WO2014045945A1

WO2014045945A1 - Blow-pipe structure

Info

Publication number: WO2014045945A1
Application number: PCT/JP2013/074402
Authority: WO
Inventors: 雅一坂口; 務濱田; 剛嗣岡田; 大本　節男; 慶一中川
Original assignee: 三菱重工業株式会社
Priority date: 2012-09-20
Filing date: 2013-09-10
Publication date: 2014-03-27
Also published as: US20150275322A1; DE112013004592T5; CN104603296A; JP2014062291A; KR20150040363A; JP6012359B2; IN2015DN02018A

Abstract

Provided is a blow-pipe structure for a blast furnace facility configured so as to be capable of suppressing slag adhesion by using a simple structure, even if pulverized coal with an unadjusted softening temperature is used. The blow-pipe structure is attached to a tuyere (22) in a blast furnace main body (20) that produces pig iron from iron ore. The blow-pipe structure injects auxiliary fuel pulverized coal (3) together with hot air (2) and includes a component that melts on to the pulverized coal (3) slag as a result of the hot air (2) and/or combustion heat from the pulverized coal (3). The blow-pipe structure has an internal/external double-pipe structure having an internal pipe (30b), that continues from a header pipe (41) that supplies the hot air (2), to the vicinity of the tuyere (22) and opens, said internal pipe (30b) being provided inside an external pipe (30a) that continues from the header pipe (41) to the tuyere (22). A pulverized coal outlet (31a) for an injection lance (31) into which the pulverized coal (3) is inserted opens to the inside of the internal pipe (30b).

Description

Blow pipe structure

The present invention relates to a blow pipe structure that is applied to blast furnace equipment, and more particularly to a blow pipe structure that is suitable when pulverized coal obtained by pulverizing low-grade coal as auxiliary fuel is blown into a furnace together with hot air.

In the blast furnace facility, raw materials such as iron ore, limestone, and coal are introduced into the main body of the blast furnace, and hot air and pulverized coal (PCI charcoal) as auxiliary fuel are blown from the tuyere at the lower side. It is now possible to produce pig iron from iron ore.
In such blast furnace equipment, when pulverized coal is blown, if low grade coal with a low ash melting point of about 1100-1300 ° C such as subbituminous coal or lignite is used as pulverized coal, pulverized coal The oxygen contained in the hot air of about 1200 ° C. used for blowing the gas into the furnace and a part of the pulverized coal show a combustion reaction. As a result, ash having a low melting point (hereinafter referred to as “slag”) is dissolved in the injection lance or tuyere by the combustion heat generated at this time.

The slag thus melted is rapidly cooled by coming into contact with the tuyere that is constantly cooled to protect it from the temperature of the blast furnace. As a result, solid slag adheres to the tuyere, causing a problem of clogging the flow path of the blow pipe.
In order to solve such a problem, when the slag softening point (temperature) in pulverized coal is low, as in the prior art disclosed in Patent Document 1 below, for example, a melting point equal to or higher than the temperature in the blast furnace A softening point adjustment process is performed to prevent slag from adhering to the tuyere.
Patent Document 2 below discloses a configuration in which a partition ring is provided in a hollow portion of a tuyere. With such a partition ring, the tip side of the tuyere has a double-pipe structure that partitions the main passage in the central region and the sub-passage in the peripheral region. It is allowed to pass separately from the passage to form a jet in the furnace.

JP-A-5-156330 Japanese Patent Laid-Open No. 6-235209

However, the above-described method of Patent Document 1 points out the following two problems.
The first problem is that it is difficult to completely (uniformly) mix the pulverized coal and the additive, and as a result, it is impossible to prevent slag formation in a portion where the mixing ratio of the additive is lower than a predetermined value. .
The second problem is that a new source of calcium oxide (CaO) such as limestone or serpentinite is required, which causes extra costs.

On the other hand, in the conventional structure disclosed in Patent Document 2, since there is a region that is not a double pipe between the lance outlet and the partition ring, at least a part of the pulverized coal does not enter the partition ring and the peripheral region. It is unavoidable to flow into the secondary passage.
From such a background, in the blow pipe structure applied to the blast furnace equipment, it is desired to suppress the adhesion of slag with a simple structure without adjusting the softening point.
The present invention has been made to solve the above-described problems, and the object of the present invention is to suppress the adhesion of slag with a simple structure even when pulverized coal that does not adjust the softening point is used. An object of the present invention is to provide a blow pipe structure for the blast furnace equipment.

In order to solve the above problems, the present invention employs the following means.
The blow pipe structure according to one aspect of the present invention is attached to a tuyere of a blast furnace body that manufactures pig iron from iron ore, and blows pulverized coal of auxiliary fuel together with hot air, and the hot air and / or the slag of the pulverized coal A blow pipe structure containing a component that is melted by the combustion heat of pulverized coal, and continuous from the mother pipe to the vicinity of the tuyere inside the outer pipe that continues from the mother pipe supplying the hot air to the tuyere. The inner and outer double-pipe structure is provided with an inner pipe that opens, and the pulverized coal outlet of the injection lance into which the pulverized coal is charged is opened inside the inner pipe.

According to such a blow pipe structure, an inner / outer double pipe structure in which an inner pipe that continuously opens from the mother pipe to the vicinity of the tuyere is provided inside the outer pipe that continues from the mother pipe supplying hot air to the tuyere. Since the pulverized coal outlet of the injection lance into which the pulverized coal is charged is open inside the inner pipe, the flow of the pulverized coal charged from the injection lance is flowed from the outer pipe wall on the upstream side of the tuyere. That is, it can be completely separated from the inner wall surface of the blow pipe. Furthermore, in the tuyere, pulverized coal can be passed away from the tuyere surface. As a result, pulverized coal slag is less likely to adhere to the tuyere surface and the inner wall surface of the blow pipe.

In the above invention, it is preferable to provide a flow path resistance at a position that is a flow path formed between the outer pipe and the inner pipe and that is near the outlet of the inner pipe.
Thereby, the flow velocity in the inner pipe can be made faster than in the outer pipe. As a result, the hot air flowing out from the outer pipe flows so as to be guided toward the center of the flow path, and the pulverized coal thrown into the inner pipe becomes difficult to flow toward the outer pipe.

In the above invention, it is preferable to provide a nitrogen input pipe for supplying nitrogen to the inner pipe.
Thereby, the operating conditions of the inner pipe and the outer pipe can be changed. In this case, the hot air temperature can be lowered by blowing nitrogen into the inner tube. Therefore, the hot air temperature in the inner pipe can be adjusted to create an environment in which pulverized coal is difficult to burn.

In the above invention, it is preferable to provide an oxygen input pipe for supplying oxygen to the outer pipe.
Thereby, the operating conditions of the inner pipe and the outer pipe can be changed. In this case, by blowing oxygen into the outer tube, the pulverized coal in the inner tube is difficult to burn as described above. However, it is possible to quickly burn the inner and outer tube gas immediately before the tuyere.

According to the above-described blow pipe structure of the present invention, the inner and outer double pipe structure is provided with an inner pipe inside the outer pipe continuous from the main pipe supplying hot air to the tuyere, and the injection lance for injecting pulverized coal is used. Since the pulverized coal outlet is open to the inside of the inner pipe, the pulverized coal slag is less likely to adhere to the tuyere surface and the blow pipe inner wall surface. Therefore, it is possible to suppress the adhesion of slag with a simple blow pipe structure of a double pipe structure without adjusting the softening point.
As a result, low grade coal having an ash melting point as low as about 1100 to 1300 ° C., such as subbituminous coal and lignite, can be used as pulverized coal as auxiliary fuel by reforming it as raw coal.

It is a longitudinal section showing an axial section as one embodiment of a blowpipe structure concerning the present invention. It is a figure which shows the structural example of the blast furnace equipment to which the blowpipe structure shown in FIG. 1 is applied.

Hereinafter, an embodiment of a blow pipe structure according to the present invention will be described with reference to the drawings.
The blow pipe structure of the present embodiment is used for blast furnace equipment in which pulverized coal whose raw coal is low-grade coal is blown into the blast furnace together with hot air from the tuyere.
For example, in a blast furnace facility as shown in FIG. 2, a raw material 1 such as iron ore, limestone, and coal is supplied from a raw material fixed supply device 10 to a furnace top hopper 21 provided at the top of a blast furnace body 20 via a carry-in conveyor 11. The The lower side wall of the blast furnace main body 20 is provided with a plurality of tuyere 22 arranged at substantially equal pitches in the circumferential direction. Each tuyere 22 is connected to a downstream end of a blow pipe 30 that supplies hot air 2 into the blast furnace body 20. The upstream end of each blow pipe 30 is connected to a hot air supply device 40 that is a supply source of the hot air 2 supplied to the inside of the blast furnace body 20.

In the vicinity of the blast furnace body 20, pretreatment (reformation) such as evaporation of moisture in the coal from raw coal (low-grade coal such as subbituminous coal and lignite) is performed, and after this pretreatment, low-grade coal is A pulverized coal production apparatus 50 that is pulverized into pulverized coal is installed.
The reformed pulverized coal (modified coal) 3 produced by the pulverized coal production apparatus 50 is gas-transported to the cyclone separator 60 by a carrier gas 4 such as nitrogen gas. After the gas transported pulverized coal 3 is separated from the transported gas 4 by the cyclone separator 60, it is dropped into the storage tank 70 and stored. The pulverized coal 3 after such reforming is used as blast furnace blown coal (PCI charcoal) of the blast furnace body 20.

The pulverized coal 3 in the storage tank 70 is supplied into the injection lance (hereinafter referred to as “lance”) 31 of the blow pipe 30 described above. The pulverized coal 3 is combusted by being supplied into the hot air flowing through the blow pipe 30 and forms a flame at the tip of the blow pipe 30 to form a raceway. Thereby, the coal etc. which are contained in the raw material 1 thrown in in the blast furnace main body 20 are burned. As a result, the iron ore contained in the raw material 1 is reduced to become pig iron (molten metal) 5 and taken out from the tap outlet 23.

A suitable property of the pulverized coal 3 that is supplied from the lance 31 to the inside of the blow pipe 30 and becomes the blast furnace blowing coal, that is, a modified pulverized coal (auxiliary fuel) obtained by reforming and pulverizing low-grade coal. As for the properties, the oxygen atom content (dry base) is 10 to 18% by weight, and the average pore diameter is 10 to 50 nm (nanometers). The more preferable average pore diameter of the modified pulverized coal is 20 to 50 nm (nanometers).
Such pulverized coal 3 is largely reduced in the main skeleton (C, H, O) although the tar-generating groups of the oxygen-containing functional groups (carboxyl group, aldehyde group, ester group, hydroxyl group, etc.) are greatly reduced. The decomposition (decrease) of the combustion component is greatly suppressed. For this reason, when the hot air 2 is blown into the blast furnace body 20 from the tuyere 22, the main skeleton contains a large amount of oxygen atoms, and the oxygen in the hot air 2 easily diffuses into the charcoal due to the large-diameter pores. In addition, since tar content is very difficult to generate, complete combustion can be achieved with almost no unburned carbon (soot).

In order to produce (modify) such pulverized coal 3, in the above-described pulverized coal production apparatus 50, low-grade coal such as sub-bituminous coal or lignite as raw coal (dry base oxygen atom content ratio: 18% by weight) A drying step is carried out by heating (110 to 200 ° C. × 0.5 to 1 hour) in a low oxygen atmosphere having an oxygen concentration of 5% by volume or less.

After removing moisture in the above-described drying step, the raw coal is heated again in a low oxygen atmosphere (oxygen concentration: 2% by volume or less) (460 to 590 ° C. (preferably 500 to 550 ° C.)) × 0.5 to 1 A dry distillation step is carried out. The raw coal is carbonized by this carbonization process, so that generated water, carbon dioxide and tar are removed as carbonized gas or carbonized oil.
Thereafter, the raw coal that has advanced to the cooling step is cooled (50 ° C. or lower) in a low oxygen atmosphere having an oxygen concentration of 2% by volume or less, and then finely pulverized (particle size: 77 μm or less (80%) Pass)) and is easily manufactured.

In the present embodiment, for example, as shown in FIG. 1, the auxiliary fuel pulverized coal 3 is blown together with the hot air 2 and attached to the tuyere 22 of the blast furnace main body 20 that produces pig iron from iron ore, and hot air is blown into the slag of the pulverized coal 3. The structure described below is adopted as the blow pipe 30 containing a component that is melted by the combustion heat of 2 and / or pulverized coal 3.
That is, the illustrated blow pipe 30 employs an inner / outer double pipe structure. This inner / outer double pipe structure is connected to the hot air feeding device 40 and continues from the main pipe 41 for supplying hot air 2 to the tuyere 22, and has a structure in which an inner pipe 30b is provided inside the outer pipe 30a. It has become.

More specifically, the outer pipe 30 a of the blow pipe 30 is branched from the mother pipe 41 and connected to the tuyere 22. On the other hand, the inner pipe 30b of the blow pipe 30 branches off from the mother pipe 41 like the outer pipe 30a, and the inner pipe outlet 30c on the downstream side opens near the inlet of the tuyere 22.
Accordingly, the blow pipe 30 has an inner pipe outlet 30c that continuously opens from the mother pipe 41 to the vicinity of the tuyere 22 inside the outer pipe 30a that continues from the mother pipe 41 that supplies the hot air 2 to the tuyere 22. The inner / outer double tube structure is provided with the tube 30b.

In other words, the blow pipe 30 has an inner / outer double pipe structure in which the inner pipe 30b into which the pulverized coal 3 is charged is provided concentrically inside the outer pipe 30a serving as the blow pipe main body and the flow path is separated.
Further, it is desirable that the outer tube 30a and the inner tube 30b of the blow pipe 30 are set so that the cross-sectional area ratio is approximately 1: 1. For example, when the inner diameter of the tuyere 22 is 160 mm, the inner diameter of the outer tube 30a is 210 mm, and the inner diameter of the inner tube 30b is 140 mm.
And the lance 31 which throws the pulverized coal 3 into the blow pipe 30 penetrates the outer tube 30a and the inner tube 30b, and the pulverized coal outlet 31a is opened inside the inner tube 30b.

In the blow pipe 30 having such an inner / outer double pipe structure, the pulverized coal 3 is introduced into the inner pipe 30b from the lance 31. Therefore, on the upstream side of the tuyere 22, the flow of the pulverized coal 3 is changed to the outer pipe 30a. Can be completely separated from the wall surface of the outer tube. That is, the flow of the pulverized coal 3 is completely separated from the inner wall surface of the blow pipe 30, and further, in the tuyere 22, the flow of the pulverized coal 3 can be passed away from the surface of the tuyere 22.
As a result, on the surface of the tuyere 22 and the inner wall surface of the outer pipe 30a serving as the blow pipe main body (the inner wall surface of the blow pipe 30), the passage amount of the pulverized coal 3 is lost as compared with the conventional structure without the inner pipe 30b. Therefore, slag adhesion of pulverized coal 3 can be significantly suppressed.

In the blow pipe structure of the present embodiment described above, the flow path cross-sectional area is set at a position that is the outer peripheral flow path 30d formed between the outer pipe 30a and the inner pipe 30b and near the outlet of the inner pipe 30b. It is desirable to provide a flow path resistance 80 that decreases. Such a channel resistance 80 can make the flow velocity in the inner tube 30b having a small channel resistance faster than in the outer tube.
As a result, since the hot air 2 flowing out from the outer pipe 30a flows so as to be guided toward the axial center of the inner pipe 30b, that is, toward the flow path center of the blow pipe 30, the pulverized coal 3 introduced into the inner pipe 30b is slag. It becomes difficult to flow in the direction of the outer tube 30a where it is desired to prevent adhesion.

The channel resistance 80 described above is a member that narrows the channel cross-sectional area by projecting from the inner wall surface of the outer tube 30a or the outer wall surface of the inner tube 30b, or from the inner wall surface of the outer tube 30a and the outer wall surface of the inner tube 30b. The cross-sectional shape is not particularly limited. However, if a wedge-shaped projecting member is provided on the inner wall surface of the outer tube 30a, such as a channel resistance 80 having an inclined surface 81 that reduces the channel cross-sectional area from the upstream side to the downstream side in the flow direction, Since the inclined surface 81 guides the hot air 2 flowing through the outer peripheral flow path 30d toward the center of the tuyere 22, the flow of the pulverized coal 3 is guided toward the center of the tuyere 22, so that slag adhesion of the pulverized coal 3 can be further suppressed. .

The blow pipe structure described above preferably includes a nitrogen input pipe 90 that supplies nitrogen into the inner pipe 30b. The nitrogen input pipe 90 is for supplying nitrogen gas to the hot air 2 flowing in the inner pipe 30b as necessary, for example, when it is desired to change the operating conditions of the inner pipe 30b and the outer pipe 30a.
Accordingly, when nitrogen is blown into the inner pipe 30b, the hot air temperature is lowered, so that the temperature of the hot air 2 can be lowered to the slag melting point or lower. That is, the nitrogen input pipe 90 adjusts the hot air temperature in the inner pipe 30b and reduces the oxygen concentration by introducing nitrogen, so that it can be adjusted to an environment in which the pulverized coal 3 is difficult to burn.

The blow pipe structure described above preferably includes an oxygen input pipe 91 that supplies oxygen to the inside of the outer pipe 30a, that is, to the inside of the outer peripheral flow path 30d. The oxygen input pipe 91 is for supplying oxygen to the hot air 2 flowing in the outer pipe 30a as necessary, for example, when it is desired to change the operating conditions of the inner pipe 30b and the outer pipe 30a.
Accordingly, the hot air 2 in which oxygen concentration is increased by blowing oxygen into the outer pipe 30a is mixed with the pulverized coal 3 introduced into the inner pipe 30b in the vicinity of the entrance of the tuyere 22, thereby quickly burning the pulverized coal 3. Can be made. Such promotion of combustion increases the temperature of the hot air 2, so that the combustion of the pulverized coal 3 is further promoted.

Here, the oxygen concentration adjustment of the hot air 2 will be specifically described with an example.
In the hot air 2 supplied from the mother pipe 41, for example, the oxygen concentration is set to 21% by volume. In order to ensure combustion after merging with the pulverized coal 3, oxygen is blown into the outer pipe 30a from the oxygen input pipe 91, and the oxygen concentration is enriched to 25 to 50% by volume, preferably 30 to 35% by volume. To do.

Thereby, in the inner pipe 30b whose oxygen concentration is relatively lower than that of the outer pipe 30a, the combustion speed of the pulverized coal 3 can be suppressed, and the slag can be prevented from adhering in the inner pipe 30b. And the hot air 2 and the pulverized coal 3 flowing in the inner pipe 30b are combined with the hot air 2 after oxygen enrichment flowing in from the outer pipe 30a, so that the combustion speed of the pulverized coal 3 is improved due to the increase in oxygen concentration, The pulverized coal 3 to be blown coal into the blast furnace body 20 can be completely burned in the raceway.
Further, in addition to such adjustment of the oxygen concentration, nitrogen is also introduced into the inner pipe 30b, and the hot air temperature in the inner pipe 30b is adjusted to be equal to or lower than the ash melting point according to the properties of the pulverized coal 3. Also good.

Thus, according to the above-described blow pipe structure of the present embodiment, an inner / outer double pipe structure in which the inner pipe 30b is provided inside the outer pipe 30a continuous from the mother pipe 41 to the tuyere 22 is used. Since the pulverized coal outlet 31a of the lance 31 to be introduced is opened inside the inner pipe 30b, the flow of the pulverized coal 3 is separated from the surface of the tuyere 22 and the inner wall surface of the blow pipe 30. As a result, the pulverized coal 3 Slag becomes difficult to adhere.
Therefore, even if the softening point of the pulverized coal 3 is not adjusted, it is possible to suppress the adhesion of slag with a simple blow pipe structure called an inner / outer double pipe structure. For this reason, for the blow pipe 30, for example, the maintenance period can be extended to the wear life of the tuyere 22.

The component contained in the slag of the pulverized coal 3 and melted by the hot air 2 or the combustion heat of the pulverized coal 3, that is, the low melting point slag component has an ash melting point of about 1100 when the hot air 2 of about 1200 ° C. is used. About 1300 ° C. Such low-melting-point slag components are also included in reformed coal using low-grade coal such as subbituminous coal and lignite as the raw coal of pulverized coal 3 and subjected to reforming treatment such as drying and dry distillation. If the blow pipe structure of this embodiment is adopted, pulverized coal 3 obtained by modifying low-grade coal as raw coal can be used as auxiliary fuel.
In addition, this invention is not limited to embodiment mentioned above, In the range which does not deviate from the summary, it can change suitably.

1 Raw material 2 Hot air 3 Pulverized coal (modified coal)
4 Gas supply 5 Pig iron (molten metal)
DESCRIPTION OF SYMBOLS 10 Raw material fixed supply apparatus 20 Blast furnace main body 21 Furnace top hopper 22 Tuyere 30 Blow pipe 30a Outer pipe 30b Inner pipe 30c Inner pipe outlet 30d Outer flow path 31 Injection lance (lance)
31a Pulverized coal outlet 40 Hot air feeding device 41 Mother pipe 50 Pulverized coal production device 60 Cyclone separator 70 Storage tank 80 Channel resistance 81 Inclined surface 90 Nitrogen input pipe 91 Oxygen input pipe

Claims

Attached to the tuyere of the blast furnace main body that produces pig iron from iron ore, the pulverized coal of auxiliary fuel is blown together with hot air, and the slag of the pulverized coal contains a component that melts by the hot air and / or the combustion heat of the pulverized coal A blow pipe structure,
An inner and outer double pipe structure is provided in which an inner pipe that continuously opens from the mother pipe to the vicinity of the tuyere is provided inside the outer pipe that continues from the mother pipe that supplies the hot air to the tuyere, A blow pipe structure in which a pulverized coal outlet of an injection lance to be introduced is opened inside the inner pipe.
The blow pipe structure according to claim 1, wherein a flow path resistance is provided in a flow path formed between the outer pipe and the inner pipe and in the vicinity of an outlet of the inner pipe.
The blowpipe structure according to claim 1 or 2, wherein a nitrogen input pipe for supplying nitrogen to the inner pipe is provided.
The blowpipe structure according to any one of claims 1 to 3, wherein an oxygen input pipe for supplying oxygen to the outer pipe is provided.