WO2014175345A1 - Wire rod and method for manufacturing same - Google Patents
Wire rod and method for manufacturing same Download PDFInfo
- Publication number
- WO2014175345A1 WO2014175345A1 PCT/JP2014/061460 JP2014061460W WO2014175345A1 WO 2014175345 A1 WO2014175345 A1 WO 2014175345A1 JP 2014061460 W JP2014061460 W JP 2014061460W WO 2014175345 A1 WO2014175345 A1 WO 2014175345A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- wire
- temperature
- pearlite
- particle size
- finish rolling
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/613—Gases; Liquefied or solidified normally gaseous material
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0075—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rods of limited length
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/525—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length for wire, for rods
Definitions
- the present invention mainly relates to a wire rod having excellent low-temperature ductility and low-temperature toughness, which is a PC steel stranded wire for reinforcing a PC structure used in an LNG (liquefied natural gas) tank of an energy-related facility.
- a wire rod having excellent low-temperature ductility and low-temperature toughness which is a PC steel stranded wire for reinforcing a PC structure used in an LNG (liquefied natural gas) tank of an energy-related facility.
- the present invention relates to a wire for terrestrial LNG and a method for manufacturing the same.
- a conventional technique of the above ground type LNG tank there is a so-called metal double shell type LNG tank provided with a metal inner tank and an outer tank proposed in Patent Document 1 and the like.
- a gap between the inner tank and the outer tank is usually filled with a cooling agent to suppress the temperature rise in the LNG tank and the accompanying LNG vaporization.
- this structure has a possibility of causing damage such as a large amount of LNG flowing out when defects occur in the inner tank and the outer tank at the same time.
- a PC breakwater equipped with a PC structure Prestressed Concrete Structure
- the inside of the PC liquid breakwater is connected to a conventional metal secondary wall.
- the PC breakwater in this technology includes concrete that forms a circular bank surrounding the LNG tank, and PC steel strands embedded in the concrete. Prestress is applied to the PC breakwater by tensioning the concrete along the circumferential direction using PC steel strands.
- Prestress is applied to the PC breakwater by tensioning the concrete along the circumferential direction using PC steel strands.
- tensile stress is applied to the PC breakwater in the circumferential direction due to the fluid pressure of the LNG that flows out, but prestress is applied to the PC breakwater. If given, this tensile stress is relaxed.
- an object of the present invention is to provide a wire rod having a low temperature ductility and a low temperature toughness superior to those of conventional PC steel stranded wires.
- the present inventors conducted a survey on the actual environment of the PC breakwater usage environment. It was. As a result, it was found that in an actual use environment, the wire may be exposed to an ambient temperature of around ⁇ 40 ° C. due to heat transfer to the LNG inside the LNG tank.
- the gist of the present invention aimed at solving the above-mentioned problems is as follows.
- the wire according to one embodiment of the present invention has a component composition of mass%, C: 0.60 to 1.20%, Si: 0.30 to 1.30%, Mn: 0.30 to 0 90%, P: 0.020% or less, S: 0.020% or less, N: 0.0025 to 0.0060%, Cr: 0 to 1.00%, and V: 0 to 0.800% And further containing one or more of Al: 0.005 to 0.100%, Ti: 0.003 to 0.050%, B: 0.0005 to 0.0040%, and the balance
- the pearlite has an average value of the particle size of the pearlite block in the cross section perpendicular to the wire axis direction and not smaller than 23 ⁇ m and the particle size of 40 ⁇ m or more in the cross section perpendicular to the wire axis direction.
- the number density of blocks is 0 to 20 pieces / mm 2 .
- the component composition is 1% or 2 out of Cr: 0.10 to 1.00% and V: 0.005 to 0.800% in mass%. It may contain seeds.
- the component composition is C: 0.70-0.90%, Si: 0.80-1.30%, Mn: 0.60-0 in mass%. .90%, and V: 0 to 0.500%.
- the component composition is one or two of Cr: 0.50 to 1.00% and V: 0.300 to 0.500% by mass%. It may contain.
- a method for producing a wire according to another aspect of the present invention comprises a method of rough rolling by heating a steel slab having the component composition described in (3) or (4) above to a rough rolling temperature of 950 to 1040 ° C.
- a step of performing blast cooling to room temperature, and the finish rolling temperature and strain rate in the wire finish rolling satisfy the following formula A.
- a PC steel stranded wire suitable for use as a tension member for a PC liquid barrier in a PC-type LNG tank due to a reduction in the particle size of the pearlite block and a limitation on the number density of the coarse pearlite block. It is possible to provide a wire rod that has better ductility and toughness in the vicinity of ⁇ 40 ° C. than the conventional wire rod.
- the wire for a PC steel stranded wire excellent in low temperature ductility and low temperature toughness according to this embodiment has a component composition of mass%, and C: 0.60 to 1.20%, Si: 0.30 to 1.30%, Mn: 0.30 to 0.90%, P: 0.020% or less, S: 0.020% or less, N: 0.0025 to 0 .0060%, Cr: 0 to 1.00%, and V: 0 to 0.800%, Al: 0.005 to 0.100%, Ti: 0.003 to 0.050%, B: Contains one or more of 0.0005 to 0.0040%, the balance is Fe and impurities, and the average value of the particle size of the pearlite block in the cross section perpendicular to the wire axis direction is 23 ⁇ m or less. Yes, in the cross section perpendicular to the wire axis direction, the particle size of 40 ⁇ m or more The pearlite block has a number density of 0
- % means mass%.
- C (C: 0.60 to 1.20%) C is an element that has the effect of increasing the cementite fraction in the wire and thereby increasing the strength of the wire.
- the lamella spacing of the pearlite can be controlled, and the strength of the wire can be increased by processing.
- the C content is less than 0.60%, even if the above-mentioned patenting conditions are adjusted, it is impossible to obtain a strength that can sufficiently tension the PC liquid bank of the PC type LNG tank.
- the C content of the wire exceeds 1.20%, network-like cementite is generated in the metal structure of the wire. Due to this mesh-like cementite, wire breakage frequently occurs during wire drawing, which may hinder wire production activities.
- a method for manufacturing a wire according to the present embodiment either a DLP (Direct in-Line Patenting) method or a Stemmore method can be adopted.
- the C content is preferably 0.70 to 0.90%.
- the lower limit value of the C content is preferably set to 0.70%. Further, if the C content is excessively increased, the wire becomes hypereutectoid steel (steel having a structure in which pearlite and cementite coexist), so that in the process of cooling the wire, the proeutectoid cementite is formed in the prior austenite grain size. To form. This network-like pro-eutectoid cementite significantly reduces the wire drawing workability of the wire. In order to avoid precipitation of network-like pro-eutectoid cementite, the upper limit value of the C content is preferably set to 0.90%. The C content is more preferably 0.80 to 0.90%.
- Si 0.30 to 1.30%)
- Si is an element that acts as a deoxidizing element during refining. This deoxidation effect is sufficiently exhibited when 0.30% or more of Si is contained. Therefore, the lower limit value of the Si content of the wire according to this embodiment is 0.30%.
- Si also has the effect of improving the strength of the wire, but this strength improvement effect is manifested when 0.80% or more of Si is contained. Therefore, it is good also considering the lower limit of Si content of the wire concerning this embodiment as 0.80%.
- Si strengthens the solid solution of ferrite, but has the effect of raising the nose of isothermal transformation during heat treatment, so an excessive amount of Si increases the cost of heat treatment. Therefore, considering the capacity of the production facility, the upper limit of the Si content is set to 1.30%.
- the Si content is 0.80 to 1.30%. It is preferable to do.
- the lower limit value of the Si content is preferably set to 0.80%.
- the Si content is more preferably 0.90 to 1.25%.
- Mn is a solid solution strengthening element and has the effect of improving the ductility and toughness of the wire and the effect of improving the hardenability.
- Mn In order to ensure the ductility and toughness of the wire, it is necessary to contain 0.30% or more of Mn.
- the lower limit value of the Mn content may be 0.60%.
- the Mn content exceeds 0.90%, a transformation delay occurs in the central portion of the wire during the production of the wire, and micro martensite is generated in the untransformed austenite portion. The micro martensite at the center of the wire causes breakage during wire drawing of the wire. Therefore, the upper limit of the Mn content needs to be 0.90%.
- the Mn content is 0.60 to 0.90%. It is preferable that When manufacturing a wire using a Stealmore method, the cooling rate of a wire becomes slower than the time of manufacture by a DLP method, and the ductility and toughness of a wire become comparatively low. In order to compensate for this decrease in strength, the lower limit value of the Mn content is preferably 0.60%. The Mn content is more preferably 0.70 to 0.90%.
- the S content exceeds 0.020%, this decrease in low temperature ductility becomes significant, so the S content is set to 0.020% or less.
- the upper limit of S content as 0.010%, 0.005%, or 0.001%.
- the P and S contents are preferably as low as possible. Therefore, the lower limit of the contents of P and S is 0%.
- N is an element that combines with Al, Ti, and B to form a nitride. Since these nitrides become austenite precipitation nuclei, the austenite grain size can be controlled when the steel is heated by controlling the number of these nitrides. As the amount of nitride increases, the crystal grains become finer. If the N content is less than 0.0025%, nitrides are not sufficiently formed, and the effect of refining the particle size cannot be sufficiently obtained. On the other hand, if the N content exceeds 0.0060%, free N that does not bind to Al, Ti, and B becomes excessive. Due to this excessive free N, age hardening occurs, and the ductility and toughness of the wire are lowered. Therefore, the N content needs to be 0.0025 to 0.0060%. Preferably, the N content is 0.0025 to 0.0040%.
- the wire according to this embodiment is one of Al: 0.005 to 0.100%, Ti: 0.003 to 0.050%, and B: 0.0005 to 0.0040%. Or 2 or more types are further contained.
- Al acts as a deoxidizer during steel refining. Further, Al has a function of forming a compound with N in steel and fixing N. By fixing N, age hardening of steel can be prevented. Furthermore, when it contains B simultaneously, the amount of solid solution B can be increased by fixing N.
- the Al content is less than 0.005%, the effect of fixing N by Al cannot be sufficiently obtained.
- the Al content exceeds 0.100%, Al 2 O 3 produced by combining with oxygen in the steel forms clusters. This cluster becomes a starting point of cracking during wire drawing. Therefore, the Al content may be 0.005 to 0.100%.
- the Al content is 0.020 to 0.050%.
- Ti acts as a steel deoxidizer. Further, Ti forms a compound with N in the steel and has an action of fixing N. By fixing N, age hardening of steel can be prevented. Furthermore, when it contains B simultaneously, the amount of solid solution B can be increased by fixing N.
- the Ti content is less than 0.003%, the effect of fixing N by Ti cannot be sufficiently obtained.
- the Ti content exceeds 0.050%, TiC generated by combining with carbon in the steel increases. This TiC becomes a starting point of cracking during wire drawing. Therefore, the Ti content may be 0.003 to 0.050%.
- the Ti content is 0.020 to 0.040%.
- Al and Ti have the same effect. Therefore, the amount of Al added can be reduced by adding Ti, and the same effect can be obtained in this case.
- B when present as a solid solution B in austenite, has the effect of improving the hardenability of the wire. If the B content is less than 0.0005%, the effect of improving hardenability cannot be sufficiently obtained. On the other hand, if the B content exceeds 0.0040%, B forms a compound with Fe and C, and precipitates such as Fe 23 (C, B) 6 are formed. This precipitate becomes a starting point of cracking during wire drawing. Therefore, the B content may be 0.0005 to 0.0040%. Preferably, the B content is 0.0009 to 0.0030%.
- the wire according to the present embodiment may further contain Cr: 0 to 1.00%, V: 0 to 0.800% in mass%.
- the inclusion of Cr is not essential. Therefore, the lower limit of the Cr content is 0%.
- Cr has the effect of increasing the strength of the wire by reducing the lamella spacing of the pearlite. This action increases the strength of the wire during wire drawing. Since this effect is obtained when the Cr content is 0.10% or more, the Cr content is preferably set to 0.10% or more. Moreover, when improving an intensity
- the upper limit of the Cr content is preferably 1.00%.
- the Cr content is set to 0.50 to 1.00%. More preferably.
- the cooling rate of the wire becomes slower than in the case of manufacturing by the DLP method, and the ductility and toughness of the wire become relatively low.
- the lower limit of the Cr content is more preferably 0.5%.
- the Cr content is more preferably 0.50 to 0.90%.
- V (V: 0 to 0.800%)
- the inclusion of V is not essential. Therefore, the lower limit of the V content is 0%.
- V is an element that combines with C and precipitates as a carbide in ferrite. By precipitation of this carbide, the ferrite is hardened, and the strength of the wire can be increased. This effect is obtained when V is contained in an amount of 0.005% or more.
- the V content exceeds 0.800%, coarse carbides precipitate. This coarse carbide becomes a starting point of cracking when the wire is processed. Therefore, the V content is preferably 0.005% or more and 0.800% or less.
- the DLP method or the Stemmore method can be adopted.
- the V content is 0.300 to 0.500%. More preferably.
- the cooling rate of the wire becomes slower than in the case of manufacturing by the DLP method, and the ductility and toughness of the wire become relatively low.
- the lower limit value of the V content is more preferably 0.300%.
- a microcrack void is formed in the base metal interface part of VC deposit when it receives a processing strain, it is more preferable to make the upper limit of V content into 0.500%.
- the V content is more preferably 0.300 to 0.400%.
- the balance of the component composition of the wire according to this embodiment is made of Fe and impurities.
- Impurities are raw materials such as ore or scrap, or components mixed in due to various factors in the manufacturing process when manufacturing steel materials industrially, and have an adverse effect on the characteristics of the wire according to this embodiment. It means what is allowed in the range.
- the pearlite block grain boundary is defined as a boundary between two adjacent pearlites having an orientation difference of 9 degrees or more, and the pearlite block is defined as a region surrounded by the pearlite block grain boundary.
- PBS perlite block particle size
- the average PBS (pearlite block particle size) in a cross section perpendicular to the wire axis direction is set to 23 ⁇ m or less.
- the wire according to this embodiment needs to have an aperture value of 30% or more.
- a drawing value of 30% or more is necessary in order to prevent disconnection during wire drawing in wire drawing.
- FIG. 1 shows that when the average PBS (pearlite block particle size) is 23 ⁇ m or less, an aperture value of 30% or more can be obtained.
- the average PBS pearlite block particle size
- the branching frequency of the crack tip decreases. Since the branching at the crack tip has an effect of suppressing crack propagation, the frequency of branching at the crack tip decreases, so that the fracture surface unit becomes large, and the low temperature ductility and low temperature toughness are lowered. Therefore, the average PBS (perlite block particle size) is 23 ⁇ m or less. Preferably, the average pearlite block particle size is 18 ⁇ m or less.
- the average PBS in the cross section perpendicular to the axial direction of the wire in the present embodiment is obtained by the following procedure. First, (1) surface layer portion (region having a depth of 30 ⁇ m from the surface of the wire), (2) 1 / 4D portion (depth from the surface of the wire to 1 ⁇ 4 of the diameter D of the wire) in the cross section perpendicular to the axial direction of the wire Area), (3) center part, (4) 3 / 4D part (area of 3/4 depth of wire diameter D from the surface of the wire.
- the average value is measured using an EBSD device.
- an average value (secondary average value) of each primary average value is calculated. This secondary average value is the average PBS in a cross section perpendicular to the axial direction of the wire in the present embodiment.
- the number density of pearlite blocks having a particle diameter of 40 ⁇ m or more in the cross section perpendicular to the wire axis direction is 0 to 20 / mm 2
- the pearlite block particle size is 40 ⁇ m or more in the cross section perpendicular to the wire axis direction.
- the number density of pearlite blocks is set to 0 to 20 pieces / mm 2 .
- the pearlite block having a particle size of 40 ⁇ m or more serves as a starting point of fracture, even if the number is small, the ductility and toughness of the wire are lowered.
- the wire according to the present embodiment in addition to controlling the average value of the pearlite block particle size as described above, it is also necessary to suppress the generation of coarse pearlite blocks. For this reason, the number density of coarse pearlite blocks is limited.
- the “pearlite block having a particle size of 40 ⁇ m or more” may be referred to as “coarse pearlite block” or “coarse PB”.
- the ductility and toughness of the wire do not satisfy the required level. Therefore, it is necessary to limit the number density of coarse pearlite blocks in a cross section perpendicular to the wire axis direction to 20 pieces / mm 2 or less.
- the upper limit of the number density of coarse pearlite blocks in a cross section perpendicular to the axial direction of the wire is 18 / mm 2 . Since the number of coarse pearlite blocks is preferably small, the lower limit of the number density of coarse pearlite blocks in the cross section perpendicular to the wire axis direction is 0 / mm 2 .
- the number density of pearlite blocks having a particle size of 40 ⁇ m or more within an arbitrary viewing angle can be obtained at an arbitrary position in a cross section perpendicular to the axial direction of the wire.
- the number density of pearlite blocks having a pearlite block particle size of 40 ⁇ m or more in a cross section perpendicular to the wire axis direction is obtained by the following procedure.
- (1) surface layer portion region having a depth of 30 ⁇ m from the surface of the wire
- (2) 1 / 4D portion depth from the surface of the wire to 1/4 of the diameter D of the wire) in a cross section perpendicular to the axial direction of the wire Area
- (3) center portion (4) 3 / 4D portion (from the surface of the wire to a region of a depth of 3/4 of the diameter D of the wire, ie, on the opposite side of (2) with respect to the wire center portion) Region), and (5) a particle size of 40 ⁇ m or more within a viewing angle of 300 ⁇ m ⁇ 180 ⁇ m at each of five locations consisting of the surface layer portion on the opposite side (that is, the region on the opposite side of (1) with respect to the wire rod central portion).
- the number density of the pearlite block is measured using an EBSD device. Next, the average value of the number density at each location is calculated. This average value is the number density of pearlite blocks having a particle diameter of 40 ⁇ m or more in the cross section perpendicular to the axial direction of the wire in the present embodiment.
- DLP Direct in-Line Patenting
- Stealmore method As a method for manufacturing the wire according to the present embodiment, there is a DLP (Direct in-Line Patenting) method and a Stealmore method.
- the finish rolling temperature and the strain rate must satisfy the relationship of the following formula 1. 13.7 ⁇ log 10 ⁇ (d ⁇ / dt) ⁇ exp (63800 / (1.98 ⁇ (T + 273.15))) ⁇ ⁇ 16.5 (Formula 1)
- d ⁇ / dt represents the strain rate in the wire finish rolling in the unit s ⁇ 1
- T represents the finish rolling temperature in the unit ° C.
- the steel slab further contains one or two of Cr: 0.50 to 1.00% and V: 0.300 to 0.500% by mass%. May be.
- Component composition of steel slabs for rough rolling within the above specified range
- the component composition of the steel slab used for rough rolling needs to be in the above-mentioned specified range.
- This specified range is narrower than the specified range described above as the component composition of the wire according to the present embodiment.
- the Stemmore method is a manufacturing method that performs blast cooling after winding, and the cooling rate by blast cooling is slower than the cooling rate of direct heat treatment with molten salt in the DLP method described later. When the cooling rate is low, the ductility and toughness of the finally obtained wire are relatively low.
- the wire according to the present embodiment is manufactured by the Stemmore method
- C, Mn, and Si which are alloy elements for improving ductility and toughness
- Cr and V are included to improve the properties of the wire
- Cr and V are also subjected to direct heat treatment with molten salt in the DLP method. It is preferable to contain relatively more than the case.
- the heating temperature (rough rolling temperature) of the steel slab before being subjected to rough rolling is set to 950 to 1040 ° C.
- the heating temperature of the steel slab before rough rolling is set to 950 ° C. or higher.
- AlN aluminum nitride
- the heating temperature of the steel slab before rough rolling exceeds 1040 ° C.
- solutionization of aluminum nitride (AlN) precipitated in the steel slab proceeds excessively.
- AlN serves as austenite precipitation nuclei and contributes to refinement of the austenite crystal grain size.
- the particle size of the austenite of the wire rod can be reduced.
- the solution of AlN proceeds excessively, the austenite crystal grain size increases. In this case, the PBS of the wire becomes coarse when the wire is manufactured later.
- the average value of the particle size of the pearlite block is more than 23 ⁇ m, and / or the number density of the pearlite block having the particle size of 40 ⁇ m or more is more than 20 / mm 2.
- the heating temperature of the steel slab before rough rolling is set to 1040 ° C. or less.
- the wire finish rolling is performed in a temperature range of 750 to 900 ° C.
- the temperature of the wire finish rolling (finish rolling temperature) is less than 750 ° C.
- an increase in the roll reaction force during rolling may cause equipment trouble such as roll breakage. °C or more.
- the temperature of the wire finish rolling exceeds 900 ° C., the austenite crystal grain size becomes coarse.
- the average value of the particle size of the pearlite block is more than 23 ⁇ m, and / or the number density of the pearlite block having the particle size of 40 ⁇ m or more is more than 20 / mm 2. .
- the ductility of the wire deteriorates due to the coarsening of the pearlite block.
- the wire finishing rolling temperature is set to 900 ° C. or less.
- the strain rate d ⁇ / dt of the wire during the finish rolling of the wire can be obtained by the following equation.
- d ⁇ / dt ⁇ ⁇ 2 ⁇ ⁇ ⁇ (N / 60) ⁇ L d (Formula 3)
- ⁇ ln (h2 / h1)
- L d (r / ⁇ h) 1/2
- ⁇ h h1-h2
- ⁇ is a strain amount in the finish rolling of the wire rod, and is a dimensionless number.
- H1 indicates the diameter of the wire before the wire finish rolling in unit mm
- h2 indicates the diameter of the wire after the wire finish rolling in unit mm
- N indicates the number of rotations of the roll for performing the wire finish rolling in the unit of rpm.
- L d indicates the projected contact length in the unit mm in the wire finishing rolling. The projected contact length is the length along the rolling direction of the region where the roll and the material to be rolled (wire) are in contact during rolling.
- r represents the roll radius in the unit mm in the wire finishing rolling.
- ⁇ h represents the amount of reduction in unit mm in the wire finish rolling.
- the strain rate is a rolling condition related to both the rolling rate and the rolling reduction.
- the upper limit value of log 10 Z is set to 16.5.
- log 10 Z is preferably 14.0 to 16.0.
- the average value of the particle size of the pearlite block exceeds 23 ⁇ m and / or the number density of the pearlite block having the particle size of 40 ⁇ m or more in the cross section perpendicular to the wire axis direction. Is over 20 pieces / mm 2 .
- the wire finish rolling speed is not particularly limited as long as log 10 Z is in the range of 13.7 to 16.5.
- the wire rod finish rolling speed is preferably 15.5 to 25.2 m / sec.
- the speed of the wire finish rolling is less than 15.5 m / sec, the strain rate decreases.
- the PBS may not be made sufficiently small.
- the wire finishing rolling speed is preferably 15.5 m / sec or more.
- the wire finish rolling speed exceeds 25.2 m / sec, heat generation during processing increases, and the austenite crystal grain size may become coarse. Also in this case, the PBS cannot be miniaturized.
- the wire finish rolling speed is set so that the log 10 Z is in the range of 13.7 to 16.5. It is necessary to change appropriately from the range of.
- the pearlite block particle diameter of the finally obtained wire cannot be adjusted to 23 ⁇ m or less, and / or the number density of pearlite blocks having a particle diameter of 40 ⁇ m or more is more than 20 / mm 2 .
- the winding temperature is set to 840 ° C. or lower.
- the winding temperature is preferably 750 to 820 ° C.
- the wound wire is cooled to room temperature by blast cooling.
- the room temperature basically indicates a temperature range of 5 to 35 ° C. as defined in JIS Z 8703.
- the cooling rate is less than 15 ° C./second (ie, slow cooling)
- the austenite particle size becomes large
- the average value of the particle size of the pearlite block in the cross section perpendicular to the wire axis direction becomes more than 23 ⁇ m
- the number density of the pearlite blocks having the particle diameter of 40 ⁇ m or more is more than 20 / mm 2 .
- the cooling rate during blast cooling is set to 15 ° C./second or more.
- the cooling rate at the time of blast cooling is preferably 25 ° C./second or more. Although it is not necessary to define the upper limit value of the cooling rate at the time of blast cooling, the upper limit value is about 50 ° C./second in consideration of the facility capacity.
- (1) component composition is mass%, C: 0.60 to 1.20%, Si: 0.30 to 1.30%, Mn: 0 .30 to 0.90%, P: 0.020% or less, S: 0.020% or less, N: 0.0025 to 0.0060%, Cr: 0 to 1.00%, and V: 0 to 0 800%, Al: 0.005 to 0.100%, Ti: 0.003 to 0.050%, B: 0.0005 to 0.0040%, or one or more of them
- the steel slab containing the composition containing Fe and impurities in the balance is heated to 950 to 1040 ° C., and then wire rolling is performed.
- Winding is performed in a temperature range of 750 to 800 ° C.
- heat treatment is directly performed with molten salt at 500 to 600 ° C.
- the steel slab as the raw material is in mass%, Cr: 0.10 to 1.00%, and V: 0.005 to 0.800%. One or two of them may be further contained.
- Component composition of steel slab used for wire rod rolling within the above-mentioned specified range
- the component composition of the steel slab used for wire rolling needs to be in the above-mentioned specified range.
- This specified range is the same as the specified range described above as the component composition of the wire according to the present embodiment.
- the production method by the DLP method has an advantage that a wire having excellent ductility and toughness can be obtained from a steel piece having relatively few alloy elements for improving ductility and toughness.
- a direct heat treatment with a molten salt is essential in the production method by the DLP method, more equipment is required for carrying out this production method than in the production method by the Stemmore method.
- Heating temperature for wire rolling 950-1040 ° C
- the heating temperature of the steel slab before wire rod rolling is set to 950 to 1040 ° C.
- the heating temperature before wire rod rolling is set to 950 ° C. or higher.
- the heating temperature before the wire rod rolling exceeds 1040 ° C.
- the solution of aluminum nitride (AlN) precipitated in the steel slab proceeds, the austenite crystal grain size increases, and finally obtained.
- the average value of the particle sizes of the pearlite blocks in the cross section perpendicular to the wire axis direction is more than 23 ⁇ m, and / or the number density of the pearlite blocks having a particle size of 40 ⁇ m or more is more than 20 / mm 2 .
- the heating temperature before wire rod rolling is set to 1040 ° C. or lower.
- the heating temperature before wire rolling is preferably 980 to 1030 ° C.
- the finishing temperature in wire rod rolling is not particularly limited, and a reasonable temperature can be appropriately selected.
- the winding temperature after wire rolling is set to 750 to 800 ° C.
- the coiling temperature is less than 750 ° C.
- the variation in the tensile strength in the longitudinal direction of the wire increases after the constant temperature transformation in the subsequent constant temperature transformation treatment step. Accordingly, the winding temperature is set to 750 ° C. or higher.
- the coiling temperature exceeds 800 ° C., the austenite particle size increases.
- the pearlite block particle diameter of the finally obtained wire cannot be adjusted to 23 ⁇ m or less, and the number density of pearlite blocks having a particle diameter of 40 ⁇ m or more cannot be adjusted to 20 pieces / mm 2 or less.
- the winding temperature is set to 800 ° C. or lower.
- Constant temperature transformation treatment method direct heat treatment
- Constant temperature transformation treatment temperature 500-600 ° C
- the wire is wound up and immediately immersed in a molten salt at 500 to 600 ° C. to perform a constant temperature transformation treatment.
- the isothermal transformation temperature is less than 500 ° C.
- a lot of non-pearlite structure is generated in the surface layer portion of the wire.
- unevenness of processing strain occurs at the interface between the pearlite structure generated inside the wire and the non-pearlite structure of the surface part of the wire, and this non-uniformity causes breakage at the wire drawing stage. There is. Therefore, the temperature of the isothermal transformation treatment is set to 500 ° C.
- the isothermal transformation temperature exceeds 600 ° C., operational problems such as increased thermal deformation of the equipment occur. Therefore, the isothermal transformation temperature is set to 600 ° C. or less. Moreover, this isothermal transformation process needs to be performed by direct heat treatment (on-line heat treatment). If direct heat treatment is not performed (that is, isothermal transformation is performed by off-line heat treatment), ⁇ grains grow by the reheating step included in off-line heat treatment. This phenomenon prevents the particle diameter of the PBS of the wire rod from being controlled to 23 ⁇ m or less.
- the conditions at the time of creating the examples are condition examples adopted to confirm the feasibility and effects of the present invention, and the present invention is not limited to these condition examples.
- the present invention can adopt various conditions as long as the object of the present invention is achieved without departing from the gist of the present invention.
- molten steel having the composition shown in Table 1-1 was continuously cast into a 300 mm ⁇ 500 mm slab, and this slab was then rolled into 122 mm square steel slabs by split rolling. Thereafter, the steel slab was heated at the heating temperature shown in Table 1-2, and the steel slab was rolled under the conditions shown in Table 1-2 to obtain a 12 mm ⁇ wire rod. The radius of the roll at the time of wire-finishing rolling was 75.5 mm.
- No. S1 to S16 are invention examples that satisfy the conditions of the present invention.
- S17 to S41 are comparative examples that do not satisfy the conditions of the present invention.
- the tensile test piece shown in FIG. 3 was manufactured from the rolled wire. Tensile strength and ductility of the wire at ⁇ 40 ° C. were measured by conducting a tensile test on the tensile test piece in a low temperature atmosphere of ⁇ 40 ° C. while adjusting the temperature with dry ice and alcohol. Furthermore, a Charpy impact test piece defined in JISZ2202 was collected from the wire by the sampling method shown in FIG. 4 to produce a 2 mm U notch Charpy impact test piece of 5 mm subsize. By performing a Charpy impact test at ⁇ 40 ° C. on these Charpy impact test pieces, the impact value of the wire at a temperature of ⁇ 40 ° C., which is close to the actual use environment temperature of the PC liquid barrier in the LNG tank, was obtained.
- the average PBS (pearlite block particle size) of the wire was obtained by the following procedure. First, (1) surface layer portion (region having a depth of 30 ⁇ m from the surface of the wire), (2) 1 / 4D portion (depth from the surface of the wire to 1 ⁇ 4 of the diameter D of the wire) in the cross section perpendicular to the axial direction of the wire Area), (3) center portion, (4) 3 / 4D portion (region having a depth of 3/4 of the diameter D of the wire from the surface of the wire, ie, the region opposite to (2) with respect to the wire center portion) ), And (5) the equivalent circle diameter of the pearlite block within the viewing angle of 300 ⁇ m ⁇ 180 ⁇ m at each of the five locations consisting of the surface layer portion on the opposite side (that is, the region opposite to (1) with respect to the central portion of the wire rod) The average value (primary average value) was measured using an EBSD device.
- the average value (secondary average value) of each primary average value was calculated.
- This secondary average value was defined as the average PBS in the cross section perpendicular to the axial direction of the wire.
- the boundary between two adjacent pearlites having an orientation difference of 9 degrees or more was determined to be a pearlite block grain boundary.
- the number density of coarse pearlite blocks in the wire was determined by the following procedure. First, (1) surface layer portion (region having a depth of 30 ⁇ m from the surface of the wire), (2) 1 / 4D portion (depth from the surface of the wire to 1 ⁇ 4 of the diameter D of the wire) in the cross section perpendicular to the axial direction of the wire Area), (3) center part, (4) 3 / 4D part (area of 3/4 depth of wire diameter D from the wire surface. Region), and (5) a particle size of 40 ⁇ m or more within a viewing angle of 300 ⁇ m ⁇ 180 ⁇ m at each of five locations consisting of the surface layer portion on the opposite side (that is, the region on the opposite side of (1) with respect to the wire center).
- the number density of pearlite blocks was measured using an EBSD apparatus. Next, the average value of the number density at each location was calculated. This average value was defined as the number density of pearlite blocks having a particle diameter of 40 ⁇ m or more in a cross section perpendicular to the axial direction of the wire.
- the heating temperature, finishing temperature, and winding temperature in the invention examples are within an appropriate temperature range.
- the pearlite block of the inventive example was made fine, and the average PBS and coarse PB number density of the inventive example were controlled to appropriate levels.
- the number density of average PBS and coarse PB in the comparative examples in which the heating temperature, finishing temperature, and winding temperature are higher than the appropriate temperature range were outside the specified range of the present invention.
- the inventive examples exhibited better properties than the comparative examples with respect to low temperature strength, low temperature toughness, and room temperature toughness.
- the finish rolling temperature was below the appropriate temperature range, so the mill load increased and rolling could not be performed.
- 5A and 5B show an SEM photograph of the pearlite block of the invention example and an SEM photograph of the pearlite block of the comparative example. It was possible to discriminate from these SEM photographs that the pearlite block particle size of the inventive example was smaller than the pearlite block particle size of the comparative example.
- FIG. 6 shows the results of a tensile test at ⁇ 40 ° C. for the inventive example (No. S6) and the comparative example (No. S17).
- the ductility of the inventive example was higher than that of the comparative example, and it was determined that it was good.
- Table 2 it can be determined that the ductility of the inventive example tends to be higher than the ductility of the comparative example. It is estimated that the difference in ductility was caused by the difference in the pearlite block particle size shown in FIGS. 5A and 5B.
- molten steel having the composition shown in Table 3 was continuously cast to form a 300 mm ⁇ 500 mm slab, and then rolled into a 122 mm square steel slab. Thereafter, the steel slab is heated at the heating temperature shown in Table 3, and further, under the conditions shown in Table 3, the steel slab is subjected to rolling, winding, and heat treatment using a molten salt to obtain a 12 mm ⁇ wire. It was. No. D1 to D16 and No. D30 to D36 were produced by heat treatment (direct heat treatment) immersed in the molten salt without being reheated after winding. No. In D17 to D29, winding was performed under the conditions shown in Table 3, and thereafter, heat treatment (offline heat treatment) for reheating to 950 ° C. and performing lead patenting treatment was performed.
- the tensile strength at ⁇ 40 ° C., the ductility at ⁇ 40 ° C., and the impact value at ⁇ 40 ° C. of the wire were determined.
- the test method for obtaining these values is described in No. 1 above. S1-No. This is the same as the method of each test performed for S41.
- the Charpy impact test at room temperature was performed on the wire, and the impact value of the wire at room temperature was obtained.
- the method for performing the Charpy impact test at room temperature was the same as the method for performing the Charpy impact test at ⁇ 40 described above, except for the test temperature.
- the average density of PBS and the number density of coarse pearlite blocks of the above-mentioned wire rods are No. S1-No. It was measured by the measurement method applied to S16.
- FIGS 7A and 7B show an SEM photograph of the pearlite block of the invention example and an SEM photograph of the pearlite block of the comparative example. It was possible to discriminate from the SEM photograph that the pearlite block particle sizes (PBS) of the invention example and the comparative example were clearly different.
- PBS pearlite block particle sizes
- FIG. 8 shows the relationship between the pearlite block particle size ( ⁇ m) and the impact value based on the impact values shown in Tables 4 and 4. From FIG. 8, it was determined that the impact value (PBS: 15 to 23 ⁇ m) of the example of the present invention was higher than the impact value of the comparative example (PBS: 30 to 45 ⁇ m) both at room temperature and at ⁇ 40 ° C.
- FIG. 9A and FIG. 9B show the results of observing the fracture surface of the Charpy impact test piece of the invention example and the comparative example with an SEM.
- FIG. 9A shows a fracture surface unit of the invention example
- FIG. 9B shows a fracture surface unit of the comparative example.
- the fracture surface unit of the invention example was finer than the fracture surface unit of the comparative example. This indicates that the inventive example is superior in terms of toughness. Also in this point, the effect of PBS miniaturization could be confirmed.
- the toughness of the inventive example is higher than the toughness of the comparative example both at room temperature and in the environment of ⁇ 40 ° C. that is exposed when the wire is actually used as the reinforcing PC of the LNG tank. was able to be determined.
- the ductility in the vicinity of ⁇ 40 ° C. of the PC steel stranded wire used for the tension material of the PC type LNG PC breakwater is better than that of the conventional material due to the reduction of the pearlite block particle size. It became possible to provide wire rods. Therefore, the present invention contributes to improving the reliability of PC steel stranded wire, which is a member of LNG tank-related equipment, which has been increasingly demanded in recent years, in a low temperature use environment, and can be used industrially. It is highly probable.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Heat Treatment Of Steel (AREA)
- Metal Rolling (AREA)
Abstract
Description
本願は、2013年4月25日に日本にて出願された特願2013-092782号、および2013年4月25日に日本にて出願された特願2013-092775号に基づき優先権を主張し、その内容をここに援用する。 The present invention mainly relates to a wire rod having excellent low-temperature ductility and low-temperature toughness, which is a PC steel stranded wire for reinforcing a PC structure used in an LNG (liquefied natural gas) tank of an energy-related facility.
This application claims priority based on Japanese Patent Application No. 2013-092782 filed in Japan on April 25, 2013 and Japanese Patent Application No. 2013-092775 filed in Japan on April 25, 2013. , The contents of which are incorporated herein.
13.7≦log10{(dε/dt)×exp(63800/(1.98×(T+273.15))}≦16.5 (式A)
ただし、dε/dtは前記線材仕上圧延の際の前記歪み速度を単位s-1で示し、Tは前記仕上圧延温度を単位℃で示す。 (5) A method for producing a wire according to another aspect of the present invention comprises a method of rough rolling by heating a steel slab having the component composition described in (3) or (4) above to a rough rolling temperature of 950 to 1040 ° C. A step of performing a wire rod finish rolling at a finishing rolling temperature of 750 to 900 ° C., a step of winding at a winding temperature of 730 to 840 ° C., and then a cooling rate of 15 ° C./second or more. And a step of performing blast cooling to room temperature, and the finish rolling temperature and strain rate in the wire finish rolling satisfy the following formula A.
13.7 ≦ log 10 {(dε / dt) × exp (63800 / (1.98 × (T + 273.15))} ≦ 16.5 (Formula A)
Where dε / dt represents the strain rate in the finish rolling of the wire in the unit s −1 , and T represents the finish rolling temperature in the unit of ° C.
Cは、線材中のセメンタイト分率を上げ、これにより線材の強度を上げる作用を有する元素である。パテンティング条件を調整することによってパーライトのラメラ間隔を制御し、且つ加工によって線材の強度を上げることが可能である。しかし、C含有量が0.60%を下回ると、たとえ上述のパテンティング条件の調整を行ったとしても、PC式LNGタンクのPC防液堤を、十分に緊張させ得る強度が得られなくなる。 (C: 0.60 to 1.20%)
C is an element that has the effect of increasing the cementite fraction in the wire and thereby increasing the strength of the wire. By adjusting the patenting conditions, the lamella spacing of the pearlite can be controlled, and the strength of the wire can be increased by processing. However, if the C content is less than 0.60%, even if the above-mentioned patenting conditions are adjusted, it is impossible to obtain a strength that can sufficiently tension the PC liquid bank of the PC type LNG tank.
本実施形態に係る線材の製造方法として、後述するように、DLP(Direct in-Line Patenting)法およびステルモア法のいずれをも採用することができるが、ステルモア法を用いて線材を製造する場合、C含有量を0.70~0.90%とすることが好ましい。ステルモア法を用いて線材を製造する場合、線材の冷却速度がDLP法による製造時よりも遅くなり、線材の延性および靱性が比較的低くなる。この強度低下を補うために、C含有量の下限値を0.70%とすることが好ましい。また、C含有量が過剰に増大すると、線材が過共析鋼(パーライトとセメンタイトとが共存する組織を有する鋼)となるので、線材を冷却する工程において旧オーステナイト粒径に初析セメンタイトが網目状に生成する。この網目状の初析セメンタイトは、線材の伸線加工性を著しく低下させる。網目状の初析セメンタイトの析出を避けるためには、C含有量の上限値を0.90%とすることが好ましい。C含有量は、さらに好ましくは0.80~0.90%である。 When the C content of the wire exceeds 1.20%, network-like cementite is generated in the metal structure of the wire. Due to this mesh-like cementite, wire breakage frequently occurs during wire drawing, which may hinder wire production activities.
As described later, as a method for manufacturing a wire according to the present embodiment, either a DLP (Direct in-Line Patenting) method or a Stemmore method can be adopted. However, when a wire is manufactured using the Stemmore method, The C content is preferably 0.70 to 0.90%. When manufacturing a wire using a Stealmore method, the cooling rate of a wire becomes slower than the time of manufacture by a DLP method, and the ductility and toughness of a wire become comparatively low. In order to compensate for this decrease in strength, the lower limit value of the C content is preferably set to 0.70%. Further, if the C content is excessively increased, the wire becomes hypereutectoid steel (steel having a structure in which pearlite and cementite coexist), so that in the process of cooling the wire, the proeutectoid cementite is formed in the prior austenite grain size. To form. This network-like pro-eutectoid cementite significantly reduces the wire drawing workability of the wire. In order to avoid precipitation of network-like pro-eutectoid cementite, the upper limit value of the C content is preferably set to 0.90%. The C content is more preferably 0.80 to 0.90%.
Siは、精錬時に脱酸元素として作用する元素である。0.30%以上のSiが含有された場合に、この脱酸効果が十分に発現する。従って、本実施形態に係る線材のSi含有量の下限値は0.30%である。Siは線材の強度を向上させる効果も有するが、0.80%以上のSiが含有された場合に、この強度向上効果が発現する。従って、本実施形態に係る線材のSi含有量の下限値を0.80%としてもよい。また、Siは、フェライトの固溶強化を行うが、熱処理時の恒温変態のノーズを上げる作用があるので、過剰な量のSiは、熱処理のコストを増大させる。従って、製造設備の能力を考慮して、Si含有量の上限を1.30%とする。
本実施形態に係る線材の製造方法として、DLP法およびステルモア法のいずれを採用してもよいが、ステルモア法を用いて線材を製造する場合、Si含有量を0.80~1.30%とすることが好ましい。ステルモア法を用いて線材を製造する場合、線材の冷却速度がDLP法による製造時よりも遅くなり、線材の延性および靱性が比較的低くなる。この強度低下を補うために、Si含有量の下限値を0.80%とすることが好ましい。Si含有量は、さらに好ましくは0.90~1.25%である。 (Si: 0.30 to 1.30%)
Si is an element that acts as a deoxidizing element during refining. This deoxidation effect is sufficiently exhibited when 0.30% or more of Si is contained. Therefore, the lower limit value of the Si content of the wire according to this embodiment is 0.30%. Si also has the effect of improving the strength of the wire, but this strength improvement effect is manifested when 0.80% or more of Si is contained. Therefore, it is good also considering the lower limit of Si content of the wire concerning this embodiment as 0.80%. Further, Si strengthens the solid solution of ferrite, but has the effect of raising the nose of isothermal transformation during heat treatment, so an excessive amount of Si increases the cost of heat treatment. Therefore, considering the capacity of the production facility, the upper limit of the Si content is set to 1.30%.
As a manufacturing method of the wire according to the present embodiment, either the DLP method or the Stemmore method may be adopted. However, when the wire is manufactured using the Stemmore method, the Si content is 0.80 to 1.30%. It is preferable to do. When manufacturing a wire using a Stealmore method, the cooling rate of a wire becomes slower than the time of manufacture by a DLP method, and the ductility and toughness of a wire become comparatively low. In order to compensate for this decrease in strength, the lower limit value of the Si content is preferably set to 0.80%. The Si content is more preferably 0.90 to 1.25%.
Mnは、固溶強化元素であり、線材の延性および靭性を向上させる効果と、焼入れ性を向上させる効果とを有する。線材の延性および靱性を確保するために、0.30%以上のMnを含有させる必要がある。また、線材の延性をさらに高めるために、Mn含有量の下限値を0.60%としてもよい。一方、Mn含有量が0.90%を超えると、線材の製造の際に、線材の中心部において変態遅れが生じ、これにより未変態オーステナイト部にミクロマルテンサイトが生成する。この線材中心部のミクロマルテンサイトは、線材の伸線加工時に断線を発生させる。したがって、Mn含有量の上限値を0.90%とする必要がある。
本実施形態に係る線材の製造方法として、DLP法およびステルモア法のいずれをも採用することができるが、ステルモア法を用いて線材を製造する場合、Mn含有量を0.60~0.90%とすることが好ましい。ステルモア法を用いて線材を製造する場合、線材の冷却速度がDLP法による製造時よりも遅くなり、線材の延性および靱性が比較的低くなる。この強度低下を補うために、Mn含有量の下限値を0.60%とすることが好ましい。Mn含有量は、さらに好ましくは0.70~0.90%である。 (Mn: 0.30-0.90%)
Mn is a solid solution strengthening element and has the effect of improving the ductility and toughness of the wire and the effect of improving the hardenability. In order to ensure the ductility and toughness of the wire, it is necessary to contain 0.30% or more of Mn. In order to further improve the ductility of the wire, the lower limit value of the Mn content may be 0.60%. On the other hand, when the Mn content exceeds 0.90%, a transformation delay occurs in the central portion of the wire during the production of the wire, and micro martensite is generated in the untransformed austenite portion. The micro martensite at the center of the wire causes breakage during wire drawing of the wire. Therefore, the upper limit of the Mn content needs to be 0.90%.
As a method for producing a wire according to the present embodiment, either the DLP method or the Stemmore method can be adopted. However, when producing a wire using the Stemmore method, the Mn content is 0.60 to 0.90%. It is preferable that When manufacturing a wire using a Stealmore method, the cooling rate of a wire becomes slower than the time of manufacture by a DLP method, and the ductility and toughness of a wire become comparatively low. In order to compensate for this decrease in strength, the lower limit value of the Mn content is preferably 0.60%. The Mn content is more preferably 0.70 to 0.90%.
(S:0.020%以下)
Pは、鋼を脆化させる作用を有する。従って、P含有量の上限値を0.020%とする必要がある。なお、線材の低温脆化の防止をさらに確実に行う場合には、P含有量の上限値を0.010%、0.005%、または0.001%としてもよい。
Sは、線材中のMnと結合してMnSを形成する元素である。Sは、鋼を精錬および凝固させる過程で、鋼の中心部に偏析するので、鋼の中心部にMnSが集積するが、このMnSは鋼の低温延性を低下させる。S含有量が0.020%を超えた場合に、この低温延性の低下が顕著となるので、S含有量は0.020%以下とする。なお、線材の低温脆化の防止をさらに確実に行う場合には、S含有量の上限値を0.010%、0.005%、または0.001%としてもよい。
本実施形態に係る線材において、PおよびSの含有量は、低い方が好ましい。従って、PおよびSそれぞれの含有量の下限値は0%である。 (P: 0.020% or less)
(S: 0.020% or less)
P has the effect | action which embrittles steel. Therefore, the upper limit of the P content needs to be 0.020%. In addition, when preventing the low-temperature embrittlement of a wire rod more reliably, it is good also considering the upper limit of P content as 0.010%, 0.005%, or 0.001%.
S is an element that combines with Mn in the wire to form MnS. S is segregated at the center of the steel in the process of refining and solidifying the steel, so MnS accumulates in the center of the steel, but this MnS lowers the low temperature ductility of the steel. When the S content exceeds 0.020%, this decrease in low temperature ductility becomes significant, so the S content is set to 0.020% or less. In addition, when performing prevention of the low temperature embrittlement of a wire more reliably, it is good also considering the upper limit of S content as 0.010%, 0.005%, or 0.001%.
In the wire according to the present embodiment, the P and S contents are preferably as low as possible. Therefore, the lower limit of the contents of P and S is 0%.
Nは、Al、Ti、およびBと結びついて窒化物を形成する元素である。これら窒化物はオーステナイトの析出核となるので、これら窒化物の個数を制御することにより、鋼の加熱時にオーステナイト粒径を制御することができる。窒化物の量が増加すると、結晶粒が微細化する。N含有量が0.0025%未満であると、窒化物を十分に形成せず、粒径の微細化効果が十分に得られない。一方、N含有量が0.0060%を超えると、Al、Ti、およびBと結合しないフリーNが過剰となる。この過剰なフリーNによって、時効硬化が起きて、線材の延性および靱性が低下する。したがって、N含有量は、0.0025~0.0060%とする必要がある。好ましくは、N含有量は0.0025~0.0040%である。 (N: 0.0025 to 0.0060%)
N is an element that combines with Al, Ti, and B to form a nitride. Since these nitrides become austenite precipitation nuclei, the austenite grain size can be controlled when the steel is heated by controlling the number of these nitrides. As the amount of nitride increases, the crystal grains become finer. If the N content is less than 0.0025%, nitrides are not sufficiently formed, and the effect of refining the particle size cannot be sufficiently obtained. On the other hand, if the N content exceeds 0.0060%, free N that does not bind to Al, Ti, and B becomes excessive. Due to this excessive free N, age hardening occurs, and the ductility and toughness of the wire are lowered. Therefore, the N content needs to be 0.0025 to 0.0060%. Preferably, the N content is 0.0025 to 0.0040%.
Alは、鋼の精錬時に脱酸材として作用する。更にAlは、鋼中のNと化合物を形成し、Nを固定する作用を有する。Nを固定することで、鋼の時効硬化を防止することができる。さらに、Bを同時に含有する場合には、Nを固定することで、固溶B量を増加させることができる。 (Al: 0.005 to 0.100%)
Al acts as a deoxidizer during steel refining. Further, Al has a function of forming a compound with N in steel and fixing N. By fixing N, age hardening of steel can be prevented. Furthermore, when it contains B simultaneously, the amount of solid solution B can be increased by fixing N.
Tiは、Alと同様に、鋼の脱酸材として作用する。更に、Tiは鋼中のNと化合物を形成し、Nを固定する作用を有する。Nを固定することで、鋼の時効硬化を防止することができる。さらに、Bを同時に含有する場合には、Nを固定することで、固溶B量を増加させることができる。 (Ti: 0.003 to 0.050%)
Ti, like Al, acts as a steel deoxidizer. Further, Ti forms a compound with N in the steel and has an action of fixing N. By fixing N, age hardening of steel can be prevented. Furthermore, when it contains B simultaneously, the amount of solid solution B can be increased by fixing N.
なお、上述のようにAlとTiは同様の効果を有する。従って、Tiの添加によってAlの添加量を低減することができ、この場合も同様の効果が得られる。 However, if the Ti content is less than 0.003%, the effect of fixing N by Ti cannot be sufficiently obtained. On the other hand, when the Ti content exceeds 0.050%, TiC generated by combining with carbon in the steel increases. This TiC becomes a starting point of cracking during wire drawing. Therefore, the Ti content may be 0.003 to 0.050%. Preferably, the Ti content is 0.020 to 0.040%.
As described above, Al and Ti have the same effect. Therefore, the amount of Al added can be reduced by adding Ti, and the same effect can be obtained in this case.
Bは、オーステナイト中に固溶Bとして存在した場合、線材の焼入れ性を向上させる作用を有する。B含有量が0.0005%未満であると、焼入れ性向上の効果が十分に得られない。一方、B含有量が0.0040%を超えると、BがFeおよびCと化合物を形成し、Fe23(C、B)6などの析出物を形成する。この析出物は、伸線加工時の割れの起点となる。したがって、B含有量を、0.0005~0.0040%としてもよい。好ましくは、B含有量は0.0009~0.0030%である。 (B: 0.0005-0.0040%)
B, when present as a solid solution B in austenite, has the effect of improving the hardenability of the wire. If the B content is less than 0.0005%, the effect of improving hardenability cannot be sufficiently obtained. On the other hand, if the B content exceeds 0.0040%, B forms a compound with Fe and C, and precipitates such as Fe 23 (C, B) 6 are formed. This precipitate becomes a starting point of cracking during wire drawing. Therefore, the B content may be 0.0005 to 0.0040%. Preferably, the B content is 0.0009 to 0.0030%.
本実施形態に係る線材において、Crの含有は必須ではない。従って、Cr含有量の下限値は0%である。しかしながら、Crは、パーライトのラメラ間隔を小さくして、線材の強度を上げる作用を有する。この作用によって、伸線加工時の線材の強度上昇が大きくなる。この効果は、Cr含有量が0.10%以上である場合に得られるので、Cr含有量を0.10%以上とすることが好ましい。また、強度をさらに向上させる場合、0.50%以上のCrを含有させることが好ましい。Cr含有量が1.00%を超えると、パーライト変態の終了時間が長くなり、線材の冷却の過程で過冷組織が生成し、線材の延性が劣化する。従って、Cr含有量の上限を1.00%とすることが好ましい。
本実施形態に係る線材の製造方法として、DLP法およびステルモア法のいずれをも採用することができるが、ステルモア法を用いて製造する場合、Cr含有量を0.50~1.00%とすることがさらに好ましい。ステルモア法を用いて製造する場合、線材の冷却速度がDLP法による製造時よりも遅くなり、線材の延性および靱性が比較的低くなる。この強度低下を補うために、Cr含有量の下限値を0.5%とすることがさらに好ましい。Cr含有量は、より一層好ましくは0.50~0.90%である。 (Cr: 0 to 1.00%)
In the wire according to this embodiment, the inclusion of Cr is not essential. Therefore, the lower limit of the Cr content is 0%. However, Cr has the effect of increasing the strength of the wire by reducing the lamella spacing of the pearlite. This action increases the strength of the wire during wire drawing. Since this effect is obtained when the Cr content is 0.10% or more, the Cr content is preferably set to 0.10% or more. Moreover, when improving an intensity | strength further, it is preferable to contain 0.50% or more of Cr. When the Cr content exceeds 1.00%, the end time of the pearlite transformation becomes long, a supercooled structure is generated in the process of cooling the wire, and the ductility of the wire is deteriorated. Therefore, the upper limit of the Cr content is preferably 1.00%.
As a method for manufacturing the wire according to the present embodiment, either the DLP method or the Stemmore method can be adopted. However, in the case of manufacturing using the Stemmore method, the Cr content is set to 0.50 to 1.00%. More preferably. In the case of manufacturing using the Stealmore method, the cooling rate of the wire becomes slower than in the case of manufacturing by the DLP method, and the ductility and toughness of the wire become relatively low. In order to compensate for this decrease in strength, the lower limit of the Cr content is more preferably 0.5%. The Cr content is more preferably 0.50 to 0.90%.
本実施形態に係る線材において、Vの含有は必須ではない。従って、V含有量の下限値は0%である。しかしながら、Vは、Cと結合して、フェライト中に炭化物として析出する元素である。この炭化物の析出によって、フェライトが硬化し、線材を高強度化することができる。この作用は、Vを0.005%以上含有した場合に得られる。しかし、V含有量が0.800%を超えると、粗大な炭化物が析出する。この粗大な炭化物は、線材の加工の際に割れの起点になる。したがって、V含有量は、0.005%以上0.800%以下とすることが好ましい。
本実施形態に係る線材の製造方法として、DLP法およびステルモア法のいずれをも採用することができるが、ステルモア法を用いて製造する場合、V含有量を0.300~0.500%とすることがさらに好ましい。ステルモア法を用いて製造する場合、線材の冷却速度がDLP法による製造時よりも遅くなり、線材の延性および靱性が比較的低くなる。この強度低下を補うために、V含有量の下限値を0.300%とすることがさらに好ましい。また、加工歪を受けた場合にVC析出物の地鉄界面部にマイクロクラックボイドが形成されるため、V含有量の上限値を0.500%とすることがさらに好ましい。V含有量は、より一層好ましくは0.300~0.400%である。 (V: 0 to 0.800%)
In the wire according to this embodiment, the inclusion of V is not essential. Therefore, the lower limit of the V content is 0%. However, V is an element that combines with C and precipitates as a carbide in ferrite. By precipitation of this carbide, the ferrite is hardened, and the strength of the wire can be increased. This effect is obtained when V is contained in an amount of 0.005% or more. However, when the V content exceeds 0.800%, coarse carbides precipitate. This coarse carbide becomes a starting point of cracking when the wire is processed. Therefore, the V content is preferably 0.005% or more and 0.800% or less.
As a method for producing the wire according to the present embodiment, either the DLP method or the Stemmore method can be adopted. However, when the wire is produced using the Stemmore method, the V content is 0.300 to 0.500%. More preferably. In the case of manufacturing using the Stealmore method, the cooling rate of the wire becomes slower than in the case of manufacturing by the DLP method, and the ductility and toughness of the wire become relatively low. In order to compensate for this decrease in strength, the lower limit value of the V content is more preferably 0.300%. Moreover, since a microcrack void is formed in the base metal interface part of VC deposit when it receives a processing strain, it is more preferable to make the upper limit of V content into 0.500%. The V content is more preferably 0.300 to 0.400%.
本実施形態に係る線材の成分組成の残部は、Feおよび不純物からなる。不純物とは、鋼材を工業的に製造する際に、鉱石若しくはスクラップ等のような原料、又は製造工程の種々の要因によって混入する成分であって、本実施形態に係る線材の特性に悪影響を与えない範囲で許容されるものを意味する。 (Balance: Fe and impurities)
The balance of the component composition of the wire according to this embodiment is made of Fe and impurities. Impurities are raw materials such as ore or scrap, or components mixed in due to various factors in the manufacturing process when manufacturing steel materials industrially, and have an adverse effect on the characteristics of the wire according to this embodiment. It means what is allowed in the range.
本実施形態では、パーライトブロック粒界は、方位差が9度以上である隣り合う2つのパーライトの境界であると定義され、パーライトブロックは、パーライトブロック粒界によって囲まれた領域であると定義され、PBS(パーライトブロック粒径)は、パーライトブロックの円相当径であると定義される。本実施形態に係る線材においては、上述のように成分組成が規定されることに加えて、線材軸方向に垂直な断面における平均PBS(パーライトブロック粒径)が23μm以下とされる。 (Average value of pearlite block particle size in cross section perpendicular to wire axis direction: 23 μm or less)
In this embodiment, the pearlite block grain boundary is defined as a boundary between two adjacent pearlites having an orientation difference of 9 degrees or more, and the pearlite block is defined as a region surrounded by the pearlite block grain boundary. , PBS (perlite block particle size) is defined as the equivalent circle diameter of a pearlite block. In the wire according to this embodiment, in addition to defining the component composition as described above, the average PBS (pearlite block particle size) in a cross section perpendicular to the wire axis direction is set to 23 μm or less.
本実施形態に係る線材においては、上述のように成分組成およびパーライトブロック粒径の平均値が規定されることに加えて、線材軸方向に垂直な断面において、パーライトブロック粒径が40μm以上であるパーライトブロックの個数密度を0~20個/mm2とする。 (The number density of pearlite blocks having a particle diameter of 40 μm or more in the cross section perpendicular to the wire axis direction is 0 to 20 / mm 2 )
In the wire according to the present embodiment, in addition to defining the component composition and the average value of the pearlite block particle size as described above, the pearlite block particle size is 40 μm or more in the cross section perpendicular to the wire axis direction. The number density of pearlite blocks is set to 0 to 20 pieces / mm 2 .
線材軸方向に垂直な前記断面において、粗大パーライトブロックの個数密度が20個/mm2超となった場合、線材の延性および靱性が要求水準を満たさなくなる。従って、線材軸方向に垂直な断面における粗大パーライトブロックの個数密度を20個/mm2以下に制限する必要がある。好ましくは、線材軸方向に垂直な断面における粗大パーライトブロックの個数密度の上限値は18個/mm2である。粗大パーライトブロックは、少ない方が好ましいので、線材軸方向に垂直な断面における粗大パーライトブロックの個数密度の下限値は0個/mm2である。 Since the pearlite block having a particle size of 40 μm or more serves as a starting point of fracture, even if the number is small, the ductility and toughness of the wire are lowered. In the wire according to the present embodiment, in addition to controlling the average value of the pearlite block particle size as described above, it is also necessary to suppress the generation of coarse pearlite blocks. For this reason, the number density of coarse pearlite blocks is limited. Hereinafter, the “pearlite block having a particle size of 40 μm or more” may be referred to as “coarse pearlite block” or “coarse PB”.
In the cross section perpendicular to the wire axis direction, when the number density of coarse pearlite blocks exceeds 20 / mm 2 , the ductility and toughness of the wire do not satisfy the required level. Therefore, it is necessary to limit the number density of coarse pearlite blocks in a cross section perpendicular to the wire axis direction to 20 pieces / mm 2 or less. Preferably, the upper limit of the number density of coarse pearlite blocks in a cross section perpendicular to the axial direction of the wire is 18 / mm 2 . Since the number of coarse pearlite blocks is preferably small, the lower limit of the number density of coarse pearlite blocks in the cross section perpendicular to the wire axis direction is 0 / mm 2 .
13.7≦log10{(dε/dt)×exp(63800/(1.98×(T+273.15)))}≦16.5 (式1)
ただし、dε/dtは線材仕上圧延の際の歪み速度を単位s-1で示し、Tは仕上圧延温度を単位℃で示す。
なお、ステルモア法による製造を行う場合、鋼片が、質量%で、Cr:0.50~1.00%、およびV:0.300~0.500%のうち1種または2種をさらに含有してもよい。 When the wire rod according to the present embodiment is manufactured by the Stemmore method, as shown in FIG. 10, (1) mass%, C: 0.70 to 0.90%, Si: 0.80 to 1.30% , Mn: 0.60 to 0.90%, P: 0.020% or less, S: 0.020% or less, N: 0.0025 to 0.0060%, Cr: 0 to 1.00%, and V : 0 to 0.500%, Al: 0.005 to 0.100%, Ti: 0.003 to 0.050%, B: one of 0.0005 to 0.0040% or A steel slab containing two or more components, the balance of which is composed of Fe and impurities, is heated to a rough rolling temperature of 950 to 1040 ° C. and then subjected to rough rolling, and (2) finish rolling at 750 to 900 ° C. (3) Winding is performed at a winding temperature of 730 to 840 ° C., and (4) Performing blast cooling to room temperature at 15 ° C. / sec or more cooling rate. At this time, the finish rolling temperature and the strain rate must satisfy the relationship of the following
13.7 ≦ log 10 {(dε / dt) × exp (63800 / (1.98 × (T + 273.15)))} ≦ 16.5 (Formula 1)
Here, dε / dt represents the strain rate in the wire finish rolling in the unit s −1 , and T represents the finish rolling temperature in the unit ° C.
In addition, when manufacturing by the Stealmore method, the steel slab further contains one or two of Cr: 0.50 to 1.00% and V: 0.300 to 0.500% by mass%. May be.
ステルモア法によって本実施形態に係る線材を製造する場合、粗圧延に供する鋼片の成分組成は、上述の規定範囲内とする必要がある。この規定範囲は、本実施形態に係る線材の成分組成として上述された規定範囲よりも狭い。ステルモア法は、巻取後に衝風冷却を行う製造方法であり、衝風冷却による冷却速度は、後述するDLP法における溶融塩による直接熱処理の冷却速度よりも遅い。冷却速度が遅い場合、最終的に得られる線材の延性および靱性が比較的低くなる。従って、ステルモア法によって本実施形態に係る線材を製造する場合は、DLP法における溶融塩による直接熱処理を行う場合よりも、延性および靱性の向上のための合金元素であるC、Mn、およびSiを比較的多く含有させる必要がある。また、ステルモア法によって本実施形態に係る線材を製造する際に、CrおよびVを含有させることにより線材の特性を向上させる場合には、CrおよびVも、DLP法における溶融塩による直接熱処理を行う場合よりも比較的多く含有させることが好ましい。 (Component composition of steel slabs for rough rolling: within the above specified range)
When manufacturing the wire which concerns on this embodiment by the Stealmore method, the component composition of the steel slab used for rough rolling needs to be in the above-mentioned specified range. This specified range is narrower than the specified range described above as the component composition of the wire according to the present embodiment. The Stemmore method is a manufacturing method that performs blast cooling after winding, and the cooling rate by blast cooling is slower than the cooling rate of direct heat treatment with molten salt in the DLP method described later. When the cooling rate is low, the ductility and toughness of the finally obtained wire are relatively low. Therefore, when the wire according to the present embodiment is manufactured by the Stemmore method, C, Mn, and Si, which are alloy elements for improving ductility and toughness, are compared to the case of performing the direct heat treatment with the molten salt in the DLP method. It is necessary to contain a relatively large amount. In addition, when manufacturing the wire according to this embodiment by the Stealmore method, when Cr and V are included to improve the properties of the wire, Cr and V are also subjected to direct heat treatment with molten salt in the DLP method. It is preferable to contain relatively more than the case.
ステルモア法による、本実施形態に係る線材の製造方法では、粗圧延に供する前の鋼片の加熱温度(粗圧延温度)を950~1040℃とする。粗圧延前の鋼片の加熱温度が950℃未満である場合、線材圧延時のロール反力が急激に増加して、ロール割損などの設備トラブルが発生する場合がある。従って、粗圧延前の鋼片の加熱温度を950℃以上とする。一方、粗圧延前の鋼片の加熱温度が1040℃を超えると、鋼片中に析出している窒化アルミニウム(AlN)の溶体化が過剰に進行する。AlNは上述のようにオーステナイトの析出核となり、オーステナイトの結晶粒径に微細化に寄与する。製造段階の線材のオーステナイトの粒径を微細化することにより、最終的に得られる線材のパーライトの粒径を微細化することができる。しかし、AlNの溶体化が過剰に進行すると、オーステナイト結晶粒径の粗大化が進む。この場合、後に線材を製造した段階で、線材のPBSが粗大化する。この場合、線材軸方向に垂直な断面においてパーライトブロックの粒径の平均値が23μm超となり、および/または、40μm以上の前記粒径を有するパーライトブロックの個数密度が20個/mm2超となる。このような現象を回避するために、粗圧延前の鋼片の加熱温度を1040℃以下とする。 (Heating temperature of steel slab before being subjected to rough rolling: 950 to 1040 ° C)
In the wire manufacturing method according to the present embodiment by the Stealmore method, the heating temperature (rough rolling temperature) of the steel slab before being subjected to rough rolling is set to 950 to 1040 ° C. When the heating temperature of the steel slab before rough rolling is less than 950 ° C., the roll reaction force at the time of wire rod rolling increases rapidly, and equipment troubles such as roll breakage may occur. Therefore, the heating temperature of the steel slab before rough rolling is set to 950 ° C. or higher. On the other hand, when the heating temperature of the steel slab before rough rolling exceeds 1040 ° C., solutionization of aluminum nitride (AlN) precipitated in the steel slab proceeds excessively. As described above, AlN serves as austenite precipitation nuclei and contributes to refinement of the austenite crystal grain size. By refining the particle size of the austenite of the wire rod in the production stage, the particle size of the pearlite of the finally obtained wire rod can be reduced. However, when the solution of AlN proceeds excessively, the austenite crystal grain size increases. In this case, the PBS of the wire becomes coarse when the wire is manufactured later. In this case, in the cross section perpendicular to the wire axis direction, the average value of the particle size of the pearlite block is more than 23 μm, and / or the number density of the pearlite block having the particle size of 40 μm or more is more than 20 / mm 2. . In order to avoid such a phenomenon, the heating temperature of the steel slab before rough rolling is set to 1040 ° C. or less.
ステルモア法による、本実施形態に係る線材の製造方法では、線材仕上圧延を、750~900℃の温度域で行う。線材仕上圧延の温度(仕上圧延温度)が750℃未満である場合、圧延時のロール反力の増加によって、ロール割損などの設備トラブルが発生する場合があるので、線材仕上圧延の温度を750℃以上とする。一方、線材仕上圧延の温度が900℃を超えると、オーステナイト結晶粒径が粗大化する。この場合、線材軸方向に垂直な断面においてパーライトブロックの粒径の平均値が23μm超となり、および/または、40μm以上の前記粒径を有するパーライトブロックの個数密度が20個/mm2超となる。パーライトブロックの粗大化により、線材の延性が劣化する。このような現象を回避するために、線材仕上圧延の温度を900℃以下とする。 (Temperature of wire finish rolling: 750-900 ° C)
In the wire manufacturing method according to the present embodiment by the Stealmore method, the wire finish rolling is performed in a temperature range of 750 to 900 ° C. When the temperature of the wire finish rolling (finish rolling temperature) is less than 750 ° C., an increase in the roll reaction force during rolling may cause equipment trouble such as roll breakage. ℃ or more. On the other hand, if the temperature of the wire finish rolling exceeds 900 ° C., the austenite crystal grain size becomes coarse. In this case, in the cross section perpendicular to the wire axis direction, the average value of the particle size of the pearlite block is more than 23 μm, and / or the number density of the pearlite block having the particle size of 40 μm or more is more than 20 / mm 2. . The ductility of the wire deteriorates due to the coarsening of the pearlite block. In order to avoid such a phenomenon, the wire finishing rolling temperature is set to 900 ° C. or less.
ステルモア法による本実施形態に係る線材の製造方法では、さらに、線材仕上圧延の際の仕上圧延温度と歪み速度との間の関係を規定する必要がある。具体的には、線材仕上圧延の際の線材の歪み速度dε/dt、線材の塑性変形の活性化エネルギーQ、および線材仕上圧延の際の仕上圧延温度Tを、以下の式2によって示されるZener-Hollomonの式に代入して得られるZ値(Zener-Hollomon parameter)の常用対数(log10Z)が13.7~16.5である必要がある。
Z=(dε/dt)×exp(Q/RT) (式2)
「dε/dt」は、歪み速度を単位s-1で示すものである。「R」は、気体定数であり、その値は1.98cal/mol・degである。「T」は、仕上圧延温度を単位Kで示すものである。仕上圧延温度の単位を℃とする場合、式2における「T」を「(T+273.15)」とする必要がある。「Q」は、線材の塑性変形の活性化エネルギーを示す。上述された化学組成を有する本実施形態に係る線材の塑性変形の活性化エネルギーは、63800cal/molであるとみなされる。
本実施形態に係る製造方法においては、線材仕上圧延の際の線材の歪み速度dε/dtを以下の式によって求めることができる。
dε/dt=ε×2×π×(N/60)×Ld (式3)
ε=ln(h2/h1) (式4)
Ld=(r/Δh)1/2 (式5)
Δh=h1-h2 (式6)
「ε」は、線材仕上圧延の際の歪み量であり、無次元数である。「h1」は、線材仕上圧延前の線材の径を単位mmで示すものであり、「h2」は、線材仕上圧延後の線材の径を単位mmで示すものである。「N」は線材仕上圧延を行うロールの回転数を単位rpmで示すものである。「Ld」は線材仕上圧延の際の投影接触長さを単位mmで示すものである。投影接触長さとは、圧延の際にロールと被圧延材(線材)とが接触している領域の、圧延方向に沿った長さである。rは線材仕上圧延の際のロール半径を単位mmで示すものである。Δhは線材仕上圧延の際の圧下量を単位mmで示すものである。式3~式6からわかるように、歪み速度とは、圧延速度および圧下率の両方に関係する圧延条件である。
本発明者らが検討した結果、線材仕上圧延の際のZ値と、最終的に得られる線材の平均パーライトブロック粒径との間には、図2に示される相関関係があることがわかった。図2からわかるように、線材軸方向に垂直な断面における平均パーライトブロック粒径を23μm以下にするためには、log10Zを13.7以上にする必要がある。また、40μm以上の粒径を有する粗大なパーライトブロックの個数密度を0~20個/mm2に抑制するためにも、同様にlog10Zを13.7以上にする必要がある。一方、log10Zを16.5超にすることは、設備能力を考慮すると困難である。Zener-Hollomonの式を見ればわかるように、Z値を大きくするためには、圧延温度を下げることと歪み速度を大きくすることとが必要とされるからである。従って、ステルモア法を用いた本実施形態に係る線材の製造方法では、log10Zの上限値を16.5とした。log10Zは、好ましくは14.0~16.0である。log10Zが上述の範囲を下回った場合、線材軸方向に垂直な断面においてパーライトブロックの粒径の平均値が23μm超となり、および/または、40μm以上の前記粒径を有するパーライトブロックの個数密度が20個/mm2超となる。 (Relationship between finish rolling temperature and strain rate in wire finish rolling: 13.7 ≦ log 10 Z ≦ 16.5)
In the manufacturing method of the wire rod according to the present embodiment by the Stealmore method, it is further necessary to define the relationship between the finish rolling temperature and the strain rate in the wire finish rolling. Specifically, the strain rate dε / dt of the wire during the wire finish rolling, the activation energy Q of the plastic deformation of the wire, and the finish rolling temperature T during the wire finish rolling are expressed by the following equation 2 -The common logarithm (log 10 Z) of the Z value (Zener-Holomon parameter) obtained by substituting into the Hollomon equation needs to be 13.7 to 16.5.
Z = (dε / dt) × exp (Q / RT) (Formula 2)
“Dε / dt” indicates the strain rate in the unit s −1 . “R” is a gas constant, and its value is 1.98 cal / mol · deg. “T” indicates the finish rolling temperature in K. When the unit of the finish rolling temperature is ° C., “T” in
In the manufacturing method according to this embodiment, the strain rate dε / dt of the wire during the finish rolling of the wire can be obtained by the following equation.
dε / dt = ε × 2 × π × (N / 60) × L d (Formula 3)
ε = ln (h2 / h1) (Formula 4)
L d = (r / Δh) 1/2 (Formula 5)
Δh = h1-h2 (Formula 6)
“Ε” is a strain amount in the finish rolling of the wire rod, and is a dimensionless number. “H1” indicates the diameter of the wire before the wire finish rolling in unit mm, and “h2” indicates the diameter of the wire after the wire finish rolling in unit mm. “N” indicates the number of rotations of the roll for performing the wire finish rolling in the unit of rpm. “L d ” indicates the projected contact length in the unit mm in the wire finishing rolling. The projected contact length is the length along the rolling direction of the region where the roll and the material to be rolled (wire) are in contact during rolling. r represents the roll radius in the unit mm in the wire finishing rolling. Δh represents the amount of reduction in unit mm in the wire finish rolling. As can be seen from
As a result of investigations by the present inventors, it has been found that there is a correlation shown in FIG. 2 between the Z value at the time of wire finish rolling and the average pearlite block particle size of the finally obtained wire. . As can be seen from FIG. 2, in order to make the average pearlite block particle size in the cross section perpendicular to the wire axis direction 23 μm or less, log 10 Z needs to be 13.7 or more. Further, in order to suppress the number density of coarse pearlite blocks having a particle diameter of 40 μm or more to 0 to 20 / mm 2 , log 10 Z needs to be 13.7 or more in the same manner. On the other hand, it is difficult to set log 10 Z to more than 16.5 in consideration of equipment capacity. This is because, as can be seen from the Zener-Holomon equation, to increase the Z value, it is necessary to lower the rolling temperature and increase the strain rate. Therefore, in the method for manufacturing the wire rod according to the present embodiment using the Stemmore method, the upper limit value of log 10 Z is set to 16.5. log 10 Z is preferably 14.0 to 16.0. When log 10 Z is less than the above range, the average value of the particle size of the pearlite block exceeds 23 μm and / or the number density of the pearlite block having the particle size of 40 μm or more in the cross section perpendicular to the wire axis direction. Is over 20 pieces / mm 2 .
(巻取後の衝風冷却速度:15℃/秒以上)
ステルモア法による本実施形態に係る線材の製造方法では、線材仕上圧延に次いで、線材を730~840℃で巻き取り、その後、15℃/秒以上の冷却速度で衝風冷却を行う。巻取温度が730℃未満であると、スケール生成量が少なくなり、メカニカルデスケーリング性が劣化するので、巻取温度を730℃以上とする。巻取温度が840℃を超えると、オーステナイト粒径が大きくなる。この場合、最終的に得られる線材のパーライトブロック粒径を23μm以下に調整できなくなり、および/または、40μm以上の粒径を有するパーライトブロックの個数密度が20個/mm2超となる。従って、巻取温度を840℃以下とする。巻取温度は、好ましくは750~820℃である。 (Winding temperature: 730-840 ° C)
(Shock cooling rate after winding: 15 ℃ / second or more)
In the method for manufacturing the wire according to the present embodiment by the Stealmore method, after the wire finish rolling, the wire is wound at 730 to 840 ° C., and then blast cooling is performed at a cooling rate of 15 ° C./second or more. If the coiling temperature is less than 730 ° C, the amount of scale generation is reduced and the mechanical descaling property is deteriorated, so the coiling temperature is set to 730 ° C or higher. When the coiling temperature exceeds 840 ° C., the austenite particle size increases. In this case, the pearlite block particle diameter of the finally obtained wire cannot be adjusted to 23 μm or less, and / or the number density of pearlite blocks having a particle diameter of 40 μm or more is more than 20 / mm 2 . Accordingly, the winding temperature is set to 840 ° C. or lower. The winding temperature is preferably 750 to 820 ° C.
なお、DLP法によって本実施形態に係る線材を製造する場合、原材料である鋼片が、質量%で、Cr:0.10~1.00%、およびV:0.005~0.800%のうち1種または2種をさらに含有してもよい。 When manufacturing the wire according to the present embodiment by the DLP method, (1) component composition is mass%, C: 0.60 to 1.20%, Si: 0.30 to 1.30%, Mn: 0 .30 to 0.90%, P: 0.020% or less, S: 0.020% or less, N: 0.0025 to 0.0060%, Cr: 0 to 1.00%, and V: 0 to 0 800%, Al: 0.005 to 0.100%, Ti: 0.003 to 0.050%, B: 0.0005 to 0.0040%, or one or more of them The steel slab containing the composition containing Fe and impurities in the balance is heated to 950 to 1040 ° C., and then wire rolling is performed. (2) Winding is performed in a temperature range of 750 to 800 ° C. (3) Immediately after completion of winding, heat treatment is directly performed with molten salt at 500 to 600 ° C.
When the wire according to the present embodiment is manufactured by the DLP method, the steel slab as the raw material is in mass%, Cr: 0.10 to 1.00%, and V: 0.005 to 0.800%. One or two of them may be further contained.
DLP法によって本実施形態に係る線材を製造する場合、線材圧延に供する鋼片の成分組成は、上述の規定範囲内とする必要がある。この規定範囲は、本実施形態に係る線材の成分組成として上述された規定範囲と同一である。DLP法による製造方法は、延性および靱性の向上のための合金元素が比較的少ない鋼片から、延性および靱性に優れた線材が得られるという利点がある。ただし、DLP法による製造方法では溶融塩による直接熱処理が必須であるので、この製造方法の実施のためには、ステルモア法による製造方法よりも多くの設備が必要とされる。 (Component composition of steel slab used for wire rod rolling: within the above-mentioned specified range)
When manufacturing the wire which concerns on this embodiment by DLP method, the component composition of the steel slab used for wire rolling needs to be in the above-mentioned specified range. This specified range is the same as the specified range described above as the component composition of the wire according to the present embodiment. The production method by the DLP method has an advantage that a wire having excellent ductility and toughness can be obtained from a steel piece having relatively few alloy elements for improving ductility and toughness. However, since a direct heat treatment with a molten salt is essential in the production method by the DLP method, more equipment is required for carrying out this production method than in the production method by the Stemmore method.
DLP法によって本実施形態に係る線材を製造する場合、鋼片の線材圧延前の加熱温度を950~1040℃とする。加熱温度を950℃未満とした場合、線材圧延時のロール反力が著しく増加して、ロール割損などの設備トラブルが発生するおそれがあるので、線材圧延前の加熱温度を950℃以上とする。一方、線材圧延前の加熱温度が1040℃を超えると、鋼片中に析出している窒化アルミニウム(AlN)の溶体化が進んで、オーステナイト結晶粒径の粗大化が進み、最終的に得られる線材のパーライトブロック粒径(PBS)が粗大化する。この場合、線材軸方向に垂直な断面においてパーライトブロックの粒径の平均値が23μm超となり、および/または、40μm以上の粒径を有するパーライトブロックの個数密度が20個/mm2超となる。このような現象を回避するために、線材圧延前の加熱温度を1040℃以下とする。線材圧延前の加熱温度は、好ましくは980~1030℃である。なお、線材圧延における仕上温度は特に制限されず、合理的な温度を適宜選択することができる。 (Heating temperature for wire rolling: 950-1040 ° C)
When manufacturing the wire according to the present embodiment by the DLP method, the heating temperature of the steel slab before wire rod rolling is set to 950 to 1040 ° C. When the heating temperature is less than 950 ° C., the roll reaction force during wire rod rolling increases remarkably, and equipment troubles such as roll breakage may occur. Therefore, the heating temperature before wire rod rolling is set to 950 ° C. or higher. . On the other hand, when the heating temperature before the wire rod rolling exceeds 1040 ° C., the solution of aluminum nitride (AlN) precipitated in the steel slab proceeds, the austenite crystal grain size increases, and finally obtained. The pearlite block particle size (PBS) of the wire becomes coarse. In this case, the average value of the particle sizes of the pearlite blocks in the cross section perpendicular to the wire axis direction is more than 23 μm, and / or the number density of the pearlite blocks having a particle size of 40 μm or more is more than 20 / mm 2 . In order to avoid such a phenomenon, the heating temperature before wire rod rolling is set to 1040 ° C. or lower. The heating temperature before wire rolling is preferably 980 to 1030 ° C. In addition, the finishing temperature in wire rod rolling is not particularly limited, and a reasonable temperature can be appropriately selected.
DLP法によって本実施形態に係る線材を製造する場合、線材圧延後の巻取温度を750~800℃とする。巻取温度が750℃未満であると、後の恒温変態処理工程における恒温変態後に、線材の長手方向の引張強度のばらつきが大きくなる。従って、巻取温度を750℃以上とする。巻取温度が800℃を超えると、オーステナイト粒径が大きくなる。この場合、最終的に得られる線材のパーライトブロック粒径を23μm以下に調整することも、40μm以上の粒径を有するパーライトブロックの個数密度を20個/mm2以下に調整することもできなくなるので、巻取温度を800℃以下とする。 (Winding temperature: 750-800 ° C)
When manufacturing the wire according to the present embodiment by the DLP method, the winding temperature after wire rolling is set to 750 to 800 ° C. When the coiling temperature is less than 750 ° C., the variation in the tensile strength in the longitudinal direction of the wire increases after the constant temperature transformation in the subsequent constant temperature transformation treatment step. Accordingly, the winding temperature is set to 750 ° C. or higher. When the coiling temperature exceeds 800 ° C., the austenite particle size increases. In this case, the pearlite block particle diameter of the finally obtained wire cannot be adjusted to 23 μm or less, and the number density of pearlite blocks having a particle diameter of 40 μm or more cannot be adjusted to 20 pieces / mm 2 or less. The winding temperature is set to 800 ° C. or lower.
(恒温変態処理温度:500~600℃)
DLP法によって本実施形態に係る線材を製造する場合、線材を巻き取った後、直ちに、500~600℃の溶融塩に浸漬して恒温変態処理を行う。恒温変態処理温度が500℃未満であると、線材の表層部に非パーライト組織が多く生成する。この場合、線材の内部に生成しているパーライト組織と、線材の表層部の非パーライト組織との界面において、加工歪の不均一が生じ、この不均一は伸線加工段階で断線を生じさせる場合がある。従って、恒温変態処理の温度は500℃以上とする。恒温変態処理温度が600℃を超えると、設備の熱変形が大きくなる等の操業上の問題が生じるので、恒温変態処理温度は600℃以下とする。また、この恒温変態処理は直接熱処理(オンライン熱処理)によって行われる必要がある。もし直接熱処理が行われなかった場合(すなわち、オフライン熱処理によって恒温変態処理が行われた場合)、オフライン熱処理が含む再加熱工程によってγ粒の成長が生じる。この現象は、線材のPBSの粒径を23μm以下に制御することを妨げる。 (Constant temperature transformation treatment method: direct heat treatment)
(Constant temperature transformation treatment temperature: 500-600 ° C)
When the wire according to this embodiment is manufactured by the DLP method, the wire is wound up and immediately immersed in a molten salt at 500 to 600 ° C. to perform a constant temperature transformation treatment. When the isothermal transformation temperature is less than 500 ° C., a lot of non-pearlite structure is generated in the surface layer portion of the wire. In this case, unevenness of processing strain occurs at the interface between the pearlite structure generated inside the wire and the non-pearlite structure of the surface part of the wire, and this non-uniformity causes breakage at the wire drawing stage. There is. Therefore, the temperature of the isothermal transformation treatment is set to 500 ° C. or higher. If the isothermal transformation temperature exceeds 600 ° C., operational problems such as increased thermal deformation of the equipment occur. Therefore, the isothermal transformation temperature is set to 600 ° C. or less. Moreover, this isothermal transformation process needs to be performed by direct heat treatment (on-line heat treatment). If direct heat treatment is not performed (that is, isothermal transformation is performed by off-line heat treatment), γ grains grow by the reheating step included in off-line heat treatment. This phenomenon prevents the particle diameter of the PBS of the wire rod from being controlled to 23 μm or less.
以下、ステルモア法を用いた製造方法による実施例について説明する。 (Example)
Hereinafter, examples of the manufacturing method using the Stealmore method will be described.
さらに、上記線材から、JISZ2202で規定されたシャルピー衝撃試験片を、図4に示す採取方法で採取することにより、5mmサブサイズの2mmUノッチシャルピー衝撃試験片を作製した。これらのシャルピー衝撃試験片に-40℃でのシャルピー衝撃試験を行うことにより、LNGタンクのPC防液堤の実使用環境温度に近い-40℃の温度での線材の衝撃値を求めた。 The tensile test piece shown in FIG. 3 was manufactured from the rolled wire. Tensile strength and ductility of the wire at −40 ° C. were measured by conducting a tensile test on the tensile test piece in a low temperature atmosphere of −40 ° C. while adjusting the temperature with dry ice and alcohol.
Furthermore, a Charpy impact test piece defined in JISZ2202 was collected from the wire by the sampling method shown in FIG. 4 to produce a 2 mm U notch Charpy impact test piece of 5 mm subsize. By performing a Charpy impact test at −40 ° C. on these Charpy impact test pieces, the impact value of the wire at a temperature of −40 ° C., which is close to the actual use environment temperature of the PC liquid barrier in the LNG tank, was obtained.
2 2mmUノッチシャルピー衝撃試験片
3 2mmUノッチ 1
Claims (5)
- 成分組成が、質量%で、
C :0.60~1.20%、
Si:0.30~1.30%、
Mn:0.30~0.90%、
P :0.020%以下、
S :0.020%以下、
N :0.0025~0.0060%、
Cr:0~1.00%、および
V :0~0.800%を含有し、
更に、
Al:0.005~0.100%、
Ti:0.003~0.050%、
B :0.0005~0.0040%
のうち1種又は2種以上を含有し、
残部がFe及び不純物からなり、
線材軸方向に垂直な断面におけるパーライトブロックの粒径の平均値が23μm以下であり、
前記線材軸方向に垂直な前記断面において、40μm以上の前記粒径を有する前記パーライトブロックの個数密度が0~20個/mm2である
ことを特徴とする線材。 Ingredient composition is mass%,
C: 0.60 to 1.20%,
Si: 0.30 to 1.30%
Mn: 0.30 to 0.90%,
P: 0.020% or less,
S: 0.020% or less,
N: 0.0025 to 0.0060%,
Cr: 0 to 1.00%, and V: 0 to 0.800%,
Furthermore,
Al: 0.005 to 0.100%,
Ti: 0.003 to 0.050%,
B: 0.0005 to 0.0040%
Containing one or more of them,
The balance consists of Fe and impurities,
The average value of the particle size of the pearlite block in the cross section perpendicular to the wire axis direction is 23 μm or less,
A wire rod, wherein the number density of the pearlite blocks having the particle diameter of 40 μm or more in the cross section perpendicular to the wire rod axis direction is 0 to 20 / mm 2 . - 前記成分組成が、質量%で、
Cr:0.10~1.00%、および
V :0.005~0.800%
のうち1種又は2種を含有する
ことを特徴とする請求項1に記載の線材。 The component composition is mass%,
Cr: 0.10 to 1.00%, and V: 0.005 to 0.800%
The wire according to claim 1, wherein one or two of them are contained. - 前記成分組成が、質量%で
C :0.70~0.90%、
Si:0.80~1.30%、
Mn:0.60~0.90%、および
V :0~0.500%
を含有することを特徴とする請求項1に記載の線材。 The component composition is, by mass%, C: 0.70 to 0.90%,
Si: 0.80 to 1.30%,
Mn: 0.60 to 0.90%, and V: 0 to 0.500%
The wire according to claim 1, comprising: - 前記成分組成が、質量%で
Cr:0.50~1.00%、および
V :0.300~0.500%
のうち1種又は2種を含有する
ことを特徴とする請求項3に記載の線材。 The component composition is, in mass%, Cr: 0.50 to 1.00%, and V: 0.300 to 0.500%
The wire according to claim 3, wherein one or two of them are contained. - 請求項3又は4に記載の前記成分組成を有する鋼片を950~1040℃の粗圧延温度に加熱して粗圧延を行う工程と、
750~900℃の仕上圧延温度で線材仕上圧延を行う工程と、
次いで、730~840℃の巻取温度で巻取を行う工程と、
その後、15℃/秒以上の冷却速度で常温まで衝風冷却を行う工程と、
を備え、
前記線材仕上圧延における前記仕上圧延温度と歪み速度とが下記式Aを満たす
ことを特徴とする線材の製造方法。
13.7≦log10{(dε/dt)×exp(63800/(1.98×(T+273.15))}≦16.5 (式A)
ただし、dε/dtは前記線材仕上圧延の際の前記歪み速度を単位s-1で示し、Tは前記仕上圧延温度を単位℃で示す。 Heating the steel slab having the component composition according to claim 3 or 4 to a rough rolling temperature of 950 to 1040 ° C., and performing rough rolling;
A step of performing wire finish rolling at a finish rolling temperature of 750 to 900 ° C .;
Next, a step of winding at a winding temperature of 730 to 840 ° C.,
Thereafter, blast cooling to room temperature at a cooling rate of 15 ° C./second or more,
With
The finish rolling temperature and the strain rate in the finish finish rolling satisfy the following formula A.
13.7 ≦ log 10 {(dε / dt) × exp (63800 / (1.98 × (T + 273.15))} ≦ 16.5 (Formula A)
Where dε / dt represents the strain rate in the finish rolling of the wire in the unit s −1 , and T represents the finish rolling temperature in the unit of ° C.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14788178.3A EP2990499B1 (en) | 2013-04-25 | 2014-04-23 | Wire rod and method for manufacturing same |
KR1020157031549A KR20150138356A (en) | 2013-04-25 | 2014-04-23 | Wire rod and method for manufacturing same |
JP2015513810A JP6256464B2 (en) | 2013-04-25 | 2014-04-23 | Wire rod and manufacturing method thereof |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013-092775 | 2013-04-25 | ||
JP2013092775 | 2013-04-25 | ||
JP2013092782 | 2013-04-25 | ||
JP2013-092782 | 2013-04-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014175345A1 true WO2014175345A1 (en) | 2014-10-30 |
Family
ID=51791913
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2014/061460 WO2014175345A1 (en) | 2013-04-25 | 2014-04-23 | Wire rod and method for manufacturing same |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP2990499B1 (en) |
JP (1) | JP6256464B2 (en) |
KR (1) | KR20150138356A (en) |
WO (1) | WO2014175345A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3235918A4 (en) * | 2014-12-15 | 2018-04-25 | Nippon Steel & Sumitomo Metal Corporation | Wire material |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016014169A (en) * | 2014-07-01 | 2016-01-28 | 株式会社神戸製鋼所 | Wire rod for steel wire and steel wire |
CN112176258B (en) * | 2020-09-30 | 2022-06-21 | 江苏省沙钢钢铁研究院有限公司 | Wire rod for 2500 MPa-grade steel strand and manufacturing method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000192148A (en) * | 1998-12-25 | 2000-07-11 | Kobe Steel Ltd | Steel wire rod excellent in cold workability and its production |
JP2006234137A (en) | 2005-02-28 | 2006-09-07 | Mitsubishi Heavy Ind Ltd | Ground type lng tank |
JP2008007856A (en) * | 2006-06-01 | 2008-01-17 | Nippon Steel Corp | Method for producing high-ductility direct patenting wire rod |
JP2010229469A (en) * | 2009-03-26 | 2010-10-14 | Nippon Steel Corp | High-strength wire rod excellent in cold working characteristic and method of producing the same |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE602005019268D1 (en) * | 2004-12-22 | 2010-03-25 | Kobe Steel Ltd | High carbon steel wire with excellent drawing properties and process for its production |
BRPI0903902B1 (en) * | 2008-03-25 | 2017-06-06 | Nippon Steel & Sumitomo Metal Corp | high strength steel wire and its production method |
US9255306B2 (en) * | 2011-03-14 | 2016-02-09 | Nippon Steel & Sumitomo Metal Corporation | Steel wire rod and method of producing same |
-
2014
- 2014-04-23 KR KR1020157031549A patent/KR20150138356A/en not_active Application Discontinuation
- 2014-04-23 EP EP14788178.3A patent/EP2990499B1/en active Active
- 2014-04-23 WO PCT/JP2014/061460 patent/WO2014175345A1/en active Application Filing
- 2014-04-23 JP JP2015513810A patent/JP6256464B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000192148A (en) * | 1998-12-25 | 2000-07-11 | Kobe Steel Ltd | Steel wire rod excellent in cold workability and its production |
JP2006234137A (en) | 2005-02-28 | 2006-09-07 | Mitsubishi Heavy Ind Ltd | Ground type lng tank |
JP2008007856A (en) * | 2006-06-01 | 2008-01-17 | Nippon Steel Corp | Method for producing high-ductility direct patenting wire rod |
JP2010229469A (en) * | 2009-03-26 | 2010-10-14 | Nippon Steel Corp | High-strength wire rod excellent in cold working characteristic and method of producing the same |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3235918A4 (en) * | 2014-12-15 | 2018-04-25 | Nippon Steel & Sumitomo Metal Corporation | Wire material |
US10385427B2 (en) | 2014-12-15 | 2019-08-20 | Nippon Steel Corporation | Wire rod |
Also Published As
Publication number | Publication date |
---|---|
EP2990499A1 (en) | 2016-03-02 |
JP6256464B2 (en) | 2018-01-10 |
KR20150138356A (en) | 2015-12-09 |
EP2990499B1 (en) | 2018-07-18 |
JPWO2014175345A1 (en) | 2017-02-23 |
EP2990499A4 (en) | 2017-01-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5776398B2 (en) | Low yield ratio high strength hot rolled steel sheet with excellent low temperature toughness and method for producing the same | |
KR101728272B1 (en) | High-carbon steel wire rod and method for manufacturing same | |
WO2013147197A1 (en) | High-strength steel pipe for line pipe having excellent hydrogen-induced cracking resistance, high-strength steel pipe for line pipe using same, and method for manufacturing same | |
WO2014041801A1 (en) | Hot-rolled steel sheet and method for manufacturing same | |
WO2014041802A1 (en) | Hot-rolled steel sheet and method for manufacturing same | |
JP2006291291A (en) | Steel wire for cold formed spring having excellent corrosion resistance, and method for producing the same | |
KR20140027470A (en) | Low-yield-ratio high-strength hot-rolled steel plate with excellent low-temperature toughness and process for producing same | |
JP7155702B2 (en) | Thick steel plate for sour linepipe and its manufacturing method | |
JP5834534B2 (en) | High strength low yield ratio steel with high uniform elongation characteristics, manufacturing method thereof, and high strength low yield ratio welded steel pipe | |
KR101572775B1 (en) | Rolled wire rod, and method for producing same | |
JP2012172256A (en) | Low yield ratio high strength hot rolled steel sheet having excellent low temperature toughness and method for manufacturing the same | |
JP2017057449A (en) | Steel sheet excellent in sour resistance and production method therefor | |
JP2018104746A (en) | Steel material for linepipe and manufacturing method therefor | |
JP2018104757A (en) | Steel material for linepipe and manufacturing method therefor | |
JP6519024B2 (en) | Method of manufacturing low yield ratio high strength hot rolled steel sheet excellent in low temperature toughness | |
JP4980172B2 (en) | Manufacturing method of high-strength ultrafine steel wire with excellent balance of strength and ductility | |
JP6288265B2 (en) | Steel wire | |
JP6812893B2 (en) | Electric pipe for line pipe and its manufacturing method | |
JP5640899B2 (en) | Steel for line pipe | |
JP6256464B2 (en) | Wire rod and manufacturing method thereof | |
JP2010229469A (en) | High-strength wire rod excellent in cold working characteristic and method of producing the same | |
JP2006009078A (en) | Seamless steel pipe for oil well use having excellent expandability | |
KR20170043662A (en) | Steel strip for electric-resistance-welded steel pipe or tube, electric-resistance-welded steel pipe or tube, and process for producing steel strip for electric-resistance-welded steel pipe or tube | |
WO2020166637A1 (en) | Steel pipe for fuel injection pipe, and fuel injection pipe employing same | |
JP2019065343A (en) | Steel pipe for oil well and manufacturing method therefor |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 14788178 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2015513810 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2014788178 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 20157031549 Country of ref document: KR Kind code of ref document: A |