WO2014038548A1 - Machine structure steel material having low heat-treatment deformation - Google Patents
Machine structure steel material having low heat-treatment deformation Download PDFInfo
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- WO2014038548A1 WO2014038548A1 PCT/JP2013/073681 JP2013073681W WO2014038548A1 WO 2014038548 A1 WO2014038548 A1 WO 2014038548A1 JP 2013073681 W JP2013073681 W JP 2013073681W WO 2014038548 A1 WO2014038548 A1 WO 2014038548A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/28—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for plain shafts
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/32—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for gear wheels, worm wheels, or the like
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Definitions
- the present invention relates to machine structural steel used as power transmission parts such as gears and shafts used in automobiles, industrial machines, and the like, and more particularly to steel for machine structure with small heat treatment deformation.
- heat treatment deformation It is known that deformation of a steel material (hereinafter referred to as “heat treatment deformation”) occurs due to heat treatment such as quenching. If there is such heat treatment deformation, the number of manufacturing processes will increase to correct the deformation, the defective part rate will increase if it cannot be corrected, or it will be caused by deformation when incorporated as a drive system part. There are adverse effects such as generating noise and vibration. Therefore, it is a very important problem in practice to keep the heat treatment deformation as small as possible.
- this heat treatment deformation is considered to be influenced by many factors other than steel, such as part shape, influence of pre-heat treatment process, physical properties of refrigerants such as quenching oil, and non-uniform cooling. Has been. Therefore, attempts have been made to reduce heat treatment deformation by optimizing them in various ways. For example, as a material countermeasure, a method has been proposed in which a soft ferrite phase is precipitated in the core of a hardened steel material to reduce heat treatment strain (see, for example, Patent Document 1).
- the means for promoting the heat transfer coefficient is due to the convection of the coating material that promotes cooling provided in the portion where cooling is delayed or the coolant formed around the portion where cooling is delayed,
- the means for reducing the heat transfer rate is said to be glass wool or a heat insulating coating material covering a portion where cooling is likely to proceed.
- the conventional method proposed above cannot always be a general purpose means. This is because, for example, in the technique of Patent Document 1, a soft phase having a low strength may be introduced into a part, and in the technique of Patent Document 2, the heat treatment furnace itself has to be changed. This is because the technique of Patent Document 3 is not necessarily a general-purpose means, for example, it requires processing for individual heat-treated parts.
- the present inventors have secured a sufficient steel material strength without relying on the generation of a ferrite structure that is soft and may reduce the strength of the component, and under a general quenching technique such as oil quenching, Even if the cooling of the steel becomes non-uniform, we have conducted intensive research on steel that can keep heat treatment deformation small. As a result, the inventors reduced the heat treatment deformation by controlling the chemical composition of the steel, the martensite transformation start temperature (Ms point), and the hardenability measured by the Jominy one-side quenching method to an appropriate range. It was found that it can be suppressed.
- Ms point martensite transformation start temperature
- an object of the present invention is to provide a steel material that is made of mechanical structural steel used as a power transmission component such as a gear or a shaft used in automobiles, industrial machines, and the like, and has less heat treatment deformation.
- a steel material for mechanical structure with small heat treatment deformation is in mass%, C: 0.20 to 0.30% Si: 0.10 to 1.50%, Mn: 0.10 to 1.20%, P: 0.030% or less, S: 0.030% or less, Cr: 1.30-2.50%, Cu: 0.30% or less, Al: 0.008 to 0.300%, O: 0.0030% or less, N: 0.0020 to 0.0300%
- a mechanical structural steel comprising the balance Fe and inevitable impurities,
- the martensitic transformation start temperature (Ms point) of the steel material made of the steel is 460 ° C.
- J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel material and J9 of the hardness at a distance of 9 mm measured by the Jominy type one-end quenching method for the steel material is in the range of 0.70 to 0.85
- the value of (J11 / J1.5) calculated by the following equation (2) using J1.5 of hardness at a distance of 1.5 mm and J11 of hardness at a distance of 11 mm is 0.67 to 0.78. In the range of A machine structural steel material with small heat treatment deformation is provided.
- the steel material for mechanical structure having a small heat treatment deformation is in mass%, C: 0.20 to 0.30% Si: 0.10 to 1.50%, Mn: 0.10 to 1.20%, P: 0.030% or less, S: 0.030% or less, Cr: 1.30-2.50%, Cu: 0.30% or less, Al: 0.008 to 0.300%, O: 0.0030% or less, N: 0.0020 to 0.0300% is contained, Furthermore, it contains one or two of Ni: 0.20 to 3.00% and Mo: 0.05 to 0.50%, It is a steel material made of mechanical structural steel consisting of the balance Fe and inevitable impurities, Furthermore, the martensitic transformation start temperature (Ms point) of this steel material is 460 ° C.
- J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel and J9 of the hardness at a distance of 9 mm measured by the Jominy one-end quenching method for this steel is in the range of 0.70 to 0.85
- the value of (J11 / J1.5) calculated by the above equation (2) using J1.5 of the hardness at a distance of 1.5 mm and J11 of the hardness at a distance of 11 mm is 0.67-0.
- a machine structural steel material with small heat treatment deformation is provided.
- a steel material for machine structural use having a small heat treatment deformation, the steel material being in mass%, C: 0.20 to 0.30% Si: 0.10 to 1.50%, Mn: 0.10 to 1.20%, P: 0.030% or less, S: 0.030% or less, Cr: 1.30-2.50%, Cu: 0.30% or less, Al: 0.008 to 0.300%, O: 0.0030% or less, N: 0.0020 to 0.0300% is contained, Further, Ti contains 0.020 to 0.200% and Nb: 0.02 to 0.20% of one or two, It is a steel material made of mechanical structural steel consisting of the balance Fe and inevitable impurities, Furthermore, the martensitic transformation start temperature (Ms point) of this steel material is 460 ° C.
- a steel material for machine structural use having a small heat treatment deformation, the steel material being in mass%, C: 0.20 to 0.30% Si: 0.10 to 1.50%, Mn: 0.10 to 1.20%, P: 0.030% or less, S: 0.030% or less, Cr: 1.30-2.50%, Cu: 0.30% or less, Al: 0.008 to 0.300%, O: 0.0030% or less, N: 0.0020 to 0.0300% is contained, Furthermore, it contains one or two of Ni: 0.20 to 3.00% and Mo: 0.05 to 0.50%, Further, Ti contains 0.020 to 0.200% and Nb: 0.02 to 0.20% of one or two, It is a steel material made of mechanical structural steel consisting of the balance Fe and inevitable impurities, Furthermore, the martensitic transformation start temperature (Ms point) of this steel material is 460 ° C.
- J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel and J9 of the hardness at a distance of 9 mm measured by the Jominy one-end quenching method for this steel is in the range of 0.70 to 0.85
- the value of (J11 / J1.5) calculated by the above equation (2) using J1.5 of the hardness at a distance of 1.5 mm and J11 of the hardness at a distance of 11 mm is 0.67-0.
- a machine structural steel material with small heat treatment deformation is provided.
- a steel material for machine structural use having a small heat treatment deformation, the steel material being in mass%, C: 0.20 to 0.30% Si: 0.10 to 1.50%, Mn: 0.10 to 1.20%, P: 0.030% or less, S: 0.030% or less, Cr: 1.30-2.50%, Cu: 0.30% or less, Al: 0.008 to 0.300%, O: 0.0030% or less, N: 0.0020 to 0.0300% Ni: 0 to 3.00%, Mo: 0 to 0.50% Ti: 0 to 0.200%, Nb: 0 to 0.20% Comprising the balance Fe and inevitable impurities,
- the steel material has a martensitic transformation start temperature (Ms point) of 460 ° C.
- the ratio of the hardness J9 at a distance of 9 mm from the quenching end of the steel material to the hardness J1.5 at a distance of 1.5 mm from the quenching end of the steel material when measured by the Jomini type one-end quenching method is in the range of 0.70 to 0.85, and the distance from the quenching end of the steel to the hardness J1.5 at a distance of 1.5 mm from the quenching end of the steel
- a steel material for machine structure having a ratio of hardness J11 at 11 mm (J11 / J1.5) in the range of 0.67 to 0.78 is provided.
- the steel material does not substantially contain Ni, Mo, Ti and Nb or contains an inevitable impurity level.
- the steel material includes one or two of Ni: 0.20 to 3.00% and Mo: 0.05 to 0.50% in mass%.
- the steel material includes one or two of Ti: 0.020 to 0.200% and Nb: 0.02 to 0.20% by mass%.
- the steel material is, by mass%, one or two of Ni: 0.20 to 3.00% and Mo: 0.05 to 0.50%, and Ti. : 0.020 to 0.200%, and Nb: 0.02 to 0.20%.
- the steel material for mechanical structure with small heat treatment deformation according to the present invention is, in mass%, C: 0.20 to 0.30%, Si: 0.10 to 1.50%, Mn: 0.10 to 1.20%, P: 0.030% or less, S: 0.030% or less, Cr: 1.30 to 2.50%, Cu: 0.30% or less, Al: 0.008 to 0.300%, O: 0.00.
- N 0.0020 to 0.0300%
- Ni 0 to 3.00%
- Mo 0 to 0.50%
- Ti 0 to 0.200%
- Nb 0 to 0.20%
- C 0.20 to 0.30%
- C is an element necessary for securing the strength after quenching and tempering of steel or the strength of the core after carburizing, quenching and tempering as mechanical structural parts, and is adjusted to a predetermined range in order to reduce heat treatment deformation. There is a need. If the C content is less than 0.20%, the strength cannot be ensured, and if it exceeds 0.30%, deformation due to heat treatment becomes too large. Therefore, the C content is set to 0.20 to 0.30%, preferably 0.22 to 0.27%.
- Si 0.10 to 1.50%
- Si is an element necessary for deoxidation and is an effective element for imparting necessary strength and hardenability to steel. However, if the Si content is less than 0.10%, the effect cannot be obtained, and if it exceeds 1.50%, the machinability is lowered. Therefore, the Si content is 0.10 to 1.50%, preferably 0.20 to 1.00%.
- Mn 0.10 to 1.20%
- Mn is an element necessary for ensuring hardenability. However, if the Mn content is less than 0.10%, sufficient effect on hardenability cannot be obtained, and if it exceeds 1.20%, the machinability is lowered. Therefore, the Mn content is 0.10 to 1.20%, preferably 0.20 to 0.80%, and more preferably 0.20 to 0.55%.
- P 0.030% or less
- P is an unavoidable element contained in scrap, but segregates at the grain boundary and lowers properties such as impact strength and bending strength. Therefore, the P content is 0.030% or less (including 0%), and typically exceeds 0 and is 0.030% or less.
- S 0.030% or less S is an element that improves machinability, but generates MnS that is a non-metallic inclusion and lowers the toughness and fatigue strength in the transverse direction. Therefore, the S content is 0.030% or less (including 0%), and typically exceeds 0 and is 0.030% or less.
- Cr 1.30-2.50% Cr is an element necessary for ensuring hardenability. However, if the Cr content is less than 1.30%, a sufficient effect on hardenability cannot be obtained. Therefore, the Cr content is set to 1.30 to 2.50%, preferably 1.50 to 2.25%.
- Ni 0.20 to 3.00%
- Ni is an optional element that improves hardenability and toughness, and in order to obtain the effect, addition of 0.20% or more is preferable. However, if the Ni content exceeds 3.00%, the workability is remarkably lowered and the cost is increased, so the content is made 3.00% or less. Therefore, the Ni content is set to 0.20 to 3.00%.
- Mo 0.05 to 0.50% Mo is an optional element that improves hardenability and toughness, and 0.05% or more is preferable for obtaining the effect. However, if the Mo content exceeds 0.50%, the workability decreases. Therefore, the Mo content is set to 0.05 to 0.50%.
- Cu 0.30% or less Cu is an inevitable element contained from scrap, but has aging properties and an effect of increasing strength. However, when the Cu content exceeds 0.30%, the hot workability is lowered. Therefore, the Cu content is set to 0.30% or less (including 0%), and typically exceeds 0 and is set to 0.30% or less.
- Al 0.008 to 0.300%
- Al is an element used as a deoxidizing material, and also binds to N and precipitates as AlN as will be described later, thereby bringing about an effect of suppressing grain coarsening. In order to obtain this effect, 0.008% or more of Al needs to be added. On the other hand, if Al is added in excess of 0.300%, large alumina inclusions are formed, and fatigue characteristics and workability are deteriorated. Therefore, the Al content is set to 0.008 to 0.300%, preferably 0.014 to 0.200%.
- O 0.0030% or less
- O is an element inevitably contained in steel. However, if O exceeds 0.0030%, workability and fatigue strength are reduced due to an increase in oxide. Therefore, the content of O is set to 0.0030% or less (including 0%), preferably 0.0020% or less (including 0%). Also, typically, it exceeds 0 and is 0.0030% or less, and desirably exceeds 0 and is 0.0020% or less.
- N 0.0020 to 0.0300%
- N is an element that finely precipitates as AlN or Nb nitride in the steel and has an effect of preventing the coarsening of crystal grains.
- the N content is set to 0.0020 to 0.0300%, preferably 0.0020 to 0.0200%.
- the N content is set to 0.0020 to 0.0100% in order to avoid a decrease in fatigue strength due to excessive TiN formation.
- Ti 0.020 to 0.200%
- Ti is an optional element that combines with C in the steel to form carbides finely and has the effect of preventing grain coarsening. To obtain this effect, 0.020% or more of Ti is added. It is preferable to do. On the other hand, if the Ti content exceeds 0.200%, the machinability is impaired. Therefore, the Ti content is set to 0.020 to 0.200%.
- Nb 0.02 to 0.20%
- Nb is an arbitrary element that forms carbides or nitrides and has an effect of preventing grain coarsening.
- nano-order sized NbC or Nb (C, N) finely dispersed in steel suppresses the growth of crystal grains. If the Nb content is less than 0.02%, the effect cannot be obtained. If the Nb content exceeds 0.20%, the amount of precipitates becomes excessive and workability deteriorates. Therefore, the Nb content is 0.02 to 0.20%, preferably 0.02 to 0.12%.
- Ms point 460 ° C. or less
- the martensite transformation start temperature Ms point
- the Ms point is restricted to 460 ° C. or lower, but preferably the Ms point is restricted to 450 ° C. or lower.
- the heat treatment deformation means bending of the shaft-shaped part, falling of the gear teeth, or twisting.
- the heat treatment deformation referred to here is the bending of the shaft-shaped part, the gear teeth falling or twisting after quenching, and the change in the dimension (length, diameter, thickness, etc.) of the part before and after quenching.
- the deformation due to heat treatment is suppressed because the martensitic transformation starts from the difficult state.
- the bainite transformation occurs excessively, so that the heat treatment deformation increases due to the influence of the bainite transformation itself, and if the hardenability is too high, the bainite structure relaxes the heat treatment deformation. It is considered that the deformation due to heat treatment is also increased due to the small amount.
- the present invention has beneficial effects such as improvement of component yield, simplification and abolition of component correction processes, and omission of gear tooth grinding for noise and vibration countermeasures. Can do.
- the comparative example No. 2 shown in Table 2 was used as a structural steel used as a power transmission component such as a gear or a shaft used in automobiles or industrial machines.
- Steel consisting of 1 to 16 component compositions, the balance Fe and unavoidable impurities was melted in a vacuum induction melting furnace to obtain a 100 kg steel ingot.
- these ingots of the present invention and comparative examples were heated at 1250 ° C. for 5 hours and then forged into a steel bar having a diameter of 32 mm.
- normalizing was performed by heating and holding at 900 ° C. for 1.5 hours and then air cooling.
- a test piece having a diameter of 20 mm and a length of 80 mm was produced from a steel bar having a diameter of 32 mm, and a groove having a depth of 5 mm, a width of 8 mm, and a length of 80 mm was applied to the side surface of the test piece.
- the cooling rate was varied greatly depending on the portion in the test piece.
- the length of the test piece was measured after the groove processing. Further, the radius and groove width were measured at each position of 2 mm, 20 mm from the end of the test piece, and 40 mm which is the center of the test piece length. Then, after carburizing these test pieces at 930 ° C., the temperature was lowered to 850 ° C. in the furnace, and further maintained for 1 hour, and then quenched into a quenching oil at 60 ° C. After quenching, the specimens that were sufficiently cooled were measured for the bend and length of the specimen and the radius and groove width at each position of 2 mm, 20 mm from the specimen edge, and 40 mm, which is the center of the specimen length.
- the radius before and after the heat treatment at each position of the total three locations of 2 mm, 20 mm from the end of the test piece, and 40 mm which is the center of the length of the test piece, and the groove width dimension measurement result After obtaining the dimensional change amount of the groove width, the values obtained by subtracting the minimum value from the maximum value among the dimensional change amounts at the three locations are defined as the radius change amount and the groove width change amount, respectively. It was evaluated as an index of deformation.
- a test piece having a diameter of 3 mm and a length of 10 mm is determined from the steel bar having a diameter of 32 mm after the above normalization, and the Ms point, which is the martensitic transformation start temperature of the steel material, is measured using a fully automatic transformation recording measuring device. did.
- the Ms point in the present embodiment is measured and measured under the condition that the cooling process of the component is assumed.
- the above-described grooved test piece having a diameter of 20 mm has an oil temperature of 60 ° C. Assuming oil quenching, the cooling rate during quenching was measured at 30 ° C./s.
- test piece was prepared from the above-described forged steel bar with a diameter of 32 mm, and “steel hardenability test method (one end) specified in JIS G 0561”. The test was conducted under the conditions according to the quenching method) and evaluated.
- Table 3 shows the Ms point measured for the steel of the present invention, J1.5 of the hardness at a distance of 1.5 mm, J9 of the hardness at a distance of 9 mm from the quenching end measured by the Jomini type one-end quenching method, and Each value of the hardness J11 at a distance of 11 mm, and the obtained (J9 / J1.5) value and (J11 / J1.5) value are shown.
- the martensite transformation start temperature that is, the Ms point is in the range of 388 to 444 ° C.
- (J9 / J1.5) of this steel material is represented by the following formula (1 ) Is in the range of 0.72 to 0.85
- the value of formula (2) shown below in (J11 / J1.5) is in the range of 0.67 to 0.78
- the bend after heat treatment Is 0.005 to 0.030 mm
- the absolute value of the difference in length of the test piece before and after heat treatment is 0.003 to 0.023 mm
- the amount of change in radius before and after heat treatment is 0.002 to 0.008 mm.
- Table 4 shows the measured Ms point of the steel of the comparative example, J1.5 of the hardness (HRC) at a distance of 1.5 mm from the quenching end measured by the Jomini type one-end quenching method, and the hardness at a distance of 9 mm.
- Jominy hardenability which is J9 of thickness (HRC) and J11 of hardness (HRC) at a distance of 11 mm, and the obtained values of (J9 / J1.5) and (J11 / J1.5) are shown. .
- the composition range excluding unavoidable impurities other than Fe, Ni, and Mo of steel materials is shown in Table 1, Ms point is set to 388 to 444 ° C. below 460 ° C., and measured by Jomini type one-end quenching method
- the value of (J9 / J1.5) calculated from the equation (1) is calculated within the range of 0.72 to 0.85 from the equation (2) (
- the value of J11 / J1.5) in the range of 0.67 to 0.78 By setting the value of J11 / J1.5) in the range of 0.67 to 0.78, the bending of the test piece after the heat treatment is reduced to a small range of 0.005 to 0.030 mm, and the test piece before and after the heat treatment is further reduced.
- the absolute value of the difference in length is in a small range of 0.003 to 0.023 mm, the change in radius before and after heat treatment is in a small range of 0.002 to 0.008 mm, and the change in groove width before and after heat treatment is 0. .Small range from 011 to 0.024mm It could be.
- the bending of the test piece after the heat treatment is 0.050 to 0.090 mm, and all are larger than the steel of the inventive example.
- these No. any one or more of the absolute value of the difference in length of the test pieces before and after the heat treatment, or the radius change amount and the groove width change amount before and after the heat treatment is the value of the present invention. Bigger than steel. Therefore, among the comparative examples, the bending of the test piece after the heat treatment, the absolute value of the difference in length of the test piece before and after the heat treatment, and the radius change amount and the groove width change amount before and after the heat treatment are all the same as the steel of the present invention example. There was no one equivalent.
- the Ms point satisfies the claims of the present invention, and the values of (J9 / J1.5) and (J11 / J1.5) satisfy the claims of the present invention.
- the bending of the test piece after the heat treatment, the absolute value of the difference in the length of the test piece before and after the heat treatment, and the radius change amount and the groove width change amount before and after the heat treatment are substantially smaller than those in the comparative example. Deformation is suppressed.
- the steel material of the present invention is used after being tempered after being subjected to heat treatment with hardening for hardening parts such as carburizing and quenching.
- the steel material according to the present invention is a steel material applicable to power transmission parts such as gears and shafts used in automobiles and industrial machines.
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Abstract
Description
C:0.20~0.30%、
Si:0.10~1.50%、
Mn:0.10~1.20%、
P:0.030%以下、
S:0.030%以下、
Cr:1.30~2.50%、
Cu:0.30%以下、
Al:0.008~0.300%、
O:0.0030%以下、
N:0.0020~0.0300%
を含有し、残部Feおよび不可避不純物からなる機械構造用鋼であり、
該鋼からなる鋼材のマルテンサイト変態開始温度(Ms点)が460℃以下であり、
該鋼材についてジョミニー式一端焼入法により測定される鋼材の焼入端からの距離1.5mmにおける硬さのJ1.5および距離9mmにおける硬さのJ9を用いて、下記の式(1)により算出の(J9/J1.5)の値が0.70~0.85の範囲にあり、
さらに距離1.5mmにおける硬さのJ1.5、および距離11mmにおける硬さのJ11を用いて下記の式(2)により算出の(J11/J1.5)の値が0.67~0.78の範囲にある、
熱処理変形の小さい機械構造用鋼材が提供される。
ただし、
(J9/J1.5)=(ジョミニー式一端焼入法により測定される焼入端からの距離9mmにおける硬さ)÷(ジョミニー式一端焼入法により測定される焼入端からの距離1.5mmの硬さ)・・・式(1)
(J11/J1.5)=(ジョミニー式一端焼入法により測定される焼入端からの距離11mmにおける硬さ)÷(ジョミニー式一端焼入法により測定される焼入端からの距離1.5mmにおける硬さ)・・・式(2) According to one aspect of the present invention, a steel material for mechanical structure with small heat treatment deformation, the steel material is in mass%,
C: 0.20 to 0.30%
Si: 0.10 to 1.50%,
Mn: 0.10 to 1.20%,
P: 0.030% or less,
S: 0.030% or less,
Cr: 1.30-2.50%,
Cu: 0.30% or less,
Al: 0.008 to 0.300%,
O: 0.0030% or less,
N: 0.0020 to 0.0300%
A mechanical structural steel comprising the balance Fe and inevitable impurities,
The martensitic transformation start temperature (Ms point) of the steel material made of the steel is 460 ° C. or less,
Using the following formula (1), J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel material and J9 of the hardness at a distance of 9 mm measured by the Jominy type one-end quenching method for the steel material. The calculated (J9 / J1.5) value is in the range of 0.70 to 0.85,
Furthermore, the value of (J11 / J1.5) calculated by the following equation (2) using J1.5 of hardness at a distance of 1.5 mm and J11 of hardness at a distance of 11 mm is 0.67 to 0.78. In the range of
A machine structural steel material with small heat treatment deformation is provided.
However,
(J9 / J1.5) = (hardness at a distance of 9 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (distance from the quenching end measured by the Jominy type one-end quenching method. 5mm hardness) ... Formula (1)
(J11 / J1.5) = (hardness at a distance of 11 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (distance from the quenching end measured by the Jominy type one-end quenching method. (Hardness at 5 mm) (2)
C:0.20~0.30%、
Si:0.10~1.50%、
Mn:0.10~1.20%、
P:0.030%以下、
S:0.030%以下、
Cr:1.30~2.50%、
Cu:0.30%以下、
Al:0.008~0.300%、
O:0.0030%以下、
N:0.0020~0.0300%を含有し、
さらにNi:0.20~3.00%およびMo:0.05~0.50%のうち1種または2種を含有し、
残部Feおよび不可避不純物からなる機械構造用鋼からなる鋼材であり、
さらに、この鋼材のマルテンサイト変態開始温度(Ms点)が460℃以下であり、
この鋼材についてのジョミニー式一端焼入法により測定される鋼材の焼入端からの距離1.5mmにおける硬さのJ1.5および距離9mmにおける硬さのJ9を用いて上記の式(1)により算出の(J9/J1.5)の値が0.70~0.85の範囲にあり、
さらに、距離1.5mmにおける硬さのJ1.5および距離11mmにおける硬さのJ11を用いて、上記の式(2)により算出の(J11/J1.5)の値が0.67~0.78の範囲にある、
熱処理変形の小さい機械構造用鋼材が提供される。 According to a preferred embodiment of the present invention, the steel material for mechanical structure having a small heat treatment deformation, the steel material is in mass%,
C: 0.20 to 0.30%
Si: 0.10 to 1.50%,
Mn: 0.10 to 1.20%,
P: 0.030% or less,
S: 0.030% or less,
Cr: 1.30-2.50%,
Cu: 0.30% or less,
Al: 0.008 to 0.300%,
O: 0.0030% or less,
N: 0.0020 to 0.0300% is contained,
Furthermore, it contains one or two of Ni: 0.20 to 3.00% and Mo: 0.05 to 0.50%,
It is a steel material made of mechanical structural steel consisting of the balance Fe and inevitable impurities,
Furthermore, the martensitic transformation start temperature (Ms point) of this steel material is 460 ° C. or less,
Using the above formula (1), J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel and J9 of the hardness at a distance of 9 mm measured by the Jominy one-end quenching method for this steel. The calculated (J9 / J1.5) value is in the range of 0.70 to 0.85,
Further, the value of (J11 / J1.5) calculated by the above equation (2) using J1.5 of the hardness at a distance of 1.5 mm and J11 of the hardness at a distance of 11 mm is 0.67-0. In the range of 78,
A machine structural steel material with small heat treatment deformation is provided.
C:0.20~0.30%、
Si:0.10~1.50%、
Mn:0.10~1.20%、
P:0.030%以下、
S:0.030%以下、
Cr:1.30~2.50%、
Cu:0.30%以下、
Al:0.008~0.300%、
O:0.0030%以下、
N:0.0020~0.0300%を含有し、
さらにTi:0.020~0.200%およびNb:0.02~0.20%のうち1種または2種を含有し、
残部Feおよび不可避不純物からなる機械構造用鋼からなる鋼材であり、
さらに、この鋼材のマルテンサイト変態開始温度(Ms点)が460℃以下であり、
この鋼材についてのジョミニー式一端焼入法により測定される鋼材の焼入端からの距離1.5mmにおける硬さのJ1.5および距離9mmにおける硬さのJ9を用いて上記の式(1)により算出の(J9/J1.5)の値が0.70~0.85の範囲にあり、
さらに、距離1.5mmにおける硬さのJ1.5および距離11mmにおける硬さのJ11を用いて、上記の式(2)により算出の(J11/J1.5)の値が0.67~0.78の範囲にある、
熱処理変形の小さい機械構造用鋼材が提供される。 According to another aspect of the present invention, there is provided a steel material for machine structural use having a small heat treatment deformation, the steel material being in mass%,
C: 0.20 to 0.30%
Si: 0.10 to 1.50%,
Mn: 0.10 to 1.20%,
P: 0.030% or less,
S: 0.030% or less,
Cr: 1.30-2.50%,
Cu: 0.30% or less,
Al: 0.008 to 0.300%,
O: 0.0030% or less,
N: 0.0020 to 0.0300% is contained,
Further, Ti contains 0.020 to 0.200% and Nb: 0.02 to 0.20% of one or two,
It is a steel material made of mechanical structural steel consisting of the balance Fe and inevitable impurities,
Furthermore, the martensitic transformation start temperature (Ms point) of this steel material is 460 ° C. or less,
Using the above formula (1), J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel material and J9 of the hardness at a distance of 9 mm measured by the Jominy one-end quenching method for this steel material. The calculated (J9 / J1.5) value is in the range of 0.70 to 0.85,
Furthermore, the value of (J11 / J1.5) calculated by the above equation (2) using the hardness J1.5 at a distance of 1.5 mm and the hardness J11 at a distance of 11 mm is 0.67-0. In the range of 78,
A machine structural steel material with small heat treatment deformation is provided.
C:0.20~0.30%、
Si:0.10~1.50%、
Mn:0.10~1.20%、
P:0.030%以下、
S:0.030%以下、
Cr:1.30~2.50%、
Cu:0.30%以下、
Al:0.008~0.300%、
O:0.0030%以下、
N:0.0020~0.0300%を含有し、
さらにNi:0.20~3.00%およびMo:0.05~0.50%のうち1種または2種を含有し、
さらにTi:0.020~0.200%およびNb:0.02~0.20%のうち1種または2種を含有し、
残部Feおよび不可避不純物からなる機械構造用鋼からなる鋼材であり、
さらに、この鋼材のマルテンサイト変態開始温度(Ms点)が460℃以下であり、
この鋼材についてのジョミニー式一端焼入法により測定される鋼材の焼入端からの距離1.5mmにおける硬さのJ1.5および距離9mmにおける硬さのJ9を用いて上記の式(1)により算出の(J9/J1.5)の値が0.70~0.85の範囲にあり、
さらに、距離1.5mmにおける硬さのJ1.5および距離11mmにおける硬さのJ11を用いて、上記の式(2)により算出の(J11/J1.5)の値が0.67~0.78の範囲にある、
熱処理変形の小さい機械構造用鋼材が提供される。 According to another aspect of the present invention, there is provided a steel material for machine structural use having a small heat treatment deformation, the steel material being in mass%,
C: 0.20 to 0.30%
Si: 0.10 to 1.50%,
Mn: 0.10 to 1.20%,
P: 0.030% or less,
S: 0.030% or less,
Cr: 1.30-2.50%,
Cu: 0.30% or less,
Al: 0.008 to 0.300%,
O: 0.0030% or less,
N: 0.0020 to 0.0300% is contained,
Furthermore, it contains one or two of Ni: 0.20 to 3.00% and Mo: 0.05 to 0.50%,
Further, Ti contains 0.020 to 0.200% and Nb: 0.02 to 0.20% of one or two,
It is a steel material made of mechanical structural steel consisting of the balance Fe and inevitable impurities,
Furthermore, the martensitic transformation start temperature (Ms point) of this steel material is 460 ° C. or less,
Using the above formula (1), J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel and J9 of the hardness at a distance of 9 mm measured by the Jominy one-end quenching method for this steel. The calculated (J9 / J1.5) value is in the range of 0.70 to 0.85,
Further, the value of (J11 / J1.5) calculated by the above equation (2) using J1.5 of the hardness at a distance of 1.5 mm and J11 of the hardness at a distance of 11 mm is 0.67-0. In the range of 78,
A machine structural steel material with small heat treatment deformation is provided.
C:0.20~0.30%、
Si:0.10~1.50%、
Mn:0.10~1.20%、
P:0.030%以下、
S:0.030%以下、
Cr:1.30~2.50%、
Cu:0.30%以下、
Al:0.008~0.300%、
O:0.0030%以下、
N:0.0020~0.0300%
Ni:0~3.00%、
Mo:0~0.50%
Ti:0~0.200%、
Nb:0~0.20%
を含み、残部Feおよび不可避不純物からなり、
該鋼材が460℃以下のマルテンサイト変態開始温度(Ms点)を有し、
ジョミニー式一端焼入法により測定された際に、該鋼材の焼入端からの距離1.5mmにおける硬さJ1.5に対する、該鋼材の焼入端からの距離9mmにおける硬さJ9の比(J9/J1.5)が0.70~0.85の範囲にあり、かつ、該鋼材の焼入端からの距離1.5mmにおける硬さJ1.5に対する、該鋼材の焼入端からの距離11mmにおける硬さJ11の比(J11/J1.5)が0.67~0.78の範囲にある、機械構造用鋼材が提供される。 According to another aspect of the present invention, there is provided a steel material for machine structural use having a small heat treatment deformation, the steel material being in mass%,
C: 0.20 to 0.30%
Si: 0.10 to 1.50%,
Mn: 0.10 to 1.20%,
P: 0.030% or less,
S: 0.030% or less,
Cr: 1.30-2.50%,
Cu: 0.30% or less,
Al: 0.008 to 0.300%,
O: 0.0030% or less,
N: 0.0020 to 0.0300%
Ni: 0 to 3.00%,
Mo: 0 to 0.50%
Ti: 0 to 0.200%,
Nb: 0 to 0.20%
Comprising the balance Fe and inevitable impurities,
The steel material has a martensitic transformation start temperature (Ms point) of 460 ° C. or less,
The ratio of the hardness J9 at a distance of 9 mm from the quenching end of the steel material to the hardness J1.5 at a distance of 1.5 mm from the quenching end of the steel material when measured by the Jomini type one-end quenching method ( J9 / J1.5) is in the range of 0.70 to 0.85, and the distance from the quenching end of the steel to the hardness J1.5 at a distance of 1.5 mm from the quenching end of the steel A steel material for machine structure having a ratio of hardness J11 at 11 mm (J11 / J1.5) in the range of 0.67 to 0.78 is provided.
Cは、機械構造用部品として鋼材の焼入焼戻し後の強度もしくは浸炭焼入焼戻し後の芯部強度を確保するために必要な元素であり、熱処理変形を小さくするために所定の範囲に調整する必要がある。Cの含有量が0.20%未満では強度を確保できず、0.30%を超えると熱処理による変形が大きくなり過ぎる。そこでCの含有量は0.20~0.30%とし、望ましくは0.22~0.27%とする。 C: 0.20 to 0.30%
C is an element necessary for securing the strength after quenching and tempering of steel or the strength of the core after carburizing, quenching and tempering as mechanical structural parts, and is adjusted to a predetermined range in order to reduce heat treatment deformation. There is a need. If the C content is less than 0.20%, the strength cannot be ensured, and if it exceeds 0.30%, deformation due to heat treatment becomes too large. Therefore, the C content is set to 0.20 to 0.30%, preferably 0.22 to 0.27%.
Siは、脱酸に必要な元素であるとともに、鋼に必要な強度、焼入性を付与するために有効な元素である。しかし、Siの含有量が0.10%未満ではその効果が得られず、1.50%を超えると機械加工性を低下させる。そこでSiの含有量は0.10~1.50%とし、望ましくは0.20~1.00%とする。 Si: 0.10 to 1.50%
Si is an element necessary for deoxidation and is an effective element for imparting necessary strength and hardenability to steel. However, if the Si content is less than 0.10%, the effect cannot be obtained, and if it exceeds 1.50%, the machinability is lowered. Therefore, the Si content is 0.10 to 1.50%, preferably 0.20 to 1.00%.
Mnは、焼入性を確保するために必要な元素である。しかし、Mnの含有量が0.10%未満では焼入性への効果は十分に得られず、1.20%を超えると機械加工性を低下させる。そこでMnの含有量は0.10~1.20%とし、望ましくは0.20~0.80%、より望ましくは0.20~0.55%とする。 Mn: 0.10 to 1.20%
Mn is an element necessary for ensuring hardenability. However, if the Mn content is less than 0.10%, sufficient effect on hardenability cannot be obtained, and if it exceeds 1.20%, the machinability is lowered. Therefore, the Mn content is 0.10 to 1.20%, preferably 0.20 to 0.80%, and more preferably 0.20 to 0.55%.
Pは、スクラップから含有される不可避な元素であるが、粒界に偏析して衝撃強度や曲げ強度などの特性を低下させる。そこでPの含有量は0.030%以下(0%を含む)とし、典型的には0を超えて0.030%以下とする。 P: 0.030% or less P is an unavoidable element contained in scrap, but segregates at the grain boundary and lowers properties such as impact strength and bending strength. Therefore, the P content is 0.030% or less (including 0%), and typically exceeds 0 and is 0.030% or less.
Sは、被削性を向上させる元素であるが、非金属介在物であるMnSを生成して横方向の靱性および疲労強度を低下する。そこでSの含有量は0.030%以下(0%を含む)とし、典型的には0を超えて0.030%以下とする。 S: 0.030% or less S is an element that improves machinability, but generates MnS that is a non-metallic inclusion and lowers the toughness and fatigue strength in the transverse direction. Therefore, the S content is 0.030% or less (including 0%), and typically exceeds 0 and is 0.030% or less.
Crは、焼入性を確保するために必要な元素である。しかし、Crの含有量が1.30%未満では焼入性への効果は十分に得られず、2.50%を超えると浸炭を阻害し、また機械加工性も低下する。そこでCrの含有量は1.30~2.50%とし、望ましくは1.50~2.25%とする。 Cr: 1.30-2.50%
Cr is an element necessary for ensuring hardenability. However, if the Cr content is less than 1.30%, a sufficient effect on hardenability cannot be obtained. Therefore, the Cr content is set to 1.30 to 2.50%, preferably 1.50 to 2.25%.
Niは、焼入性および靱性を向上させる任意元素であり、その効果を得るためには0.20%以上の添加が好ましい。しかし、Niの含有量が3.00%を超えると加工性が著しく低下し、かつ、コストアップとなるので、3.00%以下とする。そこでNiの含有量は0.20~3.00%とする。 Ni: 0.20 to 3.00%
Ni is an optional element that improves hardenability and toughness, and in order to obtain the effect, addition of 0.20% or more is preferable. However, if the Ni content exceeds 3.00%, the workability is remarkably lowered and the cost is increased, so the content is made 3.00% or less. Therefore, the Ni content is set to 0.20 to 3.00%.
Moは、焼入性および靱性を向上させる任意元素であり、その効果を得るには0.05%以上の添加が好ましい。しかし、Moの含有量が0.50%を超えると加工性が低下する。そこで、Moの含有量は0.05~0.50%とする。 Mo: 0.05 to 0.50%
Mo is an optional element that improves hardenability and toughness, and 0.05% or more is preferable for obtaining the effect. However, if the Mo content exceeds 0.50%, the workability decreases. Therefore, the Mo content is set to 0.05 to 0.50%.
Cuは、スクラップから含有される不可避な元素であるが、時効性を有し、強度を上昇させる効果がある。しかし、Cuの含有量は0.30%を超えると熱間加工性を低下させる。そこで、Cuの含有量は0.30%以下(0%を含む)とし、典型的には0を超えて0.30%以下とする。 Cu: 0.30% or less Cu is an inevitable element contained from scrap, but has aging properties and an effect of increasing strength. However, when the Cu content exceeds 0.30%, the hot workability is lowered. Therefore, the Cu content is set to 0.30% or less (including 0%), and typically exceeds 0 and is set to 0.30% or less.
Alは、脱酸材として使用される元素であり、また後述のようにNと結合してAlNとして析出して結晶粒粗大化抑制効果をもたらす。この効果を得るため、Alを0.008%以上添加する必要がある。一方、Alを0.300%を超えて添加すると大型のアルミナ系介在物を形成し、疲労特性および加工性が低下する。そこで、Alの含有量は0.008~0.300%とし、望ましくは0.014~0.200%とする。 Al: 0.008 to 0.300%
Al is an element used as a deoxidizing material, and also binds to N and precipitates as AlN as will be described later, thereby bringing about an effect of suppressing grain coarsening. In order to obtain this effect, 0.008% or more of Al needs to be added. On the other hand, if Al is added in excess of 0.300%, large alumina inclusions are formed, and fatigue characteristics and workability are deteriorated. Therefore, the Al content is set to 0.008 to 0.300%, preferably 0.014 to 0.200%.
Oは、鋼中に不可避的に含有される元素である。しかし、Oが0.0030%を超えて含有されると酸化物の増加による加工性や疲労強度の低下を招く。そこでOの含有量は0.0030%以下(0%を含む)とし、望ましくは0.0020%以下(0%を含む)とする。また、典型的には0を超えて0.0030%以下、望ましくは0を超えて0.0020%以下とする。 O: 0.0030% or less O is an element inevitably contained in steel. However, if O exceeds 0.0030%, workability and fatigue strength are reduced due to an increase in oxide. Therefore, the content of O is set to 0.0030% or less (including 0%), preferably 0.0020% or less (including 0%). Also, typically, it exceeds 0 and is 0.0030% or less, and desirably exceeds 0 and is 0.0020% or less.
Nは、鋼中でAlNやNb窒化物として微細析出し、結晶粒粗大化を防止する効果をもたらす元素であり、その効果を得るためにはNiを0.0020%以上添加する必要がある。しかし、Niの含有量が0.0300%を超えると窒化物が増加し、疲労強度や加工性が低下する。そこで、Nの含有量は0.0020~0.0300%とし、望ましくは0.0020~0.0200%とする。ただし、特にTiを0.020%以上含有する鋼においては、TiNの過剰生成による疲労強度の低下を避けるため、Nの含有量は0.0020~0.0100%とする。 N: 0.0020 to 0.0300%
N is an element that finely precipitates as AlN or Nb nitride in the steel and has an effect of preventing the coarsening of crystal grains. In order to obtain the effect, it is necessary to add 0.0020% or more of Ni. However, if the Ni content exceeds 0.0300%, nitrides increase and fatigue strength and workability deteriorate. Therefore, the N content is set to 0.0020 to 0.0300%, preferably 0.0020 to 0.0200%. However, particularly in steel containing 0.020% or more of Ti, the N content is set to 0.0020 to 0.0100% in order to avoid a decrease in fatigue strength due to excessive TiN formation.
Tiは、鋼中のCと結び付いて炭化物を微細に形成し、結晶粒粗大化を防止する効果をもたらす任意元素であるが、その効果を得るためには、Tiを0.020%以上を添加することが好ましい。一方、Tiの含有量が0.200%を超えると機械加工性を損なう。そこで、Tiの含有量は0.020~0.200%とする。 Ti: 0.020 to 0.200%
Ti is an optional element that combines with C in the steel to form carbides finely and has the effect of preventing grain coarsening. To obtain this effect, 0.020% or more of Ti is added. It is preferable to do. On the other hand, if the Ti content exceeds 0.200%, the machinability is impaired. Therefore, the Ti content is set to 0.020 to 0.200%.
Nbは、炭化物あるいは窒化物を形成し、結晶粒粗大化防止効果をもたらす任意元素である。特に鋼中に微細に分散したナノオーダーサイズのNbCまたはNb(C,N)が結晶粒の成長を抑制する。Nbの含有量が0.02%未満では、その効果は得られず、0.20%を超えると析出物の量が過剰となり加工性が低下する。そこで、Nbの含有量は0.02~0.20%、望ましくは0.02~0.12%とする。 Nb: 0.02 to 0.20%
Nb is an arbitrary element that forms carbides or nitrides and has an effect of preventing grain coarsening. In particular, nano-order sized NbC or Nb (C, N) finely dispersed in steel suppresses the growth of crystal grains. If the Nb content is less than 0.02%, the effect cannot be obtained. If the Nb content exceeds 0.20%, the amount of precipitates becomes excessive and workability deteriorates. Therefore, the Nb content is 0.02 to 0.20%, preferably 0.02 to 0.12%.
本発明による鋼材においては、鋼材の熱処理変形を小さくするために、マルテンサイト変態開始温度(Ms点)を460℃以下に規制する必要がある。Ms点を460℃以下に規制することで熱処理変形を小さくできる理由は、焼入れした際に、部品の冷却がたとい不均一であっても、冷媒の冷却性能が高い温度域で、マルテンサイト変態が起こることを回避でき、その結果、マルテンサイト変態の時期が部品の部位によって大きくずれることが抑制できるからである。そこでMs点を460℃以下に規制するが、望ましくはMs点は450℃以下に規制する。なお、この場合の熱処理変形とは、軸状部品の曲がりやギヤの歯の倒れやねじれのことである。 Ms point: 460 ° C. or less In the steel material according to the present invention, it is necessary to regulate the martensite transformation start temperature (Ms point) to 460 ° C. or less in order to reduce the heat treatment deformation of the steel material. The reason why heat treatment deformation can be reduced by restricting the Ms point to 460 ° C. or less is that, even when the parts are not cooled when quenched, the martensitic transformation occurs in the temperature range where the cooling performance of the refrigerant is high. This is because it can be avoided, and as a result, it can be suppressed that the martensitic transformation time largely deviates depending on the parts. Therefore, the Ms point is restricted to 460 ° C. or lower, but preferably the Ms point is restricted to 450 ° C. or lower. In this case, the heat treatment deformation means bending of the shaft-shaped part, falling of the gear teeth, or twisting.
(J11/J1.5)の値:0.67~0.78
ジョミニー式一端焼入法により測定した際の、鋼材の焼入端からの距離1.5mmにおける硬さJ1.5に対する、該鋼材の焼入端からの距離9mmにおける硬さJ9の比(J9/J1.5)が0.70~0.85の範囲内にあり、鋼材の焼入端からの距離1.5mmにおける硬さJ1.5に対する、該鋼材の焼入端からの距離11mmにおける硬さJ11の比(J11/J1.5)が0.67~0.78の範囲内にあると、鋼材の熱処理変形を小さく抑えることができる。ここで言う熱処理変形とは、焼入れ後の軸状部品の曲がりやギヤの歯の倒れやねじれ、また、焼入れ前後における部品の寸法(長さ、径、厚み等)の変化のことである。なお、ジョミニー焼入性を適切な範囲に制御することで熱処理変形が抑制されるメカニズムについては、未だ十分に解明できていないが、ジョミニー焼入性が低すぎても、高すぎても熱処理変形が増大することは本発明者らにより実験的に確かめられている。理論に拘束されるものではないが、この範囲のジョミニー焼入性を有する鋼においては、焼入れの冷却過程においてマルテンサイト変態に先立ってベイナイト変態が適度に起こり、鋼材強度が高められ、ある程度変形しにくくなった状態からマルテンサイト変態が開始するために熱処理変形が抑えられるものと考えられる。一方、焼入性が低すぎる場合には、ベイナイト変態が過剰に起こるため、ベイナイト変態自体の影響によって熱処理変形が増大し、また、焼入れ性が高すぎる場合には、熱処理変形を緩和するベイナイト組織が少ないためにやはり熱処理変形が増大すると考えられる。 Value of (J9 / J1.5): 0.70 to 0.85
Value of (J11 / J1.5): 0.67 to 0.78
The ratio of the hardness J9 at a distance of 9 mm from the quenching end of the steel material to the hardness J1.5 at a distance of 1.5 mm from the quenching end of the steel material (J9 / J1.5) is in the range of 0.70 to 0.85, and the hardness at a distance of 11 mm from the quenching end of the steel relative to the hardness J1.5 at a distance of 1.5 mm from the quenching end of the steel When the ratio of J11 (J11 / J1.5) is in the range of 0.67 to 0.78, the heat treatment deformation of the steel material can be kept small. The heat treatment deformation referred to here is the bending of the shaft-shaped part, the gear teeth falling or twisting after quenching, and the change in the dimension (length, diameter, thickness, etc.) of the part before and after quenching. Although the mechanism by which heat treatment deformation is suppressed by controlling the Jominy hardenability within an appropriate range has not yet been fully elucidated, heat treatment deformation can be achieved even if Jominy hardenability is too low or too high. It has been experimentally confirmed by the present inventors that this increases. Without being bound by theory, in steels with Jominy hardenability in this range, bainite transformation occurs moderately prior to martensitic transformation in the quenching cooling process, increasing the strength of the steel material and deforming to some extent. It is considered that the deformation due to heat treatment is suppressed because the martensitic transformation starts from the difficult state. On the other hand, if the hardenability is too low, the bainite transformation occurs excessively, so that the heat treatment deformation increases due to the influence of the bainite transformation itself, and if the hardenability is too high, the bainite structure relaxes the heat treatment deformation. It is considered that the deformation due to heat treatment is also increased due to the small amount.
ただし、
(J9/J1.5)=(ジョミニー式一端焼入法により測定される焼入れ端からの距離9mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入れ端からの距離1.5mmの硬さ)……(1)
(J11/J1.5)=(ジョミニー式一端焼入法により測定される焼入れ端からの距離11mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入れ端からの距離1.5mmの硬さ)……(2) Table 3 shows the Ms point measured for the steel of the present invention, J1.5 of the hardness at a distance of 1.5 mm, J9 of the hardness at a distance of 9 mm from the quenching end measured by the Jomini type one-end quenching method, and Each value of the hardness J11 at a distance of 11 mm, and the obtained (J9 / J1.5) value and (J11 / J1.5) value are shown. Further, the bending (unit: mm) evaluated after quenching the above test piece, the absolute value of the difference in length of the test piece before and after the heat treatment (unit: mm), and the radius change of the test piece before and after the heat treatment determined by the above method An amount (unit: mm) and a groove width change amount (unit: mm) are shown. Invention Example No. As shown in Table 3, in the steel material consisting of 1 to 23, the martensite transformation start temperature, that is, the Ms point is in the range of 388 to 444 ° C., and (J9 / J1.5) of this steel material is represented by the following formula (1 ) Is in the range of 0.72 to 0.85, the value of formula (2) shown below in (J11 / J1.5) is in the range of 0.67 to 0.78, and the bend after heat treatment Is 0.005 to 0.030 mm, the absolute value of the difference in length of the test piece before and after heat treatment is 0.003 to 0.023 mm, and the amount of change in radius before and after heat treatment is 0.002 to 0.008 mm. The change in groove width before and after the heat treatment was 0.011 to 0.024 mm.
However,
(J9 / J1.5) = (hardness at a distance of 9 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (1.5 mm from the quenching end measured by the Jominy type one-end quenching method) (Hardness) …… (1)
(J11 / J1.5) = (hardness at a distance of 11 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (a distance of 1.5 mm from the quenching end measured by the Jominy type one-end quenching method) (Hardness) …… (2)
Claims (4)
- 質量%で、
C:0.20~0.30%、
Si:0.10~1.50%、
Mn:0.10~1.20%、
P:0.030%以下、
S:0.030%以下、
Cr:1.30~2.50%、
Cu:0.30%以下、
Al:0.008~0.300%、
O:0.0030%以下、
N:0.0020~0.0300%を含有し、
残部Feおよび不可避不純物からなる機械構造用鋼であり、
該鋼からなる鋼材のマルテンサイト変態開始温度(Ms点)が460℃以下であり、
該鋼材についてのジョミニー式一端焼入法により測定される鋼材の焼入端からの距離1.5mmにおける硬さのJ1.5および距離9mmにおける硬さのJ9を用いて、下記の式(1)によって算出した(J9/J1.5)の値が0.70~0.85の範囲にあり、
さらに距離1.5mmにおける硬さのJ1.5および距離11mmにおける硬さのJ11を用いて、下記の式(2)によって算出した(J11/J1.5)の値が0.67~0.78の範囲にある、
熱処理変形の小さい機械構造用鋼材。
ただし、
(J9/J1.5)=(ジョミニー式一端焼入法により測定される焼入端からの距離9mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入端からの距離1.5mmの硬さ)……式(1)
(J11/J1.5)=(ジョミニー式一端焼入法により測定される焼入端からの距離11mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入端からの距離1.5mmの硬さ)……式(2) % By mass
C: 0.20 to 0.30%
Si: 0.10 to 1.50%,
Mn: 0.10 to 1.20%,
P: 0.030% or less,
S: 0.030% or less,
Cr: 1.30-2.50%,
Cu: 0.30% or less,
Al: 0.008 to 0.300%,
O: 0.0030% or less,
N: 0.0020 to 0.0300% is contained,
It is a steel for machine structure consisting of the balance Fe and inevitable impurities,
The martensitic transformation start temperature (Ms point) of the steel material made of the steel is 460 ° C. or less,
The following formula (1) is used by using J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel material and J9 of the hardness at a distance of 9 mm measured by the Jominy-type one-end quenching method for the steel material. The value of (J9 / J1.5) calculated by is in the range of 0.70 to 0.85,
Further, using the hardness J1.5 at a distance of 1.5 mm and the hardness J11 at a distance of 11 mm, the value of (J11 / J1.5) calculated by the following equation (2) is 0.67 to 0.78. In the range of
Machine structural steel with small heat treatment deformation.
However,
(J9 / J1.5) = (hardness at a distance of 9 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (distance from the quenching end measured by the Jominy type one-end quenching method. (Hardness of 5mm) …… Formula (1)
(J11 / J1.5) = (hardness of a distance of 11 mm from the quenching end measured by the Jomini-type one-end quenching method) ÷ (distance from the quenching end measured by the Jomini-type one-end quenching method. (Hardness of 5mm) …… Formula (2) - 質量%で、
C:0.20~0.30%、
Si:0.10~1.50%、
Mn:0.10~1.20%、
P:0.030%以下、
S:0.030%以下、
Cr:1.30~2.50%、
Cu:0.30%以下、
Al:0.008~0.300%、
O:0.0030%以下、
N:0.0020~0.0300%を含有し、
さらにNi:0.20~3.00%およびMo:0.05~0.50%の1種または2種を含有し、
残部Feおよび不可避不純物からなる機械構造用鋼であり、
該鋼からなる鋼材のマルテンサイト変態開始温度(Ms点)が460℃以下であり、
該鋼材についてのジョミニー式一端焼入法により測定される鋼材の焼入端からの距離1.5mmにおける硬さのJ1.5および距離9mmにおける硬さのJ9を用いて、下記の式(1)によって算出した(J9/J1.5)の値が0.70~0.85の範囲にあり、
さらに距離1.5mmにおける硬さのJ1.5および距離11mmにおける硬さのJ11を用いて、下記の式(2)によって算出した(J11/J1.5)の値が0.67~0.78の範囲にある、
熱処理変形の小さい機械構造用鋼材。
ただし、
(J9/J1.5)=(ジョミニー式一端焼入法により測定される焼入端からの距離9mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入端からの距離1.5mmの硬さ)……(1)
(J11/J1.5)=(ジョミニー式一端焼入法により測定される焼入端からの距離11mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入端からの距離1.5mmの硬さ)……(2) % By mass
C: 0.20 to 0.30%
Si: 0.10 to 1.50%,
Mn: 0.10 to 1.20%,
P: 0.030% or less,
S: 0.030% or less,
Cr: 1.30-2.50%,
Cu: 0.30% or less,
Al: 0.008 to 0.300%,
O: 0.0030% or less,
N: 0.0020 to 0.0300% is contained,
Furthermore, it contains one or two of Ni: 0.20 to 3.00% and Mo: 0.05 to 0.50%,
It is a steel for machine structure consisting of the balance Fe and inevitable impurities,
The martensitic transformation start temperature (Ms point) of the steel material made of the steel is 460 ° C. or less,
The following formula (1) is used by using J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel material and J9 of the hardness at a distance of 9 mm measured by the Jominy-type one-end quenching method for the steel material. The value of (J9 / J1.5) calculated by is in the range of 0.70 to 0.85,
Further, using the hardness J1.5 at a distance of 1.5 mm and the hardness J11 at a distance of 11 mm, the value of (J11 / J1.5) calculated by the following equation (2) is 0.67 to 0.78. In the range of
Machine structural steel with small heat treatment deformation.
However,
(J9 / J1.5) = (hardness at a distance of 9 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (distance from the quenching end measured by the Jominy type one-end quenching method. (Hardness of 5mm) …… (1)
(J11 / J1.5) = (hardness of a distance of 11 mm from the quenching end measured by the Jomini-type one-end quenching method) ÷ (distance from the quenching end measured by the Jomini-type one-end quenching method. (Hardness of 5mm) …… (2) - 質量%で、
C:0.20~0.30%、
Si:0.10~1.50%、
Mn:0.10~1.20%、
P:0.030%以下、
S:0.030%以下、
Cr:1.30~2.50%、
Cu:0.30%以下、
Al:0.008~0.300%、
O:0.0030%以下、
N:0.0020~0.0300%を含有し、
さらにTi:0.020~0.200%およびNb:0.02~0.20%の1種または2種を含有し、
残部Feおよび不可避不純物からなる機械構造用鋼であり、
該鋼からなる鋼材のマルテンサイト変態開始温度(Ms点)が460℃以下であり、
該鋼材についてジョミニー式一端焼入法により測定される鋼材の焼入端からの距離1.5mmにおける硬さのJ1.5および距離9mmにおける硬さのJ9を用いて、下記の式(1)によって算出した(J9/J1.5)の値が0.70~0.85の範囲にあり、
さらに距離1.5mmにおける硬さのJ1.5および距離11mmにおける硬さのJ11を用いて、下記の式(2)によって算出した(J11/J1.5)の値が0.67~0.78の範囲にある、
熱処理変形の小さい機械構造用鋼材。
ただし、
(J9/J1.5)=(ジョミニー式一端焼入法により測定される焼入れ端からの距離9mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入れ端からの距離1.5mmの硬さ)……(1)
(J11/J1.5)=(ジョミニー式一端焼入法により測定される焼入れ端からの距離11mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入れ端からの距離1.5mmの硬さ)……(2) % By mass
C: 0.20 to 0.30%
Si: 0.10 to 1.50%,
Mn: 0.10 to 1.20%,
P: 0.030% or less,
S: 0.030% or less,
Cr: 1.30-2.50%,
Cu: 0.30% or less,
Al: 0.008 to 0.300%,
O: 0.0030% or less,
N: 0.0020 to 0.0300% is contained,
Furthermore, it contains one or two of Ti: 0.020-0.200% and Nb: 0.02-0.20%,
It is a steel for machine structure consisting of the balance Fe and inevitable impurities,
The martensitic transformation start temperature (Ms point) of the steel material made of the steel is 460 ° C. or less,
With respect to the steel material, J1.5 of the hardness at a distance of 1.5 mm from the quenching end of the steel material measured by the Jominy type one-end quenching method and J9 of the hardness at a distance of 9 mm are used according to the following formula (1). The calculated (J9 / J1.5) value is in the range of 0.70 to 0.85,
Further, using the hardness J1.5 at a distance of 1.5 mm and the hardness J11 at a distance of 11 mm, the value of (J11 / J1.5) calculated by the following equation (2) is 0.67 to 0.78. In the range of
Machine structural steel with small heat treatment deformation.
However,
(J9 / J1.5) = (hardness at a distance of 9 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (1.5 mm from the quenching end measured by the Jominy type one-end quenching method) (Hardness) …… (1)
(J11 / J1.5) = (hardness at a distance of 11 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (a distance of 1.5 mm from the quenching end measured by the Jominy type one-end quenching method) (Hardness) …… (2) - 質量%で、
C:0.20~0.30%、
Si:0.10~1.50%、
Mn:0.10~1.20%、
P:0.030%以下、
S:0.030%以下、
Cr:1.30~2.50%、
Cu:0.30%以下、
Al:0.008~0.300%、
O:0.0030%以下、
N:0.0020~0.0300%を含有し、
さらにNi:0.20~3.00%およびMo:0.05~0.50%の1種または2種を含有し、
さらにTi:0.020~0.200%およびNb:0.02~0.20%の1種または2種を含有し、
残部Feおよび不可避不純物からなる機械構造用鋼であり、
該鋼からなる鋼材のマルテンサイト変態開始温度(Ms点)が460℃以下であり、
該鋼材についてジョミニー式一端焼入法により測定される鋼材の焼入端からの距離1.5mmにおける硬さのJ1.5および距離9mmにおける硬さのJ9を用いて、下記の式(1)によって算出した(J9/J1.5)の値が0.70~0.85の範囲にあり、
さらに距離1.5mmにおける硬さのJ1.5および距離11mmにおける硬さのJ11を用いて、下記の式(2)によって算出した(J11/J1.5)の値が0.67~0.78の範囲にある、
熱処理変形の小さい機械構造用鋼材。
ただし、
(J9/J1.5)=(ジョミニー式一端焼入法により測定される焼入れ端からの距離9mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入れ端からの距離1.5mmの硬さ)……(1)
(J11/J1.5)=(ジョミニー式一端焼入法により測定される焼入れ端からの距離11mmの硬さ)÷(ジョミニー式一端焼入法により測定される焼入れ端からの距離1.5mmの硬さ)……(2) % By mass
C: 0.20 to 0.30%
Si: 0.10 to 1.50%,
Mn: 0.10 to 1.20%,
P: 0.030% or less,
S: 0.030% or less,
Cr: 1.30-2.50%,
Cu: 0.30% or less,
Al: 0.008 to 0.300%,
O: 0.0030% or less,
N: 0.0020 to 0.0300% is contained,
Furthermore, it contains one or two of Ni: 0.20 to 3.00% and Mo: 0.05 to 0.50%,
Furthermore, it contains one or two of Ti: 0.020-0.200% and Nb: 0.02-0.20%,
It is a steel for machine structure consisting of the balance Fe and inevitable impurities,
The martensitic transformation start temperature (Ms point) of the steel material made of the steel is 460 ° C. or less,
With respect to the steel material, J1.5 of hardness at a distance of 1.5 mm from the quenching end of the steel material measured by the Jominy type one-end quenching method and J9 of hardness at a distance of 9 mm are used according to the following formula (1). The calculated (J9 / J1.5) value is in the range of 0.70 to 0.85,
Further, using the hardness J1.5 at a distance of 1.5 mm and the hardness J11 at a distance of 11 mm, the value of (J11 / J1.5) calculated by the following equation (2) is 0.67 to 0.78. In the range of
Machine structural steel with small heat treatment deformation.
However,
(J9 / J1.5) = (hardness at a distance of 9 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (1.5 mm from the quenching end measured by the Jominy type one-end quenching method) (Hardness) …… (1)
(J11 / J1.5) = (hardness at a distance of 11 mm from the quenching end measured by the Jomini type one-end quenching method) ÷ (a distance of 1.5 mm from the quenching end measured by the Jominy type one-end quenching method) (Hardness) …… (2)
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US (1) | US20150218682A1 (en) |
JP (1) | JP6057626B2 (en) |
KR (1) | KR20150047524A (en) |
WO (1) | WO2014038548A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104404224A (en) * | 2014-12-15 | 2015-03-11 | 南车长江车辆有限公司 | Heat treatment process method for EA1N-material urban rail car axle |
CN110777303A (en) * | 2019-12-04 | 2020-02-11 | 宝钢特钢韶关有限公司 | Round steel for gear and preparation method thereof |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101705168B1 (en) * | 2015-04-20 | 2017-02-10 | 현대자동차주식회사 | Carburizing alloy steel improved durability and the method of manufacturing the same |
CN109971929A (en) * | 2019-04-16 | 2019-07-05 | 中南大学 | It is a kind of high throughput material preparation and performance characterization system |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001262203A (en) * | 2000-03-22 | 2001-09-26 | Daido Steel Co Ltd | High hardness gas atomizing shot |
JP2003055734A (en) * | 2001-08-10 | 2003-02-26 | Daido Steel Co Ltd | Austenitic tool steel having excellent machinability and method for producing austenitic tool |
JP2010150566A (en) * | 2008-12-24 | 2010-07-08 | Sumitomo Metal Ind Ltd | Steel for vacuum carburizing or vacuum carbo-nitriding |
JP2011225936A (en) * | 2010-04-20 | 2011-11-10 | Daido Steel Co Ltd | Carbonitrided steel of hydrogen embrittlement type having excellent surface fatigue strength |
JP2013040364A (en) * | 2011-08-12 | 2013-02-28 | Nippon Steel & Sumitomo Metal Corp | Rolled steel bar or wire rod for hot forging |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56116857A (en) * | 1980-02-20 | 1981-09-12 | Mitsubishi Steel Mfg Co Ltd | Low-heat treated strained steel for gear |
JP5185852B2 (en) * | 2009-02-13 | 2013-04-17 | 株式会社神戸製鋼所 | Gears with excellent resistance to peeling damage |
JP5350181B2 (en) * | 2009-10-27 | 2013-11-27 | 株式会社神戸製鋼所 | Case-hardened steel with excellent grain coarsening prevention properties |
WO2012073485A1 (en) * | 2010-11-30 | 2012-06-07 | Jfeスチール株式会社 | Carburizing steel having excellent cold forgeability, and production method thereof |
-
2012
- 2012-09-04 JP JP2012193763A patent/JP6057626B2/en active Active
-
2013
- 2013-09-03 WO PCT/JP2013/073681 patent/WO2014038548A1/en active Application Filing
- 2013-09-03 US US14/425,420 patent/US20150218682A1/en not_active Abandoned
- 2013-09-03 KR KR1020157006758A patent/KR20150047524A/en not_active Application Discontinuation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001262203A (en) * | 2000-03-22 | 2001-09-26 | Daido Steel Co Ltd | High hardness gas atomizing shot |
JP2003055734A (en) * | 2001-08-10 | 2003-02-26 | Daido Steel Co Ltd | Austenitic tool steel having excellent machinability and method for producing austenitic tool |
JP2010150566A (en) * | 2008-12-24 | 2010-07-08 | Sumitomo Metal Ind Ltd | Steel for vacuum carburizing or vacuum carbo-nitriding |
JP2011225936A (en) * | 2010-04-20 | 2011-11-10 | Daido Steel Co Ltd | Carbonitrided steel of hydrogen embrittlement type having excellent surface fatigue strength |
JP2013040364A (en) * | 2011-08-12 | 2013-02-28 | Nippon Steel & Sumitomo Metal Corp | Rolled steel bar or wire rod for hot forging |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104404224A (en) * | 2014-12-15 | 2015-03-11 | 南车长江车辆有限公司 | Heat treatment process method for EA1N-material urban rail car axle |
CN110777303A (en) * | 2019-12-04 | 2020-02-11 | 宝钢特钢韶关有限公司 | Round steel for gear and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
JP6057626B2 (en) | 2017-01-11 |
KR20150047524A (en) | 2015-05-04 |
JP2014047419A (en) | 2014-03-17 |
US20150218682A1 (en) | 2015-08-06 |
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