WO2014154698A2 - Dispositif comprenant une composition de rouge a levres liquide anhydre et un element d'application poreux - Google Patents

Dispositif comprenant une composition de rouge a levres liquide anhydre et un element d'application poreux Download PDF

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Publication number
WO2014154698A2
WO2014154698A2 PCT/EP2014/055975 EP2014055975W WO2014154698A2 WO 2014154698 A2 WO2014154698 A2 WO 2014154698A2 EP 2014055975 W EP2014055975 W EP 2014055975W WO 2014154698 A2 WO2014154698 A2 WO 2014154698A2
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group
monomers
carbon atoms
formula
composition
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PCT/EP2014/055975
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English (en)
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WO2014154698A3 (fr
Inventor
Florence Lahousse
Eric Caulier
Roberto Cavazzuti
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L'oreal
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Publication of WO2014154698A2 publication Critical patent/WO2014154698A2/fr
Publication of WO2014154698A3 publication Critical patent/WO2014154698A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
    • A45D34/042—Appliances specially adapted for applying liquid, e.g. using roller or ball using a brush or the like
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/001—Preparations for care of the lips
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00—Details not otherwise provided for in A45D
    • A45D2200/05—Details of containers
    • A45D2200/054—Means for supplying liquid to the outlet of the container
    • A45D2200/055—Piston or plunger for supplying the liquid to the applicator
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00—Details not otherwise provided for in A45D
    • A45D2200/10—Details of applicators
    • A45D2200/1009—Applicators comprising a pad, tissue, sponge, or the like
    • A45D2200/1018—Applicators comprising a pad, tissue, sponge, or the like comprising a pad, i.e. a cushion-like mass of soft material, with or without gripping means
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
    • A45D34/042—Appliances specially adapted for applying liquid, e.g. using roller or ball using a brush or the like
    • A45D34/045—Appliances specially adapted for applying liquid, e.g. using roller or ball using a brush or the like connected to the cap of the container
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/31—Anhydrous
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/544—Dendrimers, Hyperbranched polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/80—Siloxanes having aromatic substituents, e.g. phenyl side groups

Definitions

  • the subject of the present invention is an application device comprising a container, an anhydrous liquid composition intended to be applied to the lips, and an application member which has a porous application surface.
  • the present invention relates to the field of making up and/or caring for the lips using fluid compositions.
  • the formulations corresponding to liquid galenical formulations conventionally comprise oils, which in particular provide gloss, optionally waxes for structuring the compositions, fillers, in particular for thickening the composition, film-forming polymers, and colorants.
  • compositions providing coverage it is important for the latter to be easy to apply to the lips, precisely and as an even layer.
  • the deposit is not expected to migrate, which would result in the outline of the lips being made imprecise.
  • the deposit is relatively thick, thereby giving it a more or less tacky nature, in particular induced by the use of these oils and of the polymers present. This nature is in particular reflected by a phenomenon of the made up lips sticking to one another, which is therefore unpleasant in terms of comfort for the user.
  • compositions which at the same time provide very good coverage of the lips, as a precise deposit, which do not migrate, and for which the tacky nature has been virtually dispensed with, are therefore sought.
  • anhydrous composition for making up and/or caring for the lips, stored in the container comprising:
  • the present invention also relates to a process for making up and/or caring for the lips, in which the composition of the abovementioned device is applied to the lips by means of the application member.
  • FIG. 1 is a sectional view of an application device according to a first embodiment
  • FIG. 2 is an exploded view of an application device according to a second embodiment
  • FIG. 3 is a sectional view of the device of Figure 2.
  • the deposit made on the lips by means of the present invention makes it possible to obtain an extremely thin deposit, in particular of about 5 ⁇ to 40 ⁇ , preferably of less than 35 ⁇ , measured before drying (wet deposit).
  • This film is so thin that it has the advantage of being virtually imperceptible by the user.
  • this deposit is not tacky. It also does not provide a feeling of dryness on the lips.
  • the deposit can be obtained in a single pass, precisely, with neither running nor migration on application. These qualities of absence of migration of the composition are found over time.
  • composition according to the invention is in an anhydrous liquid form.
  • liquid is intended to mean a fluid texture, the viscosity of which at 25°C is more particularly between 1 and 25 Pa.s, preferably between 2 and 20 Pa.s and even more advantageously between 4 and 17 Pa.s.
  • the viscosity at 25°C of a composition according to the invention is between 5 and 16 Pa.s.
  • the viscosity measurement is generally performed at 25°C, using a Rheomat RM180 viscometer equipped with a No. 2, 3 or 4 spindle, the measurement being performed after 10 minutes of rotation of the spindle in the composition (after which time stabilization of the viscosity and of the spin speed of the spindle are observed), at a shear rate of 200 rpm.
  • anhydrous composition is intended to mean a composition containing less than 5%, preferably less than 2%, preferably less than 0.5% by weight of water, relative to the total weight of the composition. Where appropriate, such small amounts of water may be introduced by means of ingredients of the composition which contain same in residual amounts, but are not intentionally introduced.
  • the composition comprises at least one non- volatile oil. More particularly, the content of non- volatile oil(s) is at least 5% by weight relative to the total weight of the composition, and advantageously at least 8% by weight. Preferably, the content of non- volatile oil(s) is between 10%> and 30%> by weight relative to the weight of the composition.
  • the non-volatile oil(s) is (are) more particularly chosen from non-volatile silicone oils, which may or may not be phenylated, non- volatile fluoro oils, polar or non-polar non- volatile hydrocarbon-based oils, or mixtures thereof.
  • oil is intended to mean a non aqueous compound, non miscible in water, liquid, at 25°C and atmospheric pressure (760mmHg; 1.013.10 5 Pa).
  • non- volatile is intended to mean an oil of which the vapour pressure at 25°C and atmospheric pressure is non-zero and is less than 0.02 mmHg (2.66 Pa) and better still less than 10 "3 mmHg (0.13 Pa).
  • silicon oil is intended to mean an oil containing at least one silicon atom, and in particular containing Si-0 groups.
  • non-phenylated silicone oil denotes a silicone oil which does not have a phenyl substituent.
  • non- volatile non-phenylated silicone oils which may be mentioned include polydimethylsiloxanes; alkyl dimethicones; vinylmethyl methicones; and also silicones modified with aliphatic groups and/or with functional groups such as hydroxyl, thiol and/or amine groups.
  • the non-volatile non-phenylated silicone oil is preferably chosen from non-volatile dimethicone oils.
  • oils can be chosen from the following non- volatile oils: - polydimethylsiloxanes (PDMSs),
  • - PDMSs comprising aliphatic groups, in particular alkyl or alkoxy groups, which are pendent and/or at the end of the silicone chain, these groups each comprising from 2 to 24 carbon atoms.
  • alkyl or alkoxy groups which are pendent and/or at the end of the silicone chain, these groups each comprising from 2 to 24 carbon atoms.
  • - PDMSs comprising aliphatic groups, or functional groups such as hydroxyl, thiol and/or amine groups,
  • these non-volatile non-phenylated silicone oils are chosen from polydimethylsiloxanes; alkyl dimethicones and also PDMSs comprising aliphatic groups, in particular C2-C24 alkyl groups, and/or functional groups such as hydroxyl, thiol and/or amine groups.
  • -phenylated silicone oil may be chosen in particular from silicones of formula (I)
  • Pvi, P 2, P 5 and P 6 are, together or separately, an alkyl radical containing 1 to 6 carbon atoms
  • P 3 and P are, together or separately, an alkyl radical containing from 1 to 6 carbon atoms, a vinyl radical, an amine radical or a hydroxyl radical
  • X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or an amine radical,
  • n and p are integers chosen so as to have a fluid compound, in particular of which the viscosity at 25°C is between 9 centistokes (cSt) (9 x 10 "6 m 2 /s) and 800 000 cSt.
  • non- volatile non-phenylated silicon oils which can be used according to the invention, mention may be made of those for which:
  • the substituents Ri to P 6 and X represent a methyl group
  • p and n are such that the viscosity is 500 000 cSt, for example the product sold under the name SE30 by the company General Electric, the product sold under the name AK 500000 by the company Wacker, the product sold under the name Mirasil DM 500 000 by the company Bluestar, and the product sold under the name Dow Corning 200 Fluid 500 000 cSt by the company Dow Corning,
  • the substituents Ri to and X represent a methyl group
  • p and n are such that the viscosity is 60 000 cSt, for example the product sold under the name Dow Corning 200 Fluid 60 000 CS by the company Dow Corning, and the product sold under the name Wacker Belsil DM 60 000 by the company Wacker,
  • the substituents Ri to R6 and X represent a methyl group, and p and n are such that the viscosity is 100 cSt or 350 cSt, for example the products sold respectively under the names Belsil DM100 and Dow Corning 200 Fluid 350 CS by the company Dow Corning,
  • the substituents Ri to R6 represent a methyl group
  • the group X represents a hydroxyl group
  • n and p are such that the viscosity is 700 cSt, for example the product sold under the name Baysilone Fluid TO.7 by the company Momentive.
  • phenylated silicone oil or "phenyl silicone oil” denotes a silicone oil having at least one phenyl substituent.
  • non-volatile phenylated silicone oils can be chosen from those which also have at least one dimethicone fragment, or from those which do not have one.
  • a dimethicone fragment corresponds to the following unit: -Si(CH3)2-0-.
  • the non- volatile phenylated silicone oil may thus be chosen from: a) phenyl silicone oils optionally having a dimethicone fragment corresponding to the following formula (I):
  • the groups R which are monovalent or divalent, represent, independently of each other, a methyl or a phenyl, with the proviso that at least one group R represents a phenyl.
  • the phenyl silicone oil comprises at least three, for example at least four, at least five or at least six, phenyl groups.
  • phenyl silicone oils optionally having a dimethicone fragment corresponding to the following formula (II): R R R
  • groups R represent, independently of each other, a methyl or a phenyl, with the proviso that at least one group R represents a phenyl.
  • the compound of formula (II) comprises at least three, for example at least four or at least five, phenyl groups.
  • Examples which may be mentioned include mixtures of triphenyl-, tetraphenyl- or pentaphenylorganopolysiloxanes.
  • phenyl silicone oils which do not have a dimethicone fragment, corresponding to formula (II) in which at least 4 or at least 5 radicals R represent a phenyl radical, the remaining radicals representing methyls.
  • non-volatile phenyl silicone oils are preferably trimethylpentaphenyltrisiloxane or tetramethyltetraphenyltrisiloxane. They are in particular sold by Dow Corning under the reference
  • PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: 1,3,5-trimethyl-l, 1,3,5,5- pentaphenyltrisiloxane; INCI name: trimethylpentaphenyltrisiloxane), or the tetramethyltetraphenyltrisiloxane sold under the reference Dow Corning 554 Cosmetic Fluid by
  • - Ri to Rio independently of each other, are saturated or unsaturated, linear, cyclic or branched C1-C30 hydrocarbon-based radicals,
  • n, p and q are, independently of each other, integers between 0 and 900, with the proviso that the sum m+n+q is other than 0.
  • the sum m+n+q is between 1 and 100.
  • the sum m+n+p+q is between 1 and 900 and preferably between 1 and 800.
  • q is equal to 0.
  • Ri to Rio independently of each other, represent a saturated or unsaturated, preferably saturated, linear or branched C1-C30 hydrocarbon-based radical, and in particular a preferably saturated, C1-C20, in particular CpCig, hydrocarbon-based radical, or a monocyclic or polycyclic Ce-Cu, and in particular C10-C13, aryl radical, or an aralkyl radical, the alkyl part of which is preferably C1-C3 alkyl.
  • Ri to Rio may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical.
  • Ri to Rio may in particular be identical, and in addition may be a methyl radical.
  • phenyl silicone oils optionally having at least one dimethicone fragment corresponding to formula (VI) below, and mixtures thereof:
  • - Ri to R6 independently of each other, are saturated or unsaturated, linear, cyclic or branched C1-C30 hydrocarbon-based radicals, a preferably C6-C14 aryl radical or an aralkyl radical, the alkyl part of which is C1-C3 alkyl,
  • n and p are, independently of each other, integers between 0 and 100, with the proviso that the sum n+m is between 1 and 100.
  • Ri to R6 independently of each other, represent a C1-C20, in particular CpCig, hydrocarbon-based, preferably alkyl, radical, or a C6-C14 aryl radical which is monocyclic (preferably C ) or polycyclic and in particular C10-C13, or an aralkyl radical (preferably the aryl part is C aryl; the alkyl part is C1-C3 alkyl).
  • Ri to R6 may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical.
  • Ri to R6 may in particular be identical, and in addition may be a methyl radical.
  • m 1 or 2 or 3
  • the non- volatile phenylated silicone oil is chosen from phenylated silicone oils having at least one dimethicone fragment.
  • oils correspond to compounds of formula (VI) in which:
  • n and p are, independently of each other, integers between 1 and 100.
  • Ri to R6 are methyl radicals.
  • the silicone oil is preferably chosen from a diphenyl dimethicone such as KF-54 from Shin Etsu (400 cSt), KF54HV from Shin Etsu (5000 cSt), KF-50- 300CS from Shin Etsu (300 cSt), KF-53 from Shin Etsu (175 cSt) or KF-50-100CS from Shin Etsu (100 cSt).
  • a diphenyl dimethicone such as KF-54 from Shin Etsu (400 cSt), KF54HV from Shin Etsu (5000 cSt), KF-50- 300CS from Shin Etsu (300 cSt), KF-53 from Shin Etsu (175 cSt) or KF-50-100CS from Shin Etsu (100 cSt).
  • phenyl silicone oils optionally having at least one dimethicone fragment correspond more particularly to formula (VII) below:
  • -OSiMe 3 and p is 0 or is between 1 and 1000, and m is between 1 and 1000.
  • m and p are such that the compound (VII) is a non- volatile oil.
  • non-volatile phenylated silicone having at least one dimethicone fragment p is between 1 and 1000 and m is more particularly such that the compound (VII) is a non-volatile oil.
  • Trimethylsiloxyphenyldimethicone sold in particular under the reference Belsil PDM 1000 by the company Wacker, may, for example, be used.
  • p is equal to 0 and m is between 1 and 1000, and in particular is such that the compound (VII) is a non- volatile oil.
  • Phenyltrimethylsiloxytrisiloxane sold in particular under the reference Dow Corning 556 Cosmetic Grade Fluid (DC556), may, for example, be used.
  • DC556 Cosmetic Grade Fluid
  • R independently of each other, are saturated or unsaturated, linear, cyclic or branched Cp C30 hydrocarbon-based radicals, preferably R is a C 1 -C30 alkyl radical, a preferably C6-C14 aryl radical, or an aralkyl radical, the alkyl part of which is C 1 -C3 alkyl,
  • n are, independently of each other, integers between 0 and 100, with the proviso that the sum n+m is between 1 and 100.
  • R independently of each other, represent a saturated or unsaturated, preferably saturated, linear or branched C 1 -C30 hydrocarbon-based radical, and in particular a preferably saturated, C1-C20, in particular CpCig and more particularly C4-C 10 , hydrocarbon-based radical, a monocyclic or polycyclic Ce-Cu, and in particular C10-C13, aryl radical, or an aralkyl radical of which preferably the aryl part is aryl and the alkyl part is C1-C3 alkyl.
  • the R may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical.
  • the R may in particular be identical, and in addition may be a methyl radical.
  • n 1 or 2 or 3
  • n is an integer between 0 and 100 and m is an integer between 1 and 100, with the proviso that the sum n+m is between 1 and 100, in formula (VIII).
  • R is a methyl radical.
  • a phenyl silicone oil of formula (VIII) with a viscosity at 25°C of between 5 and 1500 mm 2 /s (i.e. 5 to 1500 cSt), and preferably with a viscosity of between 5 and 1000 mm 2 /s (i.e. 5 to 1000 cSt), may be used.
  • diphenylsiloxyphenyl trimethicone oil when m and n are between 1 and 100
  • KF56 A from Shin Etsu
  • the Silbione 70663V30 oil from Rhone-Poulenc
  • Ri, R2, R5 and R6, which may be identical or different, are an alkyl radical containing 1 to 6 carbon atoms,
  • R3 and R4 which may be identical or different, are an alkyl radical containing from 1 to 6 carbon atoms or an aryl radical (preferably Ce-Cw), with the proviso that at least one of R3 and R4 is a phenyl radical,
  • X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or a vinyl radical,
  • n and p being an integer greater than or equal to 1 , chosen so as to give the oil a weight- average molecular weight of less than 200 000 g/mol, preferably less than 150 000 g/mol and more preferably less than 100 000 g/mol. f) and a mixture thereof
  • fluoro oil is intended to mean an oil containing at least one fluorine atom.
  • fluoro oils mention may be made of fluorosilicone oils, fluorinated polyethers, fluorosilicones in particular as described in document EP-A-847 752 and perfluoro compounds.
  • perfluoro compounds is intended to mean compounds in which all the hydrogen atoms have been replaced with fluorine atoms.
  • the fluoro oil is chosen from perfluoro oils.
  • perfluoro oils mention may be made of perfluorodecalins and perfluoroperhydrophenanthrenes.
  • the fluoro oil is chosen from perfluoroperhydrophenanthrenes, and in particular the Fiflow® products sold by the company Creations Couelles.
  • use may be made of the fluoro oil of which the INCI name is Perfluoroperhydrophenanthrene, sold under the reference Fiflow 220 by the company F2 Chemicals.
  • hydrocarbon-based oil is intended to mean an oil formed essentially from, or even constituted by, carbon and hydrogen atoms, and possibly oxygen and nitrogen atoms, and not containing any silicon or fluorine atoms.
  • It may contain alcohol, ester, ether, carboxylic acid, amine and/or amide groups.
  • the hydrocarbon-based oil in addition to being free of silicon and fluorine, is free of heteroatoms such as N and P.
  • the hydrocarbon-based oil is therefore different from a silicone oil and from a fluoro oil.
  • the non- volatile hydrocarbon-based oil comprises at least one oxygen atom.
  • this non- volatile hydrocarbon-based oil comprises at least one alcohol function (it is then an “alcohol oil”) or at least one ester function (it is then an “ester oil”).
  • ester oils that may be used in the compositions according to the invention may in particular be hydroxylated.
  • composition may comprise one or more non-volatile hydrocarbon-based oils, in particular chosen from: - Cin-C3 ⁇ 4 alcohols, preferably monoalcohols.
  • the C10-C26 alcohols are saturated or unsaturated, and branched or unbranched, and comprise from 10 to 26 carbon atoms.
  • the C10-C26 alcohols are fatty alcohols, which are preferably branched when they comprise at least 16 carbon atoms.
  • fatty alcohols that may be used according to the invention, mention may be made of linear or branched fatty alcohols, of synthetic origin or alternatively of natural origin, for example alcohols derived from plant material (coconut, palm kernel, palm, etc.) or animal material (tallow, etc.).
  • use may also be made of certain more or less long fractions of alcohols of natural origin, for instance coconut (C12 to Cie) or tallow (Ci6 to Cig) or compounds of diol or cholesterol type.
  • Use is preferably made of a fatty alcohol comprising from 10 to 24 carbon atoms and more preferentially from 12 to 22 carbon atoms.
  • lauryl alcohol myristyl alcohol, isostearyl alcohol, palmityl alcohol, oleyl alcohol, behenyl alcohol, erucyl alcohol, arachidyl alcohol, 2-butyloctanol, 2-undecylpentadecanol, 2- hexyldecyl alcohol, isocetyl alcohol and octyldodecanol, and mixtures thereof.
  • the fatty alcohol is chosen from lauryl alcohol, isostearyl alcohol, oleyl alcohol, 2-butyloctanol, 2-undecylpentadecanol, 2-hexyldecyl alcohol, isocetyl alcohol and octyldodecanol, and mixtures thereof.
  • the alcohol is chosen from octyldodecanol
  • hydroxylated diesters of a C2-Cg dicarboxylic acid and of a C2-Cg alcohol such as diisopropyl adipate, 2-diethylhexyl adipate, dibutyl adipate, diisostearyl adipate or 2- diethylhexyl succinate,
  • hydroxylated triesters of a C2-Cg tricarboxylic acid and of a C2-Cg alcohol such as citric acid esters, such as trioctyl citrate, triethyl citrate, acetyl tributyl citrate, tributyl citrate or acetyl tributyl citrate;
  • esters of a C?-Cg polyol and of one or more C?-Cg carboxylic acids such as glycol diesters of monoacids, such as neopentyl glycol diheptanoate, or glycol triesters of monoacids, such as triacetin;
  • Examples that may be mentioned include monoesters, diesters or triesters.
  • the ester oils may be hydroxylated or non-hydroxylated.
  • the non- volatile ester oil may for example be chosen from:
  • R1COOR2 monoesters comprising between 18 and 40 carbon atoms in total, in particular the monoesters of formula R1COOR2 in which Ri represents a saturated or unsaturated, linear or branched or aromatic fatty acid residue comprising from 4 to 40 carbon atoms and R2 represents a hydrocarbon-based chain, which is in particular branched, containing from 4 to 40 carbon atoms, on condition that Ri + R 2 > 18, for instance Purcellin oil (cetostearyl octanoate), isononyl isononanoate, C12 to C15 alkyl benzoate, 2-ethylhexyl palmitate, octyldodecyl neopentanoate, 2- octyldodecyl stearate, 2-octyldodecyl erucate, isostearyl isostearate, 2-octyldodecyl benzoate, alcohol or polyalcohol oc
  • esters of formula R1COOR2 in which Ri represents a linear or branched fatty acid residue containing from 4 to 40 carbon atoms and R2 represents a hydrocarbon-based chain that is in particular branched, containing from 4 to 40 carbon atoms, Ri + R2 being such that Ri + R 2 > 18.
  • the ester comprises between 18 and 40 carbon atoms in total.
  • Preferred monoesters include isononyl isononanoate, oleyl erucate and/or 2-octyldodecyl neopentanoate;
  • monoesters of a fatty acid in particular of 18 to 22 carbon atoms, and in particular of lanolic acid, oleic acid, lauric acid or stearic acid, and of diols, for instance propylene glycol monoisostearate;
  • diesters in particular comprising between 18 and 60 carbon atoms in total and in particular between 18 and 50 carbon atoms in total.
  • Use may in particular be made of diesters of a dicarboxylic acid and of monoalcohols, preferably such as diisostearyl malate, or glycol diesters of monocarboxylic acids, such as neopentyl glycol diheptanoate, propylene glycol dioctanoate, diethylene glycol diisononanoate or polyglyceryl-2 diisostearate (in particular such as the compound sold under the commercial reference Dermol DGDIS by the company Alzo);
  • hydroxylated monoesters and diesters preferably with a total carbon number ranging from 18 to 70, for instance polyglyceryl-3 diisostearate, isostearyl lactate, octyl hydroxystearate, octyldodecyl hydroxystearate, diisostearyl malate or glyceryl stearate;
  • triesters in particular comprising between 35 and 70 carbon atoms in total, in particular such as triesters of a tricarboxylic acid, such as triisostearyl citrate, or tridecyl trimellitate, or glycol triesters of monocarboxylic acids such as polyglyceryl-2 triisostearate;
  • a tricarboxylic acid such as triisostearyl citrate, or tridecyl trimellitate
  • glycol triesters of monocarboxylic acids such as polyglyceryl-2 triisostearate
  • tetraesters in particular with a total carbon number ranging from 35 to 70, such as pentaerythritol or polyglycerol tetraesters of a monocarboxylic acid, for instance pentaerythrityl tetrapelargonate, pentaerythrityl tetraisostearate, pentaerythrityl tetraisononanoate, glyceryl tris(2- decyl)tetradecanoate, polyglyceryl-2 tetraisostearate or pentaerythrityl tetrakis(2- decyl)tetradecanoate;
  • pentaerythritol or polyglycerol tetraesters of a monocarboxylic acid for instance pentaerythrityl tetrapelargonate, pentaerythrityl tetraisostearate, pentaerythrityl tetr
  • polyesters obtained by condensation of an unsaturated fatty acid dimer and/or trimer and of diol such as those described in patent application FR 0 853 634, in particular such as dilinoleic acid and 1 ,4-butanediol.
  • an unsaturated fatty acid dimer and/or trimer and of diol such as those described in patent application FR 0 853 634, in particular such as dilinoleic acid and 1 ,4-butanediol.
  • Viscoplast 14436H INCI name: dilinoleic acid/butanediol copolymer
  • copolymers of polyols and of dimer diacids, and esters thereof, such as Hailucent ISDA such as Hailucent ISDA
  • esters and polyesters of diol dimer and of monocarboxylic or dicarboxylic acid such as esters of diol dimer and of fatty acid and esters of diol dimer and of dicarboxylic acid dimer, in particular which may be obtained from a dicarboxylic acid dimer derived in particular from the dimerization of an unsaturated fatty acid in particular of Cg to C34, especially of C12 to C22, in particular of Ci6 to C20 and more particularly of Cig, such as esters of dilinoleic diacids and of dilinoleic diol dimers, for instance those sold by the company Nippon Fine Chemical under the trade names Lusplan DD-DA5® and DD-DA7®;
  • hydrocarbon-based vegetable oils such as fatty acid triglycerides (which are liquid at ambient temperature), in particular of fatty acids containing from 7 to 40 carbon atoms, such as heptanoic or octanoic acid triglycerides or jojoba oil; mention may be made in particular of saturated triglycerides such as caprylic/capric triglycerides and mixtures thereof, for example such as the product sold under the reference Myritol 318 from Cognis, glyceryl triheptanoate, glyceryl trioctanoate, and C18.C36 acid triglycerides such as those sold under the reference Dub TGI 24 by Stearineries Dubois, and unsaturated triglycerides such as castor oil, olive oil, ximenia oil or pracaxi oil;
  • Ci 7-C3 ⁇ 4_fattv acids preferably C12-C22 fatty acids, which are preferably unsaturated, such as oleic acid, linoleic acid or linolenic acid, and mixtures thereof;
  • dialkyl carbonates the 2 alkyl chains possibly being identical or different, such as dicaprylyl carbonate sold under the name Cetiol CC ® by Cognis; - and mixtures thereo
  • Non-polar non-volatile hydrocarbon-based oils are non-polar non-volatile hydrocarbon-based oils
  • composition according to the invention can also comprise at least one non-polar nonvolatile hydrocarbon-based oil.
  • oils may be of vegetable, mineral or synthetic origin.
  • non-polar oil is intended to mean an oil of which the solubility parameter at 25°C, 5 a , is equal to 0 (J/cm 3 ) 1/2 .
  • the parameters ⁇ ⁇ , 3 ⁇ 4, 3 ⁇ 4 and 5 a are expressed in (J/cm 3 ) 1 ⁇ 2 .
  • hydrocarbon-based oil is intended to mean an oil formed essentially from, or even constituted of, carbon and hydrogen atoms, and optionally oxygen and nitrogen atoms, and not containing any silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and/or amide groups.
  • the non-polar hydrocarbon oils are chosen from oils formed essentially from hydrogen atoms and carbon atoms.
  • non-polar non- volatile hydrocarbon-based oil may be chosen from linear or branched hydrocarbons of mineral or synthetic origin, such as:
  • the composition comprises at least one non- volatile oil chosen from non- volatile silicone oils, which are preferably phenylated, polar or non-polar, non- volatile hydrocarbon-based oils, or mixtures thereof.
  • the composition comprises at least one non- volatile oil chosen from phenylated non- volatile silicone oils, and polar non- volatile hydrocarbon-based oils or mixtures thereof.
  • the non- volatile hydrocarbon-based oil(s) is (are) chosen from polar nonvolatile oils, such as for example C 10 -C26 alcohols, or ester oils; from non-polar oils; and mixtures thereof.
  • the composition comprises at least one polar oil are or chosen from C 10 -C26 alcohols; hydroxylated monoesters and diesters; monoesters comprising between 18 and 40 carbon atoms in total; triesters comprising between 35 and 70 carbon atoms in total, or mixtures thereof, or at least one non-polar oil chosen from hydrogenated or non-hydrogenated poly(iso)butylenes, and also mixtures thereof.
  • polar oil are or chosen from C 10 -C26 alcohols; hydroxylated monoesters and diesters; monoesters comprising between 18 and 40 carbon atoms in total; triesters comprising between 35 and 70 carbon atoms in total, or mixtures thereof, or at least one non-polar oil chosen from hydrogenated or non-hydrogenated poly(iso)butylenes, and also mixtures thereof.
  • the composition comprises at least one polar oil, more particularly octyldodecanol.
  • composition according to the invention comprises at least one film-forming agent chosen from vinyl polymers comprising at least one carbosiloxane dendrimer-based unit; film-forming block ethylenic copolymers; alkylcelluloses; silicone resins, or mixtures thereof.
  • film-forming agent chosen from vinyl polymers comprising at least one carbosiloxane dendrimer-based unit; film-forming block ethylenic copolymers; alkylcelluloses; silicone resins, or mixtures thereof.
  • the content of film-forming agent(s) represents from 0.5% to 30% by weight of active material and preferably from 1% to 20% by weight, relative to the total weight of the composition.
  • film-forming polymer is intended to mean a polymer that is capable of forming, by itself or in the presence of an auxiliary film-forming agent, a continuous deposit on a support, in particular on keratin materials.
  • Vinyl polymer comprising at least one carbosiloxane dendrimer-based unit
  • the vinyl polymer has a backbone and at least one side chain, which comprises a carbosiloxane dendrimer-based unit having a carbosiloxane dendrimer structure.
  • carbosiloxane dendrimer structure in the context of the present invention represents a molecular structure with branched groups of high molecular weights, said structure having high regularity in the radial direction starting from the bond to the backbone.
  • Such carbosiloxane dendrimer structures are described in the form of a highly branched siloxane- silylalkylene copolymer in Japanese patent application JP 9-171 154.
  • a vinyl polymer according to the invention may contain carbosiloxane dendrimer-based units that may be represented by the following general formula (I):
  • R 1 represents an aryl group containing from 5 to 10 carbon atoms or an alkyl group containing from 1 to 10 carbon atoms;
  • R 1 is as defined above in formula (I),
  • R2 represents an alkylene radical containing from 2 to 10 carbon atoms
  • R 3 represents an alkyl group containing from 1 to 10 carbon atoms
  • . i is an integer from 1 to 10 which represents the generation of said silylalkyl group, and . a 1 is an integer from 0 to 3;
  • - Y represents a radical-polymerizable organic group chosen from:
  • organic groups containing a methacrylic group or an acrylic group said organic groups being represented by the formulae:
  • R 4 represents a hydrogen atom or an alkyl group containing from 1 to 10 carbon atoms
  • R 5 represents an alkylene group containing from 1 to 10 carbon atoms, such as a methylene group, an ethylene group, a propylene group or a butylene group, methylene and propylene groups being preferred;
  • R 6 represents a hydrogen atom or an alkyl group containing from 1 to 10 carbon atoms, such as a methyl group, an ethyl group, a propyl group or a butyl group, the methyl group being preferred:
  • R 7 represents an alkyl group containing from 1 to 10 carbon atoms
  • R 8 represents an alkylene group containing from 1 to 10 carbon atoms, such as a methylene group, an ethylene group, a propylene group or a butylene group, the ethylene group being preferred
  • * b is an integer from 0 to 4.
  • * c is 0 or 1, such that, if c is 0, -(R 8 ) c - represents a bond.
  • R 1 may represent an aryl group containing from 5 to 10 carbon atoms or an alkyl group containing from 1 to 10 carbon atoms.
  • the alkyl group may preferably be represented by a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, an isopropyl group, an isobutyl group, a cyclopentyl group or a cyclohexyl group.
  • the aryl group may preferably be represented by a phenyl group and a naphthyl group. The methyl and phenyl groups are more particularly preferred, and the methyl group is preferred among all.
  • R 2 represents an alkylene group containing from 2 to 10 carbon atoms, in particular a linear alkylene group, such as an ethylene, propylene, butylene or hexylene group; or a branched alkylene group, such as a methylmethylene, methylethylene, 1- methylpentylene or 1 ,4-dimethylbutylene group.
  • a linear alkylene group such as an ethylene, propylene, butylene or hexylene group
  • a branched alkylene group such as a methylmethylene, methylethylene, 1- methylpentylene or 1 ,4-dimethylbutylene group.
  • the ethylene, methylethylene, hexylene, 1 -methylpentylene and 1 ,4-dimethylbutylene groups are preferred among all.
  • R 3 is chosen from methyl, ethyl, propyl, butyl and isopropyl groups.
  • i indicates the number of generations and thus corresponds to the number of repeats of the silylalkyl group.
  • the carbosiloxane dendrimer may be represented by the general formula shown below, in which Y, R 1 , R 2 and R 3 are as defined above, R 12 represents a hydrogen atom or is identical to R 1 ; a 1 is identical to a 1 .
  • the total average number of groups OR 3 in a molecule is within the range from 0 to 7.
  • the carbosiloxane dendrimer may be represented by the general formula below, in which Y, R 1 , R 2 , R 3 and R 12 are the same as defined above; a 1 and a 2 represent the a 1 of the indicated generation.
  • the total average number of groups OR 3 in a molecule is within the range from 0 to 25.
  • the carbosiloxane dendrimer is represented by the
  • a vinyl polymer containing at least one carbosiloxane dendrimer-based unit has a molecular side chain containing a carbosiloxane dendrimer structure, and may be the product of polymerization of:
  • the monomer of vinyl type that is the component (A) in the vinyl polymer having at least one carbosiloxane dendrimer-based unit is a monomer of vinyl type that contains a radical- polymerizable vinyl group.
  • this monomer of vinyl type methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, isopropyl methacrylate or a methacrylate of an analagous lower alkyl; glycidyl methacrylate; butyl methacrylate, butyl acrylate, n-butyl methacrylate, isobutyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, n-hexyl methacrylate, cyclohexyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, octyl methacrylate, lauryl methacrylate, stearyl acrylate, stearyl methacrylate or a higher-analogue methacrylate; vinyl acetate, vinyl propionate or a vinyl ester of an ana
  • Multifunctional vinyl monomers may also be used.
  • trimethylolpropane trimethacrylate pentaerythrityl trimethacrylate, ethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1 ,4-butanediol dimethacrylate, 1 ,6-hexanediol dimethacrylate, neopentyl glycol dimethacrylate, trimethylolpropanetrioxyethyl methacrylate, tris(2-hydroxyethyl)isocyanurate dimethacrylate, tris(2-hydroxyethyl)isocyanurate trimethacrylate, polydimethylsiloxane capped with styryl groups containing divinylbenzene groups on both ends, or similar silicone compounds containing unsaturated groups.
  • a carbosiloxane dendrimer which is the component (B), may be represented by formula (I) as defined above.
  • group Y of formula (I) an acryloxymethyl group, a 3-acryloxypropyl group, a methacryloxymethyl group, a 3- methacryloxypropyl group, a 4-vinylphenyl group, a 3-vinylphenyl group, a 4-(2-propenyl)phenyl group, a 3-(2-propenyl)phenyl group, a 2-(4-vinylphenyl)ethyl group, a 2-(3-vinylphenyl)ethyl group, a vinyl group, an allyl group, a methallyl group and a 5-hexenyl group.
  • a carbosiloxane dendrimer according to the present invention can be represented by the formulae having the average structures below:
  • the carbosiloxane dendrimer of the composition according to the present invention is represented by the following formula:
  • Y, R 1 , R 2 and R 3 are as defined in formulae (I) and (II) above;
  • a 1 , a 2 and a 3 correspond to the definition of a 1 according to formula (II); and .
  • R is H, an aryl group containing from 5 to 10 carbon atoms or an alkyl group containing from 1 to 10 carbon atoms.
  • the carbosiloxane dendrimer of the composition according to the present invention is represented by one of the following formulae:
  • the vinyl polymer comprising the carbosiloxane dendrimer according to the invention may be manufactured according to the process for manufacturing a branched silalkylene siloxane described in Japanese patent application Hei 9-171 154.
  • organosilicon compound containing a hydrogen atom linked to a silicon atom represented by the following general formula (IV):
  • R 1 being as defined above in formula (I),
  • the organosilicon compound may be represented by 3- methacryloxypropyltris(dimethylsiloxy)silane, 3-acryloxypropyltris(dimethylsiloxy)silane and 4- vinylphenyltris(dimethylsiloxy)silane.
  • the organosilicon compound that contains an alkenyl group may be represented by vinyltris(trimethylsiloxy)silane, vinyltris(dimethylphenylsiloxy)silane, and 5 -hexenyltris(trimethylsiloxy)silane .
  • the hydrosilylation reaction is performed in the presence of a chloroplatinic acid, a complex of vinylsiloxane and of platinum, or a similar transition metal catalyst.
  • a vinyl polymer containing at least one carbosiloxane dendrimer-based unit may be chosen from polymers such that the carbosiloxane dendrimer-based unit is a carbosiloxane dendritic structure represented by formula (III):
  • the polymerization ratio between the components (A) and (B), in terms of the weight ratio between (A) and (B), is within a range from 0/100 to 99.9/0.1, or even from 0.1/99.9 to 99.9/0.1 and preferably within a range from 1/99 to 99/1.
  • a ratio between the components (A) and (B) of 0/100 means that the compound becomes a homopolymer of component (B).
  • a vinyl polymer containing at least one carbosiloxane dendrimer-based unit may be obtained by copolymerization of the components (A) and (B), or by polymerization of the component (B) alone.
  • the polymerization may be a free-radical polymerization or an ionic polymerization, but free-radical polymerization is preferred.
  • the polymerization may be performed by bringing about a reaction between the components (A) and (B) in a solution for a period of from 3 to 20 hours in the presence of a radical initiator at a temperature of from 50°C to 150°C.
  • a suitable solvent for this purpose is hexane, octane, decane, cyclohexane or a similar aliphatic hydrocarbon; benzene, toluene, xylene or a similar aromatic hydrocarbon; diethyl ether, dibutyl ether, tetrahydrofuran, dioxane or ethers; acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone or similar ketones; methyl acetate, ethyl acetate, butyl acetate, isobutyl acetate or similar esters; methanol, ethanol, isopropanol, butanol or similar alcohols; octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexamethyldisiloxane, octamethyltrisiloxane or a similar organ
  • a radical initiator may be any compound known in the art for standard free-radical polymerization reactions.
  • the specific examples of such radical initiators are 2,2'- azobis(isobutyronitrile), 2,2 ' -azobis(2-methylbutyronitrile), 2,2 ' -azobis(2,4-dimethylvaleronitrile) or similar compounds of azobis type; benzoyl peroxide, lauroyl peroxide, tert-butyl peroxybenzoate, tert-butyl peroxy-2-ethylhexanoate or a similar organic peroxide.
  • These radical initiators may be used alone or in a combination of two or more.
  • the radical initiators may be used in an amount of from 0.1 to 5 parts by weight per 100 parts by weight of the components (A) and (B).
  • a chain-transfer agent may be added.
  • the chain-transfer agent may be 2-mercaptoethanol, butyl mercaptan, n-dodecyl mercaptan, 3-mercaptopropyltrimethoxysilane, a polydimethylsiloxane containing a mercaptopropyl group or a similar compound of mercapto type; methylene chloride, chloroform, carbon tetrachloride, butyl bromide, 3-chloropropyltrimethoxysilane or a similar halogenated compound.
  • the unreacted residual vinyl monomer may be removed under conditions of heating under vacuum.
  • the number-average molecular weight of the vinyl polymer containing a carbosiloxane dendrimer may be chosen within the range between 3000 and 2 000 000 and preferably between 5000 and 800 000. It may be a liquid, a gum, a paste, a solid, a powder, or any other form.
  • the preferred forms are solutions consisting of the dilution of a dispersion or of a powder in solvents.
  • the vinyl polymer may be a dispersion of a polymer of vinyl type having a carbosiloxane dendrimer structure in its side molecular chain, in a liquid such as a silicone oil, an organic oil, an alcohol or water.
  • the silicone oil may be a dimethylpolysiloxane having the two molecular ends capped with trimethylsiloxy groups, a copolymer of methylphenylsiloxane and of dimethylsiloxane having the two molecular ends capped with trimethylsiloxy groups, a copolymer of methyl-3,3,3- trifluoropropylsiloxane and of dimethylsiloxane having the two molecular ends capped with trimethylsiloxy groups, or similar unreactive linear silicone oils, and also hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane or a similar cyclic compound.
  • modified polysiloxanes containing functional groups such as silanol groups, amino groups and polyether groups on the ends or within the molecular side chains may be used.
  • the organic oils may be isododecane, liquid paraffin, isoparaffin, hexyl laurate, isopropyl myristate, myristyl myristate, cetyl myristate, 2-octyldodecyl myristate; isopropyl palmitate, 2- ethylhexyl palmitate, butyl stearate, decyl oleate, 2-octyldodecyl oleate, myristyl lactate, cetyl lactate, lanolin acetate, stearyl alcohol, cetostearyl alcohol, oleyl alcohol, avocado oil, almond oil, olive oil, cocoa oil, jojoba oil, gum oil, sunflower oil, soybean oil, camellia oil, squalane, castor oil, cottonseed oil, coconut oil, egg yolk oil, polypropylene glycol monooleate, neopentyl glycol 2- ethylhexan
  • the alcohol may be any type that is suitable for use in combination with a cosmetic product starting material.
  • it may be methanol, ethanol, butanol, isopropanol or similar lower alcohols.
  • a solution or a dispersion of the alcohol should have a viscosity within the range from 10 to 10 9 mPa at 25°C. To improve the sensory use properties in a cosmetic product, the viscosity should be within the range from 100 to 5 10 8 mPa.s.
  • the solutions and dispersions may be readily prepared by mixing a vinyl polymer containing at least one carbosiloxane dendrimer-based unit with a silicone oil, an organic oil, an alcohol or water.
  • the liquids may be present in the polymerization step.
  • the unreacted residual vinyl monomer should be completely removed by heat treatment of the solution or dispersion under atmospheric pressure or reduced pressure.
  • the dispersity of the polymer of vinyl type may be improved by adding a surfactant.
  • Such an agent may be hexylbenzenesulfonic acid, octylbenzenesulfonic acid, decylbenzenesulfonic acid, dodecylbenzenesulfonic acid, cetylbenzenesulfonic acid, myristylbenzenesulfonic acid or anionic surfactants of the sodium salts of these acids; octyltrimethylammonium hydroxide, dodecyltrimethylammonium hydroxide, hexadecyltrimethylammonium hydroxide, octyldimethylbenzylammonium hydroxide, decyldimethylbenzylammonium hydroxide, dioctadecyldimethylammonium hydroxide, beef tallow-trimethylammonium hydroxide, coconut oil-trimethylammonium hydroxide, or a similar cationic surfactant; a polyoxyalkylene alkyl ether, a
  • a mean particle diameter of the polymer of vinyl type may be within a range of between 0.001 and 100 microns and preferably between 0.01 and 50 microns. The reason for this is that, outside the recommended range, a cosmetic product mixed with the emulsion will not have a nice enough feel on the lips or to the touch, nor sufficient spreading properties nor a pleasant feel.
  • a vinyl polymer contained in the dispersion or the solution may have a concentration within a range of between 0.1% and 95% by weight and preferably between 5% and 85% by weight. However, to facilitate the handling and the preparation of the mixture, the range should preferably be between 10%> and 75% by weight.
  • a vinyl polymer that is suitable for use in the invention may also be one of the polymers described in the examples of patent application EP 0 963 751.
  • a vinyl polymer grafted with a carbosiloxane dendrimer may be the product of polymerization of:
  • the monomers (Al) and (Bl) correspond respectively to specific monomers (A) and (B).
  • a vinyl polymer containing at least one carbosiloxane dendrimer-based unit may comprise a tris[tri(trimethylsiloxy)silylethyldimethylsiloxy]silylpropyl carbosiloxane dendrimer-based unit corresponding to one of the formulae:
  • a vinyl polymer containing at least one carbosiloxane dendrimer-based unit used in the invention comprises at least one butyl acrylate monomer.
  • a vinyl polymer may also comprise at least one fluoro organic group.
  • polymerized vinyl units constitute the backbone and carbosiloxane dendritic structures and also fluoro organic groups are attached to side chains are particularly preferred.
  • the fluoro organic groups may be obtained by replacing with fluorine atoms all or some of the hydrogen atoms of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, pentyl, neopentyl, hexyl, cyclohexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl and octadecyl groups and other alkyl groups of 1 to 20 carbon atoms, and also alkyloxyalkylene groups of 6 to 22 carbon atoms.
  • R 13 is an atom or a group chosen from a hydrogen atom, a fluorine atom, -(CH(CF 3 ) 2 - or CF(CF 3 ) 2 .
  • Such fluorine- substituted alkyl groups are exemplified by linear or branched polyfluoroalkyl or perfluoroalkyl groups represented by the formulae shown below: -CF 3 , -C 2 F 5 , -nC 3 F 7 , -CF(CF 3 ) 2 , -nC 4 F 9 , CF 2 CF(CF 3 ) 2 , -nC 5 F u , -nC 6 F 13 , -nC 8 F 17 , CH 2 CF 3 , -(CH(CF 3 ) 2 , CH 2 CH(CF 3 ) 2 -CH 2 (CF 2 ) 2 F,
  • the groups represented by -CH 2 CH 2 -(CF 2 ) m -CFR 14 -[OCF 2 CF(CF 3 )] n -OC 3 F 7 are suggested as fluoroalkyloxyfluoroalkylene groups obtained by substituting fluorine atoms for hydrogen atoms of alkyloxyalkylene groups.
  • the index "m” is 0 or 1
  • "n” is 0, 1, 2, 3, 4 or 5
  • R 14 is a fluorine atom or CF 3 .
  • fluoroalkyloxyfluoroalkylene groups are exemplified by the perfluoroalkyloxyfluoroalkylene groups represented by the formulae shown below: - CH 2 CH 2 CF(CF 3 )-[OCF 2 CF(CF 3 )] n -OC 3 F 7 , -CH 2 CH 2 CF 2 CF 2 -[OCF 2 CF(CF 3 )] n -OC 3 F 7 .
  • the number-average molecular weight of the vinyl polymer used in the present invention may be between 3000 and 2 000 000 and more preferably between 5000 and 800 000.
  • This type of fluorinated vinyl polymer may be obtained by addition:
  • a composition of the invention may comprise a vinyl polymer which has at least one carbosiloxane dendrimer-based unit and which results from the copolymerization of a vinyl monomer (Ml) as defined above, optionally of a vinyl monomer (M2) as defined above, and of a carbosiloxane dendrimer (B) as defined above,
  • said vinyl polymer having a copolymerization ratio between the monomer (Ml) and the monomer (M2) of 0.1 to 100:99.9 to 0% by weight, and a copolymerization ratio between the sum of the monomers (Ml) and (M2) and the monomer (B) of 0.1 to 99.9:99.9 to 0.1% by weight.
  • the vinyl monomers (Ml) containing fluoro organic groups in the molecule are preferably monomers represented by the general formula:
  • R 15 is a hydrogen atom or a methyl group and R f is a fluoro organic group exemplified by the fluoroalkyl and fluoroalkyloxyfluoroalkylene groups described above.
  • the compounds represented by the formulae presented below are suggested as specific examples of the component (Ml). In the formulae presented below, "z" is an integer from 1 to 4.
  • CH 2 CCH 3 COO-CF 3
  • CH 2 CCH 3 COO-C 2 F5
  • CH 2 CCH3COO-nC 3 F 7 ,
  • CH 2 CCH 3 COO-CF(CF 3 ) 2
  • CH 2 CCH 3 COO-nC 4 F 9
  • CH 2 CCH 3 COO-CF(CF 3 ) 2
  • CH 2 CCH 3 COO-nC 5 F u
  • CH 2 CCH 3 COO-nC 6 F 13
  • CH 2 CCH 3 COO-nC 8 F 17
  • CH 2 CCH 3 COO-CH 2 CF 3
  • CH 2 CCH 3 COO-CH(CF 3 ) 2
  • CH 2 CCH 3 COO-CH 2 CH(CF 3 ) 2
  • CH 2 CCH 3 COO-CH 2 (CF 2 ) 2 F
  • CH 2 CCH 3 COO-CH 2 (CF 2 ) 2 F
  • CH 2 CCH 3 COO-CH 2 (CF 2 ) 4 F
  • CH 2 CCH 3 COO-CH 2 (CF 2 ) 6 F
  • CH 2 CCH 3 COO-CH 2 (CF 2 ) 8 F
  • CH 2 CCH 3 COO-CH 2 CH 2 CF 3
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 2 F
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 3 F
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 4 F
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 6 F
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 8 F
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 10 F
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 12 F
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 14 F
  • CH 2 CCH 3 COO-CH 2 -CH 2 -(CF 2 ) 16 F
  • CH 2 CCH 3 COO-CH 2 CH 2 CH 2 CF 3
  • CH 2 CCH 3 COO-CH 2 CH 2 CH 2 (CF 2 ) 2 H
  • CH 2 CCH 3 COO-CH 2 (CF 2 ) 2 H
  • CH 2 CCH 3 COO-CH 2 (CF 2 ) 4 F
  • CH 2 CCH 3 COO-CH 2 (CF2) 3 F
  • CH 2 CCH 3 COO-CH 2 CH 2 CF 3 CF2-[OCF 2 -CF(CF 3 )]z-OC 3 F 7 ,
  • CH 2 CCH 3 COO-CH 2 CH 2 CF 2 CF 2 -[OCF 2 -CF(CF 3 )]z-OC 3 F 7 ,
  • CH 2 CHCOO-CF 3
  • CH2 CHCOO-C 2 F 5
  • CH 2 CHCOO-nC 3 F 7 ,
  • CH 2 CHCOO-nC 3 F 2
  • CH 2 CHCOO-nC 4 F 9
  • CH 2 CHCOO-CH 2 CF 3
  • CH 2 CHCOO-nC 5 F u
  • CH 2 CHCOO-nC 6 F 13
  • CH 2 CHCOO-nC 8 F 17
  • CH 2 CHCOO-CH 2 CF 3
  • CH 2 CHCOO-CH(CF 3 ) 2
  • CH 2 CHCOO-CH 2 CH(CF 3 ) 2
  • CH 2 CHCOO-CH 2 (CF 2 ) 2 F
  • CH 2 CHCOO-CH 2 (CF 2 ) 3 F
  • CH 2 CHCOO-CH 2 (CF 2 ) 4 F
  • CH 2 CHCOO-CH 2 (CF 2 ) 6 F
  • CH 2 CHCOO-CH 2 (CF 2 ) 8 F
  • CH 2 CHCOO-CH 2 CH 2 CF 3
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 2 F
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 3 F
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 4 F
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 6 F
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 8 F
  • CH 2 HCOO-CH 2 CH 2 (CF 2 ) 10 F
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 14 F
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 16 F
  • CH 2 CHCOO-CH 2 CH 2 CH 2 CF 3
  • CH 2 CHCOO-CH 2 CH 2 CH 2 (CF 2 ) 2 F
  • CH 2 CHCOO-CH 2 CH 2 CH 2 (CF) 2 H
  • CH 2 CHCOO-CH 2 (CF 2 ) 4 H
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 3 H
  • CH 2 CHCOO-CH 2 CH 2 CF(CF 3 )-, [OCF 2 -CF(CF 3 )] z -OC 3 F 7 ,
  • CH 2 CHCOO-CH 2 CH 2 CF 2 CF 2 (CF 3 )-[OCF 2 -CF(CF 3 )] 2 -OC 3 F 7 .
  • vinyl polymers represented by the formulae presented below are preferable:
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 6 F
  • CH 2 CHCOO-CH 2 CH 2 (CF 2 ) 8 F
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 6 F
  • CH 2 CCH 3 COO-CH 2 CH 2 (CF 2 ) 8 F
  • CH 2 CHCOO-CH 2 CF 3
  • CH 2 CCH 3 COO-CH 2 CF 3 .
  • CH 2 CHCOO-CH 2 CF 3
  • CH 2 CCHCOO-CH 2 CF 3 .
  • the vinyl monomers (M2) not containing any organofluorine groups in the molecule may be any monomers containing radical-polymerizable vinyl groups which are exemplified, for example, by methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, n-propyl acrylate, n- propyl methacrylate, isopropyl acrylate, isopropyl methacrylate, and other lower alkyl acrylates or methacrylates; glycidyl acrylate, glycidyl methacrylate; n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, isobutyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, n-hexyl acrylate, n-hexyl methacrylate, cyclohexyl acrylate,
  • vinyl monomers (M2) the polyfunctional vinyl monomers illustrated, for example, by trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythrityl triacrylate, pentaerythrityl trimethacrylate, ethylene glycol diacrylate, ethylene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol diacrylate, polyethylene glycol dimethacrylate, 1 ,4-butanediol diacrylate, 1 ,4-butanediol dimethacrylate, 1 ,6-hexanediol diacrylate, 1 ,6-hexanediol dimethacrylate, neopentyl glycol diacrylate, neopentyl glycol dimethacrylate, trimethylolpropanetrioxyethyl acrylate, trimethyl
  • the weight ratio between (Ml) and (M2) is preferably within the range 1 :99 to 100:0.
  • Y can be chosen, for example, from organic groups containing acrylic or methacrylic groups, organic groups containing an alkenylaryl group, or alkenyl groups containing from 2 to 10 carbon atoms.
  • organic groups containing acrylic or methacrylic groups and the alkenylaryl groups are as defined above.
  • the carbosiloxane dendrimers (B) may be prepared using the process for preparing siloxane/silalkylene branched copolymers described in document EP 1 055 674.
  • they may be prepared by subjecting organic alkenyl silicone compounds and silicone compounds comprising hydrogen atoms bonded to the silicon, represented by formula (IV) as defined above, to a hydrosilylation reaction.
  • the copolymerization ratio (by weight) between the monomer (B) and the monomers (Ml) and (M2) is preferably within the range of 1 :99 to 99:1 and even more preferably within the range of 5:95 to 95:5.
  • Amino groups may be introduced into the side chains of the vinyl polymer using, included in the component (M2), vinyl monomers containing amino groups, such as dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylammoethyl acrylate and diethylammoethyl methacrylate, followed by performing a modification with potassium acetate monochloride, ammonium acetate monochloride, the aminomethylpropanol salt of monochloroacetic acid, the triethanolamine salt of monobromoacetic acid, sodium monochloropropionate, and other alkali metal salts of halogenated fatty acids; otherwise, carboxylic acid groups may be introduced into the side chains of the vinyl polymer using, included in the component (M2), vinyl monomers containing carboxylic acids, such as acrylic acid, methacrylic acid, itaconic acid, crotonic acid, fumaric acid and maleic acid, and the like, followed by neutral
  • a fluorinated vinyl polymer may be one of the polymers described in the examples of patent application WO 03/045 337.
  • a vinyl polymer grafted in the sense of the present invention may be conveyed in an oil or a mixture of oils, which is/are preferably volatile, chosen in particular from silicone oils and hydrocarbon-based oils, and mixtures thereof.
  • a silicone oil that is suitable for use in the invention may be cyclopentasiloxane.
  • a hydrocarbon-based oil that is suitable for use in the invention may be isododecane.
  • Vinyl polymers grafted with at least one carbosiloxane dendrimer-based unit that may be particularly suitable for use in the present invention are the polymers sold under the names TIB 4- 100, TIB 4-101, TIB 4-120, TIB 4-130, TIB 4-200, FA 4002 ID (TIB 4-202), TIB 4-220 and FA 4001 CM (TIB 4-230) by the company Dow Corning.
  • the composition according to the present invention comprises the vinyl polymer having at least one carbosiloxane dendrimer-based unit in an active material content of from 0.5% to 20%, in particular from 1% to 15%, more particularly from 1.5% to 10%) and preferably from 3% to 5% by weight, relative to the total weight of said composition.
  • the composition comprises, as film- forming agent, at least one block ethylenic copolymer (also known as a block ethylenic polymer), in particular containing at least a first block with a glass transition temperature (Tg) of greater than or equal to 40°C and being totally or partly derived from one or more first monomers, which are such that the homopolymer prepared from these monomers has a glass transition temperature of greater than or equal to 40°C, and at least a second block with a glass transition temperature of less than or equal to 20°C and being derived totally or partly from one or more second monomers, which are such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20°C, said first block and said second block being connected together via a random intermediate segment comprising at least one of said first constituent monomers of the first block and at least one of said second constituent monomers of the second block, and said block copolymer having a polydispersity index I of greater than
  • the block polymer used according to the invention thus comprises at least one first block and at least one second block.
  • At least one block is intended to mean one or more blocks.
  • block polymer is intended to mean a polymer comprising at least two different blocks and preferably at least three different blocks.
  • ethylenic polymer is intended to mean a polymer obtained by polymerization of monomers comprising an ethylenic unsaturation.
  • the block ethylenic polymer used according to the invention is prepared exclusively from monofunctional monomers.
  • the block ethylenic polymer used according to the present invention does not contain any multifunctional monomers, which make it possible to break the linearity of a polymer so as to obtain a branched or even crosslinked polymer, as a function of the content of multifunctional monomer.
  • the polymer used according to the invention does not, either, contain any macromonomers (the term "macromonomer” is intended to mean a monofunctional monomer containing pendent groups of polymeric nature, and preferably having a molecular mass of greater than 500 g/mol, or alternatively a polymer comprising on only one of its ends a polymerizable (or ethylenically unsaturated) end group), which are used in the preparation of a grafted polymer.
  • macromonomers the term "macromonomer” is intended to mean a monofunctional monomer containing pendent groups of polymeric nature, and preferably having a molecular mass of greater than 500 g/mol, or alternatively a polymer compris
  • the first block and the second block of the polymer used in the invention may be advantageously mutually incompatible.
  • mutant blocks is intended to mean that the mixture formed from a polymer corresponding to the first block and from a polymer corresponding to the second block is not miscible in the polymerization solvent that is in major amount by weight for the block polymer, at ambient temperature (25°C) and atmospheric pressure (10 5 Pa), for a content of the mixture of said polymers of greater than or equal to 5% by weight, relative to the total weight of the mixture of said polymers and of said polymerization solvent, it being understood that:
  • said polymers are present in the mixture in a content such that the respective weight ratio ranges from 10/90 to 90/10, and that
  • each of the polymers corresponding to the first and second blocks has an average (weight- average or number-average) molecular weight equal to that of the block polymer ⁇ 15%.
  • said polymer mixture is immiscible in at least one of them.
  • this solvent is the solvent that is in major amount.
  • the block polymer according to the invention comprises at least a first block and at least a second block that are connected together via an intermediate segment comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block.
  • the intermediate segment also known as the intermediate block
  • the intermediate segment has a glass transition temperature Tg that is between the glass transition temperatures of the first and second blocks.
  • the intermediate segment is a block comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block of the polymer, and allows these blocks to be "compatibilized".
  • the intermediate segment comprising at least one constituent monomer of the first block and at least one constituent monomer of the second block of the polymer is a random polymer.
  • the intermediate block is derived essentially from constituent monomers of the first block and of the second block.
  • the term "essentially” is intended to mean at least at 85%, preferably at least at 90%, better still at 95%) and even better still at 100%.
  • the block polymer according to the invention is advantageously a film-forming block ethylenic polymer.
  • ethylenic polymer is intended to mean a polymer obtained by polymerization of monomers comprising an ethylenic unsaturation.
  • the polymer according to the invention does not comprise any silicon atoms in its backbone.
  • backbone is intended to mean the main chain of the polymer, as opposed to the pendent side chains.
  • the polymer according to the invention is not water-soluble, i.e. the polymer is not soluble in water or in a mixture of water and linear or branched lower monoalcohols containing from 2 to 5 carbon atoms, for instance ethanol, isopropanol or n-propanol, without modifying the pH, at an active material content of at least 1% by weight, at ambient temperature (25°C).
  • the polymer according to the invention is not an elastomer.
  • non-elastomeric polymer is intended to mean a polymer which, when it is subjected to a stress intended to pull it (for example by 30% relative to its initial length), does not return to a length substantially identical to its initial length when the stress ceases.
  • non-elastomeric polymer denotes a polymer with an instantaneous recovery R ; ⁇ 50% and a delayed recovery R 2 h ⁇ 70% after having been subjected to a 30% elongation.
  • non-elastomeric nature of the polymer is determined according to the following protocol:
  • a polymer film is prepared by pouring a solution of the polymer in a Teflon-coated mould, followed by drying for 7 days in an environment conditioned at 23 ⁇ 5°C and 50 ⁇ 10% relative humidity.
  • This sample is subjected to a tensile stress using a machine sold under the reference Zwick, under the same temperature and humidity conditions as for the drying.
  • test specimens are pulled at a speed of 50 mm/min and the distance between the jaws is 50 mm, which corresponds to the initial length (I 0 ) of the test specimen.
  • the instantaneous recovery Ri is determined in the following manner:
  • test specimen is pulled by 30% (s max ), i.e. about 0.3 times its initial length (I 0 ),
  • the stress is released by applying a return speed equal to the tensile speed, i.e. 50 mm/min, and the residual elongation of the test specimen is measured as a percentage, after returning to zero stress load (3 ⁇ 4).
  • the percentage residual elongation of the test specimen (S2h) is measured after 2 hours, 2 hours after returning to zero stress load.
  • a polymer according to one embodiment of the invention preferably has an instantaneous recovery R ; of 10% and a delayed recovery R 2h of 30%.
  • the polydispersity index of the polymer of the invention is greater than 2.
  • the block polymer used in the compositions according to the invention has a polydispersity index I of greater than 2, for example ranging from 2 to 9, preferably greater than or equal to 2.5, for example ranging from 2.5 to 8 and better still greater than or equal to 2.8, and in particular ranging from 2.8 to 6.
  • the polydispersity index I of the polymer is equal to the ratio of the weight-average mass Mw to the number-average mass Mn.
  • the weight-average molar mass (Mw) and number-average molar mass (Mn) are determined by gel permeation liquid chromatography (THF solvent, calibration curve established with linear polystyrene standards, refractometric detector).
  • the weight-average mass (Mw) of the polymer according to the invention is preferably less than or equal to 300 000; it ranges, for example, from 35 000 to 200 000 and better still from 45 000 to 150 OOO g/mol.
  • the number-average mass (Mn) of the polymer according to the invention is preferably less than or equal to 70 000; it ranges, for example, from 10 000 to 60 000 and better still from 12 000 to 50 000 g/mol.
  • the polydispersity index of the polymer according to the invention is greater than 2, for example ranging from 2 to 9, preferably greater than or equal to 2.5, for example ranging from 2.5 to 8, and better still greater than or equal to 2.8, and in particular ranging from 2.8 to 6.
  • the block with a Tg of greater than or equal to 40°C has, for example, a Tg ranging from 40 to 150°C, preferably greater than or equal to 50°C, for example ranging from 50°C to 120°C and better still greater than or equal to 60°C, for example ranging from 60°C to 120°C.
  • the glass transition temperatures indicated for the first and second blocks may be theoretical
  • Tg values determined from the theoretical Tg values of the constituent monomers of each of the blocks, which may be found in a reference manual such as the Polymer Handbook, 3rd Edition,
  • Tg values indicated for the first and second blocks in the present patent application are theoretical Tg values.
  • the difference between the glass transition temperatures of the first and second blocks is generally greater than 10°C, preferably greater than 20°C and better still greater than 30°C.
  • the block with a Tg of greater than or equal to 40°C may be a homopolymer or a copolymer.
  • the block with a Tg of greater than or equal to 40°C may be derived totally or partially from one or more monomers which are such that the homopolymer prepared from these monomers has a glass transition temperature of greater than or equal to 40°C.
  • This block may also be referred to as a "rigid block".
  • this block is derived from monomers which are such that the homopolymers prepared from these monomers have glass transition temperatures of greater than or equal to 40°C.
  • This first block may be a homopolymer consisting of only one type of monomer (for which the Tg of the corresponding homopolymer is greater than or equal to 40°C).
  • the first block is a copolymer
  • it may be totally or partially derived from one or more monomers, the nature and concentration of which are chosen such that the Tg of the resulting copolymer is greater than or equal to 40°C.
  • the copolymer may comprise, for example:
  • Tg values of greater than or equal to 40°C, for example a Tg ranging from 40°C to 150°C, preferably greater than or equal to 50°C, for example ranging from 50°C to 120°C and better still greater than or equal to 60°C, for example ranging from 60°C to 120°C, and
  • the first monomers of which the homopolymers have a glass transition temperature of greater than or equal to 40°C are chosen, preferably, from the following monomers, also known as the main monomers:
  • Ri represents a linear or branched unsubstituted alkyl group containing from 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group, or Ri represents a C4 to C 12 cycloalkyl group, preferably a Cg to C 12 cycloalkyl, such as isobornyl methacrylate,
  • R 2 represents a C4 to C 12 cycloalkyl group such as an isobornyl group or a tert- butyl group
  • R 7 and Rg which may be identical or different, each represent a hydrogen atom or a linear or branched Ci to C 12 alkyl group such as an n-butyl, t-butyl, isopropyl, isohexyl, isooctyl or isononyl group; or R 7 represents H and Rg represents a l,l-dimethyl-3-oxobutyl group,
  • R' denotes H or methyl.
  • monomers that may be mentioned include N- butylacrylamide, N-tert-butylacrylamide, N-isopropylacrylamide, N,N-dimethylacrylamide and N,N-dibutylacrylamide, - and mixtures thereof.
  • R 2 represents a C4 to C 12 cycloalkyl group, preferably a Cg to C 12 cycloalkyl, such as isobomyl.
  • the monomers and the proportions thereof are preferably chosen such that the glass transition temperature of the first block is greater than or equal to 40°C.
  • the first block is obtained from:
  • At least one acrylate monomer of formula CH 2 CH-COOR 2 in which R 2 represents a C4 to C 12 cycloalkyl group, preferably a Cg to C 12 cycloalkyl group, such as isobomyl,
  • R' 2 represents a C4 to C 12 cycloalkyl group, preferably a Cg to C 12 cycloalkyl group, such as isobomyl.
  • R 2 and R' 2 represent, independently or simultaneously, an isobomyl group.
  • the block copolymer comprises from 50% to 80% by weight of isobomyl methacrylate/acrylate, from 10% to 30% by weight of isobutyl acrylate and from 2% to 10% by weight of acrylic acid.
  • the first block may be obtained exclusively from said acrylate monomer and from said methacrylate monomer.
  • the acrylate monomer and the methacrylate monomer are preferably in mass proportions of between 30/70 and 70/30, preferably between 40/60 and 60/40 and in particular of the order of 50/50.
  • the proportion of the first block advantageously ranges from 20% to 90% by weight of the polymer, better still from 30% to 80% and even better still from 60% to 80%.
  • the first block is obtained by polymerization of isobomyl methacrylate and isobomyl acrylate.
  • the second block advantageously has a glass transition temperature Tg of less than or equal to 20°C, for example, a Tg ranging from -100°C to 20°C, preferably less than or equal to 15°C, in particular ranging from -80°C to 15°C and better still less than or equal to 10°C, for example ranging from -100°C to 10°C, in particular ranging from -30°C to 10°C.
  • Tg glass transition temperature
  • the second block is totally or partially derived from one or more second monomers, which are such that the homopolymer prepared from these monomers has a glass transition temperature of less than or equal to 20°C.
  • This block may also be referred to as a "flexible block”.
  • the monomer with a Tg of less than or equal to 20°C (known as the second monomer) is preferably chosen from the following monomers:
  • R3 representing a linear or branched, unsubstituted Ci to C12 alkyl group, with the exception of the tert-butyl group, in which one or more heteroatoms chosen from O, N and S are optionally intercalated,
  • R4 representing a linear or branched, unsubstituted Ce to C12 alkyl group, in which one or more heteroatoms chosen from O, N and S are optionally intercalated;
  • R 5 represents a linear or branched C4 to C12 alkyl group
  • N-(C 4 to Ci2)alkyl acrylamides such as N-octylacrylamide
  • the preferred monomers with a Tg of less than or equal to 20°C are isobutyl acrylate, 2- ethylhexyl acrylate or mixtures thereof in all proportions.
  • Each of the first and second blocks may contain in small proportion at least one constituent monomer of the other block.
  • the first block may contain at least one constituent monomer of the second block, and vice versa.
  • Each of the first and/or second blocks may comprise, in addition to the monomers indicated above, one or more other monomers known as additional monomers, which are different from the main monomers mentioned above.
  • This additional monomer is chosen, for example, from:
  • - ethylenically unsaturated monomers comprising at least one tertiary amine function, for instance 2-vinylpyridine, 4-vinylpyridine, dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate and dimethylaminopropylmethacrylamide, and salts thereof,
  • R 6 represents a linear or branched alkyl group containing from 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group, said alkyl group being substituted with one or more substituents chosen from hydroxyl groups (for instance 2- hydroxypropyl methacrylate and 2-hydroxyethyl methacrylate) and halogen atoms (CI, Br, I or F), such as trifluoroethyl methacrylate,
  • R9 representing a linear or branched C to C12 alkyl group in which one or more heteroatoms chosen from O, N and S are optionally intercalated, said alkyl group being substituted with one or more substituents chosen from hydroxyl groups and halogen atoms (CI, Br, I or F);
  • Rio representing a linear or branched Ci to C 12 alkyl group substituted with one or more substituents chosen from hydroxyl groups and halogen atoms (CI, Br, I or F), such as 2- hydroxypropyl acrylate and 2-hydroxyethyl acrylate, or R i0 represents a Ci to C 12 alkyl- O-POE (polyoxyethylene) with repetition of the oxyethylene unit 5 to 10 times, for example methoxy-POE, or R i0 represents a polyoxyethylenated group comprising from 5 to 10 ethylene oxide units.
  • substituents chosen from hydroxyl groups and halogen atoms (CI, Br, I or F)
  • CI, Br, I or F such as 2- hydroxypropyl acrylate and 2-hydroxyethyl acrylate
  • R i0 represents a Ci to C 12 alkyl- O-POE (polyoxyethylene) with repetition of the oxyethylene unit 5 to 10 times, for example methoxy-POE, or
  • the first block may comprise as additional monomer:
  • Ri represents a linear or branched unsubstituted alkyl group containing from 1 to 4 carbon atoms, such as a methyl, ethyl, propyl or isobutyl group,
  • R 7 and Rg which may be identical or different, each represent a hydrogen atom or a linear or branched Ci to C 12 alkyl group such as an n-butyl, t-butyl, isopropyl, isohexyl, isooctyl or isononyl group; or R 7 represents H and Rg represents a 1 , 1 - dimethyl-3-oxobutyl group,
  • R' denotes H or methyl
  • Examples of monomers that may be mentioned include N-butylacrylamide, N-tert- butylacrylamide, N-isopropylacrylamide, N,N-dimethylacrylamide and N,N-dibutylacrylamide, - and mixtures thereof.
  • the additional monomer is acrylic acid.
  • the additional monomer may represent 0.5% to 30% by weight relative to the weight of the polymer. According to one embodiment, the polymer of the invention does not contain any additional monomer.
  • the polymer of the invention comprises at least isobomyl acrylate and isobomyl methacrylate monomers in the first block and isobutyl acrylate and acrylic acid monomers in the second block.
  • the polymer comprises at least isobomyl acrylate and isobomyl methacrylate monomers in equivalent weight proportion in the first block and isobutyl acrylate and acrylic acid monomers in the second block.
  • the polymer comprises at least isobornyl acrylate and isobornyl methacrylate monomers in equivalent weight proportion in the first block, and isobutyl acrylate and acrylic acid monomers in the second block, the first block representing 70% by weight of the polymer.
  • the polymer comprises at least isobornyl acrylate and isobornyl methacrylate monomers in equivalent weight proportion in the first block and isobutyl acrylate and acrylic acid monomers in the second block.
  • the block with a Tg of greater than 40°C represents 70%) by weight of the polymer, and acrylic acid represents 5%> by weight of the polymer.
  • the first block does not comprise any additional monomer.
  • the second block comprises acrylic acid as additional monomer.
  • the second block is advantageously obtained from an acrylic acid monomer and from at least one other monomer with a Tg of less than or equal to 20°C.
  • the copolymer used in the compositions according to the invention is obtained from at least one isobornyl methacrylate monomer, at least one isobornyl acrylate monomer, at least one isobutyl acrylate monomer and at least one acrylic acid monomer.
  • the copolymer used in the invention comprises from 50% to 80% by weight of isobornyl methacrylate/acrylate mixture, from 10% to 30% by weight of isobutyl acrylate and from 2% to 10% by weight of acrylic acid.
  • the block copolymer may advantageously comprise more than 2% by weight of acrylic acid monomers, and in particular from 2% to 15% by weight, for example from 3% to 15% by weight, in particular from 4% to 15% by weight or even from 4% to 10% by weight of acrylic acid monomers, relative to the total weight of said copolymer.
  • the constituent monomers of the second block and the proportions thereof are chosen such that the glass transition temperature of the second block is less than or equal to 20°C.
  • intermediate segment (also known as the intermediate block) connects the first block and the second block of the polymer used according to the present invention.
  • the intermediate segment results from the polymerization:
  • the formation of the second block is initiated when the first monomers no longer react or are no longer incorporated into the polymer chain either because they are all consumed or because their reactivity no longer allows them to be.
  • the intermediate segment comprises the first available monomers, resulting from a degree of conversion of these first monomers of less than or equal to 90%>, during the introduction of the second monomer(s) during the synthesis of the polymer.
  • the intermediate segment of the block polymer is a random polymer (which may also be referred to as a random block). This means that it comprises a random distribution of the first monomer(s) and of the second monomer(s) and also of the additional monomer(s) optionally present.
  • the intermediate segment is a random block, as are the first block and the second block if they are not homopolymers (i.e. if they are both formed from at least two different monomers).
  • the block ethylenic copolymer according to the invention is prepared by free radical polymerization, according to the techniques that are well known for this type of polymerization.
  • the free radical polymerization is performed in the presence of an initiator, the nature of which is adapted, in a known manner, as a function of the desired polymerization temperature and of the polymerization solvent.
  • the initiator may be chosen from initiators bearing a peroxide function, redox couples or other free radical polymerization initiators known to those skilled in the art.
  • examples of initiators bearing a peroxide function that may be mentioned include:
  • peroxyesters such as tert-butyl peroxyacetate, tert-butyl perbenzoate, tert-butyl peroxy-2- ethylhexanoate (Trigonox 21 S from Akzo Nobel) or 2,5-bis (2-ethylhexanoylperoxy)- 2,5-dimethylhexane (Trigonox 141 from Akzo Nobel);
  • peroxydicarbonates such as diisopropyl peroxydicarbonate
  • peroxy ketones such as methyl ethyl ketone peroxide
  • hydroperoxides such as aqueous hydrogen peroxide solution (H 2 O 2 ) or tert-butyl hydroperoxide; e. diacyl peroxides such as acetyl peroxide or benzoyl peroxide;
  • dialkyl peroxides such as di-tert-butyl peroxide
  • inorganic peroxides such as potassium peroxodisulfate
  • potassium thiosulfate As initiator in the form of a redox couple, mention may be made of the potassium thiosulfate
  • the initiator is chosen from organic peroxides comprising from 8 to 30 carbon atoms.
  • the initiator used is 2,5-bis(2- ethylhexanoylperoxy)-2,5-dimethylhexane sold under the reference Trigonox ® 141 by the company Akzo Nobel.
  • the block copolymer used according to the invention is prepared by free radical polymerization and not by controlled or living polymerization.
  • the polymerization of the block ethylenic copolymer is performed in the absence of control agents, and in particular in the absence of control agents conventionally used in living or controlled polymerization processes, such as nitroxides, alkoxyamines, dithioesters, dithiocarbamates, dithiocarbonates or xanthates, trithiocarbonates or copper-based catalysts, for example.
  • the intermediate segment is a random block, as are the first block and the second block if they are not homopolymers (i.e. if they are both formed from at least two different monomers).
  • the block copolymer may be prepared by free radical polymerization, and in particular by a process that consists in mixing, in the same reactor, a polymerization solvent, an initiator, at least one monomer with a glass transition temperature of greater than or equal to 40°C, and at least one monomer with a glass transition temperature of less than or equal to 20°C, according to the following sequence:
  • said at least one first monomer with a Tg of greater than or equal to 40°C and optionally some of the initiator are then poured in, in a first addition, and the mixture is left to react for a time T corresponding to a maximum degree of conversion of said monomers of 90%,
  • reaction mixture is brought back to ambient temperature.
  • the acrylic acid monomer and said at least one monomer with a glass transition temperature of less than or equal to 20°C are then poured into the reactor, in a second addition, and the mixture is left to react for a time T' after which the degree of conversion of said monomers reaches a plateau,
  • reaction mixture is brought back to ambient temperature.
  • polymerization solvent is intended to mean a solvent or a mixture of solvents.
  • ketones that are liquid at ambient temperature, such as methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, isophorone, cyclohexanone or acetone;
  • propylene glycol ethers that are liquid at ambient temperature, such as propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate or dipropylene glycol n43utyl monoether;
  • esters containing from 3 to 8 carbon atoms in total, such as ethyl acetate, methyl acetate, propyl acetate, n43utyl acetate or isopentyl acetate;
  • - ethers that are liquid at ambient temperature, such as diethyl ether, dimethyl ether or dichlorodiethyl ether;
  • alkanes that are liquid at ambient temperature, such as decane, heptane, dodecane, isododecane, cyclohexane or isohexadecane;
  • the polymerization solvent is a volatile oil with a flash point of less than
  • the flash point is measured in particular according to standard ISO 3679.
  • the polymerization solvent may be chosen in particular from ethyl acetate, butyl acetate, alcohols such as isopropanol or ethanol, and aliphatic alkanes such as isododecane, and mixtures thereof.
  • the polymerization solvent is a mixture of butyl acetate and isopropanol or isododecane.
  • the copolymer may be prepared by free radical polymerization according to a preparation process that consists in mixing, in the same reactor, a polymerization solvent, an initiator, at least one monomer with a glass transition temperature of less than or equal to 20°C and at least one monomer with a Tg of greater than or equal to 40°C, according to the following sequence of steps:
  • said at least one monomer with a glass transition temperature of less than or equal to 20°C and optionally some of the initiator are then poured in, in a first addition, and the mixture is left to react for a time T corresponding to a maximum degree of conversion of said monomers of 90%, - further polymerization initiator and said at least one monomer with a Tg of greater than or equal to 40°C are then poured into the reactor, in a second addition, and the mixture is left to react for a time T' after which the degree of conversion of said monomers reaches a plateau,
  • the acrylic acid monomer and said at least one monomer with a glass transition temperature of less than or equal to 20°C and optionally some of the initiator are then poured in, in a first addition, and the mixture is left to react for a time T corresponding to a maximum degree of conversion of said monomers of 90%,
  • the polymerization temperature is preferably about 90°C.
  • the reaction time after the second addition is preferably between 3 and 6 hours.
  • alkylcelluloses that can be used in the context of the invention are more particularly those of which the alkyl residue comprises between 1 and 6 carbon atoms, preferably between 2 and 6 carbon atoms, even more preferably between 2 and 3 carbon atoms, and better still ethylcellulose.
  • the alkylcellulose is more particularly a cellulose alkyl ether comprising a chain consisting of ⁇ -anhydroglucose units linked together via acetal bonds.
  • Each anhydroglucose unit contains three replaceable hydroxyl groups, all or some of these hydroxyl groups being able to react according to the following reaction:
  • the ethylcellulose polymers used in a cosmetic composition according to the invention are preferentially polymers with a degree of substitution with ethoxy groups ranging from 2.5 to 2.6 per anhydroglucose unit, in other words comprising a content of ethoxy groups ranging from 44% to 50%.
  • a polydimethylsiloxane is not a silicone resin.
  • silicone resins also known as siloxane resins
  • MDTQ siloxane resins
  • Such resins are described, for example, in the Encyclopedia of Polymer Science and Engineering, vol. 15, John Wiley and Sons, New York, (1989), pp. 265-270, and US 2 676 182, US 3 627 851, US 3 772 247, US 5 248 739 or US 5 082 706, US 5 319 040, US 5 302 685 and US 4 935 484.
  • the appropriate resins are more particularly MQ resins.
  • the letter "M” represents the monofunctional unit of formula RlR2R3SiOi /2 , the silicon atom being bonded to only one oxygen atom in the polymer comprising this unit.
  • the letter “D” means a difunctional unit RIR2S1O 2/2 in which the silicon atom is bonded to two oxygen atoms.
  • T represents a trifunctional unit of formula Rl S1O 3/2 .
  • R represents a hydrocarbon-based (in particular alkyl) radical containing from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or a hydroxyl group.
  • Q means a tetrafunctional unit S1O 4 /2 in which the silicon atom is bonded to four oxygen atoms, which are themselves bonded to the rest of the polymer.
  • silicone resins that may be used in the compositions according to the invention, use may be made, for example, of silicone resins of MQ type, of T type or of MQT type.
  • silicone resins of MQ type By way of example of silicone resins of MQ type, mention may be made of:
  • solid silicone resins of MQ type of trimethyl siloxysilicate type mention may be made of those sold under the reference SRI 000 by the company General Electric, under the reference TMS 803 by the company Wacker, or under the name KF-7312J by the company Shin-Etsu or DC 749 or DC 593 by the company Dow Corning;
  • silicone resins comprising MQ siloxysilicate units
  • Resins comprising MQT units that are in particular known are those mentioned in document US 5 110 890.
  • a preferred form of resins of MQT type are MQT-propyl (also known as MQT Pr ) resins.
  • MQT-propyl (also known as MQT Pr ) resins Such resins that may be used in the compositions according to the invention are in particular those described and prepared in patent application WO 2005/075 542, the content of which is incorporated herein by way of reference.
  • the MQ-T-propyl resin preferably comprises the units:
  • R 1 , R 2 and R 3 independently representing a hydrocarbon-based (in particular alkyl) radical containing from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or alternatively a hydroxyl group and preferably an alkyl radical containing from 1 to 8 carbon atoms or a phenyl group,
  • a being between 0.05 and 0.5
  • d being between 0.05 and 0.6
  • the siloxane resin comprises the units:
  • R 1 and R 3 independently representing an alkyl group containing from 1 to 8 carbon atoms
  • R 1 preferably being a methyl group and R 3 preferably being a propyl group
  • a being between 0.05 and 0.5 and preferably between 0.15 and 0.4
  • c being greater than zero, preferably between 0.15 and 0.4,
  • d being between 0.05 and 0.6, preferably between 0.2 and 0.6 or alternatively between 0.2 and 0.55,
  • siloxane resins that may be used according to the invention may be obtained via a process comprising the reaction of:
  • R 1 representing an alkyl group containing from 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group
  • the ratio a/d being between 0.5 and 1.5;
  • R 3 representing an alkyl group containing from 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group
  • the A/B weight ratio is between 95/5 and 15/85 and preferably the A/B weight ratio is 30/70.
  • the A/B weight ratio is between 95/5 and 15/85.
  • the A/B ratio is less than or equal to 70/30. These preferred ratios have proven to allow comfortable deposits due to the absence of percolation of the rigid particles of MQ resin in the deposit.
  • the composition comprises at least one volatile oil.
  • the volatile oil may in particular be a silicone oil, a hydrocarbon-based oil, which is preferably non-polar, or a fluoro oil.
  • the volatile oil is a silicone oil and may be chosen in particular from silicone oils with a flash point ranging from 40°C to 102°C, preferably with a flash point of greater than 55°C and less than or equal to 95°C, and preferentially ranging from 65°C to 95°C.
  • volatile silicone oils that may be used in the invention, mention may be made of linear or cyclic silicones with a viscosity at ambient temperature of less than 8 centistokes (cSt) (8 x 10 "6 m 2 /s), and in particular containing from 2 to 10 silicon atoms and in particular from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups containing from 1 to 10 carbon atoms.
  • cSt centistokes
  • volatile silicone oils that may be used in the invention, mention may be made in particular of dimethicones with a viscosity of 5 and 6 cSt, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane and dodecamethylpentasiloxane, and mixtures thereof.
  • the volatile oil is a fluoro oil, such as nonafluoromethoxybutane or perfluoromethylcyclopentane, and mixtures thereof.
  • the volatile oil is a hydrocarbon-based oil, which is preferably non-polar.
  • the non-polar volatile hydrocarbon-based oil may have a flash point ranging from 40°C to 102°C, preferably ranging from 40°C to 55°C and preferentially ranging from 40°C to 50°C.
  • the hydrocarbon-based volatile oil may in particular be chosen from hydrocarbon-based volatile oils containing from 8 to 16 carbon atoms, and mixtures thereof, and in particular: - branched Cg-Ci6 alkanes such as Cg-Ci6 isoalkanes (also known as isoparaffins), isododecane, isodecane and isohexadecane, and, for example, the oils sold under the trade name Isopar or Permethyl,
  • the volatile oil(s) may be present in a content ranging from 0.1% to 30% by weight and in particular from 0.5%> to 25% by weight, relative to the total weight of said composition.
  • a composition in accordance with the present invention may comprise at least one colorant, which may be chosen from water-soluble or water-insoluble, liposoluble or non-liposoluble, organic or inorganic colorants, and materials with an optical effect, and mixtures thereof.
  • the term "colorant” is intended to mean a compound that is capable of producing a coloured optical effect when it is formulated in sufficient amount in a suitable cosmetic medium.
  • the water-soluble colorants used according to the invention are more particularly water- soluble dyes.
  • water-soluble dye is intended to mean any natural or synthetic, generally organic compound, which is soluble in an aqueous phase or water- miscible solvents and which is capable of colouring.
  • water-soluble is intended to mean the capacity of a compound to be dissolved in water, measured at 25°C, to a concentration at least equal to 0.1 g/1 (production of a macroscopically isotropic, transparent, coloured or colourless solution). This solubility is in particular greater than or equal to 1 g/1.
  • water-soluble dyes that are suitable for use in the invention, mention may be made in particular of synthetic or natural water-soluble dyes, for instance FDC Red 4 (CI: 14700), DC Red 6 (Lithol Rubine Na; CI: 15850), DC Red 22 (CI: 45380), DC Red 28 (CI: 45410 Na salt), DC Red 30 (CI: 73360), DC Red 33 (CI: 17200), DC Orange 4 (CI: 15510), FDC Yellow 5 (CI: 19140), FDC Yellow 6 (CI: 15985), DC Yellow 8 (CI: 45350 Na salt), FDC Green 3 (CI: 42053), DC Green 5 (CI: 61570), FDC Blue 1 (CI: 42090).
  • FDC Red 4 CI: 14700
  • DC Red 6 Liithol Rubine Na
  • CI: 15850 DC Red 22
  • DC Red 28 CI: 45410 Na salt
  • DC Red 30 CI: 73360
  • DC Red 33 CI: 17200
  • DC Orange 4 CI: 15510
  • FDC Yellow 5 CI
  • sources of water-soluble colorant(s) that may be used in the context of the present invention, mention may be made in particular of those of natural origin, such as extracts of cochineal carmine, of beetroot, of grape, of carrot, of tomato, of annatto, of paprika, of henna, of caramel and of curcumin.
  • water-soluble colorants that are suitable for use in the invention are in particular carminic acid, betanin, anthocyans, enocyanins, lycopene, ⁇ -carotene, bixin, norbixin, capsanthin, capsorubin, flavoxanthin, lutein, cryptoxanthin, rubixanthin, violaxanthin, riboflavin, rhodoxanthin, cantaxanthin and chlorophyll, and mixtures thereof.
  • They may also be copper sulfate, iron sulfate, water-soluble sulfopolyesters, rhodamine, betaine, methylene blue, the disodium salt of tartrazine and the disodium salt of fuchsin.
  • water-soluble colorants are in particular permitted for food use.
  • dyes of the carotenoid family referenced under the food codes E120, E162, E163, E160a-g, E150a, E101, E100, E140 and E141.
  • the water-soluble colorant(s) is (are) chosen from the disodium salt of brilliant yellow FCF sold by the company LCW under the name DC Yellow 6, the disodium salt of fuchsin acid D sold by the company LCW under the name DC Red 33, and the trisodium salt of Rouge Allura sold by the company LCW under the name FD & C Red 40.
  • pigments should be understood as meaning white or coloured, inorganic (mineral) or organic particles, which are insoluble in the liquid organic phase, and which are intended to colour and/or opacify the composition and/or the deposit produced with the composition.
  • the pigments may be chosen from mineral pigments, organic pigments and composite pigments (i.e. pigments based on mineral and/or organic materials).
  • the pigments may be chosen from monochromatic pigments, lakes, nacres, and pigments with an optical effect, for instance reflective pigments and goniochromatic pigments.
  • the mineral pigments may be chosen from metal oxide pigments, chromium oxides, iron oxides, titanium dioxide, zinc oxides, cerium oxides, zirconium oxides, manganese violet, Prussian blue, ultramarine blue and ferric blue, and mixtures thereof.
  • Organic lakes are organic pigments formed from a dye attached to a substrate.
  • the lakes which are also known as organic pigments, may be chosen from the materials below, and mixtures thereof:
  • organic pigments of azo dyes include anthraquinone dyes, indigoid dyes, xanthene dyes, pyrene dyes, quinoline dyes, triphenylmethane dyes or fluoran dyes.
  • organic pigments that may in particular be mentioned are those known under the following names: D&C Blue No. 4, D&C Brown No. 1, D&C Green No. 5, D&C Green No. 6, D&C Orange No. 4, D&C Orange No. 5, D&C Orange No. 10, D&C Orange No. 11, D&C Red No. 6, D&C Red No. 7, D&C Red No. 17, D&C Red No. 21, D&C Red No. 22, D&C Red No. 27, D&C Red No.
  • the organic lakes may be insoluble sodium, potassium, calcium, barium, aluminium, zirconium, strontium or titanium salts of acidic dyes such as azo, anthraquinone, indigoid, xanthene, pyrene, quinoline, triphenylmethane or fluoran dyes, these dyes possibly comprising at least one carboxylic or sulfonic acid group.
  • acidic dyes such as azo, anthraquinone, indigoid, xanthene, pyrene, quinoline, triphenylmethane or fluoran dyes, these dyes possibly comprising at least one carboxylic or sulfonic acid group.
  • the organic lakes may also be supported on an organic support such as rosin or aluminium benzoate, for example.
  • organic lakes mention may in particular be made of those known under the following names: D&C Red No. 2 Aluminium lake, D&C Red No. 3 Aluminium lake, D&C Red No. 4 Aluminium lake, D&C Red No. 6 Aluminium lake, D&C Red No. 6 Barium lake, D&C Red No. 6 Barium/Strontium lake, D&C Red No. 6 Strontium lake, D&C Red No. 6 Potassium lake, D&C Red No. 7 Aluminium lake, D&C Red No. 7 Barium lake, D&C Red No. 7 Calcium lake, D&C Red No. 7 Calcium/Strontium lake, D&C Red No. 7 Zirconium lake, D&C Red No. 8 Sodium lake, D&C Red No.
  • liposoluble dyes such as, for example, Sudan Red, DC Red 17, DC Green 6, ⁇ -carotene, soyabean oil, Sudan Brown, DC Yellow 11, DC Violet 2, DC Orange 5 and quinoline yellow.
  • the pigments may also have been subjected to a hydrophobic treatment.
  • the hydrophobic treatment agent may be chosen from silicones such as methicones, dimethicones and perfluoroalkylsilanes; fatty acids such as stearic acid; metal soaps such as aluminium dimyristate, the aluminium salt of hydrogenated tallow glutamate, perfluoroalkyl phosphates, perfluoroalkylsilanes, perfluoroalkylsilazanes, polyhexafluoropropylene oxides, polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups and amino acids; N- acylamino acids or salts thereof; lecithin, isopropyl triisostearyl titanate, and mixtures thereof.
  • the N-acylamino acids may comprise an acyl group containing from 8 to 22 carbon atoms, for instance a 2-ethylhexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group.
  • the salts of these compounds may be aluminium, magnesium, calcium, zirconium, zinc, sodium or potassium salts.
  • the amino acid may be, for example, lysine, glutamic acid or alanine.
  • alkyl denotes in particular an alkyl group containing from 1 to 30 carbon atoms and preferably containing from 5 to 16 carbon atoms.
  • Hydrophobically treated pigments are described in particular in patent application EP-A-1 086 683.
  • nacre is intended to mean coloured particles of any form, which may or may not be iridescent, in particular produced by certain molluscs in their shell, or alternatively synthesized, and which have a colour effect via optical interference.
  • nacres examples include nacreous pigments such as titanium mica coated with an iron oxide, mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with an organic dye in particular of the abovementioned type, and also nacreous pigments based on bismuth oxychloride. They may also be mica particles at the surface of which are superposed at least two successive layers of metal oxides and/or of organic colorants.
  • the nacres may more particularly have a yellow, pink, red, bronze, orangey, brown, gold and/or coppery colour or tint.
  • nacres that may be introduced as interference pigments into the first composition
  • composition according to the invention may optionally comprise at least one or more filler(s) of organic or mineral nature.
  • filler should be understood to mean colourless or white solid particles of any shape which are in a form that is insoluble and dispersed in the medium of the composition. These particles, of mineral or organic nature, can give body or rigidity to the composition and/or softness and uniformity to the makeup. They are different from colorants.
  • fillers that may be used in the compositions according to the invention, mention may be made of silica, kaolin, bentone, starch, lauroyllysine, and fumed silica particles, optionally hydrophilically or hydrophobically treated, and mixtures thereof.
  • a composition used according to the invention may comprise one or more fillers in a content ranging from 0.1% to 15% by weight and in particular from 1%> to 10%> by weight relative to the total weight of the composition.
  • composition according to the invention may furthermore comprise any of the ingredients conventionally used as additives in the cosmetics and dermatology field.
  • additives are advantageously chosen from antioxidants, thickeners, sweeteners, basifying or acidifying agents and preserving agents, and mixtures thereof, and may be chosen advantageously from those proposed in Table 1 of the Codex Alimentarius.
  • composition in accordance with the invention may advantageously comprise at least one pentaerythrityl di-t-butyl hydroxycinnamate.
  • a composition according to the invention may also contain flavourings and/or fragrances.
  • cosmetic active agents that may be used in the invention, mention may be made of sunscreens, vitamins A, E, C and B3, provitamins such as D-panthenol, calmatives such as OC- bisabolol, Aloe vera, allantoin, plant extracts or essential oils, protective or restructuring agents, refreshing agents such as menthol and derivatives thereof, emollients, moisturizers, antiwrinkle active agents and essential fatty acids, and mixtures thereof.
  • the amounts of each of these various ingredients are those conventionally used in the fields under consideration, and range, for example, from 0.01% to 10% by weight relative to the total weight of the composition.
  • composition according to the invention may be manufactured via the known processes generally used in cosmetics or dermatology.
  • compositions of the invention can in particular be applied to the area to be treated, for example the lips, by virtue of an application member which has a porous application surface.
  • the application surface is suited to being impregnated with the composition according to the invention.
  • the application member may be entirely porous, i.e. the composition may cross from an internal surface of the application member to an external surface of the application member, or vice versa.
  • the application member may in particular consist of one or more open-cell or semi-open- cell foams.
  • the application member may be made up of at least two portions of foam, of different compressibilities, which can be adhesively bonded together.
  • the foam may be non-crosslinked or preferentially crosslinked.
  • the foam(s) is (are) elastically compressible.
  • the term "elastically compressible” is intended to mean that, starting from a position deformed by a pressure exerted on its surface, the foam returns to its initial shape when the pressure is released.
  • the releasing of the composition on the surface to be treated takes place either by capillary action on contact with the lips, or by expulsion of the composition, from the pores of the applicator, in response to a slight deformation (by pressure) of said applicator on the surface to be treated.
  • the application member may have a cylindrical shape and may have a circular cross section.
  • the application member may have any other shape, for example conical, flattened- cone, nose-cone or prism shape, and can have an oval, rectangular or polygonal cross section. It may also comprise a bevelled portion and/or a concave portion forming a hollow on the application surface.
  • the application member may be symmetrical or asymmetrical relative to a longitudinal plane of said application member.
  • the visible part of the application member may have a cross section which falls within a circle advantageously having a diameter of between 2 mm and 20 mm, and preferably between 5 mm and 15 mm.
  • the visible part of the application member, in the non-compressed position may be between 2 mm and 20 mm in height.
  • the application member may consist of several different materials, in particular of a stack of foams having different characteristics.
  • the application member may consist of one or more foams chosen from polyether, polyester, polyurethane, polyester-polyurethane, NBR (natural butadiene rubber), SBR (synthetic butadiene rubber) or PVC (polyvinyl chloride) foams, or mixtures thereof, and quite particularly polyester-polyurethane, in particular the product S90 from Crest Foam Industries.
  • foams chosen from polyether, polyester, polyurethane, polyester-polyurethane, NBR (natural butadiene rubber), SBR (synthetic butadiene rubber) or PVC (polyvinyl chloride) foams, or mixtures thereof, and quite particularly polyester-polyurethane, in particular the product S90 from Crest Foam Industries.
  • the density of the foam(s) forming the application member may advantageously be between 0.02 g.cm 3 and 0.05 g.cm 3 , for example 0.03 g.cm 3 . This density makes it possible to release an appropriate amount of impregnated composition.
  • the average number of pores or cells of the foam(s) may advantageously be between 25 and 50 pores per centimetre, for example equal to 35 pores per centimetre.
  • the average pore size may advantageously be between 0.2 mm and 0.5 mm. It should be noted that the evaluation of the average number of pores is conventionally carried out visually by counting.
  • the cells or pores communicate with one another omnidirectionally.
  • the hardness of the application surface of the applicator member measured by means of an F-type durometer from Asker, may advantageously be between 10 Asker F and 70 Asker F.
  • At least one part of the surface of the application member may be covered with a flock, in particular based on polyamide, rayon, cotton, viscose or nylon fibres.
  • the flock contributes to creating a store of product, immediately in the neighbourhood of the application surface.
  • it makes it possible to impart more softness on application, in particular when the application member is made of wide-cell foam.
  • the flock may contribute to the homogenization of the spreading of the composition to form a thin film.
  • the flock may consist of a mixture of fibres of various length and/or nature and/or diameter.
  • the length of the fibres may advantageously be between 0.2 mm and 1 mm, for example equal to 0.75 mm.
  • the fibre count grading unit may advantageously be between 0.3 dtex and 3.3 dtex, for example equal to 1.7 dtex.
  • the application surface can be covered with a permeable coating of textile, perforated plastic or felt type.
  • the device comprises a composition-dispensing mechanism which makes it possible to expel said composition from the container to the application member.
  • said dispensing mechanism advantageously comprises a composition-metering means.
  • FIG. 1 is a sectional view of an application device according to a first embodiment
  • FIG. 2 is an exploded view of an application device according to a second embodiment
  • FIG. 3 is a sectional view of the device of Figure 2.
  • the device 1 comprises a cylindrical polypropylene body 2 having a longitudinal axis X.
  • the body 2 denotes a first housing 3 (container), delimited by a cylindrical skirt 19, a first end 18 of which is open, and a second end of which, opposite the first, is closed by a transverse wall 16 comprising passages which emerge to form a grille 42.
  • the transverse wall 16 separates the first housing 3 from a second housing 6, located above the first housing 3.
  • the upper housing 6 has a bottom 7, in the shape of a hemisphere, into which the passages forming the grille 42 emerge.
  • the external surface of the housing 6 comprises the figure represents a screw thread 10 intended to cooperate with a corresponding screw thread 11 provided for on the internal surface of a skirt 12 of a stopper 13.
  • the stopper is reversibly snap-fastened onto the external surface of the housing 6.
  • the stopper 13 is rigidly connected to an applicator 14 correspondingly made to match the hemispherical profile defined by the bottom 7 of the housing 6.
  • the application member 14 may be adhesively bonded, welded or crimped onto the cap 13.
  • the application member consists of an open-cell polyurethane foam.
  • the density of the foam forming the application member measured according to standard ASTM D 3574-05, is advantageously between 0.02 g.cm 3 and 0.05 g.cm 3 , for example equal to 0.03 g.cm 3 .
  • At least one part of the surface 14 of the application member is covered with a flock 15, in particular based on rayon, cotton, viscose or nylon fibres.
  • the length of the fibres is advantageously between 0.2 mm and 1 mm, for example 0.75 mm.
  • the fibre count grading unit is advantageously between 0.3 dtex and 3.3 dtex, for example equal to 1.7 dtex.
  • the application member 14 is proportioned relative to the housing 6 such that, when the stopper 13 is in the closed position, at least one portion of the application surface of the application member 14 is in contact with the bottom 7.
  • the application member 14 is proportioned such that, in this position, it is not appreciably axially compressed.
  • the composition of the invention is here referred to as product P.
  • This product P is contained inside the housing 3 forming a container, the open end 18 of the housing 3 being closed via a dispensing mechanism 30.
  • the latter is mounted by clip-fastening onto the body 2 of the housing 3, after filling with the product P inside the housing 3 through its open end 18.
  • the mechanism 30 comprises an actuating wheel 31 mounted to rotate freely with respect to the body 2, via a bulge/groove arrangement.
  • the wheel 31 is rigidly connected to a threaded rod 32 capable of axially driving a threaded piston 33, incapable of rotating inside the container, for example by virtue of a rib/notch assembly which prevents the piston from rotating inside the container.
  • the mechanism may also comprise a metering means, such as a ratchet system, capable of periodically generating an audible sound, so as to inform the user of the amount of product dispensed.
  • the mechanism associated with the first housing, for causing the product to exit may be different; for example, the walls of the body 2 may be deformable in order to apply, by crimping, an overpressure in the container so as to expel the product through the grille.
  • the user turns the actuating wheel through half or one turn, with the cap 13 in the closed position over the opening 9 of the housing 6, so as to cause a corresponding amount of product P to pass from the container to the applicator 14 contained in the housing 6, via the passage of the grille 42.
  • the product is taken up by the applicator 14, in particular by capillary action. All that then remains is for the cap 13 to be unscrewed so that the application member can be extracted therefrom and for the product P to be applied by moving the application surface of the application member 14 over lips, in order to deposit the product impregnated in the application member.
  • the application member 14 is axially oversized with respect to the housing 6.
  • the device is in the form of an applicator bottle for a product P, and comprises mainly a container or reservoir 110 consisting of a body 111, one end of which is closed by a bottom 112.
  • the other end of the reservoir 110 is surmounted by an application head which comprises an intermediate element 130 intended for mounting the head on the reservoir and an application member 120 housed in the intermediate element.
  • the intermediate element 130 comprises, on its external surface, means 132 (of screw thread or snap-fitting bead type) for enabling the removable mounting of a stopper 140 capable of covering the application member 120.
  • a dispensing mechanism can be combined with the reservoir, for example a piston mechanism as previously described, or flexible walls making it possible to generate an overpressure in the reservoir in order to expel the product.
  • a ball 160 can be placed inside the reservoir so as to homogenize the product in order to facilitate the flow thereof and/or to facilitate the conveying thereof to the application member.
  • the internal wall of the intermediate element 130 defines a cylindrical internal housing 133 which rotates about an axis X.
  • This housing 133 comprises a side wall 134 and a planar transverse wall 135 constituting the bottom of the housing.
  • a fitting skirt 136 extends the side wall beyond the transverse wall, on the opposite side from the opening 131 of the intermediate element.
  • the fitting skirt 136 is attached, by snap-fitting, onto the body of the reservoir, at the top of which a radial projection 114 is provided for, on the opposite side from the bottom 112.
  • This snap-fitting system can of course be replaced with any other system of attachment, in particular a screw attachment system.
  • a sealing skirt 137 is advantageously provided for on the transverse wall 135 of the housing so as to come into leaktight contact with the inside of the reservoir.
  • the body 111 of the reservoir, the intermediate element 130 and also the stopper 140 are made of rigid material, for example of polyethylene. It is obvious that these three independent elements can each be made of a different material. It is thus possible to envisage using a flexible material for at least one part of the reservoir.
  • the housing 133 communicates with the inside of the reservoir via a passage 139 which passes through a shaft 115 extending along the axis of the housing.
  • the shaft is made up of a single part with the transverse wall 135 from which it extends to a free end, located inside the housing 133.
  • the shaft has a circular internal cross section, which is constant throughout its axial height, whereas its external cross section decreases to the free end.
  • the diameter of the shaft is chosen according to the product contained in the reservoir, in such a way that the product coming from the reservoir can flow in the shaft, for example by simply shaking the assembly.
  • the application member 120 is mounted inside the housing 133 around the shaft 115.
  • the application member is in the form of a block of porous material(s), at least one part of which is elastically compressible.
  • the application member is made up of a block of open-cell foam, in particular a block of polyurethane foam.
  • the application member 120 may be made up of an axial succession of at least two portions of foam, of different compressibilities, which can be adhesively bonded together.
  • the application member has a cylindrical shape and has a circular cross section. It is obvious that the application member can have any other shape, and can have any other cross section.
  • the application member 120 has a side wall 121, one end 122 of which constitutes a dome- shaped application surface.
  • the application surface 122 can be covered with a flock.
  • the flock can consist of hairs of various diameters and/or of various natures and/or of various heights, or of a mixture of such hairs.
  • the application member ends with a second open end 124 which comes into contact with the transverse wall 135 of the housing.
  • the end 124 can be permanently attached to the intermediate element 130.
  • this end is removably attached so as to make it possible to easily remove the application member in order, for example, to clean it.
  • the end 124 of the application member is covered with a permanent adhesive, for example an acrylic adhesive, which adheres more to the application member than to the wall 135.
  • a portion 123 of the side wall located on the side of the open end 124 acts as a support for the application member.
  • the portion 123 acting as a support for the application member is separated from the rest of the application member by an annular groove 150 which defines a zone of smaller cross section.
  • the annular groove 150 provided for on the periphery of the application member enables the zone of smaller cross section to have a greater compressibility than the rest of the application member.
  • the application member When the application member is mounted in the housing 133, it occupies approximately the entire housing, the application member having a shape approximately complementary to the shape of the housing.
  • the application member 120 has in particular an axial recess 125, the shape of which is adjusted so that the application member comes to press against the wall of the shaft, without being substantially laterally compressed by said shaft.
  • the side wall of the application member can be at a distance from the shaft.
  • the axial recess 125 When the application member is in the relaxed position, the axial recess 125 has an axial height which is substantially greater than the axial height of the shaft 115 so as to define an internal cavity inside the application member, between an internal surface 126 located facing the shaft and the free end of the shaft.
  • the portion 127 of the application member located above the cavity has an axial thickness which is smaller than the thickness of the lateral edge 121 of the application member, measured perpendicular to the axis X.
  • the cavity can thus constitute a store of product in proximity to the application surface, it being possible for the product to come into contact with the application member only in the cavity.
  • the application member has a diameter of between 2 mm and 20 mm, and preferably between 5 mm and 15 mm. Its height, in the non-compressed position, can range between 2 mm and 20 mm.
  • the application member 120 comprises pores or open cells which have an average size of between 0.3 mm and 0.5 mm.
  • the pores or cells communicate with one another omnidirectionally.
  • the user shakes the packaging and application assembly in order to bring the product into the shaft and into the application member.
  • the user actuates a dispensing mechanism in order to bring the product to the application member.
  • Product is then kept inside the block of foam 120 of the application member by capillary action. All that is then needed is to bring the application member 120 into contact with the area to be treated; a slight pressure can be applied so as to place the product present in the cells of the foam in proximity to the application surface 122.
  • Product is then spread by passing the application surface 122 over the support to be treated, by simple capillary contact, so as to draw the product in the form of a film, under the action of the affinity of the product that is exerted between the application surface and the support to be treated, without the slightest pressure being appreciably exerted on the application assembly.
  • the shape of the applicator may be different from the shape illustrated with reference to the embodiments that have just been described.
  • the shape of the applicator is chosen according to the area to be treated. For example, in the case of an applicator for the lips, an applicator approximately in the shape of a cone, a nose-cone or a hemisphere will more particularly be used, the applicator optionally comprising a bevelled face.
  • the applicator can be dissociated from a container containing the product without a dispensing mechanism.
  • the device is then used by dipping the applicator in the container and then by applying the product to the lips by means of the applicator.
  • composition of which the ingredients are collated in the table below is prepared; the amounts are expressed in weight amount of starting material.
  • phase C the ground pigmentary material was prepared by mixing the pigments into octyldodecanol, and the whole mixture was ground in an Exakt three-roll machine.
  • Phase A and phase B were then mixed with stirring in a Rayneri mixer for 15 minutes, and then the ground pigmentary material was added. The mixture was left to stir for 20 minutes.
  • phase D The nacres (phase D), the fragrance and the silicone oil were then added.
  • the mixture was stirred until a homogeneous cream was obtained.
  • the silica was then added.
  • the mixture was stirred until a homogeneous cream was obtained.
  • composition was then introduced into a device similar to Figures 2 and 3, the application member of which consists of the S90NR foam from the company Crest Foam Industries, covered with a flock from the company ERZI Flocktechnik (0.75 mm; 1.7 dtex).
  • the device makes it possible to apply a film to the lips, measured wet (therefore before drying), of 29.9 ⁇ 3.9 ⁇
  • This protocol is an in vitro measurement.
  • composition is applied by means of the device so as to obtain an even deposit covering the entire surface of the skin square.
  • Thickness (cm) volume of composition applied (g): density of the composition (g/cm 3 ).
  • the density of the composition is 1.
  • the average thickness is given with three separate measurements.

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  • Life Sciences & Earth Sciences (AREA)
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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne un dispositif d'application comprenant : un récipient (3; 110); une composition liquide anhydre pour se maquiller et/ou prendre soin des lèvres (P), stockée dans le récipient, comprenant : a) au moins une huile non-volatile; b) au moins un agent de formation de film; un élément d'application qui comporte une surface d'application poreuse (14; 120). L'invention concerne également un procédé de maquillage et/ou de soins des lèvres, la composition susmentionnée étant appliquée sur les lèvres.
PCT/EP2014/055975 2013-03-25 2014-03-25 Dispositif comprenant une composition de rouge a levres liquide anhydre et un element d'application poreux WO2014154698A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1352652A FR3003449B1 (fr) 2013-03-25 2013-03-25 Dipositif comprenant une composition de rouge a levres liquide anhydre et un organe d'application poreux
FR1352652 2013-03-25

Publications (2)

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WO2014154698A2 true WO2014154698A2 (fr) 2014-10-02
WO2014154698A3 WO2014154698A3 (fr) 2014-11-13

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FR (1) FR3003449B1 (fr)
WO (1) WO2014154698A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113165011A (zh) * 2018-12-07 2021-07-23 花王株式会社 涂膜的形成方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017167667A1 (fr) * 2016-03-31 2017-10-05 L'oreal Émulsion aqueuse comprenant un polymère dendritique à base de silicone, une gomme de silicone et un polymère semi-cristallin ou une cire et un traitement des lèvres
FR3049458B1 (fr) * 2016-03-31 2019-08-23 L'oreal Emulsion aqueuse comprenant un polymere dendritique silicone, une gomme de silicone et un polymere semi-cristallin et procede de traitement des levres la mettant en œuvre

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
US6280748B1 (en) * 1998-06-12 2001-08-28 Dow Corning Toray Silicone, Ltd. Cosmetic raw material cosmetic product and method for manufacturing cosmetic products
US7186045B2 (en) * 2000-02-16 2007-03-06 L'oreal S.A. Device and method for applying a cosmetic product
FR2860143B1 (fr) * 2003-09-26 2008-06-27 Oreal Composition cosmetique comprenant un polymere sequence et une huile siliconee non volatile
FR2860960B1 (fr) * 2003-10-17 2007-03-30 Oreal Applicateur d'un produit, notamment cosmetique
FR2925264B1 (fr) * 2007-12-19 2011-03-18 Oreal Dispositif de conditionnement.
US8541009B2 (en) * 2008-06-11 2013-09-24 Kao Corporation Cosmetic
FR2935268B1 (fr) * 2008-09-04 2010-10-15 Oreal Composition cosmetique comprenant un polymere a motif dendrimere carbosiloxane.
FR2950232B1 (fr) * 2009-09-21 2012-06-01 Oreal Ensemble de conditionnement et d'application cosmetique pour compositions rheofluidifiantes
WO2011078407A1 (fr) * 2009-12-24 2011-06-30 Dow Corning Toray Co., Ltd. Copolymère présentant une structure de dendrimère carbosiloxane, composition et produit cosmétique contenant ce polymère

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113165011A (zh) * 2018-12-07 2021-07-23 花王株式会社 涂膜的形成方法
CN113165011B (zh) * 2018-12-07 2023-01-03 花王株式会社 涂膜的形成方法

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WO2014154698A3 (fr) 2014-11-13
FR3003449A1 (fr) 2014-09-26
FR3003449B1 (fr) 2015-05-15

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