WO2015057041A1 - In-line cavitation assembly - Google Patents

In-line cavitation assembly Download PDF

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Publication number
WO2015057041A1
WO2015057041A1 PCT/KZ2014/000018 KZ2014000018W WO2015057041A1 WO 2015057041 A1 WO2015057041 A1 WO 2015057041A1 KZ 2014000018 W KZ2014000018 W KZ 2014000018W WO 2015057041 A1 WO2015057041 A1 WO 2015057041A1
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WO
WIPO (PCT)
Prior art keywords
oil
siphon
tank
result
bubbles
Prior art date
Application number
PCT/KZ2014/000018
Other languages
French (fr)
Russian (ru)
Inventor
Юрий СУСАНОВ
Дауит НУКЕНОВ
Original Assignee
Юрий СУСАНОВ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Юрий СУСАНОВ filed Critical Юрий СУСАНОВ
Publication of WO2015057041A1 publication Critical patent/WO2015057041A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G15/00Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs
    • C10G15/08Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs by electric means or by electromagnetic or mechanical vibrations
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/06Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline

Definitions

  • the essence of the technology is to compress oil at a temperature of 20 ° C with a piston, followed by rarefaction up to 0.1 atmospheric pressure at which gasoline vapors are saturated, bubbles are released, and their further collapse, resulting in the destruction of high-molecular compounds into smaller and simpler ones resulting in low-frequency cavitation.
  • the installation makes it easy to adjust the physicochemical parameters of the oil.
  • this is a laboratory installation, of cyclic action, and cannot be used for industrial implementation.
  • the prototype of the flow cavitation installation is a pipe with local narrowing described in the Great Soviet Encyclopedia - hydrodynamic cavitation. Its essence lies in the formation of gas bubbles when pumping liquid through a local narrowing of the pipe, where there is an increase in the speed of the liquid, and as a result, a local decrease in pressure.
  • the disadvantage is the slight formation of caverns and the need to maintain high pumping speeds.
  • a “Flow cavitation installation” consisting of a constant-1 capacity tank that supports a ball valve-2, a suction pipe-3, in the form of a siphon, which provides a vacuum when pumping oil-9, atmospheric pressure OD, which ensures the height of the siphon 8-10 meters (for oil, depending on its temperature).
  • An air valve-4 is installed in the upper part of the siphon pipe to pump gas gas accumulations with a vacuum pump-5 in order to prevent the siphon from breaking.
  • An air valve with a floating ball prevents oil from entering the vacuum pipe-6.
  • the sucked-off gasoline vapors are condensed in the evaporator of the refrigeration machine-7, and collected in the tank-8, using it as intended.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Mechanical Engineering (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

An in-line cavitation assembly is intended for treating heavy and viscous crude oil for the purpose of breaking down high molecular weight compounds into smaller, simpler compounds, thus bringing about an up to tenfold reduction in the viscosity of the oil and an up to 70 percent increase in light oil yield. The assembly consists of a constant-level tank with a float valve for maintaining the level in the tank, to which crude oil is supplied from a temporary storage tank. The oil, pumped through a vertical siphon tube, begins to "boil" as a result of reduced pressure, releasing bubbles of gas (gasoline) in the body of the flow as a result of the saturation of the vapours, at a set vacuum and temperature. When they enter the pump, which raises the pressure, the bubbles begin to collapse, breaking down high molecular weight compounds as a result of hydraulic impacts. In order to prevent siphon failure due to an accumulation of bubbles, an air valve is installed at the top of the siphon tube, from which valve a vacuum pump pumps out gasoline vapours, which pass through the evaporator of a refrigerating machine and are condensed and collected in a tank for use as appropriate.

Description

Поточная кавитационная установка  Flow cavitation installation
Может использоваться в нефтедобывающей промышленности с целью воздействия на тяжелые и вязкие нефти, с целью диструкции высокомолекулярных соединений, на более мелкие и простые, в результате чего вязкость нефти уменьшается от 2-х до 10-ти раз, а количество светлых фракций нефти увеличивается на 50-70%. На опытной лабораторной установке,описанной в отчете 2007г. РГП «Казахский Национальный Университет имени К.И.Сатпаева»,( на стр. 13-16), которую можно считать аналогом. Суть технологии заключается в сжатии нефти при температуре 20 С поршнем, с последующим разрежением до 0,1 атмосферного давления при которой происходит насыщение паров бензина, с выделением пузырьков,с дальнейшим их схлопыванием,в результате чего происходит диструкция высокомалекулярных соединений, на более мелкие и простые, в результате чего происходит низкочастотная кавитация. Помимо улучшения качества высоковязкой и высокопарафинис~ой нефти, установка позволяет достаточно просто регулировать физико-химические параметры нефти. Однако это лабораторная установка, цикличного действия, и не может использоваться для промышленного внедрения. It can be used in the oil industry for the purpose of influencing heavy and viscous oils, for the purpose of the destruction of high molecular weight compounds, into smaller and simpler ones, as a result of which the oil viscosity decreases from 2 to 10 times, and the number of light fractions of oil increases by 50 -70%. At the experimental laboratory facility described in the 2007 report. RSE "Kazakh National University named after K.I.Satpayev", (on pages 13-16), which can be considered an analogue. The essence of the technology is to compress oil at a temperature of 20 ° C with a piston, followed by rarefaction up to 0.1 atmospheric pressure at which gasoline vapors are saturated, bubbles are released, and their further collapse, resulting in the destruction of high-molecular compounds into smaller and simpler ones resulting in low-frequency cavitation. In addition to improving the quality of high-viscosity and high-paraffin oil, the installation makes it easy to adjust the physicochemical parameters of the oil. However, this is a laboratory installation, of cyclic action, and cannot be used for industrial implementation.
Прототипом поточной кавитационной установки является труба, с местным сужением, описанная в Большой советской энциклопедии- гидродинамическая кавитация. Ее суть заключается в образовании пузырьков газа, при прокачке жидкости через местное сужение трубы, где происходит увеличение скорости жидкости, и как следствие, местное понижение давления. Недостатком является незначительное образование каверн и необходимость поддерживать высокие скорости прокачки.  The prototype of the flow cavitation installation is a pipe with local narrowing described in the Great Soviet Encyclopedia - hydrodynamic cavitation. Its essence lies in the formation of gas bubbles when pumping liquid through a local narrowing of the pipe, where there is an increase in the speed of the liquid, and as a result, a local decrease in pressure. The disadvantage is the slight formation of caverns and the need to maintain high pumping speeds.
Предлагается «Поточная кавитационная установка», состоящая из емкости постоянного уровня-1, которое поддерживает шаровой клапан-2, всасывающей трубы-3, в виде сифона, которая обеспечивает разрежение, при прокачке насосом-9 нефти, ОД атмосферного давления, что обеспечивает высота сифона 8-10 метров (для нефти, в зависимости от ее температуры). В верхней части сифонной трубы установлен воздушный клапан-4,для откачки вакуум-насосом-5 скоплений газов бензина, во избежании срыва сифона. Воздушный клапан, с плавающим шаром, препятствует попаданию нефти в вакуумную трубу-6. Отсасываемые пары бензина, конденсируются в испарителе холодильной машины-7, и собираются в емкости-8, с использованием по назначению. A “Flow cavitation installation” is proposed, consisting of a constant-1 capacity tank that supports a ball valve-2, a suction pipe-3, in the form of a siphon, which provides a vacuum when pumping oil-9, atmospheric pressure OD, which ensures the height of the siphon 8-10 meters (for oil, depending on its temperature). An air valve-4 is installed in the upper part of the siphon pipe to pump gas gas accumulations with a vacuum pump-5 in order to prevent the siphon from breaking. An air valve with a floating ball prevents oil from entering the vacuum pipe-6. The sucked-off gasoline vapors are condensed in the evaporator of the refrigeration machine-7, and collected in the tank-8, using it as intended.
Поскольку упругость паров зависит от температуры и вакуума необходимо поддержание температуры нефти на расчетном уровне, при заданной высоте сифонной трубы. Установка работает автоматически: при всасывании нефти, через сифонную трубу, в результате разрежения, образуются пузырьки газа (холодный крекинг),которые после насоса схлопываются, разрывая высокомолекулярные соединения, с улучшением качественных показателей нефти по вязкости, что уменьшает затраты энергии при прокачке, и повышает выход легких фракций при крекинге. Since vapor pressure depends on temperature and vacuum, it is necessary to maintain the oil temperature at the calculated level, at a given height of the siphon pipe. The unit works automatically: when oil is sucked in through a siphon pipe, as a result of rarefaction, gas bubbles form (cold cracking), which collapse after the pump, breaking high molecular weight compounds, with an improvement in the quality of oil viscosity, which reduces energy consumption during pumping, and increases yield of light fractions during cracking.

Claims

ФОРМУЛА ИЗОБРЕТЕНИЯ CLAIM
1. Поточная навигационная установка, состоящая из промежуточного резервуара, постоянного уровня с нефтью, всасывающей трубы, выполненной в виде сифона,высотой обеспечивающей насыщение паров, при работающем насосе откачки, при заданной температуре нефти, обеспечивает гидродинамическую кавитацию на потоке, вызывая диструкцию высокомолекулярных соединений, на более мелкие и простые,уменьшая вязкость до 10-ти раз и увеличивая выход светлых фракций нефтепродуктов до 70-ти процентов, при крекинге нефти. 1. In-line navigation installation, consisting of an intermediate reservoir, a constant level with oil, a suction pipe made in the form of a siphon, providing vapor saturation, with a working pump, at a given oil temperature, provides hydrodynamic cavitation in the stream, causing the destruction of high molecular weight compounds, into smaller and simpler ones, reducing viscosity up to 10 times and increasing the yield of light fractions of oil products up to 70 percent when cracking oil.
2. Устройство, по п.1, с целью поддержания постоянного уровня, в промежуточном резервуаре, подающая труба снабжена поплавковым клапаном,а воизбежания срыва сифона, при скоплении газов от разрежения, в верхней части сифонной трубы, установлен воздушный клапан отбора газовой фазы (бензина), с откачкой вакуум-насосом, через испаритель холодильной машины, в емкость, для использования по назначению.  2. The device according to claim 1, in order to maintain a constant level, in the intermediate tank, the supply pipe is equipped with a float valve, and in order to avoid the breakdown of the siphon, with the accumulation of gases from rarefaction, an air valve for gas phase selection (gasoline) is installed in the upper part of the siphon pipe ), with evacuation by a vacuum pump, through the evaporator of the refrigeration machine, into a container, for intended use.
PCT/KZ2014/000018 2013-10-18 2014-10-10 In-line cavitation assembly WO2015057041A1 (en)

Applications Claiming Priority (2)

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KZ20131387 2013-10-18
KZ2013/1387.1 2013-10-18

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108862463A (en) * 2018-08-30 2018-11-23 大连诚高科技股份有限公司 One kind is from gravity Hydrodynamic cavitation water treatment facilities

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2203870A1 (en) * 1972-10-19 1974-05-17 Neidl Georg Multistage petroleum cracker - using prepn in conventional swashplate machine before fractionation
SU1068617A1 (en) * 1982-04-20 1984-01-23 Астраханское центральное конструкторское бюро Министерства речного флота РСФСР Pumping plant
RU2078116C1 (en) * 1992-11-02 1997-04-27 Анатолий Федорович Кладов Method and installation for cracking of petroleum and petroleum products
RU116487U1 (en) * 2011-10-31 2012-05-27 Общество с ограниченной ответственностью "Производственная компания "Аргоси" INSTALLATION FOR SEPARATION OF AIR AND VAPORS FROM LIQUID

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2203870A1 (en) * 1972-10-19 1974-05-17 Neidl Georg Multistage petroleum cracker - using prepn in conventional swashplate machine before fractionation
SU1068617A1 (en) * 1982-04-20 1984-01-23 Астраханское центральное конструкторское бюро Министерства речного флота РСФСР Pumping plant
RU2078116C1 (en) * 1992-11-02 1997-04-27 Анатолий Федорович Кладов Method and installation for cracking of petroleum and petroleum products
RU116487U1 (en) * 2011-10-31 2012-05-27 Общество с ограниченной ответственностью "Производственная компания "Аргоси" INSTALLATION FOR SEPARATION OF AIR AND VAPORS FROM LIQUID

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108862463A (en) * 2018-08-30 2018-11-23 大连诚高科技股份有限公司 One kind is from gravity Hydrodynamic cavitation water treatment facilities

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