WO2014194746A1

WO2014194746A1 - Method for preparing magnesium alloy by electrolysis using magnesium oxide as raw material

Info

Publication number: WO2014194746A1
Application number: PCT/CN2014/077471
Authority: WO
Inventors: 卢旭晨; 张志敏
Original assignee: 中国科学院过程工程研究所
Priority date: 2013-06-04
Filing date: 2014-05-14
Publication date: 2014-12-11
Also published as: CN104213154B; CN104213154A

Abstract

Provided is a method for preparing a magnesium alloy by electrolysis using magnesium oxide as a raw material, comprising: (a) evenly mixing magnesium oxide, compounds of the other metal elements in the magnesium alloy, ammonium chloride, potassium chloride and additives to prepare a mixture, wherein the compounds of the other metal elements in the magnesium alloy are selected from one of the group consisting of: chlorides of the other metal elements in the magnesium alloy, oxides of the other metal elements in the magnesium alloy, and chlorides and oxides of the other metal elements in the magnesium alloy; (b) heating the mixture prepared in step (a) to a melting state, so as to prepare an electrolyte melt; and (c) electrolysing the electrolyte melt prepared in step (b), so as to obtain the magnesium alloy. The method of the present invention has a simple process, enables a continuous production, has a high degree of automation, is easy to operate and control and good in terms of environmental protection, and at the same time omits the process of producing metal magnesium and metals for the alloy, thereby shortening the overall manufacturing process of the magnesium alloy and reducing emissions and energy consumption.

Description

Method for preparing magnesium alloy by using magnesium oxide as raw material

The invention belongs to the field of alloy preparation, and in particular to a method for preparing a magnesium alloy, in particular to a method for preparing a magnesium alloy by electrolysis using magnesium oxide as a raw material. Background technique

Magnesium alloys have been widely used in the automotive industry, aerospace industry, etc. due to their low density, high specific strength and specific stiffness, good shock absorption and easy recovery. They will become the 21st century "era metal". ".

At present, there are several methods for preparing magnesium alloys:

(1) Pairing method. The metal magnesium and various metal elements are pretreated, added to a melting furnace, smelted under the protection of a flux or the like to be alloyed, and then a magnesium alloy is obtained. The method is simple in process and is a commonly used method in the industry. However, since the magnesium metal has a low melting point (649 ° C:) and a low density (1.6 _g / cm ³ ; i, if the alloy metal has a high melting point and a high density Moreover, the solubility in the alloy solution is small, and the magnesium alloy prepared by the method has serious segregation and poor alloying effect; further, for the metal alloy with strong chemical activity, when the magnesium alloy is prepared by this method, the alloy is seriously burned by the metal. Reference 1 (Ai Yanling, "Microstructure and Crystallographic Analysis of Ca and Si Magnesium Alloys" [PhD thesis: |, Guangzhou: South China University of Technology, 2004: 20-41;) with magnesium and metal Calcium is used as raw material. Firstly, the magnesium ingot is melted in an alloy melting furnace under gas protection conditions. When the temperature is raised to 650 ° C, metal calcium is added and stirred thoroughly, and then the temperature is raised to 720 ° C to obtain a magnesium alloy. , wherein the alloy is difficult to mix by stirring or thermal diffusion after heating and melting, and the alloy has segregation phenomenon. Reference 2 (CN 102220505) on the basis of the doping method, ultrasonication is performed during heating Reduced segregation of magnesium alloy and lanthanum oxide inclusions.

(2) Cathodic alloying method. It is a cathode of metal magnesium or magnesium alloy. In the molten salt electrolyte, metal ions migrate to the cathode under the action of a direct current electric field, and electrochemically reduce at the cathode, and the metal precipitated on the cathode is alloyed with the cathode. , to obtain the required magnesium Gold. For example, Reference 3 (Ren Chunxu, Zhang Kangning, "Magnesium Cathodic Electrolysis-Vacuum Distillation to Prepare Metal Antimony", Chinese Journal of Rare Earths, 1986, 4(4:) _: 73-76:) using liquid magnesium as the cathode, NdCl _{3 -} KCl-NaCl is an electrolyte (in which the content of NdCl ₃ is 20%:), the cathode current density is 1.5 A/cm ² , and electrolysis is carried out at 820 ° C ± 20 ° C, and the content of antimony in the obtained magnesium-niobium alloy can be Up to 30%, current efficiency is 65%-70%. References 4 Li Ping, Sun Jinye, et al., "Sinking rare earth-magnesium alloy by sinking cathode molten salt electrolysis", Chinese Journal of Rare Earths, 1987, 5(2:) _: 55-59:) 10wt% magnesium alloy as cathode, RE Cl ₃ -NaCl-KCl as electrolyte (rare earth content 15-20%), cathode current density of l-1.5A/cm ² , obtained by electrolysis at 750 °C 20-30% lanthanum-rich rare earth magnesium alloy. Reference 5 (CN 1908238A) uses this method to prepare electrolyte molten salt from anhydrous lithium chloride and potassium chloride, using magnesium rod as cathode, electrolysis at 450~480 °C, and deposition of metallic lithium in cathode magnesium. The surface is diffused internally to obtain a magnesium-lithium alloy. The method has the advantages of small segregation of alloy composition and low alloy burning loss; the disadvantage is that the cathode needs to be replaced in time, it is difficult to carry out continuous production, and it is difficult to industrialize; in addition, the metal magnesium or magnesium alloy cathode is separately prepared, thereby increasing the process flow and increasing The cost.

(3;) molten salt electrolytic co-deposition method. It is obtained by electrolyzing an electrolyte molten salt containing anhydrous magnesium chloride and a metal ion for alloying, and co-depositing to obtain a magnesium alloy. The advantages of this method are: (a) small segregation of alloy composition and low alloy burning loss; (b) preparation of magnesium alloy suitable for metal magnesium and alloy metal with large difference in melting point and large difference in density; (c) continuous production. The key part of the method is the preparation of high-quality electrolyte molten salt containing anhydrous magnesium chloride and metal ions for alloy. At present, anhydrous magnesium chloride and some anhydrous metal inorganic salts are used to prepare electrolyte molten salt, but anhydrous magnesium chloride and some anhydrous metal inorganic The salt preparation process is complicated and the production cost is high, which makes the commercialization of the magnesium alloy prepared by the method difficult.

Reference 6 (Renyong Hong, "Advances in science and technology of rare earth" [M] Chinese Rare Earth Society Ed., 2000: 216-220.) Using CeCl ₃ Document crystalline material and anhydrous M _g Cl ₂ as raw materials and CeCl ₃ -M _g Cl ₂ - KCl is an electrolyte (CeCl ₃ /M _g Cl ₂ /KCl=(25-35/(3-5y(60-70), mass ratio), cathode current density is 900-920 °C, and 铈40-60 is prepared. % magnesium bismuth alloy, current efficiency up to 75%. Reference 7 (Xu Guangxian, "Rare Earths" (volume) [M]. Beijing: Metallurgical Industry Press, 2002, 189-190), YCl ₃ -M _g Cl _2- KCl is an electrolyte, and electrolysis is carried out at 900 ° C to obtain a magnesium-niobium alloy containing about 60% of niobium, and the current efficiency is 70%. The above method uses anhydrous rare earth. Chloride and anhydrous magnesium chloride are used as raw materials, and the dehydration process of anhydrous rare earth chloride and anhydrous magnesium chloride is complicated, which greatly increases the cost. A method for preparing a rare earth magnesium alloy using a hydrated chloride raw material is described in detail in Reference 8 (CN 102220607 A): First, a mixture of potassium chloride, anhydrous magnesium chloride and anhydrous rare earth chloride is electrolyzed, and then aqueous magnesium chloride is added. The mixture with the aqueous rare earth chloride is electrolyzed at 820-1100 ° C to obtain a rare earth magnesium alloy. However, the addition of hydrated magnesium chloride and hydrated lanthanum chloride at high temperatures is severely hydrolyzed (Ref. 9: Han Jilong, Sun Qingguo et al., "Study on Preparation of Anhydrous Lanthanum by Vacuum Dehydration", Inorganic Salt Industry, 2009, 10: 25-26), thereby seriously reducing the current efficiency of the electrolysis process; in addition, the electrolysis temperature of the method is too high, which increases the operation difficulty and increases the cost of electrolysis.

References 10 and 11 (Cao P, Zhang ML, et al., Electrochemical Preparation of Mg-Li-Zn-Mn Alloys by Codeposition, Metallurgy and Materials Science)艮B (Metallurgical and Materials Transactions B), 2011, 42(4): 914-920; Ye K, Zhang ML, et al. Preparation of Mg-Li from LiCl-KCl-MgCl ₂ -MnCl ₂ molten salt by electrochemical co-deposition Study on the preparation of Mg-Li-Mn alloys by electrochemical codeposition from LiCl-KCl-MgCl ₂ -MnCl ₂ molten salt, Journal of applied electrochemistry, 2010, 40(7) ): 1387-1393) Mg-Li-Zn-Mn alloy and Mg-Li-Mn alloy were prepared by electrolytic co-deposition using anhydrous raw materials such as anhydrous magnesium chloride and anhydrous manganese chloride. The use of anhydrous magnesium chloride and anhydrous manganese chloride greatly increases the cost.

The preparation of magnesium lithium calcium alloy is described in detail in reference 12 (CN 101148773): using an inert metal as the cathode and graphite as the anode, a mixture of potassium chloride, lithium chloride and calcium fluoride is added to the electrolytic bath for thermal melting. After that, as the electrolyte, the magnesium oxide powder is added and melted according to 2% of the total mass of the electrolyte, and the electrolysis temperature is 450-640 ° C, the cathode current intensity is not less than 5 A/cm ³ , and the cell voltage is 4.5-6.5 V. Electrolysis, the electrolysis process is protected with argon gas, and the raw material magnesium oxide is added to the electrolytic cell at regular intervals. The method utilizes calcium fluoride to dissolve magnesium oxide in a molten salt, but the amount of magnesium oxide dissolved is small, and the amount of magnesium oxide added is also greatly limited (magnesia is a harmful impurity of electrolysis), taking into account various molten salts. The physicochemical properties, the amount of calcium fluoride added are limited, which may adversely affect electrolysis and cause a decrease in current efficiency.

Reference 13 (Cao Peng, "Multivariate co-deposited Mg-Li-X (X=Sn, La, Zn-Mn) alloy and Mechanism Research" [PhD thesis] Harbin: Harbin Engineering University, 2012: 61-71) Using anhydrous magnesium chloride, lithium chloride and zinc chloride as raw materials, adding 9.0wt.% to LiCl-KCl molten salt system Magnesium chloride, 0.3-0.4 wt.% zinc chloride, 0.2-0.3 wt.% manganese chloride, Mg-Li-Zn-Mn alloy prepared by electrolytic co-deposition method. Reference 14 (Yan YD, Zhang ML, etc.) Study on the preparation of Mg-Li-Zn alloys by electrochemical codeposition from LiCl-KC1 by electrochemical co-deposition from LiCl-KCl-M _g Cl ₂ -ZnCl ₂ melt —MgCl ₂ — ZnCl ₂ melts) , Electrochimica Acta, 2009, 54(12): 3387-3393) Using anhydrous magnesium chloride and zinc chloride as raw materials, added to LiCl-KCl molten salt system (LiCl 50wt.%, KC1 50wt .%) , Mg-Li-Zn alloy prepared by electrolytic co-deposition method. Reference 14 (: Liu Ruiguo, "Mol-Zr and Mg-Zn-Zr alloy preparation and cathode process for molten salt electrolysis" [PhD ]: Harbin Engineering University, 2011: 15-16;) using anhydrous magnesium chloride and zinc chloride as raw materials, _{_{_{M g Cl 2 -KCl-K 2}}} ZrF 6 - ZnCl ₂ is an electrolyte (M _g Cl ₂ 30 wt.%, ZnCl ₂ 1 wt.%), and a Mg-Zr-Zn alloy having a zinc content of 3.55 to 47.42% is obtained under a current density of 6.4 A m ² . .

With RECl ₃ -LiCl-KCl-M _g Cl ₂ as an electrolyte, co-deposition of rare earth metals, metallic lithium and metallic magnesium is achieved by adjusting voltage and current. References 15 Cao P, Zhan _g ML, etc., Electrochemical Behavior of Bismuth and Preparation of Mg-Li-Er Alloy by Electrodeposition (Electrochemical behaviour of erbium and preparation of Mg-Li-Er alloys by codeposition), Journal of Rare Earth Rare Earths), 2011, 29 ( 8): 763-767) using The KC1, anhydrous LiCl, dried over anhydrous M _g Cl _2, and K ₃ ErCl ₆ as raw material to prepare a _{_{KCl-10wt% M g Cl 2}} - 4wt.. Melt of %K ₃ ErCl ₆ . After electrolysis at 600 ° C, an Mg-Li-Er alloy was prepared. Reference 16 (Han W, Tian Y et al., Preparation of Mg-Li-Sm alloys of different phases by molten salt electrolysis in a LiCl-KCl-M _g Cl ₂ -SmCl ₃ melt (Preparing different phases of Mg-Li- Sm alloys by molten salt electrolysis in LiCl -KCl-MgCl 2 -SmCl 3 melts), rare earth Journal (Journal of rare Earths), 2010 , 28 (2): 227-231) using KC1, anhydrous LiCl, dried over anhydrous M _g Cl ₂ and anhydrous SmCl _{3 were used} as raw materials, and an alloy of Mg-Li-Sm was produced by electrolysis at 670 °C. Reference 17 (Zheng Tao, "Study on the mechanism of Mg-Li-RE (Pr, Ho, Er) alloy prepared by molten salt electrolysis"[Master's thesis: |, Harbin: Harbin Engineering University 2011: 47-51) Using KC1, anhydrous LiCl, anhydrous MgCl ₂ and K ₃ RECl ₆ (RE=Pr, Ho, Er) were prepared A melt of KCl-MgCl ₂ -LiCl-K ₃ REC1 ₆ was prepared by electrolysis at 700 ° C to obtain an alloy of Mg-Li-RE. The above electrolysis method utilizes anhydrous magnesium chloride, anhydrous lithium chloride and anhydrous rare earth chloride, so that the preparation cost of the alloy is greatly increased.

The advantages of molten salt electrolytic co-deposition to prepare magnesium alloys are outstanding, and it shows a viable prospect of industrialization and commercialization. A key issue that constrains the commercial application of this process is the economical preparation of high quality electrolyte melts containing anhydrous magnesium chloride and other metal ions in the magnesium alloy. At present, the preparation of the electrolyte melt is carried out by using anhydrous magnesium chloride and an anhydrous metal inorganic salt as raw materials, and the preparation process of anhydrous magnesium chloride and some anhydrous metal inorganic salts is complicated and the production cost is high, which restricts the preparation of the method. Commercialization of magnesium alloys. Summary of the invention

Based on the above problems, the inventors conducted intensive studies to provide a method for electrolytically preparing a magnesium alloy using magnesium oxide as a raw material. The method does not use anhydrous magnesium chloride and some anhydrous metal inorganic salts as raw materials, but uses magnesium oxide and hydrated metal inorganic salts or oxides as raw materials (this raw material is easy to obtain, low cost:), by forming a double salt and melting Salt dehydration produces a high quality electrolyte melt containing anhydrous magnesium chloride and other metal ions in the magnesium alloy, and then a magnesium alloy is prepared by electrolysis. By the method, a high-quality electrolyte melt for electrolytic co-deposition containing anhydrous magnesium chloride and alloy metal ions can be prepared under relatively simple process conditions under certain preferred conditions (calculated as 100% by weight of anhydrous magnesium chloride). The MgO content is less than 0.1% by weight:), which satisfies the requirements of the advanced electrolytic cell, and the current efficiency in the electrolytic process is over 80%, and the uniformity of the alloying elements is good.

Specifically, the present invention provides a method of electrolytically preparing a magnesium alloy using magnesium oxide as a raw material, the method comprising the following steps:

(a) uniformly mixing a magnesium oxide, a compound of another metal element in the magnesium alloy, ammonium chloride, potassium chloride, and an additive to prepare a mixture, wherein the compound of the other metal element in the magnesium alloy is selected from the group consisting of the following One of: a chloride of another metal element in the magnesium alloy; an oxide of other metal elements in the magnesium alloy; and a chloride and an oxide of other metal elements in the magnesium alloy;

(b) heating the mixture prepared in the step (a) to a molten state to prepare a An electrolyte melt of water magnesium chloride and other metal ions in the magnesium alloy;

(C) Electrolyzing the electrolyte melt prepared in the step (b) to produce the magnesium alloy. Compared with the prior art, the advantages of the invention are as follows: (1) The raw materials used for electrolytically preparing the magnesium alloy are magnesium oxide and hydrated metal inorganic salt chloride and/or oxide, which are easy to obtain and low in cost; Preparing a high-quality electrolyte melt for electrolytic co-deposition of other metal ions in anhydrous magnesium chloride and magnesium alloy (with anhydrous magnesium chloride, MgO content less than 0.1% by weight:), which meets the requirements of advanced electrolytic cell operation; 3) The obtained magnesium alloy has small segregation and low alloy burning loss; (4) effectively solves the problem that it is difficult to alloy due to large difference in melting point between metal magnesium and alloy metal, and large difference in density, and reduces such Production cost of magnesium alloy; (5) Simple process, continuous production, high degree of automation, easy operation and control, and good environmental protection.

In addition, the method of the present invention eliminates the production process of metal magnesium and alloy metal as compared to the conventionally used doping method in the industry, which generally shortens the manufacturing process of the magnesium alloy and reduces emissions and energy consumption. DRAWINGS

Figure 1 is a process flow diagram of a method in accordance with the present invention;

Figure 2 is an X-ray diffraction (XRD) pattern of a magnesium-lithium alloy prepared according to the method of the present invention; Figure 3 is an XRD pattern of a magnesium-niobium alloy prepared according to the method of the present invention;

Figure 4 is an elemental surface scan of a magnesium-zinc alloy prepared according to the method of the present invention;

Figure 5 is a diagram showing the energy spectrum of a magnesium-zinc alloy prepared according to the method of the present invention;

Figure 6 is an XRD pattern of a magnesium-zinc alloy prepared according to the method of the present invention;

Figure 7 is an XRD pattern of a magnesium-manganese alloy prepared according to the method of the present invention;

Figure 8 is an elemental surface scan of a magnesium-calcium alloy prepared according to the method of the present invention;

Figure 9 is an XRD pattern of a magnesium-calcium alloy prepared according to the method of the present invention;

Figure 10 is an elemental surface scan of a magnesium zinc calcium alloy prepared according to the method of the present invention; Figure 11 is an XRD pattern of a magnesium zinc calcium alloy prepared according to the method of the present invention;

Figure 12 is an elemental surface scan of a magnesium lithium niobium alloy prepared according to the method of the present invention; Figure 13 is an energy spectrum analysis diagram of a magnesium lithium niobium alloy prepared according to the method of the present invention; and Figure 14 is a magnesium lithium prepared according to the method of the present invention. XRD pattern of niobium alloy. detailed description

In the present invention, unless otherwise indicated, the term "other metal elements in the magnesium alloy" means a metal element other than the metal magnesium element in the magnesium alloy, for example, the metal manganese element in the magnesium manganese (Mg-Mn) alloy is "magnesium alloy". Other metal elements". The term "electrolyte melt containing anhydrous magnesium chloride and other metal ions in the magnesium alloy" means an electrolyte melt containing anhydrous magnesium chloride and other metal ions in the magnesium alloy as a main component prepared according to the method of the present invention, except for anhydrous In addition to other metal ions in magnesium chloride and magnesium alloys, the electrolyte melt may also include potassium chloride, calcium chloride, sodium chloride, barium chloride, calcium fluoride, potassium fluoride, lithium fluoride, magnesium fluoride, Sodium fluoride, etc. The term "waste electrolyte" means an electrolyte having less than 1% by weight of anhydrous magnesium chloride in the electrolyte melt. The term "correction factor" refers to a correction factor introduced in order to adjust the activity value of other metal ions in the magnesium alloy in the electrolyte melt to meet the composition of the target magnesium alloy during the electrolytic preparation of the magnesium alloy of the present invention, or to adjust The correction factor introduced by the physicochemical properties of the electrolyte melt for the good operation of the electrolysis process.

Further, in the present invention, unless otherwise indicated, the magnesium oxide (MgO) content in the electrolyte melt containing anhydrous magnesium chloride and other metal ions in the magnesium alloy means 100% by weight of anhydrous magnesium chloride. The weight percentage of magnesium oxide.

(b) heating the mixture prepared in the step to a molten state to prepare an electrolyte melt containing anhydrous magnesium chloride and other metal ions in the magnesium alloy;

(c) electrolyzing the electrolyte melt prepared in the step (b) to produce the magnesium alloy. According to some embodiments of the present invention, wherein in the step (a), the other metal element in the magnesium alloy is selected from one or more of the following elements: rare earth element, zinc, aluminum, manganese, lithium, Calcium, zirconium, silver, strontium, barium, cadmium, strontium, barium, lead and gallium.

According to some embodiments of the present invention, wherein in the step (a), the chloride of the other metal element in the magnesium alloy is selected from one or more of the following chlorides: rare earth element chloride, zinc chloride , aluminum chloride, manganese chloride, lithium chloride, calcium chloride, zirconium chloride, silver chloride, barium chloride, barium chloride, cadmium chloride, barium chloride, barium chloride, lead chloride and chlorine Gallium and so on.

According to some embodiments of the present invention, wherein in the step (a), the oxide of the other metal element in the magnesium alloy has a chemical property of reacting with ammonium chloride to form a corresponding chloride, and is selected from the following oxides One or more of: rare earth oxides, calcium oxide, manganese oxide, and antimony oxide.

According to some embodiments of the invention, wherein in the step (a), the additive is selected from one or more of the group consisting of: CaF ₂ , KF, NaF, LiF, MgF ₂ , CaCl ₂ , BaCl ₂ and NaCl, etc., the role of the additive is to adjust the physicochemical properties of the electrolyte melt so that the electrolysis process works well.

In the step (a), when the other metal element compound in the magnesium alloy is a chloride, the magnesium oxide, the metal chloride of the other metal element in the magnesium alloy, the mixture of ammonium chloride, potassium chloride and the additive are combined. The principle is as follows: Firstly, the amount of magnesium oxide and the amount of other metal element chloride in the magnesium alloy are determined according to the weight percentage of the metal element in the magnesium alloy, and the composition ratio of the mixture is 1.00 part by weight of the magnesium oxide. Parts by weight (without crystal water:),

Medium: is the correction factor, dimensionless, the value ranges from 0.10 to 145.00; is the weight percentage of other metal elements in the magnesium alloy; Μ is the atomic weight of other metal elements in the magnesium alloy; is the chloride of other metal elements in the magnesium alloy The valence of a metal element. According to the amount of magnesium oxide and the water content of other metal element chlorides in the magnesium alloy, the weight fraction of ammonium chloride is determined to be ^^ ₄ , ^ _{ff4a is} greater than (2.68 + 0.08 χ∑ (Α · ^)), and yttrium is in the magnesium alloy. The weight ratio of water to anhydrous chloride in the chloride of other metal elements. Determine the weight fraction of potassium chloride according to the amount of magnesium oxide converted to anhydrous magnesium chloride and the amount of anhydrous chloride of other metal elements in the magnesium alloy ^ _α , ^ = \ Μ + Ζ \ · π , where: Z1 is Correction factor, dimensionless,

Z1 values range from 0.05 to 150.00. The amount by weight of the additive is _d , W _a ^c _d = Z2 X (2.38 + +^ _α ), where: Z2 is a correction factor, dimensionless, and the Z2 value ranges from 0.005 to 0.500. In the step (a), when the other metal element compound in the magnesium alloy is an oxide, the magnesium oxide, the oxide of other metal elements in the magnesium alloy, the mixture of ammonium chloride, potassium chloride and the additive are combined. The principle is: First, according to the weight percentage of metal elements in magnesium alloys The amount of magnesium oxide is determined, and the amount of other metal element oxides in the magnesium alloy is used. The composition ratio of the mixture is 1.00 part by weight of magnesium oxide, and other metal element oxides in the magnesium alloy.

, (M _JO +8 )

The parts by weight f, °, W" =0.60xZ" where: for correction

(!-∑) M

Factor, dimensionless, value in the range of 0.05 to 100.00; weight percent of other metal elements in the magnesium alloy; atomic weight of other metal elements in the magnesium alloy; valence of metal elements in other metal element oxides in the magnesium alloy. According to the amount of other metal element oxides in the magnesium oxide and the magnesium alloy, the amount of ammonium chloride used in the amount of _4a , _{4a is} greater than (2.68 32.10 χΖ ° Π -

+). According to the amount of magnesium converted to anhydrous magnesium chloride and magnesium alloy

^∑ (1-∑ ): ',Μ

The amount of other metal elements converted to anhydrous chloride is determined by the amount of potassium used in the amount of potassium, (M _o +35.5n°.)

c! , _α =1.86+Ζ3χ (0.60 ) , where: for correction

(1-∑ a M

Factor, no class, 3 values range from 0.05 to 150.00. The amount by weight of the additive, _fld , a.

W _a ° _d =ZA Χ(2.38+∑(0.60χΖ ^{]0 1} -)+ D, where: Z4 is the correction

(1-∑ a M

Factor, dimensionless, Z4 values range from 0.005 to 0.500.

In the step (a), when the other metal element compounds in the magnesium alloy are chlorides and oxides, magnesium oxide, other metal element chlorides and oxides in the magnesium alloy, ammonium chloride, potassium chloride and additives The principle of the composition ratio of the mixture is as follows: First, the amount of magnesium oxide, the amount of other metal element chlorides and oxides in the magnesium alloy, and the composition of the mixture are determined according to the weight percentage of the metal element in the magnesium alloy. In an amount of 1.00 parts by weight, when other metal elements in the magnesium alloy are introduced with the chloride as a raw material, the amount of the chloride used is a-X (M _1C + 35.5η.)

(in the absence of crystal water), where: is the correction factor, dimensionless, the value ranges from 0.10 to 145.00; is the weight of other metal elements in the magnesium alloy (referring to other metal elements introduced by the chloride raw material:) Partial content; is the weight percentage of other metal elements in the magnesium alloy (referring to other metal elements introduced by the oxide raw material); Μ is the atomic weight of other metal elements in the magnesium alloy (refers to other metals introduced by the chloride raw material) Element) is the valence of other metal elements in magnesium alloy in anhydrous chloride (refers to other metal elements introduced by chloride raw materials. When other metal elements in magnesium alloy are introduced with their oxides as raw materials, the amount of oxides is used. Weight ^σ ,

W _; ° =0.60xZ _n c — x3⁄4^ , where: ^ is the correction factor, no], the value ranges from 0.05 to 100.00; M,. An atom of other metal elements in a magnesium alloy: (refers to other metal elements introduced by the oxide raw material); is the valence of the metal element in the oxide of other metal elements in the magnesium alloy (refers to other metal elements introduced by the oxide raw material). According to the amount of magnesium oxide, the water content of other metal element chlorides in the magnesium alloy, and the amount of other metal element oxides in the magnesium alloy, the weight fraction of ammonium chloride is determined. NH4CI NH4CI: (2.68

32.10 χ Ζ° χ η ,

+ -), where A is the other of the magnesium alloy

(1 - a. - ^α°) χ Μ

The weight ratio of water to anhydrous chloride in the chloride of the metal element (referring to other metal elements introduced by the chloride raw material). Determine the weight of potassium chloride based on the amount of magnesium oxide converted to anhydrous magnesium chloride, the amount of anhydrous chloride of other metal elements in the magnesium alloy, and the amount of other metal element oxides in the magnesium alloy converted to anhydrous chloride. , ^ =1.86+Z5-(∑^ ^C +

Ζ „ ) ) ), where _Ζ5 is the correction factor, dimensionless, (0.60 χ Ζ

(1

Ζ5 values range from 0.05 to 150.00. The weight of the additive is OW _a ^c = Z6 X (2.38+

2 α° χ (M _JO + 35.5«°)

+ (0.60 χ Ζ; -) + W ), where: Z6 is the correction factor, dimensionless, and the Z6 value ranges from 0.005 to 0.500.

According to some embodiments of the present invention, wherein in the step (b), the heating process is: first, at 300 to 550 ° C (preferably 300 to 450 ° C) for 0.5 to 3.5 hours (preferably 1.5 to 3 hours). Then, it is kept at 400 to 850 ° C (preferably 400 to 700 ° C) for 0.2 to 4.0 hours (preferably 0.5 1.5 hours) to obtain an electrolyte melt containing anhydrous magnesium chloride and other metal ions in the magnesium alloy.

According to some embodiments of the present invention, wherein in the step (c), the conditions of the electrolysis are: the anode is made of a graphite material, and the cathode is made of a steel material; the temperature at the time of electrolysis is 400 to 850 ° C ( Preferably, 400 700 ° C), the electrolysis voltage is 5 to 10 V, and the cathode current density is greater than 3 A/cm ² .

The cathode is made of a steel material, which is in a solid form, and may be a commercially available product, preferably a steel having a carbon content of less than 0.2% by weight. The anode is made of a graphite material in a solid form, and a commercially available product can be used; in the electrolysis process, chlorine is evolved from the anode.

According to some embodiments of the invention, the ammonium chloride released in step (b) is recovered and returned to step (a) for recycling, and the released ammonia is recycled.

According to some embodiments of the present invention, the waste electrolyte melt discharged during the electrolysis of the step (C) is returned to the step (a) for recycling, and the produced chlorine gas is subjected to purification and recycling.

For the raw materials used in the present invention (for example, chlorine in other magnesium oxides in magnesium oxide and magnesium alloys) The compounds and oxides, ammonium chloride, potassium chloride, etc.: are not specifically limited, and they may all be commercially available. The raw material is preferably in the form of a powder, and the particle diameter of the powder is not particularly limited as long as it does not affect uniform mixing.

The chloride of other metal elements in the magnesium alloy used in the present invention is not limited to the indicated rare earth element chloride, zinc chloride, aluminum chloride, manganese chloride, lithium chloride, calcium chloride, zirconium chloride, chlorine. Silver chloride, barium chloride, barium chloride, cadmium chloride, barium chloride, barium chloride, lead chloride, gallium chloride, etc.; chlorides of other metal elements in magnesium alloys are hydrated chloride or anhydrous chloride.

The oxide of the other metal element in the magnesium alloy used in the present invention has a chemical property of reacting with ammonium chloride to form a corresponding chloride, and is not limited to the above-mentioned oxides such as rare earth oxide, calcium oxide, manganese oxide, and cerium oxide.

Ammonium chloride and potassium chloride are employed in the process according to the invention, wherein their effects are as follows:

The function of ammonium chloride is to convert the oxides of other metal elements in magnesium oxide and magnesium alloy into corresponding chlorides. At the same time, the hydrogen chloride generated by the decomposition of ammonium chloride at a certain temperature inhibits the hydrolysis of chlorides, ensuring the anhydrous chlorine. The purity of the compound.

As the main component of the molten salt electrolyte, potassium chloride plays the following roles: (1) lowering the melting temperature of the molten salt electrolyte; (2) - improving the conductivity of the molten salt electrolyte; (3) suppressing molten salt electrolyte at high temperature Hydrolysis; (4) The precipitation potential of potassium chloride is high, metal potassium is not easily precipitated, and does not affect the purity of magnesium alloy.

For the additives used in the present invention (eg, CaF ₂ , M _g F ₂ , KF, LiF, CaCl ₂ , BaCl ₂ ,

There are no specific restrictions on the NaCl, and they can all be used in ordinary commercial products. The raw material is preferably in the form of a powder, and the particle diameter of the powder is not particularly limited as long as it does not affect uniform mixing. The role of the additive used in the present invention is to adjust the physicochemical properties of the electrolyte melt. The physicochemical properties of the electrolyte melt mainly include: conductivity, viscosity, surface tension, melting temperature, density, etc. of the electrolyte melt. The high conductivity and low viscosity of the electrolyte melt are advantageous for the electrolysis process. The addition of sodium chloride is beneficial to increase the electrical conductivity of the electrolyte melt. The addition of fluoride facilitates the collection of magnesium alloy fluid in the electrolyte melt. For magnesium alloys of different compositions, the surface tension, melting temperature, density, etc. of the electrolyte melt are adjusted depending on the specific conditions.

1 shows a method for electrolytically preparing a magnesium alloy using magnesium oxide as a raw material according to the present invention Process flow chart. In the above method, (a) magnesium oxide, a compound of other metal elements in the magnesium alloy, ammonium chloride, potassium chloride and the additive are uniformly mixed in a certain ratio, wherein the compound of the other metal element in the magnesium alloy is selected from the following a group of each of: a chloride of another metal element in the magnesium alloy; an oxide of other metal elements in the magnesium alloy; and a chloride and an oxide of other metal elements in the magnesium alloy; (b) The product obtained in step (a) is first incubated at 300-550 ° C for 0.5-3.5 hours, and then held at 400-850 ° C for 0.2-4.0 hours to obtain anhydrous magnesium chloride and other metals in the magnesium alloy. The ionic electrolyte melt, at the same time, the released ammonium chloride is recovered and returned to the cycle (a) for recycling, and the released ammonia gas is recycled; (c) the electrolyte melt obtained by the step b) is at a temperature The magnesium alloy is obtained by electrolysis at 400 850 ° C, an electrolysis voltage of 5-10 V, and a cathode current density of more than 3 A/cm ² , and the electrolysis process discharges the waste electrolyte melt while generating chlorine gas. The waste electrolyte melt discharged during the electrolysis of the step (C) is returned to the step (a) for recycling, and the generated chlorine gas is purified and recycled.

The inventors have found through a large number of experimental studies that the mechanism of the above reaction is as follows: At about 200-300 ° C, magnesium oxide reacts with ammonium chloride to form a double salt N3⁄4Cl_M _g Cl ₂ _«H ₂ O (0 ≤ « <6) Using the characteristics of weakened binding ability of crystallization water and magnesium chloride in the double salt, the crystallization water in the double salt is removed one by one (Zhang ZM, Lu XC, etc., Preparation of anhydrous magnesium chloride from magnesia, industrial & Industrial and Engineering Chemistry Research, 2012, 51(29): 9713-9718). At the same time, the inventors discovered through experiments that when the temperature rises to about 300-500 ° C, a double salt KM _g Cl _{3 is formed} , which is relatively stable at high temperatures and is not easily reacted with oxygen and water vapor in the air. The hydrolysis reaction of anhydrous magnesium chloride is inhibited, and the purity of the product is ensured; the hydrogen chloride gas generated by the decomposition of ammonium chloride at a high temperature can effectively inhibit the hydrolysis reaction of other metal elements hydrated chloride in the magnesium alloy, and chlorinate at a certain temperature. Ammonium can react the hydrolysate to form the corresponding anhydrous chloride, which ensures the purity of the product. The rare earth oxide reacts with ammonium chloride at a temperature greater than 140 °C to form a double salt "N3⁄4C1_REC1 ₃ (in the text, Li Guanfeng, Zhao Yonghe, Zhu Guocai, "Ammonium Chloride Oxide Oxide Oxide Oxide Mixture and Its Kinetics", Journal of Xinyang Normal University (Natural Science Edition), 2005, 18(2): 155-158), the temperature rises to about 400 °C Forming a double salt K ₃ REC1 ₆ , the double salt is relatively stable at high temperatures, and is not easy to react with oxygen in the air Gas and water vapor react to inhibit the occurrence of hydrolysis of anhydrous rare earth chloride (Zheng Tao, Mg-Li-RE Pr, Ho, Er) alloy mechanism research [Master's thesis], Harbin: Harbin Engineering University, 2011 : 14-15); Other metal oxides (such as calcium oxide, barium oxide, manganese oxide, etc.) can also react with ammonium chloride at 300-400 ° C to form the corresponding anhydrous metal chloride ( Shao Yuchang, "Reaction and Application of Ammonium Chloride", Soda Industry, 2008, 4: 3-12). The inventors have found that the sintering shrinkage of the chloride mixture at 200-500 ° C slows the rate of evolution of ammonium chloride so that ammonium chloride can react sufficiently. The ammonium chloride discharged in the step (b) is returned to the step (a) for recycling, thereby reducing the production cost and improving the productivity. By adjusting the activity value and polarization value of magnesium ions and alloying ions in the melt, the precipitation potentials of magnesium ions and alloying ions are similar or equal to achieve co-deposition of magnesium metal and other metals to form a magnesium alloy.

This method is highly versatile for the preparation of magnesium alloys. Since magnesium alloy materials are being widely used, the development potential is very large. The types of magnesium alloys currently developed are limited, and there is a large space for the development of new high-performance magnesium alloy materials. This method provides a preparation method for developing new high-performance magnesium alloys. .

testing method

The electrolyte melt containing anhydrous magnesium chloride and other metal ions in the magnesium alloy was measured according to the following method.

The aqueous solution precipitate is determined by titration to determine the content of magnesium oxide in the electrolyte melt of other metal ions in anhydrous magnesium chloride and magnesium alloy: the obtained electrolyte melt containing anhydrous metal chloride and other metal ions in the magnesium alloy The sample was dissolved in water, and the aqueous solution was repeatedly filtered at least three times with four Φ90πιπι quantitative filter paper (Hangzhou Special Paper Co., Ltd.) until the filtrate was particularly clear. The filter paper is repeatedly rinsed with deionized water to wash away the magnesium ions attached thereto, and the filter paper containing the magnesium oxide particles after washing is placed in a beaker, and an excess of prepared 1:100 sulfuric acid is added (analytical purity, purity 95.98%; Manufacturer: Beijing Beihua Fine Chemicals Co., Ltd.) Heat the beaker on an electric stove and let it stand for five minutes to complete the reaction. The solution in the beaker is subjected to EDTA titration to determine the content of magnesium ions, thereby obtaining magnesium oxide in the electrolyte melt. The obtained magnesium alloy was characterized according to the following method.

1. Alloy phase analysis: The phase composition of the product was determined by X-ray diffraction (XRD) using an X-ray diffractometer (Model: X'Pert PRO MPD; Factory: Philips).

2. Elemental homogeneity analysis: (1) Analysis of elemental micro-region uniformity: Magnesium in sample by Quanta 250 environmental scanning electron microscope with mineral dissociation analyzer (model: FEI MLA250; manufacturer: FEI Electronic Chemical Co., USA) Surface scanning with other alloying elements (surface scanning of lithium elements is not possible: (2) Macroscopic uniformity analysis of elements: Inductively coupled plasma is used from three different locations from the outside to the inside with an interval of approximately 5 mm. Atomic emission spectrometer (model: Optima 5300DV; manufacturer: PerkinElmer, USA) was used to determine the content of alloying elements.

3. Energy spectrum analysis: The spectrum of the sample is analyzed by the EDAX GENESIS spectrometer with the mineral dissociation analyzer (Model: FEI MLA250; manufacturer: FEI Electronic Chemical Company, USA).

4. Calculation of current efficiency: The current efficiency during electrolysis is calculated according to the following formula (see the literature for the source of the formula: Wei H, Chen Q, etc., New preparation of Mg-Li-Al alloy by electrolysis (New preparation of Mg-Li-Al) Alloys by electrolysis) , Acta Metall. Sin. (Engl. Lett.), 2010, 23(2): 129-136):

∑m x w.

x n,

M, ¹

η = x 100%

It where m—the mass of the alloy obtained by electrolysis, _g;

w - the mass percentage of each component metal, %, measured by an inductively coupled plasma mass spectrometer;

Λ^.—the atomic weight of each component metal;

η - the number of electrons of each component metal in the electrode reaction formula;

F—Faraday constant, 26.801Α·1ι·πιο1-1;

I—electrolytic current intensity, Α;

T-electrolysis time, h. EXAMPLES In order to better explain the present invention, it is convenient to understand the technical solution of the present invention, and a typical but non-limiting embodiment of the present invention is as follows:

The raw materials involved in the present invention are all commercially available products, including:

Barium chloride heptahydrate: Tianjin Damao Chemical Reagent Factory, purity 98.0%;

Lithium chloride monohydrate: Xiqiao Chemical Co., Ltd., purity 97.0%;

Manganese chloride tetrahydrate: Xiqiao Chemical Co., Ltd., purity 99.0%;

Zinc chloride: Xiqiao Chemical Co., Ltd., purity 98.0%;

Calcium Chloride: Xiqiao Chemical Co., Ltd., purity 96.0%;

Magnesium oxide: Sinopharm Chemical Reagent Co., Ltd., purity 98.5%;

Antimony oxide: Sinopharm Chemical Reagent Co., Ltd., purity 99.99%;

Calcium Oxide: Tianjin Jinhui Taiya Chemical Reagent Co., Ltd., purity 99.8%; manganese oxide: Guangzhou Wancang Chemical Co., Ltd., purity 99.0%;

Ammonium chloride: Xiqiao Chemical Co., Ltd., purity 99.5%;

Potassium chloride: Xiqiao Chemical Co., Ltd., purity 99.5%;

Sodium chloride: Xiqiao Chemical Co., Ltd., purity 99.5%;

Calcium fluoride: Sinopharm Chemical Reagent Co., Ltd., purity 98.5% _;

Hydrated cerium chloride (self-made:): heated by the above-mentioned cerium chloride heptahydrate, and judges the final product according to the weight loss condition;

Lithium chloride hydrate (self-made:): heated by the above-mentioned lithium chloride monohydrate, and judges the final product according to the weight loss condition;

Hydrated manganese chloride (homemade):

Example 1

2.61 g of magnesium oxide, 80.04 g of lithium chloride, 56.19 g of potassium chloride, 3.18 g of calcium fluoride and 28.20 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and then kept at 300 ° C for 1.5 hours, and then kept at 500 ° C for 0.5 hour to obtain a melt containing anhydrous magnesium chloride and anhydrous lithium chloride (the melt composition was: KCl (45.10wt.%)-(2.26wt.%) NaCl-MgCl ₂ (4.98wt.%) -LiCl (45.10wt.%) -CaF ₂ (3.18wt.%)) _{0 The} melt is very pure, not observed To impurities. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis condition is: the melt is an electrolyte, the spectral pure graphite rod of Φ6πιπι is an anode, the steel wire of Φΐπιπι is a cathode, and the graphite crucible having a volume of 200 mL is an electrolytic cell. The electrolysis temperature is 440 ° C, the pole pitch is 4 cm, the cathode current density is 5.4 A/cm ² , the cell voltage is 8.3-8.5 V, and the electrolysis time is 3.5 ho.

The electrolyte melt and the magnesium-lithium alloy were characterized according to the above measurement methods. The results are as follows: The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous lithium chloride was 0.06 wt%. The lithium contents of the sample from the outside to the inside were 50.78%, 50.82%, and 50.34%, respectively, and it was found that the lithium element distribution was uniform in the macroscopic view. The current efficiency of the electrolysis process was 83.2%. The XRD pattern of the alloy is shown in Fig. 2. It can be seen from the figure that the phase composition of the alloy is Li and Li ₃ M _gl7 . Example 2

Mix 6.97g of magnesium oxide, 26.30g of lithium chloride hydrate (LiCH).5H ₂ C, 43.40g of potassium chloride, 2.17g of sodium chloride, 4.02g of calcium fluoride and 40.30g of ammonium chloride, and then add to 200mL . The lid was covered with a lid and incubated at 300 ° C for 2 hours, and then incubated at 480 ° C for 1 hour to obtain a melt containing anhydrous magnesium chloride and anhydrous lithium chloride (melt composition: KC1 (39.61wt) .%)- NaCl (1.98 wt.%)-MgCl ₂ (15.13 wt.%)-LiCl (39.61 wt.%)-CaF ₂ (3.67 wt.%)) _{0 The} melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6 mm of a spectral pure graphite rod is an anode, Φΐπιπ wire is a cathode, and a volume of 200 mL of graphite crucible is an electrolytic cell. The electrolysis temperature is 480 ° C, the pole pitch is 4 cm, the cathode current density is 6.3 A/cm ² , the cell voltage is 9.1-9.5 V, and the electrolysis time is 3.5 h.

The electrolysis process and the obtained magnesium-lithium alloy were characterized according to the above measurement methods. The results are as follows:

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous lithium chloride was 0.08% by weight. The lithium content of the sample from the outer to the inner position was 4.16%, 4.35%, and 4.25%, respectively. It can be seen that the lithium element distribution of the sample was uniform at the macroscopic level. The current efficiency of the electrolysis process was 82.5%. The XRD pattern of the alloy shows that the phase composition of the alloy is Li and Li ₃ M _gl7 . Example 3

14.00 g of magnesium oxide, 100.00 g of potassium chloride, 11.40 g of cesium chloride heptahydrate, 4.88 g of calcium fluoride and 66.24 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and incubated at 400 ° C for 1.5 hours, and then held at 700 ° C for 1 hour to obtain a melt containing anhydrous magnesium chloride and anhydrous cerium chloride (melt composition: KC1 (68.65 wt) .%)-MgCl ₂ (23.14 wt.%)-LaCl ₃ (5.17 wt.%)-CaF ₂ (3.35 wt.%)), the melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6 mm of a spectrally pure graphite rod is an anode, a Φΐπιπ wire is a cathode, and a volume of 200 mL of a graphite crucible is an electrolytic cell. The electrolysis temperature is 690 ° C, the pole pitch is 4 cm, the cathode current density is 6.3 A/cm ² , the cell voltage is 7.9-8.3 V, and the electrolysis time is 3.5 ho.

The electrolysis process and the obtained magnesium bismuth alloy were characterized according to the above measurement methods. The results are as follows:

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous cerium chloride was 0.15% by weight. The strontium content of the sample from the outside to the inside was 5.15%, 5.01%, and 4.98%, respectively. It can be seen that the distribution of the ruthenium element in the sample is uniform. The current efficiency of the electrolysis process was 97.8%. The XRD pattern of the alloy is shown in Fig. 3. As can be seen from the figure, the phase composition of the alloy is Mg and La ₂ M _gl7 . Example 4

14.00 g of magnesium oxide, 100.00 g of potassium chloride, 5.00 g of cerium oxide, 4.88 g of calcium fluoride and 66.24 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and incubated at 450 ° C for 1.5 hours, and then held at 700 ° C for 1 hour to obtain a melt containing anhydrous magnesium chloride and anhydrous cerium chloride (melt composition: (68.65 wt. %)-MgCl ₂ (23.14 wt.%)-LaCl ₃ (5.17 wt.%)-CaF ₂ (3.35 wt.%)), the melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6 mm of a spectrally pure graphite rod is an anode, a Φΐπιπ wire is a cathode, and a volume of 200 mL of a graphite crucible is an electrolytic cell. The electrolysis temperature is 700 ° C, the pole pitch is 4 cm, the cathode current density is 5.4 A/cm ² , the cell voltage is 7.3-8.0 V, and the electrolysis time For 3

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous cerium chloride was 0.11% by weight. The strontium content of the sample from the outside to the inside was 6.25%, 6.18%, and 6.25%, respectively. It can be seen that the distribution of the ruthenium element in the sample is uniform. The current efficiency of the electrolysis process was 99.01%. The XRD pattern of the alloy shows that the phase composition of the alloy is Mg and La ₂ M _gl7 . Example 5

14.00 g of magnesium oxide, 100.00 g of potassium chloride, 10.41 g of cesium chloride hydrate (LaCl ₃ '5.23⁄40), 4.88 g of calcium fluoride and 66.24 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and then kept at 450 ° C for 2 hours, and then held at 700 ° C for 1.5 hours to obtain a melt containing anhydrous magnesium chloride and anhydrous barium chloride (melt composition: (68.65 wt. %)-MgCl ₂ (23.14 wt.%) -LaCl ₃ (5.17 wt.%) -CaF ₂ (3.35 wt.%)). The melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6 mm of a spectrally pure graphite rod is an anode, a Φΐπιπ wire is a cathode, and a volume of 200 mL of a graphite crucible is an electrolytic cell. The electrolysis temperature is 700 ° C, the pole pitch is 4 cm, the cathode current density is 7.8 A/cm ² , the cell voltage is 8.5-8.9 V, and the electrolysis time is 3.

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous cerium chloride was 0.20% by weight. The content of strontium from the outside to the inside of the sample was 9.34%, 9.18%, and 9.38%, respectively. It can be seen that the distribution of the ruthenium element in the sample is uniform. The current efficiency of the electrolysis process was 98.20%. The XRD pattern of the alloy shows that the phase composition of the alloy is Mg and La ₂ M _gl7 . Example 6

13.94 g of magnesium oxide, 8.28 g of zinc chloride, 82.78 g of potassium chloride and 66.24 g of ammonium chloride were mixed and added to 200 mL of mash. Cover the lid with a lid and incubate at 450 ° C for 1.5 hours. Then, the mixture was kept at 700 ° C for 1 hour to obtain a melt containing anhydrous magnesium chloride and zinc chloride (melt composition: KC1 (66.66 wt.%) - MgCl ₂ (26.67 wt.%) - ZnCl ₂ (6.67) Wt.%))o The melt is very pure and no impurities are observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6 mm of a spectral pure graphite rod is an anode, Φΐπιπι is a cathode, and a volume of 200 mL of corundum is an electrolytic cell. The electrolysis temperature is 680 ° C, the pole pitch is 4 cm, the cathode current density is 4.57 A/cm ² , the cell voltage is 5.2-5.7 V, and the electrolysis time is 4 h.

The electrolysis process and the obtained magnesium-zinc alloy were characterized according to the above measurement methods. The results are as follows:

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous zinc chloride was 0.04% by weight. The zinc content of the sample from the outside to the inside was 36.71%, 37.12%, and 37.05%, respectively. It can be seen that the sample has a uniform distribution of zinc elements in the macroscopic view. The elemental surface scan of the alloy is shown in Figure 4. It can be seen from the figure that magnesium and zinc are uniformly distributed in the alloy. The energy spectrum analysis of the alloy is shown in Fig. 5, in which the energy spectrum analysis at the lower portion Figs. 1 and 2 correspond to the results of the energy spectrum analysis detected at the marks 1 and 2 in the upper graph, respectively. Magnesium-zinc alloys are more active and easily react with oxygen or water. The 0 and C1 elements detected in the energy spectrum are incorporated during the grinding and polishing process. The current efficiency of the electrolysis process was 98.91%. Figure 6 is an XRD pattern of the alloy. It can be seen from the figure that the phase composition of the alloy is Mg, MgZn ₂ and Mg ₇ Zn ₃ . Example 7

13.94 g of magnesium oxide, 8.28 g of zinc chloride, 82.78 g of potassium chloride and 55.95 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and incubated at 400 ° C for 1.5 hours, and then held at 700 ° C for 1.5 hours to obtain a melt containing anhydrous magnesium chloride and zinc chloride (melt composition: KC1 (66.66 wt.%) )-M _g Cl ₂ (26.67 wt.%)-ZnCl ₂ (6.67 wt.%)). The melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6mm spectral pure graphite rod is an anode, Φΐπιπι steel wire is a cathode, and a volume of 200 mL corundum is an electrolytic cell The electrolysis temperature is 700 °C, the pole pitch is 4 cm, the cathode current density is 6.54 A/cm ² , the cell voltage is 6.4-6.8 V, and the electrolysis time is 2 h. The electrolysis process and the obtained magnesium-zinc alloy were characterized according to the above measurement methods. The results are as follows:

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous zinc chloride was 0.06 wt%. The zinc content of the sample from the outside to the inside was 27.59%, 27.82%, and 27.73%, respectively. It can be seen that the sample has a uniform zinc distribution in the macroscopic. The current efficiency of the electrolysis process was 95.88%. The XRD pattern of the alloy shows that the phase composition of the alloy is Mg, M _g Zn ₂ and Mg ₇ Zn ₃ . Example 8

13.94 g of magnesium oxide, 82.78 g of potassium chloride, 7.80 g of manganese chloride tetrahydrate and 55.95 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and incubated at 400 ° C for 2 hours, and then incubated at 680 ° C for 1 hour to obtain a melt containing anhydrous magnesium chloride and anhydrous manganese chloride (melt composition: KC1 (82.78wt) .%)-MgC12 (33.12 wt.%) - MnC12 (4.96 wt.%)). The melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis condition is: the melt is an electrolyte, the spectral pure graphite rod of Φ6πιπι is an anode, the steel wire of Φΐπιπι is a cathode, and the corundum crucible having a volume of 200 mL is an electrolytic cell. The electrolysis temperature was 680 ° C, the pole pitch was 4 cm, the cathode current density was 5.3 A/cm ² , the cell voltage was 5.7-6.7 V, and the electrolysis time was 3.5 h.

The electrolysis process and the obtained magnesium-manganese alloy were characterized according to the above measurement methods. The results are as follows:

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous manganese chloride was 0.04% by weight. The manganese content of the sample from the outside to the inside was 27.33%, 26.87%, and 27.24%, respectively. It can be seen that the distribution of manganese in the macroscopic sample is uniform. The current efficiency of the electrolysis process was 98.73%. Figure 7 is an XRD pattern of the alloy. It can be seen from the figure that the phase of the alloy consists of metallic magnesium and manganese metal. Example 9

13.94 g of magnesium oxide, 82.78 g of potassium chloride, 6.45 g of manganese chloride hydrate (MnCl ₂ '2.13⁄40) and 55.95 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and incubated at 400 ° C for 2 hours, and then kept at 700 ° C for 1 hour to obtain anhydrous magnesium chloride and no The melt of water manganese chloride (melt composition: KC1 (82.78 wt.%) - MgCl ₂ (33.12 wt.%) - MnCl ₂ (4.96 wt.%)) _{0 The} melt was very pure, and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6 mm spectral pure graphite rod is an anode, Φΐπιπι steel wire is a cathode, and a volume of 200 mL corundum is an electrolytic cell The electrolysis temperature is 700 ° C, the pole pitch is 4 cm, the cathode current density is 6.1 A/cm ² , the cell voltage is 7.1-8.0 V, and the electrolysis time is 3.5 h.

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous manganese chloride is 0.02% by weight. The manganese content of the sample from the outside to the inside was 29.73%, 29.64%, and 29.68%, respectively. It can be seen that the distribution of manganese in the macroscopic sample is uniform. The current efficiency of the electrolysis process was 88.65%. The XRD pattern of the alloy shows that the phase of the alloy consists of metallic magnesium and manganese metal. Example 10

13.94 g of magnesium oxide, 82.78 g of potassium chloride, 2.80 g of manganese oxide and 60.18 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and incubated at 400 ° C for 3 hours, and then held at 700 ° C for 1.5 hours to obtain a melt containing anhydrous magnesium chloride and anhydrous manganese chloride (melt composition: KCl (82.78wt) .%)-M _g Cl ₂ (33.12 wt.%) -MnCl ₂ (4.96 wt.%)). The melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6mm spectral pure graphite rod is an anode, Φΐπιπι steel wire is a cathode, and a volume of 200 mL corundum is an electrolytic cell The electrolysis temperature is 700 °C, the pole pitch is 4 cm, the cathode current density is 5.8 A/cm ² , the cell voltage is 6.8-7.5 V, and the electrolysis time is 4 h.

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous manganese chloride was 0.05% by weight. The manganese content of the sample from the outside to the inside was 19.25%, 19.53%, and 19.61%, respectively. It can be seen that the distribution of the manganese element in the sample is uniform. The current efficiency of the electrolysis process was 86.59%. The XRD pattern of the alloy shows that the phase of the alloy consists of metallic magnesium and manganese metal. Example 11

13.94 g of magnesium oxide, 82.78 g of potassium chloride, 16.56 g of calcium chloride and 87.59 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and then incubated at 400 ° C for 1.5 hours, and then kept at 700 ° C for 1 hour to obtain a melt containing anhydrous magnesium chloride and anhydrous calcium chloride (melt composition: KCl (62.5 wt) .%)-M _g Cl ₂ (25.0 wt.%)-CaCl ₂ (12.5 wt.%)). The melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6 mm spectral pure graphite rod is an anode, Φ2ππη steel wire is a cathode, and a volume of 200 mL corundum is an electrolytic cell The electrolysis temperature is 690 ° C, the pole pitch is 4 cm, the cathode current density is 5.1 A/cm ² , the cell voltage is 6.5-8.5 V, and the electrolysis time is 3 h.

The electrolysis process and the obtained magnesium-calcium alloy were characterized according to the above measurement methods. The results are as follows:

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous calcium chloride was 0.13 wt%. The calcium content of the sample from the outside to the inside was 0.58%, 0.60%, and 0.60%, respectively, and the distribution of calcium in the sample was uniform. The elemental surface scan of the alloy is shown in Figure 8. It can be seen from the figure that magnesium and calcium are uniformly distributed in the alloy. The current efficiency of the electrolysis process was 81.2%. Figure 9 is an XRD pattern of the alloy. It can be seen from the figure that the phase of the alloy consists of metallic magnesium. Since the calcium content is less than 5%, XRD does not detect the characteristic map of calcium elemental or calcium compounds. Example 12

13.94 g of magnesium oxide, 82.78 g of potassium chloride, 5.97 g of calcium oxide and 55.94 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and incubated at 450 ° C for 1.5 hours, and then held at 700 ° C for 1.5 hours to obtain a melt containing anhydrous magnesium chloride and anhydrous calcium chloride (melt composition: KC1 (62.5 wt) .%)-M _g Cl ₂ (25.0 wt.%)-CaCl ₂ (12.5 wt.%). The melt is very pure and no impurities are observed. Then, the melt is electrolyzed in an electrolytic cell, wherein electrolysis The conditions are as follows: the melt is an electrolyte, the pure graphite rod of Φόπιπι is an anode, the steel wire of Φ2πιπι is a cathode, the corundum crucible having a volume of 200 mL is an electrolytic cell, the electrolysis temperature is 700 ° C, the pole pitch is 4 cm, and the cathode current density is 6.8 A/cm ² , cell voltage 7.2-9.4V, electrolysis time For 2.5ho

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride and anhydrous calcium chloride was 0.09 wt%. The calcium content of the sample from the outside to the inside was 0.82%, 0.81%, and 0.76%, respectively. It can be seen that the sample has a uniform distribution of calcium in the macroscopic. The current efficiency of the electrolysis process was 83.4%. The XRD pattern of the alloy shows that the phase of the alloy consists of metallic magnesium. Since the calcium content is less than 5%, XRD does not detect the characteristic map of calcium elemental or calcium compounds. Example 13

13.94 g of magnesium oxide, 82.78 g of potassium chloride, 8.28 g of zinc chloride, 16.56 g of calcium chloride and 55.94 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and then kept at 450 ° C for 1.5 hours, and then kept at 700 ° C for 1 hour to obtain a melt containing anhydrous magnesium chloride, zinc chloride and anhydrous calcium chloride (the melt composition was: KC1 (58.82 wt.%) - MgCl ₂ (23.50 wt.%) -ZnCl ₂ (5.88 wt.%) -CaCl ₂ (11.77 wt.%)). The melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, <D6 mm of a spectral pure graphite rod is an anode, Φΐπιπι is a cathode, and a volume of 200 mL of corundum is an electrolytic cell. The electrolysis temperature is 680 ° C, the pole pitch is 4 cm, the cathode current density is 4.46 A/cm ² , the cell voltage is 5.2-5.3 V, and the electrolysis time is 4.5 h.

The electrolysis process and the obtained magnesium zinc calcium alloy were characterized according to the above measurement methods. The results are as follows:

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride, anhydrous calcium chloride and anhydrous zinc chloride was 0.16 wt%. The zinc content of the sample from the outside to the inside was 33.93%, 33.85%, 33.98%, and the content of calcium was 0.83%, 0.81%, and 0.85%, respectively. It can be seen that the distribution of zinc and calcium in the sample is uniform. . The elemental surface scan of the alloy is shown in Figure 10. It can be seen from the figure that magnesium, zinc and calcium are uniformly distributed in the alloy. The current efficiency of the electrolysis process was 81.2%. Figure 11 is an XRD pattern of the alloy, it can be seen from the figure, the phase composition of the alloy, and M _g7 Zn ₃ M _g Zn ₂ composition. Since the calcium content is less than 5%, no phase of Ca is observed in the XRD pattern. Example 14

13.94 g of magnesium oxide, 82.78 g of potassium chloride, 8.28 g of zinc chloride, 5.97 g of calcium oxide and 83.91 g of ammonium chloride were mixed and added to 200 mL of mash. The lid was covered with a lid and incubated at 450 ° C for 1.5 hours, and then held at 700 ° C for 1 hour to obtain a melt containing anhydrous magnesium chloride, zinc chloride and anhydrous calcium chloride (the melt composition was: KC1 (58.82 wt.%) - MgCl ₂ (23.50 wt.%) -ZnCl ₂ (5.88 wt.%) -CaCl ₂ (11.77 wt.%)) o The melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, (D6mm spectral pure graphite rod is an anode, Φΐπιπι steel wire is a cathode, and a volume of 200 mL corundum is an electrolytic cell) The electrolysis temperature is 700 ° C, the pole pitch is 4 cm, the cathode current density is 6.69 A/cm ² , the cell voltage is 7.1-7.3 V, and the electrolysis time is 4 h.

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride, anhydrous calcium chloride and anhydrous zinc chloride was 0.14% by weight. The zinc content of the sample from the outside to the inside was 14.58%, 15.11%, 15.23%, and the content of calcium was 1.25%, 1.16%, and 1.28%, respectively. It can be seen that the distribution of zinc and calcium in the sample is uniform. . The current efficiency of the electrolysis process was 88.9%. XRD pattern of the alloy show a Zn alloy phase, and M _g7 Zn ₃ M _g ₂ composition. Since the calcium content is less than 5%, no phase of Ca is observed in the XRD pattern. Example 15

7.00 g of magnesium oxide, 73.15 g of potassium chloride, 73.15 g of lithium chloride, 1.625 g of cerium oxide, 0.33 g of calcium fluoride, 1.46 g of sodium chloride and 40.66 g of ammonium chloride were mixed and added to 200 mL of hydrazine. The lid was covered with a lid and incubated at 450 ° C for 2 hours, and then held at 630 ° C for 1.5 hours to obtain a melt containing anhydrous magnesium chloride, anhydrous lithium chloride and anhydrous cerium chloride (melt composition). For: KC1

(5076 wt.%)-MgCl ₂ (11.54 wt.%)-LiCl (35.61 wt.%)-NaCl (1.01 wt.%)-LaCl ₃ (0.85 wt.%)-CaF ₂ (0.33 wt.%)) _o The melt was very pure and no impurities were observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolytic condition is: the melt is an electrolyte, Φόπιπι The pure graphite rod of the spectrum is the anode, the steel wire of Φΐπιπι is the cathode, the graphite crucible with a volume of 200 mL is the electrolytic cell, the electrolysis temperature is 580 ° C, the pole distance is 4 cm, the cathode current density is 5.5 A/cm ² , and the cell voltage is 5.3. -7.0V, electrolysis time is 4h.

The electrolysis process and the obtained magnesium lithium niobium alloy were characterized according to the above measurement methods. The results are as follows:

The content of magnesium oxide in the electrolyte melt containing anhydrous magnesium chloride, anhydrous lithium chloride and anhydrous cesium chloride was 0.07% by weight. The lithium content of the sample from the outside to the inside was 4.49%, 4.43%, and 4.38%, respectively. The content of lanthanum was 22.74%, 22.84%, and 22.68%, respectively. It can be seen that the distribution of lithium and lanthanum elements in the sample is uniform. The elemental surface scan of the alloy is shown in Figure 12. It can be seen from the figure that magnesium, lithium and niobium are evenly distributed in the alloy. The current efficiency of the electrolysis process was 78.5%. The energy spectrum analysis of the alloy is shown in Fig. 13, wherein the energy spectrum analysis at the lower portion Figs. 1 and 2 correspond to the results of the energy spectrum analysis detected at the marks 1 and 2 in the upper graph, respectively. Since the energy spectrum analysis cannot test the lithium element, only the magnesium element and the lanthanum element can be detected. The XRD pattern of the alloy is shown in Fig. 14, and the phase of the alloy is Mg, Lio. 92Mg4.08 LaMg ₂ . Example 16

7.00 g of magnesium oxide, 73.15 g of potassium chloride, 64.44 g of lithium chloride hydrate (LiCH). 63⁄40), 1.67 g of lanthanum chloride hydrate (LaCl ₃ '4.93⁄40), 0.33 g of calcium fluoride, 1.46 g of sodium chloride After mixing with 40.66 g of ammonium chloride, it was added to 200 mL of mash. The lid was covered with a lid and then incubated at 400 ° C for 2 hours, and then held at 600 ° C for 1.5 hours to obtain a melt containing anhydrous magnesium chloride, anhydrous lithium chloride and anhydrous cerium chloride (melt composition). It is: KC1 (50.76wt.%) - MgCl ₂ (11.54wt.%) -LiCl (35.61wt.%) - NaCl (1.01wt.%) -LaCl _{3 (} 0.85wt.%) - CaF ₂ (0.33wt. %)), the melt is very pure and no impurities are observed. Then, the melt is electrolyzed in an electrolytic cell, wherein the electrolysis conditions are: the melt is an electrolyte, the spectral pure graphite rod of Φ6πιπι is an anode, the steel wire of Φΐπιπ is a cathode, and the graphite crucible having a volume of 200 mL is an electrolytic cell. The electrolysis temperature was 620 ° C, the pole pitch was 4 cm, the cathode current density was 8.3 A/cm ² , the cell voltage was 8.7-9.2 V, and the electrolysis time was 2.5 h.

The electrolysis process and the obtained magnesium lithium niobium alloy were characterized according to the above measurement methods. The results are as follows: The magnesium oxide content of the electrolyte melt containing anhydrous magnesium chloride, anhydrous lithium chloride and anhydrous cesium chloride was 0.05% by weight. The lithium content of the sample from the outside to the inside was 8.72%, 8.68%, 8.82%, and the content of lanthanum was 21.54%, 21.28%, 22.02%, respectively. It can be seen that the distribution of lithium and lanthanum elements in the sample is uniform. The current efficiency of the electrolysis process was 80.3%. The XRD pattern of the alloy showed that the phase of the alloy was Mg, Lio. 92Mg4.08 LaM _g2 .

The above are magnesium oxide and barium chloride heptahydrate, lithium chloride monohydrate, manganese chloride tetrahydrate, zinc chloride, calcium chloride, barium oxide, calcium oxide, manganese oxide, hydrated barium chloride, hydrated lithium chloride, manganese chloride as starting material, the Mg-Li was prepared by the method of the present _{_{invention, M g -La, M g -Zn}} , Mg-Mn, Mg-Ca, Mg-Zn-Ca, Mg-Li-La magnesium alloy The uniformity of the distribution of alloying elements is good, and the current efficiency during electrolysis preparation is above 80%. A person skilled in the art will appreciate that many modifications and changes can be made without departing from the scope of the invention. Such modifications and variations are intended to fall within the scope of the invention as defined by the appended claims.

Claims

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A method for electrolytically preparing a magnesium alloy using magnesium oxide as a raw material, the method comprising the following steps:

(b) heating the mixture prepared in the step (a) to a molten state to prepare an electrolyte melt containing anhydrous magnesium chloride and other metal ions in the magnesium alloy;

(c) electrolyzing the electrolyte melt prepared in the step (b) to produce the magnesium alloy.

2. The method according to claim 1, wherein in the step (a), the other metal element in the magnesium alloy is selected from one or more of the following elements: rare earth element, zinc, aluminum, manganese, lithium , calcium, zirconium, silver, antimony, bismuth, cadmium, antimony, bismuth, lead and gallium.

3. The method according to claim 1, wherein in the step (a), the chloride of the other metal element in the magnesium alloy is selected from one or more of the following chlorides: rare earth element chloride, chlorine Zinc, aluminum chloride, manganese chloride, lithium chloride, calcium chloride, zirconium chloride, silver chloride, barium chloride, barium chloride, cadmium chloride, barium chloride, barium chloride, lead chloride And gallium chloride.

4. The method according to claim 1, wherein in the step (a), the oxide of the other metal element in the magnesium alloy is selected from one or more of the following oxides: rare earth element oxide, oxidation Calcium, manganese oxide and cerium oxide.

5. The method according to claim 1, wherein in the step (a), the additive is selected from one or more of the following: CaF ₂ , KF, NaF, LiF, MgF ₂ , CaCl ₂ , BaCl ₂ and NaCl.

6. The method according to claim 1, wherein in the step (a), when a compound of another metal element in the magnesium alloy is a chloride of another metal element in the magnesium alloy, the magnesium oxide, Chloride, ammonium chloride, potassium chloride and additives of other metal elements in magnesium alloys Add in the amount as follows:

The amount of the magnesium oxide is 1.00 parts by weight;

Chlorination of other metal elements in the magnesium alloy by weight

The ammonium chloride in parts by weight: NH4CI: (2.68 + 0.08 χΖ (Α·Ο) _; by weight of the potassium chloride: _α = 1.86 + Ζ 1 · ^ χ _;

The additive of the additive in parts by weight: = Ζ 2 χ (2.38 + 5 + _α ) _;

Wherein, in the range of 0.10 to 145.00; is the weight percentage of other metal elements in the magnesium alloy; Μ is the atomic weight of other metal elements in the magnesium alloy; is the valence of the metal element in the chloride of other metal elements in the magnesium alloy ^ is the weight ratio of water to anhydrous chloride in the chloride of other metal elements in the magnesium alloy; Z1 is in the range of 0.05 to 150.00; and Ζ2 is in the range of 0.005 to 0.500.

7. The method according to claim 1, wherein in the step (a), when a compound of another metal element in the magnesium alloy is an oxide of another metal element in the magnesium alloy, the magnesium oxide, The oxides, ammonium chloride, potassium chloride and additives of other metal elements in the magnesium alloy are added in the amounts described below:

The amount of the magnesium oxide is 1.00 parts by weight;

The amount of oxides of other metal elements in the magnesium alloy in parts by weight, (M _JO +8 )

W° =0.60xZ Ammonium in weight

32.10χΖ° χη : ,

(2-68 +∑

(卜∑) ^xM

W> =1.86+ of the stated potassium in terms of weight

Z3x ;

The weight of the additive is J W = Ζ 4 χ (2.38+

„ ° (M _in + 35.5n°) .

Τ(0.60χΖ; χ ^{1 J} . ^} -) + W _K ° _Cl );

厶¹ (l-∑)x _o

Wherein, in the range of 0.05 to 100.00; other metal elements in the magnesium alloy The weight percentage of other metal elements in the magnesium alloy; the valence of the metal element in the oxide of other metal elements in the magnesium alloy; Ζ3 in the range of 0.05 to 150.00; and Ζ4 in the range of 0.005 to 0.500 Inside.

8. The method according to claim 1, wherein in the step (a), when a compound of another metal element in the magnesium alloy is a chloride and an oxide of other metal elements in the magnesium alloy, Magnesium oxide, chloride of other metal elements in the magnesium alloy, oxides of other metal elements in the magnesium alloy, ammonium chloride, potassium chloride and additives are added in the amounts described below:

The amount of the magnesium oxide is 1.00 parts by weight;

The amount of chloride of other metal elements in the magnesium alloy by weight, a- X (M _1C + 35.5η. )

W = 0.6 x Z by weight of other metal elements in the magnesium alloy

Yu (2.68 + χβ„) + .86+Ζ5·( Tw; +

The w:. = Ζ6χ (2.38+) of the additive in parts by weight

Wherein, in the range of 0.10 to 145.00; the weight percentage of other metal elements in the chloride of other metal elements in the magnesium alloy; other metal elements in the oxides of other metal elements in the magnesium alloy The atomic weight of other metal elements in the chloride of other metal elements in the magnesium alloy; other metal elements in the chloride of other metal elements in the magnesium alloy in anhydrous chloride a valence; in the range of 0.05 to 100.00; an atomic weight of other metal elements in the oxide of other metal elements in the magnesium alloy; a valence of a metal element in an oxide of other metal elements in the magnesium alloy; Is the weight ratio of water to anhydrous chloride in the chloride of other metal elements in the magnesium alloy; Ζ5 is in the range of 0.05 to 150.00; and Ζ6 In the range of 0.005 to 0.500.

9. The method according to claim 1, wherein in the step (b), the heating process is: first holding at 300-550 ° C for 0.5-3.5 hours, then holding at 400-850 ° C for 0.2-4.0 In an hour, an electrolyte melt containing anhydrous magnesium chloride and other metal ions in the magnesium alloy is obtained.

10. The method according to claim 1, wherein in the step (c), the conditions of the electrolysis are: the anode is made of a graphite material, and the cathode is made of a steel material;

400-850 °C, the electrolysis voltage is 5~10V, and the cathode current density is more than 3 A/cm ² .

The method according to claim 1, wherein the ammonium chloride released in the step (b) is recovered and returned to the step (a) for recycling, and the released ammonia gas is recycled.

The method according to claim 1, wherein the waste electrolyte melt discharged during the electrolysis of c (returning to c) is recycled to the step (a), and the generated chlorine gas is subjected to purification and recycling.