WO2015007586A1 - Utilisation d'alcoxyborates de lithium et d'alcoxyaluminates de lithium en tant que sels conducteurs dans des électrolytes de piles au lithium-soufre - Google Patents

Utilisation d'alcoxyborates de lithium et d'alcoxyaluminates de lithium en tant que sels conducteurs dans des électrolytes de piles au lithium-soufre Download PDF

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Publication number
WO2015007586A1
WO2015007586A1 PCT/EP2014/064683 EP2014064683W WO2015007586A1 WO 2015007586 A1 WO2015007586 A1 WO 2015007586A1 EP 2014064683 W EP2014064683 W EP 2014064683W WO 2015007586 A1 WO2015007586 A1 WO 2015007586A1
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WO
WIPO (PCT)
Prior art keywords
alkyl
lithium
formula
alkenyl
substituted
Prior art date
Application number
PCT/EP2014/064683
Other languages
English (en)
Inventor
Arnd Garsuch
Ingo Krossing
Philipp Eiden
Michael Rohde
Lucia Alvarez Hernandez
Fadime Bitguel
Verena Leppert
Original Assignee
Basf Se
Albert-Ludwigs-Universitaet Freiburg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Albert-Ludwigs-Universitaet Freiburg filed Critical Basf Se
Publication of WO2015007586A1 publication Critical patent/WO2015007586A1/fr

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C07F5/022—Boron compounds without C-boron linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/06—Aluminium compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Secondary Cells (AREA)

Abstract

La présente invention concerne l'utilisation d'alcoxyborates de lithium et d'alcoxyaluminates de lithium en tant que sels conducteurs dans des électrolytes de piles au lithium-soufre, notamment une batterie au lithium-soufre comprenant (A) une composition d'électrolyte, (B) au moins une cathode comprenant un matériau actif de cathode contenant du soufre, et (C) au moins une anode comprenant un matériau actif d'anode choisi parmi le lithium et des alliages de lithium. La composition d'électrolyte (A) contient (i) au moins un solvant organique aprotique, (ii) au moins un composé représenté par la formule (I), (I) dans laquelle Z représente Al ou B ; (iii) facultativement au moins un sel conducteur différent du composé représenté par la formule (I) ; et (iv) facultativement au moins un autre additif.
PCT/EP2014/064683 2013-07-19 2014-07-09 Utilisation d'alcoxyborates de lithium et d'alcoxyaluminates de lithium en tant que sels conducteurs dans des électrolytes de piles au lithium-soufre WO2015007586A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13177155.2 2013-07-19
EP13177155 2013-07-19

Publications (1)

Publication Number Publication Date
WO2015007586A1 true WO2015007586A1 (fr) 2015-01-22

Family

ID=48803433

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2014/064683 WO2015007586A1 (fr) 2013-07-19 2014-07-09 Utilisation d'alcoxyborates de lithium et d'alcoxyaluminates de lithium en tant que sels conducteurs dans des électrolytes de piles au lithium-soufre

Country Status (1)

Country Link
WO (1) WO2015007586A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20210036358A1 (en) * 2019-07-31 2021-02-04 Innolith Technology AG So2-based electrolyte for a rechargeable battery cell, and rechargeable battery cells
CN113557238A (zh) * 2019-03-14 2021-10-26 三井化学株式会社 硼酸锂化合物、锂二次电池用添加剂、锂二次电池用非水电解液、锂二次电池前体、及锂二次电池的制造方法
US11489158B2 (en) 2017-12-18 2022-11-01 Dyson Technology Limited Use of aluminum in a lithium rich cathode material for suppressing gas evolution from the cathode material during a charge cycle and for increasing the charge capacity of the cathode material
US11616229B2 (en) 2017-12-18 2023-03-28 Dyson Technology Limited Lithium, nickel, manganese mixed oxide compound and electrode comprising the same
US11658296B2 (en) 2017-12-18 2023-05-23 Dyson Technology Limited Use of nickel in a lithium rich cathode material for suppressing gas evolution from the cathode material during a charge cycle and for increasing the charge capacity of the cathode material
US11769911B2 (en) 2017-09-14 2023-09-26 Dyson Technology Limited Methods for making magnesium salts
GB2617160A (en) * 2022-03-31 2023-10-04 Sumitomo Chemical Co Battery
US11817558B2 (en) 2017-09-14 2023-11-14 Dyson Technology Limited Magnesium salts
US11967711B2 (en) 2017-12-18 2024-04-23 Dyson Technology Limited Lithium, nickel, cobalt, manganese oxide compound and electrode comprising the same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000243437A (ja) * 1999-02-22 2000-09-08 Sanyo Electric Co Ltd 非水電解質電池用溶質及び非水電解質電池
US20050147886A1 (en) * 2004-01-06 2005-07-07 Moltech Corporation Electrolytes for lithium sulfur cells
JP2006107793A (ja) * 2004-09-30 2006-04-20 Sony Corp 電解質および電池
US20130108899A1 (en) * 2010-04-29 2013-05-02 Li-Tec Battery Gmbh Lithium-sulphur battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000243437A (ja) * 1999-02-22 2000-09-08 Sanyo Electric Co Ltd 非水電解質電池用溶質及び非水電解質電池
US20050147886A1 (en) * 2004-01-06 2005-07-07 Moltech Corporation Electrolytes for lithium sulfur cells
JP2006107793A (ja) * 2004-09-30 2006-04-20 Sony Corp 電解質および電池
US20130108899A1 (en) * 2010-04-29 2013-05-02 Li-Tec Battery Gmbh Lithium-sulphur battery

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11769911B2 (en) 2017-09-14 2023-09-26 Dyson Technology Limited Methods for making magnesium salts
US11817558B2 (en) 2017-09-14 2023-11-14 Dyson Technology Limited Magnesium salts
US11489158B2 (en) 2017-12-18 2022-11-01 Dyson Technology Limited Use of aluminum in a lithium rich cathode material for suppressing gas evolution from the cathode material during a charge cycle and for increasing the charge capacity of the cathode material
US11616229B2 (en) 2017-12-18 2023-03-28 Dyson Technology Limited Lithium, nickel, manganese mixed oxide compound and electrode comprising the same
US11658296B2 (en) 2017-12-18 2023-05-23 Dyson Technology Limited Use of nickel in a lithium rich cathode material for suppressing gas evolution from the cathode material during a charge cycle and for increasing the charge capacity of the cathode material
US11967711B2 (en) 2017-12-18 2024-04-23 Dyson Technology Limited Lithium, nickel, cobalt, manganese oxide compound and electrode comprising the same
CN113557238A (zh) * 2019-03-14 2021-10-26 三井化学株式会社 硼酸锂化合物、锂二次电池用添加剂、锂二次电池用非水电解液、锂二次电池前体、及锂二次电池的制造方法
EP3939982A4 (fr) * 2019-03-14 2022-12-28 Mitsui Chemicals, Inc. Composé de borate de lithium, additif pour batterie secondaire au lithium, solution électrolytique non aqueuse pour batterie secondaire au lithium, précurseur pour batterie secondaire au lithium, et procédé de production d'une batterie secondaire au lithium
US20210036358A1 (en) * 2019-07-31 2021-02-04 Innolith Technology AG So2-based electrolyte for a rechargeable battery cell, and rechargeable battery cells
US11710849B2 (en) * 2019-07-31 2023-07-25 Innolith Technology AG SO2-based electrolyte for a rechargeable battery cell, and rechargeable battery cells
GB2617160A (en) * 2022-03-31 2023-10-04 Sumitomo Chemical Co Battery

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