15

Publications (1)

Publication Number Publication Date
WO2015072888A1 true WO2015072888A1 (fr) 2015-05-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2014/000599 WO2015072888A1 (fr) 2013-11-15 2014-08-11 Structure de mur réfractaire entièrement en verre

Country Status (2)

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RU (1) RU2013150761A (fr)
WO (1) WO2015072888A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160017596A1 (en) * 2013-03-11 2016-01-21 3M Innovative Properties Company Method of forming adhesive connections
CN107859212A (zh) * 2017-11-30 2018-03-30 湖南省金为新材料科技有限公司 一种防火玻璃墙
NL2025823B1 (en) * 2020-06-12 2022-02-16 Qbiq B V A glass wall construction

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RU2202687C1 (ru) * 2001-09-13 2003-04-20 Общество с ограниченной ответственностью "Биоинъектор-Арт" Светопрозрачная входная группа и светопрозрачная поворотная дверь
RU2238386C2 (ru) * 2000-02-29 2004-10-20 Фишерверке Артур Фишер ГмбХ унд Ко.КГ Фиксатор для закрепления пластинчатого материала на основании
RU42255U1 (ru) * 2004-07-15 2004-11-27 Низаметдинов Рафик Николаевич Дверной доводчик
WO2004104346A1 (fr) * 2003-05-22 2004-12-02 Vida International Ab Moyen interne de retenue pour panneaux de verre
RU2257449C2 (ru) * 1999-07-21 2005-07-27 Дорма Гмбх + Ко. Кг Противопожарная стена
RU71367U1 (ru) * 2007-10-11 2008-03-10 Общество с ограниченной ответственностью "ГЛАССКОНЦЕПТ" Противопожарное остекление
RU2338859C1 (ru) * 2004-07-05 2008-11-20 Дорма Гмбх+Ко. Кг Стеклянная дверная створка, поворачиваемая вокруг верхней и нижней поворотных цапф
RU83792U1 (ru) * 2009-02-09 2009-06-20 Общество с ограниченной ответственностью "Компания ФОТОТЕХ" Светопрозрачное противопожарное дверное или оконное полотно
RU2419709C2 (ru) * 2005-12-23 2011-05-27 Сэн-Гобэн Гласс Франс Стеклянная стенка
RU2455441C1 (ru) * 2011-02-17 2012-07-10 Дмитрий Александрович Исаев Универсальный кодовый замок со съемным механизмом кодирования

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2257449C2 (ru) * 1999-07-21 2005-07-27 Дорма Гмбх + Ко. Кг Противопожарная стена
RU2238386C2 (ru) * 2000-02-29 2004-10-20 Фишерверке Артур Фишер ГмбХ унд Ко.КГ Фиксатор для закрепления пластинчатого материала на основании
RU2202687C1 (ru) * 2001-09-13 2003-04-20 Общество с ограниченной ответственностью "Биоинъектор-Арт" Светопрозрачная входная группа и светопрозрачная поворотная дверь
WO2004104346A1 (fr) * 2003-05-22 2004-12-02 Vida International Ab Moyen interne de retenue pour panneaux de verre
RU2338859C1 (ru) * 2004-07-05 2008-11-20 Дорма Гмбх+Ко. Кг Стеклянная дверная створка, поворачиваемая вокруг верхней и нижней поворотных цапф
RU42255U1 (ru) * 2004-07-15 2004-11-27 Низаметдинов Рафик Николаевич Дверной доводчик
RU2419709C2 (ru) * 2005-12-23 2011-05-27 Сэн-Гобэн Гласс Франс Стеклянная стенка
RU71367U1 (ru) * 2007-10-11 2008-03-10 Общество с ограниченной ответственностью "ГЛАССКОНЦЕПТ" Противопожарное остекление
RU83792U1 (ru) * 2009-02-09 2009-06-20 Общество с ограниченной ответственностью "Компания ФОТОТЕХ" Светопрозрачное противопожарное дверное или оконное полотно
RU2455441C1 (ru) * 2011-02-17 2012-07-10 Дмитрий Александрович Исаев Универсальный кодовый замок со съемным механизмом кодирования

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160017596A1 (en) * 2013-03-11 2016-01-21 3M Innovative Properties Company Method of forming adhesive connections
CN107859212A (zh) * 2017-11-30 2018-03-30 湖南省金为新材料科技有限公司 一种防火玻璃墙
CN107859212B (zh) * 2017-11-30 2023-12-29 湖南省金为新材料科技有限公司 一种防火玻璃墙
NL2025823B1 (en) * 2020-06-12 2022-02-16 Qbiq B V A glass wall construction

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