WO2014092343A1 - Functional film, and flexible printed circuit board including same - Google Patents

Functional film, and flexible printed circuit board including same Download PDF

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Publication number
WO2014092343A1
WO2014092343A1 PCT/KR2013/010060 KR2013010060W WO2014092343A1 WO 2014092343 A1 WO2014092343 A1 WO 2014092343A1 KR 2013010060 W KR2013010060 W KR 2013010060W WO 2014092343 A1 WO2014092343 A1 WO 2014092343A1
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WO
WIPO (PCT)
Prior art keywords
layer
functional film
primer
conductive
primer layer
Prior art date
Application number
PCT/KR2013/010060
Other languages
French (fr)
Korean (ko)
Inventor
남광현
Original Assignee
Nam Kwang Hyun
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nam Kwang Hyun filed Critical Nam Kwang Hyun
Publication of WO2014092343A1 publication Critical patent/WO2014092343A1/en

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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/22Secondary treatment of printed circuits
    • H05K3/28Applying non-metallic protective coatings
    • H05K3/281Applying non-metallic protective coatings by means of a preformed insulating foil
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K9/00Screening of apparatus or components against electric or magnetic fields
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/0213Electrical arrangements not otherwise provided for
    • H05K1/0216Reduction of cross-talk, noise or electromagnetic interference
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0393Flexible materials
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/01Dielectrics
    • H05K2201/0137Materials
    • H05K2201/0179Thin film deposited insulating layer, e.g. inorganic layer for printed capacitor
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/02Fillers; Particles; Fibers; Reinforcement materials
    • H05K2201/0203Fillers and particles
    • H05K2201/0242Shape of an individual particle
    • H05K2201/0245Flakes, flat particles or lamellar particles
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/02Fillers; Particles; Fibers; Reinforcement materials
    • H05K2201/0203Fillers and particles
    • H05K2201/0242Shape of an individual particle
    • H05K2201/0248Needles or elongated particles; Elongated cluster of chemically bonded particles
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/02Fillers; Particles; Fibers; Reinforcement materials
    • H05K2201/0203Fillers and particles
    • H05K2201/0242Shape of an individual particle
    • H05K2201/026Nanotubes or nanowires
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/03Conductive materials
    • H05K2201/032Materials
    • H05K2201/0323Carbon
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/03Conductive materials
    • H05K2201/0332Structure of the conductor
    • H05K2201/0335Layered conductors or foils
    • H05K2201/0338Layered conductor, e.g. layered metal substrate, layered finish layer or layered thin film adhesion layer
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/03Conductive materials
    • H05K2201/0332Structure of the conductor
    • H05K2201/0388Other aspects of conductors
    • H05K2201/0391Using different types of conductors

Definitions

  • the present application relates to a functional film and a flexible circuit board including the same.
  • FPCBs flexible printed circuit boards
  • each of the components attached to the flexible circuit board uses different frequencies. At this time, each component generates electromagnetic waves, and these electromagnetic waves interfere with each other, causing electromagnetic interference, causing malfunction, noise, and bleeding of the LCD screen, and the distance between components due to high integration due to the miniaturization tendency of the circuit. As they get closer, these disorders are becoming more frequent than ever.
  • the conventional method could not sufficiently solve the problems caused by the electromagnetic waves generated in the flexible circuit board.
  • An object of the present invention is to provide a functional film capable of preventing malfunction and smearing of a liquid crystal screen by effectively blocking the electromagnetic waves generated from the components attached to the circuit board of the flexible circuit board by improving flexibility.
  • the functional film according to the first aspect of the present application the insulating layer; A primer layer formed on the insulating layer; A conductive layer formed on the primer layer; And an adhesive layer formed on the conductive layer, wherein the primer layer may be conductive.
  • the flexible circuit board according to the second aspect of the present application including the functional film according to the first aspect of the present application, the upper side may be provided so that the adhesive layer abuts.
  • the manufacturing method of the functional film according to the third aspect of the present invention the manufacturing method of the functional film of the first aspect of the present application, forming the primer layer on the insulating layer; Forming the conductive layer on the primer layer; It may include the step of forming the adhesive layer on the conductive layer.
  • the functional film comprises a primer layer containing a conductive material, thereby improving the surface resistance value to increase the electromagnetic shielding efficiency, cracks occur in the conductive layer at the bent portion of the flexible circuit board
  • the primer layer serves as a bridge can effectively shield the electromagnetic waves.
  • FIG. 1 is a conceptual diagram showing a functional film according to an embodiment of the present application.
  • FIG. 2 is a conceptual diagram illustrating a flexible circuit board according to an embodiment of the present disclosure.
  • FIG. 3 is a conceptual diagram illustrating a tensile force applied to a functional film when a functional film according to an embodiment of the present application is attached to a flexible circuit board.
  • Figure 4 is a flow chart showing a method of manufacturing a functional film according to an embodiment of the present application.
  • 5 to 9 is a view schematically showing a manufacturing process of a functional film according to an embodiment of the present application.
  • the term “combination of these” included in the expression of the makushi form means one or more mixtures or combinations selected from the group consisting of constituents described in the expression of the makushi form, wherein the constituents It means to include one or more selected from the group consisting of.
  • the terms related to directions or positions are set based on the arrangement state of each component shown in the drawings.
  • the upper side may be the upper side
  • the lower side may be the lower side
  • the upper side and the lower side may be arranged in various directions such as being reversed.
  • the functional film 1 (hereinafter referred to as 'the present functional film') according to an embodiment of the present application will be described.
  • Electromagnetic waves generated from components attached to the flexible circuit board 3 affect different components, causing malfunctions and smearing of the LCD screen. Therefore, in order to prevent these problems, a functional film having an electromagnetic shielding function is attached on the circuit board.
  • the medium made of metal has a property of reflecting all light
  • the functional film blocks most of the electromagnetic waves by blocking most of the electromagnetic waves by reflecting most of the electromagnetic waves through the layer made of these metallic components. Therefore, the functional film has a high electrical conductivity, the better the shielding function of the electromagnetic wave is formed of a material having a very low impedance.
  • the present functional film 1 includes an insulating layer 10.
  • the functional film 1 is attached to the flexible circuit board 3 through thermal compression.
  • the press bonding process is performed at a high temperature of about 170 °C to about 180 °C
  • the lead-free soldering process of the surface mounting process is performed at a high temperature of about 250 °C to about 270 °C
  • primer layer 30 In order to protect the conductive layer 50 and the adhesive layer 70, the insulating layer 10 is provided. Therefore, the insulating layer 10 is preferably made of a material having good heat resistance.
  • the insulating layer 10 may include polyphenylene sulfide (PPS), polyethylene naphthalate (PEN), polycarbonate (PC), and the like, and preferably other It may include polyimide (PI) having better heat resistance than the material.
  • PPS polyphenylene sulfide
  • PEN polyethylene naphthalate
  • PC polycarbonate
  • PI polyimide
  • the insulating layer 10 may have a thickness of 12 ⁇ m.
  • the present functional film 1 includes a primer layer 30.
  • the primer layer 30 is formed on the insulating layer 10.
  • the primer layer 30 is conductive.
  • the functional film 1 is attached onto the flexible circuit board 3 through heating / pressurization.
  • the tensile force is applied to the conductive layer 50 to be described later to the bent portion due to the component on the substrate in the direction shown in Figure 3, the heating temperature is raised to 280 °C to 300 °C, Cracks may occur in the conductive layer 50.
  • a crack is generated in the conductive layer 50, electromagnetic waves are escaped through the cracks, thereby degrading the electromagnetic shielding effect.
  • Electromagnetic waves may affect other components.
  • the conductive primer layer 30 formed between the insulating layer 10 and the conductive layer 50 serves as a bridge to block the electromagnetic wave that escapes between the cracks of the conductive layer 50, thereby improving the surface resistance value electromagnetic waves Can be effectively blocked.
  • the primer layer 30 may include a fine structure having conductivity.
  • the microstructure is preferably formed of a material having high conductivity in order to effectively block the electromagnetic wave that escapes between the cracks of the conductive layer 50.
  • the microstructure may include any one or more of silver (Ag), copper (Cu), and nickel (Ni).
  • the present invention is not limited thereto, and the microstructure may be formed of various metal materials having high conductivity.
  • the microstructures may have the form of flakes or wires.
  • the microstructure may be disposed over a wider range with respect to the surface direction in which the primer layer 30 is formed, the electromagnetic wave may be more effectively blocked.
  • the microstructures may be silver nanowires.
  • the microstructures may be conductive carbon.
  • the microstructure is preferably carbon nanotubes (CNT) having excellent physical properties compared to the unit price.
  • CNT carbon nanotubes
  • the present invention is not limited thereto, and the microstructure may be graphene or the like.
  • the primer layer 30 may include a primer base layer 31.
  • the functional film 1 when the functional film 1 is attached onto the flexible circuit board 3, the functional film 1 is subjected to a tensile force due to a bending part due to a component on the substrate, and thus, the tensile force may be reduced.
  • the primer base layer 31 is preferably made of a flexible material so as not to be broken by the material. Through this, the flexibility of the functional film 1 can be improved.
  • the primer base layer 31 may include a polyester resin, an epoxy resin, a polyurethane resin, or the like.
  • the primer base layer 31 may be a modified polyester (epester) resin or epoxy (epoxy) resin.
  • epester polyester
  • epoxy epoxy
  • the primer layer 30 may be formed on the primer base layer 31, and may include a primer conductive layer 33 including a microstructure.
  • the primer conductive layer 33 may block the electromagnetic wave escaping through the crack of the conductive layer 50, so that the functional film 1 having a better electromagnetic shielding function may be realized.
  • the microstructures are evenly dispersed in the primer conductive layer 33 as evenly as possible.
  • the primer conductive layer 33 may include the nanostructured microstructure and the conductive carbon microstructure at the same time, or may include only one of the nanostructured microstructure or the conductive carbon microstructure.
  • the primer layer 30 may have a thickness of 0.02 ⁇ m or more and 10 ⁇ m or less.
  • the thickness of the primer layer 30 is less than 0.02 ⁇ m, the portion having conductivity is too small so that the primer layer 30 may have a conductivity enough to shield the electromagnetic waves from escaping through the crack of the conductive layer 50. none.
  • the thickness of the primer layer 30 exceeds 10 ⁇ m, since the rigidity of the primer layer 30 is increased and flexibility is reduced, the degree of being pressed onto the flexible circuit board 3 when the functional film 1 is attached is increased. It can be degraded and electromagnetic waves can affect each other between components on the substrate. Therefore, problems such as malfunction, screen blur, and the like cannot be effectively prevented.
  • the primer layer 30 may have an elongation of 30% or more and 200% or less.
  • the primer layer 30 when thermally compressing the functional film 1, the primer layer 30 may be protected from the high temperature by the insulating layer 10, but complete heat shielding is impossible, and thus the primer layer 30 itself may be somewhat heat resistant. Need to have, in order to form the primer layer 30 having an elongation of more than 200%, the primer layer 30 should include a much larger amount of rubber compared to the amount of the epoxy resin, which is the primer layer 30 Heat resistance is inferior. Accordingly, it is not possible to withstand the lead-free soldering process in the press crimping process at a high temperature of about 170 ° C to about 180 ° C and the SMT process at a high temperature of about 250 ° C to about 270 ° C. In addition, since the primer layer 30 is formed too soft, the primer layer 30 may melt and leak to the side at a high temperature.
  • the primer layer 30 may have cracking resistance and heat resistance to withstand high-temperature processes and flexibility to be in close contact with the flexible circuit board 3.
  • the primer layer 30 is formed to have an elongation of 50% or more and 150% or less, thereby ensuring optimal heat resistance and flexibility.
  • the color of the primer layer 30 may be a color having low brightness.
  • the primer layer 30 may be black.
  • the present functional film 1 includes a conductive layer 50.
  • the conductive layer 50 is preferably made of a material having a low electrical resistance so that the electromagnetic wave generated in the component can be converted into the surface current to flow on the surface of the conductive layer 50.
  • the conductive layer 50 is formed on the primer layer 30.
  • the conductive layer 50 has high electrical conductivity but may be inferior in flexibility. Therefore, in the process of attaching the functional film 1 to the flexible circuit board 3 by being pressed / heated, cracks may be generated in the conductive layer 50, and electromagnetic waves may escape through the cracks, thereby affecting other components. Can give
  • a cracking phenomenon of the conductive wire 50 may be prevented by the primer layer 30 having high flexibility.
  • the conductive layer 50 may include silver (Ag).
  • the conductive layer 50 is formed by depositing on the primer layer 30.
  • the conductive layer 50 may be formed through the cheapest process when deposited with silver (Ag).
  • the conductive layer 50 may include copper (Cu), nickel (Ni), and aluminum (Al). In addition, the conductive layer 50 may include a highly conductive material.
  • the conductive layer 50 may be formed by silver deposition to a thickness of 800 kPa.
  • the present functional film 1 includes an adhesive layer 70.
  • the adhesive layer 70 is formed on the conductive layer 50.
  • the adhesive layer 70 is attached to the flexible circuit board 3 and is preferably made of a material having excellent adhesive ability.
  • the adhesive layer 70 may include an epoxy resin or a polyester resin.
  • the adhesive layer 70 made of such a material may have excellent adhesive ability as compared with that made of polyether resin.
  • the adhesive layer 70 may include conductive particles 71.
  • the adhesive layer 70 may have anisotropic conductivity. Therefore, when the functional film 1 is attached on the flexible circuit board 3, the circuit and the conductive layer 50 can be electrically connected to each other, and can be electrically insulated between adjacent components.
  • the conductive particles 71 may mean not only spherical particles but also particles formed in a wire, plate, or the like form.
  • the conductive particles 71 may include at least one of silver (Ag), copper (Cu), nickel (Ni), and silver (Ag) coated copper (Cu).
  • the conductive particles 71 preferably have excellent conductivity so that the circuit and the conductive layer 50 can be electrically connected to each other.
  • the conductive particles 71 include silver coated copper coated with silver having low reactivity to copper having high conductivity, high conductivity and chemical stability may be secured at the same time.
  • the functional film 1 may include a protective film 90.
  • the protective film 90 may be formed under the insulating layer 10.
  • the protective film 90 may serve to protect the damage before the functional film 1 is attached onto the flexible circuit board 3.
  • the protective film 90 may include a release layer on the upper side.
  • the protective film 90 can be removed.
  • FIG. 10 compares the surface resistance values according to the tensile test of the examples of the functional film 1 and the functional films of Comparative Examples 1 and 2.
  • FIG. 10 compares the surface resistance values according to the tensile test of the examples of the functional film 1 and the functional films of Comparative Examples 1 and 2.
  • the conductive primer layer 30 is formed by coating the conductive primer layer 30 to a thickness of 3 ⁇ m on a 12 ⁇ m thick insulating layer 10 including polyimide, and then, silver is deposited on the conductive layer to conduct a thickness of 800 ⁇ m.
  • the layer 50 is formed.
  • the primer layer 30 includes 30% by weight of a phenol-modified epoxy resin and 10% by weight of polyester resin, 2% by weight of phthalic anhydride as a curing agent, and 53% by weight of methylethylketone as a solvent.
  • As the conductive microstructure 2 wt% of silver nanowires having an average particle diameter of 100 nm and an average length of 50 ⁇ m and 3 wt% of conductive carbon are formed.
  • YDPN 644 of Kukdo Chemical was used for phenol-modified epoxy resin
  • Vylon 550 of Toyobo Co., Ltd. was used
  • acid anhydride curing agent MNA of Kukdo Chemical was used for polyester resin.
  • silver nanowires were used a100 grade of KEC Tech
  • conductive carbon was used Ketjenblack 300 grade of Pyung Hwa Chemical
  • the insulating layer 10 containing polyimide was used LN grade of SKkolon.
  • the primer layer does not include the conductive microstructures included in the above-described embodiment
  • the primer layer itself of the above-described embodiment is not included, and the rest are all examples. Are formed under the same conditions as.
  • Comparative Examples 1 and 2 produced by the above components and forms are as follows.
  • the present functional film (1) containing the conductive primer layer 30 and Comparative Example 1 including the non-conductive primer layer the present functional film (1) at 30% and 50% tension Although the surface resistance of is still low and little change, it can be seen that in Comparative Example 1 the surface resistance is significantly increased. Therefore, it can be seen that the present functional film 1 having the conductive primer layer 30 is excellent in electromagnetic wave shielding effect.
  • the functional film 1 when comparing the present functional film 1 with the primer layer 30 and Comparative Example 2 without the primer layer, the functional film 1 is secured by the primer layer 30 at the time of stretching Although not broken, Comparative Example 2 has no flexibility and can be seen to be disconnected at 50% tensile strength. Therefore, it can be seen that the present functional film 1 having the primer layer 30 is excellent in flexibility and can be attached to the flexible printed circuit board 3 provided with various components without damage.
  • the flexible circuit board 3 (hereinafter referred to as "the flexible circuit board") according to an embodiment of the present application will be described.
  • the same reference numerals are used for the same or similar components as those described in the functional film 1 according to an embodiment of the present invention, and the overlapping description will be briefly or omitted.
  • the flexible printed circuit board 3 includes the present functional film 1.
  • the flexible circuit board 3 may effectively shield electromagnetic waves generated from components, such that malfunction, noise, and screen bleeding may not occur.
  • the flexible circuit board 3 may have excellent flexibility and sliding resistance.
  • the adhesive layer 70 abuts on the upper side of the flexible printed circuit board 3.
  • the functional film 1 may be bonded such that the adhesive layer 70 abuts on the flexible circuit board 3.
  • the adhesive layer 70 includes the conductive particles 71
  • electromagnetic waves may be shielded by energizing the circuit and the conductive layer 50.
  • the manufacturing method of the present functional film includes forming a primer layer 30 on the insulating layer 10 (S100).
  • the insulating layer 10 may include polyimide, and may be formed to have a thickness of 12 ⁇ m.
  • the primer layer 30 has a conductivity, serves as a bridge to block the electromagnetic waves exiting between the cracks of the conductive layer 50 so that the electromagnetic waves can be effectively blocked.
  • the forming of the primer layer 30 may include forming the primer base layer 31 on the insulating layer 10 (S110).
  • the functional film 1 is subjected to a tensile force at a bent portion due to a component on the substrate, wherein the primer base layer 31 is preferably made of a flexible material so as not to be damaged by the tensile force.
  • the primer base layer 31 may include a polyester resin, an epoxy resin, a polyurethane resin, or the like, and may include a material in which a polyester resin or an epoxy resin is modified. It is preferable to.
  • the forming of the primer layer 30 may include coating the solvent in which the conductive microstructure is dispersed on the primer base layer 31 (S120). .
  • the primer layer 30 has conductivity by the primer conductive layer 33, thereby preventing electromagnetic waves from escaping through the crack of the conductive layer 50.
  • the microstructures By coating the solvent in which the microstructures are dispersed to form the primer conductive layer 33, the microstructures may be evenly distributed on the primer base layer 31 to improve the electromagnetic shielding effect.
  • the primer layer 30 may have a thickness of 0.02 ⁇ m or more and 10 ⁇ m or less.
  • the thickness of the primer layer 30 is less than 0.02 ⁇ m, since the conductivity of the primer layer 30 is lowered, it may effectively serve as a bridge that shields electromagnetic waves emitted through the crack of the conductive layer 50. none.
  • the thickness of the primer layer 30 exceeds 10 ⁇ m, since the rigidity of the primer layer 30 is increased and flexibility is reduced, the degree of being pressed onto the flexible circuit board 3 when the functional film 1 is attached is increased. It can be degraded and electromagnetic waves can affect each other between components on the substrate. Therefore, problems such as malfunction, screen blur, and the like cannot be effectively prevented.
  • the primer layer 30 may have an elongation of 30% or more and 200% or less.
  • the primer layer 30 should include a much larger amount of rubber compared to the amount of the epoxy resin. Since the primer layer 30 is inferior in heat resistance, the primer layer 30 cannot withstand the press crimping process at a high temperature of about 170 ° C to about 180 ° C and the lead-free soldering process of the SMT process at a high temperature of about 250 ° C to about 270 ° C. In addition, since the primer layer 30 is formed too soft, the primer layer 30 may melt and leak to the side at a high temperature.
  • the primer layer 30 may have cracking resistance and heat resistance to withstand high-temperature processes and flexibility to be in close contact with the flexible circuit board 3.
  • the primer layer 30 is formed to have an elongation of 50% or more and 150% or less, thereby ensuring optimal heat resistance and flexibility.
  • the manufacturing method of the present functional film includes a step S200 of forming the conductive layer 50 on the primer layer 30 (see FIG. 8).
  • the conductive layer 50 is preferably made of a material having a low electrical resistance so that the electromagnetic wave generated in the component can be converted into the surface current to flow on the surface of the conductive layer 50.
  • the conductive layer 50 may include silver (Ag), copper (Cu), nickel (Ni), and aluminum (Al).
  • the conductive layer 50 may include a highly conductive material.
  • the conductive layer 50 may be sputter deposited on the primer layer 30.
  • the conductive layer 50 when the conductive layer 50 is formed by sputtering deposition of silver (Ag), it may be formed through the cheapest process.
  • the conductive layer 50 may be formed to have a thickness of 800 kPa through silver deposition.
  • the manufacturing method of the present functional film includes a step S300 of forming an adhesive layer 70 on the conductive layer 50 (see FIG. 9).
  • the adhesive layer 70 is a part attached to the flexible circuit board 3, and a material having excellent adhesion, for example, the adhesive layer 70 may be an epoxy resin or polyester. ) May include a resin.
  • the adhesive layer 70 may include the conductive particles 71 to have anisotropic conductivity so that the circuit and the conductive layer 50 may be energized with each other.
  • the conductive particles 71 may include, for example, any one or more of silver (Ag), copper (Cu), nickel (Ni), and silver (Ag) coated copper (Cu). .
  • the functional film 1 includes the primer layer 30, electromagnetic waves emitted between the cracks of the conductive layer 50 generated when the functional film 1 is attached to the flexible circuit board 3 through heating / pressurization of the functional film 1 may be formed. It can effectively block. Therefore, it is possible to solve the electromagnetic interference problems such as malfunction, noise, screen blur.

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Structure Of Printed Boards (AREA)
  • Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)

Abstract

The present invention relates to a functional film having an electromagnetic wave shielding function. The functional film comprises: an insulating layer; a primer layer formed on the insulating layer; a conductive layer formed on the primer layer; and an adhesive layer formed on the conductive layer, wherein the primer layer may be conductive.

Description

기능성 필름 및 이를 포함하는 연성회로기판Functional film and flexible circuit board including same
본원은 기능성 필름 및 이를 포함하는 연성회로기판에 관한 것이다.The present application relates to a functional film and a flexible circuit board including the same.
최근 무선통신 환경의 폭발적인 증가세, 전자기기의 고집적화 및 고정밀화 경향과 맞물려 휴대폰, DMB 단말기, PDA와 같은 소형 무선기기 회로에서 연성회로기판(Flexible Printed Circuit Board, FPCB)의 수요가 점차 확대되고 있다.In recent years, the demand for flexible printed circuit boards (FPCBs) is increasing in small wireless device circuits such as mobile phones, DMB terminals, and PDAs, coupled with the explosive growth of the wireless communication environment and the high integration and precision of electronic devices.
연성회로기판 상에 부착된 부품들 각각은 서로 다른 주파수를 사용한다. 이 때, 각각의 부품들은 전자파를 발생시키는데, 이러한 전자파가 서로 간섭되어 전자파 장애가 발생되어 오작동, 노이즈 발생, 액정화면의 번짐 등의 원인이 되며, 회로의 소형화 경향에 따른 고집적화에 의해 부품 간의 거리가 더 가까워져 이러한 장애가 종래에 비해 더 빈번해지고 있다. Each of the components attached to the flexible circuit board uses different frequencies. At this time, each component generates electromagnetic waves, and these electromagnetic waves interfere with each other, causing electromagnetic interference, causing malfunction, noise, and bleeding of the LCD screen, and the distance between components due to high integration due to the miniaturization tendency of the circuit. As they get closer, these disorders are becoming more frequent than ever.
이러한 문제점을 방지하기 위해서는 크게 연성회로기판에 전도성 필름을 부착하는 방법과 전도성 페이스트를 해당 회로의 상부에 인쇄하고 경화하는 방법이 있다.In order to prevent such a problem, there are largely a method of attaching a conductive film to the flexible circuit board and a method of printing and curing the conductive paste on top of the circuit.
하지만, 이러한 방법들을 사용하는 경우, 전도성 필름과 전도성 페이스트의 유연성이 떨어져 연성회로기판의 굴곡 부위에서 크랙이 발생하여 전도성이 떨어져 전자파 차단성능이 저하된다는 단점이 있다. 이와 더불어, 전도성 페이스트를 사용하는 방법의 경우, 회로의 상부에 이를 인쇄한 후 별도의 보호코팅을 해야 하므로 번거롭다는 단점이 있다.However, when using these methods, there is a disadvantage in that the flexibility of the conductive film and the conductive paste is reduced, so that cracks are generated at the bent portion of the flexible circuit board, so that the conductivity is reduced and the electromagnetic wave blocking performance is reduced. In addition, the method of using a conductive paste has a disadvantage in that it is cumbersome because a separate protective coating is to be printed after printing it on the upper part of the circuit.
이와 같은 단점으로 인해, 종래의 방법으로는 연성회로기판에서 발생되는 전자파로 인한 문제점을 충분히 해결할 수 없었다. Due to such disadvantages, the conventional method could not sufficiently solve the problems caused by the electromagnetic waves generated in the flexible circuit board.
본원은 굴곡성이 개선되어 연성회로기판의 회로 기판에 부착된 부품에서 발생되는 전자파를 효과적으로 차단함으로써, 오작동 및 액정화면의 번짐 등을 방지할 수 있는 기능성 필름을 제공하는 것을 목적으로 한다.An object of the present invention is to provide a functional film capable of preventing malfunction and smearing of a liquid crystal screen by effectively blocking the electromagnetic waves generated from the components attached to the circuit board of the flexible circuit board by improving flexibility.
상기한 기술적 과제를 달성하기 위한 기술적 수단으로서, 본원의 제 1 측면에 따른 기능성 필름은, 절연층; 상기 절연층 상에 형성되는 프라이머층; 상기 프라이머층 상에 형성되는 전도층; 및 상기 전도층 상에 형성되는 접착제층을 포함하되, 상기 프라이머층은 전도성을 갖는 것일 수 있다.As a technical means for achieving the above technical problem, the functional film according to the first aspect of the present application, the insulating layer; A primer layer formed on the insulating layer; A conductive layer formed on the primer layer; And an adhesive layer formed on the conductive layer, wherein the primer layer may be conductive.
한편, 본원의 제 2 측면에 따른 연성회로기판은, 본원의 제 1 측면에 따른 기능성 필름을 포함하되, 상측에는 상기 접착제층이 맞닿도록 구비될 수 있다.On the other hand, the flexible circuit board according to the second aspect of the present application, including the functional film according to the first aspect of the present application, the upper side may be provided so that the adhesive layer abuts.
한편, 본원의 제 3 측면에 따른 기능성 필름의 제조방법은, 본원의 제 1 측면의 기능성 필름의 제조방법으로서, 상기 절연층 상에 상기 프라이머층을 형성하는 단계; 상기 프라이머층 상에 상기 전도층을 형성하는 단계; 상기 전도층 상에 상기 접착제층을 형성하는 단계를 포함할 수 있다. On the other hand, the manufacturing method of the functional film according to the third aspect of the present invention, the manufacturing method of the functional film of the first aspect of the present application, forming the primer layer on the insulating layer; Forming the conductive layer on the primer layer; It may include the step of forming the adhesive layer on the conductive layer.
전술한 본원의 과제 해결 수단에 의하면, 기능성 필름이 전도성 물질을 포함하는 프라이머층을 포함함으로써, 표면저항값을 개선시켜 전자파 차폐효율을 높이고, 연성회로기판의 굴곡 부위에서 전도층에 크랙이 발생하여도 프라이머층이 브릿지 역할을 하여 전자파를 효과적으로 차폐할 수 있다. According to the above-described problem solving means of the present invention, the functional film comprises a primer layer containing a conductive material, thereby improving the surface resistance value to increase the electromagnetic shielding efficiency, cracks occur in the conductive layer at the bent portion of the flexible circuit board In addition, the primer layer serves as a bridge can effectively shield the electromagnetic waves.
도 1은 본원의 일 실시예에 따른 기능성 필름을 나타낸 개념도이다.1 is a conceptual diagram showing a functional film according to an embodiment of the present application.
도 2는 본원의 일 실시예에 따른 연성회로기판을 나타낸 개념도이다.2 is a conceptual diagram illustrating a flexible circuit board according to an embodiment of the present disclosure.
도 3은 연성회로기판에 본원의 일 실시예에 따른 기능성 필름이 부착되는 경우, 기능성 필름에 가해지는 인장력을 나타낸 개념도이다.3 is a conceptual diagram illustrating a tensile force applied to a functional film when a functional film according to an embodiment of the present application is attached to a flexible circuit board.
도 4는 본원의 일 실시예에 따른 기능성 필름의 제조방법을 나타낸 순서도이다.Figure 4 is a flow chart showing a method of manufacturing a functional film according to an embodiment of the present application.
도 5 내지 도 9는 본원의 일 실시예에 따른 기능성 필름의 제조과정을 개략적으로 나타낸 도면이다.5 to 9 is a view schematically showing a manufacturing process of a functional film according to an embodiment of the present application.
도 10은 본원의 일 실시예에 따른 기능성 필름과 비교예 1, 2에 따른 기능성 필름의 인장률에 따른 표면저항을 비교한 것이다.10 compares the surface resistance according to the tensile rate of the functional film according to an embodiment of the present application and the functional film according to Comparative Examples 1 and 2.
아래에서는 첨부한 도면을 참조하여 본원이 속하는 기술 분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 본원의 실시예를 상세히 설명한다. 그러나 본원은 여러 가지 상이한 형태로 구현될 수 있으며 여기에서 설명하는 실시예에 한정되지 않는다. 그리고 도면에서 본원을 명확하게 설명하기 위해서 설명과 관계없는 부분은 생략하였으며, 명세서 전체를 통하여 유사한 부분에 대해서는 유사한 도면 부호를 붙였다.DETAILED DESCRIPTION Hereinafter, exemplary embodiments of the present disclosure will be described in detail with reference to the accompanying drawings so that those skilled in the art may easily implement the present disclosure. As those skilled in the art would realize, the described embodiments may be modified in various different ways, all without departing from the spirit or scope of the present invention. In the drawings, parts irrelevant to the description are omitted for simplicity of explanation, and like reference numerals designate like parts throughout the specification.
본원 명세서 전체에서, 어떤 부재가 다른 부재 “상에” 위치하고 있다고 할 때, 이는 어떤 부재가 다른 부재에 접해 있는 경우뿐 아니라 두 부재 사이에 또 다른 부재가 존재하는 경우도 포함한다.Throughout this specification, when a member is located “on” another member, this includes not only when one member is in contact with another member but also when another member exists between the two members.
본원 명세서 전체에서, 어떤 부분이 어떤 구성요소를 "포함" 한다고 할 때, 이는 특별히 반대되는 기재가 없는 한 다른 구성요소를 제외하는 것이 아니라 다른 구성 요소를 더 포함할 수 있는 것을 의미한다. 본원 명세서 전체에서 사용되는 정도의 용어 "약", "실질적으로" 등은 언급된 의미에 고유한 제조 및 물질 허용오차가 제시될 때 그 수치에서 또는 그 수치에 근접한 의미로 사용되고, 본원의 이해를 돕기 위해 정확하거나 절대적인 수치가 언급된 개시 내용을 비양심적인 침해자가 부당하게 이용하는 것을 방지하기 위해 사용된다. 본원 명세서 전체에서 사용되는 정도의 용어 "~(하는) 단계" 또는 "~의 단계"는 "~ 를 위한 단계"를 의미하지 않는다.Throughout this specification, when a part is said to "include" a certain component, it means that it can further include other components, without excluding the other components unless specifically stated otherwise. As used throughout this specification, the terms "about", "substantially" and the like are used at, or in the sense of, numerical values when a manufacturing and material tolerance inherent in the stated meanings is indicated, Accurate or absolute figures are used to assist in the prevention of unfair use by unscrupulous infringers. As used throughout this specification, the term "step to" or "step of" does not mean "step for."
본원 명세서 전체에서, 마쿠시 형식의 표현에 포함된 “이들의 조합”의 용어는 마쿠시 형식의 표현에 기재된 구성 요소들로 이루어진 군에서 선택되는 하나 이상의 혼합 또는 조합을 의미하는 것으로서, 상기 구성 요소들로 이루어진 군에서 선택되는 하나 이상을 포함하는 것을 의미한다.Throughout this specification, the term “combination of these” included in the expression of the makushi form means one or more mixtures or combinations selected from the group consisting of constituents described in the expression of the makushi form, wherein the constituents It means to include one or more selected from the group consisting of.
참고로, 본원의 실시예에 관한 설명 중 방향이나 위치와 관련된 용어(상측, 하측, 등)는 도면에 나타나 있는 각 구성의 배치 상태를 기준으로 설정한 것이다. 예를 들면, 도 1에서 보았을 때 위쪽이 상측, 아래쪽이 하측 등이 될 수 있다. 다만, 본원의 실시예의 다양한 실제적인 적용에 있어서는, 상측과 하측이 반대가 되는 등 다양한 방향으로 배치될 수 있을 것이다.For reference, in the description of the embodiments of the present application, terms related to directions or positions (upper side, lower side, and the like) are set based on the arrangement state of each component shown in the drawings. For example, as seen in FIG. 1, the upper side may be the upper side, the lower side may be the lower side, and the like. However, in various practical applications of the embodiments of the present application, the upper side and the lower side may be arranged in various directions such as being reversed.
이하 첨부된 도면을 참조하여 본원을 상세히 설명하기로 한다.Hereinafter, with reference to the accompanying drawings will be described in detail the present application.
우선, 본원의 일 실시예에 따른 기능성 필름(1)(이하 '본 기능성 필름'이라 함)에 대해 설명한다.First, the functional film 1 (hereinafter referred to as 'the present functional film') according to an embodiment of the present application will be described.
연성회로기판(3)에 부착된 부품에서 발생되는 전자파는 서로 다른 부품에 영향을 끼치게 되어, 오작동, 액정화면의 번짐 등의 원인이 된다. 따라서, 이러한 문제점들을 방지하기 위해 회로기판 상에 전자파 차폐 기능을 갖는 기능성 필름이 부착된다. Electromagnetic waves generated from components attached to the flexible circuit board 3 affect different components, causing malfunctions and smearing of the LCD screen. Therefore, in order to prevent these problems, a functional film having an electromagnetic shielding function is attached on the circuit board.
이 때, 금속으로 이루어진 매질은 빛을 모두 반사하는 성질을 가지고 있는데, 기능성 필름은 이러한 금속 성분으로 이루어진 층을 통해 전자파의 대부분을 반사시킴으로써 전자파의 진로를 막아 전자파를 차단한다. 따라서, 기능성 필름은 높은 전기전도성을 가지고, 임피던스가 아주 낮은 재질로 형성될수록 전자파의 차폐 기능이 우수하게 된다.In this case, the medium made of metal has a property of reflecting all light, and the functional film blocks most of the electromagnetic waves by blocking most of the electromagnetic waves by reflecting most of the electromagnetic waves through the layer made of these metallic components. Therefore, the functional film has a high electrical conductivity, the better the shielding function of the electromagnetic wave is formed of a material having a very low impedance.
본 기능성 필름(1)은 절연층(10)을 포함한다.The present functional film 1 includes an insulating layer 10.
기능성 필름(1)은 열 압착을 통해 연성회로기판(3)에 부착시킨다. 이 때, 프레스 압착 공정은 약 170 ℃ 내지 약 180℃의 고온에서 이루어지며, 표면실장공정(SMT 공정) 중 무연 솔더링 공정은 약 250 ℃ 내지 약 270 ℃의 고온에서 이루어지므로, 프라이머층(30), 전도층(50) 및 접착제층(70)의 보호를 위해 절연층(10)이 구비된다. 따라서, 절연층(10)은 내열성이 좋은 물질로 이루어짐이 바람직하다.The functional film 1 is attached to the flexible circuit board 3 through thermal compression. At this time, the press bonding process is performed at a high temperature of about 170 ℃ to about 180 ℃, the lead-free soldering process of the surface mounting process (SMT process) is performed at a high temperature of about 250 ℃ to about 270 ℃, primer layer 30 In order to protect the conductive layer 50 and the adhesive layer 70, the insulating layer 10 is provided. Therefore, the insulating layer 10 is preferably made of a material having good heat resistance.
예를 들어, 절연층(10)은 폴리페닐렌 설파이드(polyphenylene sulfide, PPS), 폴리에틸렌 나프탈레이트(polyethylene naphthalate, PEN), 폴리카보네이트(poly carbonate, PC) 등을 포함할 수 있으며, 바람직하게는 다른 물질에 비해 내열성이 좋은 폴리이미드(polyimide, PI)를 포함할 수 있다. For example, the insulating layer 10 may include polyphenylene sulfide (PPS), polyethylene naphthalate (PEN), polycarbonate (PC), and the like, and preferably other It may include polyimide (PI) having better heat resistance than the material.
예를 들어, 절연층(10)은 12 ㎛의 두께를 가질 수 있다.For example, the insulating layer 10 may have a thickness of 12 μm.
본 기능성 필름(1)은 프라이머층(30)을 포함한다.The present functional film 1 includes a primer layer 30.
프라이머층(30)은 절연층(10) 상에 형성된다.The primer layer 30 is formed on the insulating layer 10.
프라이머층(30)은 전도성을 가진다.The primer layer 30 is conductive.
본 기능성 필름(1)은 가열/가압을 통하여 연성회로기판(3) 상에 부착된다. 이 때, 도 3을 참조하면, 기판 상의 부품으로 인한 굴곡 부분에 후술하는 전도층(50)에 도 3에 도시된 방향으로 인장력이 가해지며, 가열온도가 280 ℃ 내지 300 ℃까지 올라가게 되므로, 전도층(50)에 크랙이 발생할 수 있다. 전도층(50)에 크랙이 발생되는 경우, 크랙을 통해 전자파가 빠져나가게 되어 전자파 차폐 효과가 떨어진다. The functional film 1 is attached onto the flexible circuit board 3 through heating / pressurization. At this time, referring to Figure 3, the tensile force is applied to the conductive layer 50 to be described later to the bent portion due to the component on the substrate in the direction shown in Figure 3, the heating temperature is raised to 280 ℃ to 300 ℃, Cracks may occur in the conductive layer 50. When a crack is generated in the conductive layer 50, electromagnetic waves are escaped through the cracks, thereby degrading the electromagnetic shielding effect.
또한, 기능성 필름(1)의 가열/가압을 통한 연성회로기판(3) 상에 부착 시, 가해지는 압력의 크기를 낮추게 되면 기능성 필름(1)이 연성회로기판(3)에 밀착될 수 없어, 전자파가 다른 부품에 영향을 줄 수 있다. In addition, when attaching on the flexible circuit board 3 by heating / pressing the functional film 1, if the amount of pressure applied is lowered, the functional film 1 cannot be in close contact with the flexible circuit board 3, Electromagnetic waves may affect other components.
이에, 절연층(10)과 전도층(50) 사이에 형성된 전도성의 프라이머층(30)은 전도층(50)의 크랙 사이로 빠져나오는 전자파를 차단하는 브릿지 역할을 함으로써, 표면저항값이 개선되어 전자파가 효과적으로 차단되도록 할 수 있다. Thus, the conductive primer layer 30 formed between the insulating layer 10 and the conductive layer 50 serves as a bridge to block the electromagnetic wave that escapes between the cracks of the conductive layer 50, thereby improving the surface resistance value electromagnetic waves Can be effectively blocked.
프라이머층(30)은 전도성을 갖는 미세 구조체를 포함할 수 있다.The primer layer 30 may include a fine structure having conductivity.
미세 구조체는 전도층(50)의 크랙 사이로 빠져나오는 전자파를 효과적으로 차단하기 위해, 높은 전도성을 가지는 물질로 형성됨이 바람직하다. The microstructure is preferably formed of a material having high conductivity in order to effectively block the electromagnetic wave that escapes between the cracks of the conductive layer 50.
예를 들어, 미세 구조체는 은(Ag), 구리(Cu) 및 니켈(Ni) 중 어느 하나 이상을 포함할 수 있다. 다만, 이에만 한정되는 것은 아니고, 미세 구조체는 높은 전도성을 가지는 여러 금속 물질로 이루어질 수 있다.For example, the microstructure may include any one or more of silver (Ag), copper (Cu), and nickel (Ni). However, the present invention is not limited thereto, and the microstructure may be formed of various metal materials having high conductivity.
미세 구조체는 판상(flake) 또는 와이어(wire)의 형태를 가질 수 있다.The microstructures may have the form of flakes or wires.
이러한 형태를 가지는 경우, 미세 구조체가 구형의 형태를 가지는 경우에 비해 프라이머층(30)이 형성되는 면 방향에 대해 보다 넓은 범위에 걸쳐 배치될 수 있으므로, 보다 효과적으로 전자파를 차단할 수 있다. In the case of having such a shape, since the microstructure may be disposed over a wider range with respect to the surface direction in which the primer layer 30 is formed, the electromagnetic wave may be more effectively blocked.
예를 들어, 미세 구조체는 은 나노 와이어일 수 있다.For example, the microstructures may be silver nanowires.
미세 구조체는 전도성 카본(carbon)일 수 있다.The microstructures may be conductive carbon.
이 때, 미세 구조체는 단가 대비 물성이 우수한 탄소나노튜브(CNT)임이 바람직하다. 다만, 이에만 한정되는 것은 아니고, 미세 구조체는 그래핀(graphene) 등일 수도 있다.At this time, the microstructure is preferably carbon nanotubes (CNT) having excellent physical properties compared to the unit price. However, the present invention is not limited thereto, and the microstructure may be graphene or the like.
프라이머층(30)은 프라이머 베이스 층(31)을 포함할 수 있다. The primer layer 30 may include a primer base layer 31.
앞서 설명한 바와 같이, 도 3을 참조하면 기능성 필름(1)이 연성회로기판(3) 상에 부착되는 경우, 기능성 필름(1)은 기판 상의 부품으로 인한 굴곡 부위에 인장력을 받게 되므로, 이러한 인장력에 의해 파손되지 않도록 프라이머 베이스 층(31)은 유연한 물질로 이루어짐이 바람직하다. 이를 통해, 기능성 필름(1)의 굴곡성이 개선될 수 있다.As described above, referring to FIG. 3, when the functional film 1 is attached onto the flexible circuit board 3, the functional film 1 is subjected to a tensile force due to a bending part due to a component on the substrate, and thus, the tensile force may be reduced. The primer base layer 31 is preferably made of a flexible material so as not to be broken by the material. Through this, the flexibility of the functional film 1 can be improved.
예를 들어, 프라이머 베이스 층(31)은 폴리에스터(polyester) 수지, 에폭시(epoxy) 수지, 폴리 우레탄(poly urethane) 수지 등을 포함할 수 있다. For example, the primer base layer 31 may include a polyester resin, an epoxy resin, a polyurethane resin, or the like.
또한, 프라이머 베이스 층(31)은 폴리에스터(polyester) 수지 또는 에폭시(epoxy) 수지가 변성된 것일 수 있다. 프라이머 베이스 층(31)이 이와 같은 변성 수지를 포함하는 경우, 유연성이 보다 우수하게 되므로, 기능성 필름(1)의 굴곡성을 보다 향상시킬 수 있다.In addition, the primer base layer 31 may be a modified polyester (epester) resin or epoxy (epoxy) resin. When the primer base layer 31 contains such a modified resin, flexibility becomes more excellent, and thus the flexibility of the functional film 1 can be further improved.
또한, 프라이머층(30)은 프라이머 베이스 층(31) 상에 형성되고, 미세 구조체가 포함된 프라이머 전도층(33)을 포함할 수 있다.In addition, the primer layer 30 may be formed on the primer base layer 31, and may include a primer conductive layer 33 including a microstructure.
앞서 설명한 바와 같이, 프라이머 전도층(33)은 전도층(50)의 크랙을 통해 빠져나오는 전자파를 차단함으로써, 보다 우수한 전자파 차폐 기능을 갖는 기능성 필름(1)이 구현되도록 할 수 있다.As described above, the primer conductive layer 33 may block the electromagnetic wave escaping through the crack of the conductive layer 50, so that the functional film 1 having a better electromagnetic shielding function may be realized.
이 때, 미세 구조체는 프라이머 전도층(33) 내에 최대한 골고루 분산 배치됨이 바람직하다. At this time, it is preferable that the microstructures are evenly dispersed in the primer conductive layer 33 as evenly as possible.
프라이머 전도층(33)에는 나노 와이어인 미세 구조체와 전도성 카본인 미세 구조체가 동시에 포함될 수도 있고, 나노 와이어인 미세 구조체 또는 전도성 카본인 미세 구조체 중 어느 하나만이 포함될 수도 있다. The primer conductive layer 33 may include the nanostructured microstructure and the conductive carbon microstructure at the same time, or may include only one of the nanostructured microstructure or the conductive carbon microstructure.
프라이머층(30)은 두께가 0.02 ㎛ 이상이고 10㎛ 이하일 수 있다. The primer layer 30 may have a thickness of 0.02 μm or more and 10 μm or less.
프라이머층(30)의 두께가 0.02 ㎛ 미만인 경우, 전도성을 갖는 부분이 너무 적어 프라이머층(30)은 전도층(50)의 크랙을 통해 빠져나오는 전자파를 충분히 차폐할 수 있을 정도의 전도성을 가질 수 없다. When the thickness of the primer layer 30 is less than 0.02 μm, the portion having conductivity is too small so that the primer layer 30 may have a conductivity enough to shield the electromagnetic waves from escaping through the crack of the conductive layer 50. none.
또한, 프라이머층(30)의 두께가 10 ㎛ 를 초과하는 경우, 프라이머층(30)의 강성이 높아져 유연성이 떨어지므로, 기능성 필름(1)의 부착 시 연성회로기판(3)에 압착되는 정도가 저하되어 기판 상의 부품 간에 전자파가 서로 영향을 끼치게 될 수 있다. 따라서, 오작동, 화면 번짐 등과 같은 문제점을 효과적으로 방지할 수 없다.In addition, when the thickness of the primer layer 30 exceeds 10 μm, since the rigidity of the primer layer 30 is increased and flexibility is reduced, the degree of being pressed onto the flexible circuit board 3 when the functional film 1 is attached is increased. It can be degraded and electromagnetic waves can affect each other between components on the substrate. Therefore, problems such as malfunction, screen blur, and the like cannot be effectively prevented.
또한, 프라이머층(30)은 신율이 30 % 이상이고 200 % 이하일 수 있다.In addition, the primer layer 30 may have an elongation of 30% or more and 200% or less.
프라이머층(30)의 신율이 30 % 미만인 경우, 유연성이 떨어져 기능성 필름(1)을 부착하는 과정에서 크랙이 발생될 수 있고, 연성회로기판(3)과의 밀착성이 떨어질 수 있다. When the elongation of the primer layer 30 is less than 30%, cracks may occur in the process of attaching the functional film 1 due to poor flexibility, and the adhesion with the flexible circuit board 3 may be inferior.
또한, 기능성 필름(1)의 열 압착 시, 프라이머층(30)은 절연층(10)에 의해 높은 온도로부터 보호될 수는 있으나 완전한 열 차폐는 불가능하므로, 프라이머층(30) 자체도 어느 정도 내열성을 가질 필요가 있다. 또한, 신율이 200 %를 초과하는 프라이머층(30)을 형성하려면, 프라이머층(30)에는 에폭시 수지의 양에 비해 훨씬 많은 러버(rubber)의 양이 포함되어야 하는데, 이러한 프라이머층(30)은 내열성이 떨어진다. 따라서, 약 170 ℃ 내지 약 180℃의 고온에서 이루어지는 프레스 압착 공정과 약 250 ℃ 내지 약 270 ℃의 고온에서 이루어지는 SMT공정 중 무연 솔더링 공정을 견딜 수 없다. 또한, 프라이머층(30)이 너무 소프트하게 형성되므로 고온에서 프라이머층(30)이 녹아 옆으로 새어 나갈 수 있다.In addition, when thermally compressing the functional film 1, the primer layer 30 may be protected from the high temperature by the insulating layer 10, but complete heat shielding is impossible, and thus the primer layer 30 itself may be somewhat heat resistant. Need to have In addition, in order to form the primer layer 30 having an elongation of more than 200%, the primer layer 30 should include a much larger amount of rubber compared to the amount of the epoxy resin, which is the primer layer 30 Heat resistance is inferior. Accordingly, it is not possible to withstand the lead-free soldering process in the press crimping process at a high temperature of about 170 ° C to about 180 ° C and the SMT process at a high temperature of about 250 ° C to about 270 ° C. In addition, since the primer layer 30 is formed too soft, the primer layer 30 may melt and leak to the side at a high temperature.
따라서, 프라이머층(30)은 신율이 30 % 이상 200 % 이하인 경우 크랙의 발생이 방지되고 연성회로기판(3)에 밀착될 수 있는 유연성과 고온의 공정을 견딜 수 있는 내열성을 가질 수 있다. 바람직하게는, 프라이머층(30)은 신율이 50 % 이상 150 % 이하를 갖도록 형성됨으로써 최적의 내열성과 유연성을 확보할 수 있다.Therefore, when the elongation is 30% or more and 200% or less, the primer layer 30 may have cracking resistance and heat resistance to withstand high-temperature processes and flexibility to be in close contact with the flexible circuit board 3. Preferably, the primer layer 30 is formed to have an elongation of 50% or more and 150% or less, thereby ensuring optimal heat resistance and flexibility.
프라이머층(30)의 색상은 명도가 낮은 색상일 수 있다. 예를 들어, 프라이머층(30)은 검은색일 수 있다.The color of the primer layer 30 may be a color having low brightness. For example, the primer layer 30 may be black.
본 기능성 필름(1)은 전도층(50)을 포함한다.The present functional film 1 includes a conductive layer 50.
앞서 설명한 바와 같이, 전도층(50)은 부품에서 발생한 전자파가 표면전류로 변환되어 전도층(50)의 표면에서 흐를 수 있도록, 전기저항이 낮은 물질로 이루어짐이 바람직하다.As described above, the conductive layer 50 is preferably made of a material having a low electrical resistance so that the electromagnetic wave generated in the component can be converted into the surface current to flow on the surface of the conductive layer 50.
전도층(50)은 프라이머층(30) 상에 형성된다.The conductive layer 50 is formed on the primer layer 30.
전도층(50)은 높은 전기전도성을 가지나 유연성이 떨어질 수 있다. 따라서, 기능성 필름(1)이 연성회로기판(3)에 가압/가열되어 부착되는 과정에서 전도층(50)에는 크랙이 발생될 수 있고, 이러한 크랙을 통해 전자파가 빠져나오게 되어 다른 부품에 영향을 줄 수 있다.The conductive layer 50 has high electrical conductivity but may be inferior in flexibility. Therefore, in the process of attaching the functional film 1 to the flexible circuit board 3 by being pressed / heated, cracks may be generated in the conductive layer 50, and electromagnetic waves may escape through the cracks, thereby affecting other components. Can give
이에, 전도층(50)의 하부에 프라이머층(30)을 형성시킴으로써, 전도층(50)에 형성된 크랙 사이로 빠져나오는 전자파를 차단하여, 부품 간에 전자파가 서로 영향을 끼치는 문제점의 발생을 효과적으로 방지할 수 있다.Thus, by forming the primer layer 30 on the lower portion of the conductive layer 50, by blocking the electromagnetic waves exiting between the cracks formed in the conductive layer 50, it is possible to effectively prevent the occurrence of the problem that the electromagnetic waves between the components affect each other. Can be.
또한, 높은 유연성을 갖는 프라이머층(30)에 의해 전도청(50)의 깨짐 현상이 다소 방지될 수 있다.In addition, a cracking phenomenon of the conductive wire 50 may be prevented by the primer layer 30 having high flexibility.
예를 들어, 전도층(50)은 은(Ag)을 포함할 수 있다. 일반적으로, 전도층(50)은 프라이머층(30) 상에 증착됨으로써 형성되는데, 이 때, 은(Ag)으로 증착하는 경우 가장 저렴한 공정 과정을 통해 전도층(50)의 형성이 가능하다.For example, the conductive layer 50 may include silver (Ag). In general, the conductive layer 50 is formed by depositing on the primer layer 30. In this case, the conductive layer 50 may be formed through the cheapest process when deposited with silver (Ag).
또한, 전도층(50)은 구리(Cu), 니켈(Ni), 알루미늄(Al)을 포함할 수 있으며, 이 외에도 전도성이 높은 물질을 포함할 수 있다.In addition, the conductive layer 50 may include copper (Cu), nickel (Ni), and aluminum (Al). In addition, the conductive layer 50 may include a highly conductive material.
예를 들어, 전도층(50)은 800 Å의 두께로 은 증착됨으로써 형성될 수 있다.For example, the conductive layer 50 may be formed by silver deposition to a thickness of 800 kPa.
본 기능성 필름(1)은 접착제층(70)을 포함한다.The present functional film 1 includes an adhesive layer 70.
접착제층(70)은 전도층(50) 상에 형성된다.The adhesive layer 70 is formed on the conductive layer 50.
도 2를 참조하면, 접착제층(70)은 연성회로기판(3) 상에 부착되는 부분으로서, 접착 능력이 우수한 물질로 이루어짐이 바람직하다. 예를 들어, 접착제층(70)은 에폭시(epoxy) 수지 또는 폴리에스터(polyester) 수지를 포함할 수 있다. 이러한 물질로 이루어진 접착제층(70)은 폴리에테스(polyether) 수지로 이루어진 것에 비해 접착 능력이 우수할 수 있다.Referring to FIG. 2, the adhesive layer 70 is attached to the flexible circuit board 3 and is preferably made of a material having excellent adhesive ability. For example, the adhesive layer 70 may include an epoxy resin or a polyester resin. The adhesive layer 70 made of such a material may have excellent adhesive ability as compared with that made of polyether resin.
접착제층(70)은 전도성 입자(71)를 포함할 수 있다.The adhesive layer 70 may include conductive particles 71.
이를 통해 접착제층(70)은 이방 전도성을 가질 수 있다. 따라서, 연성회로기판(3) 상에 기능성 필름(1)이 부착되는 경우, 회로와 전도층(50)은 서로 전기적으로 접속될 수 있고, 인접 부품간에 전기적으로 절연될 수 있다.Through this, the adhesive layer 70 may have anisotropic conductivity. Therefore, when the functional film 1 is attached on the flexible circuit board 3, the circuit and the conductive layer 50 can be electrically connected to each other, and can be electrically insulated between adjacent components.
이 때, 전도성 입자(71)는 구형의 입자뿐만 아니라, 와이어, 판상 등의 형태로 형성되는 입자를 모두 의미하는 것일 수 있다.In this case, the conductive particles 71 may mean not only spherical particles but also particles formed in a wire, plate, or the like form.
전도성 입자(71)는 은(Ag), 동(Cu), 니켈(Ni), 및 은(Ag)이 코팅된 구리(Cu) 중 어느 하나 이상을 포함할 수 있다.The conductive particles 71 may include at least one of silver (Ag), copper (Cu), nickel (Ni), and silver (Ag) coated copper (Cu).
전도성 입자(71)는 회로와 전도층(50)이 서로 전기적으로 접속될 수 있도록 우수한 전도성을 가짐이 바람직하다. 특히, 전도성 입자(71)가 높은 전도성을 가지는 구리에 반응성이 낮은 은이 코팅된 은 코팅 구리를 포함하는 경우, 높은 전도성과 화학적 안정성이 동시에 확보될 수 있다.The conductive particles 71 preferably have excellent conductivity so that the circuit and the conductive layer 50 can be electrically connected to each other. In particular, when the conductive particles 71 include silver coated copper coated with silver having low reactivity to copper having high conductivity, high conductivity and chemical stability may be secured at the same time.
본 기능성 필름(1)은 보호필름(90)을 포함할 수 있다.The functional film 1 may include a protective film 90.
보호필름(90)은 절연층(10)의 하측에 형성될 수 있다.The protective film 90 may be formed under the insulating layer 10.
보호필름(90)은 본 기능성 필름(1)이 연성회로기판(3) 상에 부착되기 전의 손상을 보호하는 역할을 할 수 있다.The protective film 90 may serve to protect the damage before the functional film 1 is attached onto the flexible circuit board 3.
또한, 보호필름(90)은 상측에 이형층을 포함할 수 있다.In addition, the protective film 90 may include a release layer on the upper side.
이를 통해, 본 기능성 필름(1)이 연성회로기판(3) 상에 부착된 후, 보호필름(90)은 제거될 수 있다.Through this, after the functional film 1 is attached on the flexible circuit board 3, the protective film 90 can be removed.
도 10은 본 기능성 필름(1)인 실시예와, 비교예 1, 2의 기능성 필름의 인장시험에 따른 표면저항값을 비교한 것이다. FIG. 10 compares the surface resistance values according to the tensile test of the examples of the functional film 1 and the functional films of Comparative Examples 1 and 2. FIG.
실시예의 경우, 폴리이미드가 포함된 12 ㎛ 두께의 절연층(10) 상에 전도성의 프라이머층(30)을 3㎛ 두께로 코팅하여 형성한 후, 그 상부에 은을 증착하여 800 Å 두께로 전도층(50)을 형성한 것이다. 여기서, 프라이머층(30)은 수지로 페놀변성 에폭시 수지 30 중량% 및 폴리에스터 수지 10 중량%, 경화제로 무수프탈산(phthalic anhydride) 2 중량%, 용제로 메틸에틸케톤(methylethylketone) 53 중량%가 포함되고, 전도성의 미세 구조체로서 평균 입경이 100 nm이고 평균 길이가 50 ㎛인 은 나노 와이어 2 중량%, 전도성 카본 3 중량%가 포함되어 형성된다.In the exemplary embodiment, the conductive primer layer 30 is formed by coating the conductive primer layer 30 to a thickness of 3 μm on a 12 μm thick insulating layer 10 including polyimide, and then, silver is deposited on the conductive layer to conduct a thickness of 800 μm. The layer 50 is formed. Here, the primer layer 30 includes 30% by weight of a phenol-modified epoxy resin and 10% by weight of polyester resin, 2% by weight of phthalic anhydride as a curing agent, and 53% by weight of methylethylketone as a solvent. As the conductive microstructure, 2 wt% of silver nanowires having an average particle diameter of 100 nm and an average length of 50 μm and 3 wt% of conductive carbon are formed.
이 때, 페놀변성 에폭시 수지는 국도화학의 YDPN 644를 사용하였고, 폴리에스터 수지는 Toyobo 사의 Vylon 550을 사용하였으며, 무수프탈산은 국도화학의 산무수물 경화제 MNA를 사용하였다. 또한, 은 나노 와이어는 KEC Tech 사의 a100 grade를 사용하였고, 전도성 카본은 평화약품의 케첸블랙 300 grade를 사용하였으며, 폴리이미드가 포함된 절연층(10)은 SKkolon 사의 LN grade를 사용하였다. At this time, YDPN 644 of Kukdo Chemical was used for phenol-modified epoxy resin, Vylon 550 of Toyobo Co., Ltd. was used, and acid anhydride curing agent MNA of Kukdo Chemical was used for polyester resin. In addition, silver nanowires were used a100 grade of KEC Tech, conductive carbon was used Ketjenblack 300 grade of Pyung Hwa Chemical, and the insulating layer 10 containing polyimide was used LN grade of SKkolon.
한편, 비교예 1의 경우, 프라이머층에 전술한 실시예에서는 포함된 전도성의 미세 구조체가 포함되지 않고, 비교예 2의 경우, 전술한 실시예의 프라이머층 자체가 포함되지 않으며, 나머지는 모두 실시예와 동일한 조건으로 형성된다. On the other hand, in Comparative Example 1, the primer layer does not include the conductive microstructures included in the above-described embodiment, and in Comparative Example 2, the primer layer itself of the above-described embodiment is not included, and the rest are all examples. Are formed under the same conditions as.
전술한 바와 같이 형성된 실시예, 비교예 1 및 2 각각을 50 mm X 80 mm 시편으로 제작하고, 인스트롱사 만능강도기로 각각 30 %와 50 %로 인장하여 미츠비시표면 저항측정기로 각각의 표면 저항을 측정하였다(JISK 7194 시험법).Each of Examples, Comparative Examples 1 and 2 formed as described above was fabricated in 50 mm X 80 mm specimens, and each surface resistance was measured using a Mitsubishi surface resistance meter by tensioning 30% and 50%, respectively, with an Instron universal strength. It was measured (JISK 7194 test method).
위와 같은 성분 및 형태로 제작된 실시예, 비교예 1 및 2를 인장 실험한 결과를 비교해보면 다음과 같다.When comparing the results of the tensile test of the Examples, Comparative Examples 1 and 2 produced by the above components and forms are as follows.
먼저, 전도성을 갖는 프라이머층(30)이 포함된 본 기능성 필름(1)과 전도성을 갖지 않은 프라이머층이 포함된 비교예 1을 비교하면, 30% 및 50% 인장 시, 본 기능성 필름(1)의 표면저항값은 여전히 낮으며 변화가 거의 없었으나, 비교예 1은 표면저항값이 월등하게 증가됨을 알 수 있다. 따라서, 전도성의 프라이머층(30)을 갖는 본 기능성 필름(1)이 전자파 차폐 효과가 우수함을 알 수 있다.First, comparing the present functional film (1) containing the conductive primer layer 30 and Comparative Example 1 including the non-conductive primer layer, the present functional film (1) at 30% and 50% tension Although the surface resistance of is still low and little change, it can be seen that in Comparative Example 1 the surface resistance is significantly increased. Therefore, it can be seen that the present functional film 1 having the conductive primer layer 30 is excellent in electromagnetic wave shielding effect.
또한, 프라이머층(30)이 포함된 본 기능성 필름(1)과 프라이머층이 포함되지 않은 비교예 2를 비교하면, 인장 시 본 기능성 필름(1)은 프라이머층(30)에 의해 유연성이 확보되므로 파손되지 않았으나, 비교예 2는 유연성이 없어 50% 인장 시에는 단선됨을 알 수 있다. 따라서, 프라이머층(30)을 갖는 본 기능성 필름(1)은 유연성이 뛰어나 여러 부품이 구비된 연성회로기판(3)에 파손없이 부착될 수 있음을 알 수 있다.In addition, when comparing the present functional film 1 with the primer layer 30 and Comparative Example 2 without the primer layer, the functional film 1 is secured by the primer layer 30 at the time of stretching Although not broken, Comparative Example 2 has no flexibility and can be seen to be disconnected at 50% tensile strength. Therefore, it can be seen that the present functional film 1 having the primer layer 30 is excellent in flexibility and can be attached to the flexible printed circuit board 3 provided with various components without damage.
한편, 본원의 일 실시예에 따른 연성회로기판(3)(이하 '본 연성회로기판'이라 함)에 대해 설명한다. 다만, 앞서 살핀 본원의 일 실시예에 따른 기능성 필름(1)에서 설명한 구성과 동일 또는 유사한 구성에 대해서는 동일한 도면부호를 사용하고, 중복되는 설명은 간략히 하거나 생략하기로 한다.On the other hand, the flexible circuit board 3 (hereinafter referred to as "the flexible circuit board") according to an embodiment of the present application will be described. However, the same reference numerals are used for the same or similar components as those described in the functional film 1 according to an embodiment of the present invention, and the overlapping description will be briefly or omitted.
본 연성회로기판(3)은 본 기능성 필름(1)을 포함한다.The flexible printed circuit board 3 includes the present functional film 1.
이를 통해, 연성회로기판(3)은 부품에서 발생되는 전자파가 효과적으로 차폐됨으로써, 오작동, 노이즈 발생 및 화면 번짐 현상 등이 발생되지 않을 수 있다. As a result, the flexible circuit board 3 may effectively shield electromagnetic waves generated from components, such that malfunction, noise, and screen bleeding may not occur.
또한, 연성회로기판(3)은 우수한 유연성 및 내접동성(sliding resistance)을 가질 수 있다.In addition, the flexible circuit board 3 may have excellent flexibility and sliding resistance.
이 때, 본 연성회로기판(3)의 상측에는 접착제층(70)이 맞닿도록 구비된다.At this time, the adhesive layer 70 abuts on the upper side of the flexible printed circuit board 3.
도 2에 도시된 바와 같이, 본 기능성 필름(1)은 접착제층(70)이 연성회로기판(3)과 맞닿도록 접착될 수 있다. 이 때, 접착제층(70)이 전도성 입자(71)를 가지는 경우, 회로와 전도층(50)이 통전됨으로써 전자파가 차폐될 수 있다. As shown in FIG. 2, the functional film 1 may be bonded such that the adhesive layer 70 abuts on the flexible circuit board 3. In this case, when the adhesive layer 70 includes the conductive particles 71, electromagnetic waves may be shielded by energizing the circuit and the conductive layer 50.
한편, 본원의 일 실시예에 따른 기능성 필름의 제조방법(이하 '본 기능성 필름의 제조방법'이라 함)에 대해 설명한다. 다만, 앞서 살핀 본원의 일 실시예에 따른 기능성 필름(1)에서 설명한 구성과 동일 또는 유사한 구성에 대해서는 동일한 도면부호를 사용하고, 중복되는 설명은 간략히 하거나 생략하기로 한다.On the other hand, a method of manufacturing a functional film according to an embodiment of the present application (hereinafter referred to as "manufacturing method of the functional film") will be described. However, the same reference numerals are used for the same or similar components as those described in the functional film 1 according to an embodiment of the present invention, and the overlapping description will be briefly or omitted.
본 기능성 필름의 제조방법은 절연층(10) 상에 프라이머층(30)을 형성하는 단계(S100)을 포함한다.The manufacturing method of the present functional film includes forming a primer layer 30 on the insulating layer 10 (S100).
이 때, 절연층(10)은 폴리이미드를 포함하고, 12 ㎛의 두께를 갖도록 형성될 수 있다.In this case, the insulating layer 10 may include polyimide, and may be formed to have a thickness of 12 μm.
앞서 설명한 바와 같이, 프라이머층(30)은 전도성을 가짐으로써, 전도층(50)의 크랙 사이로 빠져나오는 전자파를 차단하는 브릿지 역할을 하여 전자파가 효과적으로 차단될 수 있도록 한다.As described above, the primer layer 30 has a conductivity, serves as a bridge to block the electromagnetic waves exiting between the cracks of the conductive layer 50 so that the electromagnetic waves can be effectively blocked.
도 6을 참조하면, 프라이머층(30)을 형성하는 단계(S100)는, 절연층(10) 상에 프라이머 베이스 층(31)을 형성하는 단계(S110)를 포함할 수 있다.Referring to FIG. 6, the forming of the primer layer 30 (S100) may include forming the primer base layer 31 on the insulating layer 10 (S110).
도 3을 참조하면, 기판 상의 부품으로 인한 굴곡 부위에 기능성 필름(1)은 인장력을 받게 되는데, 이 때 프라이머 베이스 층(31)은 이러한 인장력에 의해 파손되지 않도록 유연한 물질로 이루어짐이 바람직하다.Referring to FIG. 3, the functional film 1 is subjected to a tensile force at a bent portion due to a component on the substrate, wherein the primer base layer 31 is preferably made of a flexible material so as not to be damaged by the tensile force.
예를 들어, 프라이머 베이스 층(31)은 폴리에스터(polyester) 수지, 에폭시(epoxy) 수지, 폴리 우레탄(poly urethane) 수지 등을 포함할 수 있으며, 폴리에스터 수지 또는 에폭시 수지가 변성된 물질을 포함함이 바람직하다. For example, the primer base layer 31 may include a polyester resin, an epoxy resin, a polyurethane resin, or the like, and may include a material in which a polyester resin or an epoxy resin is modified. It is preferable to.
또한, 도 7을 참조하면, 프라이머층(30)을 형성하는 단계(S100)는, 프라이머 베이스 층(31) 상에 전도성의 미세 구조체가 분산된 용매를 코팅하는 단계(S120)를 포함할 수 있다.In addition, referring to FIG. 7, the forming of the primer layer 30 (S100) may include coating the solvent in which the conductive microstructure is dispersed on the primer base layer 31 (S120). .
앞서 설명한 바와 같이, 프라이머 전도층(33)에 의해 프라이머층(30)이 전도성을 가짐으로써, 전도층(50)의 크랙을 통해 빠져나오는 전자파를 차단 할 수 있다.As described above, the primer layer 30 has conductivity by the primer conductive layer 33, thereby preventing electromagnetic waves from escaping through the crack of the conductive layer 50.
미세 구조체가 분산된 용매를 코팅하여 프라이머 전도층(33)을 형성함으로써, 미세 구조체가 프라이머 베이스 층(31) 상에 골고루 분산 배치되어 전자파 차폐 효과가 향상될 수 있다.By coating the solvent in which the microstructures are dispersed to form the primer conductive layer 33, the microstructures may be evenly distributed on the primer base layer 31 to improve the electromagnetic shielding effect.
프라이머층(30)을 형성하는 단계(S100)에서, 프라이머층(30)은 두께가 0.02 ㎛ 이상이고 10㎛ 이하로 형성될 수 있다.In step S100 of forming the primer layer 30, the primer layer 30 may have a thickness of 0.02 μm or more and 10 μm or less.
앞서 설명한 바와 같이, 프라이머층(30)의 두께가 0.02 ㎛ 미만인 경우, 프라이머층(30)의 전도성이 떨어지므로, 전도층(50)의 크랙을 통해 빠져나오는 전자파를 차폐하는 브릿지 역할을 효과적으로 할 수 없다.As described above, when the thickness of the primer layer 30 is less than 0.02 μm, since the conductivity of the primer layer 30 is lowered, it may effectively serve as a bridge that shields electromagnetic waves emitted through the crack of the conductive layer 50. none.
또한, 프라이머층(30)의 두께가 10 ㎛ 를 초과하는 경우, 프라이머층(30)의 강성이 높아져 유연성이 떨어지므로, 기능성 필름(1)의 부착 시 연성회로기판(3)에 압착되는 정도가 저하되어 기판 상의 부품 간에 전자파가 서로 영향을 끼치게 될 수 있다. 따라서, 오작동, 화면 번짐 등과 같은 문제점을 효과적으로 방지할 수 없다.In addition, when the thickness of the primer layer 30 exceeds 10 μm, since the rigidity of the primer layer 30 is increased and flexibility is reduced, the degree of being pressed onto the flexible circuit board 3 when the functional film 1 is attached is increased. It can be degraded and electromagnetic waves can affect each other between components on the substrate. Therefore, problems such as malfunction, screen blur, and the like cannot be effectively prevented.
또한, 프라이머층(30)을 형성하는 단계(S100)에서, 프라이머층(30)은 신율이 30 % 이상이고 200 % 이하로 형성될 수 있다.In addition, in the step (S100) of forming the primer layer 30, the primer layer 30 may have an elongation of 30% or more and 200% or less.
앞서 설명한 바와 같이, 프라이머층(30)의 신율이 30 % 미만인 경우, 유연성이 떨어져 기능성 필름(1)의 부착 시 크랙이 발생될 수 있고, 연성회로기판(3)과의 밀착성이 떨어질 수 있다. As described above, when the elongation of the primer layer 30 is less than 30%, flexibility may be degraded, and cracks may occur when the functional film 1 is attached, and adhesion to the flexible circuit board 3 may be inferior.
또한, 신율이 200 %를 초과하는 프라이머층(30)을 형성하려면, 프라이머층(30)에는 에폭시 수지의 양에 비해 훨씬 많은 러버(rubber)의 양이 포함되어야 한다. 이러한 프라이머층(30)은 내열성이 떨어지므로, 약 170 ℃ 내지 약 180℃의 고온에서 이루어지는 프레스 압착 공정과 약 250 ℃ 내지 약 270 ℃의 고온에서 이루어지는 SMT공정의 무연 솔더링 공정을 견딜 수 없다. 또한, 프라이머층(30)이 너무 소프트하게 형성되므로 고온에서 프라이머층(30)이 녹아 옆으로 새어 나갈 수 있다.In addition, in order to form the primer layer 30 having an elongation of more than 200%, the primer layer 30 should include a much larger amount of rubber compared to the amount of the epoxy resin. Since the primer layer 30 is inferior in heat resistance, the primer layer 30 cannot withstand the press crimping process at a high temperature of about 170 ° C to about 180 ° C and the lead-free soldering process of the SMT process at a high temperature of about 250 ° C to about 270 ° C. In addition, since the primer layer 30 is formed too soft, the primer layer 30 may melt and leak to the side at a high temperature.
따라서, 프라이머층(30)은 신율이 30 % 이상 200 % 이하인 경우 크랙의 발생이 방지되고 연성회로기판(3)에 밀착될 수 있는 유연성과 고온의 공정을 견딜 수 있는 내열성을 가질 수 있다. 바람직하게는, 프라이머층(30)은 신율이 50 % 이상 150 % 이하를 갖도록 형성됨으로써 최적의 내열성과 유연성을 확보할 수 있다.Therefore, when the elongation is 30% or more and 200% or less, the primer layer 30 may have cracking resistance and heat resistance to withstand high-temperature processes and flexibility to be in close contact with the flexible circuit board 3. Preferably, the primer layer 30 is formed to have an elongation of 50% or more and 150% or less, thereby ensuring optimal heat resistance and flexibility.
본 기능성 필름의 제조방법은 프라이머층(30) 상에 전도층(50)을 형성하는 단계(S200)를 포함한다(도 8 참조).The manufacturing method of the present functional film includes a step S200 of forming the conductive layer 50 on the primer layer 30 (see FIG. 8).
앞서 설명한 바와 같이, 전도층(50)은 부품에서 발생한 전자파가 표면전류로 변환되어 전도층(50)의 표면에서 흐를 수 있도록, 전기저항이 낮은 물질로 이루어짐이 바람직하다.As described above, the conductive layer 50 is preferably made of a material having a low electrical resistance so that the electromagnetic wave generated in the component can be converted into the surface current to flow on the surface of the conductive layer 50.
예를 들어, 전도층(50)은 은(Ag), 구리(Cu), 니켈(Ni), 알루미늄(Al)을 포함할 수 있으며, 이 외에도 전도성이 높은 물질을 포함할 수 있다.For example, the conductive layer 50 may include silver (Ag), copper (Cu), nickel (Ni), and aluminum (Al). In addition, the conductive layer 50 may include a highly conductive material.
전도층(50)을 형성하는 단계(S200)에서, 전도층(50)은 프라이머층(30) 상에 스퍼터링 증착되는 것일 수 있다.In the forming of the conductive layer 50 (S200), the conductive layer 50 may be sputter deposited on the primer layer 30.
이 때, 전도층(50)이 은(Ag)을 스터퍼링 증착함으로써 형성되는 경우, 가장 저렴한 공정 과정을 통해 형성될 수 있다.In this case, when the conductive layer 50 is formed by sputtering deposition of silver (Ag), it may be formed through the cheapest process.
예를 들어, 전도층(50)은 은 증착을 통해 800 Å의 두께를 갖도록 형성될 수 있다.For example, the conductive layer 50 may be formed to have a thickness of 800 kPa through silver deposition.
본 기능성 필름의 제조방법은 전도층(50) 상에 접착제층(70)을 형성하는 단계(S300)를 포함한다(도 9 참조).The manufacturing method of the present functional film includes a step S300 of forming an adhesive layer 70 on the conductive layer 50 (see FIG. 9).
앞서 설명한 바와 같이, 접착제층(70)은 연성회로기판(3) 상에 부착되는 부분으로서, 접착 능력이 우수한 물질, 예를 들어, 접착제층(70)은 에폭시(epoxy) 수지 또는 폴리에스터(polyester) 수지를 포함할 수 있다.As described above, the adhesive layer 70 is a part attached to the flexible circuit board 3, and a material having excellent adhesion, for example, the adhesive layer 70 may be an epoxy resin or polyester. ) May include a resin.
또한, 접착제층(70)은 전도성 입자(71)를 포함함으로써 이방 전도성을 가져 회로와 전도층(50)이 서로 통전되도록 할 수 있다. 이 때, 전도성 입자(71)는, 예를 들어, 은(Ag), 동(Cu), 니켈(Ni), 및 은(Ag)이 코팅된 구리(Cu) 중 어느 하나 이상을 포함할 수 있다.In addition, the adhesive layer 70 may include the conductive particles 71 to have anisotropic conductivity so that the circuit and the conductive layer 50 may be energized with each other. In this case, the conductive particles 71 may include, for example, any one or more of silver (Ag), copper (Cu), nickel (Ni), and silver (Ag) coated copper (Cu). .
본 기능성 필름(1)은 프라이머층(30)을 포함함으로써, 기능성 필름(1)의 가열/가압을 통한 연성회로기판(3)에 부착 시 발생되는 전도층(50)의 크랙 사이로 빠져나오는 전자파를 효과적으로 블러킹할 수 있다. 따라서, 오작동, 노이즈 발생, 화면 번짐 등의 전자파 장애 문제를 해결할 수 있다. Since the functional film 1 includes the primer layer 30, electromagnetic waves emitted between the cracks of the conductive layer 50 generated when the functional film 1 is attached to the flexible circuit board 3 through heating / pressurization of the functional film 1 may be formed. It can effectively block. Therefore, it is possible to solve the electromagnetic interference problems such as malfunction, noise, screen blur.
전술한 본원의 설명은 예시를 위한 것이며, 본원이 속하는 기술분야의 통상의 지식을 가진 자는 본원의 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 쉽게 변형이 가능하다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다. 예를 들어, 단일형으로 설명되어 있는 각 구성 요소는 분산되어 실시될 수도 있으며, 마찬가지로 분산된 것으로 설명되어 있는 구성 요소들도 결합된 형태로 실시될 수 있다.The above description of the present application is intended for illustration, and it will be understood by those skilled in the art that the present invention may be easily modified in other specific forms without changing the technical spirit or essential features of the present application. Therefore, it should be understood that the embodiments described above are exemplary in all respects and not restrictive. For example, each component described as a single type may be implemented in a distributed manner, and similarly, components described as distributed may be implemented in a combined form.
본원의 범위는 상기 상세한 설명보다는 후술하는 특허청구범위에 의하여 나타내어지며, 특허청구범위의 의미 및 범위 그리고 그 균등 개념으로부터 도출되는 모든 변경 또는 변형된 형태가 본원의 범위에 포함되는 것으로 해석되어야 한다. The scope of the present application is indicated by the following claims rather than the above description, and it should be construed that all changes or modifications derived from the meaning and scope of the claims and their equivalents are included in the scope of the present application.

Claims (24)

  1. 기능성 필름에 있어서,In the functional film,
    절연층;Insulating layer;
    상기 절연층 상에 형성되는 프라이머층;A primer layer formed on the insulating layer;
    상기 프라이머층 상에 형성되는 전도층; 및A conductive layer formed on the primer layer; And
    상기 전도층 상에 형성되는 접착제층을 포함하되,Including an adhesive layer formed on the conductive layer,
    상기 프라이머층은 전도성을 갖는 것인 기능성 필름.The primer layer is a functional film having conductivity.
  2. 제 1 항에 있어서,The method of claim 1,
    상기 프라이머층은 전도성을 갖는 미세 구조체를 포함하는 것인 기능성 필름.The primer layer is a functional film comprising a fine structure having conductivity.
  3. 제 2 항에 있어서,The method of claim 2,
    상기 미세 구조체는 은(Ag), 구리(Cu) 및 니켈(Ni) 중 어느 하나 이상을 포함하는 것인 기능성 필름.The fine structure is a functional film containing any one or more of silver (Ag), copper (Cu) and nickel (Ni).
  4. 제 3 항에 있어서,The method of claim 3, wherein
    상기 미세 구조체는 판상(flake) 또는 와이어(wire)의 형태를 가지는 것인 기능성 필름.The fine structure is a functional film having a flake or wire (wire) form.
  5. 제 2 항에 있어서,The method of claim 2,
    상기 미세 구조체는 전도성 카본(carbon)인 것인 기능성 필름.The fine structure is a functional film that is conductive carbon (carbon).
  6. 제 5 항에 있어서,The method of claim 5,
    상기 미세 구조체는 탄소나노튜브(carbon nanotube, CNT)인 것인 기능성 필름.The microstructure is a carbon nanotube (carbon nanotube, CNT) is a functional film.
  7. 제 2 항에 있어서,The method of claim 2,
    상기 프라이머층은,The primer layer,
    프라이머 베이스 층; 및Primer base layer; And
    상기 프라이머 베이스 층 상에 형성되고, 상기 미세 구조체가 포함된 프라이머 전도층을 포함하는 것인 기능성 필름.A functional film formed on the primer base layer, comprising a primer conductive layer containing the microstructure.
  8. 제 7 항에 있어서,The method of claim 7, wherein
    상기 미세 구조체는 상기 프라이머 전도층 내에 분산 배치되는 것인 기능성 필름.And the microstructures are dispersed and disposed within the primer conductive layer.
  9. 제 7 항에 있어서,The method of claim 7, wherein
    상기 프라이머 베이스 층은 폴리에스터(polyester) 수지 또는 에폭시(epoxy) 수지가 변성된 것인 기능성 필름.The primer base layer is a functional film is a polyester (epester) resin or epoxy (epoxy) resin is modified.
  10. 제 1 항에 있어서,The method of claim 1,
    상기 프라이머층은 두께가 0.02㎛ 이상이고 10 ㎛ 이하인 것인 기능성 필름.The primer layer has a thickness of 0.02 ㎛ or more and less than 10 ㎛ functional film.
  11. 제 1 항에 있어서,The method of claim 1,
    상기 프라이머층은 신율이 30 % 이상이고 200 % 이하인 것인 기능성 필름.The primer layer has an elongation of 30% or more and less than 200% functional film.
  12. 제 1 항에 있어서,The method of claim 1,
    상기 프라이머층의 색상은 명도가 낮은 색상인 것인 기능성 필름.The color of the primer layer is a functional film of low brightness.
  13. 제 1 항에 있어서,The method of claim 1,
    상기 전도층은 은(Ag)을 포함하는 것인 기능성 필름.The conductive layer is a functional film containing silver (Ag).
  14. 제 1 항에 있어서,The method of claim 1,
    상기 절연층은 폴리 이미드(poly imide, PI)를 포함하는 것인 기능성 필름.The insulating layer is a functional film containing polyimide (poly imide, PI).
  15. 제 1 항에 있어서,The method of claim 1,
    상기 접착제층은 전도성 입자를 포함하는 것인 기능성 필름.The adhesive layer is a functional film containing conductive particles.
  16. 제 15 항에 있어서,The method of claim 15,
    상기 전도성 입자는 은(Ag), 동(Cu), 니켈(Ni) 및 은(Ag)이 코팅된 구리(Cu) 중 어느 하나 이상을 포함하는 것인 기능성 필름.The conductive particles include any one or more of silver (Ag), copper (Cu), nickel (Ni), and silver (Ag) coated copper (Cu).
  17. 제 1 항에 있어서,The method of claim 1,
    상기 절연층의 하측에 형성되는 보호필름을 더 포함하는 것인 기능성 필름.Functional film further comprising a protective film formed on the lower side of the insulating layer.
  18. 제 17 항에 있어서,The method of claim 17,
    상기 보호필름은 상측에 이형층을 포함하는 것인 기능성 필름.The protective film is a functional film comprising a release layer on the upper side.
  19. 연성회로기판에 있어서,In the flexible circuit board,
    청구항 1에 따른 기능성 필름을 포함하되,Including a functional film according to claim 1,
    상측에는 상기 접착제층이 맞닿도록 구비되는 것인 연성회로기판.The upper side is a flexible circuit board is provided so that the adhesive layer abuts.
  20. 청구항 1에 따른 기능성 필름의 제조방법에 있어서,In the manufacturing method of the functional film according to claim 1,
    상기 절연층 상에 상기 프라이머층을 형성하는 단계;Forming the primer layer on the insulating layer;
    상기 프라이머층 상에 상기 전도층을 형성하는 단계;Forming the conductive layer on the primer layer;
    상기 전도층 상에 상기 접착제층을 형성하는 단계를 포함하는 기능성 필름의 제조방법.Forming the adhesive layer on the conductive layer.
  21. 제 20 항에 있어서,The method of claim 20,
    상기 프라이머층을 형성하는 단계는,Forming the primer layer,
    상기 절연층 상에 프라이머 베이스 층을 형성하는 단계; 및Forming a primer base layer on the insulating layer; And
    상기 프라이머 베이스 층 상에 전도성의 미세 구조체가 분산된 용매를 코팅하는 단계를 포함하는 것인 기능성 필름의 제조방법.Coating a solvent in which a conductive microstructure is dispersed on the primer base layer.
  22. 제 20 항에 있어서,The method of claim 20,
    상기 전도층을 형성하는 단계에서,In the forming of the conductive layer,
    상기 전도층은 상기 프라이머층의 상에 은(Ag) 스퍼터링 증착되는 것인 기능성 필름의 제조방법.The conductive layer is a method for producing a functional film is silver (Ag) sputter deposited on the primer layer.
  23. 제 20 항에 있어서,The method of claim 20,
    상기 프라이머층을 형성하는 단계에서,In the forming of the primer layer,
    상기 프라이머층은 두께가 0.02㎛ 이상이고 10 ㎛ 이하로 형성되는 것인 기능성 필름의 제조방법.The primer layer has a thickness of 0.02 ㎛ or more and is formed in 10 ㎛ or less.
  24. 제 20 항에 있어서,The method of claim 20,
    상기 프라이머층을 형성하는 단계에서,In the forming of the primer layer,
    상기 프라이머층은 신율이 30 % 이상이고 200 % 이하로 형성되는 것인 기능성 필름의 제조방법.The primer layer has an elongation of 30% or more and is formed in a functional film of less than 200%.
PCT/KR2013/010060 2012-12-10 2013-11-07 Functional film, and flexible printed circuit board including same WO2014092343A1 (en)

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