TWI354041B - Woven or knitted fabric and cloth containing crimp - Google Patents

Description

1354041 IX. Description of the invention: [Technical field 3 of the invention] Technical field

The present invention relates to a knitted fabric and a garment comprising a crimped conjugate fiber, which can be moistened with water such as sweating to improve gas permeability and to reduce sultry sensation. More specifically, the present invention relates to a woven fabric comprising a polyester component joined to a side-by-side or eccentric core-sheath type and a polyamide component, and comprising a composite fiber having a marked crimp, and is a suction. The woven fabric 10 and the garment are improved in breathability when wet, in a manner that is reversibly improved in a more efficient manner when dry.

[Prior Art J BACKGROUND OF THE INVENTION Currently, a knitted fabric containing crimped fibers is used for sports clothes such as ski wear, snow suits, and outdoor sportswear, or for raincoats, men's/women's outerwear, and the like. known. However, when the water is wetted by sweating or the like, the conventional knitted fabric adheres to the skin and causes an unpleasant feeling, and has a problem that the drying speed is slow. In order to solve the aforementioned problems, there has been a gas permeable self-adjusting braid which has an increased gas permeability when water is wet and which has reduced gas permeability when dried. 20 When wearing a garment made of the aforementioned woven fabric and moistened by sweating, the breathability is improved and the moisture retained in the garment is quickly dried, and after drying, the breathability of the garment is lowered, and the garment is kept warm. The effect is improved, so that the feeling of the skin of the clothes can be maintained in a good state regardless of sweating or sweating. For example, Japanese Laid-Open Patent Publication No. 2003-41462 (Patent Document No.) discloses a composite fiber (A) which is joined by a sulfonic acid group-containing denatured polyethylene ester, a lanthanum or the like, and a size pair. The gas permeable self-adjusting braid composed of the fiber (B) whose temperature change does not substantially change, and the gas permeability of the knitted fabric is more reversibly improved when it absorbs moisture than when it is dried, but its gas permeability is improved. The amount of change is not practical. Further, Japanese Laid-Open Patent Publication No. Hei 10-77544 (Patent Document 2) discloses a woven fabric using a hygroscopic polymer (for example, a copolymerized polyvinyl ester polymer and a polyether ester copolymerized with a hydrophilic compound). The guanamine polymer or the like is formed and includes a synthetic multifilament heated to have a coefficient of 6800 to 26,000 Å, and the content of the synthetic multifilament is 30% by weight or more. Further, Japanese Laid-Open Patent Publication No. 2002-180323 (Patent Document 3) discloses a knit fabric in which a cellulose acetate fiber is used (when the humidity is 95% or more, a crimping ratio of less than 10% is exhibited, and humidity is exhibited. At 65%, it has a crimp ratio of 15 to 20% and a crimp ratio of 25/25.4 mm or more, and has a crimp ratio of 20% or more when the humidity is 45% or less. The woven fabric disclosed in the above Patent Documents 2 and 3 is improved in gas permeability by moisture absorption, but the amount of change in gas permeability is not practical, and therefore it is desirable to have a gas permeable self-adjusting woven fabric having a larger change in gas permeability. . [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. A knitted fabric containing a crimped conjugate fiber and a garment containing the woven fabric, which are improved in gas permeability by drying in a practical manner, to a degree that is more sufficiently high. The knitted fabric containing the crimped conjugate fiber which is improved in water permeability by water wetting is composed of a polyester resin component and a polyamide resin component which are bonded to each other in a side-by-side structure or an eccentric core-sheath structure, and include a yarn having a composite fiber which is crimped by heat treatment, and the content of the crimped composite fiber contained in the knitted fabric is 10 to 100% by mass: Further, a test crimped composite fiber sample is taken from the knitted fabric. And when one part of the above-mentioned composite fiber sample was left to stand in an environment of a temperature of 20 ° C and a humidity of 65% RH for 24 hours to dry, the crimping ratio DCF (%) of the crimped conjugate fiber was measured and the aforementioned composite was The other part of the fiber sample was immersed in water at a temperature of 30 ° C for 2 hours, and the sample was pulled up from the water, and it was sandwiched in the air at a temperature of 30 t and a humidity of 90% RH within 6 sec after the pulling up.丨 丨 丨 滤 滤 滤 滤 滤 滤 滤 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 69 'The aforementioned DCf (%) and HCf (%) can The following formula is satisfied: (DCf-HCf)^10 (%) ° In the knitted fabric containing the crimped conjugate fiber which is improved in water permeability by water wetting of the present invention, the above-mentioned poly 8 resin component is a finely modified poly-lipid component. Jia' and Wei (4) are responsible for the copolymerization of 2.0 to 4.5 mol% of sodium sulfoisophthalic acid based on the acid content. In the knitted fabric comprising the crimped conjugated fiber 1354041 which utilizes water to improve the gas permeability, the yarn containing the crimped conjugated fiber preferably has a number of turns of 0 to 300 T/m or less. In the knitted fabric comprising the crimped conjugate fiber which is moisturized and improved in water permeability by the present invention, the knitted fabric may further comprise the crimped conjugate fiber and the other fibers different from the crimped conjugate fiber.

In the knitted fabric comprising the crimped conjugate fiber which utilizes water wetting to improve gas permeability, the other fiber is selected from the group consisting of non-crimped fibers or fibers having a DCF-HCF system of less than 10%. . In the knitted fabric containing the crimped conjugated fiber 10 which is moistened with water and moistened by the present invention, the knitted fabric containing the crimped conjugated fiber is subjected to the measurement of the stretchability of the stretchable fabric specified in the method of JIS 丄 1086.8.14.1B (but When the load value attached to the test braid test piece is changed to 1.47 N), if the knitted fabric is a woven fabric, the stretch ratio is at least 10% selected from at least one of the warp direction and the weft direction, and When the knitted fabric is a woven fabric, it is preferably selected from the group consisting of at least one of the transverse direction and the longitudinal direction. In the knitted fabric comprising the crimped conjugate fiber which utilizes water wetting to improve gas permeability, the woven fabric containing the crimped conjugate fiber has a multilayer structure, and may contain the weight of the layer in at least one layer thereof. 100% by mass of the aforementioned crimped composite fiber. In the knitted fabric comprising the crimped conjugate fiber which utilizes water wetting to improve gas permeability, the woven fabric has a circular braided structure, and the circularly wound yarn loop may also contain the crimped conjugate fiber and The sliver of the other fibers described above is formed. 8 1354041 In the knitted fabric comprising the crimped conjugate fiber which utilizes water wetting to improve gas permeability, the knitted fabric is a woven fabric, and the yarn containing the crimped conjugate fiber is a blend of the crimped conjugate fiber and the other fiber. The sliver, in addition, the warp and weft of the fabric, or the warp or weft may be formed by the blended yarn of the crimped composite fiber and the other fibers.

In the knitted fabric comprising the crimped conjugate fiber which is improved in water permeability by water wetting, in the woven fabric, the yarn constituting the crimped conjugate fiber and the yarn constituting the other fiber may be selected from the group consisting of At least one of the direction and the weft direction, or at least one of the lateral direction and the longitudinal direction, is arranged such that at least one of the branches is interlaced. In the knitted fabric comprising the crimped conjugate fiber which is moistened by water and which has improved gas permeability, the crimped conjugate fiber and the other fiber are formed into a core/sheath type composite yarn, and the core of the composite yarn is It is composed of the above-mentioned composite fiber, and the sheath portion is preferably composed of the other fibers described above. In the knitted fabric comprising the crimped conjugate fiber which is moisturized by water and moisturizing according to the present invention, the other fiber is preferably selected from the group consisting of polyester fibers. In the knitted fabric comprising the crimped conjugate fiber which utilizes water wetting to improve gas permeability, the woven fabric can also be processed by a water absorbing agent. In the woven fabric containing the crimped conjugate fiber 20 which is moistened with water and moisturized by the present invention, the woven fabric can also be processed by applying a water repellent. In the knitted fabric comprising the crimped conjugate fiber which is moistened by water and which improves the gas permeability, the knitted fabric can also be subjected to dyeing processing. In the knitted fabric containing the crimped conjugate fiber which is moistened with water and moistened by the present invention, the test sample of the woven fabric is allowed to stand in an environment of a temperature of 20 ° C and a humidity of 9 1354041 65% RH for 24 hours and dried to prepare a woven fabric. The test sample was dried, and the test sample of the knitted fabric was immersed in water at a temperature of 30 ° C for 2 hours, and the sample was pulled up from the water, and within 60 seconds after the pull-up, at a temperature of 30 ° C and a humidity of 90%. The sample was sandwiched between 5 pairs of filter paper in the air of RH, and the sample was placed under a pressure of 490 N/m 2 (50 kgf/m 2 ) for 1 minute, and the moisture in the sample was gently removed to prepare a water-wet. The sample was subjected to the gas permeability measurement according to the method of JIS.L1096_1998_6.27.1A (Frazi® type gas permeability tester method), and the obtained measurement result was taken from the dried sample and the water-wet sample. It is better to calculate a gas permeability change rate of 30% or more. Gas permeability change rate (%) = [(water wet sample gas permeability) - (dry sample gas permeability)]

(Dry sample gas permeability) xlQQ The present invention reversibly expands the size by water wetting to improve the gas permeability.

The clothes to be coated are those comprising the aforementioned knitted fabric containing crimped composite fibers of the present invention. In the clothing of the kemin, the woven fabric containing the crimped conjugate fiber is preferably formed into at least one of the armpit portion, the side body portion, the chest, the back, and the shoulder of the garment. In the clothes of the moon, it is preferable that each portion formed of the knitted fabric containing the crimped conjugate fiber has an area of (f) or more. 20 In the clothes of Lin Ming, the knitted fabric containing the crimped conjugate fiber is preferably selected from the group consisting of a circular knitted fabric and a mesh coarse-woven fabric. The clothes of the present invention include clothes for outerwear, sports clothes, and clothes for clothing.

The crimped composite fiber contained in the knitted fabric comprising the crimped conjugate fiber of the present invention has a crimping ratio of less than 10% or more when wetted with water, and therefore contains the crimped composite fiber. When the knit phase 5 is dry, its gas permeability is remarkably improved when the water is wet. Moreover, when the knitted fabric containing the crimped conjugate fiber of the present invention is used as a material constituting all or part of the outer garment, the sportswear, and the underwear, when the water is wet due to sweating or the like when the garment is worn, Improve the breathability of the garment, dry and discharge the moisture retained in the garment, and reduce the breathability and improve the heat retention when the garment is fully dry. Therefore, the wearer's wearing feel can be maintained in a good state and maintained. Good health contributes. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional explanatory view showing an example of a cross-sectional shape of a side-by-side crimped composite fiber included in the knitted fabric of the present invention. Fig. 2 is a cross-sectional explanatory view showing an example of a cross-sectional shape of a side-by-side crimped composite fiber included in another knitted fabric of the present invention. Fig. 3 is a cross-sectional explanatory view showing an example of a cross-sectional shape of a side-by-side type crimped composite fiber included in another knitted fabric of the present invention. Fig. 4 is a cross-sectional explanatory view showing an example of a cross-sectional shape of an eccentric core-sheath type crimped 20-fiber comprising the present invention. Fig. 5 is a front elevational view showing a garment (shirt) formed of a knitted fabric of the present invention and having a plurality of portions which are moistened with water to improve the gas permeability. Fig. 6 is a front explanatory view showing a garment (shirt) which is formed of the woven fabric of the present invention and which is air-wet-enhanced to improve the air permeability of 11 1354041. Fig. 7 is a front elevational view showing a garment (shirt) formed of the woven fabric of the present invention and having a cuff bottom portion and a side body portion which are moisturized by water to improve the gas permeability. 5 Fig. 8 shows a garment (shirt) of the present invention (Example 1) and the present invention

The outer (Comparative Example 1) clothes (shirts) were worn on the human body and were subjected to static (windy 1.5 m/s)-jogging-stationary (no wind)-stationary (windy 1.5 m/s) wearing test, human body A graph of relative humidity changes in the gap between the skin and the shirt. C. BEST MODE FOR CARRYING OUT THE INVENTION The preferred embodiment of the present invention comprises a crimped composite fiber comprising a crimped conjugate fiber which is moisturized by water and which is composed of a polyester resin component and a polyamide resin component. And has a side-by-side or eccentric core-sheath type composite fiber structure. In the case of the parallel type composite fiber, for example, in the case of having a substantially circular cross-sectional shape as shown in Fig. 1, the portion 1 composed of the polyester resin component and the portion 2 composed of the polyamide resin component are juxtaposed. The relationship is joined and stretched along the long axis of the composite fiber to form an integral composite fiber. In the side-by-side type composite fiber shown in Fig. 2, the cross-sectional shape thereof is elliptical in shape, and in this case, it is preferable that the portion 1 and the portion 2 are joined along a substantially long axis of the elliptical shape of the cross section. In the side-by-side type composite fiber having the wearing shape shown in Fig. 3, a portion 1 composed of a polyester resin component and a portion 2 composed of a polyamide resin component are contained, and a part of the surface is 2 The portion 2a is exposed to the outside, and the remaining portion of the peripheral surface 12 1354041 is joined to the portion 1. In Fig. 3, part 1 is shown in a crescent-shaped cross-sectional shape and is composed of a polyester resin component, and part 2 is shown in a substantially circular cross-sectional shape and is composed of a polyamide resin component, but part 1 It may also be composed of a polyamide resin component, and part 2 may be composed of a polyester resin component.

In the eccentric core-sheath type composite fiber having the cross-sectional shape shown in Fig. 4, part 2 is composed of a polyamide resin component and is contained in a portion 1 composed of a polyester resin component, and part 2 The outer peripheral surface is not exposed to the outside, and the center point 1 a of the portion 1 is inconsistent with the center point 2 b of the portion 2 and the mutual shape of the surface is not angular, and the other polygons are formed by the polyester resin: Since the amount of the conjugate fiber included in the woven fabric of the present invention is limited to the one shown in FIGS. 1 to 4, it may be a triangle, a quadrangle, or the like, or may have a hollow portion inside. By. In the side-by-side and eccentric core-sheath type composite fibers, when the 15 parts differ from the polyamide resin component in heat shrinkability, the heat shrinkage fibers of the partial enthalpy and the part 2 exhibit a crimped state. In the cross-sectional shape of the composite fiber of the present invention, the mass ratio of the portion 2 of the composite fiber is preferably 30:70 to 7:3, and the polyester resin component of the first and second layers is more than A polycondensation product of an aromatic component and a diol component composed of one or more kinds of olefinic diols. The acid component is preferably one containing terephthalic acid as a main component, 13 1354041

Further, the diol component is preferably a component such as ethylene glycol or propylene glycol 'butanediol. Further, the copolymerization component is preferably selected from the group consisting of a metal salt group, an alkaline earth metal salt group, and a salt group, and a compound having at least one functional group is preferred. That is, the polyester resin component preferably contains a modified polyester such as a polyvinyl ester 5 copolymer, a polypropylene ester copolymer, and a polybutene ester copolymer, and the copolymers contain and have the aforementioned sulfonate groups. The aromatic dicarboxy group which is a functional group is used as a copolymerization component. Further, the compound for copolymerization having the above sulfonate diol is effective for improving the bonding property of the obtained polyester resin component to the polyamide resin component. 10 The polyester resin component of the crimped conjugate fiber for a woven fabric of the present invention is a polyvinyl ester copolymer which is denatured by the above-mentioned copolymer component containing a sulfonate group, and is excellent in versatility and low in polymer cost. Suitable for use. The aromatic dicarboxylic acid having the aforementioned sulfonate group is, for example, 5-15 sodium sulfonyl isophthalic acid and an ester derivative thereof, and 5-quinoneisophthalic acid and an ester derivative thereof, etc. The hydroxy compound containing a sulfonic acid group is sodium p-hydroxybenzenesulfonate or the like, and among these compounds, 5-sodium sulfonate is preferably used. Further, the copolymerization component content is based on the amount of the acid component of the polyester polymer contained therein, and is preferably 2.0 to 4.5 mol%, and further, the copolymerization component content is less than 2.0 mol%. Although the obtained composite fiber has sufficient performance, in the obtained composite fiber, the interface between the portion composed of the polyester resin component and the portion composed of the polyamide resin component is peeled off. Further, when the content of the copolymerization component exceeds 4.5 mol%, when the obtained unstretched composite fiber is subjected to the elongation heat treatment, the crystallization of the portion composed of the polyester resin component of 14 1354041 is insufficient, and the elongation heat treatment temperature needs to be increased. As a result, it is possible to break the wire often during the elongation heat treatment.

The polyamide resin is used as a polyamide component, and it is not limited to its kind as long as it has a mercapto bond in its 5 main chain, and is not limited to its kind, for example, it contains a rhenium- 4. Among these types, such as Nylon _6, Nylon _66, Nylon-46, and Dylon-12, Cailong·6 and Nylon _66 have excellent versatility, low polymer prices, and manufacturing. The advantages of high step stability and the like are quite suitable for the present invention. 10 The polyester resin component and the polyamide resin component are independent of each other, and may further contain an additive of more than one type, such as a pigment, a delustering agent, an antifouling agent, a fluorescent whitening agent, and a flame retardant. Agent, stabilizer, antistatic agent, light agent, and ultraviolet absorber. The single fiber fineness of the composite fiber and the number of single fibers (single 15 filaments) contained in the crepe yarn are not particularly limited, but the single yarn fineness is preferably in the range of 1 to 10 dtex, and 2 to 5 dtex is more preferable, and the number of fibers of the composite fiber contained in one yarn is preferably from 1 to 200, and more preferably from 2 to 100. Further, in the composite fiber contained in the woven fabric of the present invention, the polyester resin portion composed of the polyester resin component is higher than the polyamide resin component composed of the polyamide resin component. Shrinkage, and high moisture self-expandability. Therefore, once the composite fiber having the side-by-side or eccentric core-sheath type composite fiber structure used in the present invention is heated, since the polyamidamide resin portion 15 1554041 is more strongly shrunk than the polyester resin portion, shrinkage can be found. The resin portion having a large amount is located on the inner side, and the resin portion having a small amount of shrinkage is located on the outer crimping structure. In addition, when the yarn containing the un-crimped fiber is heated and the crimp is found on the composite fiber, the obtained yarn containing the composite fiber has a southerly fluffiness than the yarn without the crimped 5 composite fiber. 'And its apparent yarn length is shortened. When the crimped composite fiber used in the present invention is wetted by water, the polyamid resin portion in the crimped composite fiber absorbs a larger amount of water than the polyester resin portion, and the display is higher. Self-extension value. (In general, the self-elongation of the polyester resin portion by water wetting is close to ίο 〇.) Therefore, the crimp ratio of the water-wet crimped composite fiber is lower than that of the dry crimped composite fiber. The apparent length of the water-wet crimped composite fiber is also greater than the apparent length of the dried crimped composite fiber. In addition, when the water-wet crimped composite fiber is dried, the polyamide resin portion is dehydrated and shrunk, but the polyester resin portion has almost no dimensional change, so in the dry crimped 15 composite fiber, the crimp ratio thereof Will return to its original state, and its apparent length will also return to its original length. As described above, the crimped composite fiber contained in the woven fabric of the present invention reduces the crimp ratio by water wetting, increases the apparent length of the fiber, and restores the crimp ratio and the apparent length by drying. Therefore, the woven fabric comprising the yarn of the crimped conjugate fiber having the above-mentioned 20 characteristics, wherein the crimping rate of the rewound fiber is lowered by the wetting of the water, and the length of the yarn containing the crimped conjugate fiber is increased, and The gap of the sliver in the braid is increased, so that the area is enlarged and the gas permeability is improved. The gas permeability of the aforementioned woven fabric can be measured in accordance with JIS L 1096-1998.6.27 ιΑ 16 1354041 (Frazil-type gas permeability tester method). In the bat fabric containing the crimped conjugate fiber of the present invention, it is important that the gas permeability when the water is wet is higher than the air permeability when it is wet, and the gas permeability when the water is wet is the gas permeability during drying. For the reference, it is better to use a gas with a height of 5 higher than that of the lining, and Μ is higher than I5·. Better. Gas permeability change rate (%) = [(water wet sample gas permeable gas soil)] (dry sample gas permeability) ><10 〇 The aforementioned dry sample means the temperature 2 (rc, humidity 65% environment) After being placed for 24 hours, the water-wet sample is referred to as "immersed in water at a temperature of 2 hours" and pulled up by water, and within 60 seconds after pulling up, at a temperature of 3 〇. In the air of °C and humidity 9〇%rH, sandwiched between i and filter paper, and apply a pressure of 49〇N/m2 (5〇kgf/m2) to the sample for 1 minute, and gently remove the above sample. The moisture in the process is modulated. When the gas permeability change rate is less than 30%, when the clothes containing the knitted fabric of the water-wet 15 are worn and sweating, the breathability of the clothes may be insufficient, and at this time, the user may feel unventilated or stuffy due to the clothes. sense. The content of the crimped conjugate fiber contained in the woven fabric of the present invention is preferably 10 to 100% by mass, and the content is preferably 4 〇 to 1% by mass, and when the content is less than 10% by mass. The effect of crimping the composite fiber, that is, the wetting of the water of the knitted fabric of 20, drying to obtain an increase in gas permeability <__> reduction of the reversible change may be insufficient. In the woven fabric of the present invention, the crimped composite fiber is contained in a yarn of a woven fabric of 17, and the crimping ratio of the crimped conjugate fiber is lowered by water wetting, thereby containing the crimped conjugate fiber. The apparent length of the sliver is increased, and as a result, the area of the braid is enlarged and the gap of the sliver is increased. As a result, the air permeable void area and air permeability are increased. 5 According to the reduction or increase of the crimping property of the crimped composite fiber, the yarn containing the aforementioned crimped composite fiber can effectively increase or decrease the apparent length thereof, whereby the yarn is 0 to 300 T/m. It is preferred that the number of untwisted yarns or weak crepe yarns is particularly good, especially those without crepe yarns, in order to increase or decrease the permeability of the woven fabric efficiently. Once the number of turns exceeds 300 T/m, since the crimped composite fibers in the yarn 10 will mutually restrict their deformation, when the water is wet or dry, the crimping rate of the composite fiber also changes, so the yarn table There is also a limit to the change in length, which in turn limits the change in the permeability of the braid. Further, in the yarn containing the crimped fiber, interlaced air plus 15 and/or false twist crimping may be applied. At this time, the number of interlacing fibers in the sliver is about 20 to 60/m. It is better. The yarn containing the crimped conjugate fiber may further contain other fibers different from the crimped conjugate fiber, and the other fiber may be selected from the non-crimped fiber and the aforementioned DCF-HCFi value. Less than 10% of the fiber 20 dimensions. Further, the type of the polymer constituting the other fibers is not particularly limited, and examples thereof include polyesters such as polyvinyl ester, polytrimethylene ester, and polybutenyl ester, and polyamines such as Nylon-6 and Nylon-66. Polyolefins such as polyethylene and polypropylene, acrylic acid, para or meta-aramid, and such denatured polymers. Further, the other fibers may be selected from natural fibers, regenerated fibers, semi-synthetic fibers, and the like, which are suitable for clothing fibers, such as dimensional stability in wetness and phase compatibility with fibers (mixing properties, blending). The fiber/interlacing property, dyeing property, and the like are advantageous, and it is most suitable for the fiber composed of polyacetal, polypropylene acrylate, polybutylene, or denatured polyester which is copolymerized with the copolymerized component. Further, the single fiber fineness of the other fibers and the number of single fibers (the number of filaments) contained in the W are not particularly limited, but the single fiber fineness is in the range of (U to 5 dtex (more preferably 0.5 to 2 dtex). It is better, and the number of single fibers contained in the crepe bar is ~200 (more preferably 3 (M(8)) is better to improve the moisture absorption of the woven fabric, and to improve the efficiency efficiently. In addition, it is also possible to apply interlaced air to the other fibers and/or a false twist crimping process to form an interlacing number of about 2 to 60/m. In the woven fabric, the crimped conjugate fiber and the other fibers are each composed of one or more types of yarns, and the yarn yams may be interlaced, or the crimped conjugate fiber and the other fibers may constitute a mixed yarn. It is also possible to use the air-mixing method. Alternatively, the crimped composite fiber yarn and the other fiber yarns may form a twisted yarn or a blended yarn, and a composite false twist crimping process or yarn may be formed. There is no limitation on the number of braided tissues and braid layers of the inventive braid, and the braided tissue Such as: plain weave, twill weave, woven weave and other weave, jersey, circular rib knit, alternating tuck knit, add yarn weaving, single comb 栉 平 flat organization, double comb 栉 平 flat organization, etc. Further, the weave structure includes a single layer structure and a multilayer structure of two or more layers. In the woven fabric of the present invention, in order to ensure the detachability of the crimped fibers in the woven fabric, deformation versatility (volume change possibility) Therefore, it is preferable to have a tendency to expand and contract in the direction of the warp direction and the 1354041 (or) weft direction, and it is preferable that the stretch ratio is more than 20% or more, and 25 to 15% by weight. More preferably, in the woven fabric of the present invention, the conjugate fiber contained in the woven fabric has a crimped structure in which the crimping property is manifested, and the crimping ratio of the composite 5 fiber when dried is DCf (%). , the shrinkage rate when moisture absorption is He〆.〆.) When 'DCf - HCf g 1 〇 (%) (again 5〇(%) 2 DCf — HCf ^ i 〇 (%) is better) It is extremely important, and when DCf_HCf is less than 1〇%, it may not be able to lift more efficiently when it is wet. It is not applicable. Here, the crimping ratio of the crimped composite fiber in the braid is measured by the following 10 methods: First, the braid is placed in the air at a temperature of 20 ° C and a humidity of 65% RH. After 24 hours, a small piece (n number = 5) of 30 cm x 30 cm in the same direction as the woven fabric was cut out from the woven fabric. Then, the conjugate fiber was taken out from each piece, and 1.76 mN/dtex (200 mg/) was applied to the conjugate fiber sample. De) The load was measured to measure the fiber length LOf, and a load of 15 〇.〇176 mN/dtex (2 mg/de) was applied after 1 minute of de-weighting to measure the fiber length Llf. Then, the composite fiber sample was impregnated at a temperature of 30 2 ° water in °C, and pull the sample from the water, and within 60 seconds after pulling, in the air at a temperature of 30 ° C, humidity 90% RH, sandwiched between a pair of filter paper, and After applying a pressure of 0.69 mN/cm 2 to the above sample for 5 seconds, the water was gently wiped off from the sample for 20 minutes, and a load of 1.76 mN/dtex (200 mg/de) was applied to the sample to measure the fiber length LOf'. And after removing the weight for 1 minute, a load of 0.0176 mN/dtex (2 mg/de) was applied to measure the fiber length Llf'. Based on the above measurement results, the crimp ratio DCF (%) at the time of drying and the curl ratio HCF (%) of water wetness were calculated by the following formula. 20 Crimping rate DCF (%) = ((LOf - L1 f) / LOf) when dry 100 Crimping rate HCF (%) = ((LOf '-L1 f ') / L0f,) x 100 by moisture absorption The DCF and HCF calculate the difference (DCF - HCF), and the n number is 5 ' at this time and the average value is calculated. 5 The woven fabric of the present invention can also be processed by applying a water absorbing agent, and by applying water absorbing treatment to the woven fabric, the gas permeability can be easily improved even with a small amount of sweat, and the water absorbing treatment applied can be generally water absorbing processing. A water-absorbent processing agent such as polyethylene glycol diacrylic acid and a derivative thereof, or a polyethylene-Sb-ethylene-ethylidene copolymer is attached to the woven fabric, and the water absorbing agent 10 is attached with a weight of 0.25 to the woven fabric. 0.50% by weight is preferred. In addition, the water absorption processing method includes: a dye bath processing method in which a water absorbing processing agent is mixed in a dyeing liquid during dyeing processing, a method of immersing in a water absorbing processing liquid before dry heat and condensing, and a method of rolling by a roll, gravure coating method The stencil printing method and the like use a coating processing method or the like. Further, the water-repellent woven fabric of the present invention may be subjected to a water-repellent process, and a general water-repellent treatment may be applied. For example, the method disclosed in Japanese Patent No. 3,133,227 and Japanese Patent Publication No. Hei. That is, a commercially available fluorine-based water repellent (for example, Asahi Glass Co., Ltd. (ASAHI GLASS Co., Ltd., 7 Ganzifang-KLS-317) is used as a water repellent, and trimeric 20 cyanide is mixed as needed. The amine resin and the catalyst are used to prepare a processing agent having a water repellent concentration of about 3 to 15% by weight, and the method for treating the surface of the knitted fabric by using the processing agent at a pressure absorption ratio of about 50 to 90% is further processed by a processing agent. The method of the surface of the fabric may also be, for example, a pressure suction method, a spray method, etc., wherein the pressurization method in which the processing agent can be impregnated into the inside of the braid is optimal. 21 1354041 Further, the aforementioned pressure suction ratio refers to a relative processing agent. Weight ratio (%) of the weight of the fabric (before the processing agent). The water repellency of the woven fabric after water repellency is better than 4 points or more according to the JIS L 1092 6_2 (spray test) measurement, and 5 points (highest score) 5 is better. In the water-repellent woven fabric, since the shrinkage ratio of the composite fiber contained in the woven fabric is efficiently reduced during moisture absorption, the length of the composite fiber yarn becomes longer, and the void in the woven fabric becomes larger and the gas permeability is improved; On the other hand, since the conjugate fiber shrinkage rate is increased during drying, the length of the composite fiber yarn becomes 10 short. As a result, the voids in the woven fabric become short and the gas permeability is lowered. The woven fabric of the present invention can also be a dyed processor, and Hereinafter, the dyeing processing conditions and the like will be described in detail. In the present invention, for example, (1) a multilayer structure knitted fabric having two or more layers of a woven fabric, and at least one layer of the knitted fabric contains a composition 15 30% by weight or more of the total fiber weight of the composite fiber of the composite fiber ('2) The composite fiber and the other fiber are formed into a composite yarn of a circular structure' (3) The composite fiber is blended with other fibers and knitted (4) the woven fabric of the woven fabric and the other woven fabrics, and the braided yarns of the other woven fabrics are arranged in a staggered manner or interlaced with each other. 5) The woven fabric includes the conjugate fiber and the other fiber, and the 幵v is a core-sheath type composite yarn in which the conjugate fiber is disposed in the forbearing portion and the other fibers are disposed in the sheath portion. When the composite fiber and other fibers and food are dry, when the fiber length of the composite fiber is (A), and the fiber length of the other fiber 22 1354041 is (B), in the case of A < B, the gas permeability of the wet eye can be Conveniently, in the case of A > B or A = B, when the folding fiber is reduced due to wetting and the stretch ratio is reduced, the other fibers cannot be stretched because there is no excess amount, so the void ratio of the knitted fabric is lowered. , when it is wet, the gas permeability can not be improved.

Here, the measurement of the fiber length is carried out by: firstly, the braid is at a temperature of 20. (:, after standing in the air with a humidity of 65% RH for 24 hours, a small piece of 3〇cmx30cm (n number=5) was cut out from the knitted fabric. Then, the composite fiber yarn and other pieces were taken out from each small piece. The fiber sliver 'measures the fiber length A (mm) in the composite fiber sliver and the fiber length B (mm) in the other fiber sliver. At this time, if it is a non-elastic yarn, apply 1,76 mN/dtex (200 mg/ The load of de), if it is an elastic yarn, is measured by applying a load of 0.0088 mN/dtex (lmg/de). Here, the composite fiber yarn strip taken out from the small piece and the other fiber yarn strips need to be in the same 15 directions in the braid. For example, if the composite fiber sliver is taken out from the warp (weft) of the fabric, it is necessary to take out the other fiber sliver from the warp (weft). In addition, if the composite fiber sliver is used as a composite with other fiber slivers. When the yarn constitutes a woven fabric, the composite yarn (n number = 5) is taken out from the cut piece (30 cm x 30 cm), and then the composite fiber yarn is taken out from the composite yarn and the other fiber yarns 2 〇 and measured in the same manner as described above. As mentioned above, in composite fiber slivers The method for providing the difference in fiber length between the fiber slivers can be exemplified by the following methods. For example, when a composite fiber sliver and other fiber slivers are used, and the knit fabric is knitted, the boiling water shrinkage ratio of other fiber slivers is adjusted. It is a method of 5% or less (more preferably 10% or less) 23 1354041, or a method of super-feeding other fiber slivers in the composite processing of composite fiber slivers and other fiber slivers, etc. In the woven fabric, in order to ensure the movability (coiling change) of the composite fiber in the woven fabric, the mass per unit area is preferably 300 g/m 2 or less (more preferably 5 100 to 250 g/m 2 ). The woven fabric of the present invention can be easily obtained. First, a copolymer having an intrinsic viscosity of 〇.3〇~〇43 (a gas phenol solution is measured as a solvent and measured at 35 C) has a 〇~4.5 mol% of 5-sodium. Denatured polyester of sulfoisophthalic acid, and polyamine which has an intrinsic viscosity of 1.0 to 1.4 (m-phenol is a solvent and measured at 30 10 C), and is used for spinning with a side-by-side or eccentric core-sheath type composite fiber. The wire nozzle performs the melt compound spinning. At this time, It is particularly important that the intrinsic viscosity of the polyester resin component is 0.43 or less. Further, when the inherent viscosity of the polyester resin component is more than 0.43, the viscosity of the polyester component is increased, and the physical properties of the composite fiber are close to the polyester individual yarn, so the present invention cannot be obtained. The object of the invention is not suitable for weaving 15; relatively, once the inherent viscosity of the polyester resin component is less than 0.30, the melt viscosity is too low, which may result in a decrease in yarn making property and an increase in fluff generation and quality and production. The spinning nozzle used in the melt spinning is separated into the discharge holes on the high viscosity side and the low viscosity side, as shown in Fig. 1 of JP-A No. 2144518, and is preferably lowered. A spinning nozzle that spouts at a high viscosity side (increasing the discharge cross-sectional area). Further, it is preferable to discharge the pores through the high-viscosity side with the dazzling polyester, and to melt the polyamine to pass through the low-viscosity side discharge hole and to cool and solidify. In this case, the weight ratio of the polyester component to the polyamine component is preferably in the range of 30:70 to 70:30 (more preferably 40:60 to 60:40) as described above. 24 1354041 In addition, after the melt composite spinning, a partial extension method of stretching after the temporary winding may be employed, and a direct extension method of the extension heat treatment without temporary winding may be employed. In this case, the spinning/extension condition is a general condition. For example, in the case of the direct extension method, after spinning in about 1 to 3500 m/min, the winding is continuously extended at a temperature of 5 1 〇 0 to 15 〇 ° c. In addition, the stretching ratio can be appropriately selected to form a cut length of 10 to 60% (preferably 20 to 45%) of the composite fiber finally obtained, and the cutting strength is about 3. 〇 to 4.7 cN/dtex. By. Here, the above composite fiber is preferably one which satisfies the following requirements (1) and (2) at the same time. 10 (1) The composite fiber crimp ratio DC is 1.5 to 13% (more preferably 2 to 6%). (2) The difference between the crimp ratio DC and the composite fiber crimp ratio hc when water is wet (DC-HC) is 0.5% or more (more preferably 1 to 5%). However, 'drying means the state in which the sample is allowed to stand in the environment of temperature 2 (TC, humidity 65% RH for 24 hours), on the other hand, when wet, it means that the sample is immersed in water at a temperature of 30 ° C for 2 hours. After a short period of time, the crimping rate DC during drying and the crimping rate HC during wetting were measured by the following methods. First, 'Use the frame of the frame l_125m to apply the load: 49/50mN 20 x9x The total count (O.lgfx total denier) and the yarn is wound at a fixed speed, and the number of rolls is made: 10 twists, and the total number of 49/2500mNx20x9x is applied to the strands to form a 2-layer round. (2mgx20x total Danny) was placed in boiling water for 30 minutes, and after the boiling water treatment, it was dried for 30 minutes using a dryer of i〇〇°c. Then, the initial load was applied again and placed at 16 °C. Dry heat in the middle 25 1354041

5 points. The initial load was removed after the dry heat treatment and was at a temperature of 2 Torr. After being placed in a humidity of 65% RH for more than 24 hours, load the weight of the initial load and the total weight of 98/50mNx20x9x (0.2gfx20x total denier) to measure the skein length L0' and then remove only the heavy load. The length of the twisted yarn 5 is measured after the weight is removed by 1 minute. Further, the skein was subjected to an initial load and immersed in water at a temperature of 2 ° C for 2 hours, and then taken out, and the water was gently wiped off by a transfer paper at a pressure of 6969 mN/cm 2 (70 mgf/cm 2 ). Thereafter, the initial load and heavy load of the load were measured to measure the skein length L0', and then only the heavy load was removed to measure the skein length L1' after the weight was removed by one minute. From the above measured values, the crimping ratio (DC) at the time of drying 10, the crimping ratio (HC) at the time of wetting, and the crimping rate difference (DC-HC) at the time of drying and wetting were calculated by the following calculation formula. Crimping rate DC (%) = ((L0 - L1 ) / L0) x 1 The curling rate of wet water is HC (%) = ((L0, L1,) / L0,) χ 1 〇 It is preferable that the composite fiber crimp ratio HC is 0.5 to 10.0% (more preferably 15 1 to 3%) in the case of the above-mentioned wetting. Here, if the composite fiber crimp ratio DC is less than 1.5% when dry, the amount of change in the curling property of the knitted fabric may become small as the amount of curl change during wetting becomes small; When the crimp ratio of the composite fiber is higher than 13%, it is difficult to produce a curl change when wet because the crimp is too strong, and the change in the gas permeability of the knitted fabric may also be small. Further, if the difference (DC - HC) of the composite fiber crimp ratio HC during drying is less than 0.5%, the amount of change in the gas permeability of the knitted fabric may be small. Then, the conjugate fiber is used alone or after other fibers are used to knit the woven fabric, and then the crimping of the 26-composite weave is revealed by heat treatment such as dyeing. Here, when knitting into a woven fabric, as described above, it is important to use 10% by weight (preferably 4% by weight) based on the total weight of the bat fabric on the basis of weight, and the woven structure is not particularly limited. Appropriately select the aforementioned. The temperature of the dyeing process is 100 to 140 ° C (more preferably 110 to 135 ° C), and the time is preferably in the range of 5 to 40 minutes of the top temperature duration, and under such conditions, When the knitted fabric is dyed, the composite fiber is curled due to a difference in heat shrinkage between the water ester component and the polyamide component. At this time, by selecting the polymer as the polyester component and the polyamide component, a crimped structure in which the polyamide component is located inside can be formed. Dry heat finishing is generally applied to the dyed processed fabric. At this time, the dry heat final setting temperature is 120 to 2 Torr. 0 (again 140~18 (TC is better), the time is preferably in the range of 1~3 minutes. As a result, if the dry heat final condensation temperature is lower than 120C, it is easy to leave the wrinkles generated during dyeing processing. Pleating, in turn, the dimensional stability of the finished product may be deteriorated; in contrast, if the dry heat final setting temperature is higher than 200C, the composite fiber crimping which appears when the color processing is performed may be lowered, or the fiber hardening may cause texture touch change. In addition, in the woven fabric of the present invention, in addition to the foregoing processing, it can also be applied to a velvet blanket with a conventional method, an ultraviolet shielding or an antibacterial deodorant, an insect repellent, a luminous agent, and a return. Various processes such as a reflector, an anion generator, a water absorbing agent, etc. The woven fabric of the present invention reduces the volume _ by the water of the crimped conjugate fiber contained in the woven fabric, thereby, the living (four) high domain The characteristics of the gas permeability of the article are at least a part of the clothes such as clothes, clothes, clothes, and underwear 1354041. The clothes of the present invention are the above-mentioned crimping compound containing water moisturizing and improving gas permeability. Woven fabric, characterized by The size thereof is reversibly expanded by water wetness, and the gas permeability is improved, and the gas permeable effect is exhibited. 5 The clothes of the present invention include clothes for outerwear, clothes for sports, clothes for underwear, etc. In a preferred embodiment of the garment of the present invention In the case where the size is not changed by the wetness of the water, and the size is reversibly expanded by the water (we reversibly enlarge the area), in which the area is enlarged by the wetness of the water 10 is partial. Therefore, the overall size of the clothes will not be excessively enlarged, and the gap between the clothes and the wearer's skin will not be excessively enlarged, that is, wearing the clothes of the foregoing aspect, and when the wearer is sweating, moist and moist with sweat (size) The increased portion expands outward toward the outside, and increases the gap between the wearer's skin and the portion, so as to achieve an increase in the gas permeability of the wet portion, and further increase the gas permeability of 15 liters. In the clothes of the present invention, the size is not changed by water wetting. Partially refers to the use of water to create a portion of the area change rate of less than 5%, and the size of the use of water to wet the change means that the use of water is wet A portion where the area change rate is 5% or more is produced. Further, the change in the area ratio of the clothes is measured by the following method. 20 The woven fabric is left in an environment of a temperature of 20 ° C and a humidity of 65% RH for 24 hours (hereinafter referred to as drying). After the time, the sample in the same direction as the braid (cut 20 cm x 20 cm square) was used as the area (cm2) when dry. On the other hand, the sample was immersed in temperature 3 (5 minutes in TC water). After (hereinafter referred to as wet time), and pull up the sample, and within 6 seconds after pulling up, clamp the sample of 13 1354041 between two pieces of filter paper, and increase the pressure of 490N/m2 (50kgf/m2) After 1 minute' removal of the moisture remaining between the fibers, the area of the wet sample (cm2) was measured. Further, the case where the area was reduced by the wetness of the water was also included in the case where "the size did not change relative to the wetness". 5 Area change rate (%) = ((area when wet) 1 (area when dry)) / (area when dry) X100

In the above aspect of the garment of the present invention, the woven fabric formed into a portion whose size is not wetted by water may be selected from organic natural fibers such as cotton, wool, hemp, organic synthesis such as polyester, lons, and polyolefin fibers. Organic semi-synthetic fibers such as fibers, cellulose acetate fibers, and organic regenerated fibers such as mucilage fibers are not particularly limited. Among them, polyester fiber is preferred in terms of fiber strength and usability. The polyester fiber is made of a dicarboxylic acid component and a diol component. It is preferred that the dicarboxylic acid component is mainly terephthalic acid, and the diol component is preferably one or more selected from the group consisting of 15 ethylene glycol, trimethyl glycol, and tetramethyl glycol. Further, the third component other than the above-mentioned two retinoid components and the monool component may be contained in the polyg. The third component may use a cationic dye-stainable anion component such as sodium sulfonate; a dicarboxylic acid other than terephthalic acid such as isophthalic acid, naphthalene dicarboxylic acid, adipic acid, bismuth An acid; and a diol compound other than the olefinic diol, such as diethylene glycol, one or more of ethylene glycol, bisphenol A, and bisphenol sulfonate. In the fiber whose size is not changed by water wetting, it may also contain a delustering agent (titanium dioxide), a micropore-forming agent (organic sulfonic acid metal salt), a coloring preventive agent, a thermal stabilizer, and a flame retardant (three-oxidation) as needed. Citrate), a fluorescent whitening agent, an anti-29 1354041 electric agent (% acid metal salt), and a moisture absorbent (one or more kinds of polyhydroxy olefinic inorganic particles).

The fiber type whose size is not changed by water wetting is not particularly suitable for long fibers (multifilament) or short fibers, and is preferably a long fiber having a soft touch. In addition, it is also possible to apply a general false twist, a crepe, a six-woven air processing 'X, although the fiber fineness is not particularly limited, but the softness of the single fiber fineness (M~3dtex, monofilament number pure) G, the total fineness of 30~3_teX is better. In addition, the shape of the single fiber carrier surface is not limited to two, except for the circular cross section, it may be triangular, flat, cross, hexagonal, or hollow. The cross-sectional shape.

The above-mentioned knit structure of the monool), the antibacterial agent, and the 10th dimension which is not wetted with respect to water is also not particularly limited, and may be any. For example, the weaving structure of the fabric may be a three-dimensional structure such as plain weave, twill weave, and woven weave, a changeable structure, a twill weave, and the like, a vertical double-layer structure, a horizontal double-layer structure, and the like, and a vertical double velvet structure. Wait. Moreover, the type of the knitting may be a horizontal knitting or a longitudinal knitting. The horizontal weaving can be preferably, for example, a woven structure, a rib structure, a double rib structure, a double reverse tissue, a tuck organization, a float structure, a h-domain, a lace mesh structure, and a hair-increasing tissue; For example, a single combed flat warp, a single and a double combed warp (10) weave, a double combed pile velvet woven fabric, a 2 〇 back piled structure, and a jacquard weave. In the foregoing aspect of the garment of the present invention, the size is reversibly enlarged by the wetted portion, and the other portion is composed of a braid having a size which does not change with respect to the aforementioned wetting. Further, it is preferable that the size is reversibly enlarged by moistening to a portion which is more sweaty. For example, the knitted fabric portion 30 is preferably disposed in the pattern of Fig. 5 to display the knitted fabric portions 6 and 8 of the chest 7 which are schematically displayed on the front face 5 and the sixth figure, and the side body portion 9 which is schematically shown in Fig. 7. The back (not shown), at least the crotch portion of the sleeve bottom 10, and the aforementioned size of the knit fabric which is reversibly expanded by the wetness is the area of the knit portion of which the area of 5 is more than 1 cm2, and the total area is 5 〇〇. Preferably, 10000 cm2 is preferred, and the total area ratio of the knitted portion is preferably 5 70/% of the total area of the garment. In the range. If the area ratio is less than 5%, the volume of space between the clothes and the skin does not become large when wet' and the sufficient ventilation effect cannot be obtained; relatively, when the area ratio is more than 7〇%, when wet The overall size of the garment 10 will vary. The woven fabric of the local syllabus is used to form a fabric that is expanded in size by wet reversibility. In the knit construction in which the size is expanded reversibly by wetness, the number of layers and the number of layers are not particularly smear, and preferably, for example, plain weave, 'woven I weave, or the like, or jersey or double rib knit. , round Luo, ., Wen Knitting, parental ring knitting, adding yarn knitting, single comb Mei Jingping organization, = comb, 34 flat (four) knitting, etc., specially made with circular or mesh braid It is better. 20 is the size change of the P-knife is better than the above-mentioned area change rate of 10% or more gdb, 3 〇 / °, and if the area change rate is less than 10%, == between the service and the skin The volume of the space does not become large, and there is no effect on the gas, and x ' can be easily formed by the manufacturing method as described above. The weaving of the moon can also be applied with a water absorbing agent and jade, and by applying water absorption to the fabric of 31 1354041, and processing the water at the same time: can improve the adhesion of the woven fabric to the woven fabric. For example, in the vinyl ester-polyethylene ethylene-yield-decanoic acid and its derivatives, or poly: day t-ethylene glycol copolymer and other water-absorbent processing agents and in the dyeing liquid (four) Γ · · · domain hi (four) financial processing Mixing and profiting _ 2::::=: immersed in water absorption plus ... coated jade method. The gravure method, the stencil printing method, and the like are used. The garment of the present invention is a woven fabric which is reversibly expanded by wetting with a size and a size which is not changed by the wetting, and is sewn by a method. In this case, in addition to the aforementioned dyeing processing and water absorbing processing, each of the woven fabrics can also be applied to the pilling processing, the purple ray shielding or the anti- _, the quaternary (four), the anti-money, the luminous agent, and the re-reflection. Various processes of the agent 'negative ion generator, water absorbing agent and the like. 20 - Wearing the clothes of the present invention 'When sweating, the size of the portion which is reversibly enlarged by wetting becomes large, and the part exhibits a breathable effect (window box effect) during exercise, and the elimination can be eliminated. The sultry and sticky feeling of sweat produces excellent wearing comfort. Further, the above-described effects of the clothes of the present invention will be described in the following Example 4 and Comparative Example 3 with reference to Fig. 8. The clothes of the present invention can be suitably applied to garments for outerwear, sportswear, underwear, and the like. Further, in the clothes of the present invention, accessories such as buttons may be attached. Example 32 The woven fabric and the garment of the present invention will be further described by way of examples described later. In the examples and comparative examples described later, the following tests were carried out. <Polyester inherent viscosity> 5 Using n-gas phenol as a solvent' and measuring at a temperature of 35 °C. c Polyimine intrinsic viscosity > Using m-cresol as solvent' and measuring at a temperature of 3 °C. "<breaking strength & rupture elongation> φ After the fiber sample was placed in a constant temperature 1 〇忸 humidity room maintained at an air temperature of 25 ° C and a humidity of 60% RH, the sample length was 100 mm and was assembled at Co., Ltd. Shimadzu Corporation's tensile tester 亍>^:/mouth> and stretched at a speed of 200 mm/min, and measured the strength (cN/dtex) and elongation (%) at break, and The average value is obtained by η 5 . <Boiling water shrinkage rate> 15 The boiling water shrinkage ratio (hot water shrinkage ratio) (%) was measured by the method specified in JIS L ^ 4998.7.15, and the average value was obtained by n number 3. φ <composite fiber crimping rate> First, a weighting frame of 1.125 m per frame is used, a load of 49/50 mNx 9x total count (O.lgfx total denier) is applied and the yarn is wound at a fixed speed, and the number of rolls is made. 1 〇 20 turns of small strands 'and twisted the small strands to form a 2 layer of rounds, the application of 49/2500mNx20x9x total count Danny) initial load, placed in boiling water for 30 minutes, after the boiling water treatment 1 〇 (rC2 dryer is dried for 30 minutes, and then the initial load is applied again and placed in the seven dry heat of the crucible for 5 minutes. After the dry heat treatment, the initial load is removed, and at a temperature of 2 〇, 33 1354041, humidity 65% After being placed in the RH environment for more than 24 hours, the weight of the initial load and the total count of 98/50mNx20x9x (〇.2gfx20x total Danny) are loaded to measure the skein length L0, and then only the heavy load is removed to measure the weight removal. After 1 minute, the skein length L1. In addition, the skein was applied to the water of the temperature 2〇〇c 5 for 2 hours after the initial weight was applied, and taken out by the filter paper for 5 seconds 0_69 mN/cm 2 (7 〇 mgf /cm2) pressure to gently wipe off the moisture, load initial load and heavy load to measure The yarn length L0', and then only the heavy load is removed, to measure the skein length L1 after removing the weight by 1 point. According to the above measured value, the following formula is used to calculate the crimping ratio DC (%) during drying, when wet The crimping rate is HC (%), the difference in crimp ratio between drying and wetness (DC-HC) (%), and the average value is obtained by η 5 . The crimp ratio DC (%) during drying = ((L0 - L1 ) / L0) x 100 Water wet crimp ratio HC (%) = ((L0, -LI,) / L0') x 100 <Composite fiber crimp ratio in the braid > 15 After the woven fabric was allowed to stand in air at a temperature of 20 ° C and a humidity of 65% RH for 24 hours, a small piece (n number = 5) of 3 〇 cm x 30 cm in the same direction as the woven fabric was cut out from the woven fabric. The composite fiber was taken out, and a load of 1.76 mN/dtex (200 mg/de) was applied to the composite fiber sample to measure the fiber length L2, and a weight of 〇.〇丨76mN/dtex (2mg/de) was applied after 1 minute of weight removal. 20 to measure the fiber length L3. Then, the composite fiber sample was immersed at a temperature of 30. (: After 2 hours in water, the sample was taken out, and the sample was sandwiched between 1 pair of crepe paper (size 30 cm x 30 cm) within 60 seconds after removal. Between and apply 0. After a pressure of 69 mN/cm2 for 5 seconds, after gently wiping off the moisture from the above sample, a load of 1.76 mN/dtex (200 mg/de) was applied to the above sample to measure the fiber length L2', and in the weight removal 34 1354041 1 After a minute, a load of 〇_〇 176 mN/dtex (2 mg/de) was applied to measure the fiber length L3'. Based on the above measurement results, the crimp ratio DCF (°/〇) at the time of drying and the curling rate hcf (%) of the water wetting were calculated from the following formula. Further, the average value 求出5 is obtained by η 5 and the crimp ratio DCF (%) when dry is ((LOf - L1 f) / L0f) x 1 卷 The shrinkage ratio HCF (%) = (( LOf, a LI f,) / L0f,) X 1 〇〇 <breathability> The drying time is measured by the JIS.L1096-1998.6.27.1A method (Frazil-type gas permeability tester method) Gas permeability (cc/cm2/s) and 10 gas permeability (cc/cm2/s) when wet. However, drying means that the sample is at a temperature of 2 Torr. 〇, humidity 65% RH environment after 24 hours of standing, on the other hand, wet means that the sample is impregnated at temperature 3 (TC water is pulled up after 2 hours, and clamped in 1 pair within 60 seconds Between the papers (size 50cmX 50cm), and the pressure of 490N/m2 (50kgf/m2) is increased for 1 minute, the moisture content between the fibers is removed, and the gas permeability (η = 5) is measured. In addition, the gas permeability change rate is calculated by the following formula: Gas permeability change rate (%) = ((breathability when wet) - (breathability when dry)) / (breathable area when dry) Χ100 <stretching rate of knitted fabric> 20 In addition to changing the load to 1/10 (1.47N = 0.15kgf), the same method as JIS.L1096.8.14_1.B can be used to obtain the knitted fabric. The elongation rate (%) of the white and latitudinal directions is obtained. Further, the average value is obtained by η 5 . <Measurement of yarn length> First, the woven fabric is placed in air at a temperature of 20 ° C and a humidity of 65% RH. After placing 35 1354041 for 24 hours, a small piece of 30 cm x 30 cm (n number = 5) was cut from the braid. Then, the composite fiber sliver was taken out from each piece by one piece. Fiber slivers, measuring the fiber length A (mm) in the composite fiber sliver and the fiber length B (mm) in other fiber slivers. At this time, if it is a non-elastic yarn, apply 5 plus 1.76mN/dtex (200mg/ The load of de), if it is an elastic yarn, is measured by applying a load of 0.0088 mN/dtex (lmg/de). Further, the average value is obtained by η 5 . <Water repellency > Using JIS L 1092.6.2 (spray) Experiment) Measurement of water repellency. 10 <Dimensional change amount> After the woven fabric was left in an environment of a temperature of 20 ° C and a humidity of 65% RH for 24 hours, the sample in the same direction as the woven fabric was cut out (via 2 〇 cm x latitude) On the other hand, the sample was immersed in water at a temperature of 20 ° C for 5 minutes (hereinafter referred to as wet time ^), and the test material was clamped to 2 Between the pieces of filter paper, and the pressure of 490 N/m2 (50 kgf/m2) was increased for 1 minute, and the moisture remaining between the fibers was removed, and the sample area was measured as the area (cm2) at the time of wetting. Then, the following formula was used. The area change rate is calculated as the dimensional change amount (%). Area change rate (%) = ((area when wet) one (the surface when dry) 2 hoarding)) / (area when drying) x l 〇〇 Example 1 is 270 ° C, 290. (: melt intrinsic viscosity [7?] is 1.3 Nylon-6 ' and intrinsic viscosity [77 ^ 0.39 Further, a denatured polyvinyl ester having 2.6 mol% of 5-sodium sulfoisophthalic acid is copolymerized, and a spinning nozzle for a side-by-side type composite fiber disclosed in M44518 (36) (spun hole substance is used) The upper system is located on the same circumference, and the interval (d) is opened and is composed of two arcuate slits A and B, and the area SA of the arcuate slit a of the spinning nozzle hole and the slit width A, the area SB of the arcuate slit B, the slit width 艮, and the arc-shaped 5 slits A and the area SC surrounded by the inner peripheral surface of B satisfy the following formulas 1 to 4. 1 B] <A丨2 1.1'SA/SB$1.8 3 0_4g(SA+SB)/SCS10.0 4 d/A^SO) 10 The amount of sputter is 12.7 g/min, and the above polyvinyl ester is slit The A side is pushed out and the above-mentioned pair 6 is pushed out from the side of the slit B to form a side-by-side type unstretched composite yarn having the shape of the surface shown in Fig. 1. After the unstretched sliver is cooled and solidified and the oil is applied, the sliver is preheated by a preheating roll having a speed of 10 μm/min and a temperature of 60 ° C. Next, at the preheating roll and the speed of 3050 m / An extension heat treatment (extension ratio 3.05 times) was applied between the heating reports heated to a temperature of 150 ° C and coiled to prepare a composite fiber of 84 dtex / 24 fil. The obtained stretched composite fiber had a tensile strength at break of 3.4 cN/dtex and a tensile elongation at break of 40%. Further, when the composite fiber was subjected to boiling water treatment to measure the crimp ratio, the crimp ratio DC was 3.3% during drying, and the crimp ratio HC was 1.6% when wet, and the crimp ratio DC and the curl ratio at the time of drying were 2 干燥. The difference in HC (DC - HC) is 1_7 〇 / 〇. Only the above-mentioned composite fiber (composite fiber without twisting water and not crimped) was used. The double-layer circular knitting machine of No. 28 was used to have 42 latitudes/2.54 cm, 35 laps/ Double rib structure of braided density of 2.54 cm 37 1354041 Circular braid. In addition, the circular knitting material is dyed at a temperature of 130 ° C and a holding time of 15 minutes to make the potential crimping performance of the composite fiber obvious. At this time, the water-absorbing processing agent (polyethylene vinegar-polyethylene glycol copolymer) is relatively dyed. The liquid was in a ratio of 2 ml/l, 5 and was subjected to the same bath treatment at the time of dyeing processing to impart a water-absorbent processing agent to the knitted fabric' and a dry heat of 100 C was applied to the circular fabric for 1 minute. The mass per unit area of the obtained knitted fabric was 214 g/m2, the elongation in the warp direction was 70°/◦, the elongation in the weft direction was 11%, the gas permeability during drying was 90 ml/cm2/s, and the gas permeability at 10 was 370 ml/ The cm2/s and the gas permeability change rate are 311%, and the gas permeability can be greatly improved when wet. Further, in the composite fiber taken out from the knitted fabric, the crimping ratio DCF was 68% at the time of drying, the crimping ratio HCF at the time of wetting was 22%', and the crimping ratio (DCf - hcf) at the time of drying and wetting was 46%. . Example 2 15 The composite fiber used in Example 1 and a general polyethylene multifilament yarn (84 dtex/30 fil) were used, and the same 28-gauge double-layer circular knitting machine as in Example 1 was used, and the circular knitting machine was used. The upper yarn of the first yarn sliver 1 has a composite fiber yarn and a polyester multifilament yarn yarn 'to prepare a double rib with a weft density of 54 latitude/2.54 cm, 34 laps/2.54 cm. The circular knitting was organized, and the same dyeing processing, water absorbing processing, and dry heat final setting as in Example 1 were applied to the 20 circular knitting. The mass per unit area of the obtained knitted fabric was 206 g/m2, and the warp direction elongation was 50 °/. The tensile rate in the weft direction is 11%, the gas permeability during drying is 〇5〇ml/cm2/s, the gas permeability during wetting is 280ml/cm2/s, and the gas permeability change rate is 87%, and 38 is wet. When the breathability is greatly improved. Further, in the composite fiber taken out from the knitted fabric, the crimping ratio DCf was 63% during drying, the crimping rate hcf was 20% when wet, and the crimping ratio (DCF-HCF) at the time of drying and wetting was 43. %. Comparative Example 1 5 was 2 < 7 分别, respectively. (:, 290. (: melt intrinsic viscosity U) of 1.3 Nylon-6, and intrinsic viscosity U] of 0.48 and copolymerization of 2.6 mol% of modified sodium phthalate of 5-sodium sulfonate, Using the spinning nozzle for the side-by-side composite fiber shown in Example 1 and extruding with a discharge amount of 12.7 g/min, respectively, a side-by-side type composite fiber having a single cross-sectional shape as shown in Fig. 1 was formed and 10 Cooling and solidifying with oil agent. Further, the obtained unstretched fiber yarn is preheated by a preheating roll with a speed of 1000 m/min and a temperature of 60 〇c, and then heated to temperature at the preheating roll and speed of 2700 m/min. An extension heat treatment was applied between the heating members of i5〇°C and coiled to obtain a composite fiber of 84citex/24fil. In the composite fiber, the tensile strength at break was 2.3 cN/dtex, and the elongation at break was 15 41%. Further, when the composite fiber is subjected to boiling water treatment to measure the crimp ratio, the crimp ratio DC is 1.2% during drying, the crimp ratio HC is 3.9% when wet, and the crimp ratio DC and the curl ratio HC during wetting are dry. The difference (DC - HC) was 1.7%. The foregoing composite fiber was used, and the braiding was made in the same manner as in Example 1. After knitting, 'the same dyeing process, 20 water processing, and dry heat finishing coagulation as in Example 1 were applied to the circular composition. The mass per unit area of the obtained knitted fabric was 170 g/m2, and the warp direction elongation was 52%. The tensile rate in the direction is 102%, the gas permeability during drying is 230 ml/cm 2 /s, the gas permeability at the time of wetness is 160 ml/cm 2 /s, and the gas permeability change rate is 30%, and the gas permeability is lowered when wet. The composite fiber 39 1354041 taken out from the knitted fabric has a crimping rate DCF of 54% during drying, a shrinkage ratio HCF of 65% when wet, and a difference in crimp ratio (DCF-HCF) during drying and wetting. 11%. Implement your 丨3

A side-by-side composite fiber yarn of the same type as that described in Example 1 was produced, and 5 of the composite fiber yarn was supplied to a general No. 28 Greencoel warp knitting machine, and the composite fiber yarn was fully passed through and passed to the foregoing After the machine is machined, the general polyethylene vinegar multifilament false twisting and processing yarn (33dtex/36fn) with a crimping rate of 20% is fully worn and passed to the previous knitting machine, and is prepared into a double comb. Organize the composition of 0 V eve 10-12, 7 mouth > Bu 23-10 (registered trademark), and the double-bark warp-knitted fabric with 10 latitude and longitude/2.54 cm machine density. In addition, the circular composition is subjected to a temperature of 130. (:, after the dyeing process for 15 minutes, the potential crimping performance of the composite fiber is marked, and the fluororesin water-repellent working fluid is used for the pressure-sensitive processing on the dyed fabric, followed by drying at a temperature of 100 ° C. And applying a dry heat of 160 ° C for 1 minute, the final mass of the finished fabric is 220 g / m 2 , the warp direction stretch rate is 13%, the weft direction stretch rate is 30%, and the water repellency is 5 points. The air permeability during drying is 45 ml/cm 2 /s, the gas permeability at the time of wetting is 64 ml/cm 2 /s, and the gas permeability change rate is 42%, and the gas permeability can be greatly improved when wet. Further, the fabric is taken out by the braid. In the composite fiber, the crimping ratio DCF was 64% during drying and the crimping ratio was 20 when wet ((^ was 32%, and the shrinkage ratio during drying and dampness (dcf-HCf) was 32%. Comparative Example 2) In the same manner as in Comparative Example 1, a side-by-side type composite fiber yarn of a reinforced nylon 6/5-sodium succinimide copolymerized polyvinyl ester was prepared. 40 Using the composite fiber yarn, the same composition as in Example 3 was prepared. ' And apply dyeing processing, water-repellent processing' and dry heat final condensation on the braid. The unit area of the obtained knitted fabric The mass is 210 g/m2, the warp direction stretch rate is 12%, the weft direction stretch rate is 22%, the water repellency is 5 minutes, the air permeability during drying is 54 ml/cm/s, and the gas permeability during wetting is 41 mi/cm2. /s, and the gas permeability change rate is 24%, and the gas permeability is reduced when wet. Further, in the composite fiber taken out from the knitted fabric, the crimping ratio DCF is 56% when dry, and the crimping rate HCF is wet. 62%, and the difference in crimp ratio between drying and wetness (DCf - HCf) is 6%. Example 4 270 ° C '29 〇〇 C melting intrinsic viscosity [7?] is 1.3 Nile - 6. The modified viscosity [7?] is 0.39 and copolymerized 2.6 mol% of the modified polyvinyl ester of 5_sodium sulfonate, and the spinning nozzle for the side-by-side composite fiber shown in Example , is used. And using a discharge amount of 12.7 g / min to form a side-by-side type composite fiber, and after cooling and solidifying and imparting an oil agent, the gauze is preheated by a preheating roll having a speed of 1000 m/min and a temperature of 6 〇t. Next, a heat treatment between the 6-well preheating roll and a heating roll heated at a temperature of 15 ° C and a temperature of 15 ° C was subjected to elongation heat treatment and coiled to obtain 84 out / 24 In the composite fiber, the tensile strength at break is 34 CN/dtex, and the elongation at break is 40° /. Further, when the composite fiber is subjected to boiling water treatment to measure the crimp ratio, the crimp ratio DC during drying is 3.3%, the shrinkage rate Hca is 6% when wet, and the difference between the crimp ratio DC and the shrinkage ratio during wetting (DC _ HC) is 1.70 / 〇〇 only using the aforementioned composite fiber (not treated with boiling water) And the untwisted yarn without curling) was prepared into a flat stitch circular fabric having a weft density of 65 laps/2.54 cm '37 laps/2.54 cm using a double-layer circular knitting machine No. 28. In addition, the circular fabric is dyed at a temperature of 130 ° C and a holding time of 15 minutes to make the potential crimping performance of the composite fiber clear. Then, a temperature of 16 (TC, 1 minute dry heat is applied to the circular fabric 5). Condensation. The obtained fabric (the size is reversibly expanded by wetting), the mass per unit area is 120g/m2, the braiding density is 71 latitudinal number/2.54cm and 61 laps/2.54cm, and the dimensional change is 21 〇 / 0 (7% in the longitudinal direction and 13% in the horizontal direction) In addition, a 28-layer double-layer circular knitting machine was used, and a polyvinyl acetate false twist roll 10 shrink-processed yarn (56 dtex/72 fil) was used to prepare a latitude ring of 45 Number/2.54cm, 41 laps/2.54cm woven double rib weave, and after dyeing, cut the woven (sweet size unchanged) and make a short-sleeved shirt 4. Next, only the chest of the shirt 4 (15 cm in length and 20 cm in width) was cut, and the composite fiber sliver was sliced and fixed on the chest of the shirt 4 as shown in FIG. Wearing the resulting shirt 4, and adjusting it to a temperature of 28 ° C, humidity of 50%, according to The wearing step is followed by a wearing test, and the humidity inside the clothes (between the skin and the clothes) at the time of wearing is measured. The result is as shown in the curve A of FIG. 8 , even in the movement, by being placed on the shirt 4 The breathable effect of the composite fiber fabric on the chest is not sultry, and it can be quite comfortable after the exercise to greatly reduce the stuffiness by the windward ventilation effect. Steps to wear: 5 minutes of static (windy 1.5m/s) - jogging 15 Minutes (101011/11) 4 standstill 42 1354041 10 minutes (no wind) - still 20 minutes (windy 1.5 m / s) Comparative Example 3 The experimenter wears the polyvinyl acetate false twist crimping processing yarn used only in Example 1. A shirt 4 made of (56 dtex/72 fil) was subjected to the same 5 wearing test as in Example 4. As a result, as shown by the curve B of Fig. 8, in the wearing motion, the sultry feeling was strong because the gas permeable effect was hardly exhibited. And the feeling of sultry after exercise still lasts for a long time and there is a sense of discomfort. The possibility of industrial use

The knitted fabric containing the crimped conjugate fiber of the present invention and the garment of the present invention containing the knitted fabric 10 have moisture permeability by water wetting, and promote drying of the knitted fabric, and reduce air permeability and increase thermostatic property by drying. It is also useful as a garment for outerwear, sports, and underwear. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional explanatory view showing an example of a cross-sectional shape of a side-by-side crimping 15 composite fiber included in the knitted fabric of the present invention. Fig. 2 is a cross-sectional explanatory view showing an example of a cross-sectional shape of a side-by-side crimped composite fiber included in another knitted fabric of the present invention. Fig. 3 is a cross-sectional explanatory view showing an example of a cross-sectional shape of a side-by-side type crimped composite fiber included in another knitted fabric of the present invention. Fig. 4 is a cross-sectional explanatory view showing an example of a cross-sectional shape of an eccentric core-sheath type crimped composite fiber included in the present invention. Fig. 5 is a front elevational view showing a garment (shirt) formed of a knitted fabric of the present invention and having a plurality of portions which are moistened with water to improve the gas permeability. 43 1354041 Fig. 6 is a front explanatory view showing a garment (shirt) which is formed of the knitted fabric of the present invention and which is moistened with water to improve the gas permeability. Fig. 7 is a front view showing a garment (shirt) formed of the knitted fabric of the present invention and having a cuff portion and a side body portion which are moistened with water to improve the gas permeability.

Fig. 8 is a view showing that the clothes (shirts) of the present invention (Example 1) and the clothes (shirts) of the present invention (outer example 1) are worn on the human body, and are stationary (windy 1.5 m/s) - jogging - Static (no wind) - a graph of relative humidity variation in the gap between human skin and shirt during a static (windy 1.5 m/s) wearing test. 10 [Main component symbol description]

1.. . Partial la... Center point 2.. Part 2a... Part of the circumference 2b... Center point 4.. Short-sleeved shirt 5.. Front part 6.. . Knitted part 7... Chest 8.. Knitted part 9.. Side body part 10.. Sleeve bottom 11.. Knitted part 44

Claims (1)

Application No. 94133493, the scope of application for patent modification, Wang Xi, \ 曰 气 4 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 And a polyester resin component which is joined to a side-by-side structure or an eccentric core-sheath structure and a polyamide resin component, and includes a yarn having a composite fiber which is crimped by heat treatment, and the aforementioned roll included in the knitted fabric The shrinkage composite fiber content is 1〇1 to 1% of the summer%; the polyester resin component of the crimped composite fiber has an intrinsic viscosity of 〇3〇~〇39; and the polyacetamide resin component of the crimped composite fiber has iO And the intrinsic viscosity of the composite fabric of the test fabric, and the i-part of the composite fiber sample is allowed to stand in an environment of a temperature of 20 ° C and a humidity of 65% RH for 24 hours to dry. The crimping ratio DCF (%) of the crimped conjugate fiber was measured, and the other portion of the conjugate fiber sample was immersed in water at a temperature of 3 Torr for 2 hours, and the sample was pulled up from the water, and pulled. After being trapped in the air at a temperature of 3 ° C and a humidity of 90% RH in the next 6 sec., and applying a pressure of 〇.69 mN/cm 2 to the sample for 5 seconds, the measurement was carried out. At this time, the above-mentioned dcf (%) and HCF (°/〇) can satisfy the following formula: (DCf-HCf)^1〇(%) ° 2. A knitted fabric comprising a crimped conjugate fiber which is improved in moisture permeability by water wetting, wherein the polyester resin component is composed of a denatured polyester resin, and the denatured polyester resin is based on an acid component content. The copolymerization has 2.0 to 4.5 mol% of 5-naphthalene isophthalic acid. 3', as claimed in the first paragraph of the patent application, the use of water-wet to improve the gas permeability of the 1354041 application No. 94,133, 493, the application of the patent scope, the amendment, the stipulation of the stipulation of 100.4.15, the woven fabric of the composite fiber, wherein the aforementioned crimping compound The woven yarn of the fiber has a burning number of 0 to 300 T/m or less. 4. The woven fabric containing the crimped conjugate fiber which is improved in water permeability by water wetting, wherein the woven fabric contains the aforementioned roll. The 5 conjugate fiber and other fibers different from the crimped conjugate fiber. 5. The knitted fabric comprising crimped conjugate fibers which utilizes water wetting to improve gas permeability according to claim 1, wherein the other fibers are selected from non-crimped fibers or have a DCF_HCF system of less than 10%. Fiber. 10. The knitted fabric comprising the crimped conjugate fiber using the water wet mash to improve the gas permeability according to the first aspect of the invention, wherein the woven fabric containing the crimped conjugate fiber is subjected to the law specified in JIS.L1096.8.14.1B When the stretchability of the stretch fabric is measured (however, when the load value attached to the test braid test piece is changed to 1.47 N), if the knitted fabric is a woven fabric, it is selected from at least one of the 15 direction and the weft direction. When the knitted fabric is a knitted fabric, the stretch ratio of at least one of the transverse direction and the longitudinal direction is 10% or more. 7. The knitted fabric comprising a crimped conjugate fiber which utilizes water wetting to improve gas permeability according to the first aspect of the invention, wherein the woven fabric comprising the crimped conjugate fiber has a multilayer structure and is contained in at least one layer thereof. The crimped composite fiber of 30 to 1% by mass based on the weight of the layer. 8. The knitted fabric comprising a crimped conjugate fiber which utilizes water wetting to improve gas permeability according to the fourth aspect of the patent application, wherein the woven fabric has a circular braided fabric, and further, the circular knitting yarn of the circular knitting fabric is The invention relates to the invention of the above-mentioned crimping 46 1354041 Patent Application No. 94,133,493, the entire disclosure of which is incorporated herein by reference. 9. The knitted fabric comprising a crimped conjugate fiber which utilizes water wetting to improve gas permeability according to claim 4, wherein the woven fabric is a woven fabric, and the yarn containing the crimped conjugate fiber is the crimped conjugate fiber and The blended yarn of the other fibers of the above-mentioned fifth, and the warp and weft of the fabric, or the warp or weft, are composed of the blended yarn of the crimped composite fiber and the other fibers. 10. The knitted fabric comprising a crimped conjugate fiber which is improved in moisture permeability by water wetting according to item 4 of the fourth aspect of the invention, wherein in the woven fabric, the yarn consisting of the ten-coiled composite fiber and the other fiber are formed. The yarn is arranged in at least one of the warp direction and the weft direction, or at least one of the horizontal direction and the longitudinal direction, and is arranged such that at least one of the yarns is interlaced. [11] The woven fabric comprising a 15 crimped composite fiber using water wetting to improve gas permeability according to the fourth aspect of the patent application, wherein the crimped conjugate fiber and the other fiber system are formed into a core/sheath type composite yarn, and The core portion of the composite yarn is composed of the above-mentioned composite fiber, and the sheath portion is composed of the other fibers described above. A knitted fabric comprising 20 crimped composite fibers, which is selected from the group consisting of polyester fibers. 13. The woven fabric comprising a crimped conjugate fiber which utilizes water wetting to improve gas permeability according to the first aspect of the patent application, wherein the woven fabric is subjected to a water absorbing agent processor, and the application scope is amended by the application of the water absorbing agent 0 47 1354041 Date 100A15 14. A knitted fabric comprising a crimped conjugate fiber which utilizes water wetting to improve gas permeability, as in claim 1, wherein the woven fabric is subjected to a water repellent processor. 15. A knitted fabric comprising a 5 crimped composite fiber, which is water-wet and gas-permeable, according to the first aspect of the patent application, wherein the knitted fabric is subjected to a dyeing process. [16] A knitted fabric comprising a crimped conjugate fiber which utilizes water wetting to improve gas permeability according to the first aspect of the patent application, wherein the test sample of the woven fabric is placed in an environment of a temperature of 20 C and a leak of 65% RH. Hour and dry and 10 to prepare a dry sample, and 'the test sample of the aforementioned braid is immersed in water at a temperature of 30 ° C for 2 hours, and then the sample is pulled up from the water, and within 60 seconds after the pulling, at the temperature The sample was sandwiched between a pair of filter papers in an air of 30 ° C 'humidity 9〇% RH, and the sample was placed under a pressure of 490 N/m 2 (50 kgf/m 2 ) for 1 minute, and the above test 15 was gently removed. The water in the material is prepared into a water-wet sample, and the air-wet sample according to the method of JIS丄1096-1998.6.27.1A (Frazil-type gas permeability tester) is subjected to the above-mentioned dry sample and the water-wet sample. The measurement, the gas permeability change rate calculated from the obtained measurement result by the following formula is 3% or more. 2〇Vapor permeability change rate (%) = j ^Wetting sample (dry sample gas permeability)] (Dry sample gas permeability) xl0° π. - A kind of clothes' contains the patented Longdib 16 items For the woven fabric, the woven fabric can be wetted by water. 48 1354041 Application No. 94,133,493 Application No. Patent Revision No. 100A15 This reversibly expands the size to improve the gas permeability. 18_ The garment of claim 17 wherein the woven fabric comprising the crimped composite fiber is formed as at least one of an amine separation portion, a side body portion, a chest portion, a back portion and a shoulder portion of the garment. 5 I9. The garment of the ninth aspect of the invention, wherein the portion of the garment formed by the woven fabric comprising the crimped conjugate fiber has an area of 1 cm 2 or more. 2. The garment according to claim 17, wherein the knitted fabric comprising the crimped composite fiber is selected from the group consisting of a circular knitted fabric and a mesh coarse-woven fabric. 10 21. The garment of claim 17, wherein the garment is selected from the group consisting of garments for outerwear, sportswear, and underwear. «I 49