WO2015029097A1 - Textile product - Google Patents

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Publication number
WO2015029097A1
WO2015029097A1 PCT/JP2013/072669 JP2013072669W WO2015029097A1 WO 2015029097 A1 WO2015029097 A1 WO 2015029097A1 JP 2013072669 W JP2013072669 W JP 2013072669W WO 2015029097 A1 WO2015029097 A1 WO 2015029097A1
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WO
WIPO (PCT)
Prior art keywords
yarn
fiber
deodorizing
product according
textile product
Prior art date
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PCT/JP2013/072669
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French (fr)
Japanese (ja)
Inventor
嵩 片岡
Original Assignee
株式会社プロジェ・ジャパン
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Priority to PCT/JP2013/072669 priority Critical patent/WO2015029097A1/en
Publication of WO2015029097A1 publication Critical patent/WO2015029097A1/en

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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/02Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
    • D06M14/04Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/08Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
    • D06M14/12Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M14/14Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/08Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
    • D06M14/12Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M14/16Polyamides
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D2400/00Functions or special features of garments
    • A41D2400/36Deoderising or perfuming

Definitions

  • the present invention relates to a textile product having excellent characteristics in the deodorizing function.
  • Patent Document 1 describes that a deodorizing yarn is used as a sewing yarn. By setting it as such a method, a deodorizing function can be provided to a textile product with a small usage-amount. However, the use of deodorant yarn as the yarn is not described.
  • a textile product it is generally performed to perform threading for processing an end portion of a cloth. That is, the ends of the woven fabric and the knitted fabric are prone to fraying from the presence of the yarn hole. In order to prevent such fraying from the end, it is a common practice to perform a treatment with a warp yarn to make it difficult to fray. However, no attempt has been made to improve the performance of the textile product itself by imparting some function to such a warp yarn.
  • an object of the present invention is to provide a fiber product having excellent deodorizing performance and excellent durability.
  • the present invention is a textile product obtained by using a deodorizing yarn as a warp yarn.
  • the warp yarn preferably has a tensile strength of 500 cN or more.
  • the yarn is preferably deodorizing performance under wet conditions with an ammonia reduction rate of 90% or more.
  • the warp yarn is preferably a fiber obtained by binding an adsorbent substance to a cotton yarn, a nylon yarn and / or a polyester yarn by graft polymerization.
  • the warp yarn is preferably a twisted yarn of three twists or two twists.
  • the yarn is preferably a twisted yarn obtained using at least one deodorizing fiber and at least one fiber that is not a deodorizing fiber.
  • the warp yarn may be a twisted yarn obtained by using fibers made of short fibers and having a thickness of 10 to 50.
  • the twisted yarn preferably has a lower twist of 15 to 30 turns / inch.
  • the twisted yarn preferably has an upper twist of 15 to 50 turns / inch. It is preferable that the twist direction of the above-mentioned twisted yarn is opposite to that of the lower twist and the upper twist.
  • the warp yarn may be made of long fibers, and the total fineness may be 50 to 200 dtex.
  • the textile product of the present invention can be used as work clothes, underwear, socks, bedding, clothes, coats, sweaters, shirts, nightclothes, Japanese clothes, gloves or hats.
  • the fiber product of the present invention has a good deodorizing effect and is excellent in terms of product durability.
  • the present invention is described in detail below.
  • the present invention is a textile product obtained by using a deodorizing yarn as a warp yarn.
  • the yarn is used when the yarn is threaded to prevent fraying from the end of the fiber. That is, generally, fraying at the end portion is suppressed by sewing a thread near the end portion of the cloth.
  • a deodorizing yarn is used as the yarn used for such yarn threading.
  • deodorizing yarn Since the amount of use of the yarn is larger than that of the sewing yarn, a large amount of deodorizing yarn can be used. Furthermore, deodorizing performance can be imparted to any dough. Therefore, deodorizing performance can be imparted without changing the production process of the dough. Further, in the case of clothing or the like, the effect can be obtained efficiently by using the deodorizing yarn described above only in a portion where odor is particularly likely to occur.
  • the deodorizing yarn used in the present invention is not particularly limited, but preferably has a polar functional group capable of chemically adsorbing odorous substances. Such a deodorizing yarn has a particularly excellent deodorizing function.
  • the deodorant yarn having a polar functional group is not particularly limited.
  • a known arbitrary fiber such as a fiber in which a functional group that adsorbs a odorous substance to the fiber base material itself is bonded to the fiber base material by graft polymerization.
  • Deodorant yarn can be used.
  • a fiber in which a functional group capable of adsorbing an odorous substance is bonded to the fiber base material itself by performing graft polymerization on the fiber.
  • a deodorizing yarn is preferable in that it can sufficiently impart a deodorizing function to a fiber product with a use amount as a warp yarn because it has a very high ability to adsorb compounds serving as odor components.
  • deodorizing yarn will be described in detail.
  • the above graft polymerization is performed by grafting an adsorbent substance such as an anionic adsorbent substance (that is, a compound having an anionic functional group) or a cationic adsorbent substance (that is, a compound having a cationic functional group) onto a compound constituting a fiber. Polymerize.
  • the fiber thus obtained is excellent in washing resistance because the adsorptive substance is bonded to the substance constituting the fiber substrate through a chemical bond.
  • a cationic adsorbing substance and an anionic adsorbing substance can also be reacted together, it is possible to obtain a deodorizing performance that can deal with a wide range of substances.
  • an anionic functional group and a cationic functional group can be introduced at a high density, the deodorizing performance of the fiber itself is very high.
  • anionic functional group examples include a carboxyl group, a sulfone group, a phosphoric acid group, a sulfoethyl group, a phosphomethyl group, and a carbomethyl group. These functional groups adsorb odorous substances such as ammonia and amines to obtain deodorizing performance.
  • the anionic adsorptive substance the above-described compounds having a functional group and an unsaturated bond can be suitably used.
  • examples of such a cationic adsorbing substance useful in the present invention include acrylic acid, methacrylic acid, styrene sulfonic acid and salts thereof, and 2-acrylamido-2-methylpropane sulfonic acid.
  • Examples of the cationic functional group include a quaternary ammonium group and primary to tertiary amine groups such as an amino group, a methylamino group, a dimethylamino group, and a diethylamino group.
  • Preferred cationic functional groups include quaternary ammonium groups and amino groups.
  • the cationic functional group has the ability to adsorb polar substances and can neutralize with acidic substances such as hydrogen sulfide and mercaptans. As a result, the odorous substance that is an acidic substance is removed.
  • the above-described compound having a functional group and an unsaturated bond can be preferably used.
  • cationic adsorbents include, for example, vinylbenzyltrimethylammonium salt, diethylaminoethyl methacrylate, dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminomethyl methacrylate, tertiary butylaminoethyl acrylate, tertiary butyl. Mention may be made of aminoethyl methacrylate and dimethylaminopropylacrylamide. Two or more of these can be used simultaneously.
  • particularly useful reactive monomers are vinylbenzyltrimethylammonium salt and diethylaminoethyl methacrylate.
  • a reactive monomer having a group that can be converted into a cationic dissociation group is also useful in the present invention.
  • An example of such a reactive monomer is chloromethylstyrene.
  • a graft polymerization may be performed using a compound having a hydrophilic group in combination.
  • Hydrophilic group refers to a group that has an affinity for water and does not ionically dissociate when contacted with water (ie, a nonion). Such hydrophilic groups can trap water molecules present in the air, the trapped water molecules form an adsorbed water layer on the surface of the adsorbing material of the present invention, dissolve polar substances, and / or The ionic substance can be dissociated. Needless to say, such a hydrophilic group acts in water as well as in air.
  • hydrophilic group examples include a hydroxyl group, a hydroxyalkyl group (wherein the alkyl group is preferably a lower alkyl group), an amino group, and a pyrrolidonyl group. More preferred hydrophilic groups include a hydroxyl group and a hydroxyalkyl group.
  • the compound having a hydrophilic functional group the above-described compound having a hydrophilic functional group and an unsaturated bond can be suitably used.
  • Examples of compounds useful in the present invention as the compound having a hydrophilic functional group include, for example, hydroxyethyl methacrylate, hydroxypropyl acrylate, vinyl pyrrolidone, dimethylacrylamide, ethylene glycol monomethacrylate, ethylene glycol monoacrylate, ethylene glycol monomethacrylate, ethylene There are glycol diacrylate, ethylene glycol dimethacrylate, triethylene glycol diacrylate and triethylene glycol methacrylate.
  • particularly useful reactive monomers include hydroxyethyl methacrylate and vinyl pyrrolidone.
  • two or more of the above-mentioned various components may be used in combination.
  • Specific examples of preferred combinations of functional groups when two or more are used in combination include a sulfone group, a carboxyl group, a quaternary ammonium group, and a hydroxyethyl group.
  • another preferred combination of functional groups in the present invention is specifically a sulfone group, a carboxyl group, a quaternary ammonium group, and a pyrrolidonyl group.
  • a fiber capable of adsorbing a wide range of odorous substances can be obtained.
  • the fibers used as the base material for the graft polymerization include synthetic fibers such as polyester yarn, polyamide yarn, polyacrylic yarn, and rayon yarn, semi-synthetic fibers, natural fibers such as cotton yarn, wool, and silk yarn. Can be mentioned. In particular, it is preferable to use cotton yarn, nylon yarn and / or polyester yarn. Among these, polyamide yarns and cotton yarns are particularly preferable in that they have a structure capable of introducing a functional group into the molecular structure and have good compatibility when used by spinning with other fibers.
  • the fiber used as the base material may be any form of long fiber and short fiber. Further, spun yarn, twisted yarn, processed yarn, and the like may be used. In consideration of use as a deodorized yarn in a later step, cotton spun yarn or nylon long fiber is particularly preferable.
  • the adsorptive substance to be bonded on the fiber substrate is preferably bonded at a ratio of 3 to 80% by weight with respect to the weight of the fiber substrate.
  • bonding amount in the said range it is preferable at the point which can obtain favorable deodorizing and deodorizing performance.
  • the deodorizing yarn having high deodorizing performance it is preferable to use the deodorizing yarn having high deodorizing performance. For example, when a test at an initial concentration of 100 ppm of ammonia is performed by the detector tube method described in the SEK mark fiber product certification standard shown by the Japan Fiber Evaluation Technology Council, the ammonia concentration after 2 hours is 1.5 ppm. It is preferable to use a fiber having a deodorizing function as follows.
  • a spun yarn, a twisted yarn, a processed yarn or the like may be produced by a known method using the fibers after the graft polymerization, and used as a deodorized yarn.
  • spun yarns, twisted yarns, processed yarns and the like may be produced in combination with ordinary fibers not subjected to graft polymerization.
  • the amount of the fiber used is less than 30% by weight, it is not preferable because there is a possibility that sufficient deodorizing performance cannot be imparted.
  • what processed the fiber after processing such as a spun yarn, a twisted yarn, and a processed yarn, to make a deodorant yarn may be performed.
  • a twisted yarn obtained by combining a cation-adsorptive fiber and an anion-adsorptive fiber can also be used. This is preferable in that a fiber product that can deal with many kinds of odorous substances can be obtained.
  • the above-mentioned warp yarn has a tensile strength of 500 cN or more.
  • the deodorant yarn tends to have a reduced tensile strength by performing a treatment for imparting deodorant performance.
  • thread breakage tends to occur during the overlock stitching, and further, problems such as fraying easily occur when used as a textile product. Therefore, it is preferable not to cause such a problem by devising the deodorizing yarn having the above-described tensile strength by devising to increase the tensile strength.
  • the deodorizing yarn is a short fiber
  • the deodorizing yarn is a short fiber
  • An example of the case where short fibers are used is a case where cotton yarn is used as a base fiber for deodorant yarn.
  • all yarns constituting the twisted yarn may be deodorized yarns, but at least one may be normal fibers (that is, fibers not subjected to deodorizing treatment).
  • Deodorant yarn often has lower strength than normal fibers. For this reason, in order to reinforce the strength, it is preferable to use twisted yarn in combination with ordinary fibers.
  • the normal fiber is not particularly limited and may be the same type of fiber as the deodorant yarn or a different type of fiber, but it is preferable to use the same type of fiber.
  • the spun yarn constituting the twisted yarn preferably has a yarn count of 10 to 50 for both the deodorant yarn and the normal fiber. If the yarn count is less than 10th, it will not fit into the needle hole of a normal overlock sewing machine, and when used as a overlock thread, the overlock will become too thick and the skin will be stimulated by friction. That is not preferable. Furthermore, if the yarn count is 50 or more, there is a risk that the strength may be insufficient.
  • the twisted yarn is usually obtained by combining a plurality of fibers subjected to a lower twist (that is, twisting of each of the fibers constituting the twisted yarn) and then performing an upper twist (twisting as a whole twisted yarn).
  • a lower twist that is, twisting of each of the fibers constituting the twisted yarn
  • an upper twist tilting as a whole twisted yarn.
  • the twisting direction is reverse between the lower twist and the upper twist. That is, when the lower twist is a Z twist, the upper twist is preferably an S twist, and when the lower twist is an S twist, the upper twist is preferably a Z twist.
  • Such twisting is preferable in that the twisted yarn is less likely to be untwisted.
  • the number of twists is 15 to 30 times / inch. By setting the number of twists in such a range, it is possible to secure the strength when used as a sewing thread and it is preferable in that it can withstand high-speed sewing by an industrial sewing machine.
  • the above twist is preferably 15 to 30 times / inch. By setting the number of twists in such a range, it is possible to secure the strength when used as a sewing thread and it is preferable in that it can withstand high-speed sewing by an industrial sewing machine.
  • the twisted yarn is preferably provided with wax. This is preferable in that the sliding of the thread during sewing is improved.
  • the deodorant fiber which is a long fiber includes nylon long fiber, polyester long fiber and the like as a fiber serving as a base material.
  • the fiber serving as the substrate is preferably a multifilament having a total fineness of 50 to 200 dtex. Use of a material in this range is preferable in that a sufficient deodorizing function and strength can be secured when the sewing thread is used.
  • the deodorizing fiber which is the above-mentioned long fiber can have a relatively high strength, it is not always necessary to use a twisted yarn, and an ordinary multifilament or a drawn yarn using the same may be used. it can.
  • the deodorizing fiber which is a long fiber as a twisted yarn it is preferable to twist two or three yarns into a twisted yarn. At that time, all the yarns constituting the twisted yarn may be deodorized yarns, but at least one normal fiber (that is, fibers not subjected to deodorizing treatment) may be used. Deodorant yarn often has lower strength than normal fibers. For this reason, in order to reinforce the strength, it is preferable to use twisted yarn in combination with ordinary fibers.
  • the normal fiber is not particularly limited and may be the same type of fiber as the deodorant yarn or a different type of fiber, but it is preferable to use the same type of fiber.
  • the deodorizing yarn using the above-mentioned long fibers is provided with wax. This is preferable in that the sliding of the thread during sewing is improved.
  • the warp yarn used in the present invention preferably has an ammonia deodorization rate of 90% or more as measured by wet conditions described in detail below. That is, it is preferable in that the deodorizing function is further improved by using the yarn having such a high deodorizing performance.
  • the ammonia reduction rate is more preferably 95% or more, and further preferably 99% or more. Note that the measurement is performed under wet conditions because when the garment is worn, the portion where the odor is likely to occur is a portion where the garment is moistened by sweat because the portion where the odor is likely to be generated is easily sweated.
  • the textile product of the present invention is characterized in that the deodorizing yarn as described above is used as a warp yarn.
  • FIGS. 1 and 2 are shown.
  • FIG. 1 is a diagram showing the shape of a normal underwear.
  • FIG. 1 has shown the state turned over. In use, it is usually used so that the overlocked portion is hidden with the reverse side upside down in the state of FIG.
  • Such an undergarment is usually formed as a knitted fabric, and the neckline 3, the armhole 4, the opening portion 5 of the sleeve, the side 6, the hem 7, the shoulder 8, and the like are overlocked with an overlock thread.
  • the textile product of the present invention is used for the above-mentioned deodorant yarn to carry out the stitching at these portions.
  • FIG. 2 shows an enlarged view of the portion shown as 2 in FIG. 1 is a part of the shoulder 8 and is sewn. Further, overlock stitching is performed by the overlock thread 1 to prevent fraying at the end.
  • the deodorizing yarn is used as the yarn 1.
  • Overlock stitching is performed by a lock sewing machine or the like in order to prevent fraying at the end of a woven fabric, knitted fabric, or the like, and a well-known overlock stitch can be performed as such a method.
  • a well-known overlock stitch can be performed as such a method.
  • it can be performed by a known method such as one-needle overlock stitching, two-needle overlock stitching, or interlock stitching.
  • All of these over stitches may be performed with the deodorizing yarn, but only over a portion thereof with the deodorizing yarn may be performed. That is, there is a part that is particularly likely to generate odor in the human body. For example, the heel and neck are likely to smell. For this reason, for example, the neckline and neckline stitches may be performed with the deodorizing thread, and the other portions may be stitched with ordinary fibers.
  • yarn is used as a warp thread
  • the deodorizing yarn is used in sewing threads and fabrics, the deodorizing function of the textile product of the present invention can be further improved.
  • the deodorizing yarn is more preferably used only for the deodorizing yarn.
  • the textile product of the present invention can be used in applications such as work clothes, underwear, socks, bedding, clothes, coats, sweaters, shirts, nightclothes, Japanese clothes, gloves or hats. Furthermore, it can be used in any field where odor is likely to occur, such as a seat cover in a vehicle (airplane, train, etc.), a sofa cover for home use, a towel, a cloth towel, a toilet cover, and slippers.
  • Example 1 After removing impurities from the 40th cotton yarn, graft polymerization was performed to bond a functional group that adsorbs odorous substances to produce a deodorant yarn.
  • this deodorized yarn was tested at an initial concentration of 100 ppm of ammonia by the detector tube method described in the SEK mark textile product certification standard, a result that the ammonia concentration after 2 hours was 0.2 ppm was obtained. Further, when a tensile strength test was performed by the general spun yarn test method described in JIS L 1095, a result of 330 cN was obtained.
  • the underwear having the shape shown in FIG. 1 was produced using the twisted yarn thus obtained as a deodorizing yarn.
  • 100% polyester was used as the fabric
  • cotton spun yarn 40/3 was used as the sewing yarn, and the production was performed by a general knitting process and a sewing process.
  • the amount of deodorized yarn used was 4.3 g / wear for the entire underwear.
  • Comparative example As a comparative example, a similar test was conducted on a polyester fabric obtained by using the polyester fiber used in the manufacture of the undergarment fabric of the example (no over stitching with deodorant yarn).
  • Example 2 By performing graft polymerization on the 78dT single yarn, a functional group that adsorbs the odorous substance was bonded to produce a deodorant yarn. Two deodorant yarns described above and one regular yarn for reinforcing strength were twisted together to produce a deodorized yarn. At the time of production, each of the deodorized yarn and the regular yarn was twisted at 750 T / M in the Z twist direction as a lower twist. Further, a 630 T / M twist was applied in the S twist direction as an upper twist. Further, a wax agent treatment was performed to improve slippage during sewing. The warp yarn thus obtained was subjected to the deodorization test under the wet conditions described above, and the ammonia reduction rate was 99.6%.
  • a cardigan having the shape shown in FIG. 1 was produced using the twisted yarn thus obtained as a deodorizing yarn.
  • 70% acrylic + 30% hair was used as the fabric, and nylon filament yarn 78dT / 3 was used as the sewing yarn, and the production was performed by a general knitting process and a sewing process.
  • a cardigan wearing test thus obtained was tested, an excellent deodorizing function was confirmed.
  • the textile product of the present invention can be used in applications such as work clothes, underwear, socks or bedding. Furthermore, it can be used in any product such as a seat cover in a vehicle (airplane, train, etc.), a sofa cover for home use, a towel, a cloth towel, a toilet cover, and slippers.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

[Problem] To provide a textile product having excellent deodorizing function and excellent durability. [Solution] A textile product characterized in being obtained by using a deodorizing yarn as a darning yarn.

Description

繊維製品Fiber products
本発明は、消臭機能において優れた特性を有する繊維製品に関する。 The present invention relates to a textile product having excellent characteristics in the deodorizing function.
繊維に消臭機能を付与することによって、各種消臭製品を提供する試みが多くなされている。たとえば、作業服、シャツ、肌着、靴下、ストッキング等の衣料品やシーツ、枕、枕カバー等の製品においては、汗が付着すると汗中の脂質等の成分が分解されることによって悪臭を発生する。また、衣料品等においては、臭いのする場所に置いたときに、臭い物質が繊維に吸着することで臭いがついてしまう場合がある。このような悪臭を分解したり、臭い物質を吸着したり、抗菌性能を付与したりすることで悪臭発生を抑制するような機能性繊維についての検討が多くなされている。 Many attempts have been made to provide various deodorizing products by imparting a deodorizing function to fibers. For example, in clothing such as work clothes, shirts, underwear, socks, stockings, and products such as sheets, pillows, pillow covers, etc., if sweat adheres, it will cause malodor due to decomposition of lipids in the sweat . In addition, in clothing or the like, when placed in a place where odor is produced, the odorous substance may be adsorbed by the fibers and become odorous. Many studies have been made on functional fibers that suppress the generation of malodors by decomposing such malodors, adsorbing odorous substances, and imparting antibacterial performance.
このような消臭糸を繊維製品において応用する場合、繊維製品を構成する生地自体に消臭糸を使用することが一般的に行われていた。しかし、繊維製品の生地自体に消臭糸を使用すると高価な消臭糸の使用量が大量になるため、コストアップの原因となってしまう。更に、消臭糸は、強度が通常の繊維よりも劣る場合が多いため、繊維製品の物理的性質に劣るものになってしまうという問題もあった。 When such a deodorizing yarn is applied to a textile product, it is generally performed to use the deodorizing yarn for the fabric itself constituting the textile product. However, if the deodorizing yarn is used for the textile fabric itself, the amount of the expensive deodorizing yarn used becomes large, resulting in an increase in cost. Furthermore, since the deodorizing yarn is often inferior in strength to ordinary fibers, there is a problem that the physical properties of the fiber product are inferior.
特許文献1には、消臭糸をミシン糸として使用することが記載されている。このような方法とすることで、少量の使用量で繊維製品に消臭機能を付与することができるというものである。しかし、かがり糸として消臭糸を使用することは記載されていない。 Patent Document 1 describes that a deodorizing yarn is used as a sewing yarn. By setting it as such a method, a deodorizing function can be provided to a textile product with a small usage-amount. However, the use of deodorant yarn as the yarn is not described.
一方、繊維製品においては、布の端部処理のために糸かがりを行うことが一般的に行われている。すなわち、織物や編物の端部は糸口が存在するためにそこからほつれが生じやすい。このような端部からのほつれを防止するためにかがり糸で処理を行い、ほつれにくくすることが一般的に行われている。しかし、このようなかがり糸に何らかの機能を付与して、繊維製品自体の性能を向上させる試みはなされていない。 On the other hand, in a textile product, it is generally performed to perform threading for processing an end portion of a cloth. That is, the ends of the woven fabric and the knitted fabric are prone to fraying from the presence of the yarn hole. In order to prevent such fraying from the end, it is a common practice to perform a treatment with a warp yarn to make it difficult to fray. However, no attempt has been made to improve the performance of the textile product itself by imparting some function to such a warp yarn.
特開2011-132636号JP 2011-132636 A
本発明は上記に鑑み、優れた消臭性能を有し、耐久性にも優れた繊維製品を提供することを目的とする。 In view of the above, an object of the present invention is to provide a fiber product having excellent deodorizing performance and excellent durability.
本発明は、かがり糸として消臭糸を使用して得られたものであることを特徴とする繊維製品である。
かがり糸は、引張強度が500cN以上であることが好ましい。
かがり糸は、湿式条件での消臭性能がアンモニア減少率90%以上であることが好ましい。
かがり糸は、綿糸、ナイロン糸及び/又はポリエステル糸に対してグラフト重合によって吸着性物質を結合させて得られた繊維であることが好ましい。
The present invention is a textile product obtained by using a deodorizing yarn as a warp yarn.
The warp yarn preferably has a tensile strength of 500 cN or more.
The yarn is preferably deodorizing performance under wet conditions with an ammonia reduction rate of 90% or more.
The warp yarn is preferably a fiber obtained by binding an adsorbent substance to a cotton yarn, a nylon yarn and / or a polyester yarn by graft polymerization.
かがり糸は、3本撚又は2本撚の撚糸であることが好ましい。
かがり糸は、少なくとも1本の消臭繊維と少なくとも1本の消臭繊維ではない繊維とを使用して得られた撚糸であることが好ましい。
The warp yarn is preferably a twisted yarn of three twists or two twists.
The yarn is preferably a twisted yarn obtained using at least one deodorizing fiber and at least one fiber that is not a deodorizing fiber.
前記かがり糸は、短繊維からなり太さが10~50番手である繊維を使用して得られた撚糸であってもよい。
上記撚糸は、下撚が15~30回/インチであることが好ましい。
上記撚糸は、上撚が15~50回/インチであることが好ましい。
上記撚糸は、下撚と上撚との撚り方向が逆であることが好ましい。
The warp yarn may be a twisted yarn obtained by using fibers made of short fibers and having a thickness of 10 to 50.
The twisted yarn preferably has a lower twist of 15 to 30 turns / inch.
The twisted yarn preferably has an upper twist of 15 to 50 turns / inch.
It is preferable that the twist direction of the above-mentioned twisted yarn is opposite to that of the lower twist and the upper twist.
上記かがり糸は、長繊維からなり、トータル繊度が50~200dtexであってもよい。
本発明の繊維製品は、作業着、肌着、靴下、寝具、洋服、コート、セーター、ワイシャツ、寝間着、和服、手袋又は帽子として使用することができる。
The warp yarn may be made of long fibers, and the total fineness may be 50 to 200 dtex.
The textile product of the present invention can be used as work clothes, underwear, socks, bedding, clothes, coats, sweaters, shirts, nightclothes, Japanese clothes, gloves or hats.
本発明の繊維製品は、良好な消臭効果を有し、かつ、製品の耐久性という点でも優れたものである。 The fiber product of the present invention has a good deodorizing effect and is excellent in terms of product durability.
本発明の繊維製品の一例を示す図である。It is a figure which shows an example of the textiles of this invention. 図1に示した繊維製品の縫製部の拡大図を示す図である。It is a figure which shows the enlarged view of the sewing part of the textiles shown in FIG.
以下に、本発明を詳細に説明する。
本発明は、かがり糸として消臭糸を使用して得られた繊維製品である。かがり糸は、図1,2に示したように繊維の端部からのほつれを防止するために、糸かがりを行う際に使用する糸である。すなわち、布の端部付近で糸を縫い付けることによって、端部でのほつれを抑制することが一般的に行われている。
このような糸かがりに使用するかがり糸として消臭糸を使用することを特徴とする。
The present invention is described in detail below.
The present invention is a textile product obtained by using a deodorizing yarn as a warp yarn. As shown in FIGS. 1 and 2, the yarn is used when the yarn is threaded to prevent fraying from the end of the fiber. That is, generally, fraying at the end portion is suppressed by sewing a thread near the end portion of the cloth.
A deodorizing yarn is used as the yarn used for such yarn threading.
かがり糸は、縫製糸より使用量が多いことから、消臭糸を多く使用することができる。さらに、あらゆる生地に対して消臭性能を付与することができる。よって、生地の製造工程を変更することなく消臭性能を付与することができる。また、衣料品などの場合は、特に臭いを発生しやすい部位にのみ上述した消臭糸を使用することによって、効率よく効果を得ることができる。 Since the amount of use of the yarn is larger than that of the sewing yarn, a large amount of deodorizing yarn can be used. Furthermore, deodorizing performance can be imparted to any dough. Therefore, deodorizing performance can be imparted without changing the production process of the dough. Further, in the case of clothing or the like, the effect can be obtained efficiently by using the deodorizing yarn described above only in a portion where odor is particularly likely to occur.
(消臭糸)
本発明において使用する消臭糸は、特に限定されるものではないが、臭い物質を化学的吸着することができるような極性官能基を有するものであることが好ましい。このような消臭糸は特に優れた消臭機能を有するものである。極性官能基を有する消臭糸としては特に限定されず、例えば、繊維に対するグラフト重合を行うことによって、繊維基材自体に臭い物質を吸着するような官能基を結合させた繊維等の公知の任意の消臭糸を使用することができる。
(Deodorant yarn)
The deodorizing yarn used in the present invention is not particularly limited, but preferably has a polar functional group capable of chemically adsorbing odorous substances. Such a deodorizing yarn has a particularly excellent deodorizing function. The deodorant yarn having a polar functional group is not particularly limited. For example, a known arbitrary fiber such as a fiber in which a functional group that adsorbs a odorous substance to the fiber base material itself is bonded to the fiber base material by graft polymerization. Deodorant yarn can be used.
上述したもののなかでも、繊維に対するグラフト重合を行うことによって、繊維基材自体に臭い物質を吸着するような官能基を結合させた繊維を使用することが最も好ましい。このような消臭糸は、臭い成分となる化合物の吸着能が非常に高いため、かがり糸としての使用量で充分に繊維製品に対して消臭機能を付与することができる点で好ましい。以下、このような消臭糸について詳述する。 Among those described above, it is most preferable to use a fiber in which a functional group capable of adsorbing an odorous substance is bonded to the fiber base material itself by performing graft polymerization on the fiber. Such a deodorizing yarn is preferable in that it can sufficiently impart a deodorizing function to a fiber product with a use amount as a warp yarn because it has a very high ability to adsorb compounds serving as odor components. Hereinafter, such deodorizing yarn will be described in detail.
上記グラフト重合は、アニオン性吸着物質(すなわち、アニオン性官能基を有する化合物)、カチオン性吸着物質(すなわち、カチオン性官能基を有する化合物等)の、吸着性物質を繊維を構成する化合物にグラフト重合するものである。このようにして得られた繊維は、繊維基材を構成する物質と化学結合を介して吸着性物質が結合するものであることから、耐洗濯性に優れている。さらに、カチオン性吸着物質と、アニオン性吸着物質とを併用して反応させることもできることから、幅広い物質に対応できる消臭性能を得ることができる。さらに、高い密度でアニオン性官能基やカチオン性官能基を導入することもできることから、繊維自体が有する消臭性能も非常に高い。 The above graft polymerization is performed by grafting an adsorbent substance such as an anionic adsorbent substance (that is, a compound having an anionic functional group) or a cationic adsorbent substance (that is, a compound having a cationic functional group) onto a compound constituting a fiber. Polymerize. The fiber thus obtained is excellent in washing resistance because the adsorptive substance is bonded to the substance constituting the fiber substrate through a chemical bond. Furthermore, since a cationic adsorbing substance and an anionic adsorbing substance can also be reacted together, it is possible to obtain a deodorizing performance that can deal with a wide range of substances. Furthermore, since an anionic functional group and a cationic functional group can be introduced at a high density, the deodorizing performance of the fiber itself is very high.
上記アニオン性官能基としては、例えば、カルボキシル基、スルホン基、リン酸基、スルホエチル基、ホスホメチル基、カルボメチル基等がある。これらの官能基がアンモニア、アミン等の臭い物質を吸着することによって、消臭性能を得ることができる。上記アニオン性吸着物質としては、上述した官能基及び不飽和結合を有する化合物を好適に使用することができる。そのようなカチオン性吸着物質として本発明において有用なものには、例えば、アクリル酸、メタクリル酸、スチレンスルホン酸及びその塩並びに2-アクリルアミド-2-メチルプロパンスルホン酸等を挙げることができる。 Examples of the anionic functional group include a carboxyl group, a sulfone group, a phosphoric acid group, a sulfoethyl group, a phosphomethyl group, and a carbomethyl group. These functional groups adsorb odorous substances such as ammonia and amines to obtain deodorizing performance. As the anionic adsorptive substance, the above-described compounds having a functional group and an unsaturated bond can be suitably used. Examples of such a cationic adsorbing substance useful in the present invention include acrylic acid, methacrylic acid, styrene sulfonic acid and salts thereof, and 2-acrylamido-2-methylpropane sulfonic acid.
上記カチオン性官能基としては、例えば、4級アンモニウム基や、アミノ基、メチルアミノ基、ジメチルアミノ基及びジエチルアミノ基のような1級~3級アミン基がある。好ましいカチオン性官能基は、4級アンモニウム基やアミノ基を挙げることができる。カチオン性官能基は、極性物質の吸着能を有し、且つ、酸性物質、例えば硫化水素やメルカプタン類と中和反応し得る。その結果、酸性物質である臭い物質が除去されることになるのである。 Examples of the cationic functional group include a quaternary ammonium group and primary to tertiary amine groups such as an amino group, a methylamino group, a dimethylamino group, and a diethylamino group. Preferred cationic functional groups include quaternary ammonium groups and amino groups. The cationic functional group has the ability to adsorb polar substances and can neutralize with acidic substances such as hydrogen sulfide and mercaptans. As a result, the odorous substance that is an acidic substance is removed.
上記カチオン性吸着物質は、上述した官能基及び不飽和結合を有する化合物を好適に使用することができる。そのようなカチオン性吸着物質としては、例えば、ビニルベンジルトリメチルアンモニウム塩、ジエチルアミノエチルメタクリレート、ジメチルアミノエチルアクリレート、ジメチルアミノエチルメタクリレート、ジエチルアミノエチルアクリレート、ジエチルアミノメチルメタクリレート、ターシャリーブチルアミノエチルアクリレート、ターシャリーブチルアミノエチルメタクリレート及びジメチルアミノプロピルアクリルアミドを挙げることができる。これらの2種以上を同時に使用することもできる。 As the cationic adsorbing material, the above-described compound having a functional group and an unsaturated bond can be preferably used. Such cationic adsorbents include, for example, vinylbenzyltrimethylammonium salt, diethylaminoethyl methacrylate, dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminomethyl methacrylate, tertiary butylaminoethyl acrylate, tertiary butyl. Mention may be made of aminoethyl methacrylate and dimethylaminopropylacrylamide. Two or more of these can be used simultaneously.
これらのうち、特に有用な反応性単量体はビニルベンジルトリメチルアンモニウム塩やジエチルアミノエチルメタクリレートである。また、カチオン性解離基に変換可能な基を有する反応性単量体もまた、本発明において有用である。そのような反応性単量体には、例えばクロロメチルスチレンがある。 Of these, particularly useful reactive monomers are vinylbenzyltrimethylammonium salt and diethylaminoethyl methacrylate. A reactive monomer having a group that can be converted into a cationic dissociation group is also useful in the present invention. An example of such a reactive monomer is chloromethylstyrene.
上記グラフト重合においては、親水性基を有する化合物も併用してグラフト重合をおこなうものであってもよい。「親水性基」とは、水に対して親和性を有し、且つ、水と接触した場合にイオン解離しない基(つまり、ノニオン)をいう。かかる親水性基は、空気中に存在する水分子を捕捉することができ、捕捉された水分子は、本発明の吸着材料表面において吸着水層を形成し、極性物質を溶解し、及び/又は、イオン性物質を解離せしめることができる。なお、かかる親水性基が、水中においても空気中と同様の作用をすることはいうまでもない。 In the graft polymerization, a graft polymerization may be performed using a compound having a hydrophilic group in combination. “Hydrophilic group” refers to a group that has an affinity for water and does not ionically dissociate when contacted with water (ie, a nonion). Such hydrophilic groups can trap water molecules present in the air, the trapped water molecules form an adsorbed water layer on the surface of the adsorbing material of the present invention, dissolve polar substances, and / or The ionic substance can be dissociated. Needless to say, such a hydrophilic group acts in water as well as in air.
上記親水性基は、例えば、水酸基、ヒドロキシアルキル基(ここで、アルキル基は好ましくは低級アルキル基である)、アミノ基又はピロリドニル基を挙げることができる。より好ましい親水性基としては、水酸基やヒドロキシアルキル基を挙げることができる。
上記親水性官能基を有する化合物としては、上述した親水性官能基及び不飽和結合を有する化合物を好適に使用することができる。
Examples of the hydrophilic group include a hydroxyl group, a hydroxyalkyl group (wherein the alkyl group is preferably a lower alkyl group), an amino group, and a pyrrolidonyl group. More preferred hydrophilic groups include a hydroxyl group and a hydroxyalkyl group.
As the compound having a hydrophilic functional group, the above-described compound having a hydrophilic functional group and an unsaturated bond can be suitably used.
上記親水性官能基を有する化合物として本発明において有用なものには、例えば、ヒドロキシエチルメタクリレート、ヒドロキシプロピルアクリレート、ビニルピロリドン、ジメチルアクリルアミド、エチレングリコールモノメタクリレート、エチレングリコールモノアクリレート、エチレングリコールモノメタクリレート、エチレングリコールジアクリレート、エチレングリコールジメタクリレート、トリエチレングリコールジアクリレート及びトリエチレングリコールメタクリレートがある。これらのうち、特に有用な反応性単量体にはヒドロキシエチルメタクリレートやビニルピロリドンを挙げることができる。 Examples of compounds useful in the present invention as the compound having a hydrophilic functional group include, for example, hydroxyethyl methacrylate, hydroxypropyl acrylate, vinyl pyrrolidone, dimethylacrylamide, ethylene glycol monomethacrylate, ethylene glycol monoacrylate, ethylene glycol monomethacrylate, ethylene There are glycol diacrylate, ethylene glycol dimethacrylate, triethylene glycol diacrylate and triethylene glycol methacrylate. Among these, particularly useful reactive monomers include hydroxyethyl methacrylate and vinyl pyrrolidone.
上記グラフト重合においては、上述したような各種成分から2種以上併用して使用するものであってもよい。
2種以上併用する場合の官能基の好ましい組み合わせには、具体的には、スルホン基とカルボキシル基、4級アンモニウム基、及びヒドロキシエチル基のようなものがある。また、本発明における官能基の好ましい別の組み合わせには、具体的には、スルホン基とカルボキシル基、4級アンモニウム基、及びピロリドニル基のようなものがある。
In the graft polymerization, two or more of the above-mentioned various components may be used in combination.
Specific examples of preferred combinations of functional groups when two or more are used in combination include a sulfone group, a carboxyl group, a quaternary ammonium group, and a hydroxyethyl group. Further, another preferred combination of functional groups in the present invention is specifically a sulfone group, a carboxyl group, a quaternary ammonium group, and a pyrrolidonyl group.
カチオン性官能基を有する化合物とアニオン性官能基を有する化合物とを併用してグラフト重合を行うと、幅広い臭い物質を吸着することができる繊維を得ることができる点で好ましい。 When graft polymerization is performed using a compound having a cationic functional group and a compound having an anionic functional group in combination, it is preferable in that a fiber capable of adsorbing a wide range of odorous substances can be obtained.
上記グラフト重合を行う基材となる繊維としては特に限定されず、たとえば、ポリエステル糸、ポリアミド糸、ポリアクリル糸、レーヨン糸などの合成繊維、半合成繊維、綿糸、羊毛、絹糸等の天然繊維などを挙げることができる。特に、綿糸、ナイロン糸及び/又はポリエステル糸を使用することが好ましい。なかでも、ポリアミド糸及び綿糸は分子構造内に官能基を導入可能な構造を持ち、他の繊維と紡績し使用する際の相性が良いという点で特に好ましいものである。 There are no particular limitations on the fibers used as the base material for the graft polymerization, and examples thereof include synthetic fibers such as polyester yarn, polyamide yarn, polyacrylic yarn, and rayon yarn, semi-synthetic fibers, natural fibers such as cotton yarn, wool, and silk yarn. Can be mentioned. In particular, it is preferable to use cotton yarn, nylon yarn and / or polyester yarn. Among these, polyamide yarns and cotton yarns are particularly preferable in that they have a structure capable of introducing a functional group into the molecular structure and have good compatibility when used by spinning with other fibers.
上記基材となる繊維は、長繊維、短繊維の任意の形態のものを使用することができる。また、紡績糸、撚糸、加工糸等であってもよい。後の工程で消臭かがり糸として使用することを考慮すれば、綿紡績糸又は、ナイロン長繊維であることが特に好ましい。 The fiber used as the base material may be any form of long fiber and short fiber. Further, spun yarn, twisted yarn, processed yarn, and the like may be used. In consideration of use as a deodorized yarn in a later step, cotton spun yarn or nylon long fiber is particularly preferable.
上記グラフト重合において、繊維基材上に結合させる吸着性物質は、繊維基材の重量に対して、3~80重量%となる割合で結合させることが好ましい。当該範囲内の結合量とすることで、良好な消臭・防臭性能を得ることができる点で好ましい。 In the graft polymerization, the adsorptive substance to be bonded on the fiber substrate is preferably bonded at a ratio of 3 to 80% by weight with respect to the weight of the fiber substrate. By setting it as the coupling | bonding amount in the said range, it is preferable at the point which can obtain favorable deodorizing and deodorizing performance.
上記消臭糸は、消臭性能が高いものを使用することが好ましい。例えば、一般社団法人繊維評価技術協議会が示す、SEKマーク繊維製品認証基準に記載された検知管法によって、アンモニア100ppm初期濃度での試験を行った場合、2時間後のアンモニア濃度が1.5ppm以下となるような消臭機能を有する繊維を使用することが好ましい。 It is preferable to use the deodorizing yarn having high deodorizing performance. For example, when a test at an initial concentration of 100 ppm of ammonia is performed by the detector tube method described in the SEK mark fiber product certification standard shown by the Japan Fiber Evaluation Technology Council, the ammonia concentration after 2 hours is 1.5 ppm. It is preferable to use a fiber having a deodorizing function as follows.
上記グラフト重合を行った後の繊維を使用して公知の方法によって紡績糸、撚糸、加工糸等を製造し、これを消臭かがり糸として使用するものであってもよい。この場合、グラフト重合を行っていない通常の繊維と併用して紡績糸、撚糸、加工糸等を製造したものであってもよい。この場合、紡績糸、撚糸、加工糸等を構成する糸のうち、30重量%以上の割合で、上述した繊維に対するグラフト重合を行うことによって、繊維基材自体に臭い物質を吸着するような官能基を結合させた繊維を使用することが好ましい。当該繊維の使用量が30重量%未満であると、充分な消臭性能を付与することができなくなる恐れがある点で好ましいものではない。また、紡績糸、撚糸、加工糸等の加工を行った後の繊維に対して、消臭糸とするための処理を行ったものであってもよい。 A spun yarn, a twisted yarn, a processed yarn or the like may be produced by a known method using the fibers after the graft polymerization, and used as a deodorized yarn. In this case, spun yarns, twisted yarns, processed yarns and the like may be produced in combination with ordinary fibers not subjected to graft polymerization. In this case, among the yarns constituting the spun yarn, the twisted yarn, the processed yarn, etc., a function that adsorbs the odorous substance to the fiber base material itself by performing graft polymerization on the above-described fiber at a ratio of 30% by weight or more. It is preferred to use fibers with bonded groups. If the amount of the fiber used is less than 30% by weight, it is not preferable because there is a possibility that sufficient deodorizing performance cannot be imparted. Moreover, what processed the fiber after processing, such as a spun yarn, a twisted yarn, and a processed yarn, to make a deodorant yarn may be performed.
更に、カチオン吸着性の繊維とアニオン吸着性の繊維とを組み合わせて撚糸としたものを使用することもできる。これによって、多くの種類の臭い物質に対応することができる繊維製品を得ることができる点で好ましい。 Furthermore, a twisted yarn obtained by combining a cation-adsorptive fiber and an anion-adsorptive fiber can also be used. This is preferable in that a fiber product that can deal with many kinds of odorous substances can be obtained.
上記かがり糸は、引張強度が500cN以上であることが好ましい。消臭糸は消臭性能を付与するための処理を行うことによって、引張強度が低下しやすい。引張強度が十分でないかがり糸を使用すると、かがり縫いの際に糸切れを生じやすく、更に、繊維製品として使用している際にも、ほつれなどの問題を生じやすくなる。よって、引張強度を高めるための工夫を行うことによって、上記引張強度の消臭糸とすることで、このような問題が生じないようにすることが好ましい。
上述した短繊維である消臭糸を使用して上記引張強度のかがり糸とするためには、一部又は全部に消臭糸を使用した2本撚又は3本撚の撚糸とすることが好ましい。以下、このような撚糸について詳述する。
It is preferable that the above-mentioned warp yarn has a tensile strength of 500 cN or more. The deodorant yarn tends to have a reduced tensile strength by performing a treatment for imparting deodorant performance. When a warp thread having insufficient tensile strength is used, thread breakage tends to occur during the overlock stitching, and further, problems such as fraying easily occur when used as a textile product. Therefore, it is preferable not to cause such a problem by devising the deodorizing yarn having the above-described tensile strength by devising to increase the tensile strength.
In order to use the above-mentioned deodorant yarn, which is a short fiber, to obtain the above-mentioned tensile strength, it is preferable to use a double twisted or three twisted twisted yarn using the deodorized yarn in part or in whole. . Hereinafter, such a twisted yarn will be described in detail.
(短繊維である消臭糸を使用した撚糸)
まず、消臭糸が短繊維である場合について、以下に詳述する。短繊維を使用する場合としては、綿糸を消臭糸の基材繊維として使用する場合を挙げることができる。この場合、短繊維の状態でグラフト重合を行ったのちに紡績糸とするもの、紡績糸にグラフト重合を行ったものを使用することができる。
(Twisted yarn using deodorant yarn, which is a short fiber)
First, the case where the deodorizing yarn is a short fiber will be described in detail below. An example of the case where short fibers are used is a case where cotton yarn is used as a base fiber for deodorant yarn. In this case, it is possible to use a spun yarn after performing graft polymerization in a short fiber state, or a spun yarn obtained by graft polymerization.
上記撚糸として使用する場合は、撚糸を構成するすべての糸を消臭糸としてもよいが、少なくとも1本を通常の繊維(すなわち、消臭処理を施していない繊維)としてもよい。消臭糸は、通常の繊維よりも強度が劣るものとなることが多い。このため、強度を補強する目的で通常の繊維と組み合わせて撚糸とすることが好ましい。 When used as the above-described twisted yarn, all yarns constituting the twisted yarn may be deodorized yarns, but at least one may be normal fibers (that is, fibers not subjected to deodorizing treatment). Deodorant yarn often has lower strength than normal fibers. For this reason, in order to reinforce the strength, it is preferable to use twisted yarn in combination with ordinary fibers.
上記通常の繊維としては、特に限定されず、消臭糸と同じ種類の繊維であっても、異なる種類の繊維であってもよいが、同一種の繊維を使用することが好ましい。 The normal fiber is not particularly limited and may be the same type of fiber as the deodorant yarn or a different type of fiber, but it is preferable to use the same type of fiber.
上記撚糸を構成する紡績糸は、消臭糸、通常の繊維ともに、糸番手が10~50番手であることが好ましい。糸番手が10番手未満であると、通常のかがり縫い用ミシンの針穴に入らないという問題や、かがり糸に使用して製品化した場合、かがり部分が太くなりすぎて摩擦で皮膚を刺激するという点で好ましいものではない。更に、糸番手が50番手以上であると、強度が不充分になるおそれがあるという問題を生じるおそれがある。 The spun yarn constituting the twisted yarn preferably has a yarn count of 10 to 50 for both the deodorant yarn and the normal fiber. If the yarn count is less than 10th, it will not fit into the needle hole of a normal overlock sewing machine, and when used as a overlock thread, the overlock will become too thick and the skin will be stimulated by friction. That is not preferable. Furthermore, if the yarn count is 50 or more, there is a risk that the strength may be insufficient.
撚糸は、通常、下撚り(すなわち、撚糸を構成する繊維それぞれの撚り)を行った複数本の繊維を組み合わせた後に上撚り(撚糸全体としての撚り)を行うことによって得られるものである。本発明において使用する撚糸は、下撚りと上撚りとは、撚り方向が逆であることが好ましい。すなわち、下撚りがZ撚りである場合は、上撚りをS撚りとし、下撚りがS撚りである場合は上撚りをZ撚りとすることが好ましい。このような撚りとすることで、撚糸の撚り戻りが生じにくくなる点で好ましいものである。 The twisted yarn is usually obtained by combining a plurality of fibers subjected to a lower twist (that is, twisting of each of the fibers constituting the twisted yarn) and then performing an upper twist (twisting as a whole twisted yarn). In the twisted yarn used in the present invention, it is preferable that the twisting direction is reverse between the lower twist and the upper twist. That is, when the lower twist is a Z twist, the upper twist is preferably an S twist, and when the lower twist is an S twist, the upper twist is preferably a Z twist. Such twisting is preferable in that the twisted yarn is less likely to be untwisted.
上記下撚りは、撚り回数を15~30回/インチとすることが好ましい。このような範囲の撚り回数とすることで、縫製糸にした場合の強度を確保することが可能になり、工業ミシンによる高速な縫製にも耐えうることが出来る
という点で好ましいものとなる。
It is preferable that the number of twists is 15 to 30 times / inch. By setting the number of twists in such a range, it is possible to secure the strength when used as a sewing thread and it is preferable in that it can withstand high-speed sewing by an industrial sewing machine.
上記上撚りは、撚り回数を15~30回/インチとすることが好ましい。このような範囲の撚り回数とすることで、縫製糸にした場合の強度を確保することが可能になり、工業ミシンによる高速な縫製にも耐えうることが出来るという点で好ましいものとなる。 The above twist is preferably 15 to 30 times / inch. By setting the number of twists in such a range, it is possible to secure the strength when used as a sewing thread and it is preferable in that it can withstand high-speed sewing by an industrial sewing machine.
上記撚糸は、ワックスを付与したものであることが好ましい。これによって、縫製時の糸の滑りがよくなる点で好ましい。 The twisted yarn is preferably provided with wax. This is preferable in that the sliding of the thread during sewing is improved.
(長繊維である消臭繊維)
次いで、消臭糸が長繊維である場合について、以下詳述する。長繊維である消臭繊維は、基材となる繊維としては、ナイロン長繊維、ポリエステル長繊維等を挙げることができる。上記基材となる繊維としては、トータル繊度が50~200dtexとなるマルチフィラメントあることが好ましい。当該範囲のものを使用することで、縫製糸にした場合に十分な消臭機能と強度を確保出来るという点で好ましいものである。
(Deodorant fiber which is long fiber)
Next, the case where the deodorizing yarn is a long fiber will be described in detail below. The deodorant fiber which is a long fiber includes nylon long fiber, polyester long fiber and the like as a fiber serving as a base material. The fiber serving as the substrate is preferably a multifilament having a total fineness of 50 to 200 dtex. Use of a material in this range is preferable in that a sufficient deodorizing function and strength can be secured when the sewing thread is used.
上記長繊維である消臭繊維は、比較的強度が高いものとすることができるため、撚糸とすることは必ずしも必要ではなく、通常のマルチフィラメントやこれを使用した引き揃え糸を使用することもできる。
長繊維である消臭繊維を撚糸として使用する場合は、2本又は3本の糸を撚りあわせて撚糸とすることが好ましい。その際、撚糸を構成するすべての糸を消臭糸としてもよいが、少なくとも1本を通常の繊維(すなわち、消臭処理を施していない繊維)を使用してもよい。消臭糸は、通常の繊維よりも強度が劣るものとなることが多い。このため、強度を補強する目的で通常の繊維と組み合わせて撚糸とすることが好ましい。上記通常の繊維としては、特に限定されず、消臭糸と同じ種類の繊維であっても、異なる種類の繊維であってもよいが、同一種の繊維を使用することが好ましい。
Since the deodorizing fiber which is the above-mentioned long fiber can have a relatively high strength, it is not always necessary to use a twisted yarn, and an ordinary multifilament or a drawn yarn using the same may be used. it can.
When using the deodorizing fiber which is a long fiber as a twisted yarn, it is preferable to twist two or three yarns into a twisted yarn. At that time, all the yarns constituting the twisted yarn may be deodorized yarns, but at least one normal fiber (that is, fibers not subjected to deodorizing treatment) may be used. Deodorant yarn often has lower strength than normal fibers. For this reason, in order to reinforce the strength, it is preferable to use twisted yarn in combination with ordinary fibers. The normal fiber is not particularly limited and may be the same type of fiber as the deodorant yarn or a different type of fiber, but it is preferable to use the same type of fiber.
消臭かがり糸において、伸縮性が必要とされる用途もある。これは、インナーシャツやセーター等の伸縮性の高い衣服用途においては、かがり糸自体にも伸縮性が必要となる。このような場合に、長繊維からなる消臭糸を使用する場合は、嵩高加工糸を使用することが好ましい。嵩高加工を行うことによって、消臭かがり糸も伸縮性を有するものとすることができる点で好ましい。 There is also an application in which stretchability is required in the deodorized yarn. This means that in the use of clothes having high elasticity such as inner shirts and sweaters, the warp yarn itself needs to be elastic. In such a case, when using a deodorizing yarn made of long fibers, it is preferable to use a bulky processed yarn. By carrying out the bulky processing, the deodorized yarn is preferred in that it can also be stretchable.
上記長繊維を使用した消臭糸は、ワックスを付与したものであることが好ましい。これによって、縫製時の糸の滑りがよくなる点で好ましい。 It is preferable that the deodorizing yarn using the above-mentioned long fibers is provided with wax. This is preferable in that the sliding of the thread during sewing is improved.
(湿式条件での消臭性能)
本発明において使用するかがり糸は、以下に詳述する湿式条件で測定した消臭性能がアンモニア減少率90%以上であることが好ましい。すなわち、このような高い消臭性能を有するかがり糸を使用することで、消臭機能はより優れたものとなる点で好ましい。上記アンモニア減少率は95%以上であることがより好ましく、99%以上であることが更に好ましい。なお、湿式条件で測定を行うのは、衣類の着用時において、臭いが発生しやすい部位は汗をかきやすい部位であることから、汗によって衣類が湿った状態に対応させたものである。
(Deodorization performance under wet conditions)
The warp yarn used in the present invention preferably has an ammonia deodorization rate of 90% or more as measured by wet conditions described in detail below. That is, it is preferable in that the deodorizing function is further improved by using the yarn having such a high deodorizing performance. The ammonia reduction rate is more preferably 95% or more, and further preferably 99% or more. Note that the measurement is performed under wet conditions because when the garment is worn, the portion where the odor is likely to occur is a portion where the garment is moistened by sweat because the portion where the odor is likely to be generated is easily sweated.
(湿式条件での消臭性能の測定方法)
容量5リットルのテドラーバッグ又はスマートバッグ中に、かがり糸1gと3Lの空気を入れ、1mLの水を滴下する。この内部に400ppm濃度のアンモニアを封入し、空気中のアンモニア濃度を経時的に測定する。2時間経過後のアンモニア濃度について、試験開始時の400ppmに対して、どれだけが繊維に吸着されたかを%で算出する。
(Measurement method of deodorant performance under wet conditions)
Into a 5 liter Tedlar bag or smart bag, put 1 g of warp yarn and 3 L of air, and drop 1 mL of water. A 400 ppm concentration of ammonia is sealed inside, and the ammonia concentration in the air is measured over time. With respect to the ammonia concentration after 2 hours, how much is adsorbed on the fiber with respect to 400 ppm at the start of the test is calculated in%.
(繊維製品)
本発明の繊維製品は、上述したような消臭糸をかがり糸として使用した点に特徴を有するものである。このような繊維製品の一例を示す図として図1及び図2を示した。
(Fiber products)
The textile product of the present invention is characterized in that the deodorizing yarn as described above is used as a warp yarn. As an example of such a textile product, FIGS. 1 and 2 are shown.
図1は、通常の肌着の形状を示す図である。なお、図1は裏返した状態を示している。使用時には図1の状態のものを裏表が逆として、かがり縫い部分が隠れるように使用されることが通常である。このような肌着は通常、編み物として形成され、襟ぐり3、袖ぐり4、袖の開口部5、脇6、裾7、肩8等においてはかがり糸によるかがり縫いがなされている。本発明の繊維製品はこれらの部位におけるかがり縫いを上記消臭糸によって行うものである。図2には、図1に2として示した箇所の拡大図を示した。図1の2の箇所においては、肩8の一部であり、縫製が行われている。更に、端部でのほつれを防止するためにかがり縫いがかがり糸1によってなされている。当該かがり糸1として、上記消臭糸を使用するものである。 FIG. 1 is a diagram showing the shape of a normal underwear. In addition, FIG. 1 has shown the state turned over. In use, it is usually used so that the overlocked portion is hidden with the reverse side upside down in the state of FIG. Such an undergarment is usually formed as a knitted fabric, and the neckline 3, the armhole 4, the opening portion 5 of the sleeve, the side 6, the hem 7, the shoulder 8, and the like are overlocked with an overlock thread. The textile product of the present invention is used for the above-mentioned deodorant yarn to carry out the stitching at these portions. FIG. 2 shows an enlarged view of the portion shown as 2 in FIG. 1 is a part of the shoulder 8 and is sewn. Further, overlock stitching is performed by the overlock thread 1 to prevent fraying at the end. The deodorizing yarn is used as the yarn 1.
かがり縫いは、織物、編物等の端部においてほつれを防止するために、ロックミシン等によって縫いを行うものであり、このような方法として公知のかがり縫いを行うことができる。例えば、一本針オーバーロック縫い、二本針オーバーロック縫い、インターロック縫い等の公知の方法によって行うことができる。 Overlock stitching is performed by a lock sewing machine or the like in order to prevent fraying at the end of a woven fabric, knitted fabric, or the like, and a well-known overlock stitch can be performed as such a method. For example, it can be performed by a known method such as one-needle overlock stitching, two-needle overlock stitching, or interlock stitching.
これらのかがり縫いは、そのすべてを上記消臭糸によって行うものであってもよいが、一部においてのみ上記消臭糸によるかがり縫いを行うものであってもよい。すなわち、人体において特に臭いを発生しやすい部位がある。たとえば、腋、首回りは臭いが発生しやすい。このため、例えば、袖ぐり、襟ぐりのかがり縫いを上記消臭糸によって行い、その他の部分のかがり縫いは通常の繊維によって行うものであってもよい。 All of these over stitches may be performed with the deodorizing yarn, but only over a portion thereof with the deodorizing yarn may be performed. That is, there is a part that is particularly likely to generate odor in the human body. For example, the heel and neck are likely to smell. For this reason, for example, the neckline and neckline stitches may be performed with the deodorizing thread, and the other portions may be stitched with ordinary fibers.
また、本発明においては、上記消臭糸をかがり糸として使用するものであるが、同時に縫製糸や生地の一部又は全部に上記消臭糸を使用することを妨げるものではない。縫製糸や生地において上記消臭糸を使用すると、更に本発明の繊維製品の消臭機能を向上させることができる。但し、繊維製品強度やコストという観点を考慮するなら、上記消臭糸は、消臭かがり糸のみに使用することがより好ましい。 Moreover, in this invention, although the said deodorizing thread | yarn is used as a warp thread | yarn, it does not prevent using the said deodorizing thread | yarn for part or all of a sewing thread | yarn or cloth simultaneously. When the deodorizing yarn is used in sewing threads and fabrics, the deodorizing function of the textile product of the present invention can be further improved. However, from the viewpoint of fiber product strength and cost, the deodorizing yarn is more preferably used only for the deodorizing yarn.
本発明の繊維製品は、作業着、肌着、靴下、寝具、洋服、コート、セーター、ワイシャツ、寝間着、和服、手袋又は帽子等の用途において使用することができる。さらには、乗り物内(飛行機、列車等)の座席カバー、家庭用のソファーカバー、タオル、布巾、トイレカバー、スリッパ等、臭いの発生が生じやすい任意の分野において使用することができる。 The textile product of the present invention can be used in applications such as work clothes, underwear, socks, bedding, clothes, coats, sweaters, shirts, nightclothes, Japanese clothes, gloves or hats. Furthermore, it can be used in any field where odor is likely to occur, such as a seat cover in a vehicle (airplane, train, etc.), a sofa cover for home use, a towel, a cloth towel, a toilet cover, and slippers.
以下に、実施例を挙げて本発明を説明するが、本発明はこれらの実施例によって何ら限定されるものではない。 EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited to these examples.
(実施例1)
40番手単糸の綿糸の不純物を取り除いた後、グラフト重合を行うことによって、臭い物質を吸着する官能基を結合させて消臭糸を製造した。この消臭糸について、SEKマーク繊維製品認証基準に記載された検知管法によって、アンモニア100ppm初期濃度での試験を行ったところ、2時間後のアンモニア濃度が0.2ppmという結果が得られた。また、JIS L 1095に記載された一般紡績糸試験方法によって、引張強度の試験を行ったところ、330cNという結果が得られた。
Example 1
After removing impurities from the 40th cotton yarn, graft polymerization was performed to bond a functional group that adsorbs odorous substances to produce a deodorant yarn. When this deodorized yarn was tested at an initial concentration of 100 ppm of ammonia by the detector tube method described in the SEK mark textile product certification standard, a result that the ammonia concentration after 2 hours was 0.2 ppm was obtained. Further, when a tensile strength test was performed by the general spun yarn test method described in JIS L 1095, a result of 330 cN was obtained.
上記の消臭糸2本と強度補強用のレギュラー糸1本を撚り合わせた後、縫製時の撚り戻りを防止する為に約80℃で熱セットを行い、40番手3本撚りの消臭かがり糸を製造した。製造に際しては、消臭糸とレギュラー糸それぞれについて、下撚りとして、Z撚り方向に、20回/インチの撚りをかけた。更に、上撚りとしてS撚り方向に、18回/インチ撚りをかけた。さらに、縫製時の滑りを良くする為にワックス剤処理を行った。この消臭かがり糸について、JIS L 1095に記載された一般紡績糸試験方法によって、引張強度の試験を行ったところ、902cNという結果が得られた。 After twisting the above two deodorant yarns and one regular yarn for strength reinforcement, heat set at about 80 ° C to prevent untwisting at the time of sewing. Yarn was produced. At the time of production, each of the deodorized yarn and the regular yarn was twisted 20 times / inch in the Z twist direction as a lower twist. Further, 18 times / inch twist was applied in the S twist direction as the upper twist. Further, a wax agent treatment was performed to improve slippage during sewing. When this deodorized yarn was tested for tensile strength by a general spun yarn test method described in JIS L 1095, a result of 902 cN was obtained.
更に、得られた消臭かがり糸について、上述した湿式条件での消臭試験を行ったところ、アンモニア減少率は、99.9%であった。 Furthermore, when the obtained deodorized yarn was subjected to the deodorization test under the above-mentioned wet conditions, the ammonia reduction rate was 99.9%.
このようにして得られた撚糸を消臭かがり糸として使用して、図1に示す形状を有する肌着を製造した。製造に際しては、生地としてはポリエステル100%を使用し、縫製糸としては綿紡績糸40/3を使用して、一般的な編み工程及び縫製工程によって製造を行った。消臭かがり糸の使用量は、肌着全体に対して4.3g/着であった。 The underwear having the shape shown in FIG. 1 was produced using the twisted yarn thus obtained as a deodorizing yarn. In the production, 100% polyester was used as the fabric, and cotton spun yarn 40/3 was used as the sewing yarn, and the production was performed by a general knitting process and a sewing process. The amount of deodorized yarn used was 4.3 g / wear for the entire underwear.
得られた肌着において、かがり縫製部分を含むように10×10cmで切断し、これに対して消臭機能試験を行った。消臭かがり糸の使用量は、試料全体に対して0.4g/10×10cm 重量%であった。消臭機能試験方法は以下に示す方法で行った。
(消臭試験方法)
容量5リットルのテドラーバッグ又はスマートバッグに3リットルの空気を入れ、更に、100ppm濃度のアンモニアを封入した。この内部の空気中のアンモニア濃度を経時的に測定した(ブランク試験)。同様の試験をテドラーバッグ中に上述した試験サンプルを封入した状態で行った。
結果を以下に示す。なお、本発明で使用した消臭糸自体についても同様の試験を行った。その場合は、2時間後のアンモニア濃度が0.2ppm(減少率99.8%)という結果が得られた。
In the obtained underwear, it cut | disconnected by 10x10 cm so that the overlock sewing part might be included, and the deodorizing function test was done with respect to this. The amount of deodorized yarn used was 0.4 g / 10 × 10 cm 2% by weight relative to the entire sample. The deodorant function test method was performed by the method shown below.
(Deodorization test method)
3 liters of air was put into a 5 liter Tedlar bag or smart bag, and 100 ppm of ammonia was further enclosed. The ammonia concentration in the internal air was measured over time (blank test). A similar test was performed with the above-described test sample sealed in a Tedlar bag.
The results are shown below. In addition, the same test was done also about the deodorizing thread | yarn itself used by this invention. In that case, the result that the ammonia concentration after 2 hours was 0.2 ppm (reduction rate 99.8%) was obtained.
(比較例)
比較例として、実施例の肌着の生地製造に使用したポリエステル繊維を使用して得られたポリエステル生地(消臭糸によるかがり縫いなし)についても、同様の試験を行った。
(Comparative example)
As a comparative example, a similar test was conducted on a polyester fabric obtained by using the polyester fiber used in the manufacture of the undergarment fabric of the example (no over stitching with deodorant yarn).
Figure JPOXMLDOC01-appb-T000001
 
 
Figure JPOXMLDOC01-appb-T000001
 
 
表1の結果から、本発明の繊維製品は、短時間で優れた消臭効果を示すものであることが明らかとなった。 From the results in Table 1, it was revealed that the fiber product of the present invention exhibits an excellent deodorizing effect in a short time.
(実施例2)
78dT単糸にグラフト重合を行うことによって、臭い物質を吸着する官能基を結合させて消臭糸を製造した。上記の消臭糸2本と強度補強用のレギュラー糸1本を撚り合わせて消臭かがり糸を製造した。製造に際しては、消臭糸とレギュラー糸それぞれについて、下撚りとして、Z撚り方向に、750T/Mの撚りをかけた。更に、上撚りとしてS撚り方向に、630T/M撚りをかけた。さらに、縫製時の滑りを良くする為にワックス剤処理を行った。
このようにして得られたかがり糸は、上述した湿式条件での消臭試験を行ったところ、アンモニア減少率は、99.6%であった。
 
(Example 2)
By performing graft polymerization on the 78dT single yarn, a functional group that adsorbs the odorous substance was bonded to produce a deodorant yarn. Two deodorant yarns described above and one regular yarn for reinforcing strength were twisted together to produce a deodorized yarn. At the time of production, each of the deodorized yarn and the regular yarn was twisted at 750 T / M in the Z twist direction as a lower twist. Further, a 630 T / M twist was applied in the S twist direction as an upper twist. Further, a wax agent treatment was performed to improve slippage during sewing.
The warp yarn thus obtained was subjected to the deodorization test under the wet conditions described above, and the ammonia reduction rate was 99.6%.
このようにして得られた撚糸を消臭かがり糸として使用して、図1に示す形状を有するカーディガンを製造した。製造に際しては、生地としては、アクリル70%+毛30%を使用し、縫製糸としてはナイロンフィラメント糸78dT/3を使用して、一般的な編み工程及び縫製工程によって製造を行った。
このようにして得られたカーディガンの着用テストを行ったところ、優れた消臭機能が確認できた。
A cardigan having the shape shown in FIG. 1 was produced using the twisted yarn thus obtained as a deodorizing yarn. In the production, 70% acrylic + 30% hair was used as the fabric, and nylon filament yarn 78dT / 3 was used as the sewing yarn, and the production was performed by a general knitting process and a sewing process.
When a cardigan wearing test thus obtained was tested, an excellent deodorizing function was confirmed.
本発明の繊維製品は、作業着、肌着、靴下又は寝具等の用途において使用することができる。さらには、乗り物内(飛行機、列車等)の座席カバー、家庭用のソファーカバー、タオル、布巾、トイレカバー、スリッパ等の任意の製品において使用することができる。 The textile product of the present invention can be used in applications such as work clothes, underwear, socks or bedding. Furthermore, it can be used in any product such as a seat cover in a vehicle (airplane, train, etc.), a sofa cover for home use, a towel, a cloth towel, a toilet cover, and slippers.
1 かがり糸
2 図2において拡大した部分
3 襟ぐり
4 袖ぐり
5 袖の開口部
6 脇
7 裾
8 肩
DESCRIPTION OF SYMBOLS 1 Warp thread 2 The part expanded in FIG. 3 Neckline 4 Armhole 5 Sleeve opening 6 Side 7 Bottom 8 Shoulder

Claims (12)

  1. かがり糸として消臭糸を使用して得られたものであることを特徴とする繊維製品。 A fiber product obtained by using a deodorizing yarn as a warp yarn.
  2. かがり糸は、引張強度が500cN以上である請求項1記載の繊維製品。 The textile product according to claim 1, wherein the warp yarn has a tensile strength of 500 cN or more.
  3. かがり糸は、湿式条件での消臭性能がアンモニア減少率90%以上である請求項1又は2記載の繊維製品。 3. The textile product according to claim 1 or 2, wherein the yarn has a deodorizing performance under a wet condition of an ammonia reduction rate of 90% or more.
  4. かがり糸は、綿糸、ナイロン糸及び/又はポリエステル糸に対してグラフト重合によって吸着性物質を結合させて得られた繊維である請求項1~3のいずれか1記載の繊維製品。 The fiber product according to any one of claims 1 to 3, wherein the warp yarn is a fiber obtained by binding an adsorbent substance to a cotton yarn, a nylon yarn and / or a polyester yarn by graft polymerization.
  5. かがり糸は、3本撚又は2本撚の撚糸である請求項1~4のいずれか1記載の繊維製品。 The textile product according to any one of claims 1 to 4, wherein the yarn is a twisted yarn of three twists or two twists.
  6. かがり糸は、少なくとも1本の消臭繊維と少なくとも1本の消臭繊維ではない繊維とを使用して得られた撚糸である請求項5記載の繊維製品。 The textile product according to claim 5, wherein the yarn is a twisted yarn obtained by using at least one deodorizing fiber and at least one fiber that is not a deodorizing fiber.
  7. かがり糸は、短繊維からなり太さが10~50番手である繊維を使用して得られた撚糸である請求項1~6のいずれか1記載の繊維製品。 The fiber product according to any one of claims 1 to 6, wherein the yarn is a twisted yarn obtained by using fibers made of short fibers and having a thickness of 10 to 50.
  8. 撚糸は、下撚が15~30回/インチである請求項5~7のいずれか1に記載の繊維製品。 The textile product according to any one of claims 5 to 7, wherein the twisted yarn has a lower twist of 15 to 30 turns / inch.
  9. 撚糸は、上撚が15~50回/インチである請求項5~8のいずれか1に記載の繊維製品。 The textile product according to any one of claims 5 to 8, wherein the twisted yarn has an upper twist of 15 to 50 turns / inch.
  10. 撚糸は、下撚と上撚との撚り方向が逆である請求項5~9のいずれか1に記載の繊維製品。 The textile product according to any one of claims 5 to 9, wherein in the twisted yarn, the twist directions of the lower twist and the upper twist are opposite.
  11. かがり糸は、長繊維からなり、トータル繊度が50~200dTである請求項1~4のいずれ1に記載の繊維製品。 The fiber product according to any one of claims 1 to 4, wherein the yarn is made of long fibers and has a total fineness of 50 to 200 dT.
  12. 作業着、肌着、靴下、寝具、洋服、コート、セーター、ワイシャツ、寝間着、和服、手袋又は帽子である請求項1~10のいずれかに記載の繊維製品。 The textile product according to any one of claims 1 to 10, which is a work clothes, underwear, socks, bedding, clothes, coat, sweater, shirt, sleepwear, Japanese clothes, gloves or hat.
PCT/JP2013/072669 2013-08-26 2013-08-26 Textile product WO2015029097A1 (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3076995U (en) * 2000-10-13 2001-04-27 株式会社イガラシネーム Article mounting cloth
JP2002136544A (en) * 2000-10-31 2002-05-14 Jarokkusu Kk Shorts type deodorant diaper and method for manufacturing that
JP2004027447A (en) * 2002-06-28 2004-01-29 Sun Look Kk Embroidery cloth and garment having deodorizing effect, etc.
JP3111536U (en) * 2005-04-01 2005-07-28 有限会社 木下ソーイング Functional presentation type deodorant fiber products
JP3153133U (en) * 2009-05-19 2009-08-27 荒木 永子 Smell
JP2009221635A (en) * 2008-03-18 2009-10-01 Toray Ind Inc Sewing thread, and sewn product using the same
JP2009235645A (en) * 2008-03-28 2009-10-15 Toray Ind Inc Core yarn conjugate fiber yarn, sewing yarn, and sewn product using the same

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3076995U (en) * 2000-10-13 2001-04-27 株式会社イガラシネーム Article mounting cloth
JP2002136544A (en) * 2000-10-31 2002-05-14 Jarokkusu Kk Shorts type deodorant diaper and method for manufacturing that
JP2004027447A (en) * 2002-06-28 2004-01-29 Sun Look Kk Embroidery cloth and garment having deodorizing effect, etc.
JP3111536U (en) * 2005-04-01 2005-07-28 有限会社 木下ソーイング Functional presentation type deodorant fiber products
JP2009221635A (en) * 2008-03-18 2009-10-01 Toray Ind Inc Sewing thread, and sewn product using the same
JP2009235645A (en) * 2008-03-28 2009-10-15 Toray Ind Inc Core yarn conjugate fiber yarn, sewing yarn, and sewn product using the same
JP3153133U (en) * 2009-05-19 2009-08-27 荒木 永子 Smell

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