WO2014088782A1 - Huiles industrielles pour engrenages permettant de réduire les températures de fonctionnement d'un réducteur - Google Patents

Huiles industrielles pour engrenages permettant de réduire les températures de fonctionnement d'un réducteur Download PDF

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Publication number
WO2014088782A1
WO2014088782A1 PCT/US2013/070278 US2013070278W WO2014088782A1 WO 2014088782 A1 WO2014088782 A1 WO 2014088782A1 US 2013070278 W US2013070278 W US 2013070278W WO 2014088782 A1 WO2014088782 A1 WO 2014088782A1
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Prior art keywords
component
industrial gear
industrial
lubricant
weight
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Application number
PCT/US2013/070278
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English (en)
Inventor
James N. Vinci
Edward S. Akucewich
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The Lubrizol Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Lubrizol Corporation filed Critical The Lubrizol Corporation
Priority to CA2892812A priority Critical patent/CA2892812C/fr
Priority to CN201380062936.0A priority patent/CN104822809A/zh
Priority to US14/647,221 priority patent/US20150299603A1/en
Priority to JP2015545081A priority patent/JP6378691B2/ja
Priority to SG11201503993WA priority patent/SG11201503993WA/en
Priority to EP13803330.3A priority patent/EP2925839B1/fr
Publication of WO2014088782A1 publication Critical patent/WO2014088782A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C10M2203/1025—Aliphatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/102—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106—Thiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/043—Ammonium or amine salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/047—Thioderivatives not containing metallic elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049—Phosphite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Definitions

  • the invention relates to improved gear oil compositions that substantially reduce the operating temperature of a gearbox in which the gear oil compositions are used.
  • the reduced operating temperature provided by the described compositions leads to improved equipment performance.
  • the invention also relates to methods of making the described gear oil compositions and methods of using the same.
  • One means of protecting an industrial gearbox and extending the life of the fluid lubricating them is to reduce the temperature at which it operates. It is generally known that extended exposure to the high temperatures that industrial gearboxes commonly operate under increases the wear and tear on the parts of the gearboxes, eventually leading to part failure. This negative impact of high operating temperature is the result of multiple forces, including but not limited to the fact that the high temperatures can accelerate the break-down of the protective additives and increase the oxidation of the base fluid present in the industrial gearbox lubricant, thus leaving the parts of the gearbox less protected over time. Reducing the operating temperature of an industrial gearbox will result in improved performance over time.
  • the invention provides an industrial gear composition comprising: (a) an oil of lubricating viscosity; (b) an industrial gear lubricant additive package; and (c) a fatty phosphite present at no less than 1.0 percent by weight of the overall composition.
  • the present invention is not directed to automotive gear compositions and/or lubricants, but rather is focused on industrial gear oil compositions and/or lubricants dealing with the unique problems seen in industrial gearbox applications.
  • component (b), the industrial gear lubricant additive package may include one or more antiwear additives and/or extreme pressure agents, one or more rust and/or corrosion inhibitors, one or more foam inhibitors, one or more demulsifiers, or any combination thereof.
  • component (b), the industrial gear lubricant additive package may also further include one or more friction modifiers.
  • the invention further provides for component (b), the industrial gear lubricant additive package, to further include: one or more sulfurized olefins or polysulfides; one or more phosphorus amine salts; one or more thiophosphate esters, one or more thiadiazoles, tolyltriazoles, polyethers, and/or alkenyl amines; one or more ester copolymers; one or more carboxylic esters; one or more succinimide dispersants, detergents, or any combination thereof.
  • the invention provides for concentrate compositions as well as lubricant compositions.
  • the described industrial gear additive concentrates may contain up to 49 percent by weight of component (a).
  • the described industrial gear lubricants may contain at least 80 percent by weight of component (a).
  • Component (b) may be present from 1 to 5 percent by weight of the overall industrial gear lubricant; and component (c) may be present from 1.0 to 5.0 percent by weight of the overall industrial gear lubricant.
  • the invention further provides a method of reducing the operating temperature of an industrial gearbox, said method comprising the steps of: (I) adding to an industrial gear oil lubricant a fatty phosphite such that the lubricant contains at least 1.0 percent by weight fatty phosphite, and (II) operating the industrial gearbox while supplying the industrial gear oil lubricant to the industrial gearbox.
  • the invention further provides a method of reducing the operating temperature of an industrial gearbox, said method comprising the steps of: (I) supplying to an industrial gearbox the lubricant composition described herein, and (II) operating the industrial gearbox.
  • the fatty phosphite may be added to the industrial gear oil lubricant before the lubricant is supplied to the industrial gearbox, or wherein at least a portion of the fatty phosphite is added to the industrial gear oil lubricant after the lubricant is supplied to the industrial gearbox.
  • the invention provides the use of the described fatty phosphite in an industrial gear lubricant composition to reduce the operating temperature of an industrial gearbox in which the lubricant composition is used.
  • the invention also provides the use of the described industrial gear lubricant composition to reduce the operating temperature of an industrial gearbox in which the lubricant composition is used.
  • the industrial gear compositions of the invention include: (a) an oil of lubricating viscosity; (b) an industrial gear lubricant additive package; and (c) a fatty phosphite present at no less than 1.0 percent by weight of the overall composition.
  • the industrial gear lubricant additive package may include a demulsifier, a dispersant, and a metal deactivator.
  • the 1.0 percent by weight minimum of the fatty phosphite is included as it is believed that, in at least some embodiments, at least this amount of fatty phosphite is necessary to see the described benefits in the industrial gear oil compositions, namely the reduced gearbox operating temperature.
  • the extent to which the benefits of the invention are seen are expected to vary and/or be dependent somewhat on the base fluid used.
  • the oil of lubricating viscosity can be present in a major amount, for a lubricant composition, or in a concentrate forming amount, for a concentrate and/or additive composition.
  • Suitable oils include natural and synthetic lubricating oils and mixtures thereof.
  • the oil of lubricating viscosity is generally present in a major amount (i.e. an amount greater than 50 percent by weight).
  • the oil of lubricating viscosity is present in an amount of 75 to 98 percent by weight, and often greater than 80 percent by weight of the overall composition.
  • the oil of lubricating viscosity may include natural and synthetic oils, oil derived from hydrocracking, hydro genation, and hydro finishing, unrefined, refined and re-refined oils or mixtures thereof.
  • Unrefined oils are those obtained directly from a natural or synthetic source generally without (or with little) further purification treatment.
  • Refined oils are similar to the unrefined oils except they have been further treated in one or more purification steps to improve one or more properties. Purification techniques are known in the art and include solvent extraction, secondary distillation, acid or base extraction, filtration, percolation and similar processes.
  • Re -refined oils are also known as reclaimed or reprocessed oils, and are obtained by processes similar to those used to obtain refined oils. Re -refined oils are often are processed by techniques directed to removal of spent additives and oil breakdown products.
  • Natural oils useful as the oil of lubricating viscosity include animal oils and vegetable oils (e.g., castor oil, lard oil), mineral lubricating oils such as liquid petroleum oils and solvent-treated or acid-treated mineral lubricating oils of the paraffmic, naphthenic or mixed paraffmic naphthenic types and oils derived from coal or shale or mixtures thereof.
  • animal oils and vegetable oils e.g., castor oil, lard oil
  • mineral lubricating oils such as liquid petroleum oils and solvent-treated or acid-treated mineral lubricating oils of the paraffmic, naphthenic or mixed paraffmic naphthenic types and oils derived from coal or shale or mixtures thereof.
  • Synthetic oils of lubricating viscosity include hydrocarbon oils such as polymerized and interpolymerised olefins (e.g., polybutylenes, polypropylenes, propyleneisobutylene copolymers); poly(l-hexenes), poly(l-octenes), poly(l-decenes), and mixtures thereof; alkyl-benzenes (e.g., dodecylbenzenes, tetradecylbenzenes, dinonylbenzenes, di-(2-ethylhexyl)-benzenes); polyphenyls (e.g., biphenyls, terphenyls, alkylated polyphenyls); alkylated biphenyl ethers and alkylated biphenyl sulfides and the derivatives, analogs and homologs thereof or mixtures thereof.
  • hydrocarbon oils such as polymerized and interpolymerised ole
  • the oil of lubricating viscosity used in the invention is a synthetic oil that includes polymerized polyisobutylene, and in some embodiments the oil of lubricating viscosity used in the invention is a synthetic oil that includes polymerized polyisobutylene and a polyalphaolefm.
  • Another synthetic oil of lubricating viscosity includes polyol esters other than the hydrocarbyl-capped polyoxyalkylene polyol as disclosed herein, dicarboxylic esters, liquid esters of phosphorus-containing acids (e.g., tricresyl phosphate, trioctyl phosphate, and the diethyl ester of decane phosphonic acid), or polymeric tetrahydrofurans.
  • Synthetic conventional oil of lubricating viscosity also includes those produced by Fischer-Tropsch reactions and typically may be hydroisomerised Fischer-Tropsch hydrocarbons or waxes.
  • the oil of lubricating viscosity may be prepared by a Fischer-Tropsch gas-to-liquid synthetic procedure as well as other gas-to- liquid oils.
  • Oils of lubricating viscosity may further be defined as specified in the American Petroleum Institute (API) Base Oil Interchangeability Guidelines.
  • the five base oil groups are as follows: Group I (sulfur content >0.03 percent by weight, and/or ⁇ 90 percent by weight saturates, viscosity index 80-120); Group II (sulfur content ⁇ 0.03 percent by weight and >90 percent by weight saturates, viscosity index 80-120); Group III (sulfur content ⁇ 0.03 percent by weight and >90 percent by weight saturates, viscosity index >120); Group IV (all polyalphaolefms, or PAO, such as PAO-2, PAO-4, PAO-5, PAO-6, PAO-7 or PAO-8); and Group V (which encompasses "all others”).
  • PAO polyalphaolefms, or PAO, such as PAO-2, PAO-4, PAO-5, PAO-6, PAO-7 or PAO-8
  • Group V which encompasses
  • the oil of lubricating viscosity includes API Group I, Group II, Group III, Group IV, Group V oil or mixtures thereof.
  • the oil of lubricating viscosity is an API Group I, Group II, Group III, Group IV oil or mixtures thereof.
  • the oil of lubricating viscosity is often an API Group II, Group III or Group IV oil or mixtures thereof.
  • the lubricating oil component of the present invention includes a Group II or Group III base oil, or a combination thereof.
  • the oil can also be derived from the hydroisomerization of wax, such as slack wax or a Fischer-Tropsch synthesized wax.
  • Such "Gas-to-Liquid" oils are typically characterized as Group III.
  • compositions of the present invention may include some amount of Group I base oils, and even Group IV and Group V base oils.
  • the lubricating oil component of the invention contains no more than 20, 10, 5, or even 1 percent by weight Group I base oil. These limits may also apply to Group IV or Group V base oils.
  • the lubricating oil present in the compositions of the invention is at least 60, 70, 80, 90, or even 98 percent by weight Group II and/or Group III base oil.
  • the lubricating oil present in the compositions of the invention is essentially only Group II and/or Group III base oil, where small amounts of other types of base oils may be present but not in amounts that significantly impact the properties or performance of the overall composition.
  • compositions of the invention include some amount of Group I and/or Group II base oils.
  • compositions of the invention are lubricating compositions where the oil of lubricating viscosity is primarily Group I and/or Group II base oils, or even essentially Group I and/or Group II base oils, or even exclusively Group I and/or Group II base oils.
  • the invention provides a Group II composition, that is the oil of lubricating viscosity includes Group II oil, and can even be primarily if not exclusively Group II oil, while still providing synthetic oil composition performance. This is one of the benefits of the present invention.
  • the various described oils of lubricating viscosity may be used alone or in combinations.
  • the oil of lubricating viscosity may be used in the described industrial gear lubricants in the range of about 80 percent by weight to about 98 percent by weight, or from 80, 85, 90, 95, 97 or even 97.5 or 98 percent by weight oil or up to 90, 95, 97, 97.5, or even 98 percent by weight oil.
  • the oil of lubricating viscosity may be used as diluent in the described industrial gear additive concentrates in the range of about 1 percent by weight to about 49 percent by weight, or from 1, 5, even 10 percent by weight oil up to 10, 20, 30, 40, or even 45 or 49 percent by weight oil.
  • compositions of the invention include an industrial gear additive package.
  • the compositions of the invention are designed to be industrial gear lubricants, or additive packages for making the same.
  • the present invention does not relate to automotive gear lubricants or other lubricating compositions.
  • the industrial gear lubricant additive package includes a demulsifier, a dispersant, and a metal deactivator. Any combination of conventional additive packages designed for industrial gear application may be used.
  • the invention inherently assumes such additive packages are essentially free of the fatty phosphites of the present invention, or at least do not contain the type of fatty phosphites specified by the invention in the amounts specified.
  • the additives which may be present in the industrial gear additive package include a foam inhibitor, a demulsifier, a pour point depressant, an antioxidant, a dispersant, a metal deactivator (such as a copper deactivator), an antiwear agent, an extreme pressure agent, a viscosity modifier, or some mixture thereof.
  • the additives may each be present in the range from 50, 75, 100 or even 150 ppm up to 5, 4, 3, 2 or even 1.5 percent by weight, or from 75 ppm to 0.5 percent by weight, from 100 ppm to 0.4 percent by weight, or from 150 ppm to 0.3 percent by weight, where the percent by weight values are with regards to the overall lubricating oil composition.
  • additives including viscosity modifying polymers, which may alternatively be considered as part of the base fluid, may be present in higher amounts including up to 30, 40, or even 50% by weight when considered separate from the base fluid.
  • the additives may be used alone or as mixtures thereof.
  • Antifoams also known as foam inhibitors, are known in the art and include but are not limited to organic silicones and non-silicon foam inhibitors.
  • organic silicones include dimethyl silicone and polysiloxanes.
  • non-silicon foam inhibitors include but are not limited to polyethers, polyacrylates and mixtures thereof as well as copolymers of ethyl acrylate, 2-ethylhexylacrylate, and optionally vinyl acetate.
  • the antifoam is a polyacrylate. Antifoams may be present in the composition from 0.001 to 0.012 or 0.004 pbw or even 0.001 to 0.003 pbw.
  • Demulsifiers are known in the art and include but are not limited to derivatives of propylene oxide, ethylene oxide, polyoxyalkylene alcohols, alkyl amines, amino alcohols, diamines or polyamines reacted sequentially with ethylene oxide or substituted ethylene oxides or mixtures thereof.
  • demulsifiers include polyethylene glycols, polyethylene oxides, polypropylene oxides, (ethylene oxide- propylene oxide) polymers and mixtures thereof.
  • the demulsifiers are polyethers. Demulsifiers may be present in the composition from 0.002 to 0. 2 pbw.
  • Pour point depressants are known in the art and include but are not limited to esters of maleic anhydride-styrene copolymers, polymethacrylates; polyacrylates; polyacrylamides; condensation products of haloparaffin waxes and aromatic compounds; vinyl carboxylate polymers; and terpolymers of dialkyl fumarates, vinyl esters of fatty acids, ethylene -vinyl acetate copolymers, alkyl phenol formaldehyde condensation resins, alkyl vinyl ethers and mixtures thereof.
  • compositions of the invention may also include a rust inhibitor, other than some of the additives described above.
  • Suitable rust inhibitors include hydrocarbyl amine salts of dialkyldithiophosphoric acid, hydrocarbyl amine salts of hydrocarbyl arenesulphonic acid, fatty carboxylic acids or esters thereof, an ester of a nitrogen- containing carboxylic acid, an ammonium sulfonate, an imidazoline, mono-thio phosphate salts or esters, or any combination thereof; or mixtures thereof.
  • hydrocarbyl amine salts of dialkyldithiophosphoric acid of the invention include but are not limited to those described above, as well as the reaction product(s) of diheptyl or dioctyl or dinonyl dithiophosphoric acids with ethylenediamine, morpholine or PrimeneTM 81R or mixtures thereof.
  • Suitable hydrocarbyl amine salts of hydrocarbyl arenesulphonic acids used in the rust inhibitor package of the invention are represented by the formula: wherein Cy is a benzene or naphthalene ring.
  • R 1 is a hydrocarbyl group with about 4 to about 30, preferably about 6 to about 25, more preferably about 8 to about 20 carbon atoms, z is independently 1, 2, 3, or 4 and most preferably z is 1 or 2.
  • R 2 , R 3 and R 4 are the same as described above.
  • hydrocarbyl amine salts of hydrocarbyl arenesulphonic acid of the invention include but are not limited to the ethylenediamine salt of dinonylnaphthalene sulfonic acid.
  • suitable fatty carboxylic acids or esters thereof include glycerol monooleate and oleic acid.
  • An example of a suitable ester of a nitrogen-containing carboxylic acid includes oleyl sarcosine.
  • the rust inhibitors may be present in the range from 0.02 to 0.2, from 0.03 to 0.15, from 0.04 to 0.12, or from 0.05 to 0.1 percent by weight of the lubricating oil composition.
  • the rust inhibitors of the invention may be used alone or in mixtures thereof.
  • compositions of the invention may also include a metal deactivator.
  • Metal deactivators are used to neutralise the catalytic effect of metal for promoting oxidation in lubricating oil. Suitable metal deactivators include but are not limited to triazoles, tolyltriazoles, a thiadiazole, or combinations thereof, as well as derivatives thereof.
  • Examples include derivatives of benzotriazoles other than those described above, benzimidazole, 2-alkyldithiobenzimidazoles, 2-alkyldithiobenzothiazoles, 2- (N,N'-dialkyldithio-carbamoyl)benzothiazoles, 2,5-bis(alkyl-dithio)-l,3,4-thiadiazoles, 2,5-bis(N,N'-dialkyldithiocarbamoyl)-l,3,4-thiadiazoles, 2-alkyldithio-5-mercapto thiadiazoles or mixtures thereof.
  • These additives may be used from 0.01 to 0.25 percent by weight in the overall composition.
  • the metal deactivator is a hydrocarbyl substituted benzotriazole compound.
  • the benzotriazole compounds with hydrocarbyl substitutions include at least one of the following ring positions 1- or 2- or 4- or 5- or 6- or 7- benzotriazoles.
  • the hydrocarbyl groups contain about 1 to about 30, preferably about 1 to about 15, more preferably about 1 to about 7 carbon atoms, and most preferably the metal deactivator is 5-methylbenzotriazole used alone or mixtures thereof.
  • the metal deactivators may be present in the range from 0.001 to 0.5, from 0.01 to 0.04 or from 0.015 to 0.03 pbw of the lubricating oil composition. Metal deactivators may also be present in the composition from 0.002 or 0.004 to 0.02 pbw. The metal deactivator may be used alone or mixtures thereof.
  • Antioxidants may also be present including (i) an alkylated diphenylamine, and (ii) a substituted hydrocarbyl mono-sulfide.
  • the alkylated diphenylamines of the invention are bis-nonylated diphenylamine and bis-octylated diphenylamine.
  • the substituted hydrocarbyl monosulfides include n-dodecyl-2-hydroxyethyl sulfide, l-(tert-dodecylthio)-2-propanol, or combinations thereof.
  • the substituted hydrocarbyl monosulfide is l-(tert- dodecylthio)-2-propanol.
  • the antioxidant package may also include sterically hindered phenols. Examples of suitable hydrocarbyl groups for the sterically hindered phenols include but are not limited to 2-ethylhexyl or n-butyl ester, dodecyl or mixtures thereof.
  • methylene-bridged sterically hindered phenols include but are not limited to 4,4 -methylene -bis(6-tert-butyl o-cresol), 4,4 -methylene -bis(2-tert-amyl-o-cresol), 2,2 - methylene-bis(4-methyl-6-tert-butylphenol), 4,4 -methylene -bis(2,6-di-tertbutylphenol) or mixtures thereof.
  • the industrial gear lubricant additive package of the invention includes a nitrogen-containing dispersant, for example a hydrocarbyl substituted nitrogen containing additive.
  • Suitable hydrocarbyl substituted nitrogen containing additives include ashless dispersants and polymeric dispersants. Ashless dispersants are so-named because, as supplied, they do not contain metal and thus do not normally contribute to sulfated ash when added to a lubricant. However, they may, of course, interact with ambient metals once they are added to a lubricant which includes metal-containing species. Ashless dispersants are characterized by a polar group attached to a relatively high molecular weight hydrocarbon chain. Examples of such materials include succinimide dispersants, Mannich dispersants, and borated derivatives thereof.
  • the industrial gear lubricant additive package of the invention includes a sulfur-containing compound.
  • Suitable sulfur-containing compounds include sulfurized olefins and polysulfides.
  • the sulfurized olefin or polysulfides may be derived from isobutylene, butylene, propylene, ethylene, or some combination thereof.
  • the sulfur-containing compound is a sulfurized olefin derived from any of the natural oils or synthetic oils described above, or even some combination thereof.
  • the sulfurized olefin may be derived from vegetable oil.
  • the industrial gear additive packages include one or more phosphorous amine salts, but in amounts such that the additive package, or in other embodiments the resulting industrial gear lubricant compositions, contains no more than 1.0 percent by weight of such materials, or even no more than 0.75 or 0.6 percent by weight.
  • the industrial gear additive packages, or the resulting industrial gear lubricant compositions are essentially free of or even completely free of phosphorous amine salts.
  • component (b), the industrial gear lubricant additive package comprises one or more antiwear additives and/or extreme pressure agents, one or more rust and/or corrosion inhibitors, one or more foam inhibitors, one or more demulsifiers, or any combination thereof.
  • the industrial gear additive packages, or the resulting industrial gear lubricant compositions are essentially free of or even completely free of phosphorous amine salts, dispersants, or both.
  • the industrial gear additive packages, or the resulting industrial gear lubricant compositions include a demulsifier, a corrosion inhibitor, a friction modifier, or combination of two or more thereof.
  • the corrosion inhibitor includes a tolyltriazole.
  • the industrial gear additive packages, or the resulting industrial gear lubricant compositions include one or more sulfurized olefins or polysulfides; one or more phosphorus amine salts; one or more thiophosphate esters, one or more thiadiazoles, tolyltriazoles, polyethers, and/or alkenyl amines; one or more ester copolymers; one or more carboxylic esters; one or more succinimide dispersants, or any combination thereof.
  • the industrial gear additive package may be present in the overall industrial gear lubricant from 1 to 5 percent by weight, or in other embodiments from 1, 1.5, or even 2 percent by weight up to 2, 3, 4, 5, 7 or even 10 percent by weight.
  • Amounts of the industrial gear additive package that may be present in the industrial gear concentrate compositions of the invention are the corresponding amounts to the weight percent above; where the values are considered without the oil present (i.e., they may be treated as pbw values along with the actual amount of oil present).
  • compositions of the invention include a fatty phosphite present at no less than 1.0 percent by weight of the overall lubricant composition.
  • Suitable phosphites include those having at least one hydrocarbyl group with 4 or more, or 8 or more, or 12 or more, carbon atoms. Typical ranges for the number of carbon atoms on the hydrocarbyl group include 8 to 30, or 10 to 24, or 12 to 22, or 14 to 20, or 16 to 18.
  • the phosphite may be a mono-hydrocarbyl substituted phosphite, a di- hydrocarbyl substituted phosphite, or a tri-hydrocarbyl substituted phosphite.
  • the phosphite is sulphur-free, i.e., the phosphite is not a thiophosphite.
  • the phosphite having at least one hydrocarbyl group with 4 or more carbon atoms may be represented by the formulae:
  • R 5 , R 6 and R 7 may be a hydrocarbyl group containing at least 4 carbon atoms and the other may be hydrogen or a hydrocarbyl group.
  • R 5 , R 6 and R 7 are all hydrocarbyl groups.
  • the hydrocarbyl groups may be alkyl, cycloalkyl, aryl, acyclic or mixtures thereof.
  • the compound may be a tri-hydrocarbyl substituted phosphite i.e., R 5 , R 6 and R 7 are all hydrocarbyl groups.
  • Alkyl groups may be linear or branched, typically linear, and saturated or unsaturated, typically saturated.
  • alkyl groups for R 5 , R 6 and R 7 include octyl, 2-ethylhexyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, octadecenyl, nonadecyl, eicosyl or mixtures thereof.
  • the fatty phosphite component of the invention, and/or the composition overall is essentially free of, or even completely free of phosphoric acid ester and/or amine salts thereof.
  • the fatty phosphite comprises an alkenyl phosphite or esters thereof, for example, esters of dimethyl hydrogen phosphite.
  • the fatty phosphite may be present in the overall industrial gear lubricant from 1.0 to 10.0 percent by weight, or in other embodiments from 1, 1.5, or even 2 percent by weight up to 1.5, 1.9, 2, 3, 4, 5, 7 or even 10 percent by weight.
  • Amounts of the industrial gear additive package that may be present in the industrial gear concentrate compositions of the invention are the corresponding amounts to the weight percent above; where the values are considered without the oil present (i.e., they may be treated as pbw values along with the actual amount of oil present).
  • the ratio of the industrial gear additive package component (component (b)) relative to the fatty phosphite component (component (a)), on an oil free weight basis is from 1 :0.5 to 1 : 1.5. In still further embodiments, this ratio of components (b):(c) is 1 :0.5 to 1 : 1.5, or 1 :0.6 to 1 : 1.2, or 1 :0.7 to 1 : 1.1, or 1 :0.8 to 1 : 1.0.
  • the invention includes both industrial gear lubricants and industrial gear additive concentrates that may be used to make industrial gear lubricants.
  • component (a) the oil of lubricating viscosity, may be present from 80, 85, 90, 95, 97 or even 97.5 or 98 percent by weight oil up to 90, 95, 97, 97.5, or even 98 percent by weight;
  • component (b) the industrial gear lubricant additive package, may be present from 1, 1.5, or even 2 percent by weight up to 2, 3, 4, 5, 7 or even 10 percent by weight;
  • component (c) the fatty phosphite, may be present from 1, 1.5, or even 2 percent by weight up to 1.5, 1.9, 2, 3, 4, 5, 7 or even 10 percent by weight.
  • component (a), the oil of lubricating viscosity may be present from 1, 5, even 10 percent by weight oil up to 10, 20, 30, 40, or even 45 or 49 percent by weight
  • component (b), the industrial gear lubricant additive package may be present from 20, 25, 25.5, 27.5, 30, 35, 45 or even 45 percent by weight up to 45, 47.5, or even 49.5 percent by weight
  • component (c) the fatty phosphite may be present from 25.5, 27.5, 30, 35, 45 or even 45 percent by weight up to 45, 47.5, or even 49.5 percent by weight
  • the ratio of the industrial gear additive package component (component (b)) relative to the fatty phosphite component (component (a)), on an oil free weight basis is from 1 :0.5 to 1 : 1.5.
  • the ratio of components (b):(c) is from 4: 1 to 1 :5, or from 2: 1 to 1 :5, or from 1 : 1 to 1 :5, or from 1 :0.5 to 1 : 1.5, or 1 :0.6 to 1 : 1.2, or 1 :0.7 to 1 : 1.1, or 1 :0.8 to 1 : 1.0.
  • These ratios may apply to the industrial gear lubricants of the invention and/or to the industrial gear additive concentrates of the invention.
  • the invention includes methods of making the industrial gear lubricants and/or the industrial gear additive concentrates described above. Such methods include mixing the described components together. No particular order or means of addition is believed to significantly impact the results.
  • the invention also includes a method of reducing the operating temperature of an industrial gearbox.
  • the method includes the steps of: (I) adding to an industrial gear oil lubricant a fatty phosphite such that the lubricant contains at least 1.0 percent by weight fatty phosphite, and (II) operating the industrial gearbox while supplying the industrial gear oil lubricant to the industrial gearbox.
  • the method may also involve the addition of one of the industrial gear lubricants described herein to an industrial gearbox and then operating that industrial gearbox, which will result in a lower operating temperature in the industrial gearbox compared to the operating temperature the industrial gearbox would experience if operated with a similar industrial gear lubricant that does not include the specified fatty phosphite.
  • At least a portion, if not all of the fatty phosphite is added to the industrial gear oil lubricant before the lubricant is supplied to the industrial gearbox. In other embodiments at least a portion, if not all of the fatty phosphite is added to the industrial gear oil lubricant after the lubricant is supplied to the industrial gearbox.
  • the compositions of this invention are essentially free of, or even completely free of: copolymers comprising units derived from two or more methacrylic acid esters. More specifically, in some embodiments the compositions of this invention are essentially free of, or even completely free of: copolymers comprising units derived from (a) methacrylic acid esters containing from 9 to 25 carbon atoms in the ester group and (b) methacrylic acid esters containing from 7 to 12 carbon atoms in the ester group, said ester groups having 2-(C 1-4 alkyl)-substituents, and optionally (c) at least one monomer selected from the group consisting of methacrylic acid esters containing from 2 to 8 carbon atoms in the ester group atoms and which are different from methacrylic acid esters (a) and (b), vinyl aromatic compounds, and nitrogen- containing vinyl monomers with the proviso that no more than 60% by weight of the esters contain not more than 11 carbon atom
  • compositions of this invention are essentially free of, or even completely free of: a nitrogen-containing ester derived from a carboxy- containing interpolymer having a reduced specific viscosity (RSV) of from about 0.05 to about 2, said interpolymer being derived from at least two monomers.
  • RSV specific viscosity
  • compositions of this invention are essentially free of, or even completely free of: a nitrogen-containing ester derived from a carboxy-containing interpolymer having a reduced specific viscosity (RSV) of from about 0.05 to about 2, said interpolymer being derived from at least two monomers, (i) one of said monomers being at least one of an aliphatic olefin containing from 2 to about 30 carbon atoms and a vinyl aromatic monomer and (ii) the other of said monomers being at least one alpha, beta-unsaturated acylating agent, said ester being characterized by the presence within its polymeric structure of each of the following groups which are derived from the carboxy groups of said interpolymer: (A) from about 20 to about 70 mole % based on moles of carboxyl groups in said interpolymer, of ester groups containing from about 13 to about 19 carbon atoms; (B) from about 80 to about 30 mole %, based on moles
  • RSV specific viscos
  • a set of examples of industrial gear lubricants is prepared in group II base oil. Each example uses the same base oil and the same industrial gear lubricant additive package. Some examples then include a supplemental additive in order to evaluate the impact the supplement has on the operating temperature seen when an industrial gearbox is operated with the prepared industrial gear lubricants.
  • the examples are summarized in the table below. Different amounts of the different supplemental additives used in the examples reflect the different phosphorus levels of each material. Amounts were adjusted so the same amount of phosphorus was delivered when changing from one supplemental additive to another. Table 1
  • the C18 phosphite is a di-a ky substituted phosphite with C18 a ky groups.
  • the CI 6-18 phosphite is a di-alkyl substituted phosphite with CI 6-18 alkyl groups.
  • the CI 6- 18 phosphonate is a di-alkyl substituted phosphonate with CI 6- 18 alkyl groups.
  • the phos acid amine salt is an amine salt of a C18 alkyl phosphoric acid.
  • Examples B-l, B-2, B-3, B-4, and B-5 use synthetic ISO 150 base oil which is a mix of P AOs
  • Examples B-6 and B-7 use synthetic ISO 150 base oil which is a mix of PAOs and an alkyl ester copolymer.
  • Examples B-8 and B-9 use synthetic ISO 320 base oil which is a mix of PAOs and an alkyl ester copolymer.
  • the CI 8 phosphite is a di-alkyl substituted phosphite with CI 8 alkyl groups.
  • the CI 6-18 phosphite is a di-alkyl substituted phosphite with CI 6-18 alkyl groups.
  • the amount of each chemical component is presented exclusive of any solvent or diluent, which may be customarily present in the commercial material, unless otherwise indicated. It is to be understood that the upper and lower amount, range, and ratio limits set forth herein may be independently combined. Similarly, the ranges and amounts for each element of the invention can be used together with ranges or amounts for any of the other elements. As used herein, the expression “consisting essentially of permits the inclusion of substances that do not materially affect the basic and novel characteristics of the composition under consideration. All of the embodiments of the invention described herein are contemplated from and may be read from both an open-ended and inclusive view (i.e. using "comprising of language) and a closed and exclusive view (i.e., using "consisting of language).
  • hydrocarbyl substituent or “hydrocarbyl group” is used in its ordinary sense, which is well-known to those skilled in the art. Specifically, it refers to a group having a carbon atom directly attached to the remainder of the molecule and having predominantly hydrocarbon character.
  • hydrocarbyl groups include: (i) hydrocarbon substituents, that is, aliphatic (e.g., alkyl or alkenyl), alicyclic (e.g., cycloalkyl, cycloalkenyl) substituents, and aromatic-, aliphatic-, and alicyclic- substituted aromatic substituents, as well as cyclic substituents wherein the ring is completed through another portion of the molecule (e.g., two substituents together form a ring); (ii) substituted hydrocarbon substituents, that is, substituents containing non- hydrocarbon groups which, in the context of this invention, do not alter the predominantly hydrocarbon nature of the substituent (e.g., halo (especially chloro and fluoro), hydroxy, alkoxy, mercapto, alkylmercapto, nitro, nitroso, and sulfoxy); (iii) hetero substituents, that is, substituents which, while having a predominantly hydrocarbon
  • Heteroatoms include sulfur, oxygen, and nitrogen.
  • no more than two, or no more than one, non-hydrocarbon substituent will be present for every ten carbon atoms in the hydrocarbyl group; alternatively, there may be no non-hydrocarbon substituents in the hydrocarbyl group.

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Abstract

La présente invention concerne des compositions d'huiles industrielles pour engrenages améliorées qui réduisent sensiblement la température de fonctionnement d'un réducteur dans lequel sont utilisées les compositions d'huiles pour engrenages. La température de fonctionnement réduite conférée par les compositions décrites conduit à une performance améliorée de l'équipement. L'invention concerne également des procédés de fabrication des compositions d'huiles industrielles pour engrenages et des procédés les utilisant.
PCT/US2013/070278 2012-12-03 2013-11-15 Huiles industrielles pour engrenages permettant de réduire les températures de fonctionnement d'un réducteur WO2014088782A1 (fr)

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CN201380062936.0A CN104822809A (zh) 2012-12-03 2013-11-15 赋予降低的齿轮箱操作温度的工业齿轮油
US14/647,221 US20150299603A1 (en) 2012-12-03 2013-11-15 Industrial Gear Oils Imparting Reduced Gearbox Operating Temperatures
JP2015545081A JP6378691B2 (ja) 2012-12-03 2013-11-15 ギアボックスの動作温度の低下を与える工業用のギアオイル
SG11201503993WA SG11201503993WA (en) 2012-12-03 2013-11-15 Industrial gear oils imparting reduced gearbox operating temperatures
EP13803330.3A EP2925839B1 (fr) 2012-12-03 2013-11-15 Huiles industrielles pour engrenages permettant de réduire les températures de fonctionnement d'un réducteur

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EP2925839B1 (fr) 2021-09-22
TWI634204B (zh) 2018-09-01
CA2892812A1 (fr) 2014-06-12
TW201430120A (zh) 2014-08-01
US20150299603A1 (en) 2015-10-22

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