WO2014088712A8 - Electrolyte compositions and electrochemical double layer capacitors formed there from - Google Patents

Electrolyte compositions and electrochemical double layer capacitors formed there from Download PDF

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Publication number
WO2014088712A8
WO2014088712A8 PCT/US2013/065788 US2013065788W WO2014088712A8 WO 2014088712 A8 WO2014088712 A8 WO 2014088712A8 US 2013065788 W US2013065788 W US 2013065788W WO 2014088712 A8 WO2014088712 A8 WO 2014088712A8
Authority
WO
WIPO (PCT)
Prior art keywords
electrolytes
compositions
salts
ionic liquids
double layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2013/065788
Other languages
French (fr)
Other versions
WO2014088712A1 (en
Inventor
Wayne L. Gellett
Benjamin L. RUPERT
Levi J. Irwin
Leanne Beer
Shilpa A. WORLIKAR
Steven Z. Shi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
eSionic Corp
Original Assignee
eSionic Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/706,233 external-priority patent/US8907133B2/en
Application filed by eSionic Corp filed Critical eSionic Corp
Priority to JP2015546468A priority Critical patent/JP2016507888A/en
Priority to CN201380072274.5A priority patent/CN105164777A/en
Priority to KR1020157017819A priority patent/KR20150093204A/en
Priority to EP13860380.8A priority patent/EP2929553A4/en
Publication of WO2014088712A1 publication Critical patent/WO2014088712A1/en
Anticipated expiration legal-status Critical
Publication of WO2014088712A8 publication Critical patent/WO2014088712A8/en
Ceased legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/535—Organo-phosphoranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5407—Acyclic saturated phosphonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65688—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphonium compound
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65742—Esters of oxyacids of phosphorus non-condensed with carbocyclic rings or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65748—Esters of oxyacids of phosphorus the cyclic phosphorus atom belonging to more than one ring system
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/54—Electrolytes
    • H01G11/58—Liquid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/54—Electrolytes
    • H01G11/58—Liquid electrolytes
    • H01G11/62—Liquid electrolytes characterised by the solute, e.g. salts, anions or cations therein
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13—Energy storage using capacitors

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Secondary Cells (AREA)
  • Primary Cells (AREA)
  • Hybrid Cells (AREA)

Abstract

The invention generally encompasses phosphonium ionic liquids, salts, compositions and their use in many applications, including but not limited to: as electrolytes in electronic devices such as memory devices including static, permanent and dynamic random access memory, as electrolytes in energy storage devices such as batteries, electrochemical double layer capacitors (EDLCs) or supercapacitors or ultracapacitors, electrolytic capacitors, as electrolytes in dye-sensitized solar cells (DSSCs), as electrolytes in fuel cells, as a heat transfer medium, among other applications. In particular, the invention generally relates to phosphonium ionic liquids, salts, compositions, wherein the compositions exhibit superior combination of thermodynamic stability, low volatility, wide liquidus range, ionic conductivity, and electrochemical stability. The invention further encompasses methods of making such phosphonium ionic liquids, salts, compositions, operational devices and systems comprising the same.
PCT/US2013/065788 2012-12-05 2013-10-18 Electrolyte compositions and electrochemical double layer capacitors formed there from Ceased WO2014088712A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2015546468A JP2016507888A (en) 2012-12-05 2013-10-18 Electrolyte composition and electrochemical double layer capacitor formed therefrom
CN201380072274.5A CN105164777A (en) 2012-12-05 2013-10-18 Electrolyte compositions and electrochemical double layer capacitors formed there from
KR1020157017819A KR20150093204A (en) 2012-12-05 2013-10-18 Electolyte compositions and electrochemical double layer capacitors formed there from
EP13860380.8A EP2929553A4 (en) 2012-12-05 2013-10-18 Electrolyte compositions and electrochemical double layer capacitors formed there from

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/706,233 US8907133B2 (en) 2008-07-14 2012-12-05 Electrolyte compositions and electrochemical double layer capacitors formed there from
US13/706,233 2012-12-05

Publications (2)

Publication Number Publication Date
WO2014088712A1 WO2014088712A1 (en) 2014-06-12
WO2014088712A8 true WO2014088712A8 (en) 2015-07-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/065788 Ceased WO2014088712A1 (en) 2012-12-05 2013-10-18 Electrolyte compositions and electrochemical double layer capacitors formed there from

Country Status (5)

Country Link
EP (1) EP2929553A4 (en)
JP (1) JP2016507888A (en)
KR (1) KR20150093204A (en)
CN (1) CN105164777A (en)
WO (1) WO2014088712A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109903995B (en) 2011-07-08 2021-09-28 快帽系统公司 High temperature energy storage device
US9558894B2 (en) 2011-07-08 2017-01-31 Fastcap Systems Corporation Advanced electrolyte systems and their use in energy storage devices
US10872737B2 (en) 2013-10-09 2020-12-22 Fastcap Systems Corporation Advanced electrolytes for high temperature energy storage device
US9870874B2 (en) * 2014-06-26 2018-01-16 Shenzhen Capchem Technology Co., Ltd. Electrolyte solute, electrolyte, and high-voltage supercapacitor
JP2016110075A (en) * 2014-10-03 2016-06-20 株式会社半導体エネルギー研究所 Light-emitting device, module, and electronic device
KR102668693B1 (en) * 2015-01-27 2024-05-27 패스트캡 시스템즈 코포레이션 Wide temperature range ultracapacitor
WO2016204820A2 (en) 2015-01-27 2016-12-22 Fastcap Systems Corporation Wide temperature range ultracapacitor
CN105762168B (en) * 2016-04-18 2018-08-21 华中科技大学 A kind of perovskite solar cell and ultracapacitor integration member and preparation method thereof
KR20240059631A (en) 2016-12-02 2024-05-07 패스트캡 시스템즈 코포레이션 Composite electrode
CN119314806A (en) * 2019-09-30 2025-01-14 麻省理工学院 Metal-organic frameworks for supercapacitor electrodes
KR102429821B1 (en) * 2020-10-13 2022-08-08 서울시립대학교 산학협력단 High-performance and reliable electrochromic device and method for preparing the same
US12444749B2 (en) 2021-07-23 2025-10-14 Lyten, Inc. Anode protective layer for lithium-sulfur cylindrical cells
WO2023173027A1 (en) * 2022-03-09 2023-09-14 Lyten, Inc. Tab-less cylindrical cell

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0230907A3 (en) * 1986-01-17 1989-05-31 Asahi Glass Company Ltd. Electric double layer capacitor having high capacity
US7342769B2 (en) * 2002-08-23 2008-03-11 Nisshinbo Industries, Inc. Electric double-layer capacitor
JPWO2005076299A1 (en) * 2004-02-03 2007-10-18 日清紡績株式会社 Electric double layer capacitor
FR2933814B1 (en) * 2008-07-11 2011-03-25 Commissariat Energie Atomique IONIC LIQUID ELECTROLYTES COMPRISING A SURFACTANT AND ELECTROCHEMICAL DEVICES SUCH AS ACCUMULATORS COMPRISING SAME
US8778534B2 (en) * 2008-07-14 2014-07-15 Esionic Es, Inc. Phosphonium ionic liquids, compositions, methods of making and batteries formed there from
US7679884B2 (en) * 2008-07-29 2010-03-16 Wisconsin Alumni Research Foundation Organosilicon phosphorus-based electrolytes
EE05629B1 (en) * 2010-09-06 2013-02-15 O� Skeleton Technologies Method for the preparation of an electrochemical system of a high power and energy density supercapacitor, a corresponding supercapacitor and a method for making it
KR20140000235A (en) * 2010-09-30 2014-01-02 바스프 에스이 Li-based anode with ionic liquid polymer gel

Also Published As

Publication number Publication date
WO2014088712A1 (en) 2014-06-12
CN105164777A (en) 2015-12-16
EP2929553A1 (en) 2015-10-14
EP2929553A4 (en) 2016-09-07
JP2016507888A (en) 2016-03-10
KR20150093204A (en) 2015-08-17

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