WO2014073334A1

WO2014073334A1 - Wet wipe and packaging for wet wipe

Info

Publication number: WO2014073334A1
Application number: PCT/JP2013/077971
Authority: WO
Inventors: 坂東　健司; 隆宏植田
Original assignee: ユニ・チャーム株式会社
Priority date: 2012-11-09
Filing date: 2013-10-15
Publication date: 2014-05-15
Also published as: AU2013342725A1; JP2014094188A; TW201440713A; CN104603359A; KR102014909B1; IN2015DN03901A; MY163242A; KR20150084032A; JP6091168B2; CN104603359B

Abstract

The purpose of the present invention is to provide a wet wipe that can easily be withdrawn one at a time. The wet wipe disclosed herein has the following configuration. A wet wipe (105) including a nonwoven cloth (23) manufactured by a wet process, and a medicinal solution impregnated into the nonwoven cloth (23), the wet wipe (105) characterized in that the nonwoven cloth (23) includes synthetic fibers having a specific gravity of more than 1.0 in the amount of 5-40% by mass of the nonwoven cloth (23), and cellulose-based fibers in the amount of 60-95% by mass of the nonwoven cloth (23), the synthetic fibers including synthetic fibers (1) having a heteromorphic cross-sectional shape in the amount of 20-100% by mass of the synthetic fibers.

Description

Wet wipes and wet wipes packaging

The present invention relates to wet wipes and wet wipes packages.

Attempts have been made to produce bulky nonwoven fabrics by a wet process. For example, in Patent Document 1, a papermaking raw material containing moisture is supplied onto a support for the purpose of obtaining a nonwoven fabric having high strength, bulkiness, and flexibility. Forming a layer and injecting high-pressure steam onto the paper layer using a steam nozzle, and the step of injecting high-pressure steam into the paper layer has a moisture content of the paper layer of 10 to 45. The manufacturing method of the nonwoven fabric which injects high-pressure water vapor | steam to the said paper layer after setting to% is described.

In addition, Patent Document 2 aims to provide a nonwoven fabric having high strength, bulkiness, and flexibility, and supplies a papermaking raw material containing moisture onto the support. A step of forming a paper layer, a step of injecting a high-pressure water stream onto the paper layer from a high-pressure water nozzle provided on the support, and a high-pressure water stream from a steam nozzle provided on the support. A method for producing a non-woven fabric is described, which includes a step of spraying high-pressure steam onto the sprayed paper layer and a step of drying the paper layer sprayed with the high-pressure steam.

JP 2012-202004 A JP 2012-202011 A

The nonwoven fabric produced by Patent Document 1 and Patent Document 2 has high strength, is bulky, and has flexibility, but is a wet wipes package, particularly a pop-up wet wipes package. Then, depending on use conditions, wet wipes may be connected by a water film of a chemical solution, and a plurality of wet wipes may be taken out from the packaging body at a time, leaving room for improvement.
Therefore, an object of the present disclosure is to provide wet wipes that can be easily taken out one by one.

The present disclosure is a wet wipe comprising a nonwoven fabric produced by a wet method and a chemical liquid impregnated in the nonwoven fabric, wherein the nonwoven fabric has a specific gravity of 1.40% by mass of the nonwoven fabric. More than 0 synthetic fibers and 60 to 95% by weight cellulosic fibers of the nonwoven fabric, and the synthetic fibers comprise 20 to 100% by weight of the synthetic fibers and synthetic fibers having an irregular cross-sectional shape We have found a wet wipe characterized by this.

The wet wipes of the present disclosure can be easily taken out one by one.

FIG. 1 is a diagram illustrating an example of an irregular cross-sectional shape of a synthetic fiber having an irregular cross-sectional shape. FIG. 2 is a diagram illustrating another example of the irregular cross-sectional shape of the synthetic fiber having the irregular cross-sectional shape. FIG. 3 is a diagram for explaining a cross-sectional shape. FIG. 4 is a schematic view of a nonwoven fabric manufacturing apparatus for manufacturing a nonwoven fabric. FIG. 5 is a diagram illustrating an example of a high-pressure water flow nozzle. FIG. 6 is a diagram illustrating an example of a steam nozzle. FIG. 7 is a perspective view of a wet wipes package according to one embodiment of the present disclosure. FIG. 8 is a cross-sectional view taken along line AA of the wet wipes package 101 shown in FIG. FIG. 9 is a view for explaining a plurality of wet wipes housed in the wet wipes package shown in FIG. 8. FIG. 10 is a cross-sectional view of a wet wipes package according to another embodiment of the present disclosure. FIG. 11 is a cross-sectional view of a wet wipes package according to yet another embodiment of the present disclosure.

Hereinafter, the wet wipes of the present disclosure will be described in detail below.
The wet wipes of the present disclosure includes a nonwoven fabric produced by a wet method and a chemical liquid impregnated in the nonwoven fabric.
The nonwoven fabric produced by the wet method includes about 5 to about 40% by weight of the nonwoven fabric, a synthetic fiber having a specific gravity of more than 1.0, and about 60 to about 95% by weight of the nonwoven fabric of cellulosic fibers. .
The synthetic fibers include synthetic fibers having an irregular cross-sectional shape that is about 20 to about 100% by mass of the synthetic fibers.

In the present specification, “irregular cross-sectional shape” means a cross-sectional shape other than a substantially circular shape.
The irregular cross-sectional shape is preferably a cross-sectional shape having at least one depression, more preferably a cross-sectional shape consisting of a substantially polygonal shape and having at least one side of the substantially polygonal shape depressed, and More preferably, the cross-sectional shape is formed of a substantially polygonal shape and all sides of the substantially polygonal shape are recessed.
In the present specification, the “synthetic fiber having an irregular cross-sectional shape” may be abbreviated as an irregular cross-sectional synthetic fiber, and the “abnormal cross-sectional shape” may be abbreviated as an irregular cross-section.

Examples of the polygon include a substantially n-gonal shape (n is an integer of 3 or more, for example, an integer of 3 to 12, for example, a substantially triangular shape, a substantially rectangular shape, a substantially pentagonal shape, a substantially hexagonal shape, a substantially heptagonal shape, a substantially octagonal shape. A square shape etc. are mentioned.

1 (a) to 1 (d) are diagrams showing examples of deformed sections of deformed section synthetic fibers. The modified cross-section synthetic fiber 1 shown in FIG. 1A has a substantially triangular shape and a cross-sectional shape in which all three sides are recessed. More specifically, the modified cross-section synthetic fiber 1 shown in FIG. 1A is formed between three protrusions 3 (3 ′, 3 ″, and 3 ′ ″) and two adjacent protrusions 3. And has a cross-sectional shape having a total of three indentations 2 (2 ′, 2 ″ and 2 ′ ″).

The deformed cross-section synthetic fiber 1 shown in FIG. 1B has a substantially square shape and a cross-sectional shape in which all four sides are recessed. More specifically, the modified cross-section synthetic fiber 1 shown in FIG. 1 (b) has four protrusions 3 (3 ′, 3 ″, 3 ′ ″ and 3 ″ ″) adjacent to 2 It has a cross-sectional shape having a total of four depressions 2 (2 ′, 2 ″, 2 ′ ″ and 2 ″ ″) formed between the two protrusions 3.
In addition, the cross section of the irregular cross-section synthetic fiber 1 shown by FIG.1 (b) is also called a cross-section.

The deformed cross-section synthetic fiber 1 shown in FIG. 1C has a substantially pentagonal shape and a cross-sectional shape in which all five sides are recessed. More specifically, the modified cross-section synthetic fiber 1 shown in FIG. 1 (c) includes five protrusions 3 (3 ′, 3 ″, 3 ′ ″, 3 ″ ″ and 3 ″ ″. ') And two indentations 2 formed between two adjacent protrusions 3 (2', 2 '', 2 ''',2''''and2''''') And has a cross-sectional shape.
In addition, the cross section of the irregular cross-section synthetic fiber 1 shown by FIG.1 (c) is also called a star-shaped cross section.

The deformed cross-section synthetic fiber 1 shown in FIG. 1D has a substantially hexagonal shape and a cross-sectional shape in which all six sides are recessed. More specifically, the modified cross-section synthetic fiber 1 shown in FIG. 1 (d) includes six protrusions 3 (3 ′, 3 ″, 3 ′ ″, 3 ″ ″, 3 ″ ″. 'And 3 """) and two adjacent protrusions 3 formed in total 6 recesses 2 (2', 2", 2 '", 2"") , 2 '''''' and 2 '''''').
In addition, the cross section of the irregular cross-section synthetic fiber 1 shown by FIG.1 (d) is also called a star-shaped cross section.

1 (a) to 1 (d) show examples of cross sections in which all sides are recessed in the modified cross-section synthetic fiber, but in the case of wet wipes according to other embodiments of the present disclosure, the modified cross-section synthesis At least one side constituting the cross section of the fiber does not need to have a depression.
For example, in the modified cross-section synthetic fiber 1 shown in FIG. 1 (b), at least one of the four sides forming a substantially quadrilateral does not have to have a depression, that is, four depressions 2 ′, 2 ″. , 2 ″ ′ and 2 ″ ″, at least one recess may not be formed.

2 (a) to 2 (c) are diagrams showing another example of a modified cross section in a modified synthetic fiber. A modified cross-section synthetic fiber 1 shown in FIG. 2A has a substantially C-shaped cross-sectional shape, and has one recess 2 and two protrusions 3.

A modified cross-section synthetic fiber 1 shown in FIG. 2 (b) has a substantially V-shaped cross-sectional shape, and has one recess 2 and two protrusions 3.
A modified cross-section synthetic fiber 1 shown in FIG. 2C has a substantially W-shaped cross-sectional shape, and includes three depressions 2 and two protrusions 3.

As shown in FIG. 1 and FIG. 2, the modified cross-section synthetic fiber can hold a chemical solution containing water having a high surface tension in a recess or the like in its cross section. Therefore, it is difficult to connect one by one, and it can be easily taken out one by one and is easy to take out.

In addition, even when a large amount of chemical liquid is retained in the wet wipes, the modified cross-section synthetic fiber has a high volume that retains the chemical liquid containing water with high surface tension in the recess of the cross section, etc. It is difficult for wet wipes to be connected to each other by a water film of a chemical solution, and it is possible to achieve both high chemical solution concentration and ease of removal.

Furthermore, since the irregular cross-section synthetic fiber is higher in rigidity than a general synthetic fiber having the same fineness (dtex), for example, a synthetic fiber having a substantially circular cross-sectional shape, the nonwoven fabric including the irregular cross-section synthetic fiber is a chemical solution. Even when it is impregnated, the bulk tends not to be crushed. Therefore, since the buttocks of the nonwoven fabric formed by the high-pressure water stream and the high-pressure steam can maintain the bulk and keep the chemical liquid after impregnating the chemical liquid, It becomes difficult to connect by the membrane, and the phenomenon that a plurality of wet wipes are taken out from the packaging body at a time is reduced.

In addition, the cross section of the irregular-shaped synthetic fiber can be defined by the degree of irregularity when an inscribed circle and a circumscribed circle can be assumed.
The degree of profile is based on the radius r _IC of the inscribed circle of the cross section and the radius r _CC of the circumscribed circle of the cross section:
Deformity = r _CC / r _IC
Can be defined by

In wet wipes according to one of the embodiments of the present disclosure, the profile is preferably in the range of about 1.2 to about 10.0, and in the range of about 1.4 to about 8.0. Is more preferably in the range of about 1.6 to about 6.0, even more preferably in the range of about 1.7 to about 5.0, and about 1.8 to about 4 Even more preferably in the range of 0.0.
Note that the synthetic fiber not having the above-described irregular cross-sectional shape can have an irregularity of about 1.0 to about 1.2.

The greater the degree of irregularity, the greater the volume that can hold a chemical solution containing water with high surface tension, but the larger the degree of irregularity, the thinner the outer edge of the fiber cross section may become weaker, The degree of profile is preferably within the above range.
The circumscribed circle and its radius are represented as CC and r _CC in FIGS. 3A to 3D, respectively, and the inscribed circle and its radius are similarly represented as IC and r _IC , respectively. It has been.

In the wet wipes of the present disclosure, the modified cross-section synthetic fiber has a cross-sectional shape having three protrusions and three depressions as shown in FIG. 1 (a), or FIG. 1 (b). It is preferable to have a cross-sectional shape having four protrusions and four depressions as shown in FIG. 1, and four protrusions and four depressions as shown in FIG. It is more preferable to have a cross-sectional shape having

The synthetic fiber may include, in addition to the irregular cross-section synthetic fiber, a synthetic fiber having no irregular cross-sectional shape, for example, a synthetic fiber having a substantially circular cross-sectional shape.
Synthetic fibers having no irregular cross-sectional shape can be entangled with other synthetic fibers or other cellulosic fibers to impart strength, particularly wet strength, to the wet wipes of the present disclosure.

Examples of the synthetic fibers include polyolefins such as polyethylene and polypropylene, polyesters such as polyethylene terephthalate (PET), polyamides such as nylon, and the like. As the synthetic fiber, polyethylene terephthalate is preferable from the viewpoint of the stability of papermaking.

The synthetic fiber preferably has a fineness of about 0.5 to about 3.0 dtex. The synthetic fiber preferably has a fiber length of about 3 to about 15 mm. This is from the viewpoint of the stability of papermaking and the strength of the wet wipes formed, particularly the wet strength.

The synthetic fiber has a specific gravity greater than about 1.0. Since the nonwoven fabric constituting the wet wipes of the present disclosure is manufactured by a wet method, if the synthetic fiber has a specific gravity of about 1.0 or less, it is difficult to form a homogeneous web because the synthetic fiber floats in water. Because it becomes.
The synthetic fiber has no upper limit on the specific gravity from the viewpoint of the wet method, and the upper limit will be about 1.5 considering the specific gravity of a general synthetic fiber used for wet wipes.

The synthetic fiber, in particular, the modified cross-section synthetic fiber may be a hydrophilic synthetic fiber. This is because it becomes easier to hold a chemical solution containing water having a high surface tension in a recess or the like of the cross section.
Examples of the hydrophilization treatment include coating the surface of the synthetic fiber with a hydrophilic agent, mixing the hydrophilic agent with a synthetic resin that is a raw material of the synthetic fiber, and the like.

Examples of the cellulosic fibers include pulp, for example, wood pulp, for example, soft pulp, hardwood and other chemical pulp, semi-chemical pulp, mechanical pulp, mercerized pulp and crosslinked pulp formed by chemically treating the wood pulp, Non-wood fibers such as hemp and cotton, and regenerated cellulose fibers such as rayon, for example, viscose rayon, copper ammonia rayon and the like.

As the cellulose-based fiber, a combination of pulp and rayon is preferable from the viewpoints of the strength of wet wipes to be formed, particularly wet strength and touch, and cost.
Moreover, it is preferable that the said cellulose fiber has specific gravity over about 1.0 from a viewpoint of manufacturing the nonwoven fabric which comprises wet wipes with a wet method.

The nonwoven fabric constituting the wet wipes of the present disclosure comprises about 5 to about 40% by mass of the nonwoven fabric, a synthetic fiber having a specific gravity of more than 1.0, and about 60 to about 95% by mass of the cellulose-based fiber of the nonwoven fabric. Including, preferably, about 5 to about 30% by weight of the nonwoven fabric, synthetic fibers having a specific gravity greater than 1.0, and about 70 to about 95% by weight cellulosic fibers of the nonwoven fabric, and more preferably About 5 to about 20% by weight of the nonwoven fabric, synthetic fibers having a specific gravity greater than 1.0, and about 80 to about 95% by weight of the nonwoven fabric of cellulosic fibers. This is from the viewpoint of the strength of the wet wipes formed, particularly the wet strength.

In the nonwoven fabric constituting the wet wipes of the present disclosure, the synthetic fiber includes about 20 to about 100% by mass of the modified cross-section synthetic fiber, and preferably about 30 to about 90% by mass of the odd-shaped cross-section synthetic fiber. And more preferably from about 40 to about 80% by weight of modified cross-section synthetic fibers. When the amount of the modified cross-section synthetic fiber is in the above range, the wet wipes can be easily taken out one by one, particularly in the pop-up type wet wipes package.

In the present specification, the “pop-up type” related to the wet wipes packaging means that the wet wipes can be sequentially taken out from the wet wipes packaging. More specifically, when a certain wet wipe is taken out, it means that a part of the next wet wipe protrudes from the opening of the wet wipes package.

The nonwoven fabric constituting the wet wipes of the present disclosure includes a modified cross-section synthetic fiber having a specific gravity of more than 1.0 and about 1 to about 20 mass% of the nonwoven fabric, and an irregular shape of about 1 to about 20 mass% of the nonwoven fabric. And about 10 to about 40% by weight rayon of the nonwoven fabric and about 50 to about 85% pulp by weight of the nonwoven fabric. 15% by mass of a deformed cross-section synthetic fiber having a specific gravity of more than 1.0, about 2 to about 15% by mass of the non-woven fabric, a synthetic fiber having no irregular cross-sectional shape, and about 15 to about 30 mass of the non-woven fabric % Of rayon and about 55 to about 80% by weight of the non-woven fabric, and about 3 to about 10% by weight of the non-woven non-woven synthetic fiber having a specific gravity of more than 1.0 About 3 to about 10% by weight of the nonwoven fabric, And no synthetic fiber surface shape, and rayon about 15 to about 25 weight percent of the non-woven fabric, more preferably comprising about 55 to about 79 weight percent of pulp non-woven fabric.

When the nonwoven fabric has the above-described configuration, the formed wet wipes can be easily taken out one by one, and the formed wet wipes are excellent in strength, particularly wet strength.

The chemical solution to be impregnated into the nonwoven fabric is not particularly limited, and examples thereof include a mixture of antiseptics such as distilled water, propylene glycol, and parabens.
The wet wipes of the present disclosure preferably contain the chemical solution in a ratio of about 180 to about 400 parts by mass per 100 parts by mass of the nonwoven fabric. This is from the viewpoint of the stain removal property of wet wipes and the moisture remaining property on an object (for example, skin) from which the stain is removed.
In addition, in order to achieve both high chemical solution concentration and easy removal, when wet wipes hold a large amount of chemical solution, the wet wipes of the present disclosure are approximately the above chemical solution per 100 parts by mass of the nonwoven fabric. It may be included in a ratio of 300 to about 400 parts by mass.

The nonwoven fabric constituting the wet wipes of the present disclosure is not particularly limited except that the fibers constituting the nonwoven fabric are adjusted to a predetermined range. For example, the nonwoven fabric is manufactured according to the methods described in Patent Literature 1 and Patent Literature 2. be able to.
Hereinafter, an example of the manufacturing method of the nonwoven fabric which comprises the wet wipes of this indication is shown.

FIG. 4 is a schematic view of the nonwoven fabric manufacturing apparatus 11 for manufacturing the nonwoven fabric.
A papermaking raw material containing synthetic fibers and cellulosic fibers is supplied from a raw material supply head 12 onto a support of a web forming conveyor 13 to form a web 14 on the support. The support preferably has air permeability through which steam can pass, and examples thereof include a wire mesh and a blanket.

The web 14 formed on the support is moderately dehydrated by the suction box 15. The web 14 collects water jetted from the two high-pressure water nozzles 16 disposed on the upper surface of the web 14 and the high-pressure water nozzle 16 disposed at a position facing the high-pressure water nozzle 16 across the web 14. It passes between the two suction boxes 15 to perform. At this time, the web 14 has a groove formed on the upper surface (the surface on the high pressure water flow nozzle 16 side) due to the high pressure water flow injected from the high pressure water flow nozzle 16.

An example of the high-pressure water flow nozzle 16 is shown in FIG. A plurality of high-pressure water streams 31 arranged in the width direction (CD) of the web 14 are jetted toward the web 14 from the high-pressure water nozzle 16. As a result, a plurality of grooves 32 extending in the machine direction (MD) along the width direction of the web 14 are formed on the upper surface of the web 14. Moreover, the fibers of the web 14 are entangled by injecting the high-pressure water stream 31 onto the web 14.

Next, as shown in FIG. 4, the web 14 is transferred to the web transport conveyor 18, and then the web 14 is transferred to the web transport conveyor 19. Next, the web 14 is transferred to the drying dryer 20. An example of the drying dryer 20 is a Yankee dryer. The web 14 is attached to a drum heated to about 120 ° C. by steam and dried.

The moisture content of the web 14 is preferably adjusted to about 10 to about 45% by mass by drying with the drying dryer 20, and more preferably about 20 to about 40% by mass. In the present specification, the moisture content is the percentage of water relative to the total mass of the web containing water. When the moisture content of the web is lower than 10% by mass, the hydrogen bonding force between the web fibers becomes strong, and the energy required to loosen the web fibers by high-pressure steam described later becomes very high. On the other hand, when the moisture content of the web is higher than 45% by mass, the energy required for drying the web below a predetermined moisture content by high-pressure steam described later becomes very high.

Next, the web 14 is moved onto the mesh-shaped outer peripheral surface of the cylindrical suction drum 21, and high-pressure steam is sprayed onto the web 14 from the steam nozzle 22 disposed above the suction drum 21. Another groove is formed on the same surface (surface on the steam nozzle 22 side) of the web 14 as the surface on which the groove is formed by the high-pressure water flow 31 by the high-pressure steam jetted from the steam nozzle 22, and the nonwoven fabric 23 is formed. It is formed.

An example of the steam nozzle 22 is shown in FIG. A plurality of high-pressure steams 41 arranged in the width direction (CD) of the web 14 are jetted from the steam nozzle 22 toward the web 14. As a result, a plurality of grooves 42 extending in the machine direction (MD) are formed on the upper surface of the nonwoven fabric 23 to be formed.

The moisture content of the nonwoven fabric 23 after jetting high-pressure steam is preferably 45% by mass or less, and more preferably 40% by mass or less. If the moisture content is higher than 45% by mass, it may be difficult to reduce the moisture content of the nonwoven fabric 23 to 5% by mass or less by drying with a drying drier described later.

Next, as shown in FIG. 4, the nonwoven fabric 23 is transferred to a drying dryer 24. An example of the drying dryer 24 is a Yankee dryer. The nonwoven fabric 23 is attached to a drum heated to about 150 ° C. by steam and dried. The moisture content of the nonwoven fabric 23 after passing through the drying dryer 24 is preferably 5% by mass or less.
Next, the nonwoven fabric 23 is wound around the winder 25.

The nonwoven fabric constituting the wet wipes of the present disclosure can be manufactured, for example, according to the methods described in Patent Document 1 and Patent Document 2, in addition to the above-described method. For details, refer to Patent Document 1 and Patent Document 2. Please refer.

The nonwoven fabric constituting the wet wipes of the present disclosure can have a plurality of ridges and grooves derived from a high-pressure water stream, high-pressure steam, and the like. By adjusting the surface to which the high-pressure water stream and high-pressure steam are jetted, it is possible to form a plurality of types of ridges and grooves having different pitches and heights on the same surface of the nonwoven fabric, and pitch and height on different surfaces of the nonwoven fabric. Different ridges and grooves can be formed.

Moreover, the nonwoven fabric which comprises the wet wipes of this indication can have a convex part and a recessed part which originate in the shape of a support body.
The wet wipes of the present disclosure can be manufactured by impregnating a non-woven fabric constituting the wet wipes with a chemical solution.

7 is a perspective view of a wet wipes package according to one embodiment of the present disclosure, and FIG. 8 is a cross-sectional view taken along line AA of the wet wipes package 101 shown in FIG. It is.
In the wet wipes packaging body 101 shown in FIG. 7, a plurality of wet wipes (not shown) are sequentially taken out inside the packaging body 102 having a top portion T having an opening 103 and a bottom portion B. It is stored in a form that can be used.
The packaging body 102 has a sealing material 104 that covers the opening 103.

The packaging body 102 has a bag shape, and when the opening 103 is sealed with the sealing material 104, the wet wipes inside the packaging body 102 can be sealed, and the evaporation of the medicine is suppressed. Each wet wipe can be removed through the opening 103. The sealing material 104 is coated with an adhesive on the surface in contact with the packaging body 102 in order to repeatedly seal the wet wipes inside the packaging body 102.

As shown in FIG. 8, a plurality of wet wipes 105 are stacked in the direction from the top T to the bottom B inside the packaging body 102. In FIG. 8, the plurality of wet wipes 105 have a substantially Z-shaped folded structure.

FIG. 9 is a view for explaining a plurality of wet wipes housed in the wet wipes package shown in FIG. 8.
In FIG. 9, the wet wipes 105 ′ and the wet wipes 105 ″ have a portion 105 ″ T of the wet wipes 105 ″ (bottom side wet wipes) located on the bottom B side and the top thereof. Part 105′B of wet wipe 105 ′ (top wet wipe) adjacent to T side is part 105 ″ T of wet wipe 105 ″ (bottom wet wipe). 105 ′ (top wet wipes) overlap each other so as to be located on the top T side of a part 105′B.

Similarly, in FIG. 9, in relation to the wet wipes 105 ″ and the wet wipes 105 ′ ″, a portion 105 ′ of the wet wipes 105 ′ ″ (bottom side wet wipes) located on the bottom B side. ″ T and a portion 105 ″ B of the wet wipe 105 ″ (top wet wipe) adjacent to the top T side of the wet wipe 105 ′ ″ (bottom wet wipe) The portions 105 ′ ″ T overlap each other so as to be located on the top T side of the portion 105 ″ B of the wet wipes 105 ″ (the top wet wipes).

In the embodiment shown in FIG. 9, the top side end of the bottom wet wipes located on the bottom side and the bottom side end of the top wet wipes adjacent to the top side are the bottom side wet wipes. Are overlapped with each other so that the top side end portions are located on the top side with respect to the bottom side end portion of the top wet wipes.

A plurality of wet wipes are stacked as shown in FIGS. 8 and 9, so that when the wet wipes 105 ′ is taken out, a part of the wet wipes 105 ″ (mainly 105 ″ T) is pulled out and protrudes from the packaging body 102, making it easier to remove the wet wipes 105 '' for the next use.

When the part 105′B of the wet wipes 105 ′ and the part 105 ″ T of the wet wipes 105 ″ are connected by the water film of the chemical solution, when the wet wipes 105 ′ is taken out, The entire wet wipes 105 ″ may be removed together (in some cases, the entire wet wipes 105 ′ ″ may be removed together).

FIG. 10 is a cross-sectional view of a wet wipes package according to another embodiment of the present disclosure, and is a cross-sectional view corresponding to the line AA of the wet wipes package 101 shown in FIG. 7. In FIG. 10, the wet wipes 105 have a substantially C-shaped folding structure.
In the wet wipes packaging body 101 shown in FIG. 10, similarly to FIG. 9, the top side end of the bottom side wet wipes located on the bottom side, and the bottom of the top side wet wipes adjacent to the top side The side end portions overlap each other so that the top side end portion of the bottom side wet wipes is located on the top side with respect to the bottom side end portion of the top side wet wipes.

FIG. 11 is a cross-sectional view of a wet wipes package according to another embodiment of the present disclosure, and is a cross-sectional view corresponding to the line AA of the wet wipes package 101 shown in FIG. In FIG. 11, the wet wipes 105 have a substantially Z-shaped folding structure, similar to the embodiment shown in FIG. 8, but a plurality of wet wipes 105 are arranged in the opposite direction, and The range of overlapping with adjacent wet wipes is different from the embodiment shown in FIG.

7 to 11 can be manufactured according to a method known in the art, for example, a method described in JP-A-2000-51118.

Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to these examples.
The measurement conditions of the items evaluated in the examples and comparative examples are as follows.
[Nonwoven fabric basis weight]
The basis weight is measured according to 5.2 of JIS L 1906.
[Thickness of non-woven fabric]
The bulk is measured using a THICKNESS GAUGE UF-60 manufactured by Daiei Scientific Instruments.

[Removal test of wet wipes]
The non-woven fabric is cut into a size of 190 × 135 mm (extraction direction × width direction), and a total of 60 sheets are laminated as shown in FIG. 8, and the 60 laminates are packaged in a packaging body. Subsequently, the nonwoven fabric is impregnated with the chemical at a ratio of 250 parts by mass with respect to 100 parts by mass of the non-woven fabric, and then the package body is sealed to produce a pop-up wet wipes package.
The chemical solution contains water, propylene glycol as a moisturizing agent, and a preservative.

A pop-up wet wipes package is set in a commercially available wet wipe case, and the wet wipes are taken out one by one.
When the n-th wet wipes (1, 2,..., n,..., 60) are taken out, they are pulled together by the n-th wet wipes (wet wipes taken directly) together. The number of wet wipes taken out (indirectly taken out wet wipes) is counted.

For example, when the n-th wet wipe is taken out and the (n + 1) -th wet wipe below is pulled by the n-th wet wipe and taken out together The wet wipes taken out indirectly are counted as one sheet.

When the n-th wet wipe is taken out, the (n + 1) -th wet wipe below the first is pulled together by the n-th wet wipe and taken down by the second. When the (n + 2) -th wet wipes are pulled together by being pulled by the (n + 1) -th wet wipes, the indirectly removed wet wipes are counted as two. .

The experiment is continued until all 60 wet wipes are taken out, and the total number m of wet wipes taken out indirectly is counted.
Ease of removal (%), the following formula:
Ease of removal (%) = 100 × (60−m) / 60
Calculate according to

For example, when the total number of wet wipes taken out indirectly is 0, the take-out ease is 100%, and the total number of wet wipes taken out indirectly is 30 (all wet In the case of half of wipes), the ease of removal is 50%.

[Example 1]
71% by weight of softwood bleached kraft pulp (NBKP), 21% by weight of rayon (Corona, manufactured by Daiwabo Rayon Co., Ltd.) having a fineness of 1.1 dtex and a fiber length of 7 mm, a fineness of 0.6 dtex and 4% by mass of polyethylene terephthalate fiber having a fiber length of 10 mm and 4% by mass of polyethylene terephthalate fiber having a cross-section having a fineness of 2.2 dtex and a fiber length of 5 mm (trade name: X531 manufactured by Unitika Ltd.) % Was prepared, and the nonwoven fabric 1 was manufactured using the nonwoven fabric manufacturing apparatus as shown in FIG.
The polyethylene terephthalate fiber had an inscribed circle radius r _IC of 8.9 μm, a circumscribed circle radius r _CC of 17.1 μm, and an irregularity of 1.92. .

Specifically, a papermaking raw material was supplied from a raw material supply head onto a support (OS80 manufactured by Nippon Filcon Co., Ltd.), and the papermaking raw material was dehydrated using a suction box to form a web. The moisture content of the web was 80% by mass. Next, a high-pressure water stream was jetted from two high-pressure water stream nozzles onto the web. Using two high-pressure water nozzles, the high-pressure water energy injected into the web was about 0.285 kW / m ² .

The high-pressure water flow energy (kW / m ² ) is expressed by the following formula:
High-pressure water flow energy (kW / m ² )
= 1.63 × injection pressure (kg / cm ² ) × injection flow rate (m ³ / min) / processing time (m / min)
Is calculated by
The injection pressure (kg / cm ² ) is expressed by the following formula:
Injection pressure (kg / cm ² )
= 750 × Orifice opening total area (m ² ) × Injection pressure (kg / cm ² ) ^0.495
Is calculated by

The distance between the tip of the high pressure water nozzle and the top surface of the web was about 10 mm. Moreover, the hole diameter of the high-pressure water flow nozzle was about 92 μm, and the hole pitch was about 0.5 mm.
The web was transferred to two web conveyors and then transferred to a Yankee dryer heated to 120 ° C. and dried.

Next, high-pressure steam was sprayed from one steam nozzle onto the web. The vapor pressure of the high pressure steam was about 0.7 MPa and the steam temperature was about 175 ° C. The distance between the tip of the steam nozzle and the upper surface of the web was about 2 mm. Furthermore, the hole diameter of the steam nozzle was about 300 μm, and the hole pitch was about 2.0 mm. The suction force with which the suction drum sucks the web was about -1 kPa. A stainless steel 18 mesh perforated sleeve was used on the outer periphery of the suction drum.

Next, the web was transferred to a Yankee dryer heated to 150 ° C. and dried to produce a nonwoven fabric 1. Nonwoven fabric 1 had a basis weight of 48 g / m ² and a thickness of 0.318 mm.
In Example 1, the paper making speed was about 70 m / min.

Next, a pop-up wet wipes package 1 was produced from the nonwoven fabric 1 and subjected to the above-described removal test. As a result, the ease of removal (%) was 97%.

[Comparative Example 1]
71% by weight of softwood bleached kraft pulp (NBKP), 21% by weight of rayon (Corona, manufactured by Daiwabo Rayon Co., Ltd.) having a fineness of 1.1 dtex and a fiber length of 7 mm, a fineness of 0.6 dtex and A nonwoven fabric 2 was produced in the same manner as in Example 1 except that the raw material was changed to a papermaking raw material containing 8% by mass of polyethylene terephthalate fiber having a fiber length of 10 mm. Nonwoven fabric 2 had a basis weight of 48 g / m ² and a thickness of 0.322 mm.
Further, when a take-out test was carried out in the same manner as in Example 1, the take-out ease (%) was 80%.

The present disclosure relates to the following J1 to J12.
[J1]
A wet wipe containing a nonwoven fabric produced by a wet method and a chemical liquid impregnated in the nonwoven fabric,
The non-woven fabric includes 5 to 40% by mass of the non-woven fabric and a synthetic fiber having a specific gravity exceeding 1.0, and 60 to 95% by mass of the non-woven fabric cellulosic fiber, and the synthetic fiber is the synthetic fiber. 20 to 100% by weight of a synthetic fiber having an irregular cross-sectional shape,
The wet wipes as described above.

[J2]
The wet wipes according to J1, wherein the synthetic fiber having an irregular cross-sectional shape has a cross-sectional shape having at least one recess.
[J3]
The wet wipes according to J1 or J2, wherein the synthetic fiber having the irregular cross-sectional shape has a cross-sectional shape that is formed of a substantially polygonal shape and at least one side of the substantially polygonal shape is recessed.

[J4]
Any one of J1 to J3, wherein the synthetic fiber having the irregular cross-sectional shape is selected from the group consisting of a substantially triangular shape, a substantially square shape, a substantially pentagonal shape, and a substantially hexagonal shape and has a cross-sectional shape in which all sides are recessed. The wet wipes according to the item.

[J5]
The wet wipes according to J1 or J2, wherein the synthetic fiber having the irregular cross-sectional shape has a cross-sectional shape selected from the group consisting of a substantially C-type, a substantially V-type, and a substantially W-type.
[J6]
The wet wipes according to any one of J1 to J5, wherein the synthetic fiber having an irregular cross-sectional shape is a polyethylene terephthalate fiber.

[J7]
The wet wipes according to any one of J1 to J6, wherein the synthetic fiber having an irregular cross-sectional shape is hydrophilized.
[J8]
The wet wipes according to any one of J1 to J7, wherein the cellulosic fibers include pulp and regenerated cellulose fibers.

[J9]
The wet wipes according to any one of J1 to J8, which contains the chemical solution in a ratio of 300 to 400 parts by mass per 100 parts by mass of the nonwoven fabric.
[J10]
The non-woven fabric is 1 to 20% by mass of the non-woven fabric, a synthetic fiber having an irregular cross-sectional shape having a specific gravity of more than 1.0, and a synthetic fiber having 1 to 20% by mass of the non-woven fabric and not having an irregular cross-sectional shape The wet wipes according to any one of J1 to J9, comprising fibers, 10 to 40% by weight of rayon of the nonwoven fabric, and 40 to about 88% by weight of pulp of the nonwoven fabric.

[J11]
A plurality of wet wipes are stored in a form that can be sequentially taken out inside a packaging main body having a top part having an opening and a bottom part.
A plurality of wet wipes according to any one of J1 to J10 are stacked in a direction from the bottom to the top,
A part of the bottom wet wipes located on the bottom side and a part of the top wet wipes adjacent to the top side are part of the bottom wet wipes of the top wet wipes. Overlapping each other so as to be located on the top side rather than a part,
The said package body characterized by the above-mentioned.

[J12]
The package according to J11, wherein the plurality of wet wipes have a substantially Z-folded structure.

1 Synthetic fiber with irregular cross-sectional shape (irregular cross-section synthetic fiber)
DESCRIPTION OF SYMBOLS 2 Indentation part 3 Protrusion part 11 Nonwoven fabric manufacturing apparatus 12 Raw material supply head 13 Web formation conveyor 14 Web 15 Suction box 16 High pressure water flow nozzle 18, 19 Web conveyance conveyor 20, 24 Drying dryer 21 Suction drum 22 Steam nozzle 23 Nonwoven fabric 25 Winder DESCRIPTION OF SYMBOLS 31 High pressure water flow 32 Groove part 41 High pressure steam 42 Groove part 101 Wet wipes packaging body 102 Packaging body 103 Opening part 104 Sealing material 105 Wet wipes

Claims

A wet wipe comprising a nonwoven fabric produced by a wet method and a chemical liquid impregnated in the nonwoven fabric,
The non-woven fabric includes 5 to 40% by mass of the non-woven fabric and a synthetic fiber having a specific gravity of more than 1.0, and 60 to 95% by mass of the non-woven cellulosic fiber, and the synthetic fiber is the synthetic fiber. 20 to 100% by weight of a synthetic fiber having an irregular cross-sectional shape,
The wet wipes characterized by the above.
The wet wipes according to claim 1, wherein the synthetic fiber having the irregular cross-sectional shape has a cross-sectional shape having at least one recess.
The wet wipes according to claim 1 or 2, wherein the synthetic fiber having an irregular cross-sectional shape has a cross-sectional shape that is formed of a substantially polygonal shape and at least one side of the substantially polygonal shape is recessed.
The synthetic fiber having an irregular cross-sectional shape is selected from the group consisting of a substantially triangular shape, a substantially square shape, a substantially pentagonal shape, and a substantially hexagonal shape, and has a cross-sectional shape in which all sides are recessed. The wet wipes according to claim 1.
The wet wipes according to claim 1 or 2, wherein the synthetic fiber having the irregular cross-sectional shape has a cross-sectional shape selected from the group consisting of a substantially C-type, a substantially V-type and a substantially W-type.
The wet wipes according to any one of claims 1 to 5, wherein the synthetic fiber having the irregular cross-sectional shape is a polyethylene terephthalate fiber.
The wet wipes according to any one of claims 1 to 6, wherein the synthetic fiber having an irregular cross-sectional shape is hydrophilized.
The wet wipes according to any one of claims 1 to 7, wherein the cellulosic fibers include pulp and regenerated cellulose fibers.
The wet wipes according to any one of claims 1 to 8, wherein the chemical liquid is contained at a ratio of 300 to 400 parts by mass per 100 parts by mass of the nonwoven fabric.
The non-woven fabric is 1 to 20% by mass of the non-woven fabric and has a specific gravity of more than 1.0. The wet wipes according to any one of claims 1 to 9, comprising fibers, 10 to 40% by weight of rayon of the nonwoven fabric, and 40 to about 88% by weight of pulp of the nonwoven fabric.
A plurality of wet wipes are stored in a form that can be sequentially taken out inside a packaging main body having a top part having an opening and a bottom part.
A plurality of wet wipes according to any one of claims 1 to 10 are stacked in a direction from the bottom to the top,
A part of the bottom-side wet wipes located on the bottom side and a part of the top-side wet wipes adjacent to the top side are a part of the bottom-side wet wipes of the top-side wet wipes. Overlapping each other so as to be located on the top side rather than a part,
The said package body characterized by the above-mentioned.
The package according to claim 11, wherein the plurality of wet wipes have a substantially Z-shaped folding structure.