WO2014174239A1

WO2014174239A1 - Radiant burner

Info

Publication number: WO2014174239A1
Application number: PCT/GB2014/050779
Authority: WO
Inventors: Andrew James Seeley
Original assignee: Edwards Limited
Priority date: 2013-04-25
Filing date: 2014-03-14
Publication date: 2014-10-30
Also published as: GB201307489D0; CN105121957A; TW201502438A; EP2989387B1; JP6318235B2; EP2989387A1; CN105121957B; GB2513384A; US20160153655A1; US10161628B2; KR102277236B1; JP2016522379A; KR20160003670A; TWI661157B

Abstract

A radiant burner and method are disclosed. The radiant burner is for treating an effluent gas stream from a manufacturing process tool and comprises: a combustion chamber having a porous sleeve through which combustion materials pass for combustion proximate to a combustion surface of said porous sleeve; and a plenum surrounding said porous sleeve supplying said combustion materials to said porous sleeve, said plenum being configured to provide said combustion materials with varying stoichiometry along a length of said porous sleeve. This approach of varying the stoichiometric ratios of the combustion materials correspondingly varies the heat generated by those combustion materials along the length of the porous sleeve. By varying the stoichiometry of the combustion materials to compensate for variations in the heat generated within the combustion chamber along the length of the porous sleeve, a more uniform temperature can be achieved along the length of the porous sleeve within the combustion chamber.

Description

RADIANT BURNER

FIELD OF THE INVENTION

The present invention relates to a radiant burner and method.

BACKGROUND

Radiant burners are known and are typically used for treating an effluent gas stream from a manufacturing process tool used in, for example, the semiconductor or flat panel display manufacturing industry. During such manufacturing, residual perfluorinated compounds (PFCs) and other compounds exist in the effluent gas stream pumped from the process tool. PFCs are difficult to remove from the effluent gas and their release into the environment is undesirable because they are known to have relatively high greenhouse activity. Known radiant burners use combustion to remove the PFCs and other compounds from the effluent gas stream. Typically, the effluent gas stream is a nitrogen stream containing PFCs and other compounds. A fuel gas is mixed with the effluent gas stream and that gas stream mixture is conveyed into a combustion chamber that is laterally surrounded by the exit surface of a foraminous gas burner. Fuel gas and air are simultaneously supplied to the foraminous burner to affect flameless combustion at the exit surface, with the amount of air passing through the foraminous burner being sufficient to consume not only the fuel gas supplied to the burner, but also all the combustibles in the gas stream mixture injected into the combustion chamber. Although techniques exist for processing the effluent gas stream, they each have their own shortcomings. Accordingly, it is desired to provide an improved technique for processing an effluent gas stream.

SUMMARY

According to a first aspect, there is provided a radiant burner for treating an effluent gas stream from a manufacturing process tool, the radiant burner comprising: a combustion chamber having a porous sleeve through which combustion materials pass for combustion proximate to a combustion surface of the porous sleeve; and a plenum surrounding the porous sleeve supplying the combustion materials to the porous sleeve, the plenum being configured to provide the combustion materials with varying stoichiometry along a length of the porous sleeve.

The first aspect recognises that a problem with existing radiant burners is that conditions within the combustion chamber can lead to variations in temperature within the combustion chamber, which ought to be as uniform as possible. In particular, the first aspect recognises that temperature variations along the length of the combustion chamber can reduce the efficiency and life of the radiant burner.

Accordingly, a radiant burner which may treat an effluent gas stream may be provided. The radiant burner may comprise a combustion chamber which may have a porous sleeve through which combustion materials may pass in order to combust approximate or adjacent to a combustion surface of the porous sleeve. A plenum may be provided which surrounds the porous sleeve and which supplies the combustion materials to the porous sleeve. The plenum may be configured, adapted or arranged to provide combustion materials with a varying or differing stoichiometry along the length of the porous sleeve. This approach of varying the stoichiometric ratios of the combustion materials correspondingly varies the heat generated by those combustion materials along the length of the porous sleeve. By varying the stoichiometry of the combustion materials to compensate for variations in the heat generated within the combustion chamber along the length of the porous sleeve, a more uniform temperature can be achieved along the length of the porous sleeve within the combustion chamber.

In one embodiment, the combustion chamber extends axially from an effluent gas stream inlet from which the effluent gas is provided to the combustion chamber to an exhaust from which treated effluent gas is exhausted and the plenum is configured to provide the combustion materials with varying stoichiometry along an axial length of the porous sleeve. Hence the combustions may be provided in different stoichiometric ratios along the axial length of the porous sleeve. In one embodiment, the plenum is configured to increase the stoichiometry of an oxidant of the combustion materials towards the effluent gas stream inlet. Accordingly, a more lean combustion material may be provided in the vicinity of the effluent gas stream inlet in order to reduce the heat generated by the combustion materials in a region where high amounts of heat are generated due to combustion of the effluent gas stream. This may be achieved by increasing the ratio of oxidant (or decreasing the ratio of fuel) in the combustion materials towards the inlet. Embodiments recognise that more heat is generated in the vicinity of the effluent gas stream inlet which, with a uniform stoichiometry of combustion materials along the length of the combustion chamber, would lead to this region becoming much hotter than elsewhere and which can lead to sintering or degradation of the porous sleeve.

In one embodiment, the plenum is configured to decrease the stoichiometry of an oxidant of the combustion materials towards the exhaust. Accordingly, a more rich combustion material may be provided in the vicinity of the exhaust in order to increase the heat generated by the combustion materials in a region where high amounts of heat loss occurs. This may be achieved by decreasing the ratio of oxidant (or increasing the ratio of fuel) in the combustion materials towards the exhaust. Embodiments recognise that a high degree of heat loss can occur in the vicinity of the exhaust, due to the cooling effects of any downstream processing apparatus, such as a weir. This again helps to create a more uniform temperature along the length of the porous sleeve.

In one embodiment, the plenum is configure to increase the stoichiometry of an oxidant of the combustion materials towards the effluent gas stream inlet compared to the stoichiometry of an oxidant of the combustion materials towards the exhaust.

Accordingly, the stoichiometric ratios of the combustion material are configured increase the amount of excess oxidant (and/or decrease the amount of excess fuel) towards the gas stream inlet compared to that in the vicinity of the exhaust. In one embodiment, the plenum is configure to decrease the stoichiometry of an oxidant of the combustion materials towards the exhaust compared to the stoichiometry of an oxidant of the combustion materials towards the effluent gas stream inlet. Accordingly, the stoichiometric ratios of the combustion material are configured decrease the amount of excess oxidant (and/or increase the amount of excess fuel) towards the exhaust inlet compared to that in the vicinity of the inlet. In one embodiment, the combustion materials comprise a fuel and oxidant mixture and the plenum is configured to lower a fuel to oxidant ratio towards the effluent gas stream inlet.

In one embodiment, the combustion materials comprise a fuel and oxidant mixture and the plenum is configured to raise a fuel to oxidant ratio towards the exhaust.

In one embodiment, the combustion materials comprise a fuel and oxidant mixture and the plenum is configured to lower a fuel to oxidant ratio towards the effluent gas stream inlet compared to a fuel to oxidant ratio towards the exhaust.

In one embodiment, the combustion materials comprise a fuel and oxidant mixture and the plenum is configured to raise a fuel to oxidant ratio towards the exhaust compared to a fuel to oxidant ratio towards the effluent gas stream inlet. In one embodiment, the plenum comprises a combustion materials inlet which provides the combustion materials to the plenum and an oxidant inlet which provides oxidant in a vicinity of the effluent gas stream inlet to increase the stoichiometry of the oxidant of the combustion materials towards the effluent gas stream inlet.

Adding additional oxidant in the vicinity of the inlet creates a leaner mixture by decreasing the ratio of fuel and decreases the stoichiometric excess fuel near the inlet.

In one embodiment, the plenum comprises an oxidant inlet baffle in a vicinity of the oxidant inlet to create a region of increased stoichiometry of the oxidant of the combustion materials towards the effluent gas stream inlet. Providing a baffle helps to prevent mixing of different regions of differing stoichiometry combustion materials in order to provide varying stoichiometric ratios of oxidant along the length of the porous sleeve. In one embodiment, the plenum comprises a combustion materials inlet which provides the combustion materials to the plenum and a fuel inlet which provides fuel in a vicinity of the exhaust to decrease the stoichiometry of an oxidant of the combustion materials towards the exhaust. Adding additional fuel in the vicinity of the exhaust creates a richer mixture by increasing the ratio of fuel and decreases the stoichiometric excess oxidant near the exhaust.

In one embodiment, the plenum comprises a fuel inlet baffle in a vicinity of the fuel inlet to create a region of decreased stoichiometry of an oxidant of the combustion materials towards the exhaust.

In one embodiment, at least one of the fuel inlet baffle and the exhaust inlet baffle reduce fluid communication between a region in a vicinity of the combustion materials inlet and regions in a vicinity of the fuel inlet and the oxidant inlet to vary the stoichiometry of an oxidant in these regions.

In one embodiment, the plenum comprises a plurality of adjacent plenums, each providing combustion materials with differing stoichiometry. Accordingly, a number of separate, adjacent plenums may be provided along the length of the porous sleeve in order to supply combustion materials with differing stoichiometry.

According to a second aspect, there is provided a method of treating an effluent gas stream from a manufacturing process tool, the method comprising: combusting combustion materials proximate to a combustion surface of a porous sleeve of a combustion; supplying the combustion materials to the porous sleeve from a plenum surrounding the porous sleeve with varying stoichiometry along a length of the porous sleeve. In one embodiment, the combustion chamber extends axially from an effluent gas stream inlet from which the effluent gas is provided to the combustion chamber to an exhaust from which treated effluent gas is exhausted and the step of supplying comprises supplying the combustion materials with varying stoichiometry along an axial length of the porous sleeve.

In one embodiment, the step of supplying comprises increasing the stoichiometry of an oxidant of the combustion materials towards the effluent gas stream inlet.

In one embodiment, the step of supplying comprises decreasing the stoichiometry of an oxidant of the combustion materials towards the exhaust. In one embodiment, the step of supplying comprises increasing the stoichiometry of an oxidant of the combustion materials towards the effluent gas stream inlet compared to the stoichiometry of an oxidant of the combustion materials towards the exhaust.

In one embodiment, the step of supplying comprises decreasing the stoichiometry of an oxidant of the combustion materials towards the exhaust compared to the stoichiometry of an oxidant of the combustion materials towards the effluent gas stream inlet.

In one embodiment, the combustion materials comprise a fuel and oxidant mixture and the step of supplying comprises lowering a fuel to oxidant ratio towards the effluent gas stream inlet.

In one embodiment, the combustion materials comprise a fuel and oxidant mixture and the step of supplying comprises raising a fuel to oxidant ratio towards the exhaust. In one embodiment, the combustion materials comprise a fuel and oxidant mixture and the step of supplying comprises lowering a fuel to oxidant ratio towards the effluent gas stream inlet compared to a fuel to oxidant ratio towards the exhaust.

In one embodiment, the combustion materials comprise a fuel and oxidant mixture and the step of supplying comprises raising a fuel to oxidant ratio towards the exhaust compared to a fuel to oxidant ratio towards the effluent gas stream inlet. In one embodiment, the step of supplying comprises providing the combustion materials to the plenum using a combustion materials inlet and providing oxidant to the plenum in a vicinity of the effluent gas stream inlet using an oxidant inlet which to increase the stoichiometry of the oxidant of the combustion materials towards the effluent gas stream inlet.

In one embodiment, the step of supplying comprises creating a region of increased stoichiometry of the oxidant of the combustion materials towards the effluent gas stream inlet using an oxidant inlet baffle in a vicinity of the oxidant inlet.

In one embodiment, the step of supplying comprises providing the combustion materials to the plenum using a combustion materials inlet and providing fuel to the plenum using a fuel inlet in a vicinity of the exhaust to decrease the stoichiometry of an oxidant of the combustion materials towards the exhaust.

In one embodiment, the step of supplying comprises creating a region of decreased stoichiometry of an oxidant of the combustion materials towards the exhaust using a fuel inlet baffle in a vicinity of the fuel inlet. In one embodiment, the step of supplying comprises reducing fluid communication between a region in a vicinity of a combustion materials inlet and regions in a vicinity of the fuel inlet and the oxidant inlet to vary the stoichiometry of an oxidant in these regions. In one embodiment, the step of supplying comprises providing combustion materials with differing stoichiometry to a plurality of adjacent plenums.

Further particular and preferred aspects are set out in the accompanying independent and dependent claims. Features of the dependent claims may be combined with features of the independent claims as appropriate, and in combinations other than those explicitly set out in the claims. Where an apparatus feature is described as being operable to provide a function, it will be appreciated that this includes an apparatus feature which provides that function or which is adapted or configured to provide that function. BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments of the present invention will now be described further, with reference to the accompanying drawings, in which:

Figures 1A and IB illustrate a radiant burner according to embodiments. DESCRIPTION OF THE EMBODIMENTS

Overview

Before discussing the embodiments in any more detail, first an overview will be provided. Embodiments provide a radiant burner arrangement which is used in the processing of an effluent gas stream. In particular, the radiant burner is arranged to provide a variable stoichiometry of the combustion materials along the length of the porous sleeve of the burner. That is to say, the radiant burner is arranged to provide variable stoichiometric ratios of the materials which comprise the combustion materials within the burner in order to reduce temperature variation within the burner. For example, if a central or middle region of the burner is operating at a nominal surface firing rate and using combustion materials with a desired nominal stoichiometry (i.e. with a nominal ratio of fuel to oxidant), then it is beneficial to be able to operate the upper parts of the burner (those parts closest to the inlet which receives the effluent gas stream) lean (that is to reduce the ratio of fuel to oxidant compared to the nominal ratio) to reduce surface temperatures and minimise thermal degradation of the porous sleeve. Likewise, it is beneficial to operate the lower regions of the burner (those parts closest to the exhaust) rich (that is to increase the ratio of fuel to oxidant compared to the nominal ratio) in order to increase temperature and counter the thermal losses due to radiation onto any cooled surfaces of any cooling weir located in proximity to the exhaust.

One embodiment feeds a main burner plenum area with a normal fuel-air premix and provides a second plenum area fed with a more fuel-rich premix at the lower regions of the burner. Another embodiment feeds the top of the plenum with a lean mixture and the bottom of the plenum with a rich mixture and allows for an intermediate, normal fuel-air premix in a middle region. Another embodiment operates the whole fuel burner with a normal fuel-air premix and adds extra air to the upper parts and/or extra fuel to the lower parts.

In one embodiment, the stoichiometric excess of oxidant is increased towards the inlet which receives the effluent gas. This causes these regions to operate lean and reduce surface temperatures to minimise thermal degradation. Likewise, the stoichiometric excess of oxidant to fuel is decreased towards the exhaust in order to operate this part of the burner rich to increase surface temperatures in this region. This helps to provide more uniform temperatures along the length of the burner.

All of these arrangements provide for a variable stoichiometry of the combustion materials along the length of the porous sleeve in order to vary the heat generated along the length of the porous sleeve in order to reduce the variation of temperature within the combustion chamber. For example, when considering the stoichiometry in terms of a post-combustion oxygen concentration (i.e. the residual oxygen following combustion of the combustion materials on exit surface of the foraminous burner), a nominal residual oxygen concentration of around 9% to 9.5% may be provided, whilst a residual oxygen concentration of around 7.5% to 8.5% may be provided within the fuel-rich region towards the exhaust and a residual oxygen concentration of around 9.5% to 10.5% (such as 10%) may be provided within the fuel-lean region towards the inlet. It will be appreciated that these values will vary from fuel to fuel; for example, a burner using propane or liquefied petroleum gas (LPG) will be operated at slightly higher residual oxygen levels than the same burner using methane or natural gas.

Radiant Burner - General Configuration and Operation

Figures 1A and IB illustrate two radiant burners, generally 8A and 8B, according to embodiments. Figures 1A and IB each illustrate a respective halve of a radiant burner, which are symmetrical about the axis A-A. Both the radiant burners 8A; 8B treat an effluent gas stream pumped from a manufacturing process tool such as a semiconductor or flat panel display process tool, typically by means of a vacuum-pumping system. The effluent stream is received at inlets 10. The effluent stream is conveyed from the inlet 10 to a nozzle 12 which injects the effluent stream into a cylindrical combustion chamber 14. In these embodiments, the radiant burners 8A; 8B each comprise four inlets 10 arranged circumferentially, each conveying an effluent gas stream pumped from a respective tool by a respective vacuum-pumping system. Alternatively, the effluent stream from a single process tool may be split into a plurality of streams, each one of which is conveyed to a respective inlet. Each nozzle 12 is located within a respective bore 16 formed in a ceramic top plate 18 which defines an upper or inlet surface of the combustion chamber 14. The combustion chamber 14 has side walls defined by an exit surface 21 of a foraminous burner element 20, such as that described in EP0694735. The burner element 20 is cylindrical and is retained within a cylindrical outer shell 24.

As will be described in more detail below, a plenum volume 22A, 22B is defined between an entry surface of the burner element 20 and the cylindrical outer shell 24. A mixture of fuel gas, such as natural gas or a hydrocarbon, and air is introduced into the plenum volume 22A, 22B via inlet nozzles. The mixture of fuel gas and air passes from the entry surface 23 of the burner element to the exit surface 21 of the burner element for combustion within the combustion chamber 14.

The nominal ratio of the mixture of fuel gas and air is varied to vary the nominal temperature within the combustion chamber 14 to that which is appropriate for the effluent gas stream to be treated. Also, the rate at which the mixture of fuel gas and air is introduced into the plenum volume 22A, 22B is adjusted so that the mixture will burn without visible flame at the exit surface 21 of the burner element 20. The exhaust 15 of the combustion chamber 40 is open to enable the combustion products to be output from the radiant burner 8 A, 8B.

Accordingly, it can be seen that the effluent gas received through the inlets 10 and provided by the nozzles 12 to the combustion chamber 14 is combusted within the combustion chamber 14 which is heated by a mixture of fuel gas and air which combusts near the exit surface 21 of the burner element. Such combustion causes heating of the chamber 14 and provides combustion products, such as oxygen, typically with a nominal range of 7.5 % to 10.5 %, depending on the fuel air mixture (CH₄, C3¾, C4H10), provided to the combustion chamber 14. The heat and combustion products react with the effluent gas stream within the combustion chamber 14 to clean the effluent gas stream. For example, SiH₄ and NH3 may be provided within the effluent gas stream, which reacts with O2 within the combustion chamber to generate S1O2, N2, H2O, NOX. Similarly, N2, CH₄, C2F6 may be provided within the effluent gas stream, which reacts with O2 within the combustion chamber to generate CO2, HF, H2O. Baffled Plenum Arrangement

Turning now to the arrangement of the plenum 22A of the radiant burner 8A of Figure 1A, an upper baffle 100A and a lower baffle lOOC are provided. An inlet 120B is provided which provides a fuel air mixture to a region 110B within the plenum 22A. An air inlet 120A is provided which feeds air to a region 130A enclosed by the upper baffle 100A. An inlet 120C is provided which feeds fuel into a region 130C enclosed by the lower baffle lOOC.

The upper baffle 100A is provided with vents 140A through which air from the region 130A can mix in a region 110A within the plenum 22A with the fuel air mixture from the region 110B in order to create the region 130A where the mixture is lean.

Likewise, the lower baffle lOOC is provided with vents HOC through which the fuel within the region 130C can mix with the fuel air mixture from the region 110B in order to enrich the fuel air mixture within the region 1 IOC.

Accordingly, the provision of the lower and upper baffles 100A; lOOC enables the stoichiometry of the fuel air mixture to be varied along the length of the plenum 22A. This enables the heat generated along the length of the foraminous burner 20 to be adjusted in order to compensate for increases in temperature which would otherwise occur towards the nozzles 12, which can cause thermal damage, and the decrease in temperature that would otherwise occur towards the exhaust 15 which would lead to incomplete processing of the effluent gas stream. Although two different baffles 100A, lOOC and three inlets 120A-C are shown, it will be appreciated that alternative arrangements may be utilised to vary the stoichiometry of the combustion materials, as mentioned above.

Multiple Plenum Arrangements

Figure IB illustrates a radiant burner 8B according to one embodiment, having a plenum 22B formed of three adjacent sections 200A, 200B, 200C. In this arrangement, an inlet 220A feeds the plenum section 200A with a fuel air mixture which is lean and has been enhanced with a stoichiometric excess of oxidant. Hence, region 200A has a lower ratio of fuel to air than that provided to regions 200B or 200C. An inlet 220B provides a fuel air mixture to the plenum section 200B having a nominal fuel-to-air ratio, which has a higher proportion of fuel than that provided to the region 200 A. An inlet 220C provides a fuel air mixture having stoichiometric excess of fuel to the region 200C. Hence, region 200C has a higher ratio of fuel to air than that provided to regions 200 A or 200B.

As with the arrangement described above, this enables a fuel air mixture to be provided to the foraminous burner 20 with variable stoichiometry along its length in order to vary the heat generation along the length of the foraminous burner in order to compensate for excessive heat being produced towards the inlet and insufficient heat being produced towards the exhaust 15.

Although illustrative embodiments of the invention have been disclosed in detail herein, with reference to the accompanying drawings, it is understood that the invention is not limited to the precise embodiment and that various changes and modifications can be effected therein by one skilled in the art without departing from the scope of the invention as defined by the appended claims and their equivalents.

Claims

1. A radiant burner for treating an effluent gas stream from a manufacturing process tool, said radiant burner comprising:

a combustion chamber having a porous sleeve through which combustion materials pass for combustion proximate to a combustion surface of said porous sleeve; and

a plenum surrounding said porous sleeve supplying said combustion materials to said porous sleeve, said plenum being configured to provide said combustion materials with varying stoichiometry along a length of said porous sleeve.

2. The radiant burner of claim 1, wherein said combustion chamber extends axially from an effluent gas stream inlet from which said effluent gas is provided to said combustion chamber to an exhaust from which treated effluent gas is exhausted and said plenum is configured to provide said combustion materials with varying stoichiometry along an axial length of said porous sleeve.

3. The radiant burner of claim 1 or 2, wherein said plenum is configured to at least one of: increase said stoichiometry of an oxidant of said combustion materials towards said effluent gas stream inlet; and decrease said stoichiometry of an oxidant of said combustion materials towards said exhaust.

4. The radiant burner of any preceding claim, wherein said plenum is configure to at least one of: increase said stoichiometry of an oxidant of said combustion materials towards said effluent gas stream inlet compared to said stoichiometry of an oxidant of said combustion materials towards said exhaust; and decrease said stoichiometry of an oxidant of said combustion materials towards said exhaust compared to said

stoichiometry of an oxidant of said combustion materials towards said effluent gas stream inlet.

5. The radiant burner of any preceding claim, wherein said combustion materials comprise a fuel and oxidant mixture and said plenum is configured to lower a fuel to oxidant ratio towards said effluent gas stream inlet.

6. The radiant burner of any preceding claim, wherein said combustion materials comprise a fuel and oxidant mixture and said plenum is configured to raise a fuel to oxidant ratio towards said exhaust.

7. The radiant burner of any preceding claim, wherein said combustion materials comprise a fuel and oxidant mixture and said plenum is configured to lower a fuel to oxidant ratio towards said effluent gas stream inlet compared to a fuel to oxidant ratio towards said exhaust.

8. The radiant burner of any preceding claim, wherein said combustion material comprise a fuel and oxidant mixture and said plenum is configured to raise a fuel to oxidant ratio towards said exhaust compared to a fuel to oxidant ratio towards said effluent gas stream inlet.

9. The radiant burner of any preceding claim, wherein said plenum comprises a combustion materials inlet which provides said combustion materials to said plenum and an oxidant inlet which provides oxidant in a vicinity of said effluent gas stream inlet to increase said stoichiometry of said oxidant of said combustion materials towards said effluent gas stream inlet.

10. The radiant burner of any preceding claim, wherein said plenum comprises an oxidant inlet baffle in a vicinity of said oxidant inlet to create a region of increased stoichiometry of said oxidant of said combustion materials towards said effluent gas stream inlet.

11. The radiant burner of any preceding claim, wherein said plenum comprises a combustion materials inlet which provides said combustion materials to said plenum and a fuel inlet which provides fuel in a vicinity of said exhaust to decrease said stoichiometry of an oxidant of said combustion materials towards said exhaust.

12. The radiant burner of any preceding claim, wherein said plenum comprises a fuel inlet baffle in a vicinity of said fuel inlet to create a region of decreased

stoichiometry of an oxidant of said combustion materials towards said exhaust.

13. The radiant burner of any preceding claim, wherein at least one of said fuel inlet baffle and said exhaust inlet baffle reduce fluid communication between a region in a vicinity of said combustion materials inlet and regions in a vicinity of said fuel inlet and said oxidant inlet to vary said stoichiometry of an oxidant in these regions.

14. The radiant burner of any preceding claim, wherein said plenum comprises a plurality of adjacent plenums, each providing combustion materials with differing stoichiometry.

15. A method of treating an effluent gas stream from a manufacturing process tool, said method comprising:

combusting combustion materials proximate to a combustion surface of a porous sleeve of a combustion;

supplying said combustion materials to said porous sleeve from a plenum surrounding said porous sleeve with varying stoichiometry along a length of said porous sleeve.