WO2014087705A1 - Food packaged in hard container, and method for producing same - Google Patents

Food packaged in hard container, and method for producing same Download PDF

Info

Publication number
WO2014087705A1
WO2014087705A1 PCT/JP2013/071875 JP2013071875W WO2014087705A1 WO 2014087705 A1 WO2014087705 A1 WO 2014087705A1 JP 2013071875 W JP2013071875 W JP 2013071875W WO 2014087705 A1 WO2014087705 A1 WO 2014087705A1
Authority
WO
WIPO (PCT)
Prior art keywords
food
hard container
enzyme
container
hard
Prior art date
Application number
PCT/JP2013/071875
Other languages
French (fr)
Japanese (ja)
Inventor
宏司 坂本
賢哉 柴田
文彦 豊田
Original Assignee
有限会社クリスターコーポレーション
広島県
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 有限会社クリスターコーポレーション, 広島県 filed Critical 有限会社クリスターコーポレーション
Priority to CN201380063334.7A priority Critical patent/CN104883902A/en
Priority to US14/649,627 priority patent/US20160007645A1/en
Priority to JP2014504866A priority patent/JP5674178B2/en
Publication of WO2014087705A1 publication Critical patent/WO2014087705A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463Organic compounds; Microorganisms; Enzymes
    • A23L3/3571Microorganisms; Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00General methods for preserving meat, sausages, fish or fish products
    • A23B4/14Preserving with chemicals not covered by groups A23B4/02 or A23B4/12
    • A23B4/18Preserving with chemicals not covered by groups A23B4/02 or A23B4/12 in the form of liquids or solids
    • A23B4/20Organic compounds; Microorganisms; Enzymes
    • A23B4/22Microorganisms; Enzymes; Antibiotics
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B5/00Preservation of eggs or egg products
    • A23B5/08Preserving with chemicals
    • A23B5/12Preserving with chemicals in the form of liquids or solids
    • A23B5/14Organic compounds; Microorganisms; Enzymes
    • A23B5/16Microorganisms; Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/154Organic compounds; Microorganisms; Enzymes
    • A23B7/155Microorganisms; Enzymes; Antibiotics
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B9/00Preservation of edible seeds, e.g. cereals
    • A23B9/16Preserving with chemicals
    • A23B9/24Preserving with chemicals in the form of liquids or solids
    • A23B9/26Organic compounds; Microorganisms; Enzymes
    • A23B9/28Microorganisms; Enzymes; Antibiotics
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/06Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/10Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by heating materials in packages which are not progressively transported through the apparatus
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/40Complete food formulations for specific consumer groups or specific purposes, e.g. infant formula
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/28Applications of food preservatives, fungicides, pesticides or animal repellants
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

Definitions

  • the present invention relates to a food in a hard container and a method for producing the same. More specifically, the present invention relates to a food in which the hardness is adjusted while maintaining the original shape of the food, and the food in a hard container for distribution at normal temperature or chilled distribution that prevents mold deformation during the manufacturing process or transportation, and a method for manufacturing the same. About.
  • enzyme impregnation, enzyme reaction, enzyme deactivation, pasteurization or retort sterilization in a hard container, or food is put in a container before softening by enzyme reaction after impregnation of the food with enzyme under pressure
  • the enzyme reaction, enzyme deactivation, pasteurization, or retort sterilization enabled low-cost, hygienic production of shape-retaining softened food while preventing loss of shape.
  • the food material can be prevented from being deformed due to vibrations during production or distribution, and can be distributed at normal temperature or chilled without breaking the shape.
  • an enzyme for introducing an enzyme into a food material, after freezing the food material and giving the food a slack, a method of rapidly impregnating the enzyme by decompression or pressurizing operation, a method of impregnating the heated food material with the enzyme by pressure, There is a method of impregnating with a reduced pressure enzyme after heating with saturated steam, or a method of rapidly impregnating an enzyme with a decompression operation after applying heat to the tissue in advance to loosen the tissue.
  • a method of introducing an enzyme by physical impact or injection using a dedicated device such as tumbling or injection is also known.
  • a vacuum can, a vacuum cooler, or a vacuum packaging machine and introduce an enzyme by a pressurizing device using a hydrostatic pressure, a vacuum tumbler, or an injector device.
  • the enzyme is introduced into the food material, and the food material can be processed softly while maintaining its shape by the enzyme impregnation technique.
  • these softened foods tend to lose shape during the manufacturing process, for example, during heating, seasoning, packaging, packaging, moving, transporting, or handling at retailers, and they are characteristic of the product. The shape and appearance are lost.
  • a method of distributing the product as a frozen product is adopted.
  • Patent Document 1 the method of introducing rapid enzymes into the tissue of plant food materials (Patent Document 1) and the frozen and thawed vegetable foods in an enzyme solution with adjusted salt concentration etc.
  • Patent Document 2 a method in which an enzyme is introduced into a tissue by operation and sterilized without losing its seasoning and under pressure and heat.
  • Patent Document 1 relates to a rapid introduction method of an enzyme, and does not show the production of a shape-retaining softened food material.
  • Patent Document 2 is a method for producing a retort food related to a shape-retaining softened food, but it is an invention for preventing the collapse of a mold during a retort (pressure heat sterilization) process, and handling of the softened food during the production process.
  • Patent Document 2 describes a method of maintaining the softness before pressure heat sterilization. Further, as described in Examples (0018) and (0023), after the decompression treatment and the enzyme treatment, the retort treatment is performed by transferring the food material to the retort film. Since it is not a method of performing the process from the enzyme reaction to the sealing process in a hard container, careful handling is essential so as not to break the shape after the food is softened.
  • this enzyme introduction technology can be easily implemented at the site of kitchen facilities, etc., and can be prevented from losing its shape during the manufacturing process, transportation and distribution process of softened food materials, or it can be applied to food materials due to hygiene considerations.
  • a method for producing cooked food Patent Document 3 in which the enzyme introduction, enzyme reaction, and heating step can be carried out in the same packaging container.
  • the method (patent document 4) etc. which carry out pressure reduction processing in an enzyme liquid are also disclosed. In either case, an enzyme or the like is introduced into the food using an external pressure such as reduced pressure or increased pressure.
  • Patent Document 5 For animal food materials, a method of immersing the food material in the enzyme solution (Patent Document 5), a method of injecting the enzyme-containing liquid into the food material and tumbling (Patent Document 6), and applying and immersing the enzyme solution in the food material And the method (patent document 7) etc. etc. which permeate
  • Patent Document 8 As an invention of medical contrast medium test foods, there is an invention (Patent Document 8) in which an enzyme and a contrast medium are introduced into food materials by a decompression method, but this also uses external pressure, taking into account the loss of shape after manufacture. It has not been.
  • the softening treatment by enzyme treatment can soften the edible part, especially for seafood, but it cannot be made soft enough to eat bones.
  • the use of water-removed raw materials for solving the problem has led to an increase in price and hinders supply at a low price.
  • Patent Document 3 performs enzyme introduction and enzyme reaction in a soft packaging container.
  • the pressure treatment is premised on the use of external energy, the use of a soft wrapping material is essential, and the soft wrapping material is vulnerable to physical impact from the outside. For this reason, there is a problem in that the shape is lost unless it is distributed as frozen food. None of the prior art documents devised a method for performing an enzyme reaction in a rigid container.
  • Patent document 9 is a method of filling a heat-resisting container with ingredients for sugar beet together with a seasoning liquid and sterilizing by heating, but is a method of simultaneously seasoning and sterilizing in a heat-resistant container while maintaining the original texture. The object and the effect are different from those of the present invention which is performed in a container and aims to change the texture.
  • Patent Document 10 is a method of solidifying a food material softened with an enzyme with jelly, which is characterized in that it is hard enough to be cut together with the jelly in a method for producing a jelly-like food, and is a hard container. Etc. are not required.
  • Patent Document 11 is a patent in which a thickener is introduced into a softened food material to prevent water separation from the food material so that a person with difficulty in chewing or swallowing can safely eat, including the outside of the food material of the present invention. It is not an invention that prevents the loss of shape caused by vibration.
  • the object of the present invention is to prevent shape loss in the form-preserving softening type nursing food, baby food, medical field, and contrast inspection food field during the manufacturing process, transportation, and retail sale, Or it is in solving the foodstuff or the manufacturing method of foodstuffs which enabled chilled distribution. Introduce flavoring ingredients such as degrading enzymes and seasonings, oils and fats, amino acids and swallowing foods inside the food without changing the original shape of the food, changing the texture and taste, inexpensive It is to produce food that is easy to eat and delicious, distributed at normal temperature or chilled.
  • a degrading enzyme is introduced to the center of the food to soften it by recognizing what the food needs to be taken by the care recipient and the elderly so that it can be consumed with satisfaction.
  • An object of the present invention is to provide a method for producing a normal temperature distribution or chilled distribution food material capable of producing a processed food at low cost. Furthermore, it is providing the manufacturing method of the normal temperature distribution or the chilled distribution foodstuff which strengthened the nutrient component and the calorie which are indispensable for a care recipient and an elderly person.
  • the present inventors are able to solve the problem by adopting a method for producing canned foods as a method for achieving both the prevention of shape loss during the production and sale of enzyme softened foods and the form capable of being distributed at room temperature or chilled. I found it.
  • a method for producing canned foods as a method for achieving both the prevention of shape loss during the production and sale of enzyme softened foods and the form capable of being distributed at room temperature or chilled.
  • the foodstuff since the foodstuff is placed in the distribution container during the manufacturing process, it does not lose its shape, and it is not necessary to move the foodstuff itself, thereby greatly reducing the manufacturing cost.
  • a degrading enzyme or thickener can be used inside the food as much as possible. It has been found that a vacuum sealing method or a pressure sealing method is suitable as a uniform treatment.
  • a vacuum sealing method or a pressure sealing method is suitable as a uniform treatment.
  • seafood it has been found that not only the edible portion but also the bone can be softened while maintaining the shape at the level for those who are difficult to chew and swallow. Based on this knowledge, the present invention has been completed.
  • the following inventions (1) to (20) are provided.
  • (1) comprising a hard container, and ingredients, degrading enzymes, and seasoning liquid contained in the hard container;
  • the hardness of the foodstuff softened while maintaining the original shape is 1.0 ⁇ 10 2 N / m 2 or more and 1.0 ⁇ 10 7 N / m 2 or less (1) or (2) Food in a hard container as described in 1.
  • the viscosity of the liquid in the hard container is 5 mPa ⁇ s or more and 20 Pa ⁇ s or less or a gel state in a fluid sol state when measured at 20 ° C. with a B-type viscometer.
  • the food in a hard container according to any one of 1) to (3).
  • the said seasoning liquid contains at least 1 sort (s) selected from the group which consists of salt, an amino acid, fats and oils, a thickener, a medical contrast agent, saccharides, sodium hydrogencarbonate, a vitamin, and a mineral, (1) Food in a hard container according to any one of (4) to (4).
  • s selected from the group which consists of salt, an amino acid, fats and oils, a thickener, a medical contrast agent, saccharides, sodium hydrogencarbonate, a vitamin, and a mineral
  • the hard container is at least one selected from the group consisting of metal cans, bottles, and heat-resistant molded containers.
  • a method of manufacturing food containing food (11) The method for producing a food in a hard container according to (9), wherein the hard container is sealed before the enzyme reaction step or before the enzyme deactivation. (12) The method for producing a food in a hard container according to (11), wherein a pressurizing process or a depressurizing process is performed on the food before the sealing process of the hard container. (13) The hard enzyme according to any one of (8) to (12), wherein the decomposing enzyme has an enzyme activity for decomposing at least one substrate selected from the group consisting of carbohydrates, proteins, and lipids. A method for producing food.
  • the seasoning liquid contains at least one selected from the group consisting of sodium chloride, amino acids, fats and oils, thickeners, medical contrast agents, sugars, sodium bicarbonate, vitamins, and minerals (14) Or the manufacturing method of the foodstuff in a hard container as described in (15).
  • a liquid or gaseous gas component Before sealing the hard container, by adding a liquid or gaseous gas component to increase the pressure in the hard container after sealing, or by degassing the air in the container and reducing the pressure in the hard container after sealing.
  • the hardness of the food material softened while maintaining the original shape is 1.0 ⁇ 10 2 N / m 2 or more and 1.0 ⁇ 10 7 N / m 2 or less (8) to (18)
  • (20) The food in a hard container according to any one of (8) to (19), wherein the hard container is at least one selected from the group consisting of metal cans, bottles, and heat-resistant molded containers. Production method.
  • the following method can be cited as an invention for performing all steps of the enzyme impregnation step, the enzyme reaction step, the enzyme deactivation step, and the sterilization step in the bottle can.
  • energy such as external pressure is not used, but the pressure change in the bottle can is used as the enzyme impregnation energy.
  • a food material to be softened is immersed, sprayed, or applied in an enzyme solution to attach a degrading enzyme to the surface of the food material, and then sealed in a hard container.
  • the hard container can adopt the same sealing method as a normal can.
  • it may be a method in which the enzyme solution is applied, or the food and enzyme solution are filled and hermetically sealed, or a vacuum squeezing method or a high vacuum can method in which a hard container is vacuumed (reduced pressure) when sealed is used. You can also.
  • it can be sealed under pressure by adding gas or sodium hydrogen carbonate at the time of sealing.
  • the temperature is slowly increased from low or normal temperature, and finally heated to the retort sterilization temperature.
  • the foodstuff expands or generates steam in the can, and the internal pressure increases, so the enzyme and seasoning in the vicinity of the surface gradually permeate the foodstuff due to pressure, adsorption and osmotic pressure effects. Seasonings spread.
  • the internal pressure can be increased by adding a small amount of liquid nitrogen at the time of sealing.
  • the adoption of a high-vacuum can has a synergistic effect that the enzyme is effectively infiltrated into the center of the food by the enzyme impregnation by the pressure reduction treatment at the time of sealing and the internal pressure from the low temperature due to the decrease in the saturated vapor pressure in the container accompanying the pressure reduction sealing. You can also get
  • the enzyme reaction continues in the temperature zone where the enzyme activity remains, and the food material softens. In a rigid container, no physical pressure is applied from the outside to the inside, so that the shape is maintained.
  • the enzyme protein denaturation temperature for example, 70 ° C. to 100 ° C.
  • the enzyme is deactivated and some microorganisms are sterilized.
  • the temperature is further raised and the temperature exceeds 110 ° C., spore germination begins, and retort sterilization is completed by pressurizing and heating at a high temperature around 120 ° C. for a certain period of time.
  • the sterilization temperature may be 100 ° C.
  • Hardness control is determined by the temperature rise rate, enzyme concentration, heating time, and cooling rate.
  • the temperature rise rate can be changed freely. That is, the present invention allows the enzyme impregnation using the pressure change in the bottle or the can, and the enzyme reaction, enzyme deactivation and sterilization can be performed by heating the food in the container as it is. All of low cost, prevention of shape loss, hygiene, and normal temperature distribution can be achieved.
  • the following method is given as an invention in which a part of the enzyme reaction step, the enzyme deactivation step, and the sterilization step is performed in a hard container. After applying external pressure energy such as pressurization or depressurization to food, put it in a jar or canned container before softening, and let the bottle canned container perform enzyme reaction, enzyme deactivation, sterilization process, during the manufacturing process.
  • the present inventors have also made an invention that can prevent the loss of shape during transportation and handling of retail stores. This method has an effect that the softened state can be visually observed.
  • the enzyme reaction step, the enzyme deactivation step, and the sterilization step are performed in a hard container, after the food material impregnated with the enzyme in advance by a method such as pressurization or decompression is put in the hard container, or the hard container After the enzyme impregnation by a method such as pressurization or decompression, an enzyme reaction step, an enzyme deactivation step, and a sterilization step are performed.
  • the hard container can be sealed before or after the enzyme reaction. Although it can be transferred to a hard container even after the enzyme deactivation process, the food is softened, so care must be taken in handling.
  • the enzyme impregnation must be performed before sealing, but a seasoning and a thickener can be added before and after the enzyme reaction, so that the seasoning, viscosity, and hardness can be easily adjusted as appropriate.
  • the temperature of the bottle or canned container can be raised either in a sealed state or in an open state, but is preferably before the enzyme reaction step from a hygienic aspect. As each temperature increase condition, an optimum condition can be selected in each step of enzyme reaction, enzyme deactivation, and sterilization.
  • the present invention has the following effects.
  • the present invention is a technique that can provide a nursing care food that looks the same as a general meal that is generally provided. Elderly people who have reduced chewing and swallowing ability and normal healthy people Although it is different, it is a technology that realizes “barrier-free food” from the viewpoint of being able to eat meals that look the same.
  • the shape-maintaining softening technology using a degrading enzyme that has been reported so far has not been able to soften the bones of seafood. It is known that bone is softened by pressure treatment, but it is not realistic from the viewpoint of shape retention to process by impregnating enzyme impregnation, enzyme reaction, and enzyme-deactivated food material into a heat-resistant container. In the shape-maintained softened food that is continuously processed until the inactivation of the heating enzyme with soft packaging material, it is theoretically possible to soften the bone by using pressure-resistant soft packaging material. It is not possible to guarantee the shape retention. According to the present invention, it has become possible to produce a shape-retained softened food that can be distributed and stored at room temperature and softened while maintaining the shape of not only seafood but also bone.
  • the product of the present invention is extremely effective as an emergency food and stockpile during a natural disaster as a food for nursing care because it enables distribution at room temperature.
  • lifelines such as electricity, gas, and water supply ceased, and frozen products that require frozen storage or dried products that require water during use may not be usable.
  • preservative foods for soft stockpile for those with difficulty in chewing / swallowing, weaning infants, and the elderly are not widespread, and there are few choices of meals, which makes me very hard.
  • the product of the present invention can be provided only as an emergency food or a food for storage in the event of a disaster, so that only a weak person who is difficult to chew and difficult to swallow can provide a delicious meal.
  • the method for producing a shape-retaining softened food that can be distributed at normal temperature or chilled according to the present invention includes an enzyme impregnation step in which a degrading enzyme or seasoning is uniformly contained in the food, and a food that retains the shape of the food by the action of the degrading enzyme.
  • the use of a part of the process is a case where a hard container is used after the enzyme reaction process, and the enzyme impregnation process needs to be performed separately in advance, and the enzyme needs to be infiltrated in advance under reduced pressure or pressure.
  • the sealing of the hard container needs to be carried out at any one point between the respective steps, and is characterized by enabling normal temperature distribution by sealing at least before retort sterilization. The difference between retort food and chilled food is determined by the sterilization temperature of the hard container.
  • the hard container used in the present invention is a container capable of preventing the contents from being deformed by an external pressure, and examples thereof include metal cans, bottles, and heat-resistant molded containers.
  • the heat-resistant molded container is, for example, a high-barrier packaging container, which is heat-resistant and inexpensive PP (polypropylene), strength-enhancing NY (nylon), and EVOH (ethylene / vinyl alcohol copolymer resin) as a barrier material.
  • SIO X vapor deposition / alumina vapor deposition PET (polyethylene terephthalate), PVDC (polyvinylidene chloride), etc. are examples of container materials such as plastic materials or opaque packaging containers that are made of a barrier material such as aluminum foil.
  • a plastic material having a high adhesive ability such as polyethylene is used for the sealer portion of the lid.
  • soft packaging material can be used for the lid.
  • the shape and material of the container are not limited as long as the container is a rigid container that does not greatly deform even when subjected to physical pressure from the outside, particularly from the side or the bottom, and can retain the shape of the contents.
  • the food material used in the method for producing a shape-retaining soft food of the present invention may be plant or animal.
  • vegetable ingredients include vegetables such as radish, carrots, beef bowl, salmon, cabbage, Chinese cabbage, celery, asparagus, spinach, Japanese mustard spinach, green pepper, tomatoes, potatoes, potatoes, potatoes, potatoes, etc.
  • Beans such as soybeans, red beans, coffee beans, peas, grains such as rice, wheat, strawberries, strawberries, fruits such as apples, peaches, pineapples, mushrooms such as shiitake mushrooms, shimeji mushrooms, enoki, sea cucumbers, matsutake mushrooms, young cloth, Examples include seaweed such as kelp and hijiki.
  • animal ingredients include mutton, horse meat, venison, salmon, goat meat, salmon, whale meat, their internal organs, and other meats, salmon, salmon, salmon
  • fish such as sea bream, sea bream, sea bream, sea bream, sea bream, shellfish such as sea bream, oyster, scallop, sea bream, and other seafood such as shrimp, crab, squid, octopus and sea cucumber.
  • it may be a paste product such as rice cake, a meat product such as ham / sausage, a processed food such as noodles and pickles. If it is an edible food manufacturing raw material or raw material, it will not be limited to these.
  • These ingredients may be used in the raw state or by heating and cooking such as boiling, baking, steaming and frying. Microwave heating or superheated steam treatment may be used. Moreover, saturated steam heating may be used.
  • the temperature for heating is not particularly limited, but it is preferably 60 ° C. or higher, preferably 65 ° C. or higher for the purpose of denaturing the endogenous protein. In high-temperature processing such as baking, it is necessary to determine the heating temperature and the heating time in consideration of quality deterioration such as color and fragrance due to heating.
  • these foods can be used frozen or frozen / thawed. Further, the food material may be used after pretreatment such as boiling with an aqueous solution in which an organic acid such as salt or citric acid and its salt are dissolved.
  • a method such as the use of a device that pierces a needle such as a cleaver or a partial pressing with a roller.
  • the shape of the food may be either a lump or a bite size, but the size of the food can be selected as appropriate, the shape of the original food is retained, and the shape of the raw material can be confirmed, And it must be appetizing for those who have difficulty chewing or swallowing.
  • the target food of the present invention is preferably a food lump having a thickness of 5 mm or more and a volume of 500 mm 3 or more, but is not limited to molded products, noodles, green vegetables and beans.
  • the degrading enzyme used in the present invention may be any protein, carbohydrate, or fat degrading enzyme, and may be appropriately selected according to the condition of the ingestor, the enzyme substrate contained in the food to be used, and the like. it can. Mainly, an enzyme containing an enzyme activity of any one of pectinase, amylase, protease, glucanase or cellulase is used.
  • starch such as protease, peptidase and other enzymes that degrade proteins into amino acids and peptides, amylase, glucanase, cellulase, pectinase, pectinesterase, hemicellulase, ⁇ -glucosidase, mannase, xylanase, alginate lyase, chitosanase, inulinase, chitinase, etc.
  • Examples thereof include enzymes that decompose polysaccharides such as cellulose, inulin, glucomannan, xylan, alginic acid, and fucoidan into oligosaccharides or monosaccharides, and enzymes that decompose fat such as lipases. These may be used alone or in combination of two or more within a range not inhibiting each other.
  • an amino acid or a peptide can be generated and the taste can be improved by using protease or peptidase.
  • transglutaminase or the like can be used to improve the texture.
  • decomposing enzymes those derived from plants, animals, and microorganisms can be used.
  • a form of the degrading enzyme a powdered form, a liquid form, or a substance contained in a dispersion may be used.
  • the degrading enzyme solution it can be used as it is or diluted in the case of a liquid degrading enzyme preparation.
  • the degrading enzyme is dissolved or dispersed in a solute such as water. It can be used in the state.
  • the pH of the decomposing enzyme solution is preferably in the range of pH 3 to pH 10, more preferably pH 4 to pH 8. It can also be adjusted to the optimum pH of an enzyme with high enzyme activity, and can be adjusted to the same pH as the food.
  • an organic acid such as citric acid and a pH adjusting agent such as a salt or phosphate thereof can be used, and a pH-adjusted seasoning solution or the like can also be used.
  • the amount of the degrading enzyme used can be changed depending on the heating speed and heating conditions of the hard container. It can be appropriately selected depending on the degree of softening and the degree of generation of the taste component.
  • a degrading enzyme for example, a range of 0.001 to 1.0 g can be mentioned with respect to 100 g of food.
  • the decomposing enzyme can be used by dissolving or dispersing in a range of 0.01 to 3.0% by mass with respect to the solvent solution.
  • thickeners such as thickening polysaccharides, and other nutrients can be added.
  • thickeners such as starch, curdlan, agar, guar gum or xanthan gum
  • thickeners such as pectin and carboxymethylcellulose
  • water release from foods can be suppressed during chewing, and suitable foods for people with difficulty in swallowing It can also be.
  • the thickener can be used by dissolving in water, but when added at the same time as the enzyme, it does not undergo enzymatic degradation and is not dissolved in water in order to avoid reducing the enzyme impregnation effect due to viscosity.
  • the seasoning liquid before sealing the hard container is preferably so that the contents are easily diffused or the viscosity is low.
  • the measurement at 20 ° C. with a B-type rotational viscometer preferably 200 mPa ⁇ s or less, more preferably 20 mPa ⁇ s or less, and even more preferably 1 mPa ⁇ s or more and 5 mPa ⁇ s or less.
  • the thickener serves to prevent the food from being deformed by functioning as a buffer for the food in the hard container.
  • a viscous edible oil can also be used as a buffering action.
  • the viscosity of the liquid in the hard container after the sterilization process is preferably 5 mPa ⁇ s or more in a fluid sol state as measured at 20 ° C. with a B-type rotational viscometer (manufactured by Tokyo Keiki). 20 Pa ⁇ s or less, more preferably 100 mPa ⁇ s or more and 10 Pa ⁇ s or less, and further preferably 300 mPa ⁇ s or more and 1 Pa ⁇ s or less.
  • the viscosity condition is not limited to this, and a material according to the vibration condition and the condition of the eating person may be prepared.
  • the state of the thickener at 20 ° C. may be a gel state, but it may be easy to lose its shape when taken out from the container, so it is desirable to use a container that is easy to take out.
  • substances that increase nutritional value such as sugars, fats, vitamins, and minerals
  • substances that increase nutritional value such as sugars, fats, vitamins, and minerals
  • saccharides monosaccharides, sugar alcohols such as sorbitol and xylitol, and disaccharides such as maltose and trehalose are preferable.
  • fats and oils are effective for calorie strengthening, and by emulsifying and using fats and oils, the concentration of introduction into foods can be increased and high-calorie foods can be obtained.
  • protease is used as a degrading enzyme, but the texture and taste can be changed by adding lipase to decompose fats and oils. In this case, the softening effect can be further enhanced by performing tumbling or punching with a needle in advance.
  • a contrast agent can be added as a substance to be added to the hard container. In this case, it can be used as a swallowing or digestive organ contrast examination food.
  • a medical contrast agent used in the medical test meal of the present invention a medical contrast agent that can be imaged by irradiation with active energy rays by a medical projection apparatus such as X-ray imaging, CT, MRI, and PET is suitable.
  • Such a medical contrast agent include iopamidol, bipypark, iohexol, ioversol, iomeprol, iopromide, ioxirane, iotrolane, amidotrizoic acid, meglumine iotalamate, iotalamic acid, oxaglucic acid, meglumine iotroxate, iodized poppy oil
  • examples thereof include fatty acid ethyl esters, iopanoic acid, amidotrizoic acid, barium sulfate, meglumine gadopentetate, gadoteridol, iron ammonium citrate, fermoxides and the like.
  • the content of the medical contrast agent depends on the type of food and food material. For example, the content of the contrast agent in the enzyme solution contained in the container with respect to 100 g of the food is 10 to 60 g, preferably 30 to 50 g. It can be.
  • the metal can used can be a container used for ordinary canned food, and tin, steel, and aluminum are suitable. In order to prevent corrosion, it is possible to apply an inner coating, use a container, or wrap with sulfuric acid paper and seal it.
  • the bottle is preferably a heat-resistant bottle with a metal lid.
  • the internal pressure in the can during the enzyme impregnation step can be further increased by adding a gas component such as nitrogen, air, carbon dioxide or the like in liquid or gaseous form immediately before sealing.
  • a gas component such as nitrogen, air, carbon dioxide or the like in liquid or gaseous form immediately before sealing.
  • an inert gas having low reactivity such as nitrogen in order to improve the quality such as oxidation prevention.
  • the pressure in the tube at the time of sealing may be 90 KPa or less. However, a higher effect can be obtained at a setting of 50 KPa or less, preferably 30 KPa or less, more preferably 20 KPa or less.
  • Heating is possible from any starting temperature, whether the product temperature is as low as 10 ° C. or less or from room temperature. As the temperature rises, the vapor pressure rises and the internal pressure rises due to the expansion effect of the food material. The enzyme solution and the like penetrate into the food material due to the pressure, adsorption and osmotic pressure effects, and the enzymatic reaction also proceeds. This is the enzyme impregnation step and the enzyme reaction step.
  • a temperature zone below room temperature preferably 0.1 ° C./min to 10 ° C./min, more preferably 0.1 ° C./min to 5 ° C./min, the softening of the food material is gentle and uneven, and the enzyme reaction Can be made. Softening occurs when the temperature is increased at 10 ° C./min or more, but is difficult to soften if the passage time is fast.
  • the enzyme reaction is preferably performed at 0 to 70 ° C, more preferably 30 to 65 ° C. Enzyme permeation rate and enzyme degradation rate accompanying internal pressure can be increased at 50 to 65 ° C. Therefore, it is necessary to set the temperature rise rate, the holding temperature time, etc. according to the target hardness and the tolerance range of the hardness variation.
  • the product temperature exceeds 70 ° C., the enzyme deactivation process is started with most enzyme agents. After this step, increasing the temperature as soon as possible leads to cost reduction, quality and hardness stability.
  • the enzyme is partially inactivated at 65 ° C, but the microorganisms start to die, and commercial sterilization ends at about 85 ° C for foods with a pH of 4.5 or lower.
  • spore bacteria begin to die when the temperature exceeds 110 ° C.
  • retort sterilization is completed by pressurizing and heating at a high temperature of preferably 110 ° C. to 135 ° C., more preferably 115 ° C. to 125 ° C. for a certain period of time. . Since all the processes are performed in a hard container, it is low-cost, hygienic, and hardly loses its shape.
  • the container after retort sterilization can suppress the hardness variation by lot by implementing the cooling process by air cooling or water cooling.
  • a separate processing device in advance and season with enzyme impregnation or enzyme by methods such as pressurization or decompression. It is necessary to prepare foods impregnated with auxiliary materials such as materials, thickeners, sugars, emulsified oils and fats, but in order to put them into a container without losing shape while maintaining the shape, the initial stage of enzyme reaction It is preferable to put the hard food material at the stage into the container, but it is sufficient if it can be put into the hard container so as not to lose its shape.
  • the method of impregnating with the enzyme is preferably a method of pressure treatment by immersing the decomposition-containing enzyme solution or spraying the decomposition enzyme-containing solution, or a method of removing the pressure from the enzyme solution after immersion in the decomposition enzyme solution, and the like. This does not apply as long as the enzyme is attached. Thereafter, an enzyme reaction step, an enzyme deactivation step, and a sterilization step are performed.
  • the rigid container is sealed before or after the enzyme reaction. Although it is possible even after the enzyme deactivation step, before the enzyme reaction is more preferable for the purpose of the food being softened and easily deformed, and hygienic treatment.
  • the pressure treatment before sealing the bottle or canned container varies depending on the enzyme concentration, but the enzyme in the enzyme solution is 0.2%, and in the case of pressurization, it is preferably 1 MPa to 100 MPa, more preferably 10 MPa to 20 MPa. However, the same effect can be obtained at higher pressures. In the case of reduced pressure, the pressure may be 90 KPa or less, but a higher effect can be obtained with a setting of 50 KPa or less, preferably 30 KPa or less, more preferably 20 KPa or less, and a higher effect can be exhibited.
  • the method of transferring the food to a canned or bottled container is that the ingredients such as seasonings and thickeners different from the enzyme seasoning liquid to be impregnated in the food can be added at the time of sealing.
  • the ingredients such as seasonings and thickeners different from the enzyme seasoning liquid to be impregnated in the food can be added at the time of sealing.
  • seasonings and thickeners different from the enzyme seasoning liquid to be impregnated in the food can be added at the time of sealing.
  • the thickener has an effect as a buffer material for the food in the hard container, but its viscosity may interfere with enzyme permeability due to enzyme impregnation.
  • a creep meter (manufactured by Yamaden Co., Ltd.) is used as a hardness suitable for foods for the elderly or those who have difficulty chewing or swallowing hard container products.
  • the breaking strength in RE2-30005B it is preferably 1.0 ⁇ 10 2 N / m 2 or more and 1.0 ⁇ 10 7 N / m 2 or less, more preferably 1.0 ⁇ 10 3 N / m. It is preferable to adjust to 2 or more and 1.0 ⁇ 10 6 N / m 2 or less, more preferably 1.0 ⁇ 10 3 N / m 2 or more and 1.0 ⁇ 10 4 N / m 2 or less.
  • Example 1 It was boiled for 10 minutes with boiling water in which 0.1% of vitamin C was added to bamboo shoots, carrots cut into 5 mm thickness and 20 mm ⁇ 20 mm, lotus root cut into 5 mm thickness, and burdock. The chicken thighs cut to cut the fiber into bite-sized pieces were used as they were. In tin cans, ingredients, enzymes (Orientam, HB, 0.3% by mass, Papain W-40, Amano Enzyme, 0.3% by mass) and amino acid seasoning, salt, sugar, mirin, soy sauce are dissolved in small amounts.
  • the hardness As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained foodstuff, the hardness was 5 ⁇ 10 4 N / m 2 or less, and it was soft enough for people with difficulty in chewing. became. The shape remains the same and the canned food is easy to eat for care recipients. However, when it was vibrated, the shape of the food material was easily broken due to insufficient viscosity of the seasoning liquid.
  • Example 2 (Comparison) It was boiled for 10 minutes with boiling water in which 0.1% of vitamin C was added to bamboo shoots, carrots cut into 5 mm thickness and 20 mm ⁇ 20 mm, lotus root cut into 5 mm thickness, and burdock. The chicken thighs cut to cut the fiber into bite-sized pieces were used as they were.
  • Retort pouch with ingredients, enzymes (Orientam, HI, 0.3% by weight, Papain W-40, Amano Enzyme, 0.3% by weight) and amino acid seasoning, salt, sugar, mirin, soy sauce A dissolved aqueous solution (viscosity measured with a B-type rotational viscometer at 20 ° C .: 3 mPa ⁇ s) was added and sealed.
  • Example 3 A lotus root, squid, taro, carrot, chicken, and pork cut to a thickness of 10 mm were heated at 95 ° C. using steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.).
  • ingredients 1.0% by mass of enzyme (hemicellulase “Amano” 90 and papain (manufactured by Amano Enzyme)), commercially available seasoning (2%), pH adjuster (citric acid 0.1% and its sodium salt 0) 0.8%) and an aqueous solution in which salt (2%) is dissolved (viscosity measured by a B-type rotary viscometer at 20 ° C .: 3 mPa ⁇ s) is put in a tin can, and vacuum packaging machine (V-280A manufactured by TOSEI Co., Ltd.) ) Arranged in the inner tray, and reduced pressure (degree of vacuum 95%, 5 minutes).
  • the canned product returned to normal pressure was sealed after adding 5% by weight of an aqueous solution of modified starch (viscosity measured at 20 ° C. using a B-type rotary viscometer: 900 mPa ⁇ s), and a pressurized heat sterilizer (Autoclave SR-240). , Manufactured by Tommy Seiko Co., Ltd.).
  • the hardness breaking strength with a creep meter RE2-30005B
  • the hardness was 5 ⁇ 10 4 N / m 2 or less, which was sufficiently soft for those having difficulty in chewing.
  • the shape of the food is good and the flavor is good, and it has become a room-temperature-distributed food that is easy to eat for care recipients. There was no loss of shape due to vibration.
  • Example 4 Slices of green beans, spinach, soybeans, and salmon bones into slices, and ingredients, enzyme (Macero Team 2A, Yakult Pharmaceutical 0.3% by mass, Papain W-40, Amano Enzyme, 0.3% by mass) ) And an amino acid seasoning, salt, sugar, mirin, soy sauce and curdlan solution in small amounts (viscosity measured with a B-type rotational viscometer at 20 ° C .: 1000 mPa ⁇ s), and liquid in tin can Two drops of nitrogen were added and sealed. Thereafter, it was heated to 60 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.).
  • Example 5 (Comparison) Slices of green beans, spinach, soybeans, and salmon bones into slices, and ingredients, enzyme (Macero Team 2A, Yakult Pharmaceutical 0.3% by mass, Papain W-40, Amano Enzyme, 0.3% by mass) ) And an amino acid seasoning, salt, sugar, mirin, soy sauce and curdlan solution each in small amounts (viscosity measured with a B-type rotational viscometer at 20 ° C .: 1000 mPa ⁇ s), and sealed with a retort pouch . Thereafter, it was heated to 60 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.).
  • Example 6 Squid (thick skinned), octopus (thickness 1 cm), and taro were heated with boiling water for 10 minutes. Squid and octopus used a meat tenderizer (Jacquard riser MODELH) in advance. Thereafter, 0.5% by mass of enzymes (Pectriase (Nippon Chemical) and papain (manufactured by Amano Enzyme) and 1 teaspoon of commercially available seasoning, emulsified oil (30%), and salt (1%) were dissolved in water.
  • enzymes Pectriase (Nippon Chemical) and papain (manufactured by Amano Enzyme)
  • the sample was soaked in an enzyme solution adjusted to pH 6.0 with a citrate buffer solution for 5 minutes, and then an aqueous solution containing ingredients, curdlan, agar, and trehalose (measured with a B-type rotational viscometer at 20 ° C. (Viscosity: 800 mPa ⁇ s) was placed in a tin can and placed in a tray in a vacuum packaging machine (V-280A manufactured by TOSEI Co., Ltd.), and pressure reduction (degree of vacuum 95%, 5 minutes) was performed. The canned product was sealed, and rapidly heated to 124 ° C.
  • Example 7 Bone mackerel and curdlan, 1 teaspoon soy sauce, 1 teaspoon seasoning, starch, 0.5% by weight enzyme (papain, Amano Enzyme), emulsified oil (30%), salt (1%), dissolved in water
  • enzyme papain, Amano Enzyme
  • emulsified oil (30%)
  • salt 1%
  • the sample was immersed in an enzyme solution adjusted to pH 6.0 with a citrate buffer (viscosity measured with a B-type rotational viscometer at 20 ° C .: 700 mPa ⁇ s) for 5 minutes.
  • the hardness As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained food material, the hardness was 5 ⁇ 10 4 N / m 2 or less, which was sufficiently soft for those having difficulty in chewing.
  • the shape was good as it was and the mackerel bones were softened. It has become a room temperature food that is easy to eat for the care recipient. There was no loss of shape due to vibration.
  • Example 8 Bone mackerel, carrot, burdock and 1 teaspoon of soy sauce, 1 teaspoon of seasoning, 0.05% by mass of enzyme (papain, Amano Enzyme, Pectinase, Shin Nippon Chemical), salt (1%), dissolved in water
  • the solution was adjusted to pH 6.0 with a citrate buffer solution and added to an enzyme solution (viscosity measured with a B-type rotational viscometer at 20 ° C .: 5 mPa ⁇ s) to which gelled agar (1/2 amount of food) was added. Soaked for a minute. After that, it was put in a tin can and sealed by winding and then decompressed for 2 minutes at 95% vacuum. It was heated to 55 ° C.
  • Example 9 Just after thawing the bite-size 4 ° C whale meat and seasoning, citric acid, enzyme (Bromelain F, Amano Enzyme), 0.2 mass% processed starch dispersion in a bottle container (20 ° C B Using a vacuum packaging machine (V-280A manufactured by TOSEI Co., Ltd.) under reduced pressure (degree of vacuum 95%, 5 minutes). After sealing with a metal lid, it was rapidly heated to 40 ° C. at a rate of 2 ° C./min with steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 40 ° C. for 20 minutes, rapid heating was performed to 110 ° C.
  • V-280A manufactured by TOSEI Co., Ltd.
  • the hardness breaking strength with a creep meter RE2-30005B
  • the hardness was 5 ⁇ 10 4 N / m 2 or less, and it was soft enough for people with difficulty in chewing. became.
  • the viscosity of the liquid in the bottle container was 500 mPa ⁇ s as measured with a B-type rotational viscometer at 20 ° C. There was no loss of shape due to vibration.
  • Example 10 Japanese radish, yellowtail and frozen shrimp cut to 20 mm ⁇ 20 mm with a thickness of 5 mm were placed in a refrigerator at 3 ° C. and the temperature was adjusted for 10 minutes. Contrast agent (Visipark, Vispark, a solution containing 0.3% by mass of Macero Team 2A, 0.3% by mass of Yakult Pharmaceutical Co., Ltd., 0.3% by mass of Bromelain, Amano Enzyme) and amino acid seasoning, salt, sugar, mirin and soy sauce.
  • Contrast agent (Visipark, Vispark, a solution containing 0.3% by mass of Macero Team 2A, 0.3% by mass of Yakult Pharmaceutical Co., Ltd., 0.3% by mass of Bromelain, Amano Enzyme) and amino acid seasoning, salt, sugar, mirin and soy sauce.
  • Example 11 It was boiled for 10 minutes with boiling water in which 0.1% of vitamin C was added to bamboo shoots, carrots cut into 5 mm thickness and 20 mm ⁇ 20 mm, lotus root cut into 5 mm thickness, and burdock. The chicken thighs cut to cut the fiber into bite-sized pieces were used as they were.
  • Tin cans with ingredients, enzymes (Orientam HP, 0.2% by HI, PAPAIN W-40, 0.2% by Amano Enzyme) and amino acid seasoning, salt, sugar, mirin, soy sauce, baking soda A dissolved aqueous solution (viscosity measured with a B-type rotational viscometer at 20 ° C .: 5 mPa ⁇ s) was added, and the mixture was wound and sealed while degassing. Thereafter, it was heated to 60 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 60 ° C. for 10 minutes, rapid heating to 124 ° C.
  • enzymes Orientam HP, 0.2% by HI, PAPAIN W-40, 0.2% by Amano Enzyme
  • amino acid seasoning salt, sugar, mirin, soy sauce
  • baking soda A dissolved aqueous solution viscosity measured with a B-type rotational vis
  • Example 12 Commercial raw beef was cut into 15 mm ⁇ 15 mm ⁇ 15 mm and frozen at ⁇ 15 ° C. Next, trehalose 1% by mass, contrast agent (trade name: Vigipark 270) 33% by mass, papain W-40 (0.5%), modified starch 0.05% by mass and curdlan 0.1% by mass in a bottle container An aqueous solution (viscosity measured by a B-type rotational viscometer at 20 ° C .: 20 mPa ⁇ s) and beef were placed and immersed for 10 minutes at room temperature to be thawed.
  • the bottle is deaerated and sealed, and heated in hot water at a rate of 0.2 ° C./min until reaching a temperature of 60 ° C., and then heated to 118 ° C. with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.) Heating was performed for 30 minutes under pressure and heat sterilization to obtain a shape-maintaining softened medical test meal.
  • a pressure heat sterilizer Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.
  • Heating was performed for 30 minutes under pressure and heat sterilization to obtain a shape-maintaining softened medical test meal.
  • the bottle was opened and the food material was observed with a sensory and X-ray microscope (XGT-5000, manufactured by Horiba Seisakusho). It was soft enough to be consumed even by those with difficulty in swallowing and was uniformly impregnated with the contrast medium. Loss of shape due to vibration occurred.
  • Example 13 A lotus root, squid, taro, carrot, chicken, and pork cut to a thickness of 10 mm were heated at 95 ° C. using steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). Then, ingredients, 1.0% by mass of enzyme (hemicellulase “Amano” 90 and papain (manufactured by Amano Enzyme)), commercially available seasoning (2%), pH adjuster (citric acid 0.1% and its sodium salt 0) .8%) and sodium chloride (2%) in an aqueous solution, put them in a heat-resistant molding container, and arrange them on a tray in a vacuum packaging machine (V-280A manufactured by TOSEI Co., Ltd.).
  • V-280A manufactured by TOSEI Co., Ltd.
  • Reduced pressure degree of vacuum 95%, 5 minutes
  • aqueous solution containing 0.1% by weight of each modified starch, agar, gelatin, and xanthan gum (viscosity measured with a B-type rotational viscometer: 1 Pa ⁇ s)
  • the main component is polyethylene-aluminum.
  • the film as a constituent component was thermocompression-bonded and sealed, and heated at 95 ° C. for 30 minutes with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.) to produce a food for chilled food.
  • a pressure heat sterilizer Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.
  • the hardness As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained food material, the hardness was 5 ⁇ 10 4 N / m 2 or less, which was sufficiently soft for those having difficulty in chewing.
  • the shape of the food is good and the flavor is good, and it has become a room-temperature-distributed food that is easy to eat for care recipients. Loss of shape due to vibration occurred.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Microbiology (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Mechanical Engineering (AREA)
  • Mycology (AREA)
  • Pediatric Medicine (AREA)
  • Pest Control & Pesticides (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Storage Of Fruits Or Vegetables (AREA)

Abstract

[Problem] To provide: a food packaged in a hard container for normal-temperature or chilled distribution use, which can be produced at low cost and by a simple procedure without requiring the use of any specialized apparatus, and in which a softened food material can be packaged while keeping the shape thereof; and a method for producing the food. [Solution] A food packaged in a hard container for normal-temperature or chilled distribution use can be developed by: a method in which a food material, a degrading enzyme and a seasoning solution are packaged in a hard container, the hard container is warmed in a hermetically sealed state to achieve an enzyme impregnation step and an enzymatic reaction step in the hard container, and then the hard container is heated without any modification to achieve the entire process of an enzyme deactivation step and a sterilization step in the hard container; or a method in which the degrading enzyme is introduced into the food material and then the enzymatic reaction step, the enzyme deactivation step and a part of the sterilization step are achieved in the hard container.

Description

硬質容器入り食品およびその製造方法Food in hard container and method for producing the same
 本発明は、硬質容器入り食品およびその製造方法に関する。より詳細には、本発明は、食材の元の形状を保持したまま硬さ調節された食品で、製造工程または輸送中の型くずれを防止した常温流通またはチルド流通用硬質容器入り食品およびその製造方法に関する。本発明は、硬質容器内で酵素含浸、酵素反応、酵素失活、低温殺菌またはレトルト殺菌する、または食材を圧力で酵素含浸した後酵素反応により軟化する前に食材を容器に入れ、硬質容器内で酵素反応、酵素失活、低温殺菌またはレトルト殺菌することで、型崩れ防止しながら形状保持軟化食品の低コスト、衛生的製造を可能とした。さらに、製造時または流通時の振動等による食材の型崩れを防止し形状を崩すことなく常温流通またはチルド流通させることを可能とした。 The present invention relates to a food in a hard container and a method for producing the same. More specifically, the present invention relates to a food in which the hardness is adjusted while maintaining the original shape of the food, and the food in a hard container for distribution at normal temperature or chilled distribution that prevents mold deformation during the manufacturing process or transportation, and a method for manufacturing the same. About. In the present invention, enzyme impregnation, enzyme reaction, enzyme deactivation, pasteurization or retort sterilization in a hard container, or food is put in a container before softening by enzyme reaction after impregnation of the food with enzyme under pressure, The enzyme reaction, enzyme deactivation, pasteurization, or retort sterilization enabled low-cost, hygienic production of shape-retaining softened food while preventing loss of shape. In addition, the food material can be prevented from being deformed due to vibrations during production or distribution, and can be distributed at normal temperature or chilled without breaking the shape.
 食材の内部に酵素を導入する発明として、食材を凍結して食材に緩みを与えた後、減圧または加圧操作により酵素を急速に含浸させる方法、加熱した食材を圧力により酵素を含浸させる方法、飽和蒸気で加熱した後減圧酵素含浸する方法または動物食材にあっては予め蒸気加熱などを行い組織に緩みを与えた後、減圧操作により酵素を急速に含浸させる方法がある。また、タンブリングやインジェクション法など専用装置を使用して物理的衝撃や注入により酵素を導入する方法も知られている。これらは、真空缶や真空冷却機、あるいは真空包装機を使用し、また静水圧よる加圧装置、真空タンブラーやインジェクター装置により酵素を導入している。いずれも、食材内部に酵素を導入する方法であり、これら酵素含浸技術により、形状を保持したまま食材を軟らかく加工することができる。しかし、これら軟化食材は、その軟らかさ故に、製造工程中、例えば加熱、調味、容器詰め、包装、移動、輸送中、あるいは小売業者での取り扱い中に型崩れしやすく、製品の特徴である見た目に形状や見た目のおいしさが失われる。特に製造工程中では、酵素軟化後の型崩れ防止のため、酵素による軟化を行った後は冷凍状態にして、容器詰め、包装を行う必要がある。または流通も冷凍品として流通させる方法が採用されている。 As an invention for introducing an enzyme into a food material, after freezing the food material and giving the food a slack, a method of rapidly impregnating the enzyme by decompression or pressurizing operation, a method of impregnating the heated food material with the enzyme by pressure, There is a method of impregnating with a reduced pressure enzyme after heating with saturated steam, or a method of rapidly impregnating an enzyme with a decompression operation after applying heat to the tissue in advance to loosen the tissue. In addition, a method of introducing an enzyme by physical impact or injection using a dedicated device such as tumbling or injection is also known. These use a vacuum can, a vacuum cooler, or a vacuum packaging machine, and introduce an enzyme by a pressurizing device using a hydrostatic pressure, a vacuum tumbler, or an injector device. In either case, the enzyme is introduced into the food material, and the food material can be processed softly while maintaining its shape by the enzyme impregnation technique. However, because of their softness, these softened foods tend to lose shape during the manufacturing process, for example, during heating, seasoning, packaging, packaging, moving, transporting, or handling at retailers, and they are characteristic of the product. The shape and appearance are lost. In particular, during the manufacturing process, in order to prevent loss of shape after softening of the enzyme, it is necessary to pack it in a frozen state after packaging with an enzyme and then pack it in a package. Alternatively, a method of distributing the product as a frozen product is adopted.
 これまでに、植物性食品素材の組織内へ急速酵素を導入する方法(特許文献1)や、調味液の塩分濃度等を調整した酵素液に、凍結及び解凍した植物性食品を浸漬して減圧操作して酵素を組織に導入し、型崩れなく調味及び加圧加熱殺菌する方法(特許文献2)が示されている。特許文献1は、酵素の急速導入方法に関するもので、形状保持軟化食材の製造については示されていない。一方、特許文献2は形状保持軟化食材に関するレトルト食品の製造方法であるが、レトルト(加圧加熱殺菌)工程中における型崩れを防止するための発明であって、製造工程中の軟化食材の取り扱いまたは輸送中、小売店販売などにおける型崩れについて全く言及されていない。すなわち、レトルト工程中における型崩れ防止法として、食塩を4~5%添加する発明で、製造工程中に取り扱いや輸送、小売店における物理的な取り扱いにおける型崩れを防止ことはできない。特許文献2の(0006)には、加圧加熱殺菌処理前の柔らかさを維持する方法が記載されている。また、実施例の(0018)(0023)にも記載があるように、減圧処理と酵素処理した後、食材をレトルト用フィルムに食材に移し変えてレトルト処理を行っている。硬質容器内で酵素反応から密封工程までを行わせる方法ではないため、食材を軟化した後には形状を崩さないように細心の取り扱いが必須である。 So far, the method of introducing rapid enzymes into the tissue of plant food materials (Patent Document 1) and the frozen and thawed vegetable foods in an enzyme solution with adjusted salt concentration etc. There is a method (Patent Document 2) in which an enzyme is introduced into a tissue by operation and sterilized without losing its seasoning and under pressure and heat. Patent Document 1 relates to a rapid introduction method of an enzyme, and does not show the production of a shape-retaining softened food material. On the other hand, Patent Document 2 is a method for producing a retort food related to a shape-retaining softened food, but it is an invention for preventing the collapse of a mold during a retort (pressure heat sterilization) process, and handling of the softened food during the production process. There is no mention of loss of shape in retail sales during transportation. That is, as a method for preventing the loss of shape during the retort process, 4-5% of sodium chloride is added, and it is not possible to prevent the loss of shape during handling, transportation, and physical handling in the retail store during the manufacturing process. Patent Document 2 (0006) describes a method of maintaining the softness before pressure heat sterilization. Further, as described in Examples (0018) and (0023), after the decompression treatment and the enzyme treatment, the retort treatment is performed by transferring the food material to the retort film. Since it is not a method of performing the process from the enzyme reaction to the sealing process in a hard container, careful handling is essential so as not to break the shape after the food is softened.
 また、この酵素導入技術を厨房施設等の現場で簡便に実施でき、また軟化させた食品素材の製造工程・搬送・流通過程での型崩れが防止でき、あるいは衛生面の配慮から、食品素材への酵素導入、酵素反応、加熱工程を同一の包装容器の中で実施できる調理食品の製造方法(特許文献3)が知られている。さらに、飽和水蒸気で加熱した後、酵素液中で減圧処理する方法(特許文献4)なども開示されている。いずれも、減圧または加圧などの外部圧力を利用して酵素等を食材内に導入している。 In addition, this enzyme introduction technology can be easily implemented at the site of kitchen facilities, etc., and can be prevented from losing its shape during the manufacturing process, transportation and distribution process of softened food materials, or it can be applied to food materials due to hygiene considerations. There is known a method for producing cooked food (Patent Document 3) in which the enzyme introduction, enzyme reaction, and heating step can be carried out in the same packaging container. Furthermore, after heating with saturated water vapor | steam, the method (patent document 4) etc. which carry out pressure reduction processing in an enzyme liquid are also disclosed. In either case, an enzyme or the like is introduced into the food using an external pressure such as reduced pressure or increased pressure.
 動物性食品素材では、食品素材を酵素液に浸漬する方法(特許文献5)や、食品素材に酵素含有液をインジェクションしてタンブリングする方法(特許文献6)、食品素材に酵素液を塗布・浸漬して真空包装または加圧処理して酵素を浸透させる方法(特許文献7)等が提案されている。 For animal food materials, a method of immersing the food material in the enzyme solution (Patent Document 5), a method of injecting the enzyme-containing liquid into the food material and tumbling (Patent Document 6), and applying and immersing the enzyme solution in the food material And the method (patent document 7) etc. etc. which permeate | transmit an enzyme by vacuum packaging or pressurizing are proposed.
 医療用造影剤検査食の発明として、減圧法で酵素と造影剤を食材内に導入する発明(特許文献8)があるが、これも外部圧力を利用しており、製造後の型崩れは考慮されていない。 As an invention of medical contrast medium test foods, there is an invention (Patent Document 8) in which an enzyme and a contrast medium are introduced into food materials by a decompression method, but this also uses external pressure, taking into account the loss of shape after manufacture. It has not been.
 これらはいずれも酵素液や調味料を食材内部に導入するための方法であり、減圧装置や加圧装置、インジェクション装置、タンブリング装置など、物理的な機械装置を利用している。これら酵素含浸技術により、形状を保持し要介護者の健康維持と生活の質を高めるための、咀嚼・嚥下困難者用食品を製造できる。この食品製造での最重要課題は、如何に低コストで工業的に生産し、流通させるか、とりわけ型崩れが防止でき、かつ常温流通またはチルド流通可能な方法であることが求められている。冷凍品は製造コストや流通コストがかかり、製品価格の割高感は否めない。また、酵素処理による軟化処理では、特に魚介類では可食部の軟化は可能であるが、骨を食せる軟らかさにすることはできず、異物としてのクレームや、咀嚼・嚥下困難者用食品としての安全性への懸念がある一方、その解決のための骨抜き加工原料の利用は、価格増へとつながり、安価での供給の妨げとなっている。 These are all methods for introducing an enzyme solution and a seasoning into the food, and use physical mechanical devices such as a decompression device, a pressurization device, an injection device, and a tumbling device. With these enzyme impregnation techniques, foods for persons with difficulty in chewing / swallowing can be produced in order to maintain the shape and maintain the health of the care recipient and improve the quality of life. The most important issue in the production of food is required to be a method that can be industrially produced and distributed at a low cost, in particular, a method that can prevent the loss of shape and can be distributed at normal temperature or chilled. Frozen products are expensive to manufacture and distribute, and the price of the product cannot be denied. In addition, the softening treatment by enzyme treatment can soften the edible part, especially for seafood, but it cannot be made soft enough to eat bones. On the other hand, the use of water-removed raw materials for solving the problem has led to an increase in price and hinders supply at a low price.
 特許文献3以外は開放系で外部圧力処理を行なっているが、特許文献3は、軟包装容器内で酵素導入、酵素反応を行なっている。本文献では、圧力処理は外部エネルギー利用することを前提としているため、軟包材の利用が必須で、軟包材は外部からの物理的衝撃に弱い。そのため、冷凍食品として流通させなければ型崩れが生じるという問題がある。いずれの先行文献も硬質容器内で酵素反応を行わせる方法を考案していない。 Except for Patent Document 3, external pressure treatment is performed in an open system. However, Patent Document 3 performs enzyme introduction and enzyme reaction in a soft packaging container. In this document, since the pressure treatment is premised on the use of external energy, the use of a soft wrapping material is essential, and the soft wrapping material is vulnerable to physical impact from the outside. For this reason, there is a problem in that the shape is lost unless it is distributed as frozen food. None of the prior art documents devised a method for performing an enzyme reaction in a rigid container.
 特許文献9は惣菜用材料を調味液とともに耐熱性容器に充填し、加熱殺菌する方法であるが、元のテクスチャーを保持しつつ耐熱性容器内で調味と殺菌を同時に行う方法で、酵素反応を容器内で行わせ、テクスチャーを変えることを目的とした本発明とは目的及び効果が異なる。さらに、特許文献10は酵素で軟化させた食材をゼリーで固める方法であるが、ゼリー状食品を製造する方法でゼリーと一体となって切断できるほど固い性状であることを特徴としており、硬質容器等を必要としない。特許文献11は、咀嚼・嚥下困難者が安全に食すことができるように食材からの離水を防止するために軟化した食材内に増粘剤を導入する特許であり、本発明の食材外部を含めた振動による型崩れを防止した発明ではない。 Patent document 9 is a method of filling a heat-resisting container with ingredients for sugar beet together with a seasoning liquid and sterilizing by heating, but is a method of simultaneously seasoning and sterilizing in a heat-resistant container while maintaining the original texture. The object and the effect are different from those of the present invention which is performed in a container and aims to change the texture. Furthermore, Patent Document 10 is a method of solidifying a food material softened with an enzyme with jelly, which is characterized in that it is hard enough to be cut together with the jelly in a method for producing a jelly-like food, and is a hard container. Etc. are not required. Patent Document 11 is a patent in which a thickener is introduced into a softened food material to prevent water separation from the food material so that a person with difficulty in chewing or swallowing can safely eat, including the outside of the food material of the present invention. It is not an invention that prevents the loss of shape caused by vibration.
特許第3686912号公報Japanese Patent No. 3686912 特開2006-223122号公報JP 2006-223122 A 特開2008-11794号公報JP 2008-11794 A 特開2010-115164号公報JP 2010-115164 A 特開平7-31421号公報Japanese Unexamined Patent Publication No. 7-31421 特開2005-503172号公報JP 2005-503172 A 特開2004-89181号公報JP 2004-89181 A 特開2007-204413号公報JP 2007-204413 A 特開昭59-154946JP 59-154946 A 特開2011-193803JP2011-193803 特開2007-252323JP2007-252323
 本発明の課題は、製造工程中、輸送中、小売店での販売中において、形状保持軟化型の介護食や離乳食、医療分野、造影検査食分野において、型崩れを防止すること、さらに常温流通またはチルド流通を可能とした食品または食品の製造方法を解決することにある。食品の元の形状を損なうことなく、分解酵素及び調味料、油脂、アミノ酸など呈味成分及び嚥下食に必要なトロミ剤を食材内部に導入することで、食感や呈味性を変え、安価で食べやすく、おいしい常温流通またはチルド流通食品を製造することにある。また、要介護者や高齢者に摂取する食品が何であるかを認識し満足感をもって摂取することができるように、食材中心部まで分解酵素を導入し、食材の本来の形状を保持して軟化させた食品を低コストに製造することができる常温流通またはチルド流通食材の製造方法を提供することにある。さらに、要介護者や高齢者に必須の栄養成分やカロリーを強化した常温流通またはチルド流通食品の製造方法を提供することにある。 The object of the present invention is to prevent shape loss in the form-preserving softening type nursing food, baby food, medical field, and contrast inspection food field during the manufacturing process, transportation, and retail sale, Or it is in solving the foodstuff or the manufacturing method of foodstuffs which enabled chilled distribution. Introduce flavoring ingredients such as degrading enzymes and seasonings, oils and fats, amino acids and swallowing foods inside the food without changing the original shape of the food, changing the texture and taste, inexpensive It is to produce food that is easy to eat and delicious, distributed at normal temperature or chilled. In addition, a degrading enzyme is introduced to the center of the food to soften it by recognizing what the food needs to be taken by the care recipient and the elderly so that it can be consumed with satisfaction. An object of the present invention is to provide a method for producing a normal temperature distribution or chilled distribution food material capable of producing a processed food at low cost. Furthermore, it is providing the manufacturing method of the normal temperature distribution or the chilled distribution foodstuff which strengthened the nutrient component and the calorie which are indispensable for a care recipient and an elderly person.
 従来の圧力によるエネルギーを利用して酵素を食材内部へ導入し、極めて軟らかい食材を製造・販売する過程において、食材の酵素反応工程、包装工程、輸送工程での型崩れを防止するには、細心の取り扱いが必要であり、そのため酵素失活後は冷凍状態で取り扱いをしなければならなかった。酵素処理により形状を保持して軟化させた常温流通可能なレトルト食品は販売されているが、この場合、型崩れ防止の観点から、咀嚼・嚥下困難者に対応した軟らかさの製品設計は不可能であった。また、酵素処理で作製する軟化食品において、魚介類の骨は酵素による軟化ができず骨抜き原料を利用するため、使用できる食材種類が限られること、小骨が残存した場合には異物としてクレームとなること、骨抜き処理原料の使用を前提とするためコスト増につながることが課題となっている。 In the process of producing and selling extremely soft foods by introducing enzymes into the foods using the energy of conventional pressure, it is very important to prevent the foods from being deformed in the enzyme reaction process, packaging process, and transport process. Therefore, after enzyme inactivation, it had to be handled in a frozen state. Retort foods that can be distributed at room temperature that are softened while retaining their shape by enzymatic treatment are on the market, but in this case, it is impossible to design soft products that are difficult to chew and swallow from the viewpoint of preventing loss of shape Met. In addition, in softened foods produced by enzyme treatment, the bones of seafood cannot be softened by enzymes and use bone-free raw materials, so the types of food that can be used are limited, and if small bones remain, it becomes a claim as a foreign object In addition, since it is premised on the use of the water removal processing raw material, it is a problem that the cost increases.
 本発明者らは、酵素軟化食品の製造・販売過程での型崩れ防止と、常温流通またはチルド流通可能な形態を両立する方法として、缶詰食品の製造方法を取り入れることで解決可能であることを見出した。酵素含浸工程、酵素反応工程、酵素失活工程及び殺菌工程の全工程、もしくは、酵素反応工程、酵素失活工程及び殺菌工程の一部工程を金属製缶詰または瓶詰容器内で行うことで、各工程間での作業性を向上させ、低コストかつ衛生的に、酵素含浸した常温流通形状保持軟化食品を製造可能であることを見出した。また、製造工程中食材は流通容器内に置かれているため、型崩れもなく、食材そのものを移動させる必要がなくなり製造コストは大幅に低下する。容器内にある食材の形状を保持しつつ、硬さが5×10N/m以下という極めて軟らかい状態で誤嚥事故を防止するためには分解酵素や増粘剤を食材内部にできるかぎり均一に施す処置として真空密封法や加圧密封法が適していることを見出した。さらに、魚介類にあっては、可食部のみならず骨まで咀嚼・嚥下困難者用レベルに形状を保持したまま軟化できることを見出した。かかる知見に基づき、本発明を完成するに至った。 The present inventors are able to solve the problem by adopting a method for producing canned foods as a method for achieving both the prevention of shape loss during the production and sale of enzyme softened foods and the form capable of being distributed at room temperature or chilled. I found it. By performing all steps of enzyme impregnation step, enzyme reaction step, enzyme deactivation step and sterilization step, or partial steps of enzyme reaction step, enzyme deactivation step and sterilization step in a metal can or bottle container, It has been found that it is possible to improve the workability between processes, and to manufacture a cold-flowing shape-preserving softened food impregnated with an enzyme at low cost and in a sanitary manner. In addition, since the foodstuff is placed in the distribution container during the manufacturing process, it does not lose its shape, and it is not necessary to move the foodstuff itself, thereby greatly reducing the manufacturing cost. In order to prevent accidental aspiration while maintaining the shape of the food in the container and having a hardness of 5 × 10 4 N / m 2 or less, a degrading enzyme or thickener can be used inside the food as much as possible. It has been found that a vacuum sealing method or a pressure sealing method is suitable as a uniform treatment. Furthermore, in the case of seafood, it has been found that not only the edible portion but also the bone can be softened while maintaining the shape at the level for those who are difficult to chew and swallow. Based on this knowledge, the present invention has been completed.
 本発明によれば、以下の(1)~(20)の発明が提供される。
(1) 硬質容器と、前記硬質容器内に収容された、食材、分解酵素、および調味液とを含んでなり、
 前記硬質容器内において前記食材と前記分解酵素が反応して、前記食材が元の形状を保持したまま軟化したものであることを特徴とする、常温流通またはチルド流通用硬質容器入り食品。
(2) 前記分解酵素が、炭水化物、タンパク質、および脂質からなる群から選択される少なくとも1種の基質を分解する酵素活性を有する、(1)に記載の硬質容器入り食品。
(3) 元の形状を保持したまま軟化した食材の硬さが、1.0×10N/m以上1.0×10N/m以下である、(1)または(2)に記載の硬質容器入り食品。
(4) 前記硬質容器内の液状物の粘度が、B型粘度計による20℃の測定時で流動性のあるゾル状態にあっては5mPa・s以上20Pa・s以下もしくはゲル状態である、(1)~(3)のいずれかに記載の硬質容器入り食品。
(5) 前記調味液が、食塩、アミノ酸、油脂類、増粘剤、医療用造影剤、糖類、炭酸水素ナトリウム、ビタミン、およびミネラルからなる群から選択される少なくとも1種を含む、(1)~(4)のいずれかに記載の硬質容器入り食品。
(6) 前記調味液が、有機酸およびその塩を用いてpH3~pH10の範囲に調整されたものである、(1)~(5)のいずれかに記載の硬質容器入り食品。
(7) 前記硬質容器が、金属製缶、瓶、および耐熱性成形容器からなる群から選択される少なくとも1種である、(1)~(6)のいずれかに記載の硬質容器入り食品。
(8) 元の形状を保持したまま軟化した食材が収容された、常温流通またはチルド流通用硬質容器入り食品の製造方法であって、
 硬質容器内に食材および分解酵素含有液を加える工程と、
 前記硬質容器を密封する工程と、
 密封後の前記硬質容器内の温度を上昇させる工程と、
を含んでなり、
 酵素反応工程、酵素失活工程、および殺菌工程を前記硬質容器内で一連の温度上昇下で行うことを特徴とする、硬質容器入り食品の製造方法。
(9) 元の形状を保持したまま軟化した食材が収容された、常温流通またはチルド流通用硬質容器入り食品の製造方法であって、
 食材と分解酵素とを反応させる工程と、
 硬質容器内に前記分解酵素と反応した前記食材を加える工程と、
 前記硬質容器内の温度を上昇させる工程と、
を含んでなり、
 酵素反応工程、酵素失活工程、および殺菌工程を前記硬質容器内で一連の温度上昇下で行わせることを特徴とする、硬質容器食品の製造方法。
(10) 前記酵素反応工程の温度が0℃~70℃の範囲内であり、前記殺菌工程の温度が85℃~135℃の範囲内である、(8)または(9)に記載の硬質容器入り食品の製造方法。
(11) 前記酵素反応工程前または前記酵素失活前に、前記硬質容器の密封を行う、(9)に記載の硬質容器入り食品の製造方法。
(12) 前記硬質容器の密封工程前に、食材への加圧処理または減圧処理を行う、(11)に記載の硬質容器入り食品の製造方法。
(13) 前記分解酵素が、炭水化物、タンパク質、および脂質からなる群から選択される少なくとも1種の基質を分解する酵素活性を有する、(8)~(12)のいずれかに記載の硬質容器入り食品の製造方法。
(14) 前記硬質容器の密封前に、前記硬質容器内に調味液を加える、(8)~(13)のいずれかに記載の硬質容器入り食品の製造方法。
(15) 前記殺菌工程後の前記硬質容器内の液状物の粘度が、B型粘度計による20℃の測定時で流動性のあるゾル状態にあっては5mPa・s以上20Pa・s以下もしくはゲル状態である、(14)に記載の硬質容器入り食品の製造方法。
(16) 前記調味液が、食塩、アミノ酸、油脂類、増粘剤、医療用造影剤、糖類、炭酸水素ナトリウム、ビタミン、およびミネラルからなる群から選択される少なくとも1種を含む、(14)または(15)に記載の硬質容器入り食品の製造方法。
(17) 前記調味液が、有機酸およびその塩を用いてpH3~pH10の範囲に調整されたものである、(14)~(16)のいずれかに記載の硬質容器入り食品の製造方法。
(18) 前記硬質容器の密封前に、液体または気体状のガス成分を加えて密封後の硬質容器内圧力を高めることにより、あるいは容器内空気を脱気して密封後の硬質容器内圧力を減圧にすることにより、密封後の前記硬質容器内部の圧力を変化させる、(8)~(17)のいずれかに記載の硬質容器入り食品の製造方法。
(19) 元の形状を保持したまま軟化した食材の硬さが、1.0×10N/m以上1.0×10N/m以下である、(8)~(18)のいずれかに記載の硬質容器入り食品の製造方法。
(20) 前記硬質容器が、金属製缶、瓶、および耐熱性成形容器からなる群から選択される少なくとも1種である、(8)~(19)のいずれかに記載の硬質容器入り食品の製造方法。
According to the present invention, the following inventions (1) to (20) are provided.
(1) comprising a hard container, and ingredients, degrading enzymes, and seasoning liquid contained in the hard container;
A food in a hard container for normal temperature distribution or chilled distribution, wherein the food material and the degrading enzyme react in the hard container and the food material is softened while maintaining its original shape.
(2) The food in a hard container according to (1), wherein the degrading enzyme has an enzymatic activity for degrading at least one substrate selected from the group consisting of carbohydrates, proteins, and lipids.
(3) The hardness of the foodstuff softened while maintaining the original shape is 1.0 × 10 2 N / m 2 or more and 1.0 × 10 7 N / m 2 or less (1) or (2) Food in a hard container as described in 1.
(4) The viscosity of the liquid in the hard container is 5 mPa · s or more and 20 Pa · s or less or a gel state in a fluid sol state when measured at 20 ° C. with a B-type viscometer. The food in a hard container according to any one of 1) to (3).
(5) The said seasoning liquid contains at least 1 sort (s) selected from the group which consists of salt, an amino acid, fats and oils, a thickener, a medical contrast agent, saccharides, sodium hydrogencarbonate, a vitamin, and a mineral, (1) Food in a hard container according to any one of (4) to (4).
(6) The food in a hard container according to any one of (1) to (5), wherein the seasoning liquid is adjusted to a pH range of 3 to 10 using an organic acid and a salt thereof.
(7) The food in a hard container according to any one of (1) to (6), wherein the hard container is at least one selected from the group consisting of metal cans, bottles, and heat-resistant molded containers.
(8) A method for producing a food in a hard container for normal temperature distribution or chilled distribution, in which a softened food material is stored while retaining its original shape,
Adding a foodstuff and a liquid containing a degrading enzyme in a hard container;
Sealing the rigid container;
Increasing the temperature in the hard container after sealing;
Comprising
The manufacturing method of the foodstuffs containing a hard container characterized by performing an enzyme reaction process, an enzyme deactivation process, and a sterilization process under a series of temperature rises in the said hard container.
(9) A method for producing a food in a hard container for normal temperature distribution or chilled distribution, in which a softened food material is stored while retaining its original shape,
A step of reacting food ingredients with a degrading enzyme;
Adding the food material reacted with the degrading enzyme in a hard container;
Increasing the temperature in the rigid container;
Comprising
A method for producing a hard container food, characterized in that an enzyme reaction step, an enzyme deactivation step, and a sterilization step are performed in the hard container under a series of temperature rises.
(10) The rigid container according to (8) or (9), wherein the temperature of the enzyme reaction step is in the range of 0 ° C. to 70 ° C., and the temperature of the sterilization step is in the range of 85 ° C. to 135 ° C. A method of manufacturing food containing food.
(11) The method for producing a food in a hard container according to (9), wherein the hard container is sealed before the enzyme reaction step or before the enzyme deactivation.
(12) The method for producing a food in a hard container according to (11), wherein a pressurizing process or a depressurizing process is performed on the food before the sealing process of the hard container.
(13) The hard enzyme according to any one of (8) to (12), wherein the decomposing enzyme has an enzyme activity for decomposing at least one substrate selected from the group consisting of carbohydrates, proteins, and lipids. A method for producing food.
(14) The method for producing a food in a hard container according to any one of (8) to (13), wherein a seasoning liquid is added to the hard container before the hard container is sealed.
(15) When the viscosity of the liquid in the hard container after the sterilization step is 20 ° C. measured with a B-type viscometer and is in a fluid sol state, the viscosity is 5 mPa · s or more and 20 Pa · s or less or gel The method for producing a food in a hard container according to (14), which is in a state.
(16) The seasoning liquid contains at least one selected from the group consisting of sodium chloride, amino acids, fats and oils, thickeners, medical contrast agents, sugars, sodium bicarbonate, vitamins, and minerals (14) Or the manufacturing method of the foodstuff in a hard container as described in (15).
(17) The method for producing a food in a hard container according to any one of (14) to (16), wherein the seasoning liquid is adjusted to a pH of 3 to 10 using an organic acid and a salt thereof.
(18) Before sealing the hard container, by adding a liquid or gaseous gas component to increase the pressure in the hard container after sealing, or by degassing the air in the container and reducing the pressure in the hard container after sealing. The method for producing a food in a hard container according to any one of (8) to (17), wherein the pressure inside the hard container after sealing is changed by reducing the pressure.
(19) The hardness of the food material softened while maintaining the original shape is 1.0 × 10 2 N / m 2 or more and 1.0 × 10 7 N / m 2 or less (8) to (18) The manufacturing method of the foodstuff in a hard container in any one of.
(20) The food in a hard container according to any one of (8) to (19), wherein the hard container is at least one selected from the group consisting of metal cans, bottles, and heat-resistant molded containers. Production method.
 酵素含浸工程、酵素反応工程、酵素失活工程及び殺菌工程の全工程を瓶缶詰内で行なわせる発明として次のような方法が上げられる。食材の表面に付着させた分解酵素や調味料、もしくはpH調整剤、調味料等を含有する酵素液に浸漬した食材を硬質容器に入れ、硬質容器内で酵素含浸工程、酵素反応工程、酵素失活工程及び殺菌工程の全工程を行なわせる。本発明の特徴として、酵素含浸工程において、外部圧力等のエネルギーを使用せず、瓶缶詰容器内での圧力変化を酵素含浸エネルギーとして利用していることが上げられる。 The following method can be cited as an invention for performing all steps of the enzyme impregnation step, the enzyme reaction step, the enzyme deactivation step, and the sterilization step in the bottle can. Put the food soaked in the enzyme solution containing the degradation enzyme or seasoning or pH adjuster, seasoning, etc. attached to the surface of the food in a hard container, and in the hard container, the enzyme impregnation process, enzyme reaction process, enzyme loss The whole process of an active process and a sterilization process is performed. As a feature of the present invention, in the enzyme impregnation step, energy such as external pressure is not used, but the pressure change in the bottle can is used as the enzyme impregnation energy.
 具体的には、先ず、軟化させる食材を酵素液に浸漬、噴霧、あるいは塗布することにより、食材表面に分解酵素を付着させたあと、硬質容器に密封する。この時、硬質容器は通常の缶詰と同様の密封方法を採用することができる。すなわち、酵素液塗布した食材、あるいは食材と酵素液で満杯充填して密封シールする方法でも良く、あるいは密封時に硬質容器内を真空(減圧)処理する真空巻絞方式、高真空缶方式を用いることもできる。あるいは密封時にガス充填または炭酸水素ナトリウムを加えて加圧密封することもできる。その後、低温または常温からゆっくりと温度を上昇させ、最後にはレトルト殺菌温度にまで加熱する。この間、缶詰容器内では食材の膨張または蒸気発生し、内圧が高まるため徐々に表面付近の酵素や調味料は圧力、吸着及び浸透圧効果により食材内部に浸透し、最後には食材全体に酵素や調味料は拡散する。密封の際に液体窒素を少量添加することで内圧をより大きくすることができる。 Specifically, first, a food material to be softened is immersed, sprayed, or applied in an enzyme solution to attach a degrading enzyme to the surface of the food material, and then sealed in a hard container. At this time, the hard container can adopt the same sealing method as a normal can. In other words, it may be a method in which the enzyme solution is applied, or the food and enzyme solution are filled and hermetically sealed, or a vacuum squeezing method or a high vacuum can method in which a hard container is vacuumed (reduced pressure) when sealed is used. You can also. Alternatively, it can be sealed under pressure by adding gas or sodium hydrogen carbonate at the time of sealing. Thereafter, the temperature is slowly increased from low or normal temperature, and finally heated to the retort sterilization temperature. During this time, the foodstuff expands or generates steam in the can, and the internal pressure increases, so the enzyme and seasoning in the vicinity of the surface gradually permeate the foodstuff due to pressure, adsorption and osmotic pressure effects. Seasonings spread. The internal pressure can be increased by adding a small amount of liquid nitrogen at the time of sealing.
 高真空缶の採用は、密封時の減圧処理による酵素含浸と、減圧密封に伴う容器内飽和蒸気圧低下による低温時からの内圧によって、酵素を食材中心部へ効果的に浸透させる、という相乗効果を得ることもできる。 The adoption of a high-vacuum can has a synergistic effect that the enzyme is effectively infiltrated into the center of the food by the enzyme impregnation by the pressure reduction treatment at the time of sealing and the internal pressure from the low temperature due to the decrease in the saturated vapor pressure in the container accompanying the pressure reduction sealing. You can also get
 温度上昇時において、酵素活性が残存している温度帯では酵素反応が続き、食材は軟化する。硬質容器では、外部から内部に物理的圧力は加えられないので、形状は保たれる。さらに温度を上昇させ酵素タンパク質の変性温度(例えば70℃~100℃)を通過すると酵素は失活し、一部微生物も殺菌される。さらに温度を上昇させ110℃を超えると芽胞菌の死滅が始まり、120℃付近の高温で一定時間加圧加熱することでレトルト殺菌は完了する。殺菌温度は100℃以下でもよいがこの場合チルドタイプ瓶または缶詰食品となる。この間、食材は形状を保持したまま軟化されるので、効率的、衛生的かつ低コストで常温流通またはチルドタイプの形状保持軟化食材を製造できる。 When the temperature rises, the enzyme reaction continues in the temperature zone where the enzyme activity remains, and the food material softens. In a rigid container, no physical pressure is applied from the outside to the inside, so that the shape is maintained. When the temperature is further raised and the enzyme protein denaturation temperature (for example, 70 ° C. to 100 ° C.) is passed, the enzyme is deactivated and some microorganisms are sterilized. When the temperature is further raised and the temperature exceeds 110 ° C., spore germination begins, and retort sterilization is completed by pressurizing and heating at a high temperature around 120 ° C. for a certain period of time. The sterilization temperature may be 100 ° C. or lower, but in this case, it becomes a chilled type bottle or canned food. During this time, since the food is softened while maintaining its shape, it is possible to produce a normal temperature distribution or chilled type shape-maintained softened food efficiently, hygienically and at low cost.
 硬さ制御は、温度上昇速度、酵素濃度、加熱時間、冷却速度で決定される。温度上昇速度は自由に変化させることができる。即ち、本発明は、瓶または缶詰内の圧力変化を利用して酵素含浸を行なわせ、そのまま容器内の食材を加温することで酵素反応、酵素失活、殺菌を行なわせることができるため、低コスト、型崩れ防止、衛生的、常温流通のいずれも達成することができる。 Hardness control is determined by the temperature rise rate, enzyme concentration, heating time, and cooling rate. The temperature rise rate can be changed freely. That is, the present invention allows the enzyme impregnation using the pressure change in the bottle or the can, and the enzyme reaction, enzyme deactivation and sterilization can be performed by heating the food in the container as it is. All of low cost, prevention of shape loss, hygiene, and normal temperature distribution can be achieved.
 酵素反応工程、酵素失活工程及び殺菌工程の一部工程を硬質容器内で行う発明として次の方法が上げられる。加圧または減圧などの外部圧力エネルギーを食材に加えた後、軟化する前に瓶または缶詰容器に入れ、瓶缶詰容器で、酵素反応、酵素失活、殺菌工程を行なわせることで、製造工程中及び輸送中、小売店取り扱い中の型崩れが防止できること発明も行なっている。この方法は、軟化状態を目視できるという効果がある。即ち、酵素反応工程、酵素失活工程及び殺菌工程の一部工程を硬質容器内で行なわせる場合、予め加圧または減圧などの方法で酵素含浸した食材を硬質容器に入れた後、もしくは硬質容器内で加圧または減圧などの方法で酵素含浸した後、酵素反応工程、酵素失活工程及び殺菌工程を行なう。硬質容器の密封は、酵素反応前もしくは酵素反応後に行なうことができる。酵素失活工程後でも硬質容器に移すことは可能であるが、食材が軟化しているため取り扱いに注意が必要である。この場合、密封前に予め酵素含浸を行なわなければならないが、酵素反応前後に調味料や増粘剤を加えることができるので、調味や粘度、硬さを適宜調整しやすいという特徴がある。瓶または缶詰容器の温度上昇は密封状態下でも開放した状態でもできるが衛生的な面から酵素反応工程前が好ましい。各温度上昇条件は、酵素反応、酵素失活、殺菌の各工程で最適な条件を選択することができる。 The following method is given as an invention in which a part of the enzyme reaction step, the enzyme deactivation step, and the sterilization step is performed in a hard container. After applying external pressure energy such as pressurization or depressurization to food, put it in a jar or canned container before softening, and let the bottle canned container perform enzyme reaction, enzyme deactivation, sterilization process, during the manufacturing process In addition, the present inventors have also made an invention that can prevent the loss of shape during transportation and handling of retail stores. This method has an effect that the softened state can be visually observed. That is, when the enzyme reaction step, the enzyme deactivation step, and the sterilization step are performed in a hard container, after the food material impregnated with the enzyme in advance by a method such as pressurization or decompression is put in the hard container, or the hard container After the enzyme impregnation by a method such as pressurization or decompression, an enzyme reaction step, an enzyme deactivation step, and a sterilization step are performed. The hard container can be sealed before or after the enzyme reaction. Although it can be transferred to a hard container even after the enzyme deactivation process, the food is softened, so care must be taken in handling. In this case, the enzyme impregnation must be performed before sealing, but a seasoning and a thickener can be added before and after the enzyme reaction, so that the seasoning, viscosity, and hardness can be easily adjusted as appropriate. The temperature of the bottle or canned container can be raised either in a sealed state or in an open state, but is preferably before the enzyme reaction step from a hygienic aspect. As each temperature increase condition, an optimum condition can be selected in each step of enzyme reaction, enzyme deactivation, and sterilization.
本発明は次のような効果を奏する。
 本発明は、一般に提供されている普通の食事と変わらない見た目の介護食を提供することができる技術であり、咀嚼や嚥下能力の低下した高齢者と一般の健常者が、食事の軟らかさは異なるものの、同じ見た目の食事を食することができる観点から、「食のバリアフリー化」を実現する技術である。しかも、缶詰、瓶詰工程を利用することにより、これまでの冷凍が前提であったり、軟包材中で酵素及び調味液配合、含浸、失活して作業性を向上した形状保持軟化食材の製造方法と異なり、常温流通可能な食品で、かつ製造工程中、包装工程中、輸送中、小売店での取り扱い中に、形状のある極めて軟らかい食材でありながら、型崩れが生じにくい特徴をもっている。しかも、缶詰または瓶詰容器内で酵素反応から殺菌まで行なうことが可能で、低コストかつ衛生的である。冷凍品と異なり、冷凍輸送や冷凍保管の必要もなく、冷凍貯蔵コストをかけずに長期間貯蔵可能である。食品製造業のみならず、病院・介護施設の厨房、レストラン、家庭でも安価かつ簡単に取り扱える。その結果、咀嚼困難者や嚥下困難者にとって食欲増進効果が高く、購入または調理しやすくなるため、社会的貢献度においても高い効果を有する。
The present invention has the following effects.
The present invention is a technique that can provide a nursing care food that looks the same as a general meal that is generally provided. Elderly people who have reduced chewing and swallowing ability and normal healthy people Although it is different, it is a technology that realizes “barrier-free food” from the viewpoint of being able to eat meals that look the same. In addition, by using canning and bottling processes, manufacturing of shape-retaining softened foods that are premised on refrigeration and that have improved workability by combining, impregnating, and deactivating enzymes and seasonings in soft packaging materials Unlike the method, it is a food that can be distributed at room temperature and has a characteristic that it does not easily lose its shape even though it is a very soft food with a shape during the manufacturing process, packaging process, transportation, and handling in a retail store. Moreover, it is possible to carry out from the enzymatic reaction to sterilization in a canned or bottled container, and it is low cost and hygienic. Unlike frozen products, there is no need for refrigerated transport and storage, and it can be stored for a long time without incurring the cost of frozen storage. Not only in the food manufacturing industry, but also in hospitals, nursing homes, restaurants, and homes, it can be handled inexpensively and easily. As a result, the appetite enhancing effect is high for those who have difficulty chewing and those who have difficulty swallowing, and it is easy to purchase or cook.
 さらに、特筆すべき技術として、これまで報告されてきた分解酵素を利用した形状保持軟化技術は、魚介類の骨を軟化させることはできなかった。加圧処理により骨が軟化することは知られているが、酵素含浸、酵素反応、酵素失活済みの食材を耐熱容器に移し替えて処理することは形状保持の観点から現実的ではなく、一方、軟包材で一連の加熱酵素失活まで連続で行う形状保持軟化食品では、耐圧性の軟包材を利用することにより骨の軟化は理論上可能であるが、高圧加熱殺菌後の流通上の形状保持が担保できない。本発明により、魚介類の身のみならず、骨まで形状を保持したまま軟化させた常温流通・貯蔵可能な形状保持軟化食品を製造することが可能となった。 Furthermore, as a notable technology, the shape-maintaining softening technology using a degrading enzyme that has been reported so far has not been able to soften the bones of seafood. It is known that bone is softened by pressure treatment, but it is not realistic from the viewpoint of shape retention to process by impregnating enzyme impregnation, enzyme reaction, and enzyme-deactivated food material into a heat-resistant container. In the shape-maintained softened food that is continuously processed until the inactivation of the heating enzyme with soft packaging material, it is theoretically possible to soften the bone by using pressure-resistant soft packaging material. It is not possible to guarantee the shape retention. According to the present invention, it has become possible to produce a shape-retained softened food that can be distributed and stored at room temperature and softened while maintaining the shape of not only seafood but also bone.
 本発明品は、常温流通を可能にしたことで、介護食用として自然災害時の非常食、備蓄用として極めて有効である。東北地方太平洋沖地震の際、電気、ガス、水道等のライフラインは止まり、冷凍保存が前提の冷凍品や、利用時に水を必要とする乾燥品は使用できない場合もあった。特に、咀嚼・嚥下困難者や離乳児、高齢者向けのやわらかい備蓄用保存食は普及しておらず、食事の選択肢が少なく、大変つらい思いをされている。本発明品は、災害時の非常食、備蓄用食品として常備しておくことで、これら噛みにくい、飲み込みにくい弱者にとって、唯一、おいしい食事の提供を可能にしたものである。 The product of the present invention is extremely effective as an emergency food and stockpile during a natural disaster as a food for nursing care because it enables distribution at room temperature. During the Tohoku-Pacific Ocean Earthquake, lifelines such as electricity, gas, and water supply ceased, and frozen products that require frozen storage or dried products that require water during use may not be usable. In particular, preservative foods for soft stockpile for those with difficulty in chewing / swallowing, weaning infants, and the elderly are not widespread, and there are few choices of meals, which makes me very hard. The product of the present invention can be provided only as an emergency food or a food for storage in the event of a disaster, so that only a weak person who is difficult to chew and difficult to swallow can provide a delicious meal.
 本発明の常温流通またはチルド流通可能な形状保持軟化食品の製造方法は、分解酵素または調味料を食材の内部に均一に含有させる酵素含浸工程、分解酵素の作用により食材の形状を保持したまま食材に含まれる酵素基質を分解させる酵素反応工程、目的の硬さに達したら直ちに酵素を失活させる酵素失活工程、レトルト殺菌する工程の全工程もしくは一部工程を硬質容器内で行うことを特徴とする。一部工程の利用とは、酵素反応工程以降で硬質容器を利用する場合であり、酵素含浸工程は事前に別途実施し、予め酵素を食材内に減圧または加圧して浸透させておく必要がある。硬質容器の密封は、各工程間のいずれか一カ所において実施する必要があり、少なくともレトルト殺菌前に密封することにより、常温流通を可能とすることを特徴とする。レトルト食品とチルド食品の違いは硬質容器の殺菌温度で決定される。 The method for producing a shape-retaining softened food that can be distributed at normal temperature or chilled according to the present invention includes an enzyme impregnation step in which a degrading enzyme or seasoning is uniformly contained in the food, and a food that retains the shape of the food by the action of the degrading enzyme. An enzyme reaction step for decomposing the enzyme substrate contained in the enzyme, an enzyme deactivation step for deactivating the enzyme as soon as the desired hardness is reached, or a retort sterilization step, all or part of the steps being performed in a hard container And The use of a part of the process is a case where a hard container is used after the enzyme reaction process, and the enzyme impregnation process needs to be performed separately in advance, and the enzyme needs to be infiltrated in advance under reduced pressure or pressure. . The sealing of the hard container needs to be carried out at any one point between the respective steps, and is characterized by enabling normal temperature distribution by sealing at least before retort sterilization. The difference between retort food and chilled food is determined by the sterilization temperature of the hard container.
 本発明で用いられる硬質容器とは、外部からの圧力によっても内容物の型崩れが防止可能な容器であり、金属製缶、瓶、および耐熱性成形容器等が挙げられる。耐熱性成形容器は、たとえばハイバリアーの包装容器であって、耐熱性があり安価なPP(ポリプロピレン)、強度を持たせるNY(ナイロン)と、バリアー材としてEVOH(エチレン/ビニルアルコール共重合樹脂)やSIO蒸着・アルミナ蒸着PET(ポリエチレンテレフタレート)やPVDC(ポリビニリデンクロライド)などが容器素材例として上げられるプラスチック素材あるいは不透明な包装容器にはアルミ箔などのバリアー素材から構成された容器であれば、金属製缶または瓶に替えて用いることができる。この場合、蓋のシーラー部にはポリエチレンなど接着能力の高いプラスチック素材が用いられる。蓋に関しては軟包材の使用ができる。容器が外部特に横または底方向からの物理的な圧力を受けても大きく変形せず、内容物の形状を保持できる硬質容器であれば、容器の形状や素材は限定されない。 The hard container used in the present invention is a container capable of preventing the contents from being deformed by an external pressure, and examples thereof include metal cans, bottles, and heat-resistant molded containers. The heat-resistant molded container is, for example, a high-barrier packaging container, which is heat-resistant and inexpensive PP (polypropylene), strength-enhancing NY (nylon), and EVOH (ethylene / vinyl alcohol copolymer resin) as a barrier material. SIO X vapor deposition / alumina vapor deposition PET (polyethylene terephthalate), PVDC (polyvinylidene chloride), etc. are examples of container materials such as plastic materials or opaque packaging containers that are made of a barrier material such as aluminum foil. It can be used instead of a metal can or bottle. In this case, a plastic material having a high adhesive ability such as polyethylene is used for the sealer portion of the lid. For the lid, soft packaging material can be used. The shape and material of the container are not limited as long as the container is a rigid container that does not greatly deform even when subjected to physical pressure from the outside, particularly from the side or the bottom, and can retain the shape of the contents.
 本発明の形状保持軟らか食品の製造方法に用いる食材としては、植物性、動物性のいずれのものであってもよい。具体的には、植物性の食材としては、大根、人参、牛蒡、筍、キャベツ、白菜、セロリ、アスパラガス、ほうれん草、小松菜、青梗菜、トマト等の野菜、ジャガイモ、薩摩芋、里芋等の芋類、大豆、小豆、蚕豆、エンドウ豆等の豆類、米、麦、稗、粟などの穀類、リンゴ、モモ、パイナップル等の果実類、椎茸、シメジ、エノキ、ナメコ、松茸等のきのこ類、若布、昆布、ひじき等の海藻などを挙げることができる。また、動物性の食材としては、牛肉、豚肉、鳥肉の他に、羊肉、馬肉、鹿肉、猪肉、山羊肉、兎肉、鯨肉、それらの内臓等の肉類や、鯵、鮎、鰯、鰹、鮭、鯖、鮪等の魚類、鮑、牡蠣、帆立、蛤等の貝類、その他エビ、カニ、イカ、タコ、ナマコ等の魚介類を例示することができる。また、蒲鉾等の練製品やハム・ソーセージなどの畜肉製品、麺類、漬物等の加工食品であってもよい。食用の食品製造原料または素材であれば、これらに限定されない。 The food material used in the method for producing a shape-retaining soft food of the present invention may be plant or animal. Specifically, vegetable ingredients include vegetables such as radish, carrots, beef bowl, salmon, cabbage, Chinese cabbage, celery, asparagus, spinach, Japanese mustard spinach, green pepper, tomatoes, potatoes, potatoes, potatoes, potatoes, etc. , Beans such as soybeans, red beans, coffee beans, peas, grains such as rice, wheat, strawberries, strawberries, fruits such as apples, peaches, pineapples, mushrooms such as shiitake mushrooms, shimeji mushrooms, enoki, sea cucumbers, matsutake mushrooms, young cloth, Examples include seaweed such as kelp and hijiki. In addition to beef, pork, and poultry, animal ingredients include mutton, horse meat, venison, salmon, goat meat, salmon, whale meat, their internal organs, and other meats, salmon, salmon, salmon Examples include fish such as sea bream, sea bream, sea bream, sea bream, sea bream, shellfish such as sea bream, oyster, scallop, sea bream, and other seafood such as shrimp, crab, squid, octopus and sea cucumber. Further, it may be a paste product such as rice cake, a meat product such as ham / sausage, a processed food such as noodles and pickles. If it is an edible food manufacturing raw material or raw material, it will not be limited to these.
 これらの食材は、生の状態でも、また、煮る、焼く、蒸す、揚げるなど加熱・調理して用いてもよい。電子レンジ加熱や過熱蒸気処理でも良い。また、飽和水蒸気加熱でも良い。加熱する場合の温度は特に問わないが、内在のタンパク質を変性させる目的で、60℃以上、好ましくは65℃以上が望ましい。焼き上げるなどの高温処理では、加熱による色や香りなどの品質劣化を考慮して加熱温度と加熱時間を決定する必要がある。また、これらの食材は、凍結あるいは凍結・解凍処理をしたものを用いることもできる。また、食材を食塩、クエン酸などの有機酸およびその塩を溶解した水溶液で茹でるなどの前処理を行なって使用しても良い。さらに、分解酵素を内部に浸透しやすくするため筋切機など針を突き刺す装置の使用あるいはローラーで一部押さえるなどの方法を行うことができる。 These ingredients may be used in the raw state or by heating and cooking such as boiling, baking, steaming and frying. Microwave heating or superheated steam treatment may be used. Moreover, saturated steam heating may be used. The temperature for heating is not particularly limited, but it is preferably 60 ° C. or higher, preferably 65 ° C. or higher for the purpose of denaturing the endogenous protein. In high-temperature processing such as baking, it is necessary to determine the heating temperature and the heating time in consideration of quality deterioration such as color and fragrance due to heating. In addition, these foods can be used frozen or frozen / thawed. Further, the food material may be used after pretreatment such as boiling with an aqueous solution in which an organic acid such as salt or citric acid and its salt are dissolved. Furthermore, in order to facilitate the penetration of the degrading enzyme into the interior, it is possible to use a method such as the use of a device that pierces a needle such as a cleaver or a partial pressing with a roller.
 食材の形状は、塊でも一口大でもいずれの形状であってもよいが、食材の大きさは適宜選択することができ、元の食材の形状を保持し、何の素材か確認できる形状で、かつ咀嚼・嚥下困難者の食欲をそそるものでなければならない。本発明の対象食材は、厚み5mm以上で体積500mm以上の食材塊が好ましいが、成型品、麺類、緑色野菜や豆類などはその限りでない。 The shape of the food may be either a lump or a bite size, but the size of the food can be selected as appropriate, the shape of the original food is retained, and the shape of the raw material can be confirmed, And it must be appetizing for those who have difficulty chewing or swallowing. The target food of the present invention is preferably a food lump having a thickness of 5 mm or more and a volume of 500 mm 3 or more, but is not limited to molded products, noodles, green vegetables and beans.
 本発明で用いる分解酵素は、タンパク質、炭水化物、脂肪の分解酵素であればいずれも用いることができ、摂取者の状態や、使用する食材中に含まれる酵素基質等に合わせて適宜選択することができる。主に、ペクチナーゼ、アミラーゼ、プロテアーゼ、グルカナーゼまたはセルラーゼのいずれかの酵素活性を含む酵素が使用される。具体的にはプロテアーゼ、ペプチダーゼ等タンパク質をアミノ酸及びペプタイドに分解する酵素、アミラーゼ、グルカナーゼ、セルラーゼ、ペクチナーゼ、ペクチンエステラーゼ、ヘミセルラーゼ、β-グルコシダーゼ、マンナーゼ、キシラナーゼ、アルギン酸リアーゼ、キトサナーゼ、イヌリナーゼ、キチナーゼ等でんぷん、セルロース、イヌリン、グルコマンナン、キシラン、アルギン酸、フコイダン等の多糖類をオリゴ糖あるいは単糖に分解する酵素、リパーゼ等脂肪を分解する酵素などを挙げることができる。これらは1種又は相互に阻害しない範囲内で2種以上を組み合わせて使用することもできる。特に、食材として動物性食材を用いる場合、プロテアーゼやペプチターゼを用いることで、アミノ酸やペプチドを生成し、呈味性を向上させることができる。また、食感を改善するためにトランスグルタミナーゼ等も使用可能である。これら分解酵素の起源は問わず、植物由来、動物由来、微生物由来のものを使用することができる。分解酵素の形態としては、粉末状や液状、あるいは分散液に含有されたものを使用しても良い。 The degrading enzyme used in the present invention may be any protein, carbohydrate, or fat degrading enzyme, and may be appropriately selected according to the condition of the ingestor, the enzyme substrate contained in the food to be used, and the like. it can. Mainly, an enzyme containing an enzyme activity of any one of pectinase, amylase, protease, glucanase or cellulase is used. Specifically, starch, such as protease, peptidase and other enzymes that degrade proteins into amino acids and peptides, amylase, glucanase, cellulase, pectinase, pectinesterase, hemicellulase, β-glucosidase, mannase, xylanase, alginate lyase, chitosanase, inulinase, chitinase, etc. Examples thereof include enzymes that decompose polysaccharides such as cellulose, inulin, glucomannan, xylan, alginic acid, and fucoidan into oligosaccharides or monosaccharides, and enzymes that decompose fat such as lipases. These may be used alone or in combination of two or more within a range not inhibiting each other. In particular, when an animal food is used as a food, an amino acid or a peptide can be generated and the taste can be improved by using protease or peptidase. Also, transglutaminase or the like can be used to improve the texture. Regardless of the origin of these decomposing enzymes, those derived from plants, animals, and microorganisms can be used. As a form of the degrading enzyme, a powdered form, a liquid form, or a substance contained in a dispersion may be used.
 上記分解酵素液としては、液状の分解酵素製剤にあっては、そのまま、もしくは希釈して利用でき、粉末状の分解酵素製剤にあっては、分解酵素を水などの溶質に溶解若しくは分散させた状態で用いることができる。分解酵素液のpHは、pH3~pH10の範囲であることが好ましく、pH4~pH8であることがより好ましい。酵素活性の高い酵素の至適pHに調整することもでき、食材と同じpHに調整して使用することもできる。分解酵素液のpHの調整には、クエン酸のような有機酸類とその塩類やリン酸塩等のpH調整剤等を用いることができ、またpH調整された調味液等を使うこともできる。 As the above-mentioned degrading enzyme solution, it can be used as it is or diluted in the case of a liquid degrading enzyme preparation. In the case of a powdery degrading enzyme preparation, the degrading enzyme is dissolved or dispersed in a solute such as water. It can be used in the state. The pH of the decomposing enzyme solution is preferably in the range of pH 3 to pH 10, more preferably pH 4 to pH 8. It can also be adjusted to the optimum pH of an enzyme with high enzyme activity, and can be adjusted to the same pH as the food. To adjust the pH of the decomposing enzyme solution, an organic acid such as citric acid and a pH adjusting agent such as a salt or phosphate thereof can be used, and a pH-adjusted seasoning solution or the like can also be used.
 分解酵素の使用量としては、硬質容器の加温速度や加温条件によって変えることができる。軟化の程度や呈味成分の生成の度合いによって適宜選択することができ、分解酵素を使用する場合、食材100gに対して、例えば、0.001~1.0gの範囲を挙げることができる。分解酵素液の場合、例えば、溶媒液に対して0.01~3.0質量%の範囲で分解酵素を溶解あるいは分散させて使用することができる。 The amount of the degrading enzyme used can be changed depending on the heating speed and heating conditions of the hard container. It can be appropriately selected depending on the degree of softening and the degree of generation of the taste component. When a degrading enzyme is used, for example, a range of 0.001 to 1.0 g can be mentioned with respect to 100 g of food. In the case of a decomposing enzyme solution, for example, the decomposing enzyme can be used by dissolving or dispersing in a range of 0.01 to 3.0% by mass with respect to the solvent solution.
 食材に添加する調味料には、食塩、糖類、有機酸及びその塩、増粘多糖類等の増粘剤、その他、栄養素等を加えることができる。デンプン、カードラン、寒天、グアーガムまたはキサンタンガムなどのガム類、ペクチン、カルボキシメチルセルロース等の増粘剤を利用することにより、咀嚼時に食品からの離水を抑制することができ、好適な嚥下困難者用食材とすることもできる。増粘剤の使用方法として、水に溶解して用いることもできるが、酵素と同時に添加する場合は、酵素分解を受けず、粘性による酵素含浸効果の低減を避けるため、水に溶解させず分散状態で使用し増粘剤と酵素を食材内に含浸後加熱によりゾル化またはゲル化させる、ゲル状態にして酵素液と混じらない状態で酵素のみ含浸させる方法が望ましい。したがって、硬質容器を密封する前の調味液は、内容物が拡散しやすいほど、あるいは粘度は低いほど好ましく、B型回転粘度計(東京計器製)の20℃での測定で、好ましくは200mPa・s以下、より好ましくは20mPa・s以下、さらにより好ましくは1mPa・s以上5mPa・s以下である。また、増粘剤は、硬質容器内での食材の緩衝材として機能させることで、食材の型崩れの防止に役立つ。また粘性のある食用油を緩衝作用として用いることもできる。その場合の殺菌工程後の硬質容器内の液状物の粘度はB型回転粘度計(東京計器製)の20℃での測定で、流動性のあるゾル状態にあっては好ましくは5mPa・s以上20Pa・s以下、より好ましくは100mPa・s以上10Pa・s以下、さらに好ましくは300mPa・s以上1Pa・s以下が適する。硬質容器内の調味液の粘度を上記範囲内に調節することで、摂食者の食べやすさ、容器からの容易な取り出し、食材の型崩れ防止により役立つ。なお、粘度条件はこの限りではなく、振動状況、摂食者の状況に応じたものを作製してもよい。また、20℃における増粘剤の状態はゲル状態であっても良いが、容器から取り出す場合に型崩れしやすくなる場合があるので、取り出しやすい容器を利用することが望ましい。 To the seasoning added to the foodstuff, salt, saccharides, organic acids and salts thereof, thickeners such as thickening polysaccharides, and other nutrients can be added. By using thickeners such as starch, curdlan, agar, guar gum or xanthan gum, thickeners such as pectin and carboxymethylcellulose, water release from foods can be suppressed during chewing, and suitable foods for people with difficulty in swallowing It can also be. The thickener can be used by dissolving in water, but when added at the same time as the enzyme, it does not undergo enzymatic degradation and is not dissolved in water in order to avoid reducing the enzyme impregnation effect due to viscosity. A method in which a thickener and an enzyme are impregnated in a food and then heated to be sol or gelated by heating, and only an enzyme is impregnated in a gel state without being mixed with an enzyme solution is desirable. Therefore, the seasoning liquid before sealing the hard container is preferably so that the contents are easily diffused or the viscosity is low. The measurement at 20 ° C. with a B-type rotational viscometer (manufactured by Tokyo Keiki), preferably 200 mPa · s or less, more preferably 20 mPa · s or less, and even more preferably 1 mPa · s or more and 5 mPa · s or less. Moreover, the thickener serves to prevent the food from being deformed by functioning as a buffer for the food in the hard container. A viscous edible oil can also be used as a buffering action. In that case, the viscosity of the liquid in the hard container after the sterilization process is preferably 5 mPa · s or more in a fluid sol state as measured at 20 ° C. with a B-type rotational viscometer (manufactured by Tokyo Keiki). 20 Pa · s or less, more preferably 100 mPa · s or more and 10 Pa · s or less, and further preferably 300 mPa · s or more and 1 Pa · s or less. By adjusting the viscosity of the seasoning liquid in the hard container within the above range, it is useful for ease of eating by the user, easy removal from the container, and prevention of shape loss of the food. Note that the viscosity condition is not limited to this, and a material according to the vibration condition and the condition of the eating person may be prepared. Moreover, the state of the thickener at 20 ° C. may be a gel state, but it may be easy to lose its shape when taken out from the container, so it is desirable to use a container that is easy to take out.
 更に、これらの物質の他、食材に添加させる物質として、糖類、油脂、ビタミン、ミネラルなど栄養価を高める物質を利用できる。糖類として単糖の他、ソルビトール、キシリトールなどの糖アルコール類、マルトースやトレハロースなどの二糖類が好ましい。特に、油脂はカロリー強化に有効で、油脂類を乳化して利用することにより、食材内への導入濃度を高め、高カロリー食品とすることができる。 Furthermore, in addition to these substances, substances that increase nutritional value, such as sugars, fats, vitamins, and minerals, can be used as substances to be added to foods. As the saccharides, monosaccharides, sugar alcohols such as sorbitol and xylitol, and disaccharides such as maltose and trehalose are preferable. In particular, fats and oils are effective for calorie strengthening, and by emulsifying and using fats and oils, the concentration of introduction into foods can be increased and high-calorie foods can be obtained.
 肉、魚介類の場合、分解酵素としてプロテアーゼを使用するが油脂を分解するためリパーゼを添加することで食感、食味などを変えることができる。また、この場合、予めタンブリングや針による穴空けを行なうことでより軟化効果を高めることができる。 In the case of meat and seafood, protease is used as a degrading enzyme, but the texture and taste can be changed by adding lipase to decompose fats and oils. In this case, the softening effect can be further enhanced by performing tumbling or punching with a needle in advance.
 硬質容器内に添加する物質として、上記のものに加え、造影剤を添加することができる。この場合、嚥下または消化器官造影検査食として利用できる。本発明の医療用検査食に用いる医療用造影剤としては、X線撮影、CT、MRI、PET等の医療用の投影装置による活性エネルギー線照射により造影可能な医療用造影剤が適している。かかる医療用造影剤としては、具体的には、イオパミドール、ビジパーク、イオヘキソール、イオベルソール、イオメプロール、イオプロミド、イオキシラン、イオトロラン、アミドトリゾ酸、イオタラム酸メグルミン、イオタラム酸、イオキサグル酸、イオトロクス酸メグルミン、ヨード化ケシ油脂肪酸エチルエステル、イオパノ酸、アミドトリゾ酸、硫酸バリウム、ガドペンテト酸メグルミン、ガドテリドール、クエン酸鉄アンモニウム、フェルモキシデスなどを挙げることができる。医療用造影剤の含有量としては、食材、食品素材の種類にもよるが、例えば、食材100gに対して容器に入れる酵素液中の造影剤の含有量として10~60g好ましくは30~50gなどとすることができる。 In addition to the above substances, a contrast agent can be added as a substance to be added to the hard container. In this case, it can be used as a swallowing or digestive organ contrast examination food. As the medical contrast agent used in the medical test meal of the present invention, a medical contrast agent that can be imaged by irradiation with active energy rays by a medical projection apparatus such as X-ray imaging, CT, MRI, and PET is suitable. Specific examples of such a medical contrast agent include iopamidol, bipypark, iohexol, ioversol, iomeprol, iopromide, ioxirane, iotrolane, amidotrizoic acid, meglumine iotalamate, iotalamic acid, oxaglucic acid, meglumine iotroxate, iodized poppy oil Examples thereof include fatty acid ethyl esters, iopanoic acid, amidotrizoic acid, barium sulfate, meglumine gadopentetate, gadoteridol, iron ammonium citrate, fermoxides and the like. The content of the medical contrast agent depends on the type of food and food material. For example, the content of the contrast agent in the enzyme solution contained in the container with respect to 100 g of the food is 10 to 60 g, preferably 30 to 50 g. It can be.
 使用される金属製缶は、通常の缶詰食品に利用されている容器を使用可能であり、ブリキ製、スチール製の他、アルミ製が適する。腐食防止のために内面コーティングを施したり容器を利用したり、硫酸紙で包んで密封することも可能である。または瓶は、耐熱性の瓶に金属製の蓋をしたものが適する。 The metal can used can be a container used for ordinary canned food, and tin, steel, and aluminum are suitable. In order to prevent corrosion, it is possible to apply an inner coating, use a container, or wrap with sulfuric acid paper and seal it. Alternatively, the bottle is preferably a heat-resistant bottle with a metal lid.
 硬質容器内で酵素含浸工程、酵素反応工程、酵素失活工程及び殺菌工程の全工程を行なわせる方法として、硬質容器に食材及び分解酵素剤またはその酵素液の他、必要であれば調味料、増粘剤、食塩、アミノ酸、油脂または乳化油脂、増粘剤、糖類、ビタミンやミネラルなどの栄養成分などを適宜選択して入れ、pH調整、粘度調整などを行なう。密封後、食材温度をゆっくりと上昇させ、食材の膨張を促す。この過程で缶内圧力は上昇し、酵素含浸と酵素反応が進む。 As a method of performing all steps of the enzyme impregnation step, enzyme reaction step, enzyme deactivation step and sterilization step in the hard container, in addition to the ingredients and the decomposing enzyme agent or its enzyme solution in the hard container, seasoning if necessary, Thickener, salt, amino acid, fat or emulsified fat, thickener, saccharides, nutrients such as vitamins and minerals are appropriately selected and adjusted to adjust pH and viscosity. After sealing, the food temperature is slowly raised to promote food expansion. In this process, the pressure inside the can rises, and the enzyme impregnation and the enzyme reaction proceed.
 瓶缶詰密封前に、窒素、空気、二酸化炭素などのガス成分を液体または気体状で密封直前に加えることで酵素含浸工程時の缶内の内圧をより高めることができる。この場合、窒素などの反応性の低い不活性ガスを用いることが酸化防止などの品質を高めるためには好ましい。さらに、炭酸水素ナトリウムも利用して容器内の圧力を高めることも可能である。 -Before sealing the bottle can, the internal pressure in the can during the enzyme impregnation step can be further increased by adding a gas component such as nitrogen, air, carbon dioxide or the like in liquid or gaseous form immediately before sealing. In this case, it is preferable to use an inert gas having low reactivity such as nitrogen in order to improve the quality such as oxidation prevention. Furthermore, it is possible to increase the pressure in the container using sodium hydrogen carbonate.
 瓶缶詰の密封時に、減圧瓶詰め、真空巻締や高真空缶詰製法を採用すれば、密封時の減圧による酵素含浸と、減圧状態での加温による内圧上昇に伴う酵素浸透効果を相乗的に達成することもできる。この密封時の管内圧力は、90KPa以下でも良いが、50KPa以下の設定でより効果が得られ、好ましくは30KPa以下、より好ましくは20KPa以下でより高い効果が発揮できる。 When sealing canned bottles, if reduced-pressure bottling, vacuum winding, or high-vacuum canning methods are used, the enzyme impregnation effect due to the reduced pressure during sealing and the enzyme penetration effect due to the increase in internal pressure due to heating under reduced pressure can be achieved synergistically. You can also The pressure in the tube at the time of sealing may be 90 KPa or less. However, a higher effect can be obtained at a setting of 50 KPa or less, preferably 30 KPa or less, more preferably 20 KPa or less.
 加温は、品温が10℃以下の低温からでも常温からでもいずれの開始温度からも可能である。温度上昇とともに蒸気圧上昇、食材の膨張効果により内圧も上昇し、圧力、吸着及び浸透圧効果により酵素液等は食材内部に浸透していくとともに、酵素反応も進む。この間が酵素含浸工程、酵素反応工程である。常温以下の温度帯を好ましくは0.1℃/min~10℃/min、より好ましくは0.1℃/min~5℃/minでゆっくり通過させると、食材の軟化も穏やかにムラなく酵素反応させることができる。10℃/min以上で温度上昇させると軟化するが通過時間が早いと軟化しにくい。 Heating is possible from any starting temperature, whether the product temperature is as low as 10 ° C. or less or from room temperature. As the temperature rises, the vapor pressure rises and the internal pressure rises due to the expansion effect of the food material. The enzyme solution and the like penetrate into the food material due to the pressure, adsorption and osmotic pressure effects, and the enzymatic reaction also proceeds. This is the enzyme impregnation step and the enzyme reaction step. When slowly passing through a temperature zone below room temperature, preferably 0.1 ° C./min to 10 ° C./min, more preferably 0.1 ° C./min to 5 ° C./min, the softening of the food material is gentle and uneven, and the enzyme reaction Can be made. Softening occurs when the temperature is increased at 10 ° C./min or more, but is difficult to soften if the passage time is fast.
 酵素反応は好ましくは0~70℃で行い、より好ましくは30~65℃で行うことが出来る。50~65℃において内圧に伴う酵素浸透速度、酵素分解速度を高速化できる。したがって、目的の硬さ、硬さのバラツキの許容範囲に応じて、温度上昇速度、保持温度時間等を設定する必要がある。品温が70℃を超えるとほとんどの酵素剤で酵素失活工程に入る。この工程以降はできるだけ早く温度上昇させることが低コスト化、品質、硬さの安定化につながる。 The enzyme reaction is preferably performed at 0 to 70 ° C, more preferably 30 to 65 ° C. Enzyme permeation rate and enzyme degradation rate accompanying internal pressure can be increased at 50 to 65 ° C. Therefore, it is necessary to set the temperature rise rate, the holding temperature time, etc. according to the target hardness and the tolerance range of the hardness variation. When the product temperature exceeds 70 ° C., the enzyme deactivation process is started with most enzyme agents. After this step, increasing the temperature as soon as possible leads to cost reduction, quality and hardness stability.
 65℃から酵素の一部失活が起こるが微生物の死滅も始まり、pH4.5以下の食材の場合85℃程度で商業的殺菌は終了する。レトルト殺菌する場合、110℃を超えると芽胞菌が死滅し始め、好ましくは110℃~135℃、より好ましくは115℃~125℃の高温で一定時間加圧加熱することにより、レトルト殺菌が完了する。すべての工程を硬質容器内で行なわせるため、低コスト、衛生的で、型崩れはほとんど生じない。なお、レトルト殺菌後の容器は空冷または水冷による冷却工程を実施することによりロット別の硬さバラツキを抑制することができる。 The enzyme is partially inactivated at 65 ° C, but the microorganisms start to die, and commercial sterilization ends at about 85 ° C for foods with a pH of 4.5 or lower. In the case of retort sterilization, spore bacteria begin to die when the temperature exceeds 110 ° C., and retort sterilization is completed by pressurizing and heating at a high temperature of preferably 110 ° C. to 135 ° C., more preferably 115 ° C. to 125 ° C. for a certain period of time. . Since all the processes are performed in a hard container, it is low-cost, hygienic, and hardly loses its shape. In addition, the container after retort sterilization can suppress the hardness variation by lot by implementing the cooling process by air cooling or water cooling.
 酵素反応工程、酵素失活工程及びレトルト殺菌工程の一部工程を硬質容器内で行なわせる方法として、予め、別途処理装置を使用し、加圧または減圧などの方法で酵素含浸または酵素と同時に調味料、増粘剤、糖類、乳化油脂などの副材料を含浸した食材を用意しておく必要があるが、形状を保持したまま型崩れすることなく容器へ投入するためには、酵素反応の初期段階である硬い状態の食材を容器に入れることが好ましいが、型崩れしないように硬質容器に入れることができれば良い。酵素含浸する方法は、分解含有酵素液に浸漬または分解酵素含有液を噴霧して圧力処理する方法、または分解酵素液に浸漬後酵素液から取り出して圧力処理する方法などが好ましいが、食材表面に酵素が付着する状態であればこの限りではない。その後、酵素反応工程、酵素失活工程及び殺菌工程を行なう。硬質容器の密封は、酵素反応前もしくは酵素反応後に行なう。酵素失活工程後でも可能であるが、食材が軟化し型崩れしやすいこと、衛生的処理のためには、酵素反応前がより好ましい。瓶または缶詰容器の密封前の圧力処理は、酵素濃度によって異なるが酵素液中の酵素が0.2%の場合で、加圧の場合、1MPa~100MPaが好ましく、より好ましくは10MPa~20MPaであるが、これ以上の圧力でも同じ効果が得られる。減圧の場合、90KPa以下でも良いが、50KPa以下の設定でより効果が得られ、好ましくは30KPa以下、より好ましくは20KPa以下でより高い効果が発揮できる。 As a method of performing a part of the enzyme reaction step, enzyme deactivation step, and retort sterilization step in a hard container, use a separate processing device in advance and season with enzyme impregnation or enzyme by methods such as pressurization or decompression. It is necessary to prepare foods impregnated with auxiliary materials such as materials, thickeners, sugars, emulsified oils and fats, but in order to put them into a container without losing shape while maintaining the shape, the initial stage of enzyme reaction It is preferable to put the hard food material at the stage into the container, but it is sufficient if it can be put into the hard container so as not to lose its shape. The method of impregnating with the enzyme is preferably a method of pressure treatment by immersing the decomposition-containing enzyme solution or spraying the decomposition enzyme-containing solution, or a method of removing the pressure from the enzyme solution after immersion in the decomposition enzyme solution, and the like. This does not apply as long as the enzyme is attached. Thereafter, an enzyme reaction step, an enzyme deactivation step, and a sterilization step are performed. The rigid container is sealed before or after the enzyme reaction. Although it is possible even after the enzyme deactivation step, before the enzyme reaction is more preferable for the purpose of the food being softened and easily deformed, and hygienic treatment. The pressure treatment before sealing the bottle or canned container varies depending on the enzyme concentration, but the enzyme in the enzyme solution is 0.2%, and in the case of pressurization, it is preferably 1 MPa to 100 MPa, more preferably 10 MPa to 20 MPa. However, the same effect can be obtained at higher pressures. In the case of reduced pressure, the pressure may be 90 KPa or less, but a higher effect can be obtained with a setting of 50 KPa or less, preferably 30 KPa or less, more preferably 20 KPa or less, and a higher effect can be exhibited.
 この酵素含浸工程を別途実施したあと缶詰または瓶詰容器に食材を移し実施する方法は、食材に含浸したい酵素調味液とは異なる調味料や増粘剤などの副材料を密封時にそれぞれ添加できる点が特徴として挙げられる。そのため、調味やトロミ、硬さの調整しやすくなる。特に、増粘剤の添加には効果的である。増粘剤は硬質容器内の食材の緩衝材としての効果があるが、その粘性ゆえに酵素含浸による酵素浸透性が妨害される場合もある。 After carrying out this enzyme impregnation step separately, the method of transferring the food to a canned or bottled container is that the ingredients such as seasonings and thickeners different from the enzyme seasoning liquid to be impregnated in the food can be added at the time of sealing. Listed as a feature. Therefore, it becomes easy to adjust seasoning, trolley, and hardness. In particular, it is effective for adding a thickener. The thickener has an effect as a buffer material for the food in the hard container, but its viscosity may interfere with enzyme permeability due to enzyme impregnation.
 本工程では、酵素含浸時に未糊化の増粘剤を利用する方法もあるが、酵素含浸工程または酵素反応工程後に増粘剤を水等に溶解しトロミをつけた状態で添加できるのでより製造しやすい側面がある。温度上昇条件は、全工程を硬質容器内で行なう方法と同じであるが、目的の軟化度を設定し、酵素反応の進行をみながら温度上昇させること必要がある。なお、上記工程では、別途減圧または加圧処理した食材を硬質容器に詰める工程が必要である。そこで、予めそれら容器に食材と酵素調味液を充填し、密封することなく酵素の含浸処理を別途実施し、続いて上記酵素反応工程以降を実施することもできる。 In this process, there is a method that uses a non-gelatinized thickener at the time of enzyme impregnation, but it is more manufactured because the thickener can be added in water and dissolved in water after the enzyme impregnation process or enzyme reaction process. There is a side that is easy to do. The temperature increase condition is the same as the method in which all steps are performed in a hard container, but it is necessary to set the target softening degree and increase the temperature while watching the progress of the enzyme reaction. In addition, in the said process, the process of packing the foodstuff separately pressure-reduced or pressurized into the hard container is required. Therefore, it is also possible to pre-fill these containers with food and enzyme seasoning liquid, separately carry out the impregnation treatment of the enzyme without sealing, and subsequently carry out the enzyme reaction step and subsequent steps.
 通常の食材と見た目は全く変わらない食品を製造するために、硬質容器製品を殺菌・製造後における高齢者または咀嚼・嚥下困難者用の食品に適した硬さとして、クリープメーター(山電製、RE2-33005B)での破断強度の測定結果として、好ましくは1.0×10N/m以上1.0×10N/m以下、より好ましくは1,0×10N/m以上1.0×10N/m以下、さらに好ましくは1.0×10N/m以上1.0×10N/m以下に調整することが好ましい。離乳用としても適用可能である。酵素により食材の可食部は軟化し、骨はレトルト(加圧加熱処理)により軟化するので、魚介類は高齢者または咀嚼・嚥下困難者用でも骨まで食することができる。 In order to produce foods that look exactly the same as normal foods, a creep meter (manufactured by Yamaden Co., Ltd.) is used as a hardness suitable for foods for the elderly or those who have difficulty chewing or swallowing hard container products. As a result of measurement of the breaking strength in RE2-30005B), it is preferably 1.0 × 10 2 N / m 2 or more and 1.0 × 10 7 N / m 2 or less, more preferably 1.0 × 10 3 N / m. It is preferable to adjust to 2 or more and 1.0 × 10 6 N / m 2 or less, more preferably 1.0 × 10 3 N / m 2 or more and 1.0 × 10 4 N / m 2 or less. Applicable for weaning. Since the edible portion of the food material is softened by the enzyme and the bone is softened by retort (pressurized heat treatment), the seafood can eat even the bones for elderly people or those who have difficulty chewing / swallowing.
 次に本発明について実施例より詳細に説明するが、本発明の技術的範囲はこれらの実施例に限定されるものではない。 Next, the present invention will be described in more detail with reference to examples, but the technical scope of the present invention is not limited to these examples.
[例1]
 厚さ5mmで20mm×20mmに切断したタケノコ、ニンジン及び、厚さ5mmに切断したレンコン、ゴボウにビタミンCを0.1%加えた沸騰水で10分間茹でた。一口大に繊維を断ち切るように切断した鶏もも肉はそのまま使用した。ブリキ缶に食材、酵素(オリエンチーム、エイチビイアイ製、0.3質量%、パパインW-40、天野エンザイム製、0.3質量%)とアミノ酸調味料、食塩、砂糖、みりん、醤油それぞれ少量ずつ溶かした水溶液(20℃でB型回転粘度計により測定した粘度:3mPa・s)を加え、巻き締め密封した。その後、スチームコンベクション(三洋電機(株)製SOB-VS10)で0.5℃/minの速度で60℃まで加熱した。60℃で10分間保持した後、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行なった。得られた食材について硬さ(山電製、クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。形状はそのままで風味が良好で要介護者にとって食べやすい缶詰食品になった。ただし、振動させたところ、調味液の粘性不足のため、食材の形状が多少崩れ易かった。
[Example 1]
It was boiled for 10 minutes with boiling water in which 0.1% of vitamin C was added to bamboo shoots, carrots cut into 5 mm thickness and 20 mm × 20 mm, lotus root cut into 5 mm thickness, and burdock. The chicken thighs cut to cut the fiber into bite-sized pieces were used as they were. In tin cans, ingredients, enzymes (Orientam, HB, 0.3% by mass, Papain W-40, Amano Enzyme, 0.3% by mass) and amino acid seasoning, salt, sugar, mirin, soy sauce are dissolved in small amounts. An aqueous solution (viscosity measured with a B-type rotational viscometer at 20 ° C .: 3 mPa · s) was added, and the product was wound and sealed. Thereafter, it was heated to 60 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 60 ° C. for 10 minutes, rapid heating to 124 ° C. was performed with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.). As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained foodstuff, the hardness was 5 × 10 4 N / m 2 or less, and it was soft enough for people with difficulty in chewing. became. The shape remains the same and the canned food is easy to eat for care recipients. However, when it was vibrated, the shape of the food material was easily broken due to insufficient viscosity of the seasoning liquid.
[例2](比較)
 厚さ5mmで20mm×20mmに切断したタケノコ、ニンジン及び、厚さ5mmに切断したレンコン、ゴボウにビタミンCを0.1%加えた沸騰水で10分間茹でた。一口大に繊維を断ち切るように切断した鶏もも肉はそのまま使用した。レトルト用パウチに食材、酵素(オリエンチーム、エイチビイアイ製、0.3質量%、パパインW-40、天野エンザイム製、0.3質量%)とアミノ酸調味料、食塩、砂糖、みりん、醤油それぞれ少量ずつ溶かした水溶液(20℃でB型回転粘度計により測定した粘度:3mPa・s)を入れ密封した。その後、スチームコンベクション(三洋電機(株)製SOB-VS10)で0.5℃/minの速度で60℃まで加熱した。60℃で10分間保持した後、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行なった。得られた食材について硬さ(山電製、クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。形状はそのままで風味が良好で要介護者にとって食べやすいレトルトパウチ食品になった。ただし、指で押さえたり、振動させたりしたところ食材の形状が崩れた。
[Example 2] (Comparison)
It was boiled for 10 minutes with boiling water in which 0.1% of vitamin C was added to bamboo shoots, carrots cut into 5 mm thickness and 20 mm × 20 mm, lotus root cut into 5 mm thickness, and burdock. The chicken thighs cut to cut the fiber into bite-sized pieces were used as they were. Retort pouch with ingredients, enzymes (Orientam, HI, 0.3% by weight, Papain W-40, Amano Enzyme, 0.3% by weight) and amino acid seasoning, salt, sugar, mirin, soy sauce A dissolved aqueous solution (viscosity measured with a B-type rotational viscometer at 20 ° C .: 3 mPa · s) was added and sealed. Thereafter, it was heated to 60 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 60 ° C. for 10 minutes, rapid heating to 124 ° C. was performed with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.). As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained foodstuff, the hardness was 5 × 10 4 N / m 2 or less, and it was soft enough for people with difficulty in chewing. became. Retort pouch food that is easy to eat for care recipients with the same shape and flavor. However, when pressed with fingers or vibrated, the shape of the ingredients collapsed.
[例3]
 厚さ10mm、一口大に切断したレンコン、イカ、サトイモ、ニンジン、鶏肉、豚肉をスチームコンベクション(三洋電機(株)製SOB-VS10)を用いて95℃で加熱した。その後、食材と1.0質量%の酵素(ヘミセルラーゼ「アマノ」90及びパパイン(天野エンザイム製))及び市販調味料(2%)、pH調整剤(クエン酸0.1%及びそのナトリウム塩0.8%)、食塩(2%)を溶かした水溶液(20℃でB型回転粘度計により測定した粘度:3mPa・s)をブリキ缶に入れ、真空包装機(TOSEI(株)製V-280A)内トレイに並べ、減圧(真空度95%、5分)を行なった。常圧に戻した缶詰に加工デンプン5質量%水溶液を添加後に密封し(この時の20℃でB型回転粘度計により測定した粘度:900mPa・s)、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行なった。得られた食材について硬さ(クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。形状はそのままで風味が良好で要介護者にとって食べやすい常温流通食品になった。振動による型崩れは生じなかった。
[Example 3]
A lotus root, squid, taro, carrot, chicken, and pork cut to a thickness of 10 mm were heated at 95 ° C. using steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). Then, ingredients, 1.0% by mass of enzyme (hemicellulase “Amano” 90 and papain (manufactured by Amano Enzyme)), commercially available seasoning (2%), pH adjuster (citric acid 0.1% and its sodium salt 0) 0.8%) and an aqueous solution in which salt (2%) is dissolved (viscosity measured by a B-type rotary viscometer at 20 ° C .: 3 mPa · s) is put in a tin can, and vacuum packaging machine (V-280A manufactured by TOSEI Co., Ltd.) ) Arranged in the inner tray, and reduced pressure (degree of vacuum 95%, 5 minutes). The canned product returned to normal pressure was sealed after adding 5% by weight of an aqueous solution of modified starch (viscosity measured at 20 ° C. using a B-type rotary viscometer: 900 mPa · s), and a pressurized heat sterilizer (Autoclave SR-240). , Manufactured by Tommy Seiko Co., Ltd.). As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained food material, the hardness was 5 × 10 4 N / m 2 or less, which was sufficiently soft for those having difficulty in chewing. The shape of the food is good and the flavor is good, and it has become a room-temperature-distributed food that is easy to eat for care recipients. There was no loss of shape due to vibration.
[例4]
 インゲン、ほうれんそう、大豆、鯛の骨付き切り身を1口大に切断し、食材、酵素(マセロチーム2A、ヤクルト薬品工業製0.3質量%、パパインW-40、天野エンザイム製、0.3質量%)とアミノ酸調味料、食塩、砂糖、みりん、醤油、カードランをそれぞれ少量ずつ溶かした水溶液(20℃でのB型回転粘度計により測定した粘度:1000mPa・s)を加え、ブリキ製缶詰に液体窒素を2滴加え、密封した。その後、スチームコンベクション(三洋電機(株)製SOB-VS10)で0.5℃/minの速度で60℃まで加熱した。60℃で10分間保持した後、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行なった。得られた食材について硬さ(山電製、クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。その後、サナスウェルアルファ(とろみ剤、日本デンプン工業社製)を溶かした増粘剤を添加して試食したところ、鯛の骨も軟らかく軟化しており、形状はそのままで風味が良好で要介護者にとって食べやすい常温流通食品になった。振動による型崩れは生じなかった。
[Example 4]
Slices of green beans, spinach, soybeans, and salmon bones into slices, and ingredients, enzyme (Macero Team 2A, Yakult Pharmaceutical 0.3% by mass, Papain W-40, Amano Enzyme, 0.3% by mass) ) And an amino acid seasoning, salt, sugar, mirin, soy sauce and curdlan solution in small amounts (viscosity measured with a B-type rotational viscometer at 20 ° C .: 1000 mPa · s), and liquid in tin can Two drops of nitrogen were added and sealed. Thereafter, it was heated to 60 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 60 ° C. for 10 minutes, rapid heating to 124 ° C. was performed with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.). As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained foodstuff, the hardness was 5 × 10 4 N / m 2 or less, and it was soft enough for people with difficulty in chewing. became. After that, after adding a thickener containing Sanus Well Alpha (thickener, manufactured by Nippon Starch Kogyo Co., Ltd.) and eating it, the bones of the sea bream were softened and softened. It became easy to eat at room temperature. There was no loss of shape due to vibration.
[例5](比較)
 インゲン、ほうれんそう、大豆、鯛の骨付き切り身を1口大に切断し、食材、酵素(マセロチーム2A、ヤクルト薬品工業製0.3質量%、パパインW-40、天野エンザイム製、0.3質量%)とアミノ酸調味料、食塩、砂糖、みりん、醤油、カードランをそれぞれ少量ずつ溶かした水溶液(20℃でのB型回転粘度計により測定した粘度:1000mPa・s)を加え、レトルトパウチで密封した。その後、スチームコンベクション(三洋電機(株)製SOB-VS10)で0.5℃/minの速度で60℃まで加熱した。60℃で10分間保持した後、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行なった。得られた食材について硬さ(山電製、クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。鯛の骨も軟らかく軟化しており、形状はそのままで風味が良好で要介護者にとって食べやすい常温流通食品になった。しかし、ダンボールに積み重ねて1時間放置後、レトルトパウチの食材を観察したところ、食材が一部崩壊していた。
[Example 5] (Comparison)
Slices of green beans, spinach, soybeans, and salmon bones into slices, and ingredients, enzyme (Macero Team 2A, Yakult Pharmaceutical 0.3% by mass, Papain W-40, Amano Enzyme, 0.3% by mass) ) And an amino acid seasoning, salt, sugar, mirin, soy sauce and curdlan solution each in small amounts (viscosity measured with a B-type rotational viscometer at 20 ° C .: 1000 mPa · s), and sealed with a retort pouch . Thereafter, it was heated to 60 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 60 ° C. for 10 minutes, rapid heating to 124 ° C. was performed with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.). As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained foodstuff, the hardness was 5 × 10 4 N / m 2 or less, and it was soft enough for people with difficulty in chewing. became. The bones of the cocoons are soft and soft, and the shape remains as it is, and the flavor is good, and it has become a room-temperature-distributed food that is easy to eat for care recipients. However, after being stacked on cardboard and left for 1 hour, the ingredients in the retort pouch were observed, and the ingredients were partially collapsed.
[例6]
 イカ(皮を剥いだもの)、タコ(厚さ1cm)、サトイモを沸騰水で10分間加熱した。イカ、タコは、予め、ミートテンダライザー(ジャガード製ライザーMODELH)を使用した。その後、食材に0.5質量%の酵素(ペクトリアーゼ(新日本化学)及びパパイン(天野エンザイム製)及び市販調味料小さじ1、乳化油脂(30%)、食塩(1%)、を水に溶いたものをクエン酸緩衝液でpH6.0に調整した酵素液に5分間漬けた。その後、食材と、カードラン、寒天、およびトレハロースを含有する水溶液(20℃でのB型回転粘度計により測定した粘度:800mPa・s)とをブリキ缶に入れ、真空包装機(TOSEI(株)製V-280A)内トレイに並べ、減圧(真空度95%、5分)を行なった。常圧に戻した缶詰を密封し、加圧加熱殺菌機(山電製、オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行なった。得られた食材について硬さ(クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。形状はそのままで風味が良好で要介護者にとって食べやすい常温流通食品になった。振動による型崩れは生じなかった。
[Example 6]
Squid (thick skinned), octopus (thickness 1 cm), and taro were heated with boiling water for 10 minutes. Squid and octopus used a meat tenderizer (Jacquard riser MODELH) in advance. Thereafter, 0.5% by mass of enzymes (Pectriase (Nippon Chemical) and papain (manufactured by Amano Enzyme) and 1 teaspoon of commercially available seasoning, emulsified oil (30%), and salt (1%) were dissolved in water. The sample was soaked in an enzyme solution adjusted to pH 6.0 with a citrate buffer solution for 5 minutes, and then an aqueous solution containing ingredients, curdlan, agar, and trehalose (measured with a B-type rotational viscometer at 20 ° C. (Viscosity: 800 mPa · s) was placed in a tin can and placed in a tray in a vacuum packaging machine (V-280A manufactured by TOSEI Co., Ltd.), and pressure reduction (degree of vacuum 95%, 5 minutes) was performed. The canned product was sealed, and rapidly heated to 124 ° C. with a pressure heat sterilizer (manufactured by Yamaden, Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.) The resulting food was hard (creep meter RE2-33). Breaking strength) As a result of measuring the in 05B, the hardness becomes 5 × 10 4 N / m 2 or less, was sufficient softness. Shapes flavor intact eat for good care recipient as chewable difficult person The food was easy to distribute at normal temperature, and it did not lose its shape due to vibration.
[例7]
 骨付きサバとカードラン、醤油小さじ1、調味料小さじ1、デンプン、0.5質量%の酵素(パパイン、天野エンザイム製)、乳化油脂(30%)、食塩(1%)、を水に溶いたものをクエン酸緩衝液でpH6.0に調整した酵素液(20℃でB型回転粘度計により測定した粘度:700mPa・s)に5分間漬けた。その後、食材と、酵素液と、調味付け煮こごり少量とをブリキ缶に入れ、巻き締め密封後、スチームコンベクション(三洋電機(株)製SOB-VS10)で0.5℃/minの速度で55℃まで加熱した。55℃で20分間保持した後、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行ない、20分間保持した。得られた食材について硬さ(クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。形状はそのままで風味が良好で、サバの骨も軟化していた。要介護者にとって食べやすい常温流通食品になった。振動による型崩れは生じなかった。
[Example 7]
Bone mackerel and curdlan, 1 teaspoon soy sauce, 1 teaspoon seasoning, starch, 0.5% by weight enzyme (papain, Amano Enzyme), emulsified oil (30%), salt (1%), dissolved in water The sample was immersed in an enzyme solution adjusted to pH 6.0 with a citrate buffer (viscosity measured with a B-type rotational viscometer at 20 ° C .: 700 mPa · s) for 5 minutes. Thereafter, the ingredients, enzyme solution, and a small amount of seasoned boiled rice are put in a tin can, sealed by sealing, and then steam-convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.) at a rate of 0.5 ° C./min. Heated to ° C. After holding at 55 ° C. for 20 minutes, rapid heating was performed to 124 ° C. with a pressure heating sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.), and the mixture was held for 20 minutes. As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained food material, the hardness was 5 × 10 4 N / m 2 or less, which was sufficiently soft for those having difficulty in chewing. The shape was good as it was and the mackerel bones were softened. It has become a room temperature food that is easy to eat for the care recipient. There was no loss of shape due to vibration.
[例8]
 骨付きサバ、ニンジン、ゴボウと醤油小さじ1、調味料小さじ1、0.05質量%の酵素(パパイン、天野エンザイム製、ペクチナーゼ、新日本化学製)、食塩(1%)、を水に溶いたものをクエン酸緩衝液でpH6.0に調整し、ゲル化寒天(食材の1/2分量)を加えた酵素液(20℃でB型回転粘度計により測定した粘度:5mPa・s)に5分間漬けた。その後、ブリキ缶に入れ、巻き締め密封後、95%真空度で2分間減圧した。スチームコンベクション(三洋電機(株)製SOB-VS10)で0.5℃/minの速度で55℃まで加熱した。55℃で50分間保持した後、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行ない、20分間保持した。得られた食材について硬さ(クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。この時のブリキ缶内の液状物の20℃でB型回転粘度計により測定した粘度は800mPa・sであった。形状はそのままで風味が良好で、サバの骨も軟化していた。要介護者にとって食べやすい常温流通食品になった。振動による型崩れは生じなかった。
[Example 8]
Bone mackerel, carrot, burdock and 1 teaspoon of soy sauce, 1 teaspoon of seasoning, 0.05% by mass of enzyme (papain, Amano Enzyme, Pectinase, Shin Nippon Chemical), salt (1%), dissolved in water The solution was adjusted to pH 6.0 with a citrate buffer solution and added to an enzyme solution (viscosity measured with a B-type rotational viscometer at 20 ° C .: 5 mPa · s) to which gelled agar (1/2 amount of food) was added. Soaked for a minute. After that, it was put in a tin can and sealed by winding and then decompressed for 2 minutes at 95% vacuum. It was heated to 55 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 55 ° C. for 50 minutes, rapid heating was performed to 124 ° C. with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.), and the mixture was held for 20 minutes. As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained food material, the hardness was 5 × 10 4 N / m 2 or less, which was sufficiently soft for those having difficulty in chewing. The viscosity of the liquid material in the tin can at this time measured at 20 ° C. with a B-type rotational viscometer was 800 mPa · s. The shape was good as it was and the mackerel bones were softened. It has become a room temperature food that is easy to eat for the care recipient. There was no loss of shape due to vibration.
[例9]
 一口大の解凍直後の芯温4℃のくじら肉と調味料、クエン酸、酵素(ブロメラインF、天野エンザイム製)、0.2質量%加工デンプンの分散液を瓶容器に入れ(20℃でB型回転粘度計により測定した粘度:2mPa・s)、真空包装機(TOSEI(株)製V-280A)を利用して、減圧(真空度95%、5分)を行った。金属製蓋で密封後、スチームコンベクション(三洋電機(株)製SOB-VS10)で2℃/minの速度で40℃まで急速加熱した。40℃で20分間保持した後、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で110℃まで急速加熱を行ない、20分間保持した。得られた食材について硬さ(山電製、クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。この時の瓶容器内の液状物の20℃でB型回転粘度計により測定した粘度は500mPa・sであった。振動による型崩れは生じなかった。
[Example 9]
Just after thawing the bite-size 4 ° C whale meat and seasoning, citric acid, enzyme (Bromelain F, Amano Enzyme), 0.2 mass% processed starch dispersion in a bottle container (20 ° C B Using a vacuum packaging machine (V-280A manufactured by TOSEI Co., Ltd.) under reduced pressure (degree of vacuum 95%, 5 minutes). After sealing with a metal lid, it was rapidly heated to 40 ° C. at a rate of 2 ° C./min with steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 40 ° C. for 20 minutes, rapid heating was performed to 110 ° C. with a pressure heating sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.), and the mixture was held for 20 minutes. As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained foodstuff, the hardness was 5 × 10 4 N / m 2 or less, and it was soft enough for people with difficulty in chewing. became. At this time, the viscosity of the liquid in the bottle container was 500 mPa · s as measured with a B-type rotational viscometer at 20 ° C. There was no loss of shape due to vibration.
[例10]
 厚さ5mmで20mm×20mmに切断したダイコン、ブリ、及び冷凍エビを3℃の冷蔵庫に入れ、10分間温度調整を行なった。酵素(マセロチーム2A、ヤクルト薬品工業製0.3質量%、ブロメライン、天野エンザイム製0.3質量%)とアミノ酸調味料、食塩、砂糖、みりん、醤油それぞれ少量ずつ溶かした水溶液に造影剤(ビジパーク、第一三共製)として30%含ませた液(B型回転粘度計により測定した粘度:5mPa・s)を調整し、ブリキ缶に入れ密封前に真空度90%で5分間減圧した後、それぞれ0.1質量%のキサンタンガム、寒天を溶かした増粘剤を加え、巻き締め密封した。その後、スチームコンベクション(三洋電機(株)製SOB-VS10)で0.5℃/minの速度で55℃まで加熱した。55℃で10分間保持した後、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行なった。得られた食材について硬さ(クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、十分な軟らかさと形状を保持した消化器官造影検査食が調整できた。振動による型崩れは生じなかった。
[Example 10]
Japanese radish, yellowtail and frozen shrimp cut to 20 mm × 20 mm with a thickness of 5 mm were placed in a refrigerator at 3 ° C. and the temperature was adjusted for 10 minutes. Contrast agent (Visipark, Vispark, a solution containing 0.3% by mass of Macero Team 2A, 0.3% by mass of Yakult Pharmaceutical Co., Ltd., 0.3% by mass of Bromelain, Amano Enzyme) and amino acid seasoning, salt, sugar, mirin and soy sauce. Daiichi Sankyo Co., Ltd.) 30% liquid (viscosity measured with a B-type rotational viscometer: 5 mPa · s) was adjusted, put into a tin can and reduced in pressure at 90% vacuum for 5 minutes before sealing, Each was added with 0.1% by mass of xanthan gum and a thickener in which agar was dissolved, and sealed by winding. Thereafter, the mixture was heated to 55 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 55 ° C. for 10 minutes, rapid heating to 124 ° C. was performed with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.). As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained food material, the hardness was 5 × 10 4 N / m 2 or less, and a digestive organ contrast-enhanced inspection food having sufficient softness and shape was obtained. I was able to adjust. There was no loss of shape due to vibration.
[例11]
 厚さ5mmで20mm×20mmに切断したタケノコ、ニンジン及び、厚さ5mmに切断したレンコン、ゴボウにビタミンCを0.1%加えた沸騰水で10分間茹でた。一口大に繊維を断ち切るように切断した鶏もも肉はそのまま使用した。ブリキ缶に食材、酵素(オリエンチームHP、エイチビイアイ製0.2質量%、パパインW-40、天野エンザイム製0.2質量%)とアミノ酸調味料、食塩、砂糖、みりん、醤油、重曹それぞれ少量ずつ溶かした水溶液(20℃でのB型回転粘度計により測定した粘度:5mPa・s)を加え脱気しながら巻き締め密封した。その後、スチームコンベクション(三洋電機(株)製SOB-VS10)で0.5℃/minの速度で60℃まで加熱した。60℃で10分間保持した後、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で124℃まで急速加熱を行なった。得られた食材について硬さ(山電製、クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。振動による型崩れを防止するため、特別なコンテナで輸送する必要があった。摂食時にかたくり粉を溶かした増粘剤を添加したところ、形状はそのままで風味が良好で要介護者にとって食べやすい缶詰食品になった。
[Example 11]
It was boiled for 10 minutes with boiling water in which 0.1% of vitamin C was added to bamboo shoots, carrots cut into 5 mm thickness and 20 mm × 20 mm, lotus root cut into 5 mm thickness, and burdock. The chicken thighs cut to cut the fiber into bite-sized pieces were used as they were. Tin cans with ingredients, enzymes (Orientam HP, 0.2% by HI, PAPAIN W-40, 0.2% by Amano Enzyme) and amino acid seasoning, salt, sugar, mirin, soy sauce, baking soda A dissolved aqueous solution (viscosity measured with a B-type rotational viscometer at 20 ° C .: 5 mPa · s) was added, and the mixture was wound and sealed while degassing. Thereafter, it was heated to 60 ° C. at a rate of 0.5 ° C./min by steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). After holding at 60 ° C. for 10 minutes, rapid heating to 124 ° C. was performed with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.). As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained foodstuff, the hardness was 5 × 10 4 N / m 2 or less, and it was soft enough for people with difficulty in chewing. became. In order to prevent deformation due to vibration, it was necessary to transport in a special container. The addition of a thickener that dissolved katakuri during feeding resulted in a canned food that was easy to eat for the care recipient, with the same shape and flavor.
[例12]
 市販の生牛肉を15mm×15mm×15mmに切断し、-15℃で冷凍した。次いで、瓶容器にトレハロース1質量%、造影剤(商品名:ビジパーク270)33質量%、パパインW-40(0.5質量)、加工デンプン0.05質量%及びカードラン0.1質量%含有する水溶液(20℃でのB型回転粘度計により測定した粘度:20mPa・s)と牛肉を入れ室温で10分間浸漬し解凍した。瓶を脱気密封後、湯中で60℃達温まで0.2℃/分の速度で加温し、その後加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で118℃まで加熱し30分間加圧加熱殺菌を行い、形状保持軟化医療用検査食を得た。冷却後瓶を開けて食材を官能及びX線顕微鏡(XGT-5000、堀場製作所製)で観察したところ、嚥下困難者でも摂食可能な軟らかさでかつ造影剤は均一に含浸されていた。振動による型崩れは生じなった。
[Example 12]
Commercial raw beef was cut into 15 mm × 15 mm × 15 mm and frozen at −15 ° C. Next, trehalose 1% by mass, contrast agent (trade name: Vigipark 270) 33% by mass, papain W-40 (0.5%), modified starch 0.05% by mass and curdlan 0.1% by mass in a bottle container An aqueous solution (viscosity measured by a B-type rotational viscometer at 20 ° C .: 20 mPa · s) and beef were placed and immersed for 10 minutes at room temperature to be thawed. The bottle is deaerated and sealed, and heated in hot water at a rate of 0.2 ° C./min until reaching a temperature of 60 ° C., and then heated to 118 ° C. with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.) Heating was performed for 30 minutes under pressure and heat sterilization to obtain a shape-maintaining softened medical test meal. After cooling, the bottle was opened and the food material was observed with a sensory and X-ray microscope (XGT-5000, manufactured by Horiba Seisakusho). It was soft enough to be consumed even by those with difficulty in swallowing and was uniformly impregnated with the contrast medium. Loss of shape due to vibration occurred.
[例13]
 厚さ10mm、一口大に切断したレンコン、イカ、サトイモ、ニンジン、鶏肉、豚肉をスチームコンベクション(三洋電機(株)製SOB-VS10)を用いて95℃で加熱した。その後、食材と1.0質量%の酵素(ヘミセルラーゼ「アマノ」90及びパパイン(天野エンザイム製))及び市販調味料(2%)、pH調整剤(クエン酸0.1%及びそのナトリウム塩0.8%)、食塩(2%)を溶かした水溶液を耐熱性成型容器に入れ、真空包装機(TOSEI(株)製V-280A)内トレイに並べ、減圧(真空度95%、5分)を行なった。常圧に戻した耐熱性成型容器に加工デンプン、寒天、ゼラチン、キサンタンガムそれぞれ0.1質量%含む水溶液(B型回転粘度計により測定した粘度:1Pa・s)を添加後、ポリエチレン-アルミを主構成成分とするフィルムで熱圧着して密封し、加圧加熱殺菌機(オートクレーブSR-240、株式会社トミー精工製)で95℃、30分加熱し、チルド用食品を製造した。得られた食材について硬さ(クリープメーターRE2-33005Bで破断強度)を測定した結果、硬さは5×10N/m以下となり、咀嚼困難者用として十分な軟らかさになった。形状はそのままで風味が良好で要介護者にとって食べやすい常温流通食品になった。振動による型崩れは生じなった。
[Example 13]
A lotus root, squid, taro, carrot, chicken, and pork cut to a thickness of 10 mm were heated at 95 ° C. using steam convection (SOB-VS10 manufactured by Sanyo Electric Co., Ltd.). Then, ingredients, 1.0% by mass of enzyme (hemicellulase “Amano” 90 and papain (manufactured by Amano Enzyme)), commercially available seasoning (2%), pH adjuster (citric acid 0.1% and its sodium salt 0) .8%) and sodium chloride (2%) in an aqueous solution, put them in a heat-resistant molding container, and arrange them on a tray in a vacuum packaging machine (V-280A manufactured by TOSEI Co., Ltd.). Reduced pressure (degree of vacuum 95%, 5 minutes) Was done. After adding an aqueous solution containing 0.1% by weight of each modified starch, agar, gelatin, and xanthan gum (viscosity measured with a B-type rotational viscometer: 1 Pa · s) to a heat-resistant molded container that has been returned to normal pressure, the main component is polyethylene-aluminum. The film as a constituent component was thermocompression-bonded and sealed, and heated at 95 ° C. for 30 minutes with a pressure heat sterilizer (Autoclave SR-240, manufactured by Tommy Seiko Co., Ltd.) to produce a food for chilled food. As a result of measuring the hardness (breaking strength with a creep meter RE2-30005B) of the obtained food material, the hardness was 5 × 10 4 N / m 2 or less, which was sufficiently soft for those having difficulty in chewing. The shape of the food is good and the flavor is good, and it has become a room-temperature-distributed food that is easy to eat for care recipients. Loss of shape due to vibration occurred.

Claims (20)

  1.  硬質容器と、
     前記硬質容器内に収容された、食材、分解酵素、および調味液と、
    を含んでなり、
     前記硬質容器内において前記食材と前記分解酵素が反応して、前記食材が元の形状を保持したまま軟化したものであることを特徴とする、常温流通またはチルド流通用硬質容器入り食品。
    A rigid container;
    Foodstuffs, degrading enzymes, and seasonings contained in the hard container;
    Comprising
    A food in a hard container for normal temperature distribution or chilled distribution, wherein the food material and the degrading enzyme react in the hard container and the food material is softened while maintaining its original shape.
  2.  前記分解酵素が、炭水化物、タンパク質、および脂質からなる群から選択される少なくとも1種の基質を分解する酵素活性を有する、請求項1に記載の硬質容器入り食品。 The food in a hard container according to claim 1, wherein the decomposing enzyme has an enzyme activity for decomposing at least one substrate selected from the group consisting of carbohydrates, proteins, and lipids.
  3.  元の形状を保持したまま軟化した食材の硬さが、1.0×10N/m以上1.0×10N/m以下である、請求項1または2に記載の硬質容器入り食品。 Hardness ingredients softened while retaining the original shape, is 1.0 × 10 2 N / m 2 or more 1.0 × 10 7 N / m 2 or less, rigid container according to claim 1 or 2 Entered food.
  4.  前記硬質容器内の液状物の粘度が、B型粘度計による20℃の測定時で流動性のあるゾル状態にあっては5mPa・s以上20Pa・s以下もしくはゲル状態である、請求項1~3のいずれか一項に記載の硬質容器入り食品。 The viscosity of the liquid in the hard container is 5 mPa · s or more and 20 Pa · s or less or a gel state in a fluid sol state when measured at 20 ° C. with a B-type viscometer. The food in a hard container as described in any one of 3.
  5.  前記調味液が、食塩、アミノ酸、油脂類、増粘剤、医療用造影剤、糖類、炭酸水素ナトリウム、ビタミン、およびミネラルからなる群から選択される少なくとも1種を含む、請求項1~4のいずれか一項に記載の硬質容器入り食品。 The said seasoning liquid contains at least one selected from the group consisting of salt, amino acids, oils and fats, thickeners, medical contrast agents, sugars, sodium bicarbonate, vitamins, and minerals. Food in a hard container according to any one of the above.
  6.  前記調味液が、有機酸およびその塩を用いてpH3~pH10の範囲に調整されたものである、請求項1~5のいずれか一項に記載の硬質容器入り食品。 The food in a hard container according to any one of claims 1 to 5, wherein the seasoning liquid is adjusted to a pH range of 3 to 10 using an organic acid and a salt thereof.
  7.  前記硬質容器が、金属製缶、瓶、および耐熱性成形容器からなる群から選択される少なくとも1種である、請求項1~6のいずれか一項に記載の硬質容器入り食品。 The food in a hard container according to any one of claims 1 to 6, wherein the hard container is at least one selected from the group consisting of metal cans, bottles, and heat-resistant molded containers.
  8.  元の形状を保持したまま軟化した食材が収容された、常温流通またはチルド流通用硬質容器入り食品の製造方法であって、
     硬質容器内に食材および分解酵素含有液を加える工程と、
     前記硬質容器を密封する工程と、
     密封後の前記硬質容器内の温度を上昇させる工程と、
    を含んでなり、
     酵素反応工程、酵素失活工程、および殺菌工程を前記硬質容器内で一連の温度上昇下で行うことを特徴とする、硬質容器入り食品の製造方法。
    A method for producing a food in a hard container for distribution at normal temperature or chilled distribution, which contains softened ingredients while retaining the original shape,
    Adding a foodstuff and a liquid containing a degrading enzyme in a hard container;
    Sealing the rigid container;
    Increasing the temperature in the hard container after sealing;
    Comprising
    The manufacturing method of the foodstuffs containing a hard container characterized by performing an enzyme reaction process, an enzyme deactivation process, and a sterilization process under a series of temperature rises in the said hard container.
  9.  元の形状を保持したまま軟化した食材が収容された、常温流通またはチルド流通用硬質容器入り食品の製造方法であって、
     食材と分解酵素とを反応させる工程と、
     硬質容器内に前記分解酵素と反応した前記食材を加える工程と、
     前記硬質容器内の温度を上昇させる工程と、
    を含んでなり、
     酵素反応工程、酵素失活工程、および殺菌工程を前記硬質容器内で一連の温度上昇下で行わせることを特徴とする、硬質容器食品の製造方法。
    A method for producing a food in a hard container for distribution at normal temperature or chilled distribution, which contains softened ingredients while retaining the original shape,
    A step of reacting food ingredients with a degrading enzyme;
    Adding the food material reacted with the degrading enzyme in a hard container;
    Increasing the temperature in the rigid container;
    Comprising
    A method for producing a hard container food, characterized in that an enzyme reaction step, an enzyme deactivation step, and a sterilization step are performed in the hard container under a series of temperature rises.
  10.  前記酵素反応工程の温度が0℃~70℃の範囲内であり、前記殺菌工程の温度が85℃~135℃の範囲内である、請求項8または9に記載の硬質容器入り食品の製造方法。 The method for producing a food in a hard container according to claim 8 or 9, wherein the temperature of the enzyme reaction step is in the range of 0 ° C to 70 ° C, and the temperature of the sterilization step is in the range of 85 ° C to 135 ° C. .
  11.  前記酵素反応工程前または前記酵素失活前に、前記硬質容器の密封を行う、請求項9に記載の硬質容器入り食品の製造方法。 The method for producing a food in a hard container according to claim 9, wherein the hard container is sealed before the enzyme reaction step or before the enzyme deactivation.
  12.  前記硬質容器の密封工程前に、食材への加圧処理または減圧処理を行う、請求項11に記載の硬質容器入り食品の製造方法。 The method for producing a food in a hard container according to claim 11, wherein the food is pressurized or depressurized before the hard container is sealed.
  13.  前記分解酵素が、炭水化物、タンパク質、および脂質からなる群から選択される少なくとも1種の基質を分解する酵素活性を有する、請求項8~12のいずれか一項に記載の硬質容器入り食品の製造方法。 The production of the food in a hard container according to any one of claims 8 to 12, wherein the degrading enzyme has an enzymatic activity for degrading at least one substrate selected from the group consisting of carbohydrates, proteins, and lipids. Method.
  14.  前記硬質容器の密封前に、前記硬質容器内に調味液を加える、請求項8~13のいずれか一項に記載の硬質容器入り食品の製造方法。 The method for producing a food in a hard container according to any one of claims 8 to 13, wherein a seasoning liquid is added into the hard container before the hard container is sealed.
  15.  前記殺菌工程後の前記硬質容器内の液状物の粘度が、B型粘度計による20℃の測定時で流動性のあるゾル状態にあっては5mPa・s以上20Pa・s以下もしくはゲル状態である、請求項14に記載の硬質容器入り食品の製造方法。 When the viscosity of the liquid in the hard container after the sterilization step is measured at 20 ° C. with a B-type viscometer, it is in a fluid sol state, being 5 mPa · s or more and 20 Pa · s or less, or a gel state. The manufacturing method of the foodstuff in a hard container of Claim 14.
  16.  前記調味液が、食塩、アミノ酸、油脂類、増粘剤、医療用造影剤、糖類、炭酸水素ナトリウム、ビタミン、およびミネラルからなる群から選択される少なくとも1種を含む、請求項14または15に記載の硬質容器入り食品の製造方法。 The said seasoning liquid contains at least 1 sort (s) selected from the group which consists of salt, an amino acid, fats and oils, a thickener, a medical contrast agent, saccharides, sodium hydrogencarbonate, a vitamin, and a mineral in Claim 14 or 15 The manufacturing method of the foodstuff in a hard container of description.
  17.  前記調味液が、有機酸およびその塩を用いてpH3~pH10の範囲に調整されたものである、請求項14~16のいずれか一項に記載の硬質容器入り食品の製造方法。 The method for producing a food in a hard container according to any one of claims 14 to 16, wherein the seasoning liquid is adjusted to a pH of 3 to 10 using an organic acid and a salt thereof.
  18.  前記硬質容器の密封前に、液体または気体状のガス成分を加えて密封後の硬質容器内圧力を高めることにより、あるいは容器内空気を脱気して密封後の硬質容器内圧力を減圧にすることにより、密封後の前記硬質容器内部の圧力を変化させる、請求項8~17のいずれか一項に記載の硬質容器入り食品の製造方法。 Before sealing the hard container, the liquid pressure or gaseous gas component is added to increase the pressure inside the hard container after sealing, or the air inside the container is deaerated to reduce the pressure inside the hard container after sealing. The method for producing a food in a hard container according to any one of claims 8 to 17, wherein the pressure inside the hard container after sealing is changed.
  19.  元の形状を保持したまま軟化した食材の硬さが、1.0×10N/m以上1.0×10N/m以下である、請求項8~18のいずれか一項に記載の硬質容器入り食品の製造方法。 The hardness of the food material softened while maintaining the original shape is 1.0 × 10 2 N / m 2 or more and 1.0 × 10 7 N / m 2 or less. The manufacturing method of the foodstuff in hard container as described in 2.
  20.  前記硬質容器が、金属製缶、瓶、および耐熱性成形容器からなる群から選択される少なくとも1種である、請求項8~19のいずれか一項に記載の硬質容器入り食品の製造方法。 The method for producing a food in a hard container according to any one of claims 8 to 19, wherein the hard container is at least one selected from the group consisting of a metal can, a bottle, and a heat-resistant molded container.
PCT/JP2013/071875 2012-12-04 2013-08-13 Food packaged in hard container, and method for producing same WO2014087705A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201380063334.7A CN104883902A (en) 2012-12-04 2013-08-13 Food packaged in hard container, and method for producing same
US14/649,627 US20160007645A1 (en) 2012-12-04 2013-08-13 Food packaged in hard container, and method for producing same
JP2014504866A JP5674178B2 (en) 2012-12-04 2013-08-13 Food in hard container and method for producing the same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2012265691 2012-12-04
JP2012-265691 2012-12-04
JP2013033979 2013-02-23
JP2013-033979 2013-02-23

Publications (1)

Publication Number Publication Date
WO2014087705A1 true WO2014087705A1 (en) 2014-06-12

Family

ID=50883136

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2013/071875 WO2014087705A1 (en) 2012-12-04 2013-08-13 Food packaged in hard container, and method for producing same

Country Status (4)

Country Link
US (1) US20160007645A1 (en)
JP (1) JP5674178B2 (en)
CN (1) CN104883902A (en)
WO (1) WO2014087705A1 (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015159753A (en) * 2014-02-27 2015-09-07 イーエヌ大塚製薬株式会社 Processed food and method for manufacturing the same
WO2017017953A1 (en) * 2015-07-27 2017-02-02 三菱商事フードテック株式会社 Food product for individuals with difficulty in chewing which is refrigeration and freezing tolerant and which can be cooked
WO2019008641A1 (en) * 2017-07-03 2019-01-10 イーエヌ大塚製薬株式会社 Method for manufacturing processed food
JP2019156869A (en) * 2018-03-07 2019-09-19 東洋製罐グループホールディングス株式会社 Container-contained organic nanofiber dispersion and method for producing same
WO2020105590A1 (en) * 2018-11-20 2020-05-28 海商株式会社 Packaged precooked seafood product and method for producing same
JP2020158129A (en) * 2019-03-25 2020-10-01 株式会社クラレ Product having packaging container
WO2021045204A1 (en) * 2019-09-05 2021-03-11 海商株式会社 Packaged fish meat paste product
WO2021149574A1 (en) * 2020-01-22 2021-07-29 学校法人常翔学園 Processed cereal, method for manufacturing processed cereal, and method for manufacturing softened processed cereal
JP2023150020A (en) * 2022-03-31 2023-10-16 イーエヌ大塚製薬株式会社 Processed meat food easy to swallow and manufacturing method thereof

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI657745B (en) * 2017-11-09 2019-05-01 統一企業股份有限公司 Method for preparing meat product containing softened meat
KR102149232B1 (en) * 2018-12-20 2020-08-31 주식회사 아워홈 Method for softening vegetable food material
JP7473488B2 (en) * 2021-01-15 2024-04-23 日立グローバルライフソリューションズ株式会社 Cooking device and control method thereof
JP7250840B2 (en) * 2021-03-31 2023-04-03 大和製罐株式会社 food set
CN117322591B (en) * 2023-11-01 2024-06-11 广东官栈营养健康科技有限公司 Preparation method of normal-temperature fresh stewed sea cucumber with long shelf life

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH034770A (en) * 1988-09-29 1991-01-10 Tulip Slagterierne Amba Seasoned minced meat with improved property, preparation thereof and heat-sensitive enzyme-containing substance for use for preparation thereof
JPH03210144A (en) * 1990-01-12 1991-09-13 Ajinomoto Co Inc Production of canned meat food
JPH08126481A (en) * 1994-10-31 1996-05-21 Ajinomoto Co Inc Prevention of fading of tuna fish and production of canned tuna
JPH10276729A (en) * 1997-04-11 1998-10-20 Naoyuki Takeuchi Wrapped/processed abalone and its production
JP2001346529A (en) * 2000-06-06 2001-12-18 Katokichi Co Ltd Method for producing cooked rice food
JP2006223122A (en) * 2005-02-15 2006-08-31 Mishima Shokuhin Kk Method for producing soft vegetable food
JP2007054065A (en) * 2005-07-29 2007-03-08 House Foods Corp Method for preparation of processed meat piece and method for preparation of thermally sterilized food
JP2008011794A (en) * 2006-07-06 2008-01-24 Hiroshima Pref Gov Method for producing cooked food
JP2008237196A (en) * 2007-03-29 2008-10-09 Food Research:Kk Greenish yellow vegetable food product and method for producing the same

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5552681B2 (en) * 2006-02-01 2014-07-16 広島県 Medical test food and manufacturing method thereof
US20100215804A1 (en) * 2007-10-02 2010-08-26 Reika Goto Food product suitable for person who has difficulty in chewing or swallowing

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH034770A (en) * 1988-09-29 1991-01-10 Tulip Slagterierne Amba Seasoned minced meat with improved property, preparation thereof and heat-sensitive enzyme-containing substance for use for preparation thereof
JPH03210144A (en) * 1990-01-12 1991-09-13 Ajinomoto Co Inc Production of canned meat food
JPH08126481A (en) * 1994-10-31 1996-05-21 Ajinomoto Co Inc Prevention of fading of tuna fish and production of canned tuna
JPH10276729A (en) * 1997-04-11 1998-10-20 Naoyuki Takeuchi Wrapped/processed abalone and its production
JP2001346529A (en) * 2000-06-06 2001-12-18 Katokichi Co Ltd Method for producing cooked rice food
JP2006223122A (en) * 2005-02-15 2006-08-31 Mishima Shokuhin Kk Method for producing soft vegetable food
JP2007054065A (en) * 2005-07-29 2007-03-08 House Foods Corp Method for preparation of processed meat piece and method for preparation of thermally sterilized food
JP2008011794A (en) * 2006-07-06 2008-01-24 Hiroshima Pref Gov Method for producing cooked food
JP2008237196A (en) * 2007-03-29 2008-10-09 Food Research:Kk Greenish yellow vegetable food product and method for producing the same

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015159753A (en) * 2014-02-27 2015-09-07 イーエヌ大塚製薬株式会社 Processed food and method for manufacturing the same
WO2017017953A1 (en) * 2015-07-27 2017-02-02 三菱商事フードテック株式会社 Food product for individuals with difficulty in chewing which is refrigeration and freezing tolerant and which can be cooked
JPWO2017017953A1 (en) * 2015-07-27 2018-05-17 三菱商事フードテック株式会社 Food for people with difficulty in chewing that has resistance to refrigeration and freezing and can be cooked by heating
JP7001689B2 (en) 2017-07-03 2022-01-19 イーエヌ大塚製薬株式会社 Manufacturing method of processed foods
WO2019008641A1 (en) * 2017-07-03 2019-01-10 イーエヌ大塚製薬株式会社 Method for manufacturing processed food
JPWO2019008641A1 (en) * 2017-07-03 2020-04-30 イーエヌ大塚製薬株式会社 Processed food manufacturing method
JP2019156869A (en) * 2018-03-07 2019-09-19 東洋製罐グループホールディングス株式会社 Container-contained organic nanofiber dispersion and method for producing same
JP7275474B2 (en) 2018-03-07 2023-05-18 東洋製罐グループホールディングス株式会社 Containerized organic nanofiber dispersion and method for producing the same
WO2020105590A1 (en) * 2018-11-20 2020-05-28 海商株式会社 Packaged precooked seafood product and method for producing same
JP2020080854A (en) * 2018-11-20 2020-06-04 海商株式会社 Packaged cooked seafood product and manufacturing method therefor
JP2020158129A (en) * 2019-03-25 2020-10-01 株式会社クラレ Product having packaging container
JP7186649B2 (en) 2019-03-25 2022-12-09 株式会社クラレ Products with packaging
WO2021045204A1 (en) * 2019-09-05 2021-03-11 海商株式会社 Packaged fish meat paste product
WO2021149574A1 (en) * 2020-01-22 2021-07-29 学校法人常翔学園 Processed cereal, method for manufacturing processed cereal, and method for manufacturing softened processed cereal
JP2023150020A (en) * 2022-03-31 2023-10-16 イーエヌ大塚製薬株式会社 Processed meat food easy to swallow and manufacturing method thereof
JP7425531B2 (en) 2022-03-31 2024-01-31 イーエヌ大塚製薬株式会社 Processed meat food that is easy to swallow and its manufacturing method

Also Published As

Publication number Publication date
CN104883902A (en) 2015-09-02
US20160007645A1 (en) 2016-01-14
JP5674178B2 (en) 2015-02-25
JPWO2014087705A1 (en) 2017-01-05

Similar Documents

Publication Publication Date Title
JP5674178B2 (en) Food in hard container and method for producing the same
JP4947630B2 (en) Method for producing cooked food
WO2007088918A1 (en) Food and process for producing food
JP6052654B2 (en) Soft food manufacturing method and food
US11154080B2 (en) High pressure frozen sterilization process
JP6304836B2 (en) Method for producing containerized food
CN101808535A (en) Method of producing matured food
Guillou et al. High‐pressure processing of meat and meat products
CN101869239A (en) Instant sea cucumber rice and production method thereof
JP5435384B2 (en) Nursing food cooking aids, nursing food using the same, and nursing food cooking utensils
JP2015159753A (en) Processed food and method for manufacturing the same
JP5881418B2 (en) Method for producing enzyme-containing food and enzyme-containing food
WO2020105590A1 (en) Packaged precooked seafood product and method for producing same
JP7173516B2 (en) Method for producing shape-retaining softened food
CN101326999A (en) Longevity mushroom edible fungus soup and method for producing the same
US20150272143A1 (en) Method for pasturizing ground poultry
JP7093883B1 (en) Manufacturing method of packaged food
JP7341421B2 (en) Preserved food and method for producing preserved food
US20210204577A1 (en) System and method for using calcium chloride to create a flavored tomato product
CN101366536A (en) Instant blue crab foods and its processing method
JPH03290172A (en) Sterilizing preservation of food
RU2307512C1 (en) Method for processing and preparing of meat-containing packaged product
JP2022077499A (en) Method of producing food product
CN102101538A (en) Vacuum packaging method of smoked chicken and series products
JP2002171950A (en) Dry food material with heat history under pressure and method for producing the same

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2014504866

Country of ref document: JP

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13859932

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 14649627

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 13859932

Country of ref document: EP

Kind code of ref document: A1