WO2015016431A1 - Fiberization method of knots derived from pulp, fiberized knots and paper products using same - Google Patents

Fiberization method of knots derived from pulp, fiberized knots and paper products using same Download PDF

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Publication number
WO2015016431A1
WO2015016431A1 PCT/KR2013/010862 KR2013010862W WO2015016431A1 WO 2015016431 A1 WO2015016431 A1 WO 2015016431A1 KR 2013010862 W KR2013010862 W KR 2013010862W WO 2015016431 A1 WO2015016431 A1 WO 2015016431A1
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WO
WIPO (PCT)
Prior art keywords
note
cleaner
notebook
screen
knots
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Application number
PCT/KR2013/010862
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French (fr)
Korean (ko)
Inventor
박시한
이종훈
박현민
Original Assignee
무림피앤피 주식회사
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Priority claimed from KR1020130103671A external-priority patent/KR101517426B1/en
Application filed by 무림피앤피 주식회사 filed Critical 무림피앤피 주식회사
Publication of WO2015016431A1 publication Critical patent/WO2015016431A1/en

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/14Secondary fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/001Modification of pulp properties
    • D21C9/007Modification of pulp properties by mechanical or physical means

Definitions

  • the present invention relates to a fiberization method of knots recovered as a by-product during the pulp papermaking process, through which fiberized knots, and paper products using the fiberized knots.
  • Chemical pulp is generally produced through the process of cooking and bleaching wood chips.
  • cooking, separating and filtering without fibrosis is called knots.
  • Dictionary means knots in wood knots or plurals, but knots in pulp paper are bundles of unsealed chips, wood knots, undissociated fibers that are not pulped after the pulp cooking process. It is common to name in-shive and other impurities rejected in the pulp cooking process.
  • knots are not collected but not disposed of, the knots are classified as wastes, resulting in processing costs. Therefore, knots were not discarded, but were inevitably recovered in the cooking process and reused in the pulp production process.
  • the present invention has been made to solve such a conventional problem, a method of fiberizing knots derived from pulp to reuse knots that have not been kneaded in the pulp cooking process outside the pulp production process, and fiberized using the same.
  • the purpose is to provide knots, and fiberized knots as raw materials for paper products.
  • the fiberization method of knots comprises a collection step of collecting undigested notes in the process of cooking wood chips to produce pulp; A grinding step of crushing the collected notes; A primary cleaner step of removing impurities of the ground notebook; And it is characterized in that it comprises a concentration step in which the notebook is subjected to the cleaner step is concentrated and the waste liquid is separated.
  • the collecting step may include a first collecting step in which a non-digested and separated note is collected on a screen in a process of cooking wood chips; And a second collecting step in which the collected notes are dehydrated to remove the black liquor.
  • the collected notebook may be dehydrated to have a water content of 1 to 50 parts by weight.
  • the grinding step may include a first grinding step in which the notebook, which has undergone the collection step, is pulverized by passing through a screen having a diameter of 11 to 17 mm installed in the grinder.
  • the screen of the first grinding step may be a screen having a diameter of 12 to 15mm.
  • the pulverizing step may further include a second pulverizing step in which the pulverized note is pulverized through a screen having a diameter of 8 to 11 mm installed in a pulverizer.
  • the screen of the second milling step may be a screen having a diameter of 9 to 10.5mm.
  • the primary cleaner step may include a first cleaner step in which the crushed notebook is diluted; And a second cleaner step in which impurities contained in the diluted notebook are removed.
  • the note may be diluted to a concentration of 3 to 6 parts by weight.
  • impurities included in the notebook may be removed by centrifugation.
  • the notebook may be concentrated to a concentration of 25 to 35 parts by weight.
  • the fiberization method of the note may further include a pulper treatment step of dividing the note pulverized in the crushing step is separated into fibrous between the grinding step and the primary cleaner step.
  • the pulper treatment step may include a first pulper treatment step in which the ground notebook is diluted to a concentration of 4.5 to 6.5 parts by weight; And a second pulper treatment step in which the diluted notebook is separated into fibers by pulper.
  • the diluted notes are 1 Pulper treatment for from 30 minutes.
  • the fiberizing method of the note may further include a deflake processing step of dispersing the bound fiber material by mixing and stirring the cleaner treated note using a deflake between the cleaner step and the concentration step.
  • the deflake processing step may use a bar type deflake having a bar spacing of 2 to 4 mm.
  • the fiberization method of the note may further include a secondary cleaner step of removing the foreign matter by diluting the deflake treated note, between the deflake processing step and the concentration step.
  • the deflaked notebook may be diluted to a concentration of 0.5 to 2 parts by weight.
  • the fiberization method of the note further includes a pressure screening step between the first cleaner step and the concentration step, the foreign matter of the note that passed through the second cleaner step is further removed through the screen to improve the quality of the final fiber product. can do.
  • the diameter of the screen in the pressure screening step may be 0.2 to 0.4mm.
  • the fiberizing method of the notes according to the present invention is a collection step of collecting unexplained notes in the process of cooking wood chips to produce pulp; A grinding step of crushing the collected notes; A pulper treatment step of dividing the notes pulverized in the crushing step into fibrous phases; A primary cleaner step of removing impurities of the ground notebook; A deflake processing step of dispersing the bound fiber material by mixing and stirring the cleaner-treated note using a deflake; A secondary cleaner step of diluting the deflaked notebook to remove foreign substances; A pressure screening step in which foreign substances of the notebook which have undergone the cleaner step are further removed through the screen to improve the quality of the final fiber product; And it is characterized in that it comprises a concentration step in which the notebook is subjected to the cleaner step is concentrated and the waste liquid is separated.
  • the fiberized notebook according to the present invention is characterized in that the fiberized by the fiberizing method according to the present invention described above.
  • the paper product according to the invention is characterized in that it comprises a fiberized notebook according to the present invention described above.
  • the paper products may include industrial wipers, hand towels, napkins, tissues, industrial packaging paper, paper boards, commercial paper, and AFH products.
  • knots according to the present invention by treating the knots that are classified as conventional wastes and excessively consumed in processing, the knots can be utilized for a novel use as a raw material of paper products. Therefore, it is possible to reduce the disposal cost of the note in the pulp process, and lower the risk of lowering the final quality of the conventional pulp.
  • the 'pulp manufacturing process' refers to the process of manufacturing wood chips from wood, cooking, washing, first screening, bleaching, and second screening ( It is a process including screening), drying process and finishing process, and refers to a process for producing pulp, which is a raw material such as fiber or paper.
  • 'Steaming' is a process that treats wood chips with chemicals and then boils them at high temperatures and / or high pressures to weaken lignin, which binds fibers to fibers. In the process of boiling, non-fibrous substances in plant raw materials are melted, and the fibers are separated in a relatively pure state.
  • Knots are unpulled pulped at the end of the cooking process during the pulp manufacturing process, unfiltered chips screened, wood knots, shived bundles of undissociated fibers, and rejected in the pulp cooking process. It means other impurities.
  • Pulper means a device for dissolving dry pulp, old paper, damaged paper, and the like into the pulp dispersion.
  • Dissociation is an essential step in the pulp manufacturing process, and means to separate the pulp material into fibrous form.
  • 'Bonding fiber' refers to a bundle of yet less loose fibers in the pulp fibers that are the paper stock.
  • 'Impurities' or 'foreign materials' refers to materials other than fibres in knots, and refers to black liquor, waste liquid, undissociated materials, stone powder, rubber, and other chemical components.
  • 'Paper' means a small piece of paper.
  • Black liquor' refers to blackish brown waste which is produced when cooking wood is pulp.
  • a “deflake” is a device that dissolves and dissociates raw fibers by mixing the raw fibers at high speed and stirring them.
  • 'Paper products' include industrial wipers, hand towels, napkins, tissues, industrial packaging, paper boards, and AFH (Away From Home) products used in industrial or non-home use or in spaces used by many people.
  • AFH Away From Home
  • the fiberizing method of knots according to the present invention includes a collection step of collecting unexplained notes in the process of cooking wood chips to produce pulp; A grinding step of crushing the collected notes; A primary cleaner step of removing impurities of the ground notebook; And it is characterized in that it comprises a concentration step in which the notebook is subjected to the cleaner step is concentrated and the waste liquid is separated.
  • the fiberization method of the knot according to the present invention may further include a pulper treatment step in which the knots pulverized in the crushing step are separated into fibrous phases between the crushing step and the first cleaner step.
  • the fiberizing method of the notebook according to the present invention is a mixture between the primary cleaner step and the concentration step, the primary cleaner-treated knot is mixed and stirred using a de-flake to disperse the bound fiber material
  • the deflake processing step may be further included.
  • the fiberizing method of the notebook according to the present invention may further include a secondary cleaner step of removing the foreign matter by diluting the deflaked notebook between the deflake processing step and the concentration step. have.
  • the fiberizing method of the notebook according to the present invention between the first cleaner step and the concentration step, to remove the foreign matter of the note that passed through the cleaner step through the screen to increase the quality of the final fiber product.
  • the pressure screening step may be further included.
  • the fiberizing method of the notes according to the present invention is a collection step of collecting unexplained notes in the process of cooking wood chips to produce pulp; A grinding step of crushing the collected notes; A pulper treatment step of dividing the notes pulverized in the crushing step into fibrous phases; A primary cleaner step of removing impurities of the ground notebook; A deflake processing step of dispersing the bound fiber material by mixing and stirring the cleaner-treated note using a deflake; A secondary cleaner step of diluting the deflaked notebook to remove foreign substances; A pressure screening step in which foreign substances of the notebook which have undergone the cleaner step are further removed through the screen to improve the quality of the final fiber product; And it is characterized in that it comprises a concentration step in which the notebook is subjected to the cleaner step is concentrated and the waste liquid is separated.
  • the collecting step includes a first collecting step of separating and collecting knots that have been filtered out on the screen by cooking the wood chips; And a second collecting step in which the collected notes are dehydrated to remove the black liquor.
  • the knots collected in the first collection step are collected together with the waste liquid of the chemical used in the pulp cooking process, so that the moisture content is high, but the knots having a moisture content of 70 parts by weight or more are inferior in mechanical treatment efficiency. . Therefore, dehydration work to separate the waste fluid from knots while lowering the water content to lower the water content to 50 parts by weight or less. It is preferable that moisture content is 1-50 weight part. Centrifugal dehydrator, screen, etc. may be used in the dehydration operation, but is not limited thereto. Dewatering wastewater is sent to a water treatment plant.
  • the notes processed in the collecting step are pulverized through a pulverizer, and the moisture of knots is dried to 30 to 40 parts by weight through the pulverizing step.
  • the pulverizer may be used without limitation, such as wood chip grinding (grinding) machine, a machine for crushing plastic, a machine for producing sawdust, a mixer-type machine, etc. used in the conventional pulp manufacturing process.
  • grinding grinding
  • a machine for crushing plastic a machine for producing sawdust
  • mixer-type machine etc.
  • power consumption of 1000 kW or more is low and economic efficiency is low.
  • the grinding step may be divided into two steps, the first grinding step and the second grinding step, depending on the size of the screen installed in the grinder to prevent carbonization of the note.
  • the screen may be installed at the bottom of the mill, and is a device for filtering knots that have been milled.
  • the diameter of the screen used in the first grinding step may be 11 to 17mm, preferably 12 to 15mm ( ⁇ , pie), more preferably 12mm in diameter can be used. If the diameter is smaller than 12mm, clogging occurs because the note containing water cannot pass. If the diameter is over 12mm, it passes smoothly. However, since most of the notebooks pass through without grinding when the diameter of the screen is 15 mm or more, it is preferable to use the diameter of the screen of 12 to 15 mm.
  • the diameter of the screen is smaller than that of the first grinding step so as to be 8 to 11 mm, preferably 9 to 10.5 mm, more preferably 10 mm in diameter. If the diameter is smaller than 9mm, the notebook cannot pass through and blockage occurs. If the diameter is 10.5mm or more, it passes without the second grinding step. Therefore, the diameter of the screen is 9 to 10.5mm, more preferably, 10mm in diameter. desirable.
  • the dehydrated notebook may be crushed by a mixer-type device.
  • the grinding step may be composed of one step of grinding the note with a mixer without passing through the screen.
  • a mixer a super mixer which is a mixer type device can be used.
  • the pulverized note is diluted with a pulper to dissociate.
  • Dissociation is an essential step in the pulp manufacturing process, and means to separate the pulp material into fibrous form.
  • Pulper refers to an apparatus for dissolving dry pulp, old paper, damaged paper, and the like into a pulp dispersion. Pulper may use Intensa Pulper, which is commercially available from general paper companies.
  • the pulper treatment step may include a first pulper treatment step in which the ground notebook is diluted to a concentration of 4.5 to 6.5 parts by weight; And a second pulper treatment step in which the diluted notebook is separated into fibers by pulper.
  • the intensa pulper may be dissociated smaller than the size of the screen while crushing knots with a rotating screen and a circular screen facility of 3 to 6.5 pies.
  • the note is diluted to a concentration of 4.5 to 6.5 parts by weight, preferably 5 to 6 parts by weight, in an intensa pulper, with a concentration of 5 to 6 parts by weight being the most effective. It is preferable that the notes are processed for 1 to 30 minutes in the intensa pulper, and there is no significant difference in the processing efficiency of the notes according to the processing time at 30 minutes or more.
  • the primary cleaner step is a pulper treatment This process removes undissociated substances from the note or other impurities that may damage the equipment when entering the product manufacturing process, such as stone powder and rubber, by centrifugation in a high concentration cleaner.
  • the primary cleaner step may include a first cleaner step in which the crushed notebook is diluted; And a second cleaner step in which impurities contained in the diluted notebook are removed.
  • the first cleaner step may dilute the notebook to a concentration of 3 to 6 parts by weight.
  • a high concentration cleaner may be used, and the high concentration cleaner may use, for example, an apparatus generally used in the paper industry as a high concentration cleaner.
  • impurities included in the notebook may be removed by centrifugation.
  • the undissociated knots in the impurities may be recovered and then transferred to the intensa pulper to be pulped again.
  • the deflake processing step is a step of adding the primary cleaner-treated notes to a deflaker, mixing and stirring at high speed, dispersing fiber material and dissociating undissolved paper chips.
  • the deflaker has a blade-shaped rotating body therein and separates and dissociates the fiber material passing through the rotating body at high speed.
  • the dissociation effect is excellent when the bar spacing is 2 to 4 mm, and is most preferable at 3.0 mm.
  • the secondary cleaner step may dilute the notes and remove the foreign matter by centrifugation in order to remove the binding fibers remaining after the deflake processing. Lower the concentration compared to the primary cleaner stage. This is because large foreign substances have already been removed in the first cleaner stage. Binding fibers must be removed because they can degrade product quality or cause paper jams in paper manufacturing.
  • the cleaner may use a low concentration cleaner commonly used in the paper industry.
  • the note may be diluted to a concentration of 0.5 to 2 parts by weight in a low concentration cleaner, preferably to a concentration of 0.5 to 1 parts by weight.
  • the pressure screen may use a pressure screen generally used in the paper industry.
  • the diameter of the screen is preferably 0.2 to 0.4mm, more preferably a screen of 0.3mm can be used.
  • Foreign materials may pass through the screen in the screen of 0.4 mm or more, and when the screen of less than 0.2 mm is used, the yield may be significantly reduced to less than 85% compared to the product quality improvement effect.
  • the fiberized notes can be concentrated while undergoing a cleaner step or a pressure screening step. At the same time, the waste liquid contained in the notebook can be separated.
  • the thickener used in the thickening step may be a screw type thickener commonly used in the paper industry, for example, a screw press from Voith.
  • the notebook may be concentrated to a concentration of 25 to 35 parts by weight, preferably 30 parts by weight. Through the concentration step, finally fibrized knots can be obtained.
  • Knots fiberized by the fiberization method comprising the above steps can be used for the manufacture of paper products.
  • the paper products may include industrial wipers, hand towels, napkins, tissues, industrial packaging paper, paper boards, commercial paper, and AFH products.
  • AFH products are products excluding home use, and are products such as toilet paper, wipers, napkins, hand towels, etc., which are provided in public places, and include wipers used as a means for wiping machines or machine parts for industrial purposes.
  • knots separated on the screen are separated and the water content is reduced to 50 parts by weight using a centrifugal dehydrator.
  • the dehydrated notebook is crushed using a sawdust maker and passed through a 12 mm diameter screen.
  • the notebook is placed in a high-density cleaner (Voith), diluted to 4.5 parts by weight, and stone dust, rubber and binding fibers are removed.
  • the note is concentrated to a concentration of 30 parts by weight using a screw press (Voith).
  • the waste liquor is separated through the screen of the concentrator to obtain fibrosis notes.
  • knots separated on the screen are separated and the water content is reduced to 50 parts by weight using a centrifugal dehydrator.
  • the dehydrated notebook is crushed using a sawdust maker and passed through a 12 mm diameter screen. It is then crushed again and passed through a 10 mm diameter screen.
  • Purified water was added to the pulverized notebook, diluted to 5.5 parts by weight, and placed in an Intensa pulper having a circular screen having a diameter of 5 mm, followed by dissociation for 20 minutes.
  • the dissociated notes are added to a high concentration cleaner (Voith), diluted to 4.5 parts by weight, and stone powder, rubber and binding fibers are removed.
  • the notebook is placed in a deflaker with a bar spacing of 3 mm to disperse the binding fibers and dissociate the undissolved pieces (small pieces of paper).
  • the notebook dispersed in a deflake is added to a low concentration cleaner (Voith), diluted to 1.2 parts by weight, and the remaining binding fibers are removed.
  • a low concentration cleaner Voith
  • the notes processed in the pressure screen instrument are concentrated to a concentration of 304 parts by means of a screw press (Voith).
  • the waste liquor is separated through the screen of the concentrator to obtain fibrosis notes.
  • the mixed natural pulp and fiberized note mixture was added to a low concentration cleaner (Voith, Inc.), diluted to 1.2 parts by weight, and foreign substances were removed.
  • a low concentration cleaner Vinyl, Inc.
  • the mixture passed through the low concentration cleaner was put in a pressure screen (Voith, Inc.) to remove foreign matter once more using pressure.
  • the mixture is introduced into a commercial papermaking machine and 0.9 parts by weight of fibers are injected through a head box of the machine.
  • the injected fiber forms a paper-based sheet on the wire (forming step).
  • the paper-based paper formed on the wire has a water content of 40 parts by weight during the pressing step.
  • the mixed natural pulp and fiberized note mixture was added to a low concentration cleaner (Voith, Inc.), diluted to 1.2 parts by weight, and foreign substances were removed.
  • a low concentration cleaner Vinyl, Inc.
  • the mixture passed through the low concentration cleaner was put in a pressure screen (Voith, Inc.) to remove foreign matter once more using pressure.
  • the mixture is introduced into a commercial papermaking machine and 0.9 parts by weight of fibers are injected through a head box of the machine.
  • the injected fiber forms a paper-based sheet on the wire (forming step).
  • the paper-based paper formed on the wire has a water content of 40 parts by weight during the pressing step.
  • Example 5 A manufacturing method of an industrial wiper including a fiberized notebook
  • the fiberized notebook according to Example 2 was diluted to 4 parts by weight, and then subjected to beating treatment by adding to a Double Disk Refiner (DDR).
  • DDR Double Disk Refiner
  • the mixed natural pulp and fiberized note mixture was added to a low concentration cleaner (Voith, Inc.), diluted to 1.2 parts by weight, and foreign substances were removed.
  • a low concentration cleaner Vinyl, Inc.
  • the mixture passed through the low concentration cleaner was put in a pressure screen (Voith, Inc.) to remove foreign matter once more using pressure.
  • the mixture is introduced into a tissue machine and a 0.9 weight part fiber is injected through a head box of the machine.
  • the injected fiber forms a paper-based sheet on the wire (forming step).
  • the paper-based paper formed on the wire has a water content of 40 parts by weight during the pressing step.
  • the knots are fiberized through the manufacturing method of the fiberized notes according to the present invention, and paper products are manufactured using the fiberized notes, thereby reducing the disposal cost of the notes in the pulp process and recycling them with conventional pulp. This can reduce the risk of degrading the final quality of the pulp.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Paper (AREA)

Abstract

The present invention relates to a fiberization method of knots for the reuse of undigested knots during the digestion of wood chips for manufacturing pulp outside a pulp production process, fiberized knots using same and paper products using the fiberized knots. By fiberizing and using knots, which have commonly been classified as waste and involve excessive cost to discard, in the production of paper products, the cost for discarding knots in a pulp process may be reduced, and the danger of degrading the final quality of pulp (when knots are recycled into pulp using a method of the prior art) may be reduced.

Description

펄프에서 유래한 노트의 섬유화방법, 섬유화된 노트 및 이를 이용한 종이 제품Fibrosis method of knots derived from pulp, fiberized knots and paper products using same
본 발명은 펄프 제지 공정 중 부산물로 회수되는 노트(knots)의 섬유화 방법, 이를 통하여 섬유화된 노트(knots), 및 그 섬유화된 노트(knots)를 이용한 종이 제품에 관한 것이다.The present invention relates to a fiberization method of knots recovered as a by-product during the pulp papermaking process, through which fiberized knots, and paper products using the fiberized knots.
화학펄프는 일반적으로 나무칩(wood chip)을 증해(cooking)하는 과정과 표백(bleaching)하는 과정을 거쳐 생산하고 있다. 증해 과정에서 증해, 섬유화되지 않고 분리되어 걸러지는 부분을 노트(knots)라고 한다. 사전적으로 노트는 나무옹이 또는 복수형으로 사용될 경우에는 매듭이라는 뜻이나, 펄프 제지 분야에서 노트(knots)는 펄프 증해 공정 후단에서 펄프화되지 않고 스크린에 걸러진 미증해 칩, 나무옹이, 해리되지 않은 섬유 다발인 샤이브(shive), 및 펄프 증해 공정에서 리젝트 처리된 기타 불순물을 통칭하는 것이 일반적이다.Chemical pulp is generally produced through the process of cooking and bleaching wood chips. In the cooking process, cooking, separating and filtering without fibrosis is called knots. Dictionary means knots in wood knots or plurals, but knots in pulp paper are bundles of unsealed chips, wood knots, undissociated fibers that are not pulped after the pulp cooking process. It is common to name in-shive and other impurities rejected in the pulp cooking process.
종래 펄프 증해 공정에서 증해되지 않은 노트(knots)는 증해 공정으로 회수되어 재사용되는 것이 일반적이었으나, 다시 증해공정을 거칠 경우 처음 증해 공정에서 사용한 약품을 다시 투입해야 하는 문제가 있었으며, 또한 약품을 투입하여 증해 공정을 반복하더라도 수율이 낮아 펄프의 최종 품질을 저하시킨다는 문제가 있었다.In the conventional pulp cooking process, knots that were not cooked in the pulp cooking process were generally recovered and reused in the cooking process, but when the cooking process was performed again, there was a problem of re-injecting the chemicals used in the first cooking process. Even if the cooking process was repeated, there was a problem that the yield was low, which lowered the final quality of the pulp.
나아가, 미증해된 노트(knots)를 회수하지 않고 폐기처리 할 경우에도, 노트(knots)는 폐기물로 분류되므로 처리 비용이 발생된다. 따라서 노트(knots)가 폐기되지 않고 부득이하게 증해 공정으로 회수되어 펄프 생산 공정에서 재사용되는 문제가 있었다. Furthermore, even when knots are not collected but not disposed of, the knots are classified as wastes, resulting in processing costs. Therefore, knots were not discarded, but were inevitably recovered in the cooking process and reused in the pulp production process.
따라서, 전세계적으로 노트(knots)를 재활용하기 위한 시도가 계속되고 있으며, 일부는 발생된 노트(knots)를 아스팔트의 원료로 사용하고 있으나, 미증해된 노트를 섬유화시켜 섬유로 재활용하여 상업용 제지 등 종이 제품 생산의 원료로 사용되고 있는 사례는 없다. Therefore, attempts are being made to recycle knots all over the world, and some use knots as raw materials for asphalt. However, unused knots are made into fibers and recycled into fibers for commercial paper making. There is no case that is used as raw material of paper product production.
이에, 본 발명은 이러한 종래의 문제점을 해결하기 위하여 이루어진 것으로, 펄프 증해 공정에서 미증해된 노트(knots)를 펄프 생산 공정 외에서 재사용하기 위하여 펄프에서 유래한 노트를 섬유화하는 방법, 이를 이용하여 섬유화된 노트(knots), 및 섬유화된 노트(knots)를 종이 제품의 원료로 제공하는데 그 목적이 있다.Accordingly, the present invention has been made to solve such a conventional problem, a method of fiberizing knots derived from pulp to reuse knots that have not been kneaded in the pulp cooking process outside the pulp production process, and fiberized using the same. The purpose is to provide knots, and fiberized knots as raw materials for paper products.
상기한 목적을 달성하기 위하여, 본 발명에 따른 노트(knots)의 섬유화방법은 펄프를 제조하기 위하여 목재칩을 증해하는 공정에서 미증해된 노트를 수집하는 수집단계; 상기 수집된 노트가 분쇄되는 분쇄단계; 상기 분쇄된 노트의 불순물이 제거되는 1차 클리너단계; 및 상기 클리너단계를 거친 노트가 농축되고 폐액이 분리되는 농축단계를 포함하는 것을 특징으로 한다.In order to achieve the above object, the fiberization method of knots according to the present invention comprises a collection step of collecting undigested notes in the process of cooking wood chips to produce pulp; A grinding step of crushing the collected notes; A primary cleaner step of removing impurities of the ground notebook; And it is characterized in that it comprises a concentration step in which the notebook is subjected to the cleaner step is concentrated and the waste liquid is separated.
상기 수집단계는 목재칩을 증해하는 공정에서 미증해되어 분리된 노트가 스크린으로 수집되는 제1수집단계; 및 상기 수집된 노트가 탈수되어 흑액이 제거되는 제2수집단계를 포함하여 구성될 수 있다.The collecting step may include a first collecting step in which a non-digested and separated note is collected on a screen in a process of cooking wood chips; And a second collecting step in which the collected notes are dehydrated to remove the black liquor.
상기 제2수집단계에서 상기 수집된 노트는 수분함량이 1 내지 50중량부가 되도록 탈수될 수 있다.In the second collecting step, the collected notebook may be dehydrated to have a water content of 1 to 50 parts by weight.
상기 분쇄단계는 상기 수집단계를 거친 노트가 분쇄기에 설치된 직경 11 내지 17mm의 스크린을 통과하여 분쇄되는 제1분쇄단계를 포함할 수 있다.The grinding step may include a first grinding step in which the notebook, which has undergone the collection step, is pulverized by passing through a screen having a diameter of 11 to 17 mm installed in the grinder.
상기 제1분쇄단계의 스크린은 직경 12 내지 15mm의 스크린일 수 있다.The screen of the first grinding step may be a screen having a diameter of 12 to 15mm.
상기 분쇄단계는 상기 분쇄된 노트가 분쇄기에 설치된 직경 8 내지 11mm의 스크린을 통과하여 분쇄되는 제2분쇄단계를 추가로 포함하여 구성될 수 있다.The pulverizing step may further include a second pulverizing step in which the pulverized note is pulverized through a screen having a diameter of 8 to 11 mm installed in a pulverizer.
상기 제2분쇄단계의 스크린은 직경 9 내지 10.5mm의 스크린일 수 있다.The screen of the second milling step may be a screen having a diameter of 9 to 10.5mm.
상기 1차 클리너단계는 분쇄된 노트가 희석되는 제1클리너단계; 및 상기 희석된 노트에 포함된 불순물이 제거되는 제2클리너단계를 포함하여 구성될 수 있다.The primary cleaner step may include a first cleaner step in which the crushed notebook is diluted; And a second cleaner step in which impurities contained in the diluted notebook are removed.
상기 제1클리너단계는 노트가 3 내지 6중량부의 농도로 희석될 수 있다.In the first cleaner step, the note may be diluted to a concentration of 3 to 6 parts by weight.
상기 제2클리너단계는 노트에 포함된 불순물이 원심분리를 통하여 제거될 수 있다.In the second cleaner step, impurities included in the notebook may be removed by centrifugation.
상기 농축단계에서는 노트가 25 내지 35중량부의 농도로 농축될 수 있다.In the concentration step, the notebook may be concentrated to a concentration of 25 to 35 parts by weight.
또한, 상기 노트의 섬유화방법은 분쇄단계와 1차 클리너단계 사이에, 상기 분쇄단계에서 분쇄된 노트가 희석되어 섬유상으로 분리되는 펄퍼 처리단계를 추가로 포함할 수 있다. In addition, the fiberization method of the note may further include a pulper treatment step of dividing the note pulverized in the crushing step is separated into fibrous between the grinding step and the primary cleaner step.
상기 펄퍼 처리단계는 상기 분쇄된 노트가 4.5 내지 6.5중량부의 농도로 희석되는 제1펄퍼처리단계; 및 상기 희석된 노트가 펄퍼에 의해 섬유상으로 분리되는 제2펄퍼처리단계를 포함하여 구성될 수 있다.The pulper treatment step may include a first pulper treatment step in which the ground notebook is diluted to a concentration of 4.5 to 6.5 parts by weight; And a second pulper treatment step in which the diluted notebook is separated into fibers by pulper.
상기 제2펄퍼처리단계에서는 희석된 노트가 1 내지 30분 동안 펄퍼 처리될 수 있다.In the second pulper treatment step, the diluted notes are 1 Pulper treatment for from 30 minutes.
또한, 상기 노트의 섬유화방법은 클리너단계와 농축단계 사이에, 상기 클리너 처리된 노트가 디플레이커를 이용하여 혼합 교반되어 결속된 섬유물질이 분산되는 디플레이커 처리단계를 추가로 포함할 수 있다.In addition, the fiberizing method of the note may further include a deflake processing step of dispersing the bound fiber material by mixing and stirring the cleaner treated note using a deflake between the cleaner step and the concentration step.
상기 디플레이커 처리단계는 바 간격이 2 내지 4mm인 바 타입의 디플레이커를 이용할 수 있다.The deflake processing step may use a bar type deflake having a bar spacing of 2 to 4 mm.
또한, 상기 노트의 섬유화방법은 디플레이커 처리단계와 농축단계 사이에, 상기 디플레이커 처리된 노트를 희석하여 이물질을 제거하는 2차 클리너단계를 추가로 포함할 수 있다.In addition, the fiberization method of the note may further include a secondary cleaner step of removing the foreign matter by diluting the deflake treated note, between the deflake processing step and the concentration step.
상기 2차 클리너단계에서는 상기 디플레이커 처리된 노트가 0.5 내지 2중량부의 농도로 희석될 수 있다.In the secondary cleaner step, the deflaked notebook may be diluted to a concentration of 0.5 to 2 parts by weight.
또한, 상기 노트의 섬유화방법은 1차 클리너단계와 농축단계 사이에, 최종 섬유 제품의 품질을 높이기 위하여 상기 2차 클리너단계를 거친 노트의 이물질이 스크린을 통하여 추가 제거되는 압력 스크리닝단계를 추가로 포함할 수 있다.In addition, the fiberization method of the note further includes a pressure screening step between the first cleaner step and the concentration step, the foreign matter of the note that passed through the second cleaner step is further removed through the screen to improve the quality of the final fiber product. can do.
상기 압력 스크리닝단계에서의 스크린의 직경은 0.2 내지 0.4mm 일 수 있다.The diameter of the screen in the pressure screening step may be 0.2 to 0.4mm.
또한, 상기한 목적을 달성하기 위하여, 본 발명에 따른 노트의 섬유화방법은 펄프를 제조하기 위하여 목재칩을 증해하는 공정에서 미증해된 노트를 수집하는 수집단계; 상기 수집된 노트가 분쇄되는 분쇄단계; 상기 분쇄단계에서 분쇄된 노트가 희석되어 섬유상으로 분리되는 펄퍼 처리단계; 상기 분쇄된 노트의 불순물이 제거되는 1차 클리너단계; 상기 클리너 처리된 노트가 디플레이커를 이용하여 혼합 교반되어 결속된 섬유물질이 분산되는 디플레이커 처리단계; 상기 디플레이커 처리된 노트를 희석하여 이물질을 제거하는 2차 클리너단계; 최종 섬유 제품의 품질을 높이기 위하여 상기 클리너단계를 거친 노트의 이물질이 스크린을 통하여 추가 제거되는 압력 스크리닝단계; 및 상기 클리너단계를 거친 노트가 농축되고 폐액이 분리되는 농축단계를 포함하는 것을 특징으로 한다.In addition, in order to achieve the above object, the fiberizing method of the notes according to the present invention is a collection step of collecting unexplained notes in the process of cooking wood chips to produce pulp; A grinding step of crushing the collected notes; A pulper treatment step of dividing the notes pulverized in the crushing step into fibrous phases; A primary cleaner step of removing impurities of the ground notebook; A deflake processing step of dispersing the bound fiber material by mixing and stirring the cleaner-treated note using a deflake; A secondary cleaner step of diluting the deflaked notebook to remove foreign substances; A pressure screening step in which foreign substances of the notebook which have undergone the cleaner step are further removed through the screen to improve the quality of the final fiber product; And it is characterized in that it comprises a concentration step in which the notebook is subjected to the cleaner step is concentrated and the waste liquid is separated.
또한, 상기한 목적을 달성하기 위하여, 본 발명에 따른 섬유화 노트는 상기한 본 발명에 따른 섬유화 방법으로 섬유화된 것을 특징으로 한다.In addition, in order to achieve the above object, the fiberized notebook according to the present invention is characterized in that the fiberized by the fiberizing method according to the present invention described above.
또한, 상기한 목적을 달성하기 위하여, 본 발명에 따른 종이제품은 상기한 본 발명에 따른 섬유화 노트를 포함하는 것을 특징으로 한다.In addition, in order to achieve the above object, the paper product according to the invention is characterized in that it comprises a fiberized notebook according to the present invention described above.
상기 종이제품은 산업용와이퍼, 핸드타월, 냅킨, 티슈, 산업포장용지, 페이퍼 보드, 상업용 제지, 및 AFH 제품을 포함할 수 있다. The paper products may include industrial wipers, hand towels, napkins, tissues, industrial packaging paper, paper boards, commercial paper, and AFH products.
상기한 바와 같은 본 발명에 따른 노트의 섬유화 방법을 통하여 종래 폐기물로 분류되어 처리 시 과다한 비용이 소모되는 노트(knots)를 섬유화 처리함으로써, 종이 제품의 원료라는 신규한 용도로 활용할 수 있게 되었다. 따라서 펄프 공정에서 노트의 폐기비용을 줄이고, 종래 펄프의 최종 품질을 저하시킬 위험성을 낮출 수 있다.Through the fiberizing method of knots according to the present invention as described above, by treating the knots that are classified as conventional wastes and excessively consumed in processing, the knots can be utilized for a novel use as a raw material of paper products. Therefore, it is possible to reduce the disposal cost of the note in the pulp process, and lower the risk of lowering the final quality of the conventional pulp.
나아가, 별도로 생산할 필요 없이 펄프 제조공정에서 필수적으로 배출되는 노트(knots)를 섬유화하여 종이 제품을 제조함으로써 자원낭비를 줄일 수 있다.Furthermore, it is possible to reduce the waste of resources by producing paper products by fiberizing knots, which are essentially discharged from the pulp manufacturing process, without having to produce them separately.
먼저, 본 명세서에서 쓰이는 단어를 정의한다.First, the words used in the present specification are defined.
'펄프 제조 공정'이란 나무를 원료로 하여 목재칩을 제조하는 공정, 증해하는 공정(cooking), 세척공정(washing), 1차 정선공정(screening), 표백공정(bleaching), 2차 정선공정(screening), 건조공정(drying), 마감공정(finishing)을 포함하여 이루어지는 공정으로, 섬유나 종이 등의 원료가 되는 펄프를 제조하는 공정을 말한다.The 'pulp manufacturing process' refers to the process of manufacturing wood chips from wood, cooking, washing, first screening, bleaching, and second screening ( It is a process including screening), drying process and finishing process, and refers to a process for producing pulp, which is a raw material such as fiber or paper.
'증해'란 목재칩에 화학약품을 처리한 후 고온 또는/및 고압으로 처리하여 삶는 공정으로, 섬유질과 섬유질을 결속시키는 리그닌을 약화시키는 공정이다. 삶는 과정에서 식물 원료 속에 들어 있는 비섬유소 물질이 녹아 나오고, 섬유가 비교적 순수한 상태로 분리된다.'Steaming' is a process that treats wood chips with chemicals and then boils them at high temperatures and / or high pressures to weaken lignin, which binds fibers to fibers. In the process of boiling, non-fibrous substances in plant raw materials are melted, and the fibers are separated in a relatively pure state.
'노트(knots)'란 펄프 제조 공정 중 증해 공정 후단에서 펄프화되지 않고 스크린에 걸러진 미증해 칩, 나무옹이, 해리되지 않은 섬유 다발인 샤이브(shive), 및 펄프 증해 공정에서 리젝트 처리된 기타 불순물을 의미한다.Knots are unpulled pulped at the end of the cooking process during the pulp manufacturing process, unfiltered chips screened, wood knots, shived bundles of undissociated fibers, and rejected in the pulp cooking process. It means other impurities.
'펄퍼'란 건조 펄프, 헌종이, 파손지 등을 펄프 분산액에 용해하기 위한 장치를 의미한다. "Pulper" means a device for dissolving dry pulp, old paper, damaged paper, and the like into the pulp dispersion.
'해리'란 펄프 제조 공정에서 필수적인 공정으로, 펄프원료를 섬유상으로 분리하는 것을 말한다."Dissociation" is an essential step in the pulp manufacturing process, and means to separate the pulp material into fibrous form.
'결속 섬유'란 종이 원료가 되는 펄프섬유 중에 있는 아직 덜 풀린 섬유의 뭉치를 의미한다.'Bonding fiber' refers to a bundle of yet less loose fibers in the pulp fibers that are the paper stock.
'불순물' 또는 '이물질'이란 노트(knots)에서 섬유물질을 제외한 물질로, 흑액, 폐액, 해리되지 않은 물질, 돌가루, 고무, 기타 약품성분 등을 의미한다.'Impurities' or 'foreign materials' refers to materials other than fibres in knots, and refers to black liquor, waste liquid, undissociated materials, stone powder, rubber, and other chemical components.
'지편'이란 종이의 작은 조각을 의미한다.'Paper' means a small piece of paper.
'흑액'이란 펄프 제조 시 원목재를 증해할 때 생성되는 흑갈색의 폐액을 의미한다.'Black liquor' refers to blackish brown waste which is produced when cooking wood is pulp.
'디플레이커'란 원료섬유를 고속으로 혼합하여 교반하는 것으로, 원료섬유를 분섬하여 해리시키는 장치이다.A "deflake" is a device that dissolves and dissociates raw fibers by mixing the raw fibers at high speed and stirring them.
'종이 제품'이란 산업용와이퍼, 핸드타월, 냅킨, 티슈, 산업포장용지, 페이퍼 보드, 가정용이 아닌 산업용 또는 다수의 사람들이 사용하는 공간에서 사용되는 AFH(Away From Home) 제품 등을 포함한다.'Paper products' include industrial wipers, hand towels, napkins, tissues, industrial packaging, paper boards, and AFH (Away From Home) products used in industrial or non-home use or in spaces used by many people.
본 발명에 따른 노트(knots)의 섬유화방법은 펄프를 제조하기 위하여 목재칩을 증해하는 공정에서 미증해된 노트를 수집하는 수집단계; 상기 수집된 노트가 분쇄되는 분쇄단계; 상기 분쇄된 노트의 불순물이 제거되는 1차 클리너단계; 및 상기 클리너단계를 거친 노트가 농축되고 폐액이 분리되는 농축단계를 포함하는 것을 특징으로 한다. The fiberizing method of knots according to the present invention includes a collection step of collecting unexplained notes in the process of cooking wood chips to produce pulp; A grinding step of crushing the collected notes; A primary cleaner step of removing impurities of the ground notebook; And it is characterized in that it comprises a concentration step in which the notebook is subjected to the cleaner step is concentrated and the waste liquid is separated.
일 실시예에 따르면, 본 발명에 따른 노트의 섬유화방법은 분쇄단계와 1차 클리너단계 사이에, 상기 분쇄단계에서 분쇄된 노트가 희석되어 섬유상으로 분리되는 펄퍼 처리단계를 추가로 포함할 수 있다.According to an embodiment, the fiberization method of the knot according to the present invention may further include a pulper treatment step in which the knots pulverized in the crushing step are separated into fibrous phases between the crushing step and the first cleaner step.
또한, 일 실시예에 따르면, 본 발명에 따른 노트의 섬유화방법은 1차 클리너단계와 농축단계 사이에, 상기 1차 클리너 처리된 노트가 디플레이커를 이용하여 혼합 교반되어 결속된 섬유물질이 분산되는 디플레이커 처리단계를 추가로 포함할 수 있다.In addition, according to one embodiment, the fiberizing method of the notebook according to the present invention is a mixture between the primary cleaner step and the concentration step, the primary cleaner-treated knot is mixed and stirred using a de-flake to disperse the bound fiber material The deflake processing step may be further included.
또한, 일 실시예에 따르면, 본 발명에 따른 노트의 섬유화방법은 디플레이커 처리단계와 농축단계 사이에, 상기 디플레이커 처리된 노트를 희석하여 이물질을 제거하는 2차 클리너단계를 추가로 포함할 수 있다.In addition, according to one embodiment, the fiberizing method of the notebook according to the present invention may further include a secondary cleaner step of removing the foreign matter by diluting the deflaked notebook between the deflake processing step and the concentration step. have.
또한, 다른 일 실시예에 따르면, 본 발명에 따른 노트의 섬유화방법은 1차 클리너단계와 농축단계 사이에, 최종 섬유 제품의 품질을 높이기 위하여 상기 클리너단계를 거친 노트의 이물질이 스크린을 통하여 추가 제거되는 압력 스크리닝단계를 추가로 포함 할 수 있다.In addition, according to another embodiment, the fiberizing method of the notebook according to the present invention, between the first cleaner step and the concentration step, to remove the foreign matter of the note that passed through the cleaner step through the screen to increase the quality of the final fiber product. The pressure screening step may be further included.
또한, 또 다른 일 실시예에 따르면, 본 발명에 따른 노트의 섬유화방법은 펄프를 제조하기 위하여 목재칩을 증해하는 공정에서 미증해된 노트를 수집하는 수집단계; 상기 수집된 노트가 분쇄되는 분쇄단계; 상기 분쇄단계에서 분쇄된 노트가 희석되어 섬유상으로 분리되는 펄퍼 처리단계; 상기 분쇄된 노트의 불순물이 제거되는 1차 클리너단계; 상기 클리너 처리된 노트가 디플레이커를 이용하여 혼합 교반되어 결속된 섬유물질이 분산되는 디플레이커 처리단계; 상기 디플레이커 처리된 노트를 희석하여 이물질을 제거하는 2차 클리너단계; 최종 섬유 제품의 품질을 높이기 위하여 상기 클리너단계를 거친 노트의 이물질이 스크린을 통하여 추가 제거되는 압력 스크리닝단계; 및 상기 클리너단계를 거친 노트가 농축되고 폐액이 분리되는 농축단계를 포함하는 것을 특징으로 한다.In addition, according to another embodiment, the fiberizing method of the notes according to the present invention is a collection step of collecting unexplained notes in the process of cooking wood chips to produce pulp; A grinding step of crushing the collected notes; A pulper treatment step of dividing the notes pulverized in the crushing step into fibrous phases; A primary cleaner step of removing impurities of the ground notebook; A deflake processing step of dispersing the bound fiber material by mixing and stirring the cleaner-treated note using a deflake; A secondary cleaner step of diluting the deflaked notebook to remove foreign substances; A pressure screening step in which foreign substances of the notebook which have undergone the cleaner step are further removed through the screen to improve the quality of the final fiber product; And it is characterized in that it comprises a concentration step in which the notebook is subjected to the cleaner step is concentrated and the waste liquid is separated.
이하 각 단계를 순서대로 설명하기로 한다.Each step will be described below in order.
1. 수집단계1. Collection stage
먼저, 수집단계는 목재칩을 증해하는 공정(Cooking)에서 미증해되어 스크린에 걸러진 노트(knots)를 분리하여 수집하는 제1수집단계; 및 상기 수집된 노트가 탈수되어 흑액이 제거되는 제2수집단계를 포함하여 구성될 수 있다.First, the collecting step includes a first collecting step of separating and collecting knots that have been filtered out on the screen by cooking the wood chips; And a second collecting step in which the collected notes are dehydrated to remove the black liquor.
제1수집단계에서 수집된 노트(knots)는 펄프 증해 공정에 사용된 약품의 폐액과 함께 수집되기 때문에 수분 함량이 높으나, 수분함량이 70중량부 이상으로 높은 노트(knots)는 기계적 처리 효율이 떨어진다. 따라서 수분 함량을 낮추면서 폐액을 노트(knots)와 분리하기 위하여 탈수 작업하여 수분 함량을 50중량부 이하로 낮춘다. 수분함량이 1 내지 50중량부가 되는 것이 바람직하다. 탈수 작업 시 원심 탈수기, 스크린 등을 사용할 수 있으나 이에 제한되는 것은 아니다. 탈수 폐액은 수처리 시설로 이송된다.  The knots collected in the first collection step are collected together with the waste liquid of the chemical used in the pulp cooking process, so that the moisture content is high, but the knots having a moisture content of 70 parts by weight or more are inferior in mechanical treatment efficiency. . Therefore, dehydration work to separate the waste fluid from knots while lowering the water content to lower the water content to 50 parts by weight or less. It is preferable that moisture content is 1-50 weight part. Centrifugal dehydrator, screen, etc. may be used in the dehydration operation, but is not limited thereto. Dewatering wastewater is sent to a water treatment plant.
2. 분쇄단계2. Crushing Step
상기 수집단계에서 처리된 노트는 분쇄기를 통하여 분쇄되며, 분쇄단계를 통하여 노트(knots)의 수분이 30 내지 40중량부로 건조된다. 상기 분쇄기는 종래 펄프제조 공정에 이용되는 나무칩 분쇄(그라인딩)기기, 플라스틱을 분쇄하는 기기, 톱밥을 제조하는 기기, 믹서타입의 기기 등 제한 없이 이용될 수 있다. 다만, 종래 기계펄프 공정의 그라인딩 공정을 이용할 경우 1000kw 이상의 전력이 소모되어 경제성이 낮다.The notes processed in the collecting step are pulverized through a pulverizer, and the moisture of knots is dried to 30 to 40 parts by weight through the pulverizing step. The pulverizer may be used without limitation, such as wood chip grinding (grinding) machine, a machine for crushing plastic, a machine for producing sawdust, a mixer-type machine, etc. used in the conventional pulp manufacturing process. However, when the grinding process of the conventional mechanical pulp process is used, power consumption of 1000 kW or more is low and economic efficiency is low.
상기 분쇄단계는 노트의 탄화를 방지하기 위하여 분쇄기에 설치된 스크린의 크기의 대소에 따라 제1분쇄단계 및 제2분쇄단계의 두 개의 단계로 나뉘어 분쇄될 수 있다. 상기 스크린은 분쇄기 하단에 설치될 수 있으며, 분쇄 과정을 거친 노트(knots)를 여과하기 위한 장치이다.The grinding step may be divided into two steps, the first grinding step and the second grinding step, depending on the size of the screen installed in the grinder to prevent carbonization of the note. The screen may be installed at the bottom of the mill, and is a device for filtering knots that have been milled.
수집단계를 거친 노트에서 흑액은 제거되었으나 수분을 포함하고 있으므로, 수분을 포함하는 노트가 분쇄과정 중 스크린 및 분쇄기 내벽에 붙어 스크린을 막을 가능성이 높다. 스크린을 통해 배출되지 못한 노트는 탄화될 수 있으며, 탄화될 경우 노트 섬유가 변형되어 이후 산업용 제지 등으로 활용이 불가능할 수 있다. 따라서 이러한 탄화를 방지하기 위하여 제1분쇄단계에서는 보다 큰 크기의 스크린을 사용하여 1차로 분쇄하고, 이후 제2분쇄단계에서 보다 작은 크기의 스크린을 사용하여 분쇄하는 것이 바람직하다.Since the black liquor was removed from the collected notebook but contained water, there is a high possibility that the notebook containing the water stuck to the screen and the inner wall of the grinder during the grinding process to block the screen. Note that can not be discharged through the screen can be carbonized, if the carbonized note fiber may not be available for industrial paper and the like. Therefore, in order to prevent such carbonization, it is preferable to grind first using a screen of a larger size in the first grinding step, and then to grind using a screen of a smaller size in the second grinding step.
이를 위하여, 상기 제1분쇄단계에 사용되는 스크린의 직경은 11 내지 17mm일 수 있으며, 바람직하게는 12 내지 15mm(¢, 파이), 더욱 바람직하게는 직경 12mm의 스크린을 사용할 수 있다. 12mm보다 직경이 작을 경우 수분을 포함한 노트가 통과할 수 없어 막힘 현상이 발생하며 12mm 이상일 경우 원활하게 통과된다. 다만, 대부분의 노트는 스크린의 직경이 15mm 이상일 경우 분쇄되지 않고 통과되므로, 스크린의 직경이 12 내지 15mm인 것을 이용하는 것이 바람직하다.To this end, the diameter of the screen used in the first grinding step may be 11 to 17mm, preferably 12 to 15mm (¢, pie), more preferably 12mm in diameter can be used. If the diameter is smaller than 12mm, clogging occurs because the note containing water cannot pass. If the diameter is over 12mm, it passes smoothly. However, since most of the notebooks pass through without grinding when the diameter of the screen is 15 mm or more, it is preferable to use the diameter of the screen of 12 to 15 mm.
상기 제2분쇄단계에서는 제1분쇄단계보다 스크린의 직경을 작게 하여 8 내지 11mm가 되도록 하며, 바람직하게는 9 내지 10.5mm, 더욱 바람직하게는 직경 10mm의 스크린을 사용할 수 있다. 9mm보다 직경이 작을 경우 노트가 통과할 수 없어 막힘 현상이 발생하며 10.5mm 이상일 경우 제2분쇄단계를 거치지 않고도 통과되므로, 스크린의 직경은 9 내지 10.5mm, 더욱 바람직하게는 직경 10mm인 것을 이용하는 것이 바람직하다. In the second grinding step, the diameter of the screen is smaller than that of the first grinding step so as to be 8 to 11 mm, preferably 9 to 10.5 mm, more preferably 10 mm in diameter. If the diameter is smaller than 9mm, the notebook cannot pass through and blockage occurs. If the diameter is 10.5mm or more, it passes without the second grinding step. Therefore, the diameter of the screen is 9 to 10.5mm, more preferably, 10mm in diameter. desirable.
상기 분쇄단계는 탈수 처리된 노트를 믹서타입의 기기로 분쇄할 수 있다. In the crushing step, the dehydrated notebook may be crushed by a mixer-type device.
본 발명의 일 실시예에 따르면, 상기 분쇄단계는 스크린을 거치치 않고 노트를 믹서로 분쇄하는 1개의 단계로 구성될 수 있다. 믹서로는 믹서타입의 기기인 수퍼믹서를 사용할 수 있다.According to one embodiment of the invention, the grinding step may be composed of one step of grinding the note with a mixer without passing through the screen. As a mixer, a super mixer which is a mixer type device can be used.
3. 펄퍼 처리단계3. Pulper Treatment Step
상기 펄퍼 처리단계는 상기 분쇄처리된 노트를 펄퍼(pulper)로 희석하여 해리시킨다. 해리란 펄프 제조 공정에서 필수적인 공정으로, 펄프원료를 섬유상으로 분리하는 것을 말한다. 펄퍼란 건조 펄프, 헌종이, 파손지 등을 펄프 분산액에 용해하기 위한 장치를 말한다. 펄퍼는 일반 제지 업체에서 상용화되어 있는 인텐사 펄퍼(Intensa Pulper)를 이용할 수 있다. In the pulper treatment step, the pulverized note is diluted with a pulper to dissociate. Dissociation is an essential step in the pulp manufacturing process, and means to separate the pulp material into fibrous form. Pulper refers to an apparatus for dissolving dry pulp, old paper, damaged paper, and the like into a pulp dispersion. Pulper may use Intensa Pulper, which is commercially available from general paper companies.
상기 펄퍼 처리단계는 상기 분쇄된 노트가 4.5 내지 6.5중량부의 농도로 희석되는 제1펄퍼처리단계; 및 상기 희석된 노트가 펄퍼에 의해 섬유상으로 분리되는 제2펄퍼처리단계를 포함하여 구성될 수 있다.The pulper treatment step may include a first pulper treatment step in which the ground notebook is diluted to a concentration of 4.5 to 6.5 parts by weight; And a second pulper treatment step in which the diluted notebook is separated into fibers by pulper.
펄퍼처리단계에서 인텐사 펄퍼는 회전체 및 3 내지 6.5 파이의 원형 스크린 설비를 구비하여 노트(knots)를 분쇄하면서 스크린의 크기보다 작게 해리할 수 있다. 노트는 인텐사 펄퍼에서 4.5 내지 6.5중량부, 바람직하게는 5 내지 6중량부의 농도로 희석되며, 5 내지 6중량부의 농도가 처리 효율이 가장 높다. 인텐사 펄퍼에서 노트는 1 내지 30분간 처리되는 것이 바람직하며, 30분 이상에서는 처리 시간에 따른 노트의 처리 효율에 큰 차이가 없다.In the pulper treatment step, the intensa pulper may be dissociated smaller than the size of the screen while crushing knots with a rotating screen and a circular screen facility of 3 to 6.5 pies. The note is diluted to a concentration of 4.5 to 6.5 parts by weight, preferably 5 to 6 parts by weight, in an intensa pulper, with a concentration of 5 to 6 parts by weight being the most effective. It is preferable that the notes are processed for 1 to 30 minutes in the intensa pulper, and there is no significant difference in the processing efficiency of the notes according to the processing time at 30 minutes or more.
4. 1차 클리너단계4. Primary Cleaner Step
상기 1차 클리너단계는 펄퍼 처리된 노트에서 미해리된 물질 또는 돌가루, 고무 등 제품 제조 공정에 들어갈 시 기기 파손의 위험이 있는 기타 불순물을 고농도 클리너에서 원심분리를 이용하여 제거하는 공정이다. 상기 1차 클리너단계는 분쇄된 노트가 희석되는 제1클리너단계; 및 상기 희석된 노트에 포함된 불순물이 제거되는 제2클리너단계를 포함하여 구성될 수 있다.The primary cleaner step is a pulper treatment This process removes undissociated substances from the note or other impurities that may damage the equipment when entering the product manufacturing process, such as stone powder and rubber, by centrifugation in a high concentration cleaner. The primary cleaner step may include a first cleaner step in which the crushed notebook is diluted; And a second cleaner step in which impurities contained in the diluted notebook are removed.
상기 제1클리너단계는 노트를 3 내지 6중량부의 농도로 희석할 수 있다. 희석 시에는 고농도 클리너를 사용할 수 있고, 고농도 클리너는 예를 들어 제지업계에서 일반적으로 고농도 클리너로 사용하고 있는 기기를 사용할 수 있다.The first cleaner step may dilute the notebook to a concentration of 3 to 6 parts by weight. When diluting, a high concentration cleaner may be used, and the high concentration cleaner may use, for example, an apparatus generally used in the paper industry as a high concentration cleaner.
상기 제2클리너단계에서는 노트에 포함된 불순물이 원심분리를 통하여 제거될 수 있다. 불순물 중 미해리된 노트는 회수된 후 인텐사 펄퍼로 이송되어 다시 펄퍼 처리될 수 있다. In the second cleaner step, impurities included in the notebook may be removed by centrifugation. The undissociated knots in the impurities may be recovered and then transferred to the intensa pulper to be pulped again.
5. 디플레이커 처리단계5. Deflake Processing Step
상기 디플레이커 처리단계는 상기 1차 클리너 처리된 노트를 디플레이커(deflaker)에 투입하여 고속으로 혼합 교반하며 섬유물질을 분산하고 용해되지 않은 지편을 해리하는 공정이다. 디플레이커(deflaker)는 내부에 날 형상의 회전체를 구비하며, 노트를 고속으로 회전하는 회전체에 통과시켜 통과하는 섬유물질을 분리하여 해리시킨다. 바(bar) 타입의 디플레이커를 사용할 경우, 바 간격이 2 내지 4mm 일 경우 해리 효과가 뛰어나며, 3.0mm일 때 가장 바람직하다. The deflake processing step is a step of adding the primary cleaner-treated notes to a deflaker, mixing and stirring at high speed, dispersing fiber material and dissociating undissolved paper chips. The deflaker has a blade-shaped rotating body therein and separates and dissociates the fiber material passing through the rotating body at high speed. In the case of using a bar type deflake, the dissociation effect is excellent when the bar spacing is 2 to 4 mm, and is most preferable at 3.0 mm.
6. 2차 클리너단계6. Secondary cleaner step
2차 클리너단계는 상기 디플레이커 처리 후에도 남아있는 결속 섬유를 제거하기 위하여 노트를 희석하고 원심분리를 통하여 이물질을 제거할 수 있다. 1차클리너단계에 비해 농도를 낮춰 처리한다. 이는 제1클리너 단계에서 이미 큰 이물질이 제거되었기 때문이다. 결속섬유는 제품 품질을 저하시키거나, 종이 제조 시 지절의 원인으로 작용할 수 있으므로 반드시 제거가 필요하다.The secondary cleaner step may dilute the notes and remove the foreign matter by centrifugation in order to remove the binding fibers remaining after the deflake processing. Lower the concentration compared to the primary cleaner stage. This is because large foreign substances have already been removed in the first cleaner stage. Binding fibers must be removed because they can degrade product quality or cause paper jams in paper manufacturing.
2차 클리너단계에서 클리너는 제지업계에서 일반적으로 사용하고 있는 저농도클리너를 사용할 수 있다.In the secondary cleaner stage, the cleaner may use a low concentration cleaner commonly used in the paper industry.
상기 노트는 저농도 클리너에서 0.5 내지 2중량부의 농도로 희석될 수 있으며, 바람직하게는 0.5 내지 1 중량부의 농도로 희석될 수 있다The note may be diluted to a concentration of 0.5 to 2 parts by weight in a low concentration cleaner, preferably to a concentration of 0.5 to 1 parts by weight.
7. 압력 스크리닝단계7. Pressure Screening Step
압력 스크리닝단계에서는 상기 클리너 처리된 노트에서 최종 섬유 제품의 품질을 높이기 위하여, 스크린을 통해 이물질을 추가 제거할 수 있다. 압력 스크리닝단계에서 압력스크린은 제지업계에서 일반적으로 사용하고 있는 압력스크린을 사용할 수 있다. 상기 스크린의 직경은 0.2 내지 0.4mm인 것이 바람직하며, 더욱 바람직하게는 0.3mm인 스크린을 사용할 수 있다. 0.4mm 이상의 스크린에서는 이물질이 스크린을 통과할 수 있고, 0.2mm 미만의 스크린을 사용할 경우, 제품 품질 개선 효과 대비 수율이 85%미만으로 현저하게 저하될 수 있다. In the pressure screening step, foreign matter may be further removed through the screen to improve the quality of the final fiber product in the cleaner treated notebook. In the pressure screening step, the pressure screen may use a pressure screen generally used in the paper industry. The diameter of the screen is preferably 0.2 to 0.4mm, more preferably a screen of 0.3mm can be used. Foreign materials may pass through the screen in the screen of 0.4 mm or more, and when the screen of less than 0.2 mm is used, the yield may be significantly reduced to less than 85% compared to the product quality improvement effect.
8. 농축단계(Thickner)8. Thickener
농축단계에서는 클리너단계 또는 압력 스크리닝단계를 거치면서 섬유화된 노트를 농축시킬 수 있다. 동시에 노트에 포함된 폐액을 분리할 수 있다. 농축단계 에서 사용하는 농축기기는 예를 들어 Voith사의 스크류프레스와 같이 제지업계에서 일반적으로 사용하는 스크류 타입의 농축기기를 사용할 수 있다. 상기 농축단계에서 노트는 25 내지 35중량부의 농도로 농축될 수 있으며, 바람직하게는 30중량부로 농축될 수 있다. 농축단계를 거쳐 최종적으로 섬유화된 노트(knots)가 얻어질 수 있다. In the concentration step, the fiberized notes can be concentrated while undergoing a cleaner step or a pressure screening step. At the same time, the waste liquid contained in the notebook can be separated. The thickener used in the thickening step may be a screw type thickener commonly used in the paper industry, for example, a screw press from Voith. In the concentration step, the notebook may be concentrated to a concentration of 25 to 35 parts by weight, preferably 30 parts by weight. Through the concentration step, finally fibrized knots can be obtained.
상기 단계를 포함하는 섬유화 방법에 의해 섬유화된 노트(knots)는 종이 제품 제조에 사용될 수 있다. 상기 종이제품은 산업용와이퍼, 핸드타월, 냅킨, 티슈, 산업포장용지, 페이퍼 보드, 상업용 제지, 및 AFH 제품을 포함할 수 있다. AFH 제품이란 가정용을 제외한 제품으로, 공중이 이용하는 장소에 구비된 화장지, 와이퍼, 냅킨, 핸드타월 등의 제품으로, 산업용으로 기계 또는 기계부품을 닦기 위한 수단으로 사용되는 와이퍼 등을 포함한다.Knots fiberized by the fiberization method comprising the above steps can be used for the manufacture of paper products. The paper products may include industrial wipers, hand towels, napkins, tissues, industrial packaging paper, paper boards, commercial paper, and AFH products. AFH products are products excluding home use, and are products such as toilet paper, wipers, napkins, hand towels, etc., which are provided in public places, and include wipers used as a means for wiping machines or machine parts for industrial purposes.
<실시예 1> 노트의 섬유화 방법 1(수집, 분쇄, 농축단계)Example 1 Fibrosis Method 1 of the Note (Gathering, Grinding, and Concentration)
펄프 제조를 위하여 목재칩을 증해하는 공정에서 스크린 상으로 분리되는 노트(knots)를 분리하고, 원심탈수기를 이용하여 수분함량을 50중량부로 낮춘다.In the process of cooking wood chips for pulp, knots separated on the screen are separated and the water content is reduced to 50 parts by weight using a centrifugal dehydrator.
탈수된 노트는 톱밥제조기를 이용하여 분쇄한 후 직경 12mm의 스크린을 통과시킨다. The dehydrated notebook is crushed using a sawdust maker and passed through a 12 mm diameter screen.
노트를 고농도클리너(Voith社)에 투입하여 4.5중량부의 농도로 희석하고 돌가루, 고무, 결속 섬유를 제거한다.The notebook is placed in a high-density cleaner (Voith), diluted to 4.5 parts by weight, and stone dust, rubber and binding fibers are removed.
상기 노트를 스크류프레스(Voith社)를 이용하여 30중량부의 농도로 농축시킨다. 폐액은 농축기기의 스크린을 통하여 분리하여, 섬유화 노트를 얻는다.The note is concentrated to a concentration of 30 parts by weight using a screw press (Voith). The waste liquor is separated through the screen of the concentrator to obtain fibrosis notes.
<실시예 2> 노트의 섬유화 방법 2Example 2 Fibrous Method of Notebook 2
펄프 제조를 위하여 목재칩을 증해하는 공정에서 스크린 상으로 분리되는 노트(knots)를 분리하고, 원심탈수기를 이용하여 수분함량을 50중량부로 낮춘다.In the process of cooking wood chips for pulp, knots separated on the screen are separated and the water content is reduced to 50 parts by weight using a centrifugal dehydrator.
탈수된 노트는 톱밥제조기를 이용하여 분쇄한 후 직경 12mm의 스크린을 통과시킨다. 이후 다시 분쇄하여 직경 10mm의 스크린을 통과시킨다.The dehydrated notebook is crushed using a sawdust maker and passed through a 12 mm diameter screen. It is then crushed again and passed through a 10 mm diameter screen.
분쇄된 노트에 정제수를 가하여 5.5중량부로 희석하고, 직경 5mm의 원형스크린을 구비한 인텐사 펄퍼(Intensa pulper)에 투입한 후 20분 처리하여 해리시킨다.Purified water was added to the pulverized notebook, diluted to 5.5 parts by weight, and placed in an Intensa pulper having a circular screen having a diameter of 5 mm, followed by dissociation for 20 minutes.
해리된 노트를 고농도클리너(Voith社)에 투입하여 4.5중량부의 농도로 희석하고 돌가루, 고무, 결속 섬유 등을 제거한다.The dissociated notes are added to a high concentration cleaner (Voith), diluted to 4.5 parts by weight, and stone powder, rubber and binding fibers are removed.
다음으로, 노트를 바 간격이 3mm인 디플레이커(deflaker)에 투입하여 결속 섬유를 분산시키고 녹지 않았던 지편(작은 종이 조각)을 해리시킨다.Next, the notebook is placed in a deflaker with a bar spacing of 3 mm to disperse the binding fibers and dissociate the undissolved pieces (small pieces of paper).
디플레이커로 분산된 노트를 저농도클리너(Voith社)에 투입하여 1.2중량부로 희석하고 남아 있는 결속 섬유를 제거한다.The notebook dispersed in a deflake is added to a low concentration cleaner (Voith), diluted to 1.2 parts by weight, and the remaining binding fibers are removed.
스크린 크기를 0.3mm로 한 압력스크린(Voith社)를 이용하여 압력을 이용하여 마지막으로 결속 섬유 및 이물질을 제거한다.Using a pressure screen (Voith, Inc.) with a screen size of 0.3 mm, the binding fibers and foreign substances are finally removed using pressure.
압력스크린 기기에서 처리된 노트를 스크류프레스(Voith社)를 이용하여 304 량부의 농도가 되도록 농축시킨다. 폐액은 농축기기의 스크린을 통하여 분리하여 섬유화 노트를 얻는다.The notes processed in the pressure screen instrument are concentrated to a concentration of 304 parts by means of a screw press (Voith). The waste liquor is separated through the screen of the concentrator to obtain fibrosis notes.
<실시예 3> 섬유화 노트를 포함하는 상업용 제지 제품의 제조방법Example 3 Manufacturing Method of Commercial Paper Making Products Comprising Fiberized Notebooks
실시예 1에 따른 섬유화 노트를 4중량부 농도로 희석한 후, DDR(Rouble Disk Refiner)에 투입하여 고해 처리 하였다.After diluting the fiberized notebook according to Example 1 to 4 parts by weight, it was added to DDR (Rouble Disk Refiner) and subjected to beating treatment.
특성 보완을 위하여 고해 처리된 섬유화노트 70중량부에 천연펄프 30중량부를 혼합하였다.To compensate for the characteristics, 30 parts by weight of natural pulp was mixed with 70 parts by weight of a fiberized note.
혼합한 천연펄프 및 섬유화노트 혼합물을 저농도클리너(Voith社)에 투입하여 1.2중량부로 희석하고 이물질을 제거하였다. The mixed natural pulp and fiberized note mixture was added to a low concentration cleaner (Voith, Inc.), diluted to 1.2 parts by weight, and foreign substances were removed.
저농도클리너를 거친 혼합물을 압력스크린(Voith社)에 투입하여 압력을 이용하여 한번 더 이물질을 제거하였다.The mixture passed through the low concentration cleaner was put in a pressure screen (Voith, Inc.) to remove foreign matter once more using pressure.
상업용 제지 생산 머신에 상기 혼합물을 투입하고, 머신의 헤드박스(Head box)를 통해 농도 0.9중량부의 섬유를 사출시킨다. 사출된 섬유는 와이어 상에 지필을 형성하였다(포밍(Forming)단계).The mixture is introduced into a commercial papermaking machine and 0.9 parts by weight of fibers are injected through a head box of the machine. The injected fiber forms a paper-based sheet on the wire (forming step).
와이어 상에 형성된 지필은 프레스 단계를 거치면서 수분함량이 40중량부가 된다.The paper-based paper formed on the wire has a water content of 40 parts by weight during the pressing step.
제지 생산 머신의 드라이어(Yankee Dryer)를 통과하며 수분함량이 4~7중량부가 되도록 건조하여 상업용 제지 제품을 제조하였다. Commercial paper products were manufactured by passing through a dryer (Yankee Dryer) of the paper production machine to dry the moisture content of 4-7 parts by weight.
<실시예 4> 섬유화 노트를 포함하는 상업용 제지 제품의 제조방법Example 4 Manufacturing Method of Commercial Paper Making Products Comprising Fibrous Notebooks
실시예 2에 따른 섬유화 노트를 4중량부 농도로 희석한 후, DDR(Rouble Disk Refiner)에 투입하여 고해 처리 하였다.After diluting the fiberized notebook according to Example 2 to 4 parts by weight, it was added to DDR (Rouble Disk Refiner) and subjected to beating treatment.
특성 보완을 위하여 고해 처리된 섬유화노트 70중량부에 천연펄프 30중량부를 혼합하였다.To compensate for the characteristics, 30 parts by weight of natural pulp was mixed with 70 parts by weight of a fiberized note.
혼합한 천연펄프 및 섬유화노트 혼합물을 저농도클리너(Voith社)에 투입하여 1.2중량부로 희석하고 이물질을 제거하였다. The mixed natural pulp and fiberized note mixture was added to a low concentration cleaner (Voith, Inc.), diluted to 1.2 parts by weight, and foreign substances were removed.
저농도클리너를 거친 혼합물을 압력스크린(Voith社)에 투입하여 압력을 이용하여 한번 더 이물질을 제거하였다.The mixture passed through the low concentration cleaner was put in a pressure screen (Voith, Inc.) to remove foreign matter once more using pressure.
상업용 제지 생산 머신에 상기 혼합물을 투입하고, 머신의 헤드박스(Head box)를 통해 농도 0.9중량부의 섬유를 사출시킨다. 사출된 섬유는 와이어 상에 지필을 형성하였다(포밍(Forming)단계).The mixture is introduced into a commercial papermaking machine and 0.9 parts by weight of fibers are injected through a head box of the machine. The injected fiber forms a paper-based sheet on the wire (forming step).
와이어 상에 형성된 지필은 프레스 단계를 거치면서 수분함량이 40중량부가 된다.The paper-based paper formed on the wire has a water content of 40 parts by weight during the pressing step.
제지 생산 머신의 드라이어(Yankee Dryer)를 통과하며 수분함량이 5중량부가 되도록 건조하여 상업용 제지 제품을 제조하였다. Commercial paper products were manufactured by passing through a dryer (Yankee Dryer) of the paper production machine and dried to 5 parts by weight of water.
<실시예 5> 섬유화 노트를 포함하는 산업용 와이퍼의 제조방법Example 5 A manufacturing method of an industrial wiper including a fiberized notebook
실시예 2에 따른 섬유화 노트를 4중량부 농도로 희석한 후, DDR(Double Disk Refiner)에 투입하여 고해처리하였다.The fiberized notebook according to Example 2 was diluted to 4 parts by weight, and then subjected to beating treatment by adding to a Double Disk Refiner (DDR).
특성 보완을 위하여 고해처리된 섬유화노트 70중량부에 천연펄프 30중량부를 혼합하였다.In order to supplement the characteristics, 30 parts by weight of natural pulp was mixed with 70 parts by weight of beaten fiberized notes.
혼합한 천연펄프 및 섬유화노트 혼합물을 저농도클리너(Voith社)에 투입하여 1.2중량부로 희석하고 이물질을 제거하였다.The mixed natural pulp and fiberized note mixture was added to a low concentration cleaner (Voith, Inc.), diluted to 1.2 parts by weight, and foreign substances were removed.
저농도클리너를 거친 혼합물을 압력스크린(Voith社)에 투입하여 압력을 이용하여 한번 더 이물질을 제거하였다.The mixture passed through the low concentration cleaner was put in a pressure screen (Voith, Inc.) to remove foreign matter once more using pressure.
티슈머신에 상기 혼합물을 투입하고, 머신의 헤드박스(Head box)를 통해 농도 0.9중량부의 섬유를 사출시킨다. 사출된 섬유는 와이어 상에 지필을 형성하였다(포밍(Forming)단계).The mixture is introduced into a tissue machine and a 0.9 weight part fiber is injected through a head box of the machine. The injected fiber forms a paper-based sheet on the wire (forming step).
와이어 상에 형성된 지필은 프레스 단계를 거치면서 수분함량이 40중량부가 된다.The paper-based paper formed on the wire has a water content of 40 parts by weight during the pressing step.
티슈머신의 양키 드라이어(Yankee Dryer)를 통과하며 수분함량이 7중량부가 된다. 마지막으로 클랩핑 처리하여 종이에 주름을 형성한 후, 플라이 머신에 투입하여 산업용 와이퍼를 제조하였다.It passes through the Yankee Dryer of the tissue machine and has a water content of 7 parts by weight. Finally, after forming the wrinkles on the paper by the clapping treatment, it was put into a fly machine to prepare an industrial wiper.
상기한 바와 같이 본 발명에 따른 섬유화 노트의 제조방법을 통하여 노트(knots)를 섬유화 처리하고, 섬유화된 노트를 이용하여 종이 제품을 제조함으로써, 펄프 공정에서 노트의 폐기비용을 줄이고, 종래 펄프로 재활용할 경우에 펄프의 최종 품질을 저하시킬 위험성을 낮출 수 있다.As described above, the knots are fiberized through the manufacturing method of the fiberized notes according to the present invention, and paper products are manufactured using the fiberized notes, thereby reducing the disposal cost of the notes in the pulp process and recycling them with conventional pulp. This can reduce the risk of degrading the final quality of the pulp.

Claims (24)

  1. 펄프를 제조하기 위하여 목재칩을 증해하는 공정에서 미증해된 노트를 수집하는 수집단계;A collection step of collecting unexplained notes in a process of cooking wood chips to produce pulp;
    상기 수집된 노트가 분쇄되는 분쇄단계;A grinding step of crushing the collected notes;
    상기 분쇄된 노트의 불순물이 제거되는 1차 클리너단계; 및A primary cleaner step of removing impurities of the ground notebook; And
    상기 클리너단계를 거친 노트가 농축되고 폐액이 분리되는 농축단계를 포함하는 것을 특징으로 하는 노트의 섬유화방법.The fiber of the note characterized in that it comprises a concentration step of the concentrated notebook is subjected to the cleaner step and the waste liquid is separated.
  2. 청구항 1에 있어서,The method according to claim 1,
    상기 수집단계는 The collecting step
    목재칩을 증해하는 공정에서 미증해되어 분리된 노트가 스크린으로 수집되는 제1수집단계; 및 상기 수집된 노트가 탈수되어 흑액이 제거되는 제2수집단계를 포함하여 구성되는 것을 특징으로 하는 노트의 섬유화방법.A first collecting step of collecting the undigested notes on the screen by the wood chip cooking process; And a second collecting step in which the collected notes are dehydrated to remove the black liquor.
  3. 청구항 2에 있어서,The method according to claim 2,
    상기 제2수집단계는 상기 수집된 노트가 수분함량이 1 내지 50중량부가 되도록 탈수되는 것을 특징으로 하는 노트의 섬유화방법.The second collecting step is a fiberization method of the note, characterized in that the collected notes are dehydrated so that the water content of 1 to 50 parts by weight.
  4. 청구항 1에 있어서,The method according to claim 1,
    상기 분쇄단계는 상기 수집단계를 거친 노트가 분쇄기에 설치된 직경 11 내지 17mm의 스크린을 통과하여 분쇄되는 제1분쇄단계를 포함하는 것을 특징으로 하는 노트의 섬유화방법.The pulverizing step comprises a first pulverizing step of the crushed note is passed through a screen having a diameter of 11 to 17mm installed in the crusher.
  5. 청구항 4에 있어서,The method according to claim 4,
    상기 제1분쇄단계의 스크린은 직경 12 내지 15mm의 스크린인 것을 특징으로 하는 노트의 섬유화방법.The screen of the first milling step is a fiber of the note, characterized in that the screen of 12 to 15mm in diameter.
  6. 청구항 4에 있어서,The method according to claim 4,
    상기 분쇄단계는 상기 분쇄된 노트가 분쇄기에 설치된 직경 8 내지 11mm의 스크린을 통과하여 분쇄되는 제2분쇄단계를 추가로 포함하여 구성되는 것을 특징으로 하는 노트의 섬유화방법.The grinding step may further comprise a second grinding step that the crushed note is crushed through a screen having a diameter of 8 to 11mm installed in the crusher.
  7. 청구항 5에 있어서,The method according to claim 5,
    상기 제2분쇄단계의 스크린은 직경 9 내지 10.5mm의 스크린인 것을 특징으로 하는 노트의 섬유화방법.The screen of the second milling step is a fiber of the note, characterized in that the screen of 9 to 10.5mm in diameter.
  8. 청구항 1에 있어서,The method according to claim 1,
    상기 1차 클리너단계는The primary cleaner step is
    분쇄된 노트가 희석되는 제1클리너단계; 및A first cleaner step in which the ground notebook is diluted; And
    상기 희석된 노트에 포함된 불순물이 제거되는 제2클리너단계를 포함하여 구성되는 것을 특징으로 하는 노트의 섬유화방법.And a second cleaner step of removing impurities contained in the diluted notebook.
  9. 청구항 8에 있어서,The method according to claim 8,
    상기 제1클리너단계는 노트가 3 내지 6중량부의 농도로 희석되는 것을 특징으로 하는 노트의 섬유화방법.The first cleaner step is a fiber of the note, characterized in that the note is diluted to a concentration of 3 to 6 parts by weight.
  10. 청구항 8에 있어서,The method according to claim 8,
    상기 제2클리너단계는 노트에 포함된 불순물이 원심분리를 통하여 제거되는 것을 특징으로 하는 노트의 섬유화방법.The second cleaner step, the fiber of the note characterized in that the impurities contained in the note is removed by centrifugation.
  11. 청구항 1에 있어서,The method according to claim 1,
    상기 농축단계는 노트가 25 내지 35중량부의 농도로 농축되는 것을 특징으로 하는 노트의 섬유화방법.The concentration step is a fiber of the note characterized in that the notebook is concentrated to a concentration of 25 to 35 parts by weight.
  12. 청구항 1에 있어서,The method according to claim 1,
    상기 노트의 섬유화방법은 분쇄단계와 1차 클리너단계 사이에,The fiberization method of the note is between the grinding step and the primary cleaner step,
    상기 분쇄단계에서 분쇄된 노트가 희석되어 섬유상으로 분리되는 펄퍼 처리단계를 추가로 포함하는 것을 특징으로 하는 노트의 섬유화방법.And a pulp treatment step of diluting the notes pulverized in the crushing step and separating them into fibrous forms.
  13. 청구항 12에 있어서,The method according to claim 12,
    상기 펄퍼 처리단계는 상기 분쇄된 노트가 4.5 내지 6.5중량부의 농도로 희석되는 제1펄퍼처리단계; 및 상기 희석된 노트가 펄퍼에 의해 섬유상으로 분리되는 제2펄퍼처리단계를 포함하여 구성되는 것을 특징으로 하는 노트의 섬유화방법.The pulper treatment step may include a first pulper treatment step in which the ground notebook is diluted to a concentration of 4.5 to 6.5 parts by weight; And a second pulper treatment step in which the diluted notebook is separated into fibrous by pulper.
  14. 청구항 13에 있어서,The method according to claim 13,
    상기 제2펄퍼처리단계는 희석된 노트가 1 내지 30분 동안 펄퍼 처리되는 것을 특징으로 하는 노트의 섬유화방법.The second pulper treatment step is diluted notes 1 The fiberizing method of the note, characterized in that the pulp treatment for 30 minutes.
  15. 청구항 1에 있어서,The method according to claim 1,
    상기 노트의 섬유화방법은 클리너단계와 농축단계 사이에,The fiberization method of the note is between the cleaner step and the concentration step,
    상기 1차 클리너 처리된 노트가 디플레이커를 이용하여 혼합 교반되어 결속된 섬유물질이 분산되는 디플레이커 처리단계를 추가로 포함하는 것을 특징으로 하는 노트의 섬유화방법.And a deflavor treatment step of dispersing the bound fiber material by mixing and stirring the primary cleaner-treated note using a deflake.
  16. 청구항 15에 있어서,The method according to claim 15,
    상기 디플레이커 처리단계는 바 간격이 2 내지 4mm인 바 타입의 디플레이커를 이용하는 것을 특징으로 하는 노트의 섬유화방법.The deflake processing step is a fiberizing method of the note, characterized in that using a bar-type deflake having a bar interval of 2 to 4mm.
  17. 청구항 15에 있어서,The method according to claim 15,
    상기 노트의 섬유화방법은 디플레이커 처리단계와 농축단계 사이에, The fiberizing method of the note is between the deflake processing step and the concentration step,
    상기 디플레이커 처리된 노트를 희석하여 이물질을 제거하는 2차 클리너단계를 추가로 포함하는 것을 특징으로 하는 노트의 섬유화방법.And a secondary cleaner step of diluting the deflaked note to remove foreign matters.
  18. 청구항 16에 있어서,The method according to claim 16,
    상기 2차 클리너단계는 상기 디플레이커 처리된 노트가 0.5 내지 2중량부의 농도로 희석되는 것을 특징으로 하는 노트의 섬유화방법.In the secondary cleaner step, the fiber of the note, characterized in that the deflake-treated note is diluted to a concentration of 0.5 to 2 parts by weight.
  19. 청구항 1에 있어서,The method according to claim 1,
    상기 노트의 섬유화방법은 1차 클리너단계와 농축단계 사이에,The fiberization method of the note between the first cleaner step and the concentration step,
    최종 섬유 제품의 품질을 높이기 위하여 상기 클리너단계를 거친 노트의 이물질이 스크린을 통하여 추가 제거되는 압력 스크리닝단계를 추가로 포함하는 것을 특징으로 하는 노트의 섬유화방법.And a pressure screening step of further removing the foreign matters of the note that passed through the cleaner step through the screen in order to increase the quality of the final fiber product.
  20. 청구항 19에 있어서,The method according to claim 19,
    상기 압력 스크리닝단계에서의 스크린의 직경은 0.2 내지 0.4mm인 것을 특징으로 하는 노트의 섬유화방법.The diameter of the screen in the pressure screening step is a fiber of the note, characterized in that 0.2 to 0.4mm.
  21. 펄프를 제조하기 위하여 목재칩을 증해하는 공정에서 미증해된 노트를 수집하는 수집단계;A collection step of collecting unexplained notes in a process of cooking wood chips to produce pulp;
    상기 수집된 노트가 분쇄되는 분쇄단계;A grinding step of crushing the collected notes;
    상기 분쇄단계에서 분쇄된 노트가 희석되어 섬유상으로 분리되는 펄퍼 처리단계;A pulper treatment step of dividing the notes pulverized in the crushing step into fibrous phases;
    상기 분쇄된 노트의 불순물이 제거되는 1차 클리너단계; A primary cleaner step of removing impurities of the ground notebook;
    상기 클리너 처리된 노트가 디플레이커를 이용하여 혼합 교반되어 결속된 섬유물질이 분산되는 디플레이커 처리단계;A deflake processing step of dispersing the bound fiber material by mixing and stirring the cleaner-treated note using a deflake;
    상기 디플레이커 처리된 노트를 희석하여 이물질을 제거하는 2차 클리너단계;A secondary cleaner step of diluting the deflaked notebook to remove foreign substances;
    최종 섬유 제품의 품질을 높이기 위하여 상기 클리너단계를 거친 노트의 이물질이 스크린을 통하여 추가 제거되는 압력 스크리닝단계; 및A pressure screening step in which foreign substances of the notebook which have undergone the cleaner step are further removed through the screen to improve the quality of the final fiber product; And
    상기 클리너단계를 거친 노트가 농축되고 폐액이 분리되는 농축단계를 포함하는 것을 특징으로 하는 노트의 섬유화방법.The fiber of the note characterized in that it comprises a concentration step of the concentrated notebook is subjected to the cleaner step and the waste liquid is separated.
  22. 청구항 1 내지 21 중 어느 하나의 항에 의한 방법으로 섬유화된 것을 특징으로 하는 섬유화 노트.A fibrosis note, characterized in that fiberized by the method according to any one of claims 1 to 21.
  23. 청구항 22에 의한 섬유화된 노트를 포함하는 것을 특징으로 하는 종이제품.Paper product comprising the fiberized notebook according to claim 22.
  24. 청구항 23에 있어서, 상기 종이제품은 산업용와이퍼, 핸드타월, 냅킨, 티슈, 산업포장용지, 페이퍼 보드, 상업용 제지, 및 AFH 제품을 포함하는 것을 특징으로 하는 종이제품.24. The paper product of claim 23, wherein the paper product comprises an industrial wiper, a hand towel, a napkin, a tissue, an industrial packaging paper, a paper board, a commercial paper, and an AFH product.
PCT/KR2013/010862 2013-07-31 2013-11-27 Fiberization method of knots derived from pulp, fiberized knots and paper products using same WO2015016431A1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10108709A (en) * 1996-02-27 1998-04-28 Oji Paper Co Ltd Core material for shoes
US20040256065A1 (en) * 2003-06-18 2004-12-23 Aziz Ahmed Method for producing corn stalk pulp and paper products from corn stalk pulp
US20080124414A1 (en) * 2003-11-12 2008-05-29 Willfoer Stefan Use Of Knotwood Extracts
US20100240104A1 (en) * 2007-12-19 2010-09-23 Xiao Zhang Conversion of knot rejects from chemical pulping
JP4719633B2 (en) * 2006-06-26 2011-07-06 株式会社竹中工務店 Method for producing wood fiber bundle and wood fiber bundle obtained thereby

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10108709A (en) * 1996-02-27 1998-04-28 Oji Paper Co Ltd Core material for shoes
US20040256065A1 (en) * 2003-06-18 2004-12-23 Aziz Ahmed Method for producing corn stalk pulp and paper products from corn stalk pulp
US20080124414A1 (en) * 2003-11-12 2008-05-29 Willfoer Stefan Use Of Knotwood Extracts
JP4719633B2 (en) * 2006-06-26 2011-07-06 株式会社竹中工務店 Method for producing wood fiber bundle and wood fiber bundle obtained thereby
US20100240104A1 (en) * 2007-12-19 2010-09-23 Xiao Zhang Conversion of knot rejects from chemical pulping

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