WO2014182830A1 - Hydrophilic organosilanes - Google Patents
Hydrophilic organosilanes Download PDFInfo
- Publication number
- WO2014182830A1 WO2014182830A1 PCT/US2014/037175 US2014037175W WO2014182830A1 WO 2014182830 A1 WO2014182830 A1 WO 2014182830A1 US 2014037175 W US2014037175 W US 2014037175W WO 2014182830 A1 WO2014182830 A1 WO 2014182830A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbon atoms
- group containing
- organosilane
- composition
- hydrogen
- Prior art date
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- -1 R1 Chemical group 0.000 claims description 67
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- FSIJKGMIQTVTNP-UHFFFAOYSA-N bis(ethenyl)-methyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C=C)C=C FSIJKGMIQTVTNP-UHFFFAOYSA-N 0.000 description 1
- DSVRVHYFPPQFTI-UHFFFAOYSA-N bis(ethenyl)-methyl-trimethylsilyloxysilane;platinum Chemical group [Pt].C[Si](C)(C)O[Si](C)(C=C)C=C DSVRVHYFPPQFTI-UHFFFAOYSA-N 0.000 description 1
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- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
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- 239000003086 colorant Substances 0.000 description 1
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- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 description 1
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- 125000003700 epoxy group Chemical group 0.000 description 1
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- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical compound C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 1
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- 150000002367 halogens Chemical group 0.000 description 1
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- 239000011487 hemp Substances 0.000 description 1
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
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- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 210000000050 mohair Anatomy 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229920006285 olefinic elastomer Polymers 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229920009441 perflouroethylene propylene Polymers 0.000 description 1
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- 239000013034 phenoxy resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
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- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- MMABHMIOCAINNH-UHFFFAOYSA-N pyrrole-2,5-dione;triazine Chemical compound C1=CN=NN=C1.O=C1NC(=O)C=C1.O=C1NC(=O)C=C1 MMABHMIOCAINNH-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 229920006230 thermoplastic polyester resin Polymers 0.000 description 1
- 229920006342 thermoplastic vulcanizate Polymers 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- CENHPXAQKISCGD-UHFFFAOYSA-N trioxathietane 4,4-dioxide Chemical compound O=S1(=O)OOO1 CENHPXAQKISCGD-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C07F7/1872—Preparation; Treatments not provided for in C07F7/20
- C07F7/1876—Preparation; Treatments not provided for in C07F7/20 by reactions involving the formation of Si-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/05—Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C08L101/10—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
Definitions
- These surfaces may include substrates such as fibers, textiles, plastics, glass, or metals.
- Treating the surface to render them more hydrophilic may improve properties such as moisture pick up, absorbency, surface wetting, breathability and the like. Many of the hydrophilic surface treatments are based on the physical absorption of the treatment molecules with a surface. As such, the treatments are not robust and are easily washed off or removed.
- compositions comprising an organosilane having the formula
- n 1 or 2
- a ⁇ 1 , b may vary from 0 to 30, with the proviso a ⁇ b,
- R 1 is a hydrocarbon group containing 1 to 12 carbon atoms
- R 2 is hydrogen or an alkyl group containing 1 to 6 carbon atoms
- R3 is a divalent hydrocarbon group containing 2 to 12 carbon atoms
- R 4 is hydrogen, R 1 , or an acetyl group.
- the present organosilanes, or compositions containing reaction products derived from the present organosilanes are particularly useful to treat various surfaces to render them, among other things, more hydrophilic.
- the present organosilanes and related compositions are useful to treat textiles, fibers, or hard surfaces to improve, among other properties, the hydrophilicity of the surface.
- the treated surface may have improved absorbency, moisture pick up, or surface wettability properties.
- subsequent surface treatments with the present compositions are more permanent (or substantially more permanent or semipermanent) than many treatments.
- compositions comprising an organosilane, or reaction products therefrom, having the formula
- n 1 or 2
- n 2
- R 1 is a hydrocarbon group containing 1 to 12 carbon atoms
- R 1 is an alkyl group or a phenyl group
- R 1 is methyl
- R 2 is hydrogen or an alkyl group contain 1 to 6 carbon atoms
- R 2 is methyl or ethyl
- R 2 is ethyl
- R 3 is a divalent hydrocarbon group containing 2 to 12 carbon atoms
- R 3 contains 2 to 6 carbon atoms
- R 3 is propylene, or isobutylene
- R 3 is -CH 2 CH 2 C(CH3)2- alternatively R 3 is propylene
- R 4 is hydrogen, R 1 , or an acetyl group
- R 4 is methyl
- the present organosilanes contain a polyoxyalkylene moiety which is predominately a polyoxyethylene chain as designated by (CH2CH20) a in the above formula.
- the polyoxyalkylene group comprises predominately oxyethylene units (C2H4O), but may also contain oxypropylene units (C3HgO), oxybutylene units (C4H8O), or mixtures thereof.
- the polyoxyalkylene group comprises a mixture of (C2H4O)
- the oxyalkylene groups are typically randomized with the group but can also be blocked.
- the polyoxyalkylene group comprises a majority of polyoxyethylene units, as defined on a molar basis and indicated in the above formula by the "a" subscript.
- the subscript "a” is equal to or greater than 1 ,
- a may vary from 4 to 30,
- a may vary from 4 to 20,
- a may vary from 4 to 10
- a may vary from 5 to 8
- b may vary from 1 to 30,
- a may vary from 1 to 20,
- a may vary from 10 to 20,
- a may vary from 15 to 20,
- the organosilane has the following average formula
- the organosilane has the following average formula
- the present organosilanes may be prepared by any method known in the art for preparing organosilanes, or alternatively the organosilanes may be prepared by the process as discussed below.
- the organosilane may be prepared by a process comprising reacting:
- R 1 is a hydrocarbon group containing 1 to 12 carbon atoms
- R 2 is hydrogen or an alkyl group contain 1 to 6 carbon atoms, the subscript n is 1 or 2, alternatively n is 2,
- R 4 is hydrogen, R 1 , or an acetyl group
- R5 is an unsaturated aliphatic hydrocarbon group
- Component a) is an organosilane of the formula (R 1 )( 3 _ n )(R 2 0) n SiH.
- organosilanes suitable as component a) in the present process include;
- the polyoxyalkylene useful as component b) can be any polyoxyalkylene that is terminated at one molecular chain end with an unsaturated aliphatic hydrocarbon group containing 2 to 12 carbon atoms.
- the polyoxyalkylene may result from the polymerization of ethylene oxide, propylene oxide, butylene oxide, 1 ,2-epoxyhexane, 1 , 2-epoxyoctance, cyclic epoxides such as cyclohexene oxide or exo-2,3-epoxynorborane.
- the polyoxyalkylene group comprises predominately oxyethylene units (C 2 H40), but may also contain minor amounts of oxypropylene units (C 3 HgO), oxybutylene units (C4H8O), or mixtures thereof.
- the polyoxyalkylene group comprises a majority of oxyethylene units, as defined on a molar basis and indicated in the above formula by the "a" subscript.
- the oxypropylene units are indicated in the above formula by the "b" susbscript.
- H 2 C C(CH 3 )CH 2 -
- H 2 C CHCH 2 CH 2 -
- H 2 C CHCH 2 CH 2 CH 2 -
- H 2 C CHCH 2 CH 2 CH 2 CH 2 -.
- alkynyl groups are shown by the following structures; HC ⁇ C-, HC ⁇ CCH 2 -, HC ⁇ CCH(CH 3 ) - ,
- H 2 C CHC(CH 3 ) 2 - .
- Polyoxyalkylenes having an unsaturated aliphatic hydrocarbon group at one molecular terminal are known in the art, and many are commercially available.
- H2C CHCH 2 0[C2H 4 0] a [C 3 H 6 0] b H
- H2C CHCH 2 0[C2H 4 0] a CH 3
- H 2 C CHC(CH 3 ) 2 0 [C 2 H 4 0] a CH 3
- H 2 C CHCH 2 0[C 2 H 4 0] a C(0)CH 3
- H2C C(CH 3 )CH 2 0[C2H 4 0] a H
- Polyoxyalkylenes having an unsaturated aliphatic hydrocarbon group at one molecular terminal are commercially available from numerous suppliers including; NOF (Nippon Oil and Fat, Tokyo, Japan), Clariant Corp. (Switzerland), and Dow Chemical Corp. (Midland, Ml). Commercial examples of these materials include Uniox MUS-4 from NOF, Polyglykol AM 450 from Clariant, and SF 400 and SF 443 from Dow Chemical Corp.
- the amounts of components a) and b) used in the hydrosilylation reaction may vary.
- the molar ratio of the SiH units of component a) to the aliphatic unsaturated groups of component b) may range from 10/1 to 1/10, alternatively from 5/1 to 1 /5, or alternatively from 1 /1 to 1 /2.
- the amounts of components a) and b) are selected to provide molar excess of the unsaturated groups of component b) to the SiH groups in component a).
- Component c) is a hydrosilylation catalyst.
- the hydrosilylation catalyst may be any suitable Group VIII metal based catalyst selected from a platinum, rhodium, iridium, palladium or ruthenium.
- Group VIII group metal containing catalysts useful to catalyze curing of the present compositions can be any of those known to catalyze reactions of silicon bonded hydrogen atoms with silicon bonded unsaturated hydrocarbon groups.
- the preferred Group VIII metal for use as a catalyst to effect cure of the present compositions by hydrosilylation is a platinum based catalyst.
- Some preferred platinum based hydrosilylation catalysts for curing the present composition are platinum metal, platinum compounds and platinum complexes.
- Suitable platinum catalysts are described in US 2,823,218 (commonly referred to as “Speier's catalyst) and U.S. Patent No. 3,923,705.
- the platinum catalyst may be "Karstedt's catalyst", which is described in Karstedt's U.S. Patent Nos. 3,715,334 and 3,814,730.
- Karstedt's catalyst is a platinum divinyl tetramethyl disiloxane complex typically containing about one-weight percent of platinum in a solvent such as toluene.
- the platinum catalyst may be a reaction product of chloroplatinic acid and an organosilicon compound containing terminal aliphatic unsaturation, as described in U.S. Patent No. 3,419,593.
- the hydrosilylation catalyst is a neutralized complex of platinum chloride and divinyl tetramethyl disiloxane, as described in US 5,175,325.
- the hydrosilylation catalyst may be added in an amount equivalent to as little as 0.001 part by weight of elemental platinum group metal, per one million parts (ppm) of the total reaction composition.
- concentration of the hydrosilylation catalyst in the reaction composition is that capable of providing the equivalent of at least 1 part per million of elemental platinum group metal.
- a catalyst concentration providing the equivalent of 1 to 500, alternatively 50 to 500, alternatively 50 to 200 parts per million of elemental platinum group metal may be used.
- the reaction effected in the present process is a hydrosilylation reaction, wherein the SiH units of component a) react with the unsaturated aliphatic hydrocarbon group of component b) form an Si-C bond.
- the reaction may be conducted under those conditions known in the art for effecting hydrosilylations reactions.
- the hydrosilylation reaction can be conducted neat or in the presence of a solvent.
- the solvent can be an alcohol such as methanol, ethanol, isopropanol, butanol, or n-propanol, a ketone such as acetone, methylethyl ketone, or methyl isobutyl ketone; an aromatic hydrocarbon such as benzene, toluene, or xylene; an aliphatic hydrocarbon such as heptane, hexane, or octane; a glycol ether such as propylene glycol methyl ether, dipropylene glycol methyl ether, propylene glycol n-butyl ether, propylene glycol n-propyl ether, or ethylene glycol n-butyl ether, a halogenated hydrocarbon such as dichloromethane, 1 ,1 ,1 -trichloroethane or methylene chloride, chloride
- the amount of solvent can be up to 70 weight percent, but is typically from 20 to 50 weight percent, said weight percent being based on the total weight of components in the hydrosilylation reaction.
- the solvent used during the hydrosilylation reaction can be subsequently removed from the resulting organosilane by various known methods.
- Additional components can be added to the hydrosilylation reaction which are known to enhance such reactions. These components include salts such as sodium acetate which have a buffering effect in combination with platinum catalysts.
- the present disclosure also relates to the organosilane compositions produced by the aforementioned process.
- the present organosilanes contain at least one alkoxy group, as represented by
- the present organosilanes will hydrolyze in aqueous medium, and may further condense to form oligomeric or higher molecular weight polymeric siloxanes.
- the present disclosure relates to the reaction products resulting from the hydrolysis and/or condensation of the aforementioned organosilanes.
- the present organosilanes, or subsequently produced oligomeric or polymeric siloxanes derived from the organosilanes may react with hydroxyl functional compounds or surfaces. Since the present organosilanes contain a polyalkylene oxide chain that is predominately ethylene oxide, the present organosilanes may be considered as "hydrophilic".
- the present organosilanes may be used to treat various surfaces to impart greater "hydrophilicity" to the surface.
- the reactivity of the silane moiety may allow the present compositions to bond to various surfaces to provide a longer lasting, more durable hydrophilic treatment.
- the organosilanes when compositions comprising the present organosilanes are applied to various surfaces (e.g., the surfaces of a fibers), the organosilanes can react with functional groups on the surfaces (e.g., epoxy, hydroxyl, carbinol, and ester) thereby forming a substantially permanent bond with the surface.
- the same reactions can occur when compositions comprising the present organosilanes are incorporated into (e.g., blended with) thermoplastic resins, thermoset resins, and the like, either as the resins are made or into molten resin.
- the organosilanes, or reaction products derived therefrom may be applied or incorporated neat, as an aqueous solution, as a solution in an organic solvent, or as a component in a multi-component formulation.
- additional components such as acids or bases to buffer the pH may be added to the solution that are known to enhance the hydrolysis and condensation of alkoxysilanes.
- the present organosilanes, or reaction products derived therefrom may be used to decrease the surface energy and the water contact angles of various surfaces, which is indicative of increased hydrophilicity of those surfaces.
- the organosilanes, or reaction products derived therefrom may be used to impart anti-fogging properties, water sheeting properties, higher gloss, higher surface smoothness, etc., to surfaces, including films (e.g., agricultural film and automotive window film), while maintaining high transparency.
- the treatments may be longer lasting or more durable than conventional treatments.
- the organosilanes, or reaction products derived therefrom may improve one or more of the following properties: wet out properties, dispersion properties, solubility properties, adhesion properties, mechanical properties, optical properties, surface properties, flame retardant properties, surface smoothness, may lower the coefficient of friction of a surface, etc.
- Fibers suitable for treatment include various hard surfaces such as glass, metals, plastics, minerals, and woods.
- the surfaces further include fibers, fabrics or textile surfaces.
- Fibers or textiles that can be treated with the treatment composition include natural fibers such as cotton, silk, linen, wool, flax, kapok, hemp, flax, ramie, alpaca, cashmere, mohair, sisal, abaca, jute, kenaf, camel hair, etc.; regenerated fibers such as lycocell, rayon, acetate, viscose, cupra, polynosic, high wet modulus rayon, solvent-spun cellulose, etc.; synthetic fibers such as polyesters, polyamides, polyacrylonitriles, polyolefins (e.g., polyethylenes and polypropylenes), vinylon, polyvinyl chloride, promix, fiberglass, aramids, azlons, modacrylics, novoloids, nytrils, spandex,
- polyamide refers broadly to any long-chain polymer having recurring amide groups as an integral part of the polymer chain.
- examples of polyamides include nylon 6; nylon 6,6; nylon 1 ,1 ; and nylon 6,10.
- polyester refers broadly to any long-chain polymer having recurring ester groups.
- polyesters include aromatic polyesters, such as polyethylene terephthalate (PET), polypropylene terephthalate, polybutylene terephthalate (PBT), polytrimethylene terephthalate (PTT), and polytriphenylene terephthalate, and aliphatic polyesters, such as polylactic acid (PLA) and polyglycolide and the like.
- polyolefin includes, for example, polypropylene, polyethylene, and combinations thereof.
- Polyaramid includes, for example, poly-p-phenyleneteraphthalamid (i.e., KevlarTM), poly-m-phenyleneteraphthalamid (i.e., NomexTM), and combinations thereof.
- Suitable fibers include, but are not limited to, the fibers disclosed in Published U.S. Patent Appl. Nos. 2012/0277356; 201 1/0015310; 2008/0153735; and 2002/0160675, the entireties of all of which are incorporated by reference as if fully set forth herein.
- the fiber treatment composition comprising the present organosilanes, oligomeric or polymers derived therefrom, can be applied to the fiber and/or textile during making the fibers or textiles, or later via a post application process. After application, carriers (if any) can be removed from the treatment composition for example by drying the composition at ambient or elevated temperature.
- the amount of treatment composition applied to the fibers and textiles is typically sufficient to provide 0.1 to 15 weight percent of the composition on the fibers and textiles, based on their dry weight, preferably in an amount of 0.2 to 5 weight percent based on the dry weight of the fiber or textile.
- the organosilanes, or reaction products derived therefrom may be incorporated into a variety of compositions including, but not limited to, paints and other coatings, including marine coatings and architectural coatings; inks (e.g., ink-jet printer inks); and thermoplastic and/or thermoset compositions (e.g., thermoplastic resins; thermoset resins; and rubber compounds, including thermoplastic elastomers), including thermoplastic and/or thermoset formulations that can be formed into fibers, textiles or other articles of manufacture, including films, tires, automotive parts, etc.
- paints and other coatings including marine coatings and architectural coatings
- inks e.g., ink-jet printer inks
- thermoplastic and/or thermoset compositions e.g., thermoplastic resins; thermoset resins; and rubber compounds, including thermoplastic elastomers
- thermoplastic and/or thermoset formulations that can be formed into fibers, textiles or other articles of manufacture, including films, tires, automotive parts, etc.
- thermoset resins include, but are not limited to, those commonly known in the art, such as natural rubbers, crosslinked synthetic rubbers such as polyisoprene, polybutadiene, neoprene, acryl, silicone and ester rubbers, thermosetting fluoroelastomers such as those made by crosslinking polymerized vinyl compounds such as hexafluoropropylene, vinylidene fluoride, tetrafluoroethylene, chlorotrifluoroethylene, and copolymers thereof (e.g., those manufactured under the tradename of VitonTM), or by crosslinking polymerized alkyi acrylates and/or alkyi methacrylates (hereinafter referred to as "alkyi acrylate” monomers or simply “alkyi acrylates”), such as hexafluorobutyl methacrylate, and hexafluorobutyl acrylate.
- thermoset resins include polyurethanes, epoxy resins, phenoxy resins, cyanate esters, polyimides, phenolic resins, polyphenol-formaldehyde, polymelamine-formaldehyde, polyurea-formaldehyde, bis-maleimide triazine, and crosslinked versions of poly(n-alkyl acrylates), polyesters, polyolefins, polystyrenes, polyvinyl chlorides, vinyl esters and polyamides.
- thermoplastic resins include, but are not limited to, styrene- based polymers such as polystyrene (including atactic, syndiotactic and isotactic polystyrene), halogen-substituted styrene polymers, styrene acrylonitrile copolymers, acrylonitrile-butadiene-styrene (ABS) resins, styrene-butadiene copolymers, styrene- butadiene-styrene (SBS) block copolymers, blends of styrene-acrylonitrile copolymer and ethylene-styrene interpolymer, polycarbonate/acrylonitrile-butadiene-styrene terpolymer alloys, and SEBS resins, polyacrylonitrile, condensation polymers such as polyesters including polyethylene terephthalate, polybutylene
- copolymers of styrene and substituted styrene e.g., styrene/p- methylstyrene copolymers. These copolymers can be atactic, isotactic, or syndiotactic.
- thermoplastic resins include polyacetals, polyamide-imides, polypthalamides, polyetherimides, polyformaldehydes such as DelrinTM, polyethyleneimine, poly-N-vinylcarbazole, polytetrafluoroethylene, fluorinated ethylene propylene, perfluoroalkoxy, polychlorotrifluoroethylene, ethylene tetrafluoroethylene, polyetherketone, polyether etherketone, polyether ketone ether ketone, polyoxymethylene(acetal) homopolymer copolymers, polyester urethane, polyether urethane, ethylene/vinyl acetate copolymer, copolymers of ethylene or propylene with other alpha-olefins, copolymers of acrylonitrile-butadiene-styrene (ABS), copolymers of acrylonitrile and styrene impact-modified with ethylene-propylene
- DelrinTM
- amorphous polyamide or copolymer polyamide having a Tg of above 120 5 C amorphous polyamide or copolymer polyamide having a Tg of above 120 5 C
- glycol-modified polyester amorphous polyurethanes or their blends with at least 60 wt. % of glycol-modified polyester, and impact-modified poly(methyl methacrylate).
- thermoplastic resin includes one or more copolymers selected from a-b type block copolymers, a-b-a type block copolymers, b-a-b type block copolymers, a grafted b copolymers and b grafted a copolymers, where a is a non-reactive block with a glass transition temperature or melting transition temperature higher than that of a rubbery b block.
- a is a non-reactive block with a glass transition temperature or melting transition temperature higher than that of a rubbery b block.
- many such block copolymers and blends thereof are known as thermoplastic elastomers.
- portions a of the a-b, a-b-a or b-a-b type block copolymer examples include atactic polystyrene, polymethylmethacrylate.
- portions b one or more polymers or copolymers selected from conjugated diene, hydrogenated product of conjugated diene, conjugated diene modified with acid anhydride, hydrogenated product of conjugated diene modified with acid anhydride, organopolysiloxane and polyalkylacrylate can be given along with their halogenated and partially halogenated homologs.
- portion b examples include polymers and copolymers of isoprene, butadiene, hydrogenated butadiene, hydrogenated isoprene, dimethylsiloxane, butadiene modified with maleic anhydride, hydrogenated product of butadiene modified with maleic anhydride, isoprene modified with maleic anhydride, hydrogenated product of isoprene modified with maleic anhydride, phenylmethylsiloxane, methyl-3,3,3-trifluoropropylsiloxane, n-butyl acrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, and 1 H,1 H,3H-tetrafluoropropylacrylate.
- Graft copolymers which can be used are indicated in terms of a grafted b copolymers or b grafted a copolymers.
- examples are a styrene-butadiene block copolymer rubber (SB, SBS, BSB), rubbers obtained by partially or completely hydrogenating the butadiene portion of a styrene-butadiene block copolymer (SEBS, SEB), a styrene-isoprene block copolymer rubber (SI, SIS, ISI), rubbers obtained by partially or completely hydrogenating the isoprene portion of a styrene-isoprene block copolymer (SEP, SEPS), SBS modified with maleic anhydride, SEBS modified with maleic anhydride, SEP modified with maleic anhydride and SIS modified with maleic anhydride.
- SB styrene-butadiene block copolymer rubber
- SEBS st
- elastomers include; an AABS elastomer, obtained by adding acrylonitrile and styrene to a rubber latex which has been obtained by copolymerizing butadiene and alkyl acrylate, and then graft polymerizing them, and a SBR elastomer (trade name: Metablen IP-2, produced by Mitsubishi Rayon Co., Ltd.), obtained by graft polymerizing styrene to polybutadiene.
- SBR elastomer trade name: Metablen IP-2, produced by Mitsubishi Rayon Co., Ltd.
- thermoset or thermoplastic resin or resins may be modified with supplemental additives including, but not limited to, antioxidants, coloring agents such as pigments and dyes, flame retardants, process aids, antistatic agents, impact modifiers, nucleating agents, flow aids, ignition resistant additives, coupling agents, lubricants, antiblocking agents, mold release additives, plasticizers, ultraviolet ray inhibitors, thermal stabilizers.
- supplemental additives including, but not limited to, antioxidants, coloring agents such as pigments and dyes, flame retardants, process aids, antistatic agents, impact modifiers, nucleating agents, flow aids, ignition resistant additives, coupling agents, lubricants, antiblocking agents, mold release additives, plasticizers, ultraviolet ray inhibitors, thermal stabilizers.
- the organosilanes, or reaction products derived therefrom may improve, among other things, the dispersion of one or more of the aforementioned supplemental additives.
- the thermoset or thermoplastic resin or resins may also include fillers or reinforcing agents.
- fillers and reinforcing agents can be fibrous, granular or powder in form and include, but are not limited to, fibrous components such as glass fiber, carbon fiber, alumina fiber, and granular or powder components such as silica, clay, talc, carbon black, graphite, titanium dioxide, mica, calcium carbonate, calcium sulfate, barium carbonate, magnesium carbonate, magnesium sulfate, barium sulfate, oxysulfate, tin oxide, alumina, kaolin, silicon carbide, and metal powder.
- the organosilanes, or reaction products derived therefrom may improve, among other things, the dispersion of one or more of the aforementioned fillers and/or reinforcing agents.
- PG SF-Allyl E07-Me (463.73 g; UNIOX MUS-4 from NOF Corporation) and sodium acetate (0.05 g; from Fisher Biotech) were loaded in a 2 L 3-necked round- bottomed flask (RBF) fitted with a crescent-shaped paddle stirring rod, a Claisen adaptor itself fitted with a water cooled condenser and a 250 mL additional funnel loaded with methyldiethoxylsilane (136.52 g; from Gelest, Inc), and a thermometer adaptor itself fitted with a thermal couple, all under nitrogen purge.
- the reaction mixture was heated to 60 5 C when 20 wt.% or 28 g of methyldiethoxylsilane was fed in the RBF immediately followed by the addition of 1 % Dow Corning® 2-0707 INT catalyst in IPA (-400 ⁇ _ or 6 ppm). The exotherm observed instantaneously was 18 5 C. The remaining methyldiethoxylsilane in the additional funnel was being dispensed into the RBF at -1 .21 g/min rate while temperature was set at 80 5 C and being maintained below 85 5 C throughout the addition. The second charge of 1 % Dow Corning® 2-0707 INT catalyst in IPA (-500 ⁇ _ or 7 ppm) was done after the first hour of silane addition and -5 5 C exotherm was seen.
- the product mixture was stripped for 1 h under 10-40 mmHg vacuum pressure at 90 5 C.
- the final residual SiH content measured by IR was 4 ppm at 2150 cm "1 .
- the final finished product was pressure-filtered on 20 ⁇ sized filter paper to remove sodium acetate.
- the Claisen adapter was replaced by a water cooled condenser fitted with a 250 mL round- bottomed flask.
- the set-up was connected to vacuum for stripping.
- the product mixture was stripped for 1 h under 10-20 mmHg vacuum pressure at 60 5 C.
- the final residual SiH content measured by IR was 4 ppm at 2150 cm "1 .
- the final finished product was pressure-filtered on 20 ⁇ sized filter paper to remove sodium acetate.
- PG SF-Allyl E07-OH (191 .85 g; from Dow Chemical Company) and sodium acetate (0.05 g; from Fisher Biotech) were loaded in a 500 mL 3-necked round-bottomed flask (RBF) fitted with a crescent-shaped paddle stirring rod, a Claisen adaptor itself fitted with a water cooled condenser and a 250 mL additional funnel loaded with methyldiethoxylsilane (58.67 g from Gelest, Inc), and a thermometer adaptor itself fitted with a thermal couple, all under nitrogen purge.
- the reaction mixture was heated to 60 5 C when 10 wt.% or 6 g of methyldiethoxylsilane was dispensed in the RBF immediately followed by the addition of 1 % Dow Corning® 2-0707 INT catalyst in IPA (-230 ⁇ or 8 ppm). The exotherm observed instantaneously was 7 5 C.
- the remaining methyldiethoxylsilane in the additional funnel was being dispensed into the RBF at ⁇ 0.88g/min rate while temperature was set at 67 5 C and being maintained at -75 5 C throughout the addition. When all methyldiethoxylsilane was added to the RBF, the temperature was set at 75 5 C to reflux for an hour to allow the reaction to go to completion.
- the reaction mixture was cooled down to 60 5 C and 159 ppm of residual SiH was obtained by IR at peak 2150 cm "1 .
- a second addition of 1 % Dow Corning® 2-0707 INT catalyst in IPA (-50 ⁇ or ⁇ 1 .7 ppm) was charged to the reaction mixture, however, no exotherm was detected.
- the reaction temperature was increased to 80 5 C and refluxed for an hour.
- the residual SiH was measured 126 ppm.
- the product mixture was transferred to a 1 L round-bottomed flask for rotary evaporation. Some material was stripped out while the vacuum pressure was at -3-4 mmHg and the water bath was at 80 5 C. This process lasted for two hour and the final product has 13 ppm of SiH left.
- the final product was pressure-filtered on 20 ⁇ filter paper to remove sodium acetate.
- the reaction mixture was heated to 45.6 5 C when 10 wt.% or 2 g of Dow Corning® Z-6701 Silane was dispensed in the RBF immediately followed by the addition of 1 % Dow Corning® 2-0707 INT catalyst in IPA (-60 ⁇ _ or 5 ppm). The exotherm observed instantaneously was 0.9 5 C.
- the remaining Dow Corning® Z-6701 Silane in the additional funnel was being dispensed into the RBF at -0.21 g/min rate while temperature was set at 50 5 C and being maintained at -49-51 5 C throughout the addition. When all methyldiethoxylsilane was added to the RBF, the temperature was set at 57 5 C to reflux for 2.5 hours to allow reaction gone for completion.
- the reaction mixture was cooled down to room temperature and 121 ppm of residual SiH was obtained by IR at peak 2150 cm -1 .
- extra PG SF-Allyl E07-OH (5.48 g from Dow Chemical Company) was added to the reaction mixture while holding the reaction at 57 ⁇ 1 5 C for 4.5 h, resulting in 20 ppm residual SiH.
- the Claisen adapter was replaced by a water cooled condenser fitted with a 250 mL round-bottomed flask the day after. The setup was connected to vacuum for stripping.
- the product mixture was stripped for 3 h under 10-50 mmHg vacuum pressure at 80 5 C.
- the final residual SiH content measured by IR was still 20 ppm at 2150 cm "1 .
- the final finished product was pressure-filtered on 20 ⁇ sized filter paper to remove sodium acetate.
- PG SF-Allyl E07-Ac (247.77g) and sodium acetate (0.05 g from Fisher Biotech) were loaded in a 500 mL 3-necked round-bottomed flask (RBF) fitted with a crescent- shaped paddle stirring rod, a Claisen adaptor itself fitted with a water cooled condenser and a 250 mL additional funnel loaded with Dow Corning® Z-6701 Silane (52.98 g), and a thermometer adaptor itself fitted with a thermal couple, all under nitrogen purge.
- the reaction mixture was heated to 47 5 C when 10 wt.% or 5 g of Dow Corning® Z-6701 Silane was dispensed in the RBF immediately followed by the addition of 1 % Dow Corning® 2-0707 INT catalyst in IPA (-270 ⁇ or 8 ppm). The exotherm observed instantaneously was 1 -2 5 C.
- the remaining Dow Corning® Z-6701 Silane in the additional funnel was being dispensed into the RBF at -0.79 g/min rate while temperature was set at 54 5 C and being maintained below 58 5 C throughout the addition.
- Corning® Z-6701 Silane was added to the RBF, the temperature was set at 54 5 C to reflux for an hour to allow reaction gone for completion. 540 ppm of residual SiH was obtained by IR at peak 2150 cm "1 . Another hour of reflux was proceeded and the residual SiH was measured 300 ppm.
- the Claisen adapter was replaced by a water cooled condenser fitted with a 250 mL round-bottomed flask. The set-up was connected to vacuum for stripping. The product mixture was stripped for a total of 3 h under 20-80 mmHg vacuum pressure at 62 5 C. The final residual SiH content measured by IR was 28 ppm at 2150 cm "1 . The final finished product was pressure-filtered on 20 ⁇ sized filter paper to remove sodium acetate.
- a syringe pump (Model: Cole Parmer 74900 series) was utilized since it could be programmed to dispense liquid at a constant rate and the syringe was filled with Dl water. The time for the circle area to fill with liquid by spreading was recorded. It should be recognized that some of the add-on weight to the cloth could include silane + residual moisture that was not removed during the drying process. The results from these tests are summarized below in Table 1 .
- the remaining methyldimethoxysilane is added from the addition funnel at a rate so that the temperature of the mixture remains below 50°C.
- the reaction vessel is maintained at 50° ⁇ 3°C for 3 hours.
- the volatiles are removed from the product by increasing the flow of N2 through the reaction vessel. A low viscosity liquid is obtained.
- a reactor includes a plurality of reactors, such as in a series of reactors.
- the term “or” is used to refer to a nonexclusive or, such that "A or B” includes “A but not B,” “B but not A,” and “A and B,” unless otherwise indicated.
- substantially refers to a majority of, or mostly, as in at least about 50%, 60%, 70%, 80%, 90%, 95%, 96%, 97%, 98%, 99%, 99.5%, 99.9%, 99.99%, or at least about 99.999% or more.
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US10428229B2 (en) | 2017-12-28 | 2019-10-01 | Industrial Technology Research Institute | Aqueous coating material and method for manufacturing the same |
US11760841B2 (en) | 2018-12-21 | 2023-09-19 | Dow Silicones Corporation | Silicone-polycarbonate copolymer, sealants comprising same, and related methods |
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Also Published As
Publication number | Publication date |
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TWI601738B (en) | 2017-10-11 |
US20160122478A1 (en) | 2016-05-05 |
JP2016526061A (en) | 2016-09-01 |
EP2994475B1 (en) | 2018-09-05 |
KR20160030092A (en) | 2016-03-16 |
US10011687B2 (en) | 2018-07-03 |
TW201502131A (en) | 2015-01-16 |
JP6440688B2 (en) | 2018-12-19 |
CN105339373A (en) | 2016-02-17 |
EP2994475A1 (en) | 2016-03-16 |
KR102223256B1 (en) | 2021-03-09 |
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