WO2014072210A1 - Composition for permanently hydrophilizing polyolefin fibers and use thereof - Google Patents
Composition for permanently hydrophilizing polyolefin fibers and use thereof Download PDFInfo
- Publication number
- WO2014072210A1 WO2014072210A1 PCT/EP2013/072678 EP2013072678W WO2014072210A1 WO 2014072210 A1 WO2014072210 A1 WO 2014072210A1 EP 2013072678 W EP2013072678 W EP 2013072678W WO 2014072210 A1 WO2014072210 A1 WO 2014072210A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition according
- alkoxylated
- composition
- component
- group
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/007—Addition polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
- D06M13/295—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing polyglycol moieties; containing neopentyl moieties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
Definitions
- composition for the permanent hydrophilization of polyolefin fibers and their use
- Patent 4,988,449 discloses hydrophilizing compositions containing diethanolamides and nonionic surfactants, alkyl phosphates, quaternary ammonium salts and / or alkyl imidazolium salts, and used as liquid permeability agents for polyolefin nonwovens.
- No. 5,258,129 discloses hydrophilizing compositions which contain polyoxyalkylene-modified polydimethylsiloxanes, alone or in combination with nonionic surfactants, alkyl phosphates, quaternary ammonium salts and / or alkylimidazolium salts.
- EP 410 485 B1 discloses a method for hydrophilicizing polyolefin-by applying an aqueous alkoxylated surfactant to the surface of the fibers, wherein the composition either at least 80% consists of alkoxylated triglycerides of C 8 fatty acids, wherein these triglycerides a large proportion at least 80% of a mixture of alkoxylated or alkoxylated and hydrogenated ricinolein, a polyalkylene-modified water-soluble polydimethylsiloxane and an antistatic compound, the latter being, for example, a neutralized phosphoric acid ester, an alkoxylated phosphate, Potassium salt, ammonium salt or an alkoxylated ammonium salt.
- EP 0 839 947 A2 discloses hydrophilizing compositions which comprise nonionic surfactants in combination with a polyoxyalkylene-modified polydimethylsiloxane and / or a quaternary am
- EP 1 600 532 B1 describes hydrophilizing compositions which consist of an alkoxylated glycerol esterified with a fatty acid and an alkoxylated or alkoxylated and hydrogenated ricinolein esterified with a fatty acid.
- the invention is therefore based on the object of providing a composition with good permanent hydrophilizing properties as well as a rapid passage capability and a low tendency to migrate into adjacent hydrophobic nonwoven areas.
- This object is achieved according to the invention by a composition for the permanent hydrophilization of polyolefin fibers and filaments and textile fabrics produced therefrom, such as nonwovens and other nonwoven fabrics, according to claim 1.
- composition according to the invention for the permanent hydrophilization of polyolefin fibers and filaments and textile fabrics produced therefrom comprises:
- R 2 and R 3 independently of one another are an alkyl group having 1 to 22 C atoms, Hydroxyethyl or a polyglycol radical,
- Phosphate, lactate, citrate, and m and n are independently an integer from 1 to 6;
- quaternary ammonium compound is a solid at room temperature (20 ° C);
- R 4 , R 5 and R 6 are independent of each other
- any suitable bases such as LiOH, NaOH, KOH, NH 3 , mono-, di-, or triethanolamine can be used.
- the radicals R 1 to R 3 in formula (I) are preferably alkyl groups as derived from vegetable oils and oil mixtures.
- the radicals R 1 , R 2 and R 3 are particularly preferably derived from vegetable oils having a high proportion of saturated fatty acids, in particular palm oil or palm kernel oil.
- the composition according to the invention preferably consists of components (A), (B) and (C), and optionally one or more of the additives according to component (D).
- the component (A) is particularly preferably present in a proportion of 20-35% by weight, component (B) in an amount of 25-35% by weight and component (C) in a proportion of 35-45 Wt .-%, each based on the total weight of components (A), (B) and (C).
- the corrosion inhibitor is admixed subsequently to the application liquor.
- the emulsifier used is preferably likewise a fatty acid ethoxylate, particularly preferably a coconut fatty acid alkylate such as Genagen C100 from Clariant, a coconut fatty acid having up to 10 ethoxy units, or a coconut fatty acid having up to 10 ethoxy and 3 propoxy units.
- the proportion of the emulsifier in the composition according to the invention is preferably from 1 to 50% by weight, based on the total weight of the composition.
- polystyrene resin As the polyolefin, it is possible to preferably use homo- or copolymers based on ethylene or propylene.
- polystyrene resins examples include polyethylenes such as HDPE (high density polyethylene), LDPE (low density polyethylene), VLDPE (very low density polyethylene), LLDPE (linear low density polyethylene), MDPE (medium density Polyethylenes), UHMPEs (ultra high molecular weight polyethylenes), XLPE (cross-linked polyethylene), HPPE (high pressure polyethylenes); Polypropylenes such as isotactic polypropylene; syndiotactic polypropylene, metallocene catalyzed polypropylene, impact modified polypropylene; Random copolymers based on ethylene and propylene, block copolymers based on ethylene and propylene; EPM (poly [ethylene-co-propylene]); EPDM (poly [ethylene-co-propylene-co-conjugated diene]).
- HDPE high density polyethylene
- LDPE low density polyethylene
- VLDPE very low density polyethylene
- LLDPE linear low density
- polystyrene polystyrene
- Poly (methylstyrene) Poly (oxymethylene); Metallocene catalyzed alpha-olefin or cycloolefin copolymers such as norbornene-ethylene copolymers; Copolymers containing at least 60% ethylene and / or styrene and less than 40% monomers such as vinyl acetate, acrylic acid esters, methacrylic acid esters, acrylic acid, acrylonitrile or vinyl chloride.
- examples of such polymers are poly (ethylene-co-ethyl acrylate), poly (ethylene-co-vinyl acetate), poly (ethylene-co-vinyl chloride) and poly (styrene-co-acrylonitrile).
- graft copolymers and polymer blends that is to say mixtures of polymers in which, inter alia, the abovementioned polymers are present, for example polymer blends based on polyethylene and polypropylene.
- core / shell bicomponent fibers such as PE / PP and PP / PET bicopolymers can be used.
- composition according to the invention can be applied to the fibers, filaments or nonwovens in the form of an aqueous emulsion or in the form of an aqueous dispersion, preferably in an amount of from 0.1 to 2% based on the dry weight of the respective product (fiber, filament, Fleece).
- the fiber webs equipped according to the invention are particularly preferably uncompressed random fiber webs or nonwoven or chemically or physically bonded, for example needled or thermally fixed, nonwoven webs.
- Components A, B and C were thoroughly mixed, homogenized and optionally neutralized. Then, the resulting composition was diluted with distilled or demineralized water to form a dispersion containing 5% by weight of the composition.
- Components A, B and C were thoroughly mixed together, homogenized and optionally neutralized. Then, the resulting composition was diluted with distilled or demineralized water to form a dispersion containing 5% by weight of the composition.
- Component A 24.0% by weight of C12-C14 fatty alcohol polyethylene glycol ether 6EO
- Components A, B and C were thoroughly mixed together, homogenized and optionally neutralized. Then, the resulting composition was diluted with distilled or demineralized water to form a dispersion containing 5% by weight of the composition.
- a fiber preparation was prepared according to the compositions described in US 4,988,449, which consisted of a Alkyldiethanolamide, a salt of an acidic alkylphosphoric acid ester, a nonionic surfactant, and a quaternary modified polydimethylsiloxane.
- Comparative Example 6 As another example, a permanent hydrophilizing fiber preparation based on fatty acid polyethylene glycol esters commercially available under the name Stantex TM S 6327 (Pulcra Chemicals) was used.
- compositions according to Examples 1 and 2 and Comparative Examples 1 to 6 were used as a fiber preparation for the permanent hydrophilic finish of a polypropylene (PP) spunbond nonwoven having a basis weight of 15 g / m 2 .
- the time required for 5 ml of a synthetic urine solution to penetrate a prepared fleece and to pass into the underlying absorption layer of filter paper is measured.
- the measurement is carried out on the same nonwoven five times in succession, whereby the absorption filter paper is renewed in each case.
- the five readings are in seconds.
- a PP spunbond nonwoven with an inclination of 45 ° is placed on a filter paper serving as an absorption layer. It determines the run length required until a defined amount of a synthetic urine solution has been passed completely through the web into the underlying absorbent layer. To pass the test, a maximum drop length of 30 mm may be achieved.
- test In the ten-drop test according to an in-house test method, a 10-well metal stencil is placed on a nonwoven piece as an absorbent layer. In each well of the metal template, one drop of a synthetic urine solution is pipetted successively. A test field counts if the amount of fluid has been absorbed within 2 seconds by the underlying absorption layer. In order to obtain information about the permanence of a fiber preparation, the test is repeated after a waiting time of 3 minutes without replacing the absorption layer. The test result indicates the number of passed test fields.
- Grade 3 6 to 15 wetting sites with ⁇ 2 mm diameter visible
- Grade 4 more than 15 wetting sites with ⁇ 2 mm diameter visible
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Nonwoven Fabrics (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015540107A JP6241829B2 (en) | 2012-11-06 | 2013-10-30 | Composition for continuously hydrophilizing polyolefin fibers and use thereof |
DK13786214.0T DK2917398T3 (en) | 2012-11-06 | 2013-10-30 | Composition for permanent hydrophilization of polyolefin fibers and their use |
KR1020157013146A KR102106115B1 (en) | 2012-11-06 | 2013-10-30 | Composition for permanently hydrophilizing polyolefin fibers and use thereof |
MYPI2015701324A MY185896A (en) | 2012-11-06 | 2013-10-30 | Composition for permanently hydrophilizing polyolefin fibers and use thereof |
CN201380058160.5A CN104903509B (en) | 2012-11-06 | 2013-10-30 | For the composition and its purposes of polyolefine fiber permanent hydrophilic |
ES13786214.0T ES2613880T3 (en) | 2012-11-06 | 2013-10-30 | Composition for permanent hydrophilization of polyolefin fibers and their use |
US14/439,280 US20150292144A1 (en) | 2012-11-06 | 2013-10-30 | Composition for permanently hydrophilizing polyolefin fibers and use thereof |
EP13786214.0A EP2917398B1 (en) | 2012-11-06 | 2013-10-30 | Composition for permanently hydrophilizing polyolefin fibers and use thereof |
SA515360388A SA515360388B1 (en) | 2012-11-06 | 2015-05-05 | Composition for permanently hydrophilizing polyolefin fibers and use thereof |
IL238665A IL238665B (en) | 2012-11-06 | 2015-05-06 | Composition for permanently hydrophilizing polyolefin fibers and use thereof |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012021742.0 | 2012-11-06 | ||
DE102012021742.0A DE102012021742A1 (en) | 2012-11-06 | 2012-11-06 | Composition for the permanent hydrophilization of polyolefin fibers and their use |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014072210A1 true WO2014072210A1 (en) | 2014-05-15 |
Family
ID=49518945
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2013/072678 WO2014072210A1 (en) | 2012-11-06 | 2013-10-30 | Composition for permanently hydrophilizing polyolefin fibers and use thereof |
Country Status (12)
Country | Link |
---|---|
US (1) | US20150292144A1 (en) |
EP (1) | EP2917398B1 (en) |
JP (1) | JP6241829B2 (en) |
KR (1) | KR102106115B1 (en) |
CN (1) | CN104903509B (en) |
DE (1) | DE102012021742A1 (en) |
DK (1) | DK2917398T3 (en) |
ES (1) | ES2613880T3 (en) |
IL (1) | IL238665B (en) |
MY (1) | MY185896A (en) |
SA (1) | SA515360388B1 (en) |
WO (1) | WO2014072210A1 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102014111881A1 (en) | 2014-08-20 | 2016-02-25 | Klaus Schmitt Beteiligungsgesellschaft Mbh | Aqueous waterproofing agent for fabrics of hydrophobic thermoplastic materials and products made therefrom |
WO2016098796A1 (en) * | 2014-12-17 | 2016-06-23 | 花王株式会社 | Liquid film cleavage agent |
DE102014119332A1 (en) | 2014-12-22 | 2016-06-23 | Schill + Seilacher Gmbh | Composition for permanent hydrophilic finishing of textile fibers and textile products |
CN105332278B (en) * | 2015-11-26 | 2017-12-05 | 常州市灵达化学品有限公司 | The environmentally friendly multiple hydrophilic finishing agent of polyolefm non-woven cloth |
CN105316944B (en) * | 2015-11-26 | 2017-10-10 | 常州市灵达化学品有限公司 | The multiple hydrophilizing agent of polyolefm non-woven cloth longtitudinal dispersion type |
CN105714561A (en) * | 2015-12-28 | 2016-06-29 | 福建恒安集团有限公司 | Finishing agent of emulsion composition for polypropylene spunbonded nonwoven |
CN105714555A (en) * | 2015-12-28 | 2016-06-29 | 福建恒安集团有限公司 | Polypropylene spunbonded nonwoven after going through surface hydrophilic treatment |
CN108611697A (en) * | 2018-05-08 | 2018-10-02 | 浙江理工大学 | A kind of multiple hydrophilic finish of ES fibers |
CN108611852A (en) * | 2018-05-08 | 2018-10-02 | 浙江理工大学 | A kind of ES fibers are without the multiple hydrophilic finish of silicon |
KR102106060B1 (en) | 2018-06-22 | 2020-04-29 | 한국에너지기술연구원 | Method of hydrophilic surface modification for hydrophobic polylefin and use thereof |
CN108998889A (en) * | 2018-08-17 | 2018-12-14 | 绩溪袁稻农业产业科技有限公司 | A kind of preparation process of ES hydrophilic fibers non-woven fabrics |
KR102420139B1 (en) | 2020-10-16 | 2022-07-12 | 도레이첨단소재 주식회사 | Highly absorbent composite fiber, highly absorbent non-woven fabric and article including the non-woven fabric |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5789669A (en) * | 1980-11-14 | 1982-06-04 | Teijin Ltd | Spinning oil agent for polyester fiber |
US5258129A (en) * | 1987-12-02 | 1993-11-02 | Takemoto Yushi Kabushiki Kaisha | Fluid-permeable agent for non-woven sheets of polyolefin fibers and method of application thereof |
EP0839947A2 (en) * | 1996-11-04 | 1998-05-06 | Schill & Seilacher GmbH & Co. | Composition for the permanent hydrophilic treatment of polyolefines, use of the composition and the fibres treated therewith |
DE10045345A1 (en) * | 1999-09-24 | 2001-03-29 | Chisso Corp | Hydrophilic fiber, useful for fleeces disposable diapers, sanitary towels, incontinence pads, cloths, fleeces, filters, and cleaning rags for furniture and cars, includes a thermoplastic resin and a quaternary ammonium salt |
DE112004000559T5 (en) * | 2003-04-01 | 2006-03-02 | Matsumoto Yushi-Seiyaku Co., Ltd. | Water-permeable agent and fiber to which the water-permeable agent has been applied |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS646176A (en) | 1987-06-25 | 1989-01-10 | Takemoto Oil & Fat Co Ltd | Treating agent for hydrophilizing cotton of polyolefinic fiber |
US5045387A (en) | 1989-07-28 | 1991-09-03 | Hercules Incorporated | Rewettable polyolefin fiber and corresponding nonwovens |
DE69214618T2 (en) * | 1991-12-31 | 1997-02-20 | Stepan Europ | Quaternary ammonium surfactants, processes for their preparation, bases and their plasticizers |
JP4411667B2 (en) * | 1998-07-10 | 2010-02-10 | チッソ株式会社 | Durable hydrophilic fiber and fiber molded body using the same |
JP4089996B2 (en) * | 1999-06-22 | 2008-05-28 | 竹本油脂株式会社 | Processing agent and processing method for polyolefin fiber for manufacturing nonwoven fabric by dry method |
ATE364741T1 (en) | 2004-05-26 | 2007-07-15 | Boehme Chem Fab Kg | HYDROPHILATING MATERIALS CONTAINING POLYOLEFIN AND/OR POLYESTER |
JP5159534B2 (en) * | 2008-09-18 | 2013-03-06 | 松本油脂製薬株式会社 | Water permeability imparting agent, water permeable fiber to which it is attached, and method for producing nonwoven fabric |
JP5277131B2 (en) * | 2009-09-29 | 2013-08-28 | 松本油脂製薬株式会社 | Water permeability imparting agent, water permeable fiber, and method for producing nonwoven fabric |
-
2012
- 2012-11-06 DE DE102012021742.0A patent/DE102012021742A1/en not_active Withdrawn
-
2013
- 2013-10-30 DK DK13786214.0T patent/DK2917398T3/en active
- 2013-10-30 CN CN201380058160.5A patent/CN104903509B/en not_active Expired - Fee Related
- 2013-10-30 EP EP13786214.0A patent/EP2917398B1/en not_active Not-in-force
- 2013-10-30 KR KR1020157013146A patent/KR102106115B1/en active IP Right Grant
- 2013-10-30 JP JP2015540107A patent/JP6241829B2/en not_active Expired - Fee Related
- 2013-10-30 ES ES13786214.0T patent/ES2613880T3/en active Active
- 2013-10-30 US US14/439,280 patent/US20150292144A1/en not_active Abandoned
- 2013-10-30 MY MYPI2015701324A patent/MY185896A/en unknown
- 2013-10-30 WO PCT/EP2013/072678 patent/WO2014072210A1/en active Application Filing
-
2015
- 2015-05-05 SA SA515360388A patent/SA515360388B1/en unknown
- 2015-05-06 IL IL238665A patent/IL238665B/en active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5789669A (en) * | 1980-11-14 | 1982-06-04 | Teijin Ltd | Spinning oil agent for polyester fiber |
US5258129A (en) * | 1987-12-02 | 1993-11-02 | Takemoto Yushi Kabushiki Kaisha | Fluid-permeable agent for non-woven sheets of polyolefin fibers and method of application thereof |
EP0839947A2 (en) * | 1996-11-04 | 1998-05-06 | Schill & Seilacher GmbH & Co. | Composition for the permanent hydrophilic treatment of polyolefines, use of the composition and the fibres treated therewith |
DE10045345A1 (en) * | 1999-09-24 | 2001-03-29 | Chisso Corp | Hydrophilic fiber, useful for fleeces disposable diapers, sanitary towels, incontinence pads, cloths, fleeces, filters, and cleaning rags for furniture and cars, includes a thermoplastic resin and a quaternary ammonium salt |
DE112004000559T5 (en) * | 2003-04-01 | 2006-03-02 | Matsumoto Yushi-Seiyaku Co., Ltd. | Water-permeable agent and fiber to which the water-permeable agent has been applied |
Also Published As
Publication number | Publication date |
---|---|
EP2917398B1 (en) | 2016-12-07 |
JP2015533391A (en) | 2015-11-24 |
JP6241829B2 (en) | 2017-12-06 |
CN104903509B (en) | 2018-07-03 |
MY185896A (en) | 2021-06-14 |
IL238665A0 (en) | 2015-06-30 |
ES2613880T3 (en) | 2017-05-26 |
IL238665B (en) | 2019-02-28 |
DE102012021742A1 (en) | 2014-05-08 |
EP2917398A1 (en) | 2015-09-16 |
CN104903509A (en) | 2015-09-09 |
DK2917398T3 (en) | 2017-03-06 |
SA515360388B1 (en) | 2016-02-25 |
US20150292144A1 (en) | 2015-10-15 |
KR20150082329A (en) | 2015-07-15 |
KR102106115B1 (en) | 2020-05-04 |
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