WO2015068443A1 - Method for producing weld joint - Google Patents
Method for producing weld joint Download PDFInfo
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- WO2015068443A1 WO2015068443A1 PCT/JP2014/070878 JP2014070878W WO2015068443A1 WO 2015068443 A1 WO2015068443 A1 WO 2015068443A1 JP 2014070878 W JP2014070878 W JP 2014070878W WO 2015068443 A1 WO2015068443 A1 WO 2015068443A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
- B23K35/0222—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in soldering, brazing
- B23K35/0244—Powders, particles or spheres; Preforms made therefrom
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
- B23K35/0255—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
- B23K35/0255—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
- B23K35/0261—Rods, electrodes, wires
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- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
- B23K35/0255—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
- B23K35/0261—Rods, electrodes, wires
- B23K35/0266—Rods, electrodes, wires flux-cored
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/306—Fe as the principal constituent with C as next major constituent, e.g. cast iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/3066—Fe as the principal constituent with Ni as next major constituent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/3073—Fe as the principal constituent with Mn as next major constituent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/308—Fe as the principal constituent with Cr as next major constituent
- B23K35/3086—Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/3093—Fe as the principal constituent with other elements as next major constituents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
- B23K35/3602—Carbonates, basic oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
- B23K35/3603—Halide salts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
- B23K35/3603—Halide salts
- B23K35/3605—Fluorides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/368—Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials
Definitions
- the present invention has a weld metal that has high hardness, excellent wear resistance, and is resistant to low-temperature cracking when welding high-hardness steel plates with excellent wear resistance used in the construction machinery and industrial machinery fields.
- the present invention relates to a method for manufacturing a welded joint.
- the hardness of the steel sheet varies depending on the environment and purpose of use, but in general, it is HB400 grade (Brinell hardness standard value HB360 to HB440, Vickers hardness standard value HV380 to HV469), HB450 grade (Brinell hardness) Standard values of HB410 to HB490, Vickers hardness standard value of HV435 to HV533), HB500 class (Brinell hardness standard value of HB450 to HB550, Vickers hardness standard value of HV478 to HV585) or HB600 class ( Abrasion-resistant steel sheets having a standard value of Brinell hardness of HB550 to HB650 and a standard value of Vickers hardness of HV585 to HV693) are often used.
- the weld metal may require wear resistance close to that of the base material (wear-resistant steel).
- the base material wear-resistant steel
- the hardness of the weld metal is increased, low temperature cracks caused by hydrogen that enters during welding are very likely to occur.
- the wear-resistant steel having high hardness is used as the base material, the strengthening of the restraining force is also a cause of low temperature cracking.
- the hardness of the weld metal is preferably about the same as that of the base material.
- the hardness of the weld metal is at least HV337 (HB320) or higher, preferably HV380 (HB360) or higher.
- the weld metal part what is important from the viewpoint of wear resistance is the hardness near the surface.
- the weld metal in the lower layer is reheated by subsequent passes, so that the hardness is slightly reduced.
- the weld metal in the uppermost layer is used. It is sufficient that the vicinity of each surface of the metal has sufficient hardness.
- the surface hardness is HV337 or more and HV533 or less and having sufficient wear resistance
- a welding method that forms a weld metal that does not occur is considered extremely useful.
- Patent Documents 1 to 5 have been proposed as techniques for suppressing the low-temperature cracking caused by hydrogen generated in a high-strength weld metal.
- patent document 1 prevents generation
- Patent Document 2 prevents the occurrence of cold cracking by causing an oxide to function as a hydrogen trap site for a steel sheet that is also used for applications such as a high-strength line pipe.
- Patent Document 3 discloses a technique for preventing the occurrence of cold cracking by causing Mo carbide to function as a trap site for a steel material having a tensile strength of 800 to 1150 MPa.
- Patent Document 4 discloses that the amount of diffusible hydrogen in the weld metal immediately after welding is reduced to about 3.0 to 4.0 ml / 100 g by adding an appropriate amount of Mg to the coating material of the coated arc welding material, thereby increasing the tensile strength.
- a technique for improving cold cracking resistance of a steel material of 880 to 1180 MPa is disclosed.
- Patent document 5 is disclosing the technique which suppresses a low temperature crack by restrict
- an austenitic stainless steel welding material when used, the penetration of hydrogen into the weld metal is greatly reduced, so that the low temperature cracking susceptibility can be lowered. Moreover, since it is an austenite structure, a ductile fall cracking is hard to produce. However, a weld metal using an austenitic stainless steel welding material is not easy to increase strength, that is, hardness, and cannot be expected to have wear resistance.
- the surface hardness is HV 337 or higher and HV 533 or lower. It is demanded to form a weld metal that is difficult to be welded or a weld metal that has a surface hardness of HV380 or more and HV533 or less and that is excellent in wear resistance and that does not easily cause cold cracking by gas shield arc welding.
- An object of the present invention is a welded joint using a high-hardness steel plate having a high C content and a surface hardness of HV380 or more and HV693 or less as a base material, and having a surface hardness of HV337 or more and HV533 or less.
- a method for producing a welded metal having excellent wear resistance and low-temperature cracking, or a welded joint having a surface hardness of HV380 to HV533 and having excellent wear resistance and low-temperature cracking. Is to provide.
- the preheating temperature at the time of welding was important to prevent low temperature cracking, so it was common to weld with the preheating temperature as the top priority with a welding material for mild steel. Therefore, the problem was that the hardness of the weld metal part was low and wear was very likely to occur.
- the present invention has newly found that when the hardness of the weld metal part is increased, the weld metal itself is very susceptible to cracking, not the heat-affected part of the base material. Therefore, after investigating the relationship between weld metal CEN and cracks, we found the appropriate range of weld metal CEN.
- FIG. 1 shows that the y-type weld cracking test specified in JIS Z3158 was carried out under various conditions with various steel sheets and welding materials with different flux compositions, etc. It is the result of having produced the weld metal which has the amount of diffusible hydrogen, and calculated
- FIG. 1 shows the relationship between the amount of diffusible hydrogen in the weld metal and the limit preheating temperature at which cracking is suppressed, organized according to the hardness level of the weld metal.
- the low-temperature cracking test was conducted at room temperature (25 ° C.) in accordance with JIS Z3158 (y-type weld cracking test method: 1993), and was accepted as having passed on the surface and the cross section.
- the measurement test of the amount of diffusible hydrogen was carried out by a gas chromatograph method based on JIS Z3118 (method for measuring the amount of hydrogen in steel welds; 2007).
- the limit preheating temperature for the occurrence of cold cracking does not depend much on the hardness of the weld metal. Therefore, by setting the amount of diffusible hydrogen to less than 1.0 ml / 100 g, the low-temperature cracking susceptibility between a weld metal having a hardness of HV337 to HV533 and a weld metal having a hardness of HV380 to HV533 is greatly reduced. Can do.
- the weld metal contains a certain amount of fluoride such as CaF 2 in the flux component, the amount of oxide is adjusted, and the compounding ratio of fluoride and oxide is within a certain range. It was found that the amount of diffusible hydrogen therein can be stably suppressed to less than 1.0 ml / 100 g.
- Low-temperature cracking susceptibility of weld metal depends greatly on the hardness of the weld metal, but is also affected by alloying elements.
- the inventors investigated the relationship between various alloy compositions and low-temperature cracking susceptibility (cracking suppression preheating temperature) of a weld metal of HV337 to HV533 and a weld metal of HV380 to HV533.
- the low temperature cracking test is conducted in accordance with JIS Z3158 (y-type weld cracking test method: 1993), and the minimum preheating temperature that does not cause low temperature cracking by changing the preheating temperature is determined as the crack initiation limit preheating temperature. did.
- the flux-cored welding wire of the present invention described below is used, and the amount of diffusible hydrogen in the weld metal is less than 1.0 ml / 100 g.
- CEN calculated by Equation 1 (see Welding Form 10. “Welding of Steel Materials”, Industrial Publication (1999), p. 163) is 0.58% by mass or less. It has been found that the cracking limit preheating temperature can be set to room temperature (25 ° C.) or less, and the occurrence of low temperature cracking can be suppressed without preheating.
- the present invention has been made on the basis of the above findings, and the gist thereof is as follows.
- the method for manufacturing a welded joint according to the first aspect of the present invention has a Vickers hardness HV of 380 to 514, a plate thickness of 20 to 100 mm, and a C content of 0.120 to 0. .300 mass%, CEN calculated by the following formula 1 is 0.20 to 0.75 mass%, Vickers hardness HV is more than 514 and less than 565, and the thickness is 12 to 100 mm.
- the preheating operation is performed so that the temperature of the steel plate is 10 ° C or higher, and (b) the flux-cored wire is CaF 2 , When one or more of BaF 2 , SrF 2 , and MgF 2 are contained and the total content thereof is ⁇ , the ⁇ is 3.3 to 8.0 in terms of mass% with respect to the total mass of the flux-cored wire. %, And containing at least one of Ti oxide, Si oxide, Mg oxide, and Al oxide, where ⁇ is the total content, ⁇ is the total mass of the flux-cored wire Vs.
- the total content of MgCO 3 is less than 0.60% by mass% relative to the total weight of the flux-cored wire Yes, the content of iron powder in the flux is less than 10.0% by mass% with respect to the total mass of the flux-cored wire, and the ratio of the CaF 2 content to ⁇ is 0.90 or more.
- the ratio of ⁇ to ⁇ is 3.0 or more and 80.0 or less, and the content of CaO is less than 0.20% by mass% with respect to the total mass of the flux-cored wire.
- the chemical components in the flux-cored wire excluding oxides and metal carbonates, in mass% with respect to the total mass of the flux-cored wire: C: 0.010 to less than 0.060%; Si: 0.0. 5 to 1.80%; Mn: 0.50 to 4.00%; P: 0.050% or less; S: 0.020% or less; Al: 0.005 to 0.150%; Cu: 0 to 0 Ni: 0 to less than 1.00%; Cr: 0 to 3.50%; Mo: 0 to 1.50%; Ti: 0 to 0.150%; Nb: 0 to 0.15%; V: 0 to 0.45%; B: 0 to 0.0500%; Mg: 0 to 2.0%; Ca: 0 to 2.0%; REM: 0 to 0.0150%; balance: Fe and impurities (C) the chemical composition of the weld metal of the weld joint is in mass%: C: 0.100 to 0.170%; Si: 0.05 to 0.80%; Mn: 0.20 to 2.50%; Al: 0.00
- CEN [C] + (0.75 + 0.25 ⁇ tanh (20 ⁇ ([C] ⁇ 0.12))) ⁇ ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 ⁇ [B]) (Formula 1)
- the element with [] represents the content (% by mass) of each element.
- the Vickers hardness HV is 380 to 514
- the plate thickness is 20 to 100 mm
- the C content is 0.120 to 0. .300 mass%
- CEN calculated by the following formula 1 is 0.20 to 0.75 mass%
- Vickers hardness HV is more than 514 and less than 565
- the thickness is 12 to 100 mm.
- the preheating operation is performed so that the temperature of the steel plate is 10 ° C or higher, and (b) the flux-cored wire is CaF 2 , When one or more of BaF 2 , SrF 2 , and MgF 2 are contained and the total content thereof is ⁇ , the ⁇ is 3.3 to 8.0 in terms of mass% with respect to the total mass of the flux-cored wire. %, And containing at least one of Ti oxide, Si oxide, Mg oxide, and Al oxide, where ⁇ is the total content, ⁇ is the total mass of the flux-cored wire Vs.
- the total content of MgCO 3 is less than 0.60% by mass% relative to the total weight of the flux-cored wire Yes, the content of iron powder in the flux is less than 10.0% by mass% with respect to the total mass of the flux-cored wire, and the ratio of the CaF 2 content to ⁇ is 0.90 or more.
- the ratio of ⁇ to ⁇ is 3.0 or more and 80.0 or less, and the content of CaO is less than 0.20% by mass% with respect to the total mass of the flux-cored wire.
- the chemical components in the flux-cored wire excluding oxides and metal carbonates, in mass% with respect to the total mass of the flux-cored wire: C: 0.060 to 0.350%; Si: 0.05 1.80%; Mn: 0.50 to 4.00%; P: 0.050% or less; S: 0.020% or less; Al: 0.005 to 0.150%; Cu: 0 to 0.75 Ni: 0 to less than 1.00%; Cr: 0 to 3.50%; Mo: 0 to 1.50%; Ti: 0 to 0.150%; Nb: 0 to 0.15%; V: B: 0 to 0.0500%; Mg: 0 to 2.0%; Ca: 0 to 2.0%; REM: 0 to 0.0150%; balance: Fe and impurities; (C) the chemical composition of the weld metal of the weld joint is in mass%: C: 0.120-0.250%; Si: 0.05-0.80%; Mn: 0.20-2.
- the method for manufacturing a welded joint according to the third aspect of the present invention has a Vickers hardness HV of more than 565 and not more than 693, a plate thickness of 12 to 20 mm, and a C content of 0.350 to 0.
- a steel sheet having a C content of 0.350 to 0.450 mass% and a CEN calculated by the following formula 2 of 0.20 to 0.85 mass% a method of manufacturing a welded joint by performing gas shielded arc welding using a flux-cored wire in which a steel outer sheath is filled with flux, (a) during the gas shielded arc welding, The plate thickness is 20m
- the preheating operation is performed so that the temperature of the steel plate is 100 ° C. or more.
- the flux-cored wire contains one or more of CaF 2 , BaF 2 , SrF 2 , and MgF 2 , and when the total content is ⁇ , the ⁇ is the flux-cored wire.
- It is 3.3 to 8.0% by mass with respect to the total mass, and contains at least one of Ti oxide, Si oxide, Mg oxide, and Al oxide, and the total content is ⁇ and The ⁇ is 0.10 to 1.50% by mass% with respect to the total mass of the flux-cored wire, and the total content of CaCO 3 , BaCO 3 , SrCO 3 , and MgCO 3 is the flux-cored wire.
- the whole quality of Less than 0.60% by mass% with respect to the content of iron powder in said flux is less than 10.0% in percentage by weight relative to the total weight of the flux-cored wire, inclusion of the CaF 2 with respect to the ⁇
- the ratio of the amount is 0.90 or more, the ratio of ⁇ to ⁇ is 3.0 or more and 80.0 or less, and the content of CaO is 0.20 by mass% with respect to the total mass of the flux-cored wire.
- the chemical composition of the weld metal of the weld joint is in mass%: C: 0.120 to 0.250%; Si: 0.05 to 0.80%; Mn: 0.20 to 2.50% Al: 0.0050 to 0.1000%; P: 0.050% or less; S: 0.020% or less; N: 0.015% or less; Cu: 0 to 0.50%; Ni: 0 to 0 Less than 70%; Cr
- CEN [C] + (0.75 + 0.25 ⁇ tanh (20 ⁇ ([C] ⁇ 0.12))) ⁇ ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 ⁇ [B]) (Formula 2)
- the element with [] represents the content (% by mass) of each element.
- the content of the CaO in the flux-cored wire is 0.15% or less by mass% with respect to the total mass of the flux-cored wire. It may be.
- the chemical composition may be Ni: 0 to 0.1% by mass% with respect to the total mass of the flux-cored wire.
- perfluoropolyether oil may be applied to the surface of the flux-cored wire.
- the inventors In a welded joint using a high-hardness steel plate as a base material, the inventors, as described above, have a cold crack initiation limit preheating temperature if the amount of diffusible hydrogen in the weld metal immediately after welding is less than 1.0 ml / 100 g. Has found that it does not depend much on the hardness of the weld metal and can greatly reduce the low-temperature cracking susceptibility between a weld metal of HV 337 and HV 533 and a weld metal of HV 380 and HV 533.
- the inventors have repeatedly studied various combinations and combinations of flux components of the flux-cored wire in order to reduce the amount of diffusible hydrogen in the weld metal immediately after welding to less than 1.0 ml / 100 g. It was. As a result, fluorides such as CaF 2 are particularly effective in reducing hydrogen. By containing a certain amount of the flux component, the amount of diffusible hydrogen in the weld metal can be greatly reduced. The inventors have found that the amount of diffusible hydrogen can be stably suppressed to less than 1.0 ml / 100 g by adjusting the amount and keeping the blending ratio of fluoride and oxide within a certain range.
- the present invention has been made based on such studies. Hereinafter, an aspect of the method for manufacturing the welded joint according to the present embodiment will be described.
- the present invention uses, as a base material, a high-hardness thick steel plate having a C content of 0.12 to 0.45% by mass, HV380 or more and HV693 or less, which is widely used as a wear-resistant steel plate.
- the target is a welded joint formed by gas shielded arc welding.
- the weld metal has the chemical composition described in (1) or (2) above.
- the reason for limiting the chemical composition of the weld metal will be described. In the following description, “%” means “% by mass” unless otherwise specified.
- C is an element that most affects the hardness of the weld metal.
- the base metal hardness is HV380 or higher, it is desirable that the surface hardness of the weld metal is at least HV337 in order to ensure a certain degree of wear resistance in the weld metal.
- the C content of the weld metal needs to be 0.100% or more.
- the base metal hardness is HV380 or more, it is desirable that the surface hardness of the weld metal is HV380 or more in order to ensure wear resistance close to that of the base material.
- the C content of the weld metal needs to be 0.120% or more.
- the upper limit of the C content is set to 0.250%.
- the C content of the weld metal of a welded joint made using a flux-cored wire having a C content of 0.010 to less than 0.060%, which will be described later may be 0.100 to 0.170%. It is normal.
- the lower limit of the C content may be 0.130% or 0.140%.
- the upper limit of C content it is good also considering the upper limit of C content as 0.230% or 0.210%.
- Si 0.05-0.80%
- Si is a deoxidizing element, and a certain amount is added to the flux in order to reduce the O content of the weld metal and increase the cleanliness. Therefore, the Si content in the weld metal is also 0.05% or more. If necessary, the lower limit of the Si content may be 0.10%, 0.15%, or 0.20%. If Si is contained in an amount exceeding 0.80%, the toughness of the weld metal may be deteriorated, so this is the upper limit. In order to improve the toughness of the weld metal, the upper limit of the Si content may be 0.70%, 0.65%, 0.60%, or 0.50%.
- Mn 0.20-2.50% Since Mn has the effect of forming MnS and suppressing grain boundary embrittlement due to S, it is contained in the weld metal at least 0.20% or more. Further, since Mn is an element that has the effect of ensuring the hardenability of the weld metal and increasing the strength, it is desirable to contain 0.50% or more in order to stably obtain the hardness. In order to improve the hardness of the weld metal, the lower limit of the Mn content may be 0.60%, 0.70%, 0.80%, or 0.90%. On the other hand, if Mn exceeds 2.50%, the grain boundary embrittlement susceptibility increases and the toughness of the weld metal deteriorates, so this is the upper limit. In order to improve the toughness of the weld metal, the upper limit of the Mn content may be limited to 2.30%, 2.10%, 1.90%, 1.70%, or 1.50%.
- Al is a deoxidizing element and, like Si, has the effect of improving the cleanliness of the weld metal by reducing the O content in the weld metal, so a certain amount needs to be added to the flux. .
- the weld metal of the welded joint obtained using the flux cored wire according to the present embodiment usually contains 0.0050% or more of Al.
- the amount of Al is less than 0.0050%, the low temperature toughness of the weld metal may be reduced.
- the content exceeds 0.1000%, nitrides and oxides are formed and the toughness of the weld metal is deteriorated, so this is the upper limit.
- the upper limit of the Al content may be limited to 0.0900%, 0.0800%, 0.0700%, or 0.0600%.
- P 0.050% or less
- the P content of the weld metal is limited to 0.050% or less as a range in which an adverse effect on toughness can be tolerated.
- the upper limit of the P content may be limited to 0.030%, 0.0250%, 0.0200%, or 0.0150%. There is no need to limit the lower limit of the P content.
- the lower limit of the P content is 0%.
- S is also an impurity element, and if it is excessively present in the weld metal, it deteriorates both toughness and ductility, so it is preferable to reduce it as much as possible.
- the S content of weld metal is limited to 0.020% or less. If necessary, the upper limit of the S content may be limited to 0.015%, 0.010%, 0.008%, or 0.006%. There is no need to limit the lower limit of the S content. The lower limit of the S content is 0%.
- N 0.015% or less
- the N content is limited to 0.015% or less as an upper limit that can allow an influence on the weld metal. If necessary, the upper limit of the N content may be limited to 0.010%, 0.008%, or 0.006%. There is no need to limit the lower limit of the N content.
- the lower limit of the N content is 0%.
- O is inevitably contained in the weld metal, but the O content of the weld metal is limited to 0.100% or less as a range in which an adverse effect on toughness and ductility can be tolerated.
- the upper limit of the O content may be 0.080%, 0.060%, 0.050%, or 0.040%.
- the lower limit of the O content is 0%.
- Cu can improve the strength and toughness of the weld metal, it can be contained as a selective element. However, if the Cu content exceeds 0.50%, the toughness may decrease, so the Cu content of the weld metal is set to 0.50% or less. If necessary, the upper limit of Cu content may be 0.40% or 0.30%. There is no need to limit the lower limit of the Cu content. For this reason, the minimum of Cu content is 0%. On the other hand, in order to obtain a sufficient strengthening effect, the weld metal may be contained by 0.10% or more. As a method for incorporating Cu into the weld metal, there are a method of plating the outer surface of the wire, or a method of adding it as a simple substance or an alloy element to the flux.
- Ni 0 to less than 0.70%
- Ni can be contained as a selective element that is effective for improving toughness.
- the C content is high, the effect is limited and it is also an expensive element, so the Ni content in the weld metal is less than 0.70%.
- the upper limit of the Ni content may be 0.60%, 0.40%, or 0.20%.
- the lower limit of the Ni content is 0%.
- 0.05% or more may be contained in the weld metal.
- Cr is an element effective for improving the hardness of the weld metal by increasing the hardenability, and can be contained as a selective element. However, if the content exceeds 2.50% excessively, the toughness may be reduced, so the upper limit of the Cr content is 2.50%. If necessary, the upper limit of the Cr content may be 1.50%, 1.00%, 0.70%, or 0.40%. There is no need to limit the lower limit of the Cr content. For this reason, the lower limit of the Cr content is 0%. On the other hand, when it is added for the purpose of improving the hardness of the weld metal, it may be contained by 0.10% or more in order to obtain the effect.
- Mo is an element effective for improving the hardness of the weld metal by increasing the hardenability, and can be contained as a selective element. However, if the content exceeds 1.00% excessively, the toughness may be lowered, so the Mo content is limited to 1.00%. If necessary, the upper limit of the Mo content may be 0.70%, 0.60%, 0.40%, or 0.20%. There is no need to limit the lower limit of the Mo content. For this reason, the lower limit of the Mo content is 0%. On the other hand, when added for the purpose of improving the hardness, 0.05% or more may be contained in order to obtain the effect.
- Ti is effective as a deoxidizing element, has an effect of reducing the O content in the weld metal, and can be contained as a selective element. It is also effective for fixing the solid solution N and mitigating the adverse effect on toughness.
- the upper limit of the Ti content is set to 0.100%. If necessary, the upper limit of the Ti content may be 0.080%, 0.050%, 0.030%, or 0.020%. There is no need to limit the lower limit of the Ti content. For this reason, the lower limit of the Ti content is 0%. You may make it contain 0.010% or more for the purpose of toughness improvement.
- Nb has the effect of improving the hardness of the weld metal by solid solution, and can be contained as a selective element. However, if the content exceeds 0.100%, it is not preferable because it is excessively contained in the weld metal and coarse precipitates are formed to deteriorate toughness. Therefore, the upper limit of the Nb content is 0.100%. To do. If necessary, the upper limit of the Nb content may be 0.080%, 0.050%, 0.030%, or 0.020%. There is no need to limit the lower limit of the Nb content. For this reason, the lower limit of the Nb content is 0%. You may make it contain 0.010% or more for the purpose of the hardness improvement of a weld metal.
- V is an element effective for improving the hardness of the weld metal by increasing the hardenability, and can be contained as a selective element. However, if the content exceeds 0.30%, the toughness may be lowered, so the V content is 0.30% as the upper limit. As needed, it is good also considering the upper limit of V content as 0.25%, 0.20%, or 0.15. There is no need to limit the lower limit of the V content. For this reason, the lower limit of the V content is 0%. You may make it contain 0.01% or more for the hardness improvement of a weld metal.
- B (B: 0 to 0.0100%)
- B has an effect of forming a BN in combination with the solid solution N and reducing the adverse effect on the toughness of the solid solution N.
- B also has the effect of enhancing the hardenability and contributing to the strength improvement, and can be contained as a selective element. In order to obtain these effects, 0.0003% or more may be contained.
- the upper limit of the B content when B is contained is 0.0100%. If necessary, the upper limit of the B content may be 0.0080%, 0.0060%, 0.0040%, or 0.0020%. There is no need to limit the lower limit of the B content, and the lower limit of the B content is 0%.
- Mg 0 to 0.100%
- Mg is a strong deoxidizing element, and may be contained by 0.001% or more in order to reduce the O content in the weld metal and improve the ductility and toughness of the weld metal.
- Mg content in the weld metal exceeds 0.100%, a decrease in toughness due to the formation of coarse oxides in the weld metal cannot be ignored. For this reason, also when it contains Mg, Mg content shall be 0.100% or less.
- the upper limit of the Mg content may be 0.0080%, 0.0060%, 0.0040%, or 0.0020%.
- Ca and REM are effective in improving the ductility and toughness by changing the structure of the sulfide in the weld metal and reducing the size of the sulfide and oxide. You may contain REM 0.0002% or more. On the other hand, if it is contained excessively, it causes coarsening of sulfides and oxides, leading to deterioration of ductility and toughness. Therefore, the upper limit of each inclusion is 0.100% for Ca and 0.0100% for REM. To do.
- the weld metal containing the above chemical composition may contain impurities that are mixed in during the manufacturing process, etc., as long as the balance containing iron (Fe) as a main component does not hinder the characteristics of the welded joint according to the present embodiment. .
- CEN 0.20 to 0.58 mass%
- CEN calculated by Formula 1 is 0.58% by mass or less.
- the crack initiation limit preheating temperature is 25 ° C. or less, and welding without substantially preheating becomes possible.
- the upper limit of CEN may be set to 0.55% by mass, 0.53% by mass, 0.50% by mass, 0.47% by mass, or 0.45% by mass.
- the lower limit of CEN is 0.20% by mass.
- the base material has a Vickers hardness HV of 380 to 514 (corresponding to HB 360 to 475), the base material has a thickness of 20 to 100 mm, and the base material has a C content of 0.120 to A base material having 0.300% and CEN calculated by Formula 1 of 0.20 to 0.75% by mass.
- the Vickers hardness HV of the base material is 514 to 565 or less (corresponding to HB475 to 530 or less), the thickness of the base material is 12 to 100 mm, and the C content of the base material is 0.120 to A base material having 0.300% and CEN calculated by Formula 1 of 0.20 to 0.75% by mass.
- the base material has a Vickers hardness HV of over 565 to 693 (corresponding to HB 530 of over 650), the base material has a thickness of 6 to 12 mm, and the base material has a C content of 0.350 to A base material having 0.450% and CEN calculated by Formula 1 of 0.20 to 0.85 mass%.
- the base metal temperature satisfying any one of the above (a) to (c) is 10 ° C or higher during gas shielded arc welding, there is no need to perform preheating work during welding.
- the temperature of the material is less than 10 ° C.
- the upper limit of the base material temperature (preheating temperature) is not particularly required, but may be less than 75 ° C or less than 50 ° C.
- the base material has a Vickers hardness HV of more than 565 and less than 693 (corresponding to more than HB 530 and less than 650), the thickness of the base material is 12 to 20 mm, and the C content of the base material is 0.350 to A base material having 0.450% and CEN calculated by Formula 1 of 0.20 to 0.85 mass%.
- the Vickers hardness HV of the base material is more than 565 to 693 or less (corresponding to HB 530 or more and 650 or less), the thickness of the base material is more than 20 mm and 50 mm or less, and the C content of the base material is 0.350.
- the base material when the thickness of the base material is 20 mm or less during gas shielded arc welding, the base material is preheated to 100 ° C. or more, and the thickness of the base material is In the case of over 20 mm, the base material is preheated to 150 ° C. or higher.
- the upper limit of the base material temperature (preheating temperature) is not particularly required, but may be less than 175 ° C or less than 150 ° C.
- CEN shall be 0.20 mass% or more.
- the average Vickers hardness of 1 mm below the surface of the weld metal is further set to HV337 or higher and HV533 or lower, or HV380 or higher and HV533 or lower.
- the amount of diffusible hydrogen immediately after welding is set to be less than 1.0 ml / 100 g for the weld metal. If the hardness at a position 1 mm below the surface is HV337 or higher and HV533 or lower, the wear resistance requirement necessary for the weld metal is satisfied. If it is less than HV337, the wear resistance is insufficient. If it exceeds HV533, cold cracking is likely to occur.
- the hardness is measured by cutting a cross section perpendicular to the welding direction in a weld metal, collecting a polished sample, measuring 10 points of Vickers hardness at a position 1 mm below the surface of the weld metal, and calculating an average value. Shall be determined by
- the amount of diffusible hydrogen in the weld metal immediately after welding is less than 1.0 ml / 100 g. It does not depend much on the hardness, and the cold cracking susceptibility of the weld metal having a hardness of HV337 to HV533 and the weld metal of HV380 to HV533 can be greatly reduced.
- the amount of diffusible hydrogen is measured by a gas chromatographic method based on JIS Z 3118 (Method for measuring the amount of hydrogen in steel welds; 2007). Since the diffusion rate of hydrogen is relatively high at room temperature, the amount of diffusible hydrogen in the weld metal must be measured immediately after welding. For this reason, unless it measures immediately after welding, the amount of diffusible hydrogen cannot be measured correctly.
- a welded joint having a weld metal As described above, a high-hardness thick steel plate to be welded is used as a base material, and, for example, the two base materials are set at a welding position so as to form a groove therebetween. Then, by performing gas shielded arc welding using a flux-cored welding wire and generating a weld metal between the base materials, a weld joint composed of the weld metal and base metal plates on both sides thereof is formed.
- steel plates, flux-cored welding wires, welding conditions and the like used for forming the weld metal will be described.
- a high-hardness thick steel plate having a C content of 0.120% or more and 0.450% or less and HV380 or more and HV693 or less in mass% is an object.
- the plate thickness of the steel plate to be used the thickness of 6 mm or more and 100 mm or less, which is generally referred to as a thick plate, is targeted.
- Steel sheets satisfying such conditions are widely used in places where wear resistance is required, such as machinery for civil engineering and construction work, and there is no particular limitation on the chemical composition other than the C content.
- C 0.120 to 3.000%, Si: 0.10 to 0.55%, Mn: 0.20 to 2.00%, Al: 0.01 to 0.10%, P: 0.020%
- S 0.015% or less
- Cu 0.50% or less
- Ni 1.00% or less
- Cr 1.20% or less
- Mo 0.60% or less
- Nb 0.05% or less
- the CEN calculated by the equation 1 is 0.20 to 0.85% by mass.
- the upper limit of CEN is set to 0.85% by mass.
- the upper limit of CEN is 0.80 mass%, 0.75 mass%, 0.73 mass%, 0.70 mass%, 0.68 mass%, 0 It is good also as .65 mass%, 0.63 mass%, or 0.60 mass%.
- the lower limit of CEN is 0.20% by mass.
- the lower limit of CEN may be 0.24 mass%, 0.28 mass%, 0.30 mass%, 0.32 mass%, 0.35 mass% or 0.38 mass%. Good.
- a steel sheet having a base metal hardness of HV565 or less generally has a CEN of less than 0.75% by mass.
- the upper limit of the CEN of a steel sheet having a base metal hardness of HV565 or less is set to 0.75% by mass.
- the method for measuring the hardness of the base material is a method in which five or more Vickers hardnesses at a position 1 mm below the surface of the cross section in the thickness direction of the base material are measured to obtain an average value.
- the flux-cored welding wire to be used will be described separately for the flux component and the alloy component.
- content of the component in description about a flux cored welding wire represents the mass% with respect to the total mass of a flux cored welding wire.
- Ti oxide eg TiO 2
- Si oxide eg SiO 2
- Mg oxide eg MgO
- Al oxide for example, Al 2 O 3
- the total amount ⁇ is 3.3% or more by mass% with respect to the total mass of the flux-cored wire, 8 0.0% or less, and when the total amount of Ti oxide, Si oxide, Mg oxide and Al oxide contained is ⁇ , the total amount ⁇ is 0% by mass with respect to the total mass of the flux-cored wire.
- the ratio of the CaF 2 content to the ⁇ is 0.90 or more, and the ratio of the total amount ⁇ to the total amount ⁇ ([total amount ⁇ ] / [Total amount ⁇ ]) is 3.0 or more and 80.0 or less.
- the total amount ⁇ of the metal fluoride contained is less than 3.3%, the amount of diffusible hydrogen in the weld metal cannot be stably reduced to less than 1.0 ml / 100 g.
- the lower limit of the total amount ⁇ may be 3.5%, 3.7%, or 3.9%.
- the upper limit of the total amount ⁇ may be 7.5%, 7.0%, 6.5%, 6.0%, or 5.7%.
- the total amount ⁇ of the metal oxides contained is less than 0.10%, the shape of the weld bead may be deteriorated, and if it exceeds 1.50%, the toughness may be lowered.
- the lower limit of the total amount ⁇ may be 0.20%, 0.30%, 0.40%, or 0.50%.
- the upper limit of the total amount ⁇ may be 1.30%, 1.20%, 1.10%, 1.00%, 0.90%, or 0.80%.
- the ratio of the total amount ⁇ to the total amount ⁇ is less than 3.0, the amount of diffusible hydrogen in the weld metal cannot be stably reduced to less than 1.0 ml / 100 g, and if it exceeds 80.0 Since welding fume and slag are excessively generated, welding workability is remarkably lowered, which is not preferable.
- the lower limit of the ratio ([total amount ⁇ ] / [total amount ⁇ ]) is set to 3.2, 3.5, 3.7, or 4.0. Also good.
- the upper limit of the ratio ([total amount ⁇ ] / [total amount ⁇ ]) is set to 40.0, 30.0, 20.0, 15.0 or 13. It may be 0.
- the ratio of the content of CaF 2 to ⁇ is less than 0.90, the amount of diffusible hydrogen in the weld metal cannot be made less than 1.0 ml / 100 g. This is because CaF 2 has the greatest effect of reducing the amount of diffusible hydrogen among metal fluorides.
- the ratio of the content of CaF 2 with respect to ⁇ is maximized when no metal fluoride other than CaF 2 is contained in the flux. Therefore, the upper limit of the ratio of the content of CaF 2 to ⁇ is 1.0.
- the ratio of the total amount ⁇ of metal fluoride to the total amount ⁇ of metal fluoride, the total amount ⁇ of metal oxide, and the total amount ⁇ of metal oxide is limited as described above.
- the total amount ⁇ is the content in the flux-cored wire, and the total content is also included in binders (water glass containing SiO 2 as a main component) used for flux granulation. .
- one or more metal carbonates of CaCO 3 , BaCO 3 , SrCO 3 , and MgCO 3 are further added for the purpose of improving the arc stability action and the arc concentration. it can.
- these metal carbonates are added in an amount of 0.60% or more, the arc concentration is too strong, resulting in an increased amount of spatter and an increased amount of oxygen in the weld metal. Therefore, when these metal carbonates are contained, the total content is less than 0.60%.
- the lower limit of the total content of these metal carbonates is 0%.
- the upper limit may be set to 0.50%, 0.40%, 0.20%, or 0.10% in order to suppress the amount of spatter generated.
- metal fluoride reduces the amount of diffusible hydrogen is not necessarily clear, but was metal fluoride decomposed by a welding arc, and the generated fluorine combined with hydrogen and dissipated into the atmosphere as HF gas? Alternatively, it is considered that hydrogen is fixed as HF in the weld metal as it is.
- the lower limit value of the CaO content is 0%.
- CaO may be contained in the flux raw material.
- the CaO content is limited to less than 0.20%.
- it is 0.15% or less or 0.10% or less. If the content is limited to less than 0.20%, the effect of the welded joint manufacturing method according to the present embodiment can be obtained. Since CaO changes to CaOH when exposed to the atmosphere, it may increase diffusible hydrogen in the weld metal.
- the amount of alloying elements in the flux-cored wire excluding metal fluorides, metal oxides, and metal carbonates is also limited as follows.
- C When the average Vickers hardness HV 1 mm below the surface of the weld metal is 337 to 440, it is 0.010 to 0.350%, and the average Vickers hardness HV 1 mm below the surface of the weld metal is 380 to 533. In the case of 0.060 to 0.350%) If the C content in the flux-cored wire is less than 0.010%, the C content in the weld metal is less than 0.100% and the hardness of the weld metal is less than HV337. The C content is 0.010% or more.
- the C content in the flux-cored wire is less than 0.060%, the C content of the weld metal is less than 0.120% and the hardness of the weld metal is less than HV380.
- the C content in the flux-cored wire is set to 0.060% or more.
- the lower limit value of the C content may be 0.020% or 0.030%.
- the lower limit of the C content may be 0.070%, 0.080%, 0.090%, 0.100%, or 0.110%.
- the C content in the flux-cored wire exceeds 0.350%, the C content in the weld metal exceeds 0.250%, so the C content in the flux-cored wire is 0.350% or less.
- the upper limit of the C content may be 0.300%, 0.250%, 0.180%, 0.170%, or 0.160%.
- the Si content in the flux-cored wire is less than 0.05%, the Si content in the weld metal is less than 0.05%, so the Si content in the flux-cored wire is 0.05% or more. .
- the lower limit of the Si content may be 0.10%, 0.20%, 0.30%, or 0.40%. If the Si content in the flux-cored wire exceeds 1.80%, the Si content in the weld metal exceeds 0.80% even if oxidation consumption is taken into consideration, so the Si content in the flux-cored wire is 1 80% or less.
- the upper limit of the Si content may be 1.50%, 1.20%, 1.00%, 0.80%, or 0.60%.
- the Mn content in the flux-cored wire is less than 0.50%, the Mn content in the weld metal is less than 0.20%, so the Mn content in the flux-cored wire is 0.50% or more. .
- the lower limit of the Mn content may be 0.70%, 0.80%, 0.90%, 1.00%, or 1.10%. If the Mn content in the flux-cored wire exceeds 4.00%, the Mn content of the weld metal exceeds 2.50% even if oxidation consumption is taken into consideration, so the Mn content in the flux-cored wire is 4. 00% or less.
- the upper limit of the Mn content may be 3.00%, 2.50%, 2.20%, 2.00%, or 1.80%.
- the P content in the flux-cored wire exceeds 0.050%, the P content in the weld metal may exceed 0.050%, so the P content in the flux-cored wire is 0.050%.
- the upper limit of the P content may be limited to 0.030%, 0.025%, 0.020%, or 0.015%. There is no need to limit the lower limit of the P content.
- the lower limit of the P content is 0%.
- the S content in the flux-cored wire exceeds 0.020%, the S content in the weld metal may exceed 0.020%, so the S content in the flux-cored wire is 0.020%.
- the upper limit of the S content may be limited to 0.015%, 0.010%, 0.008%, or 0.006%.
- the lower limit of the S content is 0%.
- the Al content in the flux-cored wire is less than 0.005%, the Al content in the weld metal is less than 0.005%, so the Al content in the flux-cored wire is 0.005% or more. .
- the lower limit of the Al content may be 0.007%, 0.010%, or 0.012%. If the Al content in the flux cored wire exceeds 0.150%, the Al content in the weld metal may exceed 0.100%, so the Al content in the flux cored wire is 0.150%.
- the upper limit of the Al content may be limited to 0.090%, 0.070%, 0.050%, or 0.040%.
- the Cu content in the flux-cored wire exceeds 0.75%, the Cu content in the weld metal exceeds 0.50%, so the Cu content in the flux-cored wire is 0.75% or less. .
- the Cu content may be 0.50% or less.
- the upper limit of Cu content may be 0.40% or 0.30%.
- the minimum of Cu content is 0%.
- the weld metal may contain 0.10% or more of Cu.
- the Ni content in the flux-cored wire is 1.00% or more, the Ni content of the weld metal is 0.70% or more, and the alloy cost of the wire becomes high. Therefore, the Ni content in the flux-cored wire is Less than 1.00%.
- the upper limit of the Ni content may be 0.50%, 0.40%, 0.30%, 0.20%, or 0.10%. There is no need to limit the lower limit of the Ni content. For this reason, the lower limit of the Ni content is 0%.
- the Cr content in the flux-cored wire exceeds 3.50%, the Cr content in the weld metal exceeds 2.50%, so the Cr content in the flux-cored wire is 3.50% or less. .
- the upper limit of the Cr content may be 1.50%, 1.00%, 0.50%, or 0.10%.
- the lower limit of the Cr content is 0%.
- 0.05% or more may be contained in order to obtain the effect.
- Mo 0 to 1.50%
- the Mo content in the flux-cored wire exceeds 1.50%, the Mo content in the weld metal exceeds 1.00%, so the Mo content in the flux-cored wire is 1.50% or less.
- the upper limit of the Mo content may be 0.70%, 0.50%, 0.30%, or 0.20%.
- the lower limit of the Mo content is 0%.
- 0.05% or more may be contained in order to obtain the effect.
- the Ti content in the flux-cored wire exceeds 0.150%, the Ti content of the weld metal exceeds 0.100%, so the Ti content in the flux-cored wire is 0.150% or less. .
- the upper limit of the Ti content may be 0.100%, 0.080%, or 0.050%. There is no need to limit the lower limit of the Ti content. For this reason, the lower limit of the Ti content is 0%. You may make it contain 0.010% or more for the purpose of toughness improvement.
- the Nb content in the flux-cored wire exceeds 0.15%, the Nb content in the weld metal exceeds 0.10%, so the Nb content in the flux-cored wire is 0.15% or less. .
- the upper limit of the Nb content may be 0.10%, 0.08%, or 0.05%.
- the lower limit of the Nb content is 0%. You may make it contain 0.01% or more for the purpose of the hardness improvement of a weld metal.
- V (V: 0 to 0.45%) If the V content in the flux-cored wire exceeds 0.45%, the V content in the weld metal exceeds 0.30%, so the V content in the flux-cored wire is 0.45% or less. .
- the upper limit of the V content may be 0.25%, 0.20%, or 0.15%. There is no need to limit the lower limit of the V content. For this reason, the lower limit of the V content is 0%. You may make it contain 0.01% or more for the hardness improvement of a weld metal.
- the B content in the flux-cored wire exceeds 0.0500%, the B content in the weld metal exceeds 0.0100%, so the B content in the flux-cored wire is 0.0500% or less.
- the upper limit of the B content may be 0.0400%, 0.0200%, 0.0100%, or 0.0050%.
- the lower limit of the B content is 0%.
- the Mg content in the flux-cored wire exceeds 2.0%, the Mg content in the weld metal exceeds 0.10%, so the Mg content in the flux-cored wire is 2.0% or less. .
- the upper limit of the Mg content may be 1.5%, 1.0%, 0.4%, or 0.2%. There is no need to limit the lower limit of the Mg content, and the lower limit of the Mg content is 0%.
- the Ca content in the flux-cored wire exceeds 2.0%, the Ca content in the weld metal exceeds 0.10%, so the Ca content in the flux-cored wire is 2.0% or less. .
- the upper limit of the Ca content may be 1.5%, 1.0%, 0.5%, or 0.3%. There is no need to limit the lower limit of the Ca content, and the lower limit of the Ca content is 0%.
- the REM content in the flux-cored wire exceeds 0.0150%, the REM content in the weld metal exceeds 0.0100%, so the REM content in the flux-cored wire is 0.0150% or less.
- the upper limit of the REM content may be 0.0100%, 0.0050%, or 0.0030%. There is no need to limit the lower limit of the REM content, and the lower limit of the REM content is 0%.
- the above is the reason for limitation regarding the chemical composition of the flux-cored wire according to the present embodiment.
- Other chemical components of the remaining alloy may contain impurities mixed in the manufacturing process or the like as long as the balance containing Fe as a main component does not hinder the characteristics of the welded joint according to the present embodiment.
- the Fe component includes Fe in the steel outer shell, iron powder added in the flux, and Fe in the alloy component.
- the content of iron powder in the flux is less than 10.0% in mass% with respect to the total mass of the flux-cored wire. When there is much iron powder content, the amount of oxygen may increase. If necessary, the iron powder content may be less than 5.0% or less than 1.0%. Since it is not necessary to contain iron powder, the lower limit of the iron powder content is 0%.
- a flux-cored wire includes a seamless wire without a slit-like seam in the steel outer shell (that is, a wire in which the steel outer seam is welded), and a wire having a seam with a slit-like gap at the steel outer seam. And can be broadly divided. In the present invention, any cross-sectional structure can be adopted, but it is preferable that there is no slit-like seam (seamless wire) in order to suppress cold cracking of the weld metal.
- Hydrogen that penetrates into the weld during welding diffuses into the weld metal and on the steel side, accumulates in the stress concentration part, and causes cold cracking.
- This hydrogen source can increase moisture contained in the welding material, moisture mixed in from the atmosphere, rust and scale attached to the steel surface, etc., but under the welding where the cleanliness of the weld and the gas shield conditions are sufficiently controlled. Then, hydrogen mainly contained in water in the wire is a main factor of diffusible hydrogen existing in the weld joint.
- the steel outer shell into a slit-like seamless (seamless) pipe, and to suppress the invasion of hydrogen in the atmosphere from the steel outer shell to the flux after the wire is manufactured and used.
- a pipe with a slit-like seam (having a seam) in the steel outer skin moisture in the atmosphere easily enters the flux from the slit-like seam (seam part) of the outer skin, and as it is, hydrogen such as moisture Source intrusion cannot be prevented. Therefore, when the period until use after production is long, the entire wire is preferably vacuum-packed or stored in a container that can be kept dry.
- lubricating oil may be applied to the wire surface. From the viewpoint of reducing diffusible hydrogen, the lubricating oil applied to the wire surface is preferably an oil that does not contain hydrogen, such as perfluoropolyether (PFPE) oil.
- PFPE perfluoropolyether
- the flux cored wire used in the present invention can be manufactured by the same manufacturing process as that of a normal flux cored wire manufacturing method. That is, first, a steel strip to be an outer skin and a flux containing metal fluoride, an alloy component, a metal oxide, a metal carbonate, and an arc stabilizer are prepared so as to have predetermined contents. While feeding the steel strip in the longitudinal direction, it is formed into an open tube (U-shaped) with a forming roll to form a steel outer shell. During this forming, flux is supplied from the opening of the open tube, and the opposing edge surface of the opening is Butt seam welding.
- a seamless pipe obtained by welding is drawn and annealed during or after the drawing process to obtain a slit-like seamless (seamless) wire having a desired wire diameter.
- a wire having a slit-like seam (having a seam) is obtained by supplying a flux from an opening of an open pipe, then forming a pipe with a seam without seam welding, and drawing the wire.
- a cross section of a wire without slit-like gaps made by butt seam welding looks like FIG. 3A. If this cross section is polished and etched, welding marks are observed, but if not etched, no welding marks are observed. Therefore, it may be called seamless.
- FIG. 3B a wire without slit-like gaps can be obtained even after brazing and brazing or brazing as shown in FIG. 3C.
- the wire as it is without brazing becomes a wire having a slit-like gap.
- the object can be achieved, and the method of gas shield arc welding is not particularly limited, and a commonly used method can be adopted.
- the shielding gas in addition to 100% CO 2 gas, a mixed gas of Ar gas and 3 to 20 vol% CO 2 gas can be used.
- the flow rate of the shielding gas can be a normal condition, that is, about 15 to 30 L / min.
- the welding conditions such as current and voltage are, for example, a current of 200 to 350 A and a voltage of 25 to 35 V.
- the welding speed may be controlled so that the welding heat input is 10 to 50 kJ / cm.
- the shape of the welded joint to be manufactured is determined according to the application and is not particularly limited. It can be applied to welded joints that form grooves, such as ordinary butt joints, square joints, and T joints. Therefore, the shape of the steel plate to be welded is not limited as long as at least the portion forming the welded joint is plate-like, and the whole may not be a plate, and includes, for example, a shape steel. Moreover, it is not limited to what is comprised from a separate steel plate, The butt-welding joint of what shape
- a steel plate having the components shown in Table 1 was used as a base material.
- the same steel plate as the base material was used for the backing metal for welding.
- a seamless pipe was used, and annealing was performed in the course of drawing the drawn wire, and a flux-cored wire with a final wire diameter of ⁇ 1.2 mm was made as a trial product.
- a part of the tube was a slit-like pipe that was not seam-welded, and a wire with a wire diameter of ⁇ 1.2 mm was prototyped by drawing it.
- the entire wire was vacuum-packed and stored in a container that can be kept dry until welding.
- the analysis of the chemical composition of the prototype flux cored wire was performed as follows. First, the filled flux was taken out from the flux-cored wire, and the flux-cored wire was divided into a steel outer shell and a flux. The chemical component of the steel outer skin was determined by measuring the content of each metal component by chemical analysis. The chemical composition of the flux was performed according to the following procedure.
- the above base material was abutted at a root gap of 16 mm and a groove angle of 20 °, and using a backing metal, under the welding conditions shown in Tables 4-1-1 to 4-2-3 Welding was performed.
- the groove surface of the base material and the surface of the backing metal were subjected to buttering with two or more layers and a height of 3 mm or more using a flux-cored wire to be tested.
- Ti oxide, Si oxide, Mg oxide, Al oxide respectively by using the TiO 2, SiO 2, MgO, Al 2 O 3.
- the metal carbonates are CaCO 3 , BaCO 3 , SrCO 3 , and MgCO 3 .
- the chemical composition analysis results of the obtained weld metal are shown in Table 5-1-1, Table 5-1-2, Table 5-2-1, Table 5-2-2, Table 5-2-4, and Table 5-2. Shown in -5.
- a sample obtained by polishing a cross section perpendicular to the welding direction was taken from this weld metal, measured at 10 points of Vickers hardness at a position 1 mm below the surface of the weld metal, and Brinell hardness from SAE J417 (1983) hardness conversion table. Converted to Further, a No. 4 Charpy test piece (2 mmV notch) based on JIS Z3111 (2005) was sampled, and the Charpy absorbed energy at ⁇ 40 ° C. of the weld metal was measured. A sample having an absorption energy of ⁇ 40 ° C. or more of 27 J or more was regarded as acceptable.
- the obtained hardness and Charpy test results are shown in Tables 5-1-3, 5-2-3 and 5-2-6.
- the low temperature crack test and the diffusible hydrogen content measurement test were done to the welded joint obtained by the same welding conditions, respectively.
- the low-temperature cracking test was conducted at room temperature (25 ° C.) in accordance with JIS Z3158 (y-type weld cracking test method: 1993).
- the diffusible hydrogen content measurement test was carried out by a gas chromatograph method based on JIS Z3118 (Method for measuring the hydrogen content of steel welds; 2007). This diffusible hydrogen content was less than 1.0 ml / 100 g.
- Table 5-1-3, Table 5-2-3, and Table 5-2-6 The results are shown in Table 5-1-3, Table 5-2-3, and Table 5-2-6.
- the weld metals of Examples 1 to 54 which are examples of the present invention, are all excellent in hardness, toughness, cold crack resistance, and welding workability. there were.
- the weld metals of Comparative Examples 101 to 165 do not satisfy the requirements specified in the present invention. At least one of cold cracking resistance and welding workability was rejected.
- the underlined numbers in the comparative examples in Tables 5-2-1 to 5-2-6 indicate that they are outside the scope of the present invention.
- the surface hardness is HV337 or more and HV533 or less
- wear resistance Weld metal with excellent surface resistance or weld metal with surface hardness of HV380 or higher and HV533 or lower and excellent wear resistance can be obtained without generating low-temperature cracks without preheating.
- the value in the industry is extremely high.
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Abstract
Description
本願は、2013年11月8日に国際出願されたPCT/JP2013/080242号に基づき優先権を主張し、その内容をここに援用する。 The present invention has a weld metal that has high hardness, excellent wear resistance, and is resistant to low-temperature cracking when welding high-hardness steel plates with excellent wear resistance used in the construction machinery and industrial machinery fields. The present invention relates to a method for manufacturing a welded joint.
This application claims priority based on PCT / JP2013 / 080242 internationally filed on November 8, 2013, the contents of which are incorporated herein by reference.
溶接金属の硬さは、母材と同等程度であることが望ましい。例えばHB400あるいはHB500級耐摩耗鋼を母材とする場合では、溶接金属の硬さを少なくともHV337(HB320)以上、できればHV380(HB360)以上とすることが望ましい。 In order to avoid such cold cracking, preheating is generally performed prior to welding. However, since wear-resistant steel is more likely to be reduced in hardness by heating than ordinary steel, it cannot take a very high preheating temperature.
The hardness of the weld metal is preferably about the same as that of the base material. For example, when HB400 or HB500 class wear resistant steel is used as a base material, it is desirable that the hardness of the weld metal is at least HV337 (HB320) or higher, preferably HV380 (HB360) or higher.
以上のようなことから、HV380以上、HV693以下である高硬度の耐摩耗鋼を母材とする溶接継手において、表面硬さがHV337以上、HV533以下であり十分な耐摩耗性を有しながら、予熱をしなくても低温割れが発生しない溶接金属を形成させる溶接方法、または表面硬さがHV380以上、HV533以下であり十分な耐摩耗性を有しながら、予熱をしなくても低温割れが発生しない溶接金属を形成させる溶接方法があれば極めて有用であると考えられる。 Further, in the weld metal part, what is important from the viewpoint of wear resistance is the hardness near the surface. In multi-layer welding, the weld metal in the lower layer is reheated by subsequent passes, so that the hardness is slightly reduced. In multi-layer welding, the weld metal in the uppermost layer is used. It is sufficient that the vicinity of each surface of the metal has sufficient hardness.
From the above, in a welded joint using a high-hardness wear-resistant steel of HV380 or more and HV693 or less as a base material, the surface hardness is HV337 or more and HV533 or less and having sufficient wear resistance, A welding method for forming a weld metal that does not generate cold cracks even without preheating, or a surface hardness of HV380 or higher and HV533 or lower and sufficient wear resistance, and low temperature cracks without preheating. A welding method that forms a weld metal that does not occur is considered extremely useful.
これらのうち特許文献1は、高強度ラインパイプなどの用途に用いられる鋼板について、残留オーステナイトを水素のトラップサイトとして機能させることにより、低温割れの発生を防ぐものである。特許文献2は、やはり高強度ラインパイプなどの用途に用いられる鋼板について、酸化物を水素のトラップサイトとして機能させることにより、低温割れの発生を防ぐものである。 For example, methods disclosed in
Among these,
これらはいずれも母材および溶接金属の強度が1200MPa未満であり、HV380(引張強さ換算約1200MPa)以上の硬さを有して耐摩耗性を具備する溶接金属の低温割れ性を改善できる技術ではない。 Patent Document 3 discloses a technique for preventing the occurrence of cold cracking by causing Mo carbide to function as a trap site for a steel material having a tensile strength of 800 to 1150 MPa. Patent Document 4 discloses that the amount of diffusible hydrogen in the weld metal immediately after welding is reduced to about 3.0 to 4.0 ml / 100 g by adding an appropriate amount of Mg to the coating material of the coated arc welding material, thereby increasing the tensile strength. A technique for improving cold cracking resistance of a steel material of 880 to 1180 MPa is disclosed. Patent document 5 is disclosing the technique which suppresses a low temperature crack by restrict | limiting the amount of hydrogen contained in the flux cored wire for gas shield arc welding.
These are technologies that can improve the low-temperature cracking property of weld metal having a base metal and weld metal strength of less than 1200 MPa, and having a hardness of HV380 (approximately 1200 MPa in terms of tensile strength) or more and wear resistance. is not.
ここで、低温割れ試験は、JIS Z3158(y形溶接割れ試験方法;1993年)に準拠し、室温(25℃)にて試験を実施し、表面および断面に割れがないことをもって合格とした。拡散性水素量の測定試験は、JIS Z3118(鋼溶接部の水素量測定方法;2007年)に準拠したガスクロマトグラフ法にて実施した。 FIG. 1 shows that the y-type weld cracking test specified in JIS Z3158 was carried out under various conditions with various steel sheets and welding materials with different flux compositions, etc. It is the result of having produced the weld metal which has the amount of diffusible hydrogen, and calculated | required the limit preheating temperature which suppresses the crack generation. FIG. 1 shows the relationship between the amount of diffusible hydrogen in the weld metal and the limit preheating temperature at which cracking is suppressed, organized according to the hardness level of the weld metal.
Here, the low-temperature cracking test was conducted at room temperature (25 ° C.) in accordance with JIS Z3158 (y-type weld cracking test method: 1993), and was accepted as having passed on the surface and the cross section. The measurement test of the amount of diffusible hydrogen was carried out by a gas chromatograph method based on JIS Z3118 (method for measuring the amount of hydrogen in steel welds; 2007).
CEN=[C]+(0.75+0.25×tanh(20×([C]-0.12)))×([Si]/24+[Mn]/6+[Cu]/15+[Ni]/20+([Cr]+[Mo]+[Nb]+[V])/5+5×[B]) ・・・(式1)
ただし、[]付元素は、それぞれの元素の含有量(質量%)を表す。また、添加元素が無しの場合は、[]内にゼロを代入する。 As a result, as shown in FIG. 2, if CEN calculated by Equation 1 (see
CEN = [C] + (0.75 + 0.25 × tanh (20 × ([C] −0.12))) × ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 × [B]) (Formula 1)
However, the element with [] represents the content (% by mass) of each element. If there is no additive element, zero is substituted in [].
CEN=[C]+(0.75+0.25×tanh(20×([C]-0.12)))×([Si]/24+[Mn]/6+[Cu]/15+[Ni]/20+([Cr]+[Mo]+[Nb]+[V])/5+5×[B]) ・・・(式1)
ただし、[]付元素は、それぞれの元素の含有量(質量%)を表す。 (1) The method for manufacturing a welded joint according to the first aspect of the present invention has a Vickers hardness HV of 380 to 514, a plate thickness of 20 to 100 mm, and a C content of 0.120 to 0. .300 mass%, CEN calculated by the following
CEN = [C] + (0.75 + 0.25 × tanh (20 × ([C] −0.12))) × ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 × [B]) (Formula 1)
However, the element with [] represents the content (% by mass) of each element.
CEN=[C]+(0.75+0.25×tanh(20×([C]-0.12)))×([Si]/24+[Mn]/6+[Cu]/15+[Ni]/20+([Cr]+[Mo]+[Nb]+[V])/5+5×[B]) ・・・(式1)
ただし、[]付元素は、それぞれの元素の含有量(質量%)を表す。
(3)本発明の第三の態様に係る溶接継手の製造方法は、ビッカース硬さHVが565超693以下であり、板厚が12~20mmであり、Cの含有量が0.350~0.450質量%であり、下記の式2で計算されるCENが、0.20~0.85質量%である鋼板、およびビッカース硬さHVが565超693以下であり、板厚が20mm超50mm以下であり、Cの含有量が0.350~0.450質量%であり、下記の式2で計算されるCENが、0.20~0.85質量%である鋼板、のいずれか一つに対し、鋼製外皮にフラックスが充填されたフラックス入りワイヤを用いて、ガスシールドアーク溶接を行うことにより、溶接継手を製造する方法であって、(a)前記ガスシールドアーク溶接時に、前記鋼板の前記板厚が20mm以下の場合、前記鋼板の温度が100℃以上となるように予熱作業を行い、前記鋼板の前記板厚が20mm超の場合、前記鋼板の温度が150℃以上となるように前記予熱作業を行い、(b)前記フラックス入りワイヤが、CaF2、BaF2、SrF2、MgF2のうちの1種以上を含有し、その含有量の合計をαとしたとき、前記αが前記フラックス入りワイヤの全質量に対する質量%で3.3~8.0%であり、Ti酸化物、Si酸化物、Mg酸化物、Al酸化物のうちの1種以上を含有し、その含有量の合計をβとしたとき、前記βが前記フラックス入りワイヤの全質量に対する質量%で0.10~1.50%であり、CaCO3、BaCO3、SrCO3、MgCO3の含有量の合計が、前記フラックス入りワイヤの全質量に対する質量%で0.60%未満であり、前記フラックス中の鉄粉の含有量が、前記フラックス入りワイヤの全質量に対する質量%で10.0%未満であり、前記αに対する前記CaF2の含有量の比が0.90以上であり、前記βに対する前記αの比が3.0以上80.0以下であり、CaOの含有量が、前記フラックス入りワイヤの全質量に対する質量%で0.20%未満であり、金属弗化物、金属酸化物、および金属炭酸塩を除く、前記フラックス入りワイヤ中の化学成分が、前記フラックス入りワイヤの全質量に対する質量%で:C:0.060~0.350%;Si:0.05~1.80%;Mn:0.50~4.00%;P:0.050%以下;S:0.020%以下;Al:0.005~0.150%;Cu:0~0.75%;Ni:0~1.00%未満;Cr:0~3.50%;Mo:0~1.50%;Ti:0~0.150%;Nb:0~0.15%;V:0~0.45%;B:0~0.0500%;Mg:0~2.0%;Ca:0~2.0%;REM:0~0.0150%;残部:Feおよび不純物;からなり、(c)前記溶接継手の溶接金属の化学組成が、質量%で:C:0.120~0.250%;Si:0.05~0.80%;Mn:0.20~2.50%;Al:0.0050~0.1000%;P:0.050%以下;S:0.020%以下;N:0.015%以下;Cu:0~0.50%;Ni:0~0.70%未満;Cr:0~2.50%;Mo:0~1.00%;Ti:0~0.100%;Nb:0~0.100%;V:0~0.30%;B:0~0.0100%;O:0~0.100%;Mg:0~0.100%;Ca:0~0.100%;REM:0~0.0100%;残部:Feおよび不純物;からなり、前記溶接金属の、下記の式2で計算されるCENが、0.20~0.58質量%であり、前記溶接金属の表面下1mmの平均ビッカース硬さHVが、380~533であり、上記(a)~(c)の全てを満足する。
CEN=[C]+(0.75+0.25×tanh(20×([C]-0.12)))×([Si]/24+[Mn]/6+[Cu]/15+[Ni]/20+([Cr]+[Mo]+[Nb]+[V])/5+5×[B]) ・・・(式2)
ただし、[]付元素は、それぞれの元素の含有量(質量%)を表す。 (2) In the method for manufacturing a welded joint according to the second aspect of the present invention, the Vickers hardness HV is 380 to 514, the plate thickness is 20 to 100 mm, and the C content is 0.120 to 0. .300 mass%, CEN calculated by the following
CEN = [C] + (0.75 + 0.25 × tanh (20 × ([C] −0.12))) × ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 × [B]) (Formula 1)
However, the element with [] represents the content (% by mass) of each element.
(3) The method for manufacturing a welded joint according to the third aspect of the present invention has a Vickers hardness HV of more than 565 and not more than 693, a plate thickness of 12 to 20 mm, and a C content of 0.350 to 0. .450% by mass, CEN calculated by the following formula 2 is 0.20 to 0.85% by mass, and the Vickers hardness HV is more than 565 to 693 and the plate thickness is more than 20 mm and 50 mm. Any one of the following: a steel sheet having a C content of 0.350 to 0.450 mass% and a CEN calculated by the following formula 2 of 0.20 to 0.85 mass% On the other hand, a method of manufacturing a welded joint by performing gas shielded arc welding using a flux-cored wire in which a steel outer sheath is filled with flux, (a) during the gas shielded arc welding, The plate thickness is 20m In the following cases, the preheating operation is performed so that the temperature of the steel plate is 100 ° C. or more. When the plate thickness of the steel plate is more than 20 mm, the preheating operation is performed so that the temperature of the steel plate is 150 ° C. or more. (B) The flux-cored wire contains one or more of CaF 2 , BaF 2 , SrF 2 , and MgF 2 , and when the total content is α, the α is the flux-cored wire. It is 3.3 to 8.0% by mass with respect to the total mass, and contains at least one of Ti oxide, Si oxide, Mg oxide, and Al oxide, and the total content is β and The β is 0.10 to 1.50% by mass% with respect to the total mass of the flux-cored wire, and the total content of CaCO 3 , BaCO 3 , SrCO 3 , and MgCO 3 is the flux-cored wire. The whole quality of Less than 0.60% by mass% with respect to the content of iron powder in said flux is less than 10.0% in percentage by weight relative to the total weight of the flux-cored wire, inclusion of the CaF 2 with respect to the α The ratio of the amount is 0.90 or more, the ratio of α to β is 3.0 or more and 80.0 or less, and the content of CaO is 0.20 by mass% with respect to the total mass of the flux-cored wire. % Of the chemical component in the flux-cored wire, excluding metal fluoride, metal oxide, and metal carbonate, in terms of mass% with respect to the total mass of the flux-cored wire: C: 0.060-0. 350%; Si: 0.05 to 1.80%; Mn: 0.50 to 4.00%; P: 0.050% or less; S: 0.020% or less; Al: 0.005 to 0.150 %: Cu: 0 to 0.75% Ni: 0 to less than 1.00%; Cr: 0 to 3.50%; Mo: 0 to 1.50%; Ti: 0 to 0.150%; Nb: 0 to 0.15%; V: 0 to 0.45%; B: 0-0.0500%; Mg: 0-2.0%; Ca: 0-2.0%; REM: 0-0.0150%; balance: Fe and impurities; (C) The chemical composition of the weld metal of the weld joint is in mass%: C: 0.120 to 0.250%; Si: 0.05 to 0.80%; Mn: 0.20 to 2.50% Al: 0.0050 to 0.1000%; P: 0.050% or less; S: 0.020% or less; N: 0.015% or less; Cu: 0 to 0.50%; Ni: 0 to 0 Less than 70%; Cr: 0 to 2.50%; Mo: 0 to 1.00%; Ti: 0 to 0.100%; Nb: 0 to 0.100%; V: 0 to 0.30%; B O: 0 to 0.100%; Mg: 0 to 0.100%; Ca: 0 to 0.100%; REM: 0 to 0.0100%; balance: Fe and impurities; The CEN calculated by the following formula 2 of the weld metal is 0.20 to 0.58% by mass, and the average Vickers hardness HV 1 mm below the surface of the weld metal is 380 to 533. All of the above (a) to (c) are satisfied.
CEN = [C] + (0.75 + 0.25 × tanh (20 × ([C] −0.12))) × ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 × [B]) (Formula 2)
However, the element with [] represents the content (% by mass) of each element.
(8)上記(1)~(6)のいずれか一項に記載の溶接継手の製造方法は、前記フラックス入りワイヤの前記鋼製外皮にスリット上の隙間がなくてもよい。 (7) In the method for manufacturing a welded joint according to any one of (1) to (6) above, there may be a slit-like gap in the steel outer sheath of the flux-cored wire.
(8) In the method for manufacturing a welded joint according to any one of the above (1) to (6), there may be no gap on the slit in the steel outer shell of the flux-cored wire.
その結果、水素低減に特に効果のあるのはCaF2をはじめとする弗化物であり、フラックス成分に一定量を含有させることにより溶接金属中の拡散性水素量を大きく低減でき、さらに酸化物の量を調整し、かつ弗化物と酸化物の配合比を一定範囲とすることにより、拡散性水素量を安定して1.0ml/100g未満に抑制することができることを知見するに至った。 Furthermore, the inventors have repeatedly studied various combinations and combinations of flux components of the flux-cored wire in order to reduce the amount of diffusible hydrogen in the weld metal immediately after welding to less than 1.0 ml / 100 g. It was.
As a result, fluorides such as CaF 2 are particularly effective in reducing hydrogen. By containing a certain amount of the flux component, the amount of diffusible hydrogen in the weld metal can be greatly reduced. The inventors have found that the amount of diffusible hydrogen can be stably suppressed to less than 1.0 ml / 100 g by adjusting the amount and keeping the blending ratio of fluoride and oxide within a certain range.
本発明は、耐摩耗鋼板として広く用いられている、C含有量が質量%で0.12~0.45%で、HV380以上、HV693以下の高硬度の厚鋼板を母材として用い、それをガスシールドアーク溶接して形成した溶接継手を対象とする。
本発明では、溶接金属を、上記(1)または(2)に記載した化学組成を有するものとする。
以下、溶接金属の化学組成の限定理由について説明する。以下の説明において、「%」は特に説明がない限り、「質量%」を意味する。 The present invention has been made based on such studies. Hereinafter, an aspect of the method for manufacturing the welded joint according to the present embodiment will be described.
The present invention uses, as a base material, a high-hardness thick steel plate having a C content of 0.12 to 0.45% by mass, HV380 or more and HV693 or less, which is widely used as a wear-resistant steel plate. The target is a welded joint formed by gas shielded arc welding.
In the present invention, the weld metal has the chemical composition described in (1) or (2) above.
Hereinafter, the reason for limiting the chemical composition of the weld metal will be described. In the following description, “%” means “% by mass” unless otherwise specified.
Cは、溶接金属の硬さに最も影響する元素である。母材硬さがHV380以上であるときに、溶接金属にある程度の耐摩耗性を確保するためには、溶接金属の表面硬さは少なくともHV337以上であることが望ましい。そのためには溶接金属のC含有量は0.100%以上が必要である。また、母材硬さがHV380以上であるときに、母材に近い耐摩耗性を確保するためには、溶接金属の表面硬さもHV380以上であることが望ましい。溶接金属の表面硬さをHV380以上にする必要がある場合には、溶接金属のC含有量を0.120%以上にする必要がある。しかし、C含有量が0.250%を超えると、溶接金属の硬さがHV533を超えて溶接金属の靭性が低下することがあるので、C含有量の上限を0.250%とする。なお、後述するC含有量が0.010~0.060%未満のフラックス入りワイヤを用いて作られた溶接継手の溶接金属のC含有量は、0.100~0.170%となることが通常である。安定してHV380以上の母材硬さを得るためには、C含有量の下限を0.130%または0.140%としてもよい。また、溶接金属の靭性を安定して得るために、C含有量の上限を0.230%または0.210%としてもよい。 (C: 0.100 to 0.250%)
C is an element that most affects the hardness of the weld metal. When the base metal hardness is HV380 or higher, it is desirable that the surface hardness of the weld metal is at least HV337 in order to ensure a certain degree of wear resistance in the weld metal. For that purpose, the C content of the weld metal needs to be 0.100% or more. Further, when the base metal hardness is HV380 or more, it is desirable that the surface hardness of the weld metal is HV380 or more in order to ensure wear resistance close to that of the base material. When the surface hardness of the weld metal needs to be HV380 or more, the C content of the weld metal needs to be 0.120% or more. However, if the C content exceeds 0.250%, the hardness of the weld metal exceeds HV533 and the toughness of the weld metal may decrease, so the upper limit of the C content is set to 0.250%. Note that the C content of the weld metal of a welded joint made using a flux-cored wire having a C content of 0.010 to less than 0.060%, which will be described later, may be 0.100 to 0.170%. It is normal. In order to stably obtain a base material hardness of HV380 or higher, the lower limit of the C content may be 0.130% or 0.140%. Moreover, in order to acquire the toughness of a weld metal stably, it is good also considering the upper limit of C content as 0.230% or 0.210%.
Siは、脱酸元素であり、溶接金属のO含有量を低減して清浄度を高めるためにフラックスには一定量添加する。そのため溶接金属中のSi含有量も0.05%以上が含有される。必要に応じて、Si含有量の下限を0.10%、0.15%又は0.20%としてもよい。Siは、0.80%を超えて含有すると溶接金属の靱性を劣化させることがあるため、これを上限とする。溶接金属の靭性改善のため、Si含有量の上限を0.70%、0.65%、0.60%又は0.50%としてもよい。 (Si: 0.05-0.80%)
Si is a deoxidizing element, and a certain amount is added to the flux in order to reduce the O content of the weld metal and increase the cleanliness. Therefore, the Si content in the weld metal is also 0.05% or more. If necessary, the lower limit of the Si content may be 0.10%, 0.15%, or 0.20%. If Si is contained in an amount exceeding 0.80%, the toughness of the weld metal may be deteriorated, so this is the upper limit. In order to improve the toughness of the weld metal, the upper limit of the Si content may be 0.70%, 0.65%, 0.60%, or 0.50%.
Mnは、MnSを形成してSによる粒界脆化を抑制する効果があるので、溶接金属には少なくとも0.20%以上含有させるようにする。またMnは溶接金属の焼入性を確保して強度を高める効果のある元素であるので、硬さを安定的に得るためには、0.50%以上含有することが望ましい。溶接金属の硬さ向上のため、Mn含有量の下限を0.60%、0.70%、0.80%又は0.90%としてもよい。一方、Mnは、2.50%を超えて含有すると、粒界脆化感受性が増加して溶接金属の靱性が劣化するため、これを上限とする。溶接金属の靭性改善のため、Mn含有量の上限を2.30%、2.10%、1.90%、1.70%又は1.50%に制限してもよい。 (Mn: 0.20-2.50%)
Since Mn has the effect of forming MnS and suppressing grain boundary embrittlement due to S, it is contained in the weld metal at least 0.20% or more. Further, since Mn is an element that has the effect of ensuring the hardenability of the weld metal and increasing the strength, it is desirable to contain 0.50% or more in order to stably obtain the hardness. In order to improve the hardness of the weld metal, the lower limit of the Mn content may be 0.60%, 0.70%, 0.80%, or 0.90%. On the other hand, if Mn exceeds 2.50%, the grain boundary embrittlement susceptibility increases and the toughness of the weld metal deteriorates, so this is the upper limit. In order to improve the toughness of the weld metal, the upper limit of the Mn content may be limited to 2.30%, 2.10%, 1.90%, 1.70%, or 1.50%.
Alは脱酸元素であり、Siと同様に、溶接金属中のO含有量を低減することにより、溶接金属の清浄度を向上させる効果があるので、フラックスには一定量を添加する必要がある。本実施形態に係るフラックス入りワイヤを用いて得られた溶接継手の溶接金属には、通常、0.0050%以上のAlが含まれる。Al量が0.0050%未満であった場合、溶接金属の低温靱性が低下するおそれがある。一方、0.1000%を超えて含有させると、窒化物や酸化物を形成して、溶接金属の靱性を劣化させるので、これを上限とする。溶接金属の靭性改善のため、Al含有量の上限を0.0900%、0.0800%、0.0700%又は0.0600%に制限してもよい。 (Al: 0.0050 to 0.1000%)
Al is a deoxidizing element and, like Si, has the effect of improving the cleanliness of the weld metal by reducing the O content in the weld metal, so a certain amount needs to be added to the flux. . The weld metal of the welded joint obtained using the flux cored wire according to the present embodiment usually contains 0.0050% or more of Al. When the amount of Al is less than 0.0050%, the low temperature toughness of the weld metal may be reduced. On the other hand, if the content exceeds 0.1000%, nitrides and oxides are formed and the toughness of the weld metal is deteriorated, so this is the upper limit. In order to improve the toughness of the weld metal, the upper limit of the Al content may be limited to 0.0900%, 0.0800%, 0.0700%, or 0.0600%.
Pは不純物元素であり、靱性を劣化させる。そのため極力低減する必要があるが、靱性への悪影響が許容できる範囲として、溶接金属のP含有量は0.050%以下に制限する。必要に応じて、P含有量の上限を0.030%、0.0250%、0.0200%又は0.0150%に制限してもよい。P含有量の下限を制限する必要はない。P含有量の下限は0%である。 (P: 0.050% or less)
P is an impurity element and degrades toughness. Therefore, although it is necessary to reduce as much as possible, the P content of the weld metal is limited to 0.050% or less as a range in which an adverse effect on toughness can be tolerated. If necessary, the upper limit of the P content may be limited to 0.030%, 0.0250%, 0.0200%, or 0.0150%. There is no need to limit the lower limit of the P content. The lower limit of the P content is 0%.
Sも不純物元素であり、溶接金属中に過大に存在すると靱性と延性とをともに劣化させるため、極力低減することが好ましい。靱性、延性への悪影響が許容できる範囲として、溶接金属のS含有量は0.020%以下に制限する。必要に応じて、S含有量の上限を0.015%、0.010%、0.008%又は0.006%に制限してもよい。S含有量の下限を制限する必要はない。S含有量の下限は0%である。 (S: 0.020% or less)
S is also an impurity element, and if it is excessively present in the weld metal, it deteriorates both toughness and ductility, so it is preferable to reduce it as much as possible. As a range in which an adverse effect on toughness and ductility can be tolerated, the S content of weld metal is limited to 0.020% or less. If necessary, the upper limit of the S content may be limited to 0.015%, 0.010%, 0.008%, or 0.006%. There is no need to limit the lower limit of the S content. The lower limit of the S content is 0%.
Nは、溶接金属中には不可避的に含有されるが、0.015%を超えると粗大なAlNやBNを形成して靭性を低下させる。溶接金属への影響を許容できる上限としてN含有量は0.015%以下に制限する。必要に応じて、N含有量の上限を0.010%、0.008%又は0.006%に制限してもよい。N含有量の下限を制限する必要はない。N含有量の下限は0%である。 (N: 0.015% or less)
N is inevitably contained in the weld metal, but if it exceeds 0.015%, coarse AlN or BN is formed and the toughness is lowered. The N content is limited to 0.015% or less as an upper limit that can allow an influence on the weld metal. If necessary, the upper limit of the N content may be limited to 0.010%, 0.008%, or 0.006%. There is no need to limit the lower limit of the N content. The lower limit of the N content is 0%.
Oは、溶接金属中には不可避的に含有されるが、靱性、延性への悪影響が許容できる範囲として、溶接金属のO含有量は0.100%以下に制限する。必要に応じて、O含有量の上限を0.080%、0.060%、0.050%又は0.040%としてもよい。O含有量の下限を制限する必要はない。O含有量の下限は0%である。 (O: 0 to 0.100%)
O is inevitably contained in the weld metal, but the O content of the weld metal is limited to 0.100% or less as a range in which an adverse effect on toughness and ductility can be tolerated. If necessary, the upper limit of the O content may be 0.080%, 0.060%, 0.050%, or 0.040%. There is no need to limit the lower limit of the O content. The lower limit of the O content is 0%.
Cuは、溶接金属の強度と靭性とを向上させることができるので、選択元素として含有できる。しかしながら、Cu含有量が0.50%を超えると靭性が低下することがあるため、溶接金属のCu含有量は0.50%以下とする。必要に応じて、Cu含有量の上限を0.40%又は0.30%としてもよい。Cu含有量の下限を制限しなくてもよい。このため、Cu含有量の下限は0%である。一方、強化効果を十分に得るために、溶接金属に0.10%以上含有させてもよい。溶接金属中にCuを含有させる方法としては、ワイヤの外皮表面のめっき、あるいは、フラックスに単体または合金元素として添加する等の方法がある。 (Cu: 0 to 0.50%)
Since Cu can improve the strength and toughness of the weld metal, it can be contained as a selective element. However, if the Cu content exceeds 0.50%, the toughness may decrease, so the Cu content of the weld metal is set to 0.50% or less. If necessary, the upper limit of Cu content may be 0.40% or 0.30%. There is no need to limit the lower limit of the Cu content. For this reason, the minimum of Cu content is 0%. On the other hand, in order to obtain a sufficient strengthening effect, the weld metal may be contained by 0.10% or more. As a method for incorporating Cu into the weld metal, there are a method of plating the outer surface of the wire, or a method of adding it as a simple substance or an alloy element to the flux.
Niは靱性向上に有効な元素とされる選択元素として含有できる。しかし、C含有量が高い場合にはその効果は限定的であり、高価な元素でもあるので、溶接金属へのNi含有量は0.70%未満とする。必要に応じて、Ni含有量の上限を0.60%、0.40%又は0.20%としてもよい。Ni含有量の下限を制限しなくてもよい。このため、Ni含有量の下限は0%である。一方、靭性向上効果を得るために、溶接金属に0.05%以上含有させてもよい。 (Ni: 0 to less than 0.70%)
Ni can be contained as a selective element that is effective for improving toughness. However, when the C content is high, the effect is limited and it is also an expensive element, so the Ni content in the weld metal is less than 0.70%. If necessary, the upper limit of the Ni content may be 0.60%, 0.40%, or 0.20%. There is no need to limit the lower limit of the Ni content. For this reason, the lower limit of the Ni content is 0%. On the other hand, in order to obtain the effect of improving toughness, 0.05% or more may be contained in the weld metal.
Crは、焼入性を高めることにより溶接金属の硬さ向上に有効な元素であり、選択元素として含有できる。しかしながら、2.50%を超えて過剰に含有させると、靱性を低下させることがあるため、Cr含有量は2.50%を上限とする。必要に応じて、Cr含有量の上限を1.50%、1.00%、0.70%又は0.40%としてもよい。Cr含有量の下限を制限しなくてもよい。このため、Cr含有量の下限は0%である。一方、溶接金属の硬さ向上の目的で添加する場合には、その効果を得るために0.10%以上含有させてもよい。 (Cr: 0-2.50%)
Cr is an element effective for improving the hardness of the weld metal by increasing the hardenability, and can be contained as a selective element. However, if the content exceeds 2.50% excessively, the toughness may be reduced, so the upper limit of the Cr content is 2.50%. If necessary, the upper limit of the Cr content may be 1.50%, 1.00%, 0.70%, or 0.40%. There is no need to limit the lower limit of the Cr content. For this reason, the lower limit of the Cr content is 0%. On the other hand, when it is added for the purpose of improving the hardness of the weld metal, it may be contained by 0.10% or more in order to obtain the effect.
Moは、焼入性を高めることにより溶接金属の硬さ向上に有効な元素であり、選択元素として含有できる。しかしながら、1.00%を超えて過剰に含有させると、靱性を低下させることがあるため、Mo含有量は1.00%を上限とする。必要に応じて、Mo含有量の上限を0.70%、0.60%、0.40%又は0.20%としてもよい。Mo含有量の下限を制限しなくてもよい。このため、Mo含有量の下限は0%である。一方、硬さ向上の目的で添加する場合には、その効果を得るために0.05%以上含有させてもよい。 (Mo: 0-1.00%)
Mo is an element effective for improving the hardness of the weld metal by increasing the hardenability, and can be contained as a selective element. However, if the content exceeds 1.00% excessively, the toughness may be lowered, so the Mo content is limited to 1.00%. If necessary, the upper limit of the Mo content may be 0.70%, 0.60%, 0.40%, or 0.20%. There is no need to limit the lower limit of the Mo content. For this reason, the lower limit of the Mo content is 0%. On the other hand, when added for the purpose of improving the hardness, 0.05% or more may be contained in order to obtain the effect.
TiもAlと同様、脱酸元素として有効であり、溶接金属中のO含有量を低減させる効果があり、選択元素として含有できる。また、固溶Nを固定して靱性への悪影響を緩和するためにも有効であるが、溶接金属中のTi含有量が0.100%を超えて過剰になると、粗大な酸化物の形成に起因した靱性劣化、過度な析出強化による靱性劣化が生じる可能性が大きくなるので、Ti含有量の上限は0.100%とする。必要に応じて、Ti含有量の上限を0.080%、0.050%、0.030%又は0.020%としてもよい。Ti含有量の下限を制限しなくてもよい。このため、Ti含有量の下限は0%である。靱性改善の目的に、0.010%以上含有させてもよい。 (Ti: 0 to 0.100%)
Ti, like Al, is effective as a deoxidizing element, has an effect of reducing the O content in the weld metal, and can be contained as a selective element. It is also effective for fixing the solid solution N and mitigating the adverse effect on toughness. However, when the Ti content in the weld metal exceeds 0.100%, it becomes a coarse oxide. Since the possibility of toughness deterioration due to excessive toughening due to excessive precipitation strengthening increases, the upper limit of the Ti content is set to 0.100%. If necessary, the upper limit of the Ti content may be 0.080%, 0.050%, 0.030%, or 0.020%. There is no need to limit the lower limit of the Ti content. For this reason, the lower limit of the Ti content is 0%. You may make it contain 0.010% or more for the purpose of toughness improvement.
Nbは固溶により溶接金属の硬さを向上させる効果があり、選択元素として含有できる。しかしながら、0.100%を超えて含有させると、溶接金属中に過剰に含有され、粗大な析出物を形成して靭性を劣化させるため好ましくないので、Nb含有量の上限を0.100%とする。必要に応じて、Nb含有量の上限を0.080%、0.050%、0.030%又は0.020%としてもよい。Nb含有量の下限を制限しなくてもよい。このため、Nb含有量の下限は0%である。溶接金属の硬さ向上目的に0.010%以上含有させてもよい。 (Nb: 0 to 0.100%)
Nb has the effect of improving the hardness of the weld metal by solid solution, and can be contained as a selective element. However, if the content exceeds 0.100%, it is not preferable because it is excessively contained in the weld metal and coarse precipitates are formed to deteriorate toughness. Therefore, the upper limit of the Nb content is 0.100%. To do. If necessary, the upper limit of the Nb content may be 0.080%, 0.050%, 0.030%, or 0.020%. There is no need to limit the lower limit of the Nb content. For this reason, the lower limit of the Nb content is 0%. You may make it contain 0.010% or more for the purpose of the hardness improvement of a weld metal.
Vは、焼入性を高めることにより溶接金属の硬さ向上に有効な元素であり、選択元素として含有できる。しかしながら、0.30%を超えて過剰に含有させると、靱性を低下させることがあるため、V含有量は0.30%を上限とする。必要に応じて、V含有量の上限を0.25%、0.20%又は0.15としてもよい。V含有量の下限を制限しなくてもよい。このため、V含有量の下限は0%である。溶接金属の硬さ向上のために0.01%以上含有させてもよい。 (V: 0 to 0.30%)
V is an element effective for improving the hardness of the weld metal by increasing the hardenability, and can be contained as a selective element. However, if the content exceeds 0.30%, the toughness may be lowered, so the V content is 0.30% as the upper limit. As needed, it is good also considering the upper limit of V content as 0.25%, 0.20%, or 0.15. There is no need to limit the lower limit of the V content. For this reason, the lower limit of the V content is 0%. You may make it contain 0.01% or more for the hardness improvement of a weld metal.
Bは、溶接金属中に適正量含有させると、固溶Nと結びついてBNを形成して、固溶Nの靭性に対する悪影響を減じる効果がある。またBは、焼入性を高めて強度向上に寄与する効果もあり、選択元素として含有できる。これらの効果を得るために0.0003%以上含有させてもよい。一方、B含有量が0.0100%超になると、溶接金属中のBが過剰となり、粗大なBNやFe23(C、B)6等のB化合物を形成して靭性を逆に劣化させるため、好ましくない。そこで、Bを含有させる場合のB含有量の上限は0.0100%とする。必要に応じて、B含有量の上限を0.0080%、0.0060%、0.0040%又は0.0020%としてもよい。B含有量の下限を制限する必要はなく、B含有量の下限は0%である。 (B: 0 to 0.0100%)
When an appropriate amount of B is contained in the weld metal, it has an effect of forming a BN in combination with the solid solution N and reducing the adverse effect on the toughness of the solid solution N. B also has the effect of enhancing the hardenability and contributing to the strength improvement, and can be contained as a selective element. In order to obtain these effects, 0.0003% or more may be contained. On the other hand, when the B content exceeds 0.0100%, B in the weld metal becomes excessive, and coarse toughness is deteriorated by forming coarse B compounds such as BN and Fe 23 (C, B) 6. Is not preferable. Therefore, the upper limit of the B content when B is contained is 0.0100%. If necessary, the upper limit of the B content may be 0.0080%, 0.0060%, 0.0040%, or 0.0020%. There is no need to limit the lower limit of the B content, and the lower limit of the B content is 0%.
Mg含有量の下限を制限する必要はなく、Mg含有量の下限は0%である。しかし、Mgは強脱酸元素であり、溶接金属中のO含有量を低減し、溶接金属の延性及び靭性を向上させために、0.001%以上含有させてもよい。しかし、溶接金属中のMg含有量が0.100%を超えると、溶接金属中での粗大酸化物の形成による靭性低下が無視できなくなる。このため、Mgを含有させる場合にも、Mg含有量を0.100%以下とする。必要に応じて、Mg含有量の上限を0.0080%、0.0060%、0.0040%又は0.0020%としてもよい。 (Mg: 0 to 0.100%)
There is no need to limit the lower limit of the Mg content, and the lower limit of the Mg content is 0%. However, Mg is a strong deoxidizing element, and may be contained by 0.001% or more in order to reduce the O content in the weld metal and improve the ductility and toughness of the weld metal. However, if the Mg content in the weld metal exceeds 0.100%, a decrease in toughness due to the formation of coarse oxides in the weld metal cannot be ignored. For this reason, also when it contains Mg, Mg content shall be 0.100% or less. If necessary, the upper limit of the Mg content may be 0.0080%, 0.0060%, 0.0040%, or 0.0020%.
(REM:0~0.0100%)
CaおよびREM含有量の下限を制限する必要はなく、CaおよびREM含有量の下限は0%である。しかし、Ca、REMはいずれも溶接金属中での硫化物の構造を変化させ、また硫化物、酸化物のサイズを微細化して延性及び靭性向上に有効であり、Caを0.002%以上、REMを0.0002%以上、含有してもよい。一方、過剰に含有すると、硫化物や酸化物の粗大化を生じ、延性、靭性の劣化を招くため、含有させる場合のそれぞれの上限を、Caでは0.100%、REMでは0.0100%とする。 (Ca: 0 to 0.100%)
(REM: 0-0.0100%)
There is no need to limit the lower limit of Ca and REM content, and the lower limit of Ca and REM content is 0%. However, both Ca and REM are effective in improving the ductility and toughness by changing the structure of the sulfide in the weld metal and reducing the size of the sulfide and oxide. You may contain REM 0.0002% or more. On the other hand, if it is contained excessively, it causes coarsening of sulfides and oxides, leading to deterioration of ductility and toughness. Therefore, the upper limit of each inclusion is 0.100% for Ca and 0.0100% for REM. To do.
図2に示すように、HV380以上、HV533以下の溶接金属において、溶接金属中の拡散性水素量が1.0ml/100g未満であるとき、式1で計算されるCENを0.58質量%以下とすることで、JIS Z3158のy形溶接割れ試験において、割れ発生限界予熱温度が25℃以下となり、実質的に予熱なしでの溶接が可能となる。
ここで、溶接割れを確実に防止するために、CENの上限を0.55質量%、0.53質量%、0.50質量%、0.47質量%又は0.45質量%としてもよい。溶接金属の硬さをHV380以上とするために、CENの下限を0.20質量%とする。溶接金属の硬さが高い方が、耐摩耗性が向上するため、CENの下限を0.24質量%、0.28質量%、0.30質量%又は0.32質量%としてもよい。
(a)母材のビッカース硬さHVが380以上514以下(HB360以上475以下に相当)であり、母材の板厚が20~100mmであり、母材のCの含有量が0.120~0.300%であり、式1で計算されるCENが、0.20~0.75質量%である母材。
(b)母材のビッカース硬さHVが514超565以下(HB475超530以下に相当)であり、母材の板厚が12~100mmであり、母材のCの含有量が0.120~0.300%であり、式1で計算されるCENが、0.20~0.75質量%である母材。
(c)母材のビッカース硬さHVが565超693以下(HB530超650以下に相当)であり、母材の板厚が6~12mmであり、母材のCの含有量が0.350~0.450%であり、式1で計算されるCENが、0.20~0.85質量%である母材。
上記(a)~(c)のいずれかひとつを満足する母材に対し、ガスシールドアーク溶接時に、母材の温度が10℃以上の場合、溶接時の予熱作業を行う必要がないが、母材の温度が10℃未満の場合には、母材の温度が10℃以上となるように予熱作業を行う必要がある。つまり、母材(鋼板)の温度が10℃未満の場合のみ、母材(鋼板)の温度が10℃以上になるように予熱作業を行う必要がある。この母材の温度(予熱温度)の上限を特に定める必要はないが、75℃未満又は50℃未満としても差し支えない。
(d)母材のビッカース硬さHVが565超693以下(HB530超650以下に相当)であり、母材の板厚が12~20mmであり、母材のCの含有量が0.350~0.450%であり、式1で計算されるCENが、0.20~0.85質量%である母材。
(e)母材のビッカース硬さHVが565超693以下(HB530超650以下に相当)であり、母材の板厚が20mm超50mm以下であり、母材のCの含有量が0.350~0.450%であり、式1で計算されるCENが、0.20~0.85質量%である母材。
上記(d)または(e)を満足する母材に対し、ガスシールドアーク溶接時に、母材の板厚が20mm以下の場合、母材を100℃以上に予熱を行い、母材の板厚が20mm超の場合、母材を150℃以上の予熱を行う。この母材の温度(予熱温度)の上限を特に定める必要はないが、175℃未満又は150℃未満としても差し支えない。また、HV380以上にするために、CENを0.20質量%以上とする。
CEN=[C]+(0.75+0.25×tanh(20×([C]-0.12)))×([Si]/24+[Mn]/6+[Cu]/15+[Ni]/20+([Cr]+[Mo]+[Nb]+[V])/5+5×[B]) ・・・(式1)
ただし、[]付元素は、それぞれの元素の含有量(質量%)を表す。 (CEN: 0.20 to 0.58 mass%)
As shown in FIG. 2, in a weld metal of HV380 or more and HV533 or less, when the amount of diffusible hydrogen in the weld metal is less than 1.0 ml / 100 g, CEN calculated by
Here, in order to reliably prevent weld cracking, the upper limit of CEN may be set to 0.55% by mass, 0.53% by mass, 0.50% by mass, 0.47% by mass, or 0.45% by mass. In order to make the hardness of the weld metal HV380 or more, the lower limit of CEN is 0.20% by mass. The higher the hardness of the weld metal, the better the wear resistance. Therefore, the lower limit of CEN may be 0.24 mass%, 0.28 mass%, 0.30 mass%, or 0.32 mass%.
(A) The base material has a Vickers hardness HV of 380 to 514 (corresponding to HB 360 to 475), the base material has a thickness of 20 to 100 mm, and the base material has a C content of 0.120 to A base material having 0.300% and CEN calculated by
(B) The Vickers hardness HV of the base material is 514 to 565 or less (corresponding to HB475 to 530 or less), the thickness of the base material is 12 to 100 mm, and the C content of the base material is 0.120 to A base material having 0.300% and CEN calculated by
(C) The base material has a Vickers hardness HV of over 565 to 693 (corresponding to HB 530 of over 650), the base material has a thickness of 6 to 12 mm, and the base material has a C content of 0.350 to A base material having 0.450% and CEN calculated by
If the base metal temperature satisfying any one of the above (a) to (c) is 10 ° C or higher during gas shielded arc welding, there is no need to perform preheating work during welding. When the temperature of the material is less than 10 ° C., it is necessary to perform preheating work so that the temperature of the base material becomes 10 ° C. or higher. That is, it is necessary to perform the preheating work so that the temperature of the base material (steel plate) is 10 ° C. or higher only when the temperature of the base material (steel plate) is less than 10 ° C. The upper limit of the base material temperature (preheating temperature) is not particularly required, but may be less than 75 ° C or less than 50 ° C.
(D) The base material has a Vickers hardness HV of more than 565 and less than 693 (corresponding to more than HB 530 and less than 650), the thickness of the base material is 12 to 20 mm, and the C content of the base material is 0.350 to A base material having 0.450% and CEN calculated by
(E) The Vickers hardness HV of the base material is more than 565 to 693 or less (corresponding to HB 530 or more and 650 or less), the thickness of the base material is more than 20 mm and 50 mm or less, and the C content of the base material is 0.350. A base material having a CEN of 0.20 to 0.85% by mass calculated from
For a base material satisfying the above (d) or (e), when the thickness of the base material is 20 mm or less during gas shielded arc welding, the base material is preheated to 100 ° C. or more, and the thickness of the base material is In the case of over 20 mm, the base material is preheated to 150 ° C. or higher. The upper limit of the base material temperature (preheating temperature) is not particularly required, but may be less than 175 ° C or less than 150 ° C. Moreover, in order to make it HV380 or more, CEN shall be 0.20 mass% or more.
CEN = [C] + (0.75 + 0.25 × tanh (20 × ([C] −0.12))) × ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 × [B]) (Formula 1)
However, the element with [] represents the content (% by mass) of each element.
表面下1mmの位置の硬さが、HV337以上、HV533以下となれば、溶接金属に必要な耐摩耗性の要件を満たす。HV337未満では、耐磨耗性が不足する。HV533を超えると、低温割れが発生しやすくなる。
硬さの測定は、溶接金属において、溶接方向と垂直の断面を切断し、研磨したサンプルを採取し、溶接金属の表面下1mmの位置のビッカース硬さを10点測定し、平均値を算出することによって求めるものとする。 In the present invention, the average Vickers hardness of 1 mm below the surface of the weld metal is further set to HV337 or higher and HV533 or lower, or HV380 or higher and HV533 or lower. In the present invention, the amount of diffusible hydrogen immediately after welding is set to be less than 1.0 ml / 100 g for the weld metal.
If the hardness at a
The hardness is measured by cutting a cross section perpendicular to the welding direction in a weld metal, collecting a polished sample, measuring 10 points of Vickers hardness at a
拡散性水素量は、JIS Z 3118(鋼溶接部の水素量測定方法;2007年)に準拠したガスクロマトグラフ法により測定する。
なお、水素の拡散速度は常温で比較的大きいため、溶接金属の拡散性水素量は溶接直後に測定する必要がある。このため、溶接直後に測定しない限り、拡散性水素量を正確に測定できない。 Further, as described above with reference to FIG. 1, the amount of diffusible hydrogen in the weld metal immediately after welding is less than 1.0 ml / 100 g. It does not depend much on the hardness, and the cold cracking susceptibility of the weld metal having a hardness of HV337 to HV533 and the weld metal of HV380 to HV533 can be greatly reduced.
The amount of diffusible hydrogen is measured by a gas chromatographic method based on JIS Z 3118 (Method for measuring the amount of hydrogen in steel welds; 2007).
Since the diffusion rate of hydrogen is relatively high at room temperature, the amount of diffusible hydrogen in the weld metal must be measured immediately after welding. For this reason, unless it measures immediately after welding, the amount of diffusible hydrogen cannot be measured correctly.
以下、上記溶接金属を形成するために用いられる、鋼板、フラックス入り溶接ワイヤ及び溶接条件などについて説明する。 In order to manufacture a welded joint having a weld metal as described above, a high-hardness thick steel plate to be welded is used as a base material, and, for example, the two base materials are set at a welding position so as to form a groove therebetween. Then, by performing gas shielded arc welding using a flux-cored welding wire and generating a weld metal between the base materials, a weld joint composed of the weld metal and base metal plates on both sides thereof is formed.
Hereinafter, steel plates, flux-cored welding wires, welding conditions and the like used for forming the weld metal will be described.
用いる鋼板の板厚としては、一般的に厚板といわれる6mm以上100mm以下のものを対象としている。
このような条件を満たす鋼板は、土木・建築作業用の機械など、耐摩耗性が必要な個所に広く用いられているもので、C含有量以外の化学組成について特に限定されるものではないが、一例をあげれば、
C:0.120~3.000%、Si:0.10~0.55%、Mn:0.20~2.00%、Al:0.01~0.10%、P:0.020%以下、S:0.015%以下、Cu:0.50%以下、Ni:1.00%以下、Cr:1.20%以下、Mo:0.60%以下、Nb:0.05%以下、V:0.10%以下、B:0.0050%以下を含有する鋼がある。また、式1で計算されるCENが0.20~0.85質量%であるものを対象としている。
母材の溶接熱影響部(HAZ)で溶接割れを生じないようにするために、CENの上限を0.85質量%とする。より確実にHAZ部での溶接割れを防止するために、CENの上限を0.80質量%、0.75質量%、0.73質量%、0.70質量%、0.68質量%、0.65質量%、0.63質量%又は0.60質量%としてもよい。母材の硬さをHV380以上とするために、CENの下限を0.20質量%とする。母材の硬さを高めるため、CENの下限を0.24質量%、0.28質量%、0.30質量%、0.32質量%、0.35質量%又は0.38質量%としてもよい。母材の硬さがHV565以下の鋼板は一般的にCENが0.75質量%を超えることは少ないため、母材の硬さがHV565以下の鋼板のCENの上限を0.75質量%とする。
母材の硬さの測定方法は、母材の板厚方向断面の表面下1mmの位置のビッカース硬さを5点以上測定し、平均値を求める方法とする。 As a steel plate used as a base material, a high-hardness thick steel plate having a C content of 0.120% or more and 0.450% or less and HV380 or more and HV693 or less in mass% is an object.
As the plate thickness of the steel plate to be used, the thickness of 6 mm or more and 100 mm or less, which is generally referred to as a thick plate, is targeted.
Steel sheets satisfying such conditions are widely used in places where wear resistance is required, such as machinery for civil engineering and construction work, and there is no particular limitation on the chemical composition other than the C content. For example,
C: 0.120 to 3.000%, Si: 0.10 to 0.55%, Mn: 0.20 to 2.00%, Al: 0.01 to 0.10%, P: 0.020% Hereinafter, S: 0.015% or less, Cu: 0.50% or less, Ni: 1.00% or less, Cr: 1.20% or less, Mo: 0.60% or less, Nb: 0.05% or less, There is steel containing V: 0.10% or less and B: 0.0050% or less. Further, the CEN calculated by the
In order to prevent weld cracks from occurring in the weld heat affected zone (HAZ) of the base metal, the upper limit of CEN is set to 0.85% by mass. In order to prevent weld cracking in the HAZ part more reliably, the upper limit of CEN is 0.80 mass%, 0.75 mass%, 0.73 mass%, 0.70 mass%, 0.68 mass%, 0 It is good also as .65 mass%, 0.63 mass%, or 0.60 mass%. In order to make the hardness of the base material HV380 or more, the lower limit of CEN is 0.20% by mass. In order to increase the hardness of the base material, the lower limit of CEN may be 0.24 mass%, 0.28 mass%, 0.30 mass%, 0.32 mass%, 0.35 mass% or 0.38 mass%. Good. A steel sheet having a base metal hardness of HV565 or less generally has a CEN of less than 0.75% by mass. Therefore, the upper limit of the CEN of a steel sheet having a base metal hardness of HV565 or less is set to 0.75% by mass. .
The method for measuring the hardness of the base material is a method in which five or more Vickers hardnesses at a
最初に、ワイヤの鋼製外皮の内部に挿入されるフラックス成分について説明する。 Subsequently, the flux-cored welding wire to be used will be described separately for the flux component and the alloy component. In addition, content of the component in description about a flux cored welding wire represents the mass% with respect to the total mass of a flux cored welding wire.
First, the flux component inserted into the inside of the steel outer sheath of the wire will be described.
この効果を得るには、含有するCaF2、BaF2、SrF2、MgF2の合計量をαとしたとき、合計量αがフラックス入りワイヤの全質量に対する質量%で3.3%以上、8.0%以下であること、また含有するTi酸化物、Si酸化物、Mg酸化物、Al酸化物の合計量をβとしたとき、合計量βがフラックス入りワイヤの全質量に対する質量%で0.10%以上、1.50%以下であること、さらに上記αに対する上記CaF2の含有量の比が0.90以上であり、上記合計量βに対する上記合計量αの比([合計量α]/[合計量β])が3.0以上、80.0以下であることが要件となる。 One or more metal fluorides of CaF 2 , BaF 2 , SrF 2 , MgF 2 , Ti oxide (eg TiO 2 ), Si oxide (eg SiO 2 ), Mg oxide (eg MgO), By containing a certain amount of one or more metal oxides of Al oxide (for example, Al 2 O 3 ) in the welding wire and keeping the ratio of the fluoride and oxide within a certain range. The amount of diffusible hydrogen in the weld metal can be stably reduced to less than 1.0 ml / 100 g.
In order to obtain this effect, when the total amount of CaF 2 , BaF 2 , SrF 2 and MgF 2 to be contained is α, the total amount α is 3.3% or more by mass% with respect to the total mass of the flux-cored wire, 8 0.0% or less, and when the total amount of Ti oxide, Si oxide, Mg oxide and Al oxide contained is β, the total amount β is 0% by mass with respect to the total mass of the flux-cored wire. The ratio of the CaF 2 content to the α is 0.90 or more, and the ratio of the total amount α to the total amount β ([total amount α ] / [Total amount β]) is 3.0 or more and 80.0 or less.
さらに、上記合計量βに対する上記合計量αの比が3.0未満では、溶接金属中の拡散性水素量を安定して1.0ml/100g未満とすることができず、80.0超では、溶接ヒューム、スラグが過剰に生成するため、溶接作業性が著しく低下し、好ましくない。溶接金属中の拡散性水素量をより低減するために、上記比([合計量α]/[合計量β])の下限を3.2、3.5、3.7又は4.0にしてもよい。溶接ヒュームやスラグの過剰生成などを回避するために、上記比([合計量α]/[合計量β])の上限を40.0、30.0、20.0、15.0又は13.0としてもよい。αに対するCaF2の含有量の比が0.90未満である場合、溶接金属中の拡散性水素量を1.0ml/100g未満とすることができなくなる。何故なら、CaF2は、金属弗化物の中で最も拡散性水素量を低減させる効果が大きいからである。αに対するCaF2の含有量の比が最大となるのは、フラックス中にCaF2以外の金属弗化物が含まれない場合である。従って、αに対するCaF2の含有量の比の上限値は1.0である。 If the total amount α of the metal fluoride contained is less than 3.3%, the amount of diffusible hydrogen in the weld metal cannot be stably reduced to less than 1.0 ml / 100 g. In order to further reduce the amount of diffusible hydrogen in the weld metal, the lower limit of the total amount α may be 3.5%, 3.7%, or 3.9%. On the other hand, if it exceeds 8.0%, welding fume and slag are excessively generated, so that welding workability is remarkably lowered, which is not preferable. In order to avoid excessive formation of welding fume and slag, the upper limit of the total amount α may be 7.5%, 7.0%, 6.5%, 6.0%, or 5.7%. If the total amount β of the metal oxides contained is less than 0.10%, the shape of the weld bead may be deteriorated, and if it exceeds 1.50%, the toughness may be lowered. In order to improve the shape of the weld bead, the lower limit of the total amount β may be 0.20%, 0.30%, 0.40%, or 0.50%. In order to improve toughness, the upper limit of the total amount β may be 1.30%, 1.20%, 1.10%, 1.00%, 0.90%, or 0.80%.
Further, if the ratio of the total amount α to the total amount β is less than 3.0, the amount of diffusible hydrogen in the weld metal cannot be stably reduced to less than 1.0 ml / 100 g, and if it exceeds 80.0 Since welding fume and slag are excessively generated, welding workability is remarkably lowered, which is not preferable. In order to further reduce the amount of diffusible hydrogen in the weld metal, the lower limit of the ratio ([total amount α] / [total amount β]) is set to 3.2, 3.5, 3.7, or 4.0. Also good. In order to avoid excessive generation of welding fume and slag, the upper limit of the ratio ([total amount α] / [total amount β]) is set to 40.0, 30.0, 20.0, 15.0 or 13. It may be 0. When the ratio of the content of CaF 2 to α is less than 0.90, the amount of diffusible hydrogen in the weld metal cannot be made less than 1.0 ml / 100 g. This is because CaF 2 has the greatest effect of reducing the amount of diffusible hydrogen among metal fluorides. The ratio of the content of CaF 2 with respect to α is maximized when no metal fluoride other than CaF 2 is contained in the flux. Therefore, the upper limit of the ratio of the content of CaF 2 to α is 1.0.
なお、上記合計量βは、フラックス入りワイヤ中の含有量であり、フラックスの造粒に使用されるバインダー(SiO2を主成分とする水ガラス)などに含まれるものも合計した含有量とする。 From the above, the ratio of the total amount α of metal fluoride to the total amount α of metal fluoride, the total amount β of metal oxide, and the total amount β of metal oxide is limited as described above.
The total amount β is the content in the flux-cored wire, and the total content is also included in binders (water glass containing SiO 2 as a main component) used for flux granulation. .
フラックス入りワイヤ中のC含有量が0.010%未満であると、溶接金属のC含有量が0.100%未満になって溶接金属の硬さがHV337未満になるので、フラックス入りワイヤ中のC含有量は0.010%以上とする。さらにフラックス入りワイヤ中のC含有量が0.060%未満であると、溶接金属のC含有量が0.120%未満になって溶接金属の硬さがHV380未満になるので、溶接金属の硬さをHV380とするためには、フラックス入りワイヤ中のC含有量は0.060%以上とする。溶接金属の硬さの向上のために、C含有量の下限値を0.020%または0.030%としてもよい。溶接金属の硬さのさらなる向上のために、C含有量の下限を0.070%、0.080%、0.090%、0.100%又は0.110%としてもよい。フラックス入りワイヤ中のC含有量が0.350%を超えると、溶接金属のC含有量が0.250%を超えてしまうので、フラックス入りワイヤ中のC含有量は0.350%以下とする。溶接金属の耐低温割れ性の改善のため、C含有量の上限を0.300%、0.250%、0.180%、0.170%又は0.160%としてもよい。 (C: When the average
If the C content in the flux-cored wire is less than 0.010%, the C content in the weld metal is less than 0.100% and the hardness of the weld metal is less than HV337. The C content is 0.010% or more. Furthermore, if the C content in the flux-cored wire is less than 0.060%, the C content of the weld metal is less than 0.120% and the hardness of the weld metal is less than HV380. In order to set the thickness to HV380, the C content in the flux-cored wire is set to 0.060% or more. In order to improve the hardness of the weld metal, the lower limit value of the C content may be 0.020% or 0.030%. In order to further improve the hardness of the weld metal, the lower limit of the C content may be 0.070%, 0.080%, 0.090%, 0.100%, or 0.110%. If the C content in the flux-cored wire exceeds 0.350%, the C content in the weld metal exceeds 0.250%, so the C content in the flux-cored wire is 0.350% or less. . In order to improve the cold cracking resistance of the weld metal, the upper limit of the C content may be 0.300%, 0.250%, 0.180%, 0.170%, or 0.160%.
フラックス入りワイヤ中のSi含有量が0.05%未満であると、溶接金属のSi含有量が0.05%未満になるので、フラックス入りワイヤ中のSi含有量は0.05%以上とする。溶接金属中のO含有量の低減のため、Si含有量の下限を0.10%、0.20%、0.30%又は0.40%としてもよい。フラックス入りワイヤ中のSi含有量が1.80%を超えると、酸化消耗を考慮しても溶接金属のSi量が0.80%を超えてしまうので、フラックス入りワイヤ中のSi含有量は1.80%以下とする。溶接金属の靭性改善のため、Si含有量の上限を1.50%、1.20%、1.00%、0.80%又は0.60%としてもよい。 (Si: 0.05-1.80%)
If the Si content in the flux-cored wire is less than 0.05%, the Si content in the weld metal is less than 0.05%, so the Si content in the flux-cored wire is 0.05% or more. . In order to reduce the O content in the weld metal, the lower limit of the Si content may be 0.10%, 0.20%, 0.30%, or 0.40%. If the Si content in the flux-cored wire exceeds 1.80%, the Si content in the weld metal exceeds 0.80% even if oxidation consumption is taken into consideration, so the Si content in the flux-cored wire is 1 80% or less. In order to improve the toughness of the weld metal, the upper limit of the Si content may be 1.50%, 1.20%, 1.00%, 0.80%, or 0.60%.
フラックス入りワイヤ中のMn含有量が0.50%未満であると、溶接金属のMn含有量が0.20%未満になるので、フラックス入りワイヤ中のMn含有量は0.50%以上とする。溶接金属の硬さの向上のため、Mn含有量の下限を0.70%、0.80%、0.90%、1.00%又は1.10%としてもよい。フラックス入りワイヤ中のMn含有量が4.00%を超えると、酸化消耗を考慮しても溶接金属のMn量が2.50%を超えてしまうので、フラックス入りワイヤ中のMn量は4.00%以下とする。溶接金属の靭性改善のため、Mn含有量の上限を3.00%、2.50%、2.20%、2.00%又は1.80%としてもよい。 (Mn: 0.50 to 4.00%)
If the Mn content in the flux-cored wire is less than 0.50%, the Mn content in the weld metal is less than 0.20%, so the Mn content in the flux-cored wire is 0.50% or more. . In order to improve the hardness of the weld metal, the lower limit of the Mn content may be 0.70%, 0.80%, 0.90%, 1.00%, or 1.10%. If the Mn content in the flux-cored wire exceeds 4.00%, the Mn content of the weld metal exceeds 2.50% even if oxidation consumption is taken into consideration, so the Mn content in the flux-cored wire is 4. 00% or less. In order to improve the toughness of the weld metal, the upper limit of the Mn content may be 3.00%, 2.50%, 2.20%, 2.00%, or 1.80%.
フラックス入りワイヤ中のP含有量が0.050%を超えると、溶接金属のP含有量が0.050%を超えてしまうことがあるので、フラックス入りワイヤ中のP含有量は0.050%以下とする。必要に応じて、P含有量の上限を0.030%、0.025%、0.020%又は0.015%に制限してもよい。P含有量の下限を制限する必要はない。P含有量の下限は0%である。 (P: 0.050% or less)
If the P content in the flux-cored wire exceeds 0.050%, the P content in the weld metal may exceed 0.050%, so the P content in the flux-cored wire is 0.050%. The following. If necessary, the upper limit of the P content may be limited to 0.030%, 0.025%, 0.020%, or 0.015%. There is no need to limit the lower limit of the P content. The lower limit of the P content is 0%.
フラックス入りワイヤ中のS含有量が0.020%を超えると、溶接金属のS含有量が0.020%を超えてしまうことがあるので、フラックス入りワイヤ中のS含有量は0.020%以下とする。必要に応じて、S含有量の上限を0.015%、0.010%、0.008%又は0.006%に制限してもよい。S含有量の下限を制限する必要はない。S含有量の下限は0%である。 (S: 0.020% or less)
If the S content in the flux-cored wire exceeds 0.020%, the S content in the weld metal may exceed 0.020%, so the S content in the flux-cored wire is 0.020%. The following. If necessary, the upper limit of the S content may be limited to 0.015%, 0.010%, 0.008%, or 0.006%. There is no need to limit the lower limit of the S content. The lower limit of the S content is 0%.
フラックス入りワイヤ中のAl含有量が0.005%未満であると、溶接金属のAl含有量が0.005%未満になるので、フラックス入りワイヤ中のAl含有量は0.005%以上とする。溶接金属中のO含有量の一層の低減のため、Al含有量の下限を0.007%、0.010%又は0.012%としてもよい。フラックス入りワイヤ中のAl含有量が0.150%を超えると、溶接金属のAl含有量が0.100%を超えてしまうことがあるので、フラックス入りワイヤ中のAl含有量は0.150%以下とする。溶接金属の靭性改善のため、Al含有量の上限を0.090%、0.070%、0.050%又は0.040%に制限してもよい。 (Al: 0.005 to 0.150%)
If the Al content in the flux-cored wire is less than 0.005%, the Al content in the weld metal is less than 0.005%, so the Al content in the flux-cored wire is 0.005% or more. . In order to further reduce the O content in the weld metal, the lower limit of the Al content may be 0.007%, 0.010%, or 0.012%. If the Al content in the flux cored wire exceeds 0.150%, the Al content in the weld metal may exceed 0.100%, so the Al content in the flux cored wire is 0.150%. The following. In order to improve the toughness of the weld metal, the upper limit of the Al content may be limited to 0.090%, 0.070%, 0.050%, or 0.040%.
フラックス入りワイヤ中のCu含有量が0.75%を超えると、溶接金属のCu含有量が0.50%を超えてしまうので、フラックス入りワイヤ中のCu含有量は0.75%以下とする。溶接金属のCu含有量を低減するために、Cu含有量を0.50%以下としてもよい。必要に応じて、Cu含有量の上限を0.40%又は0.30%としてもよい。Cu含有量の下限を制限しなくてもよい。このため、Cu含有量の下限は0%である。一方、溶接金属の硬さを向上させるために、溶接金属にCuを0.10%以上含有させてもよい。 (Cu: 0 to 0.75% or less)
If the Cu content in the flux-cored wire exceeds 0.75%, the Cu content in the weld metal exceeds 0.50%, so the Cu content in the flux-cored wire is 0.75% or less. . In order to reduce the Cu content of the weld metal, the Cu content may be 0.50% or less. If necessary, the upper limit of Cu content may be 0.40% or 0.30%. There is no need to limit the lower limit of the Cu content. For this reason, the minimum of Cu content is 0%. On the other hand, in order to improve the hardness of the weld metal, the weld metal may contain 0.10% or more of Cu.
フラックス入りワイヤ中のNi含有量が1.00%以上であると、溶接金属のNi含有量が0.70%以上となり、ワイヤの合金コストが高くなるので、フラックス入りワイヤ中のNi含有量は1.00%未満とする。溶接金属の凝固割れの防止のため、Ni含有量の上限を、0.50%、0.40%、0.30%、0.20%又は0.10%としてもよい。Ni含有量の下限を制限しなくてもよい。このため、Ni含有量の下限は0%である。 (Ni: 0 to less than 1.00%)
When the Ni content in the flux-cored wire is 1.00% or more, the Ni content of the weld metal is 0.70% or more, and the alloy cost of the wire becomes high. Therefore, the Ni content in the flux-cored wire is Less than 1.00%. In order to prevent solidification cracking of the weld metal, the upper limit of the Ni content may be 0.50%, 0.40%, 0.30%, 0.20%, or 0.10%. There is no need to limit the lower limit of the Ni content. For this reason, the lower limit of the Ni content is 0%.
フラックス入りワイヤ中のCr含有量が3.50%を超えると、溶接金属のCr含有量が2.50%を超えてしまうので、フラックス入りワイヤ中のCr含有量は3.50%以下とする。必要に応じて、Cr含有量の上限を1.50%、1.00%、0.50%又は0.10%としてもよい。Cr含有量の下限を制限しなくてもよい。このため、Cr含有量の下限は0%である。一方、溶接金属の硬さ向上の目的で添加する場合には、その効果を得るために0.05%以上含有させてもよい。 (Cr: 0 to 3.50%)
If the Cr content in the flux-cored wire exceeds 3.50%, the Cr content in the weld metal exceeds 2.50%, so the Cr content in the flux-cored wire is 3.50% or less. . If necessary, the upper limit of the Cr content may be 1.50%, 1.00%, 0.50%, or 0.10%. There is no need to limit the lower limit of the Cr content. For this reason, the lower limit of the Cr content is 0%. On the other hand, when added for the purpose of improving the hardness of the weld metal, 0.05% or more may be contained in order to obtain the effect.
フラックス入りワイヤ中のMo含有量が1.50%を超えると、溶接金属のMo含有量が1.00%を超えてしまうので、フラックス入りワイヤ中のMo含有量は1.50%以下とする。靱性向上のため、Mo含有量の上限を0.70%、0.50%、0.30%又は0.20%としてもよい。Mo含有量の下限を制限しなくてもよい。このため、Mo含有量の下限は0%である。一方、溶接金属の硬さ向上の目的で添加する場合には、その効果を得るために0.05%以上含有させてもよい。 (Mo: 0 to 1.50%)
If the Mo content in the flux-cored wire exceeds 1.50%, the Mo content in the weld metal exceeds 1.00%, so the Mo content in the flux-cored wire is 1.50% or less. . In order to improve toughness, the upper limit of the Mo content may be 0.70%, 0.50%, 0.30%, or 0.20%. There is no need to limit the lower limit of the Mo content. For this reason, the lower limit of the Mo content is 0%. On the other hand, when added for the purpose of improving the hardness of the weld metal, 0.05% or more may be contained in order to obtain the effect.
フラックス入りワイヤ中のTi含有量が0.150%を超えると、溶接金属のTi含有量が0.100%を超えてしまうので、フラックス入りワイヤ中のTi含有量は0.150%以下とする。靱性向上のため、Ti含有量の上限を0.100%、0.080%又は0.050%としてもよい。Ti含有量の下限を制限しなくてもよい。このため、Ti含有量の下限は0%である。靱性改善の目的に、0.010%以上含有させてもよい。 (Ti: 0 to 0.150%)
If the Ti content in the flux-cored wire exceeds 0.150%, the Ti content of the weld metal exceeds 0.100%, so the Ti content in the flux-cored wire is 0.150% or less. . In order to improve toughness, the upper limit of the Ti content may be 0.100%, 0.080%, or 0.050%. There is no need to limit the lower limit of the Ti content. For this reason, the lower limit of the Ti content is 0%. You may make it contain 0.010% or more for the purpose of toughness improvement.
フラックス入りワイヤ中のNb含有量が0.15%を超えると、溶接金属のNb含有量が0.10%を超えてしまうので、フラックス入りワイヤ中のNb含有量は0.15%以下とする。靱性向上のため、Nb含有量の上限を0.10%、0.08%又は0.05%としてもよい。Nb含有量の下限を制限しなくてもよい。このため、Nb含有量の下限は0%である。溶接金属の硬さ向上の目的で0.01%以上含有させてもよい。 (Nb: 0 to 0.15%)
If the Nb content in the flux-cored wire exceeds 0.15%, the Nb content in the weld metal exceeds 0.10%, so the Nb content in the flux-cored wire is 0.15% or less. . In order to improve toughness, the upper limit of the Nb content may be 0.10%, 0.08%, or 0.05%. There is no need to limit the lower limit of the Nb content. For this reason, the lower limit of the Nb content is 0%. You may make it contain 0.01% or more for the purpose of the hardness improvement of a weld metal.
フラックス入りワイヤ中のV含有量が0.45%を超えると、溶接金属のV含有量が0.30%を超えてしまうので、フラックス入りワイヤ中のV含有量は0.45%以下とする。靭性向上のため、V含有量の上限を0.25%、0.20%又は0.15%としてもよい。V含有量の下限を制限しなくてもよい。このため、V含有量の下限は0%である。溶接金属の硬さ向上のために0.01%以上含有させてもよい。 (V: 0 to 0.45%)
If the V content in the flux-cored wire exceeds 0.45%, the V content in the weld metal exceeds 0.30%, so the V content in the flux-cored wire is 0.45% or less. . In order to improve toughness, the upper limit of the V content may be 0.25%, 0.20%, or 0.15%. There is no need to limit the lower limit of the V content. For this reason, the lower limit of the V content is 0%. You may make it contain 0.01% or more for the hardness improvement of a weld metal.
フラックス入りワイヤ中のB含有量が0.0500%を超えると、溶接金属のB含有量が0.0100%を超えてしまうので、フラックス入りワイヤ中のB含有量は0.0500%以下とする。靭性の向上のため、B含有量の上限を0.0400%、0.0200%、0.0100%又は0.0050%としてもよい。B含有量の下限を制限する必要はなく、B含有量の下限は0%である。 (B: 0-0.0500%)
If the B content in the flux-cored wire exceeds 0.0500%, the B content in the weld metal exceeds 0.0100%, so the B content in the flux-cored wire is 0.0500% or less. . In order to improve toughness, the upper limit of the B content may be 0.0400%, 0.0200%, 0.0100%, or 0.0050%. There is no need to limit the lower limit of the B content, and the lower limit of the B content is 0%.
フラックス入りワイヤ中のMg含有量が2.0%を超えると、溶接金属のMg含有量が0.10%を超えてしまうので、フラックス入りワイヤ中のMg含有量は2.0%以下とする。溶接金属の靭性と延性の改善のため、Mg含有量の上限を1.5%、1.0%、0.4%又は0.2%としてもよい。Mg含有量の下限を制限する必要はなく、Mg含有量の下限は0%である。 (Mg: 0-2.0%)
If the Mg content in the flux-cored wire exceeds 2.0%, the Mg content in the weld metal exceeds 0.10%, so the Mg content in the flux-cored wire is 2.0% or less. . In order to improve the toughness and ductility of the weld metal, the upper limit of the Mg content may be 1.5%, 1.0%, 0.4%, or 0.2%. There is no need to limit the lower limit of the Mg content, and the lower limit of the Mg content is 0%.
フラックス入りワイヤ中のCa含有量が2.0%を超えると、溶接金属のCa含有量が0.10%を超えてしまうので、フラックス入りワイヤ中のCa含有量は2.0%以下とする。溶接金属の靭性と延性の改善のため、Ca含有量の上限を1.5%、1.0%、0.5%又は0.3%としてもよい。Ca含有量の下限を制限する必要はなく、Ca含有量の下限は0%である。 (Ca: 0 to 2.0%)
If the Ca content in the flux-cored wire exceeds 2.0%, the Ca content in the weld metal exceeds 0.10%, so the Ca content in the flux-cored wire is 2.0% or less. . In order to improve the toughness and ductility of the weld metal, the upper limit of the Ca content may be 1.5%, 1.0%, 0.5%, or 0.3%. There is no need to limit the lower limit of the Ca content, and the lower limit of the Ca content is 0%.
フラックス入りワイヤ中のREM含有量が0.0150%を超えると、溶接金属のREM含有量が0.0100%を超えてしまうので、フラックス入りワイヤ中のREM含有量は0.0150%以下とする。溶接金属の靭性と延性の改善のため、REM含有量の上限を0.0100%、0.0050%又は0.0030%としてもよい。REM含有量の下限を制限する必要はなく、REM含有量の下限は0%である。 (REM: 0-0.0150%)
If the REM content in the flux-cored wire exceeds 0.0150%, the REM content in the weld metal exceeds 0.0100%, so the REM content in the flux-cored wire is 0.0150% or less. . In order to improve the toughness and ductility of the weld metal, the upper limit of the REM content may be 0.0100%, 0.0050%, or 0.0030%. There is no need to limit the lower limit of the REM content, and the lower limit of the REM content is 0%.
フラックス入りワイヤには、鋼製外皮にスリット状の継目がないシームレスワイヤ(すなわち鋼製外皮の継目が溶接されているワイヤ)と、鋼製外皮の継目にスリット状の隙間を有するシームを有するワイヤとに大別できる。本発明ではいずれの断面構造も採用することができるが、溶接金属の低温割れを抑制するためには、スリット状の継ぎ目がない(シームレスワイヤ)とすることが好ましい。 Subsequently, the form of the flux-cored wire will be described.
A flux-cored wire includes a seamless wire without a slit-like seam in the steel outer shell (that is, a wire in which the steel outer seam is welded), and a wire having a seam with a slit-like gap at the steel outer seam. And can be broadly divided. In the present invention, any cross-sectional structure can be adopted, but it is preferable that there is no slit-like seam (seamless wire) in order to suppress cold cracking of the weld metal.
また、ワイヤの送給性をよくするため、ワイヤ表面に潤滑油が塗布される場合がある。拡散性水素を低減する観点から、ワイヤ表面に塗布される潤滑油は、パーフルオロポリエーテル(PFPE)油のように水素分を含まない油が好ましい。 For this reason, it is desirable to make the steel outer shell into a slit-like seamless (seamless) pipe, and to suppress the invasion of hydrogen in the atmosphere from the steel outer shell to the flux after the wire is manufactured and used. . In the case of a pipe with a slit-like seam (having a seam) in the steel outer skin, moisture in the atmosphere easily enters the flux from the slit-like seam (seam part) of the outer skin, and as it is, hydrogen such as moisture Source intrusion cannot be prevented. Therefore, when the period until use after production is long, the entire wire is preferably vacuum-packed or stored in a container that can be kept dry.
Further, in order to improve the wire feedability, lubricating oil may be applied to the wire surface. From the viewpoint of reducing diffusible hydrogen, the lubricating oil applied to the wire surface is preferably an oil that does not contain hydrogen, such as perfluoropolyether (PFPE) oil.
すなわち、まず、外皮となる鋼帯、及び、金属弗化物、合金成分、金属酸化物、金属炭酸塩及びアーク安定剤が所定の含有量になるように配合したフラックスを準備する。鋼帯を長手方向に送りながら成形ロールによりオープン管(U字型)に成形して鋼製外皮とし、この成形途中でオープン管の開口部からフラックスを供給し、開口部の相対するエッジ面を突合せシーム溶接する。溶接により得られた継目無し管を伸線し、伸線途中あるいは伸線工程完了後に焼鈍処理して、所望の線径を有するスリット状の継ぎ目がない(シームレス)ワイヤを得る。また、スリット状の継目がある(シームを有する)ワイヤは、オープン管の開口部からフラックスを供給した後、シーム溶接をしない継目有りの管とし、それを伸線することで得られる。突合せシーム溶接されて作ったスリット状の隙間が無いワイヤを切断した断面は、図3Aのように見える。この断面は、研磨して、エッチングすれば、溶接跡が観察されるが、エッチングしないと溶接跡は観察されない。そのため、シームレスと呼ぶことがある。溶接学会編「新版 溶接・接合技術入門」(2008年)産報出版、p.111には、シームレスタイプと記載されている。図3Bのように、突合せてから、ろう付けしたり、図3Cのように、かしめてから、ろう付けしても、スリット状の隙間が無いワイヤが得られる。図3B、図3Cにおいて、ろう付けせず、そのままのワイヤは、スリット状の隙間があるワイヤとなる。 The flux cored wire used in the present invention can be manufactured by the same manufacturing process as that of a normal flux cored wire manufacturing method.
That is, first, a steel strip to be an outer skin and a flux containing metal fluoride, an alloy component, a metal oxide, a metal carbonate, and an arc stabilizer are prepared so as to have predetermined contents. While feeding the steel strip in the longitudinal direction, it is formed into an open tube (U-shaped) with a forming roll to form a steel outer shell. During this forming, flux is supplied from the opening of the open tube, and the opposing edge surface of the opening is Butt seam welding. A seamless pipe obtained by welding is drawn and annealed during or after the drawing process to obtain a slit-like seamless (seamless) wire having a desired wire diameter. Further, a wire having a slit-like seam (having a seam) is obtained by supplying a flux from an opening of an open pipe, then forming a pipe with a seam without seam welding, and drawing the wire. A cross section of a wire without slit-like gaps made by butt seam welding looks like FIG. 3A. If this cross section is polished and etched, welding marks are observed, but if not etched, no welding marks are observed. Therefore, it may be called seamless. It is described as “seamless type” in the “New Edition Introduction to Welding and Joining Technology” (2008) Sangyo Shuppan, p.111, edited by the Japan Welding Society. As shown in FIG. 3B, a wire without slit-like gaps can be obtained even after brazing and brazing or brazing as shown in FIG. 3C. In FIG. 3B and FIG. 3C, the wire as it is without brazing becomes a wire having a slit-like gap.
また、電流、電圧などの溶接条件については、例えば電流200~350A、電圧25~35Vなどである。溶接入熱が10~50kJ/cmとなるように、溶接速度を制御してもよい。 In the present invention, for the steel sheet, using a flux-cored wire that meets the above-mentioned conditions, by performing multi-layer welding by gas shield arc welding, and forming a weld metal that meets the above-described conditions, The object can be achieved, and the method of gas shield arc welding is not particularly limited, and a commonly used method can be adopted. For example, as the shielding gas, in addition to 100% CO 2 gas, a mixed gas of Ar gas and 3 to 20 vol% CO 2 gas can be used. The flow rate of the shielding gas can be a normal condition, that is, about 15 to 30 L / min.
The welding conditions such as current and voltage are, for example, a current of 200 to 350 A and a voltage of 25 to 35 V. The welding speed may be controlled so that the welding heat input is 10 to 50 kJ / cm.
表1に示す成分の鋼板を母材として使用した。また、溶接の裏当金には母材と同じ鋼板を使用した。
鋼帯を長手方向に送りながら成形ロールによりオープン管に成形し、この成形途中でオープン管の開口部からフラックスを供給し、開口部の相対するエッジ面を突合わせシーム溶接することでスリット状の継目が無い管とし、造管したワイヤの伸線作業の途中で焼鈍を加え、最終のワイヤ径がφ1.2mmのフラックス入りワイヤを試作した。また、一部は、シーム溶接をしないスリット状の継目がある管とし、それを伸線することで、ワイヤ径がφ1.2mmのフラックス入りワイヤを試作した。スリット状の隙間が有るワイヤの場合、溶接施工するまで、ワイヤ全体を真空包装して乾燥した状態に保持できる容器内に保存した。
試作したフラックス入りワイヤの化学成分の分析は以下のように行った。まず、充填されたフラックスをフラックス入りワイヤから取り出し、フラックス入りワイヤを鋼製外皮とフラックスとに分けた。鋼製外皮の化学成分は、化学分析によって各金属成分の含有量を測定することにより求められた。フラックスの化学成分は以下の手順により行われた。先ずX線回折、及び蛍光X線分析によってフラックスの構成物および成分についての定量評価を行った。この後、浮遊選鉱、及び磁力選鉱などの選鉱法を用いてフラックスをスラグ分と合金分とに分離し、それぞれの化学成分を、化学分析、及びガス分析などを行うことにより分析した。試作したフラックス入りワイヤの化学組成を表2-1-1~表2-2、表3-1-1~表3-2に示す。 Next, the feasibility and effect of the welded joint according to the present embodiment will be described by way of examples.
A steel plate having the components shown in Table 1 was used as a base material. In addition, the same steel plate as the base material was used for the backing metal for welding.
While forming the steel strip in the longitudinal direction, it is formed into an open tube by a forming roll. During this forming, a flux is supplied from the opening of the open tube, and the opposite edge surfaces of the opening are butt-seamed and welded to form a slit. A seamless pipe was used, and annealing was performed in the course of drawing the drawn wire, and a flux-cored wire with a final wire diameter of φ1.2 mm was made as a trial product. A part of the tube was a slit-like pipe that was not seam-welded, and a wire with a wire diameter of φ1.2 mm was prototyped by drawing it. In the case of a wire having a slit-like gap, the entire wire was vacuum-packed and stored in a container that can be kept dry until welding.
The analysis of the chemical composition of the prototype flux cored wire was performed as follows. First, the filled flux was taken out from the flux-cored wire, and the flux-cored wire was divided into a steel outer shell and a flux. The chemical component of the steel outer skin was determined by measuring the content of each metal component by chemical analysis. The chemical composition of the flux was performed according to the following procedure. First, quantitative evaluation of the constituents and components of the flux was performed by X-ray diffraction and fluorescent X-ray analysis. Thereafter, the flux was separated into a slag component and an alloy component using a beneficiation method such as flotation and magnetic beneficiation, and each chemical component was analyzed by performing chemical analysis and gas analysis. Tables 2-1-1 to 2-2 and Tables 3-1-1 to 3-2 show the chemical compositions of the prototype flux cored wires.
ここで、Ti酸化物、Si酸化物、Mg酸化物、Al酸化物は、それぞれTiO2、SiO2、MgO、Al2O3を使用した。表2-2、表2-4において、金属炭酸塩とはCaCO3、BaCO3、SrCO3、MgCO3である。 Using this flux-cored wire, the above base material was abutted at a root gap of 16 mm and a groove angle of 20 °, and using a backing metal, under the welding conditions shown in Tables 4-1-1 to 4-2-3 Welding was performed. The groove surface of the base material and the surface of the backing metal were subjected to buttering with two or more layers and a height of 3 mm or more using a flux-cored wire to be tested.
Here, Ti oxide, Si oxide, Mg oxide, Al oxide, respectively by using the TiO 2, SiO 2, MgO, Al 2 O 3. In Tables 2-2 and 2-4, the metal carbonates are CaCO 3 , BaCO 3 , SrCO 3 , and MgCO 3 .
得られた硬さおよびシャルピー試験の結果を表5-1-3、表5-2-3、表5-2-6に示す。 The chemical composition analysis results of the obtained weld metal are shown in Table 5-1-1, Table 5-1-2, Table 5-2-1, Table 5-2-2, Table 5-2-4, and Table 5-2. Shown in -5. A sample obtained by polishing a cross section perpendicular to the welding direction was taken from this weld metal, measured at 10 points of Vickers hardness at a
The obtained hardness and Charpy test results are shown in Tables 5-1-3, 5-2-3 and 5-2-6.
それぞれの結果を表5-1-3、表5-2-3、表5-2-6に示す。 Moreover, the low temperature crack test and the diffusible hydrogen content measurement test were done to the welded joint obtained by the same welding conditions, respectively. The low-temperature cracking test was conducted at room temperature (25 ° C.) in accordance with JIS Z3158 (y-type weld cracking test method: 1993). The diffusible hydrogen content measurement test was carried out by a gas chromatograph method based on JIS Z3118 (Method for measuring the hydrogen content of steel welds; 2007). This diffusible hydrogen content was less than 1.0 ml / 100 g.
The results are shown in Table 5-1-3, Table 5-2-3, and Table 5-2-6.
一方、表5-2-3、表5-2-6の試験結果に示されるように、比較例101~165の溶接金属は、本発明で規定する要件を満たしていないため、硬さ、靭性、耐低温割れ性、溶接作業性の少なくとも1つ以上が不合格となった。表5-2-1~表5-2-6の比較例における下線の数字は、本発明範囲外であることを示す。 As shown in the test results of Table 5-1-3, the weld metals of Examples 1 to 54, which are examples of the present invention, are all excellent in hardness, toughness, cold crack resistance, and welding workability. there were.
On the other hand, as shown in the test results of Tables 5-2-3 and 5-2-6, the weld metals of Comparative Examples 101 to 165 do not satisfy the requirements specified in the present invention. At least one of cold cracking resistance and welding workability was rejected. The underlined numbers in the comparative examples in Tables 5-2-1 to 5-2-6 indicate that they are outside the scope of the present invention.
Claims (9)
- ビッカース硬さHVが380以上514以下であり、
板厚が20~100mmであり、
Cの含有量が0.120~0.300質量%であり、
下記の式1で計算されるCENが、0.20~0.75質量%である鋼板、
ビッカース硬さHVが514超565以下であり、
板厚が12~100mmであり、
Cの含有量が0.120~0.300質量%であり、
下記の式1で計算されるCENが、0.20~0.75質量%である鋼板、および
ビッカース硬さHVが565超693以下であり、
板厚が6~12mmであり、
Cの含有量が0.350~0.450質量%であり、
下記の式1で計算されるCENが、0.20~0.85質量%である鋼板、
のいずれか一つに対し、鋼製外皮にフラックスが充填されたフラックス入りワイヤを用いて、ガスシールドアーク溶接を行うことにより、溶接継手を製造する方法であって、
(a)前記ガスシールドアーク溶接時に、前記鋼板の温度が10℃以上の場合に予熱作業を行わず、前記鋼板の温度が10℃未満の場合には前記鋼板の温度が10℃以上となるように前記予熱作業を行い、
(b)前記フラックス入りワイヤが、
CaF2、BaF2、SrF2、MgF2のうちの1種以上を含有し、その含有量の合計をαとしたとき、前記αが前記フラックス入りワイヤの全質量に対する質量%で3.3~8.0%であり、
Ti酸化物、Si酸化物、Mg酸化物、Al酸化物のうちの1種以上を含有し、その含有量の合計をβとしたとき、前記βが前記フラックス入りワイヤの全質量に対する質量%で0.10~1.50%であり、
CaCO3、BaCO3、SrCO3、MgCO3の含有量の合計が、前記フラックス入りワイヤの全質量に対する質量%で0.60%未満であり、
前記フラックス中の鉄粉の含有量が、前記フラックス入りワイヤの全質量に対する質量%で10.0%未満であり、
前記αに対する前記CaF2の含有量の比が0.90以上であり、
前記βに対する前記αの比が3.0以上80.0以下であり、
CaOの含有量が、前記フラックス入りワイヤの全質量に対する質量%で0.20%未満であり、
金属弗化物、金属酸化物、および金属炭酸塩を除く、前記フラックス入りワイヤ中の化学成分が、前記フラックス入りワイヤの全質量に対する質量%で:
C:0.010~0.060%未満;
Si:0.05~1.80%;
Mn:0.50~4.00%;
P:0.050%以下;
S:0.020%以下;
Al:0.005~0.150%;
Cu:0~0.75%;
Ni:0~1.00%未満;
Cr:0~3.50%;
Mo:0~1.50%;
Ti:0~0.150%;
Nb:0~0.15%;
V:0~0.45%;
B:0~0.0500%;
Mg:0~2.0%;
Ca:0~2.0%;
REM:0~0.0150%;
残部:Feおよび不純物;
からなり、
(c)前記溶接継手の溶接金属の化学組成が、質量%で:
C:0.100~0.170%;
Si:0.05~0.80%;
Mn:0.20~2.50%;
Al:0.0050~0.1000%;
P:0.050%以下;
S:0.020%以下;
N:0.015%以下;
Cu:0~0.50%;
Ni:0~0.70%未満;
Cr:0~2.50%;
Mo:0~1.00%;
Ti:0~0.100%;
Nb:0~0.100%;
V:0~0.30%;
B:0~0.0100%;
O:0~0.100%;
Mg:0~0.100%;
Ca:0~0.100%;
REM:0~0.0100%;
残部:Feおよび不純物;
からなり、
前記溶接金属の、下記の式1で計算されるCENが、0.20~0.58質量%であり、
前記溶接金属の表面下1mmの平均ビッカース硬さHVが、337~440であり、
上記(a)~(c)の全てを満足する
ことを特徴とする溶接継手の製造方法。
CEN=[C]+(0.75+0.25×tanh(20×([C]-0.12)))×([Si]/24+[Mn]/6+[Cu]/15+[Ni]/20+([Cr]+[Mo]+[Nb]+[V])/5+5×[B]) ・・・(式1)
ただし、[]付元素は、それぞれの元素の含有量(質量%)を表す。 Vickers hardness HV is 380 or more and 514 or less,
The plate thickness is 20-100mm,
The C content is 0.120 to 0.300 mass%,
A steel sheet having a CEN calculated by the following formula 1 of 0.20 to 0.75% by mass,
Vickers hardness HV is more than 514 and less than 565,
The plate thickness is 12-100mm,
The C content is 0.120 to 0.300 mass%,
A steel sheet having a CEN calculated by the following formula 1 of 0.20 to 0.75% by mass, and a Vickers hardness HV of more than 565 and not more than 693,
The plate thickness is 6-12mm,
The C content is 0.350 to 0.450 mass%,
A steel sheet having a CEN calculated by the following formula 1 of 0.20 to 0.85 mass%,
For any one of the above, a method for manufacturing a welded joint by performing gas shielded arc welding using a flux-cored wire filled with a flux in a steel outer shell,
(A) During the gas shielded arc welding, no preheating work is performed when the temperature of the steel plate is 10 ° C. or higher, and when the temperature of the steel plate is lower than 10 ° C., the temperature of the steel plate is 10 ° C. or higher. To perform the pre-heating work,
(B) The flux-cored wire is
When one or more of CaF 2 , BaF 2 , SrF 2 , and MgF 2 are contained and the total content is α, the α is 3.3% by mass% with respect to the total mass of the flux-cored wire. 8.0%,
When one or more of Ti oxide, Si oxide, Mg oxide, and Al oxide is contained, and the total content is β, the β is a mass% with respect to the total mass of the flux-cored wire. 0.10 to 1.50%,
The total content of CaCO 3 , BaCO 3 , SrCO 3 , MgCO 3 is less than 0.60% in mass% with respect to the total mass of the flux-cored wire,
The content of iron powder in the flux is less than 10.0% by mass% with respect to the total mass of the flux-cored wire,
The ratio of the content of CaF 2 to α is 0.90 or more,
The ratio of α to β is 3.0 or more and 80.0 or less,
The content of CaO is less than 0.20% by mass% with respect to the total mass of the flux-cored wire,
The chemical components in the flux-cored wire, excluding metal fluorides, metal oxides, and metal carbonates, in mass% with respect to the total mass of the flux-cored wire:
C: 0.010 to less than 0.060%;
Si: 0.05 to 1.80%;
Mn: 0.50 to 4.00%;
P: 0.050% or less;
S: 0.020% or less;
Al: 0.005 to 0.150%;
Cu: 0 to 0.75%;
Ni: 0 to less than 1.00%;
Cr: 0 to 3.50%;
Mo: 0 to 1.50%;
Ti: 0 to 0.150%;
Nb: 0 to 0.15%;
V: 0 to 0.45%;
B: 0 to 0.0500%;
Mg: 0 to 2.0%;
Ca: 0 to 2.0%;
REM: 0 to 0.0150%;
Balance: Fe and impurities;
Consists of
(C) The chemical composition of the weld metal of the weld joint is in mass%:
C: 0.100 to 0.170%;
Si: 0.05 to 0.80%;
Mn: 0.20 to 2.50%;
Al: 0.0050 to 0.1000%;
P: 0.050% or less;
S: 0.020% or less;
N: 0.015% or less;
Cu: 0 to 0.50%;
Ni: 0 to less than 0.70%;
Cr: 0-2.50%;
Mo: 0 to 1.00%;
Ti: 0 to 0.100%;
Nb: 0 to 0.100%;
V: 0 to 0.30%;
B: 0 to 0.0100%;
O: 0 to 0.100%;
Mg: 0 to 0.100%;
Ca: 0 to 0.100%;
REM: 0 to 0.0100%;
Balance: Fe and impurities;
Consists of
CEN calculated by the following formula 1 of the weld metal is 0.20 to 0.58% by mass,
The average Vickers hardness HV of 1 mm below the surface of the weld metal is 337 to 440,
A method for producing a welded joint satisfying all of the above (a) to (c).
CEN = [C] + (0.75 + 0.25 × tanh (20 × ([C] −0.12))) × ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 × [B]) (Formula 1)
However, the element with [] represents the content (% by mass) of each element. - ビッカース硬さHVが380以上514以下であり、
板厚が20~100mmであり、
Cの含有量が0.120~0.300質量%であり、
下記の式1で計算されるCENが、0.20~0.75質量%である鋼板、
ビッカース硬さHVが514超565以下であり、
板厚が12~100mmであり、
Cの含有量が0.120~0.300質量%であり、
下記の式1で計算されるCENが、0.20~0.75質量%である鋼板、および
ビッカース硬さHVが565超693以下であり、
板厚が6~12mmであり、
Cの含有量が0.350~0.450質量%であり、
下記の式1で計算されるCENが、0.20~0.85質量%である鋼板、
のいずれか一つに対し、鋼製外皮にフラックスが充填されたフラックス入りワイヤを用いて、ガスシールドアーク溶接を行うことにより、溶接継手を製造する方法であって、
(a)前記ガスシールドアーク溶接時に、前記鋼板の温度が10℃以上の場合に予熱作業を行わず、前記鋼板の温度が10℃未満の場合には前記鋼板の温度が10℃以上となるように前記予熱作業を行い、
(b)前記フラックス入りワイヤが、
CaF2、BaF2、SrF2、MgF2のうちの1種以上を含有し、その含有量の合計をαとしたとき、前記αが前記フラックス入りワイヤの全質量に対する質量%で3.3~8.0%であり、
Ti酸化物、Si酸化物、Mg酸化物、Al酸化物のうちの1種以上を含有し、その含有量の合計をβとしたとき、前記βが前記フラックス入りワイヤの全質量に対する質量%で0.10~1.50%であり、
CaCO3、BaCO3、SrCO3、MgCO3の含有量の合計が、前記フラックス入りワイヤの全質量に対する質量%で0.60%未満であり、
前記フラックス中の鉄粉の含有量が、前記フラックス入りワイヤの全質量に対する質量%で10.0%未満であり、
前記αに対する前記CaF2の含有量の比が0.90以上であり、
前記βに対する前記αの比が3.0以上80.0以下であり、
CaOの含有量が、前記フラックス入りワイヤの全質量に対する質量%で0.20%未満であり、
金属弗化物、金属酸化物、および金属炭酸塩を除く、前記フラックス入りワイヤ中の化学成分が、前記フラックス入りワイヤの全質量に対する質量%で:
C:0.060~0.350%;
Si:0.05~1.80%;
Mn:0.50~4.00%;
P:0.050%以下;
S:0.020%以下;
Al:0.005~0.150%;
Cu:0~0.75%;
Ni:0~1.00%未満;
Cr:0~3.50%;
Mo:0~1.50%;
Ti:0~0.150%;
Nb:0~0.15%;
V:0~0.45%;
B:0~0.0500%;
Mg:0~2.0%;
Ca:0~2.0%;
REM:0~0.0150%;
残部:Feおよび不純物;
からなり、
(c)前記溶接継手の溶接金属の化学組成が、質量%で:
C:0.120~0.250%;
Si:0.05~0.80%;
Mn:0.20~2.50%;
Al:0.0050~0.1000%;
P:0.050%以下;
S:0.020%以下;
N:0.015%以下;
Cu:0~0.50%;
Ni:0~0.70%未満;
Cr:0~2.50%;
Mo:0~1.00%;
Ti:0~0.100%;
Nb:0~0.100%;
V:0~0.30%;
B:0~0.0100%;
O:0~0.100%;
Mg:0~0.100%;
Ca:0~0.100%;
REM:0~0.0100%;
残部:Feおよび不純物;
からなり、
前記溶接金属の、下記の式1で計算されるCENが、0.20~0.58質量%であり、
前記溶接金属の表面下1mmの平均ビッカース硬さHVが、380~533であり、
上記(a)~(c)の全てを満足する
ことを特徴とする溶接継手の製造方法。
CEN=[C]+(0.75+0.25×tanh(20×([C]-0.12)))×([Si]/24+[Mn]/6+[Cu]/15+[Ni]/20+([Cr]+[Mo]+[Nb]+[V])/5+5×[B]) ・・・(式1)
ただし、[]付元素は、それぞれの元素の含有量(質量%)を表す。 Vickers hardness HV is 380 or more and 514 or less,
The plate thickness is 20-100mm,
The C content is 0.120 to 0.300 mass%,
A steel sheet having a CEN calculated by the following formula 1 of 0.20 to 0.75% by mass,
Vickers hardness HV is more than 514 and less than 565,
The plate thickness is 12-100mm,
The C content is 0.120 to 0.300 mass%,
A steel sheet having a CEN calculated by the following formula 1 of 0.20 to 0.75% by mass, and a Vickers hardness HV of more than 565 and not more than 693,
The plate thickness is 6-12mm,
The C content is 0.350 to 0.450 mass%,
A steel sheet having a CEN calculated by the following formula 1 of 0.20 to 0.85 mass%,
For any one of the above, a method for manufacturing a welded joint by performing gas shielded arc welding using a flux-cored wire filled with a flux in a steel outer shell,
(A) During the gas shielded arc welding, no preheating work is performed when the temperature of the steel plate is 10 ° C. or higher, and when the temperature of the steel plate is lower than 10 ° C., the temperature of the steel plate is 10 ° C. or higher. To perform the pre-heating work,
(B) The flux-cored wire is
When one or more of CaF 2 , BaF 2 , SrF 2 , and MgF 2 are contained and the total content is α, the α is 3.3% by mass% with respect to the total mass of the flux-cored wire. 8.0%,
When one or more of Ti oxide, Si oxide, Mg oxide, and Al oxide is contained, and the total content is β, the β is a mass% with respect to the total mass of the flux-cored wire. 0.10 to 1.50%,
The total content of CaCO 3 , BaCO 3 , SrCO 3 , MgCO 3 is less than 0.60% in mass% with respect to the total mass of the flux-cored wire,
The content of iron powder in the flux is less than 10.0% by mass% with respect to the total mass of the flux-cored wire,
The ratio of the content of CaF 2 to α is 0.90 or more,
The ratio of α to β is 3.0 or more and 80.0 or less,
The content of CaO is less than 0.20% by mass% with respect to the total mass of the flux-cored wire,
The chemical components in the flux-cored wire, excluding metal fluorides, metal oxides, and metal carbonates, in mass% with respect to the total mass of the flux-cored wire:
C: 0.060 to 0.350%;
Si: 0.05 to 1.80%;
Mn: 0.50 to 4.00%;
P: 0.050% or less;
S: 0.020% or less;
Al: 0.005 to 0.150%;
Cu: 0 to 0.75%;
Ni: 0 to less than 1.00%;
Cr: 0 to 3.50%;
Mo: 0 to 1.50%;
Ti: 0 to 0.150%;
Nb: 0 to 0.15%;
V: 0 to 0.45%;
B: 0 to 0.0500%;
Mg: 0 to 2.0%;
Ca: 0 to 2.0%;
REM: 0 to 0.0150%;
Balance: Fe and impurities;
Consists of
(C) The chemical composition of the weld metal of the weld joint is in mass%:
C: 0.120 to 0.250%;
Si: 0.05 to 0.80%;
Mn: 0.20 to 2.50%;
Al: 0.0050 to 0.1000%;
P: 0.050% or less;
S: 0.020% or less;
N: 0.015% or less;
Cu: 0 to 0.50%;
Ni: 0 to less than 0.70%;
Cr: 0-2.50%;
Mo: 0 to 1.00%;
Ti: 0 to 0.100%;
Nb: 0 to 0.100%;
V: 0 to 0.30%;
B: 0 to 0.0100%;
O: 0 to 0.100%;
Mg: 0 to 0.100%;
Ca: 0 to 0.100%;
REM: 0 to 0.0100%;
Balance: Fe and impurities;
Consists of
CEN calculated by the following formula 1 of the weld metal is 0.20 to 0.58% by mass,
The average Vickers hardness HV of 1 mm below the surface of the weld metal is 380 to 533,
A method for producing a welded joint satisfying all of the above (a) to (c).
CEN = [C] + (0.75 + 0.25 × tanh (20 × ([C] −0.12))) × ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 × [B]) (Formula 1)
However, the element with [] represents the content (% by mass) of each element. - ビッカース硬さHVが565超693以下であり、
板厚が12~20mmであり、
Cの含有量が0.350~0.450質量%であり、
下記の式2で計算されるCENが、0.20~0.85質量%である鋼板、および
ビッカース硬さHVが565超693以下であり、
板厚が20mm超50mm以下であり、
Cの含有量が0.350~0.450質量%であり、
下記の式2で計算されるCENが、0.20~0.85質量%である鋼板、
のいずれか一つに対し、鋼製外皮にフラックスが充填されたフラックス入りワイヤを用いて、ガスシールドアーク溶接を行うことにより、溶接継手を製造する方法であって、
(a)前記ガスシールドアーク溶接時に、前記鋼板の前記板厚が20mm以下の場合、前記鋼板の温度が100℃以上となるように予熱作業を行い、前記鋼板の前記板厚が20mm超の場合、前記鋼板の温度が150℃以上となるように前記予熱作業を行い、
(b)前記フラックス入りワイヤが、
CaF2、BaF2、SrF2、MgF2のうちの1種以上を含有し、その含有量の合計をαとしたとき、前記αが前記フラックス入りワイヤの全質量に対する質量%で3.3~8.0%であり、
Ti酸化物、Si酸化物、Mg酸化物、Al酸化物のうちの1種以上を含有し、その含有量の合計をβとしたとき、前記βが前記フラックス入りワイヤの全質量に対する質量%で0.10~1.50%であり、
CaCO3、BaCO3、SrCO3、MgCO3の含有量の合計が、前記フラックス入りワイヤの全質量に対する質量%で0.60%未満であり、
前記フラックス中の鉄粉の含有量が、前記フラックス入りワイヤの全質量に対する質量%で10.0%未満であり、
前記αに対する前記CaF2の含有量の比が0.90以上であり、
前記βに対する前記αの比が3.0以上80.0以下であり、
CaOの含有量が、前記フラックス入りワイヤの全質量に対する質量%で0.20%未満であり、
金属弗化物、金属酸化物、および金属炭酸塩を除く、前記フラックス入りワイヤ中の化学成分が、前記フラックス入りワイヤの全質量に対する質量%で:
C:0.060~0.350%;
Si:0.05~1.80%;
Mn:0.50~4.00%;
P:0.050%以下;
S:0.020%以下;
Al:0.005~0.150%;
Cu:0~0.75%;
Ni:0~1.00%未満;
Cr:0~3.50%;
Mo:0~1.50%;
Ti:0~0.150%;
Nb:0~0.15%;
V:0~0.45%;
B:0~0.0500%;
Mg:0~2.0%;
Ca:0~2.0%;
REM:0~0.0150%;
残部:Feおよび不純物;
からなり、
(c)前記溶接継手の溶接金属の化学組成が、質量%で:
C:0.120~0.250%;
Si:0.05~0.80%;
Mn:0.20~2.50%;
Al:0.0050~0.1000%;
P:0.050%以下;
S:0.020%以下;
N:0.015%以下;
Cu:0~0.50%;
Ni:0~0.70%未満;
Cr:0~2.50%;
Mo:0~1.00%;
Ti:0~0.100%;
Nb:0~0.100%;
V:0~0.30%;
B:0~0.0100%;
O:0~0.100%;
Mg:0~0.100%;
Ca:0~0.100%;
REM:0~0.0100%;
残部:Feおよび不純物;
からなり、
前記溶接金属の、下記の式2で計算されるCENが、0.20~0.58質量%であり、
前記溶接金属の表面下1mmの平均ビッカース硬さHVが、380~533であり、
上記(a)~(c)の全てを満足する
ことを特徴とする溶接継手の製造方法。
CEN=[C]+(0.75+0.25×tanh(20×([C]-0.12)))×([Si]/24+[Mn]/6+[Cu]/15+[Ni]/20+([Cr]+[Mo]+[Nb]+[V])/5+5×[B]) ・・・(式2)
ただし、[]付元素は、それぞれの元素の含有量(質量%)を表す。 Vickers hardness HV is more than 565 and less than 693,
The plate thickness is 12-20mm,
The C content is 0.350 to 0.450 mass%,
A steel sheet having a CEN calculated by the following formula 2 of 0.20 to 0.85 mass%, and a Vickers hardness HV of more than 565 and not more than 693,
The plate thickness is more than 20 mm and 50 mm or less,
The C content is 0.350 to 0.450 mass%,
A steel sheet having a CEN calculated by the following formula 2 of 0.20 to 0.85 mass%,
For any one of the above, a method for manufacturing a welded joint by performing gas shielded arc welding using a flux-cored wire filled with a flux in a steel outer shell,
(A) At the time of the gas shield arc welding, when the plate thickness of the steel plate is 20 mm or less, a preheating operation is performed so that the temperature of the steel plate is 100 ° C. or more, and the plate thickness of the steel plate is more than 20 mm The preheating operation is performed so that the temperature of the steel sheet is 150 ° C. or higher,
(B) The flux-cored wire is
When one or more of CaF 2 , BaF 2 , SrF 2 , and MgF 2 are contained and the total content is α, the α is 3.3% by mass% with respect to the total mass of the flux-cored wire. 8.0%,
When one or more of Ti oxide, Si oxide, Mg oxide, and Al oxide is contained, and the total content is β, the β is a mass% with respect to the total mass of the flux-cored wire. 0.10 to 1.50%,
The total content of CaCO 3 , BaCO 3 , SrCO 3 , MgCO 3 is less than 0.60% in mass% with respect to the total mass of the flux-cored wire,
The content of iron powder in the flux is less than 10.0% by mass% with respect to the total mass of the flux-cored wire,
The ratio of the content of CaF 2 to α is 0.90 or more,
The ratio of α to β is 3.0 or more and 80.0 or less,
The content of CaO is less than 0.20% by mass% with respect to the total mass of the flux-cored wire,
The chemical components in the flux-cored wire, excluding metal fluorides, metal oxides, and metal carbonates, in mass% with respect to the total mass of the flux-cored wire:
C: 0.060 to 0.350%;
Si: 0.05 to 1.80%;
Mn: 0.50 to 4.00%;
P: 0.050% or less;
S: 0.020% or less;
Al: 0.005 to 0.150%;
Cu: 0 to 0.75%;
Ni: 0 to less than 1.00%;
Cr: 0 to 3.50%;
Mo: 0 to 1.50%;
Ti: 0 to 0.150%;
Nb: 0 to 0.15%;
V: 0 to 0.45%;
B: 0 to 0.0500%;
Mg: 0 to 2.0%;
Ca: 0 to 2.0%;
REM: 0 to 0.0150%;
Balance: Fe and impurities;
Consists of
(C) The chemical composition of the weld metal of the weld joint is in mass%:
C: 0.120 to 0.250%;
Si: 0.05 to 0.80%;
Mn: 0.20 to 2.50%;
Al: 0.0050 to 0.1000%;
P: 0.050% or less;
S: 0.020% or less;
N: 0.015% or less;
Cu: 0 to 0.50%;
Ni: 0 to less than 0.70%;
Cr: 0-2.50%;
Mo: 0 to 1.00%;
Ti: 0 to 0.100%;
Nb: 0 to 0.100%;
V: 0 to 0.30%;
B: 0 to 0.0100%;
O: 0 to 0.100%;
Mg: 0 to 0.100%;
Ca: 0 to 0.100%;
REM: 0 to 0.0100%;
Balance: Fe and impurities;
Consists of
CEN calculated by the following formula 2 of the weld metal is 0.20 to 0.58% by mass,
The average Vickers hardness HV of 1 mm below the surface of the weld metal is 380 to 533,
A method for producing a welded joint satisfying all of the above (a) to (c).
CEN = [C] + (0.75 + 0.25 × tanh (20 × ([C] −0.12))) × ([Si] / 24 + [Mn] / 6 + [Cu] / 15 + [Ni] / 20 + ([Cr] + [Mo] + [Nb] + [V]) / 5 + 5 × [B]) (Formula 2)
However, the element with [] represents the content (% by mass) of each element. - 前記フラックス入りワイヤ中の前記CaOの含有量が、前記フラックス入りワイヤの全質量に対する質量%で0.15%以下であることを特徴とする請求項1~3のいずれか一項に記載の溶接継手の製造方法。 The welding according to any one of claims 1 to 3, wherein a content of the CaO in the flux-cored wire is 0.15% or less by mass% with respect to a total mass of the flux-cored wire. A method for manufacturing a joint.
- 前記金属弗化物、前記金属酸化物、および前記金属炭酸塩を除く、前記フラックス入りワイヤ中の前記化学組成が、前記フラックス入りワイヤの全質量に対する質量%で:
Ni:0~0.1%である
ことを特徴とする請求項1~4のいずれか一項に記載の溶接継手の製造方法。 Except for the metal fluoride, the metal oxide, and the metal carbonate, the chemical composition in the flux-cored wire is in mass% with respect to the total mass of the flux-cored wire:
The method for producing a welded joint according to any one of claims 1 to 4, wherein Ni is 0 to 0.1%. - 前記金属弗化物、前記金属酸化物、および前記金属炭酸塩を除く、前記フラックス入りワイヤ中の前記化学組成が、前記フラックス入りワイヤの全質量に対する質量%で:
Cu:0~0.50%;
Cr:0~1.00%;
Mo:0~0.50%;
Ti:0~0.050%;
Nb:0~0.05%
であることを特徴とする請求項1~5のいずれか一項に記載の溶接継手の製造方法。 Except for the metal fluoride, the metal oxide, and the metal carbonate, the chemical composition in the flux-cored wire is in mass% with respect to the total mass of the flux-cored wire:
Cu: 0 to 0.50%;
Cr: 0 to 1.00%;
Mo: 0 to 0.50%;
Ti: 0 to 0.050%;
Nb: 0 to 0.05%
The method for producing a welded joint according to any one of claims 1 to 5, wherein: - 前記フラックス入りワイヤの前記鋼製外皮に、スリット状の隙間がないことを特徴とする請求項1~6のいずれか一項に記載の溶接継手の製造方法。 The method for manufacturing a welded joint according to any one of claims 1 to 6, wherein there is no slit-like gap in the steel outer sheath of the flux-cored wire.
- 前記フラックス入りワイヤの前記鋼製外皮に、スリット状の隙間があることを特徴とする、請求項1~6のいずれか一項に記載の溶接継手の製造方法。 The method for manufacturing a welded joint according to any one of claims 1 to 6, wherein a slit-like gap is formed in the steel outer sheath of the flux-cored wire.
- 前記フラックス入りワイヤの表面にパーフルオロポリエーテル油が塗布されていることを特徴とする請求項1~8のいずれか一項に記載の溶接継手の製造方法。 The method for manufacturing a welded joint according to any one of claims 1 to 8, wherein perfluoropolyether oil is applied to a surface of the flux-cored wire.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02217195A (en) * | 1989-02-18 | 1990-08-29 | Nippon Steel Corp | Flux cored wire for gas shielded arc welding for heat resistant steel |
JPH08197283A (en) * | 1995-01-23 | 1996-08-06 | Nippon Steel Corp | Flux cored wire for mig welding by which high-toughness weld zone having lessened welding deformation is obtainable |
JPH08257785A (en) * | 1995-01-23 | 1996-10-08 | Nippon Steel Corp | Flux cored wire for arc welding to improve low temp. crack resistance of steel weld zone |
JP2001205483A (en) * | 2000-01-19 | 2001-07-31 | Nippon Steel Weld Prod & Eng Co Ltd | Flux-containing wire for gas shield arc welding |
WO2013168670A1 (en) * | 2012-05-08 | 2013-11-14 | 新日鐵住金株式会社 | Flux-containing wire for welding ultrahigh-tensile steel |
WO2014119082A1 (en) * | 2013-01-31 | 2014-08-07 | 新日鐵住金株式会社 | Flux cored wire, welding method using flux cored wire, method for producing welded joint using flux cored wire, and welded joint |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3354460B2 (en) | 1997-11-11 | 2002-12-09 | 川崎製鉄株式会社 | Covered arc welding method for high strength steel |
JP4564245B2 (en) | 2003-07-25 | 2010-10-20 | 新日本製鐵株式会社 | Super high strength welded joint with excellent low temperature cracking property of weld metal and method for producing high strength welded steel pipe |
JP5136466B2 (en) | 2008-03-28 | 2013-02-06 | 新日鐵住金株式会社 | Flux-cored wire for welding high-strength steel and method for producing the same |
WO2009145347A1 (en) * | 2008-05-27 | 2009-12-03 | 新日鐵住金ステンレス株式会社 | Flux-cored wire for welding of duplex stainless steel which enables the miniaturization of solidified crystal particles |
CN102655978B (en) * | 2009-12-16 | 2015-08-05 | 新日铁住金株式会社 | Can the coat core-wire for gas-protection arc welding of all-position welding |
KR101211284B1 (en) * | 2010-06-07 | 2012-12-11 | 신닛테츠스미킨 카부시키카이샤 | Ultra high-strength welded joint and method for producing same |
JP5607002B2 (en) | 2011-02-02 | 2014-10-15 | 株式会社神戸製鋼所 | Weld metal with excellent resistance to hydrogen embrittlement |
BR112013020444B1 (en) * | 2011-02-14 | 2022-09-20 | Nippon Steel Corporation | DUPLEX STAINLESS STEEL WELDED JOINT |
JP5606985B2 (en) | 2011-04-08 | 2014-10-15 | 株式会社神戸製鋼所 | Weld metal with excellent resistance to hydrogen embrittlement |
-
2013
- 2013-11-08 WO PCT/JP2013/080242 patent/WO2015068261A1/en active Application Filing
-
2014
- 2014-08-07 MY MYPI2015704221A patent/MY158148A/en unknown
- 2014-08-07 AU AU2014345139A patent/AU2014345139B2/en active Active
- 2014-08-07 CN CN201480030521.XA patent/CN105339132B/en active Active
- 2014-08-07 KR KR1020157033517A patent/KR101655057B1/en active IP Right Grant
- 2014-08-07 CA CA2926569A patent/CA2926569C/en active Active
- 2014-08-07 BR BR112015029349-2A patent/BR112015029349B1/en active IP Right Grant
- 2014-08-07 MX MX2015017087A patent/MX352525B/en active IP Right Grant
- 2014-08-07 WO PCT/JP2014/070878 patent/WO2015068443A1/en active Application Filing
- 2014-08-07 CA CA2915026A patent/CA2915026C/en active Active
-
2015
- 2015-11-25 PH PH12015502625A patent/PH12015502625A1/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02217195A (en) * | 1989-02-18 | 1990-08-29 | Nippon Steel Corp | Flux cored wire for gas shielded arc welding for heat resistant steel |
JPH08197283A (en) * | 1995-01-23 | 1996-08-06 | Nippon Steel Corp | Flux cored wire for mig welding by which high-toughness weld zone having lessened welding deformation is obtainable |
JPH08257785A (en) * | 1995-01-23 | 1996-10-08 | Nippon Steel Corp | Flux cored wire for arc welding to improve low temp. crack resistance of steel weld zone |
JP2001205483A (en) * | 2000-01-19 | 2001-07-31 | Nippon Steel Weld Prod & Eng Co Ltd | Flux-containing wire for gas shield arc welding |
WO2013168670A1 (en) * | 2012-05-08 | 2013-11-14 | 新日鐵住金株式会社 | Flux-containing wire for welding ultrahigh-tensile steel |
WO2014119082A1 (en) * | 2013-01-31 | 2014-08-07 | 新日鐵住金株式会社 | Flux cored wire, welding method using flux cored wire, method for producing welded joint using flux cored wire, and welded joint |
Cited By (13)
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EP3427890A4 (en) * | 2016-03-08 | 2019-10-30 | Nippon Steel Corporation | Flux-cored wire, weld joint manufacturing method and weld joint |
WO2017154122A1 (en) * | 2016-03-08 | 2017-09-14 | 新日鐵住金株式会社 | Flux-cored wire, weld joint manufacturing method and weld joint |
JPWO2017154120A1 (en) * | 2016-03-08 | 2018-09-13 | 新日鐵住金株式会社 | Flux-cored wire, welded joint manufacturing method, and welded joint |
JPWO2017154122A1 (en) * | 2016-03-08 | 2018-10-04 | 新日鐵住金株式会社 | Flux-cored wire, welded joint manufacturing method, and welded joint |
AU2016396548B2 (en) * | 2016-03-08 | 2019-09-12 | Nippon Steel Corporation | Flux-cored wire, weld joint manufacturing method and weld joint |
AU2016396546B2 (en) * | 2016-03-08 | 2019-10-17 | Nippon Steel Corporation | Flux-cored wire, manufacturing method of welded joint, and welded joint |
WO2017154120A1 (en) * | 2016-03-08 | 2017-09-14 | 新日鐵住金株式会社 | Flux-cored wire, weld joint manufacturing method and weld joint |
EP3427891A4 (en) * | 2016-03-08 | 2019-11-13 | Nippon Steel Corporation | Flux-cored wire, weld joint manufacturing method and weld joint |
US10946486B2 (en) | 2016-03-08 | 2021-03-16 | Nippon Steel Corporation | Flux-cored wire, manufacturing method of welded joint, and welded joint |
US11331742B2 (en) | 2016-03-08 | 2022-05-17 | Nippon Steel Corporation | Flux-cored wire, manufacturing method of welded joint, and welded joint |
US11400539B2 (en) | 2016-11-08 | 2022-08-02 | Nippon Steel Corporation | Flux-cored wire, manufacturing method of welded joint, and welded joint |
WO2021125280A1 (en) * | 2019-12-20 | 2021-06-24 | Jfeスチール株式会社 | Steel wire for gas-shielded arc welding, gas-shielded arc welding method, and method for manufacturing gas-shielded arc welded joint |
JP6969705B1 (en) * | 2019-12-20 | 2021-11-24 | Jfeスチール株式会社 | Steel wire for gas shielded arc welding, gas shielded arc welding method, and manufacturing method of gas shielded arc welded joint |
Also Published As
Publication number | Publication date |
---|---|
BR112015029349B1 (en) | 2020-12-08 |
MY158148A (en) | 2016-09-15 |
BR112015029349A2 (en) | 2017-07-25 |
KR101655057B1 (en) | 2016-09-06 |
PH12015502625B1 (en) | 2016-03-07 |
MX2015017087A (en) | 2016-04-11 |
CA2915026C (en) | 2016-10-04 |
CN105339132A (en) | 2016-02-17 |
MX352525B (en) | 2017-11-29 |
CA2926569C (en) | 2017-04-18 |
CN105339132B (en) | 2017-04-12 |
AU2014345139B2 (en) | 2016-03-31 |
WO2015068261A1 (en) | 2015-05-14 |
AU2014345139A1 (en) | 2015-12-17 |
PH12015502625A1 (en) | 2016-03-07 |
CA2926569A1 (en) | 2015-05-14 |
KR20150136551A (en) | 2015-12-07 |
CA2915026A1 (en) | 2015-05-14 |
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