WO2014024642A1 - Method for manufacturing low-protein rice and food using low-protein rice - Google Patents

Method for manufacturing low-protein rice and food using low-protein rice Download PDF

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Publication number
WO2014024642A1
WO2014024642A1 PCT/JP2013/069182 JP2013069182W WO2014024642A1 WO 2014024642 A1 WO2014024642 A1 WO 2014024642A1 JP 2013069182 W JP2013069182 W JP 2013069182W WO 2014024642 A1 WO2014024642 A1 WO 2014024642A1
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WO
WIPO (PCT)
Prior art keywords
rice
oil
low protein
protein
steamed
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PCT/JP2013/069182
Other languages
French (fr)
Japanese (ja)
Inventor
誠史 関根
哲雄 高木
Original Assignee
日清オイリオグループ株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by 日清オイリオグループ株式会社 filed Critical 日清オイリオグループ株式会社
Priority to KR1020157003647A priority Critical patent/KR101877603B1/en
Priority to IN836DEN2015 priority patent/IN2015DN00836A/en
Priority to JP2014529401A priority patent/JP6204914B2/en
Priority to CN201380041461.7A priority patent/CN104519753A/en
Publication of WO2014024642A1 publication Critical patent/WO2014024642A1/en
Priority to PH12015500223A priority patent/PH12015500223A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/196Products in which the original granular shape is maintained, e.g. parboiled rice
    • A23L7/1965Cooked; Precooked; Fried or pre-fried in a non-aqueous liquid frying medium, e.g. oil
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • A23L5/11General methods of cooking foods, e.g. by roasting or frying using oil
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • A23L5/13General methods of cooking foods, e.g. by roasting or frying using water or steam

Definitions

  • the present invention relates to a method for producing low protein rice and a food obtained by cooking low protein rice obtained by such production method.
  • This application claims priority based on Japanese Patent Application No. 2012-176505 filed in Japan on August 8, 2012 and Japanese Patent Application No. 2012-223444 filed in Japan on October 5, 2012. , The contents of which are incorporated herein.
  • a diet that restricts protein intake usually reduces the amount of energy consumed or causes a shortage of nutrient intake because the amount of the meal itself is reduced or the type of meal that is consumed is restricted.
  • low protein rice has been proposed mainly for patients with kidney disease.
  • the low protein dry rice obtained by drying the low protein rice obtained by the action of the proteolytic enzyme may cause a problem that the rice grains are brittle and the rice grains collapse during distribution. Therefore, retort-packed low-protein rice has been developed, but low-protein rice has a low protein content, so the taste is not rich, and retort-packed low-protein rice has long-term storage stability.
  • the amount of pre-packed rice is fixed, there is a problem that the necessary amount cannot be measured and used.
  • Patent Document 1 discloses a method in which a protein contained in raw rice is decomposed with a proteolytic enzyme, and the resulting low protein rice is steamed and dried.
  • low protein rice obtained by steaming and drying low protein rice obtained by enzymatic reaction is difficult to disintegrate during distribution, but some rice grains disintegrate during cooking, There may be a problem that many rice grains are attached.
  • the present invention has been made in view of the above circumstances, and a method for producing low protein rice that is less likely to disintegrate during distribution and rice cooking and has less rice grain adhesion during rice cooking, and a low protein obtained by such a production method. It is an object to provide food using rice.
  • the present invention has, for example, the following aspects.
  • the first aspect of the present invention is a method for producing low protein rice, characterized in that raw rice is proteolytically treated, and the resulting treated rice is washed and then fried in oil.
  • the condition of frying with oil is fried at 100 ° C. or higher and lower than 150 ° C. for 60 to 300 seconds, or fried at 150 ° C. or higher and 185 ° C. or lower for 20 to 50 seconds.
  • the second aspect of the present invention is a food such as cooked rice or fried rice obtained by cooking low protein rice obtained by the production method of the first aspect.
  • the third aspect of the present invention is a method for producing low protein fried rice, characterized in that raw rice is proteolytically processed, and the resulting treated rice is washed and then fried in oil.
  • the oil is fried at 60 ° C. to 150 ° C. for 60 to 600 seconds or 150 ° C. to 185 ° C. for 20 to 50 seconds.
  • the rice after washing the treated rice, the rice may be immersed in oil of 90 ° C. or less to remove water, and then fried in oil.
  • the oil of 90 ° C. or less to be immersed is preferably an oil of 5 to 75 ° C.
  • the fourth aspect of the present invention is food such as cooked rice or fried rice obtained by cooking the low protein fried rice obtained by the production method of the third aspect.
  • the raw rice is subjected to proteolytic treatment, the treated rice obtained is washed, the rice is immersed in oil of 90 ° C. or less to remove water, and then steamed.
  • This is a method for producing low protein steamed rice.
  • the oil of 90 ° C. or lower to be immersed is preferably an oil of 5 to 75 ° C.
  • the sixth aspect of the present invention is food such as rice balls and fried rice obtained by cooking low protein steamed rice obtained by the production method of the fifth aspect.
  • a seventh aspect of the present invention is a method for producing a dried product of low protein steamed rice, characterized in that the low protein steamed rice obtained by the method of the fifth aspect is dried.
  • the eighth aspect of the present invention is food such as cooked rice or fried rice obtained by cooking a dried product of low protein steamed rice obtained by the production method of the seventh aspect.
  • the ninth aspect of the present invention is low protein fried rice produced by proteolytically treating raw rice, washing the resulting treated rice, and then frying in oil.
  • the oil frying condition is preferably 100 ° C. or higher and lower than 150 ° C. for 60 to 600 seconds, or 150 ° C. or higher and 185 ° C. or lower for 20 to 50 seconds.
  • the rice after the washing, the rice may be immersed in oil of 90 ° C. or less to remove water, and then fried in oil.
  • the oil of 90 ° C. or lower to be immersed is preferably an oil of 5 to 75 ° C.
  • the raw rice is subjected to proteolytic treatment, and the resulting treated rice is washed, and then the rice is immersed in oil of 90 ° C. or less to remove water, and then steamed. Low protein steamed rice produced.
  • the oil of 90 ° C. or lower is preferably an oil of 5 to 75 ° C.
  • the eleventh aspect of the present invention is a dried product of low protein steamed rice produced by drying the low protein steamed rice of the tenth aspect.
  • the present invention has the following aspects. (1) Proteolytic treatment of raw rice, washing the resulting treated rice, and then attaching oil to the rice, and gelatinizing the rice to which the oil has adhered , (2) attaching oil to the rice, immersing rice in oil, immersing rice in oil-containing immersion water containing oil, immersing rice in oil-containing emulsion immersion liquid; and The method for producing low-protein rice according to (1), which is at least one step selected from the group consisting of washing with water after applying oil to rice, (3) Gelatinizing the rice is at least one step selected from the group consisting of frying rice with oil, steaming the rice, and retorting the rice, (1) or (2) the method for producing low-protein rice according to (4) The method for producing low-protein rice according to (1), wherein the oil is attached to the rice and the rice is gelatinized by frying the rice with oil, (5) The method for producing a low protein rice according to (1) or (2), further comprising drying the rice after gelatinizing the rice, (6) A food obtained by
  • the present invention it is possible to provide a method for producing low protein rice (dried product of low protein fried rice and low protein steamed rice) in which rice grains are less likely to disintegrate during distribution and rice cooking, and less sticky to rice grains during rice cooking. . Therefore, when using the low protein fried rice obtained by the production method of the present invention and the dried product of the low protein steamed rice, the low protein rice is distributed in the same manner as raw rice, not retort packed rice. Can do. Even the same amount of rice is advantageous in terms of physical distribution because it has a smaller capacity and weight than retort packed low protein rice containing a lot of water.
  • the low protein fried rice obtained by the production method of the present invention and the dried product of low protein steamed rice have the same form as raw rice, so the amount of rice used is different from that of retort packed rice. It can be freely adjusted, is easy to use, and can be widely used in various dishes. Furthermore, according to the production method of the present invention, low protein rice having a rich taste and high energy can be produced. Since energy is higher than normal rice that does not reduce the protein content, patients with kidney disease prevent the reduction of energy intake by ingesting low protein rice obtained by the production method of the present invention. be able to. Moreover, the low protein fried rice obtained by the production method of the present invention and the dried product of the low protein steamed rice have high hygiene due to low water content.
  • the low protein rice in the present invention is rice that has undergone proteolytic treatment, washing treatment, and gelatinization treatment, and has a protein content less than that of raw rice.
  • Examples of the form include fried rice, steamed rice, dried products thereof, and retort-treated rice.
  • the steamed rice is rice obtained by steaming the rice
  • the steamed rice dry product is dry rice obtained by drying the steamed rice.
  • methods for steaming rice include steaming rice, steaming rice, and applying heated steam to the rice.
  • Steamed rice obtained by such steaming treatment includes steamed rice, steamed baked rice, heated steamed rice, etc., and as steamed rice dried products, steamed rice dried products, steamed baked rice dried products, Examples include dried products of heat steamed rice.
  • low protein rice which has been gelatinized by frying rice that has been subjected to proteolytic treatment and washing treatment with oil, is referred to as “low protein fried rice”, proteolysis treatment and washing treatment.
  • the rice that has been gelatinized by steaming the processed rice is "low-protein steamed rice", the dried low-protein steamed rice is “dried low-protein steamed rice", rice that has been proteolytically processed and washed Steamed rice is "low protein steamed rice", dried low protein steamed rice is “low protein steamed rice dry product", gelatinized by steaming and baking rice that has been proteolytically treated and washed
  • the low-protein steamed and baked rice is dried, and the low-protein steamed and baked rice is dried and the low-protein steamed and baked rice is dried.
  • the low-protein heated steam-treated rice is gelatinized and the low-protein heated steam-treated rice is dried.
  • the dried low-protein steamed rice is retorted.
  • the low protein rice in the present invention preferably has a protein content of 0.1 to 4% by mass, more preferably 0.1 to 2% by mass, and even more preferably 0.1 to 1% by mass.
  • the method for producing low protein rice according to one aspect of the present invention comprises subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, and gelatinizing the rice to which the oil has adhered. A method for producing low protein rice.
  • the type of raw rice is not particularly limited, and indica rice, japonica rice and the like can be used.
  • the present invention can exert an effect on Indica rice in which rice grains are likely to disintegrate after proteolytic treatment.
  • the proteolytic treatment in the present invention is to decompose proteins in rice.
  • the proteolytic treatment is not particularly limited, and known methods such as proteolytic treatment with a proteolytic enzyme and fermentation treatment with lactic acid bacteria can be used.
  • protease M manufactured by Amano Enzyme Co., Ltd.
  • a commercially available proteolytic enzyme can be used, for example, protease M (manufactured by Amano Enzyme Co., Ltd.) can be used.
  • the proteolytic reaction by the enzyme is preferably performed with a solution having a pH of 3 to 6, more preferably with a solution having a pH of 4 to 5.
  • a buffer solution such as an acetate buffer solution or a citrate buffer solution can be used, but is not limited thereto.
  • the reaction solution for proteolytic treatment can be prepared by adding a proteolytic enzyme to the solution having the above pH, and the content of the proteolytic enzyme in the reaction solution is preferably 0.01 to 2% by mass.
  • the content is preferably 0.1 to 1% by mass, and most preferably 0.3 to 0.7% by mass.
  • the amount of the reaction solution for proteolytic treatment is preferably 1.5 to 10 times the mass of the raw rice raw material, more preferably 3 to 7 times the mass, and 4 to 6 is preferred. Most preferably it is double the mass.
  • the proteolytic treatment it is preferable to immerse raw rice in the reaction solution at 20 ° C. to 60 ° C. for 2 hours to 50 hours, and to react the raw rice at 30 ° C. to 50 ° C. for 10 hours to 40 hours. It is more preferable to immerse in the liquid, and it is particularly preferable to immerse the raw rice in the reaction liquid at 40 to 45 ° C. for 15 to 30 hours.
  • the protein content in the rice can be adjusted to 0.1 to 2 g / 100 g, preferably 0.1 to 1 g / 100 g. Therefore, it is possible to produce low protein rice in which the protein content is reduced to about 1/10 to 1/30 of the protein content in raw raw rice.
  • the protein content in rice can be measured by the Kjeldahl method.
  • an emulsifier may be added to the reaction solution when proteolytic treatment is performed. It is thought that the outflow of starch from rice can be suppressed by adding an emulsifier.
  • the emulsifier is not particularly limited as long as it is generally used, and examples thereof include glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, and lecithin, and lecithin is preferable.
  • the rice it is preferable to wash the rice after the proteolytic treatment. By washing, protein degradation products can be removed from the rice. In order to maintain the shape of the rice grains at the time of washing, it is preferable to use the buffer solution described above or an aqueous salt solution generally used as the buffer solution for washing water.
  • the draining time is preferably 10 minutes to 60 minutes.
  • the attaching of oil to the rice includes immersing rice in oil, immersing rice in oil-containing immersion water containing oil, immersing rice in oil-containing emulsion immersion liquid, and oil in rice It is preferably at least one step selected from the group consisting of washing with water after coating.
  • the oil used in immersing rice in the oil may be any oil that is in a liquid state at the time of immersion, and vegetable oil and animal oil can be used.
  • soybean oil, rapeseed oil, corn oil, noodles One or more selected from oil, safflower oil, olive oil, rice oil, palm oil, palm fractionated oil, hydrogenated oil of these oils, transesterified oil of any of the above oils, etc. can be used.
  • rapeseed oil and soybean oil are preferred.
  • a palm hydrogenated oil having a melting point of 50 ° C. or a palm oil having a melting point of 26 ° C. it is solid at 25 ° C.
  • the immersion treatment is preferably performed at 50 to 90 ° C. when palm hydrogenated oil is used, and at 26 to 90 ° C. when palm oil is used.
  • the temperature of the soaking oil and the soaking time in soaking rice in the oil is preferably 5 to 90 ° C. for 5 seconds to 60 minutes, more preferably 5 to 80 ° C. for 5 seconds to 30 minutes, More preferably, the temperature is 10 to 70 ° C. for 5 seconds to 30 minutes.
  • the dipping treatment in oil may be performed under the condition that most of the water adhering to the rice can be removed. Specifically, the dipping for 5 seconds or more is preferably performed once or more, and the dipping for 10 seconds to 24 hours is 1 More preferably, it is more than once, more preferably 2 to 10 times. When it is desired to efficiently remove water in a relatively short production time, for example, it is preferable to perform immersion for 1 to 10 times for 5 seconds to 10 minutes while applying physical vibration to the rice to be immersed. Further, in order to increase the work efficiency of the production, even when the human is not working, specifically, for one night to one day (16 to 24 hours) after the proteolytic treatment, the oil may be immersed once. Good.
  • the oil-containing immersion water includes oil and water.
  • Examples of the oil contained in the oil-containing immersion water include those described above, and rapeseed oil and soybean oil are preferred.
  • the amount of oil in the oil-containing immersion water is preferably 0.17 ml or more, more preferably 0.17 to 2.5 ml, further preferably 0.18 to 1.5 ml, with respect to 1 g of raw raw rice. 0.18 to 1 ml is particularly preferred, and 0.18 to 0.7 ml is most preferred.
  • the oil content in the oil-containing immersion water is not particularly limited as long as the amount of oil relative to 1 g of raw raw rice is within the above range, but the oil-containing immersion water is 4 to 50% (vol./vol.).
  • the water content in the oil-containing immersion water is not particularly limited as long as the amount of oil relative to 1 g of raw raw rice is within the above range, but 50 to 96% (vol./vol.) In the oil-containing immersion water is It is preferably 70 to 96% (vol./vol.), More preferably 80 to 96% (vol./vol.), And particularly preferably 90 to 96% (vol./vol.).
  • the amount of the oil-containing immersion water with respect to 100 parts by mass of raw rice is not particularly limited as long as the amount of oil with respect to 1 g of raw rice is within the above range, but is 100 to 1000 parts by mass with respect to 100 parts by mass of raw rice. It is preferably 200 to 800 parts by mass, more preferably 300 to 700 parts by mass, and particularly preferably 400 to 600 parts by mass.
  • the temperature and the immersion time of the oil-containing immersion water are preferably 5 to 90 ° C. for 5 seconds to 60 minutes, and 5 to 80 ° C. for 5 seconds to 30 minutes. More preferably, the time is more preferably 10 to 70 ° C. for 5 seconds to 30 minutes.
  • Examples of the method for immersing rice in oil-containing immersion water include a method in which a gold monkey containing rice is placed in a container containing oil-containing immersion water, and the rice is immersed in oil-containing immersion water.
  • a stainless colander can be used, and its shape is not particularly limited, and may be round or square.
  • the size of the gold monkey used varies depending on the production scale of low protein rice, but when raw raw rice is added to the gold monkey, the raw raw rice occupies 1 to 80% of the volume of the gold monkey. It is preferable to use a large size, and it is more preferable to use a size that occupies 10 to 70%.
  • the size of the gold monkey to be used can be other than the above range, but the above range is preferable from the viewpoint of the efficiency of the dipping operation.
  • a stainless round colander having a diameter of 50 to 60 mm and a depth of 35 to 45 mm can be used.
  • a stainless round colander having a diameter of 150 to 180 mm and a depth of 65 to 75 mm can be used.
  • the weight of raw rice is about 1000 to 2000 g, a stainless square monkey having a length of 220 to 260 mm, a width of 300 to 350 mm, and a height of 70 to 90 mm can be used.
  • the container containing the oil-containing immersion water can be made of various materials such as a plastic container and a stainless steel container, and the shape thereof is not particularly limited. It may be, but it is efficient to use the same type as the monkey.
  • the size of the container to be used varies depending on the production scale of the low protein rice, but it is preferably 1.05 to 3 times the volume of the gold monkey to be put in the container, and 1.1 to 2 times the volume. More preferred. Although the thing of the magnitude
  • a plastic round container having a diameter of 55 to 65 mm and a depth of 35 to 45 mm can be used.
  • a stainless round colander having a diameter of 150 to 180 mm and a depth of 65 to 75 mm is used, a stainless round container having a diameter of 160 to 200 mm and a depth of 70 to 90 mm can be used.
  • the oil-containing emulsion immersion liquid contains water, oil, and an emulsifier.
  • the oil contained in the oil-containing emulsion immersion liquid include those described above, and rapeseed oil is preferred.
  • the emulsifier include lecithin, glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, and the like. At least one emulsifier selected from these is preferable, and lecithin is more preferable.
  • the oil content in the oil-containing emulsion immersion liquid is preferably 1 to 50% by mass, more preferably 2 to 30% by mass, and even more preferably 3 to 20% by mass.
  • the content of the emulsifier in the oil-containing emulsion immersion liquid is preferably 0.01 to 10% by mass, more preferably 0.02 to 5% by mass, and further preferably 0.03 to 5% by mass.
  • the water content in the oil-containing emulsion immersion liquid is preferably 40 to 99.99% by mass, more preferably 65 to 97.98% by mass, and even more preferably 77 to 96.97% by mass.
  • the amount of the oil-containing emulsion immersion liquid to 100 parts by mass of raw rice is preferably 100 to 1000 parts by mass, more preferably 150 to 500 parts by mass, and even more preferably 150 to 300 parts by mass.
  • the temperature of the oil-containing emulsion immersion liquid and the immersion time in immersing rice in the oil-containing emulsion immersion liquid are preferably 5 to 50 ° C. for 1 to 60 minutes, and 1 to 5 to 40 ° C. for 1 hour. More preferred is ⁇ 30 minutes, and further more preferred is 10 to 40 ° C. for 1 to 30 minutes.
  • a method of applying oil to rice a method of spraying (that is, spraying) oil on rice is preferable.
  • coating oil to rice it is preferable to wash
  • the temperature and time of washing the rice is preferably 5 to 90 ° C. for 5 seconds to 60 minutes, more preferably 5 to 80 ° C. for 5 seconds to 30 minutes, and more preferably 10 to 70 ° C. for 5 seconds. More preferred is ⁇ 30 minutes.
  • the method for producing low protein rice according to another aspect of the present invention includes subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, and gelatinizing the rice. And a method for producing low protein rice, wherein the gelatinization of the rice comprises at least one selected from the group consisting of frying rice with oil, steaming the rice, and retorting the rice. It is preferable that it is a process.
  • the method for steaming the rice include steaming the rice, steaming the rice, and applying heated steam to the rice.
  • gelatinization means that starch becomes pasty by heating in a state where water coexists.
  • a container containing boiling water and rice is put in a regular steamer and steamed.
  • the time for steaming the rice is preferably 1 to 120 minutes, more preferably 5 to 60 minutes, and even more preferably 5 to 30 minutes.
  • Examples of the method for steaming the rice include a method using a steam oven.
  • the temperature and time for steaming the rice is preferably 100 to 180 ° C. for 3 to 30 minutes, more preferably 100 to 160 ° C. for 3 to 30 minutes, and even more preferably 100 to 140 ° C. for 3 to 30 minutes.
  • the temperature of the water vapor and the time for which the water vapor is applied to the rice is preferably 100 to 500 ° C. for 1 second to 60 minutes, more preferably 150 to 450 ° C. for 1 second to 30 minutes, and 200 to 400 ° C. for 1 hour. More preferably, the second to 15 minutes.
  • the retort treatment of rice in the present invention is to wrap rice after cooking, to heat the rice after packaging, or to pressurize and heat the rice after packaging.
  • a method for producing low protein rice comprising subjecting raw rice to proteolytic treatment, washing the resulting treated rice, and then attaching oil to the rice, or gelatinizing the rice to which the oil has adhered. And drying the gelatinized rice.
  • the gelatinization of the rice is at least one step selected from the group consisting of steaming the rice, steaming the rice, applying heated steam to the rice, and retorting the rice. Preferably there is.
  • the method for producing low protein rice according to another aspect of the present invention comprises subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, and gelatinizing the rice to which the oil has adhered Including.
  • oil is attached to the rice and the rice to which the oil is attached is gelatinized by frying.
  • This is a method for producing low-protein rice according to the first aspect of the present invention, that is, low-protein rice characterized by subjecting raw rice to proteolytic treatment, washing the resulting treated rice, and then frying it with oil. That is, a method for producing low protein fried rice. In one process of frying rice with oil, two things can be done: attaching the oil to the rice and gelatinizing the rice with the oil attached.
  • oils and animal oils usually used for frying can be used. Specifically, soybean oil, rapeseed oil, corn oil, noodle seed oil, safflower oil, olive oil, rice oil, palm oil 1 or 2 kinds selected from palm fractionated oil, beef tallow, lard, hydrogenated oil of these oils, transesterified oil of any of the above oils, among these, rapeseed oil, Soybean oil is preferred.
  • the conditions of the temperature and frying time of the oil when frying rice may be any conditions that reduce the moisture of the rice and do not burn the rice.
  • a low-temperature frying treatment at 100 ° C. or more and less than 150 ° C. it is preferably fried for 60 to 600 seconds, more preferably 60 to 420 seconds, even more preferably 60 to 300 seconds, and 70 to 250 It is particularly preferred to fry for a second, most preferably fried for 80 to 250 seconds.
  • the high-temperature frying treatment at 150 ° C. or higher and 185 ° C. or lower it is preferably fried for 20 to 50 seconds, more preferably fried for 20 to 40 seconds, and most preferably fried for 25 to 35 seconds.
  • both low temperature frying processing and high temperature frying processing may be performed.
  • both the low-temperature fried treatment and the high-temperature fried treatment are performed, whichever may be performed first, it is preferable to perform the low-temperature fried treatment first.
  • the water content of the rice can be reduced to 3 to 15% by mass, preferably 3 to 10% by mass. From the viewpoint of rice storage stability and hygiene, it is preferable to reduce the water content of rice to 3 to 10% by mass.
  • the low protein fried rice obtained as described above is produced by frying a large amount of rice at a time, the rice tends to adhere to each other after the frying process. Even if the rice adheres to each other after the frying process, the rice is then separated by cooking or steaming, so that it can be used without any problem in taste.
  • it is preferable to remove the water adhering to the washed rice. Examples of a method for removing water adhering to the washed rice include a method of removing water adhering to the rice with a waste cloth after washing the enzyme-treated rice and before frying it with oil.
  • the rice is oil of 90 ° C. or less, preferably 5 to 75 ° C., more preferably 15 It is preferred to remove the water by immersing in an oil at ⁇ 65 ° C., most preferably at 25 ° -45 ° C.
  • the method for producing low protein rice according to another aspect of the present invention includes subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, and gelatinizing the rice. . And attaching oil to the rice, immersing rice in oil, immersing rice in oil-containing immersion water containing oil, immersing rice in oil-containing emulsion immersion liquid, and rice It is at least one step selected from the group consisting of washing with water after applying oil to the paste, and preferably further comprising drying the rice after gelatinizing the rice.
  • Examples of the method for drying rice include a method using a shelf dryer, a flat dryer, a conveyor dryer, a drum dryer, and the like, and a method using a shelf dryer is preferable.
  • the temperature and time for drying rice is preferably 20 to 90 ° C. for 0.1 to 8 hours, 40 to 90 ° C. for 0.5 to 6 hours, more preferably 60 to 80 ° C. for 1 to 4 hours. Further preferred.
  • the rice is gelatinized by retort treatment, since the retort food usually contains more water than the dried product as a product, the rice does not need to be dried after the retort treatment.
  • the low protein of the present invention comprising subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, steaming the rice, and then drying the rice
  • the dried product of low protein steamed rice produced by the rice production method or the proteolytic treatment of raw rice, washing the resulting treated rice, and then frying in oil The produced low protein fried rice can solidify the low protein rice and prevent the rice from collapsing.
  • low protein rice can be distributed in the same way as raw rice, not retort packed rice. Even the same amount of rice is advantageous in terms of physical distribution because it has a smaller capacity and weight than retort packed low protein rice containing a lot of water.
  • the low protein fried rice obtained by the production method of the present invention and the dried product of the low protein steamed rice have the same form as raw rice, so the amount of rice used is different from that of retort packed rice. Can be adjusted freely, is easy to use, and can be widely used in various dishes.
  • low protein rice having a rich taste and high energy can be produced.
  • the energy of rice is higher, so patients with kidney disease can reduce the intake energy by ingesting the low protein rice obtained by the production method of the present invention. Can be prevented.
  • the low-protein fried rice of the present invention and the dried product of low-protein steamed rice have the characteristics that rice grains are difficult to disintegrate during distribution and cooking, are rich, and have high energy. After washing the enzyme-treated rice and before frying it with oil, if the rice is immersed in oil at 90 ° C or lower to remove water, the rice will not adhere to each other during production or cooking, etc. You can get rice in the state.
  • the food according to another aspect of the present invention is obtained by cooking low protein rice obtained by the production method described above. And especially the case where low protein fried rice is used as low protein rice is the foodstuff of the said 4th aspect.
  • Examples of the method for cooking low protein rice of the present invention include rice cooking and steaming cooking.
  • the mass ratio of rice and water is preferably 1: 0.5-2.
  • the ratio is more preferably 1: 0.7 to 1.5, and particularly preferably 1: 0.8 to 1.2.
  • steaming refers to cooking by steaming a container containing boiling water and rice in a regular steamer, or cooking in a steamed state by spraying heated steam.
  • the ratio of the mass of boiling water and rice is preferably 1: 0.5 to 2, more preferably 1: 0.7 to 1.5, and 1: 0.8. Is particularly preferred.
  • Steamed cooking is preferably carried out in a conventional steamer for about 3 to 15 minutes.
  • the low protein rice of this invention can make various foods by cooking like raw rice.
  • examples of such foods include cooked rice, rice balls, rice cakes, fried rice, pho, and bread.
  • Another aspect of the present invention is a method for producing low protein steamed rice, which comprises subjecting raw rice to proteolytic treatment, washing the resulting treated rice, and then immersing the rice in oil of 90 ° C. or less to remove water. And then steaming, a method for producing low protein steamed rice. And in the manufacturing method of the said low protein steamed rice, the case where steaming is performed by the method of steaming is the manufacturing method of the low protein steamed rice of the said 5th aspect.
  • the raw rice to be used can be the same as that used in the method for producing the low protein fried rice described above, and the proteolytic treatment method, the treated rice washing method, and the draining rice The method can also be performed in the same manner as the method for producing low protein fried rice described above.
  • the immersion process of the treated rice in oil in the present invention will be described.
  • the dipping treatment in oil may be performed under the condition that most of the water adhering to the rice can be removed. Specifically, the dipping for 5 seconds or more is preferably performed once or more, and the dipping for 10 seconds to 24 hours is 1 More preferably, it is more than once, more preferably 2 to 10 times.
  • a method of performing immersion for 1 to 10 times for 5 seconds to 10 minutes while applying physical vibration to the rice to be immersed may be performed.
  • the oil may be immersed once. Good.
  • the immersion treatment it is considered that even if steaming is performed, adhesion between the rice grains after steaming is almost eliminated.
  • the oil used for the dipping may be an oil in a liquid state at the time of dipping.
  • rapeseed oil and soybean oil are preferred.
  • a palm hydrogenated oil having a melting point of 50 ° C. or a palm oil having a melting point of 26 ° C. it is solid at 25 ° C. Therefore, it is preferable to perform the dipping treatment at a temperature at which the oil used is in a liquid state.
  • the immersion treatment is preferably performed at 50 to 90 ° C. when palm hydrogenated oil is used, and at 26 to 90 ° C. when palm oil is used.
  • the steaming process in this invention is demonstrated.
  • Examples of the steaming treatment in the present invention include steaming rice, steaming rice, and applying heated steam to the rice.
  • a method of steaming rice it means cooking in a steamer by putting a container containing boiling water and rice in a regular steamer, or cooking in a steamed state by spraying heated steam.
  • the ratio of the mass of boiling water and rice is preferably 1: 0.5 to 2, more preferably 1: 0.7 to 1.5, and particularly preferably 1: 0.8 to 1.2.
  • Steamed cooking is preferably carried out in a conventional steamer for about 3 to 15 minutes.
  • Examples of the method for steaming the rice include a method using a steam oven.
  • the temperature and time for steaming the rice is preferably 100 to 180 ° C. for 3 to 30 minutes, more preferably 100 to 160 ° C. for 3 to 30 minutes, and even more preferably 100 to 140 ° C. for 3 to 30 minutes. According to the production method of the present invention, it is possible to produce a low-protein steamed rice having almost no adhesion between rice grains after steaming.
  • the food according to another aspect of the present invention is food such as rice balls and fried rice obtained by cooking low protein steamed rice obtained by the production method described above.
  • the cooked food in case the said low protein steamed rice is the low protein steamed rice obtained by the manufacturing method of a 5th aspect is foodstuffs, such as a rice ball and fried rice of the said 6th aspect.
  • the low protein steamed rice obtained by the production method of the present invention can be eaten as it is or cooked to produce food, and can be stored for a long time in a retort pack. Examples of the cooking method include molded cooking and fried cooking. For example, various foods such as rice balls and fried rice can be made. Retort-packed low protein steamed rice can be eaten by warming it with a microwave or hot water.
  • a method for producing a dried product of low protein steamed rice wherein the low protein steamed rice obtained by the production method described above is dried.
  • This is a dry product manufacturing method.
  • the low protein steamed rice is the low protein steamed rice obtained by the manufacturing method of the fifth aspect.
  • This is a method for producing dried protein steamed rice.
  • the food according to another aspect of the present invention is a food such as cooked rice or fried rice obtained by cooking a dried product of low protein steamed rice obtained by the production method described above.
  • the cooked food when the dried product of the low protein steamed rice is the dried product of the low protein steamed rice obtained by the production method of the seventh aspect is the cooked rice or fried rice of the eighth aspect. It is food.
  • the dried product of low-protein steamed rice has the same form as raw rice, unlike steamed rice before drying, so the amount of rice used can be adjusted freely, and it is easy to use. It can be widely used for foods such as.
  • Another aspect of the present invention is a low protein fried rice, that is, the ninth embodiment is a low protein fried rice produced by proteolytically treating raw rice, washing the obtained treated rice, and then frying in oil. Rice.
  • the explanation about the production of the low protein fried rice in the ninth aspect is the same as the explanation about the production method of the low protein fried rice of the third aspect.
  • the low protein steamed rice is obtained by subjecting raw rice to proteolytic treatment, washing the resulting treated rice, immersing the rice in 90 ° C. or lower oil, and removing water.
  • a low protein steamed rice produced by steaming The explanation about the production of the low protein steamed rice is the same as the explanation about the production of the low protein steamed rice described above.
  • the low protein steamed rice manufactured by performing the steaming process by the method of steaming is the low protein steamed rice of the tenth aspect.
  • the description related to the production of the low protein steamed rice in the tenth aspect is the same as the description related to the manufacture of the low protein steamed rice in the fifth aspect.
  • the dried product of low protein steamed rice according to another aspect of the present invention is a dried product of low protein steamed rice produced by drying the low protein steamed rice described above.
  • the explanation about the production of the dried product of the low protein steamed rice is the same as the explanation about the method for producing the dried product of the low protein steamed rice described above.
  • the low protein steamed rice of the eleventh aspect is used. It is a dried rice product.
  • the description relating to the production of the dried product of the low protein steamed rice of the eleventh aspect is the same as the explanation relating to the method for producing the dried product of the seventh aspect.
  • Another aspect of the present invention provides a method for producing low protein rice, Proteolytic treatment of raw rice, washing the resulting treated rice, and attaching oil to the rice, Gelatinizing the rice to which oil has adhered, and after gelatinizing the rice, further comprising drying the rice,
  • To attach oil to the rice is to immerse the rice in oil-containing immersion water containing oil, Gelatinizing the rice is steaming the rice,
  • the oil-containing immersion water includes water and oil
  • the oil comprises soybean oil, rapeseed oil, corn oil, noodle seed oil, safflower oil, olive oil, rice oil, palm oil, palm fractionated oil, hydrogenated oil of these oils, and transesterified oil of any of the above oils
  • At least one oil selected from the group
  • the oil content in the oil-containing immersion water is 0.17 to 2.5 ml with respect to 1 g of the raw rice,
  • the oil content in the oil-containing immersion water is 4 to 50% (vol./vol.)
  • Another aspect of the present invention provides a method for producing low protein rice, Proteolytic treatment of raw rice, washing the resulting treated rice, and attaching oil to the rice, Gelatinizing the rice to which oil has adhered, and after gelatinizing the rice, further comprising drying the rice,
  • To attach the oil to the rice is to immerse the rice in the oil-containing emulsion immersion liquid, Gelatinizing the rice is steaming the rice,
  • the oil-containing emulsion immersion liquid contains water, oil and an emulsifier,
  • the oil comprises soybean oil, rapeseed oil, corn oil, noodle seed oil, safflower oil, olive oil, rice oil, palm oil, palm fractionated oil, hydrogenated oil of these oils, and transesterified oil of any of the above oils
  • the emulsifier is at least one emulsifier selected from the group consisting of lecithin, glycerin fatty acid ester, polyglycerin fatty acid este
  • ⁇ Production of low protein rice (1) Various low protein rice was produced using indica rice as raw raw rice.
  • a pH 4.0 buffer solution 0.5% by mass of proteolytic enzyme (Protease M, Amano Enzyme Co., Ltd.) and emulsifier preparation (trade name: Ryoto Ester SMO, manufactured by Mitsubishi Chemical Foods Co., Ltd., composition: 2% by mass of sucrose fatty acid ester 3.5%, glycerin fatty acid ester 3.5%, oligosaccharide 43%, water 50%) was dissolved to prepare a reaction solution.
  • 350 ml of the reaction solution was added to 75 g of Indica rice (raw rice), and the enzyme treatment was performed while stirring with a stirrer at 42 ° C.
  • [Comparative Example 1] Indica rice drying process
  • the dried indica rice was dried by air drying at 70 ° C. for 90 minutes to obtain low protein indica rice.
  • [Comparative Example 2] Indica rice steaming treatment
  • Drained indica rice was put in a steamer and steamed for 5 minutes, and then dried by air drying at 70 ° C. for 90 minutes to obtain low protein Indica rice.
  • Example 1 Indica rice fried processing
  • the drained indica rice was fried for 30 seconds with 180 ° C. corn oil (trade name: Nisshin Corn Oil, manufactured by Nisshin Oilio Group Co., Ltd.) to obtain low protein Indica rice (low protein Indica fried rice).
  • low protein rice having a water content of 10% by mass or less and having good storage stability could be obtained.
  • the protein content could be reduced to about 1/10 of the raw rice by performing proteolytic treatment with proteolytic enzymes. Since the protein content is calculated based on the dry weight of 100 g, the rice after drained, air-dried, steamed or fried (rice in Comparative Examples 1 and 2 or rice in Example 1) The protein content of is considered to be the same as the protein content of drained rice shown in Table 2.
  • the boiling water of the same ratio as cooked rice was put into the rice of Example 1, steamed cooking was performed with a steamer, and steamed cooked rice was made.
  • the hardness of the obtained cooked rice and steamed cooked rice was measured by the following method. Hardness was measured with a device (RE-33005 RHEONER, manufactured by YAMADEN) that measures the compressive stress of a substance by linear motion for 10 g of cooked rice and steamed cooked rice filled in a container with a diameter of 40 mm and a height of 15 mm, respectively. . The measurement was performed by compression twice using a resin plunger having a diameter of 20 mm and a height of 8 mm at a compression speed of 10 mm / s and a clearance of 5 mm. The results are shown in Table 4.
  • the cooked rice of Example 1 had a lower hardness load than cooked rice of raw raw rice, and the steamed cooked rice of Example 1 had a greater hardness load than cooked rice of raw rice, There was no problem.
  • the rice cooked rice of Comparative Example 1 was evaluated as not delicious because it had a poor appearance and was very soft.
  • the cooked rice of the rice of Example 1 is almost the same as the cooked rice of Indica rice in terms of color and shape of rice grains, and in terms of taste, it is richer than commercially available low protein rice, and is evaluated to be delicious. there were.
  • the rice cooked rice of Comparative Example 2 was not evaluated as soft and delicious compared to the rice cooked rice of Example 1 because 1/3 to 1/2 of the whole rice grains collapsed.
  • Low protein rice was produced using indica rice or japonica rice as raw raw rice.
  • 0.5% by mass of a protease (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer solution to prepare a reaction solution.
  • 80 ml of the reaction solution was added to 15 g of Indica rice, and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 16 hours.
  • 80 ml of pH 4.0 buffer solution was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed.
  • the washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein rice such as indica rice or japonica rice.
  • [Comparative Example 3] Indica rice drying process
  • the dried indica rice was dried by air drying at room temperature for 30 minutes to obtain low protein indica rice.
  • [Comparative Example 4] Japonica rice air-dried) Dried japonica rice was dried by air drying at room temperature for 30 minutes to obtain low protein japonica rice.
  • [Example 2] Indica rice fried processing) Drained indica rice was fried for 30 seconds with rapeseed oil (trade name: Nisshin Canola Oil, manufactured by Nisshin Oilio Group Co., Ltd.) at 180 ° C. to obtain low protein indica rice (low protein indica rice).
  • Example 3 Japonica rice fried processing
  • the drained japonica rice was fried for 30 seconds with rapeseed oil at 180 ° C. (trade name: Nissin Canola Oil, Nissin Oilio Group Co., Ltd.) to obtain low protein japonica rice (low protein japonica rice).
  • low protein rice having a water content of 10% by mass or less and having good storage stability could be obtained.
  • the protein content By performing proteolytic treatment with a proteolytic enzyme, the protein content could be reduced to about 1/25 of the raw rice in both rice varieties. Since the protein content is calculated based on the dry weight of 100 g, the rice after drained or air-dried rice (rice in Comparative Examples 3 and 4 or rice in Examples 2 and 3) The protein content is considered to be the same as the protein content of drained rice shown in Table 9.
  • the rice cooked rice of Comparative Example 3 and Comparative Example 4 was evaluated as not delicious because it had a poor appearance and was very soft.
  • the rice cooked rice of Example 2 and Example 3 is almost the same as the cooked rice of Indica rice or Japonica rice in terms of color and shape of rice grains, and in terms of taste, it is richer than commercially available low protein rice There was an evaluation that it was delicious.
  • the energy of the rice of Example 2 and the rice of Comparative Example 3 was obtained by multiplying each analytical value by the energy conversion factor according to the nutrition labeling standard (2003 Ministry of Health, Labor and Welfare Notification No. 176). That is, 4 kcal / g for protein, 9 kcal / g for lipid, and 4 kcal / g for carbohydrate were multiplied.
  • the low protein rice obtained by the production method of the present invention has a higher amount of lipid and thus higher energy than the low protein rice obtained by air-drying the low protein rice.
  • Low protein rice was produced using Indica rice as raw raw rice.
  • 0.65 mass% of proteolytic enzyme (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer solution to prepare a reaction solution.
  • 350 ml of the reaction solution was added to 75 g of Indica rice (raw rice), and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 24 hours.
  • 350 ml of water was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed.
  • the washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein rice of Indica rice.
  • Example 4 Indica rice low-temperature fried processing Drained indica rice was fried for 90 seconds with rapeseed oil (trade name: Nisshin Canola Oil, manufactured by Nisshin Oilio Group Co., Ltd.) at 130 ° C. to obtain low protein indica rice (low protein indica rice).
  • rapeseed oil trade name: Nisshin Canola Oil, manufactured by Nisshin Oilio Group Co., Ltd.
  • Example 5 (Low-temperature fried treatment after oil immersion treatment, Indica rice) Prepare a container containing 75 ml of rapeseed oil (trade name: Nissin Canola Oil, Nissin Oilio Group Co., Ltd.) at 25 ° C., and drain the gold monkey containing 150 g of Indica low protein rice. The rice was put in oil and immersed in oil for 5 seconds.
  • rapeseed oil trade name: Nissin Canola Oil, Nissin Oilio Group Co., Ltd.
  • the gold monkey was taken out from the container, and the gold monkey was again put into a container containing rapeseed oil, so that the rice was again immersed in the oil for 5 seconds.
  • This dipping operation was repeated, and dipping for 5 seconds was performed 10 times in total.
  • the water adhering to the rice was removed, and water droplets had accumulated on the bottom of the container filled with oil.
  • the soaked rice is drained with gold colander, then fried for 240 seconds with rapeseed oil (trade name: Nisshin Canola Oil, Nisshin Oilio Group Co., Ltd.) at 130 ° C., and low protein indica fried rice (moisture) 10.8% by mass).
  • Example 6 Low-temperature fried treatment after oil immersion treatment, japonica rice
  • drained japonica rice was used in the same manner as in Example 5 to obtain low protein japonica fried rice (moisture 12.6% by mass).
  • Example 7 Low-temperature fried treatment after oil immersion treatment, Indica rice
  • Indica rice was produced in the same manner as Example 5 using rapeseed oil at 75 ° C (trade name: Nisshin Canola Oil, Nisshin Oilio Group Co., Ltd.) instead of rapeseed oil at 25 ° C, and low protein.
  • Indica fried rice water content 10.5% by mass was obtained.
  • Example 8 Low-temperature fried treatment without oil immersion treatment, Indica rice
  • rapeseed oil at 130 ° C (trade name: Nisshin Canola Oil, Nisshin Oillio Group Co., Ltd.)
  • rapeseed oil at 130 ° C (trade name: Nisshin Canola Oil, Nisshin Oillio Group Co., Ltd.)
  • rapeseed oil at 130 ° C (trade name: Nisshin Canola Oil, Nisshin Oillio Group Co., Ltd.)
  • rapeseed oil at 130 ° C (trade name: Nisshin Canola Oil, Nisshin Oillio Group Co., Ltd.)
  • rapeseed oil at 130 ° C (trade name: Nisshin Canola Oil, Nisshin Oillio Group Co., Ltd.)
  • rapeseed oil at 130 ° C (trade name: Nisshin Canola Oil, Nisshin Oill
  • B It is whiter and uncomfortable than the raw material Indica rice (raw rice).
  • Example 6 A: It is whiteness comparable as raw material japonica rice (raw rice).
  • B It is whiter and uncomfortable than raw material japonica rice (raw rice).
  • B Softer than A.
  • C Very soft.
  • B Overall evaluation is between A and C.
  • C The evaluation is not comprehensive or unfavorable.
  • Example 8 where the immersion treatment in oil was not performed before the frying treatment, many rice grains adhered were present, but when rice was cooked, adhesion of the rice grains was almost recognized. In other words, it was found that low protein cooked rice with an excellent appearance and texture was obtained. In addition, it was found that Examples 5-7, which were soaked before the frying treatment, yielded a low-protein rice with an excellent appearance and texture, as in the case of no soaking treatment. As for Japonica rice, it was found that low protein rice with excellent appearance and texture was obtained as in Indica rice.
  • the immersion oil used at this time was put into a centrifuge tube, and centrifuged (condition: 3000 rpm, 10 minutes) to separate water. Water accumulated in the bottom of the centrifuge tube was quantified with a micropipette, and the amount of water was defined as the amount of water removed from the rice that had been immersed once. Subsequently, the drained rice was put in another container containing 200 ml of rapeseed oil at 25 ° C. and immersed again for 5 seconds, and then the gold monkey was taken out from the container and drained. The immersion oil used at this time was put into a centrifuge tube, and centrifuged (condition: 3000 rpm, 10 minutes) to separate water.
  • Example 9 After oil immersion treatment, steaming treatment, drying) Prepare a container containing 75 ml of rapeseed oil (trade name: Nisshin Canola Oil, Nissin Oilio Group Co., Ltd.) at 25 ° C., and rapeseed oil containing gold monkey containing 15 g of indica low protein rice drained.
  • rapeseed oil trade name: Nisshin Canola Oil, Nissin Oilio Group Co., Ltd.
  • the gold colander was taken out of the container, and the gold colander was again put in the container, so that the rice was again immersed in the oil for 5 seconds.
  • This dipping operation was repeated, and dipping for 5 seconds was performed 10 times in total.
  • the soaked rice was degreased with a gold colander and then steamed with a commercially available steamer for 5 minutes to obtain low protein Indica steamed rice.
  • the obtained low protein Indica steamed rice was dried at 65 ° C.
  • the low-protein steamed rice had many rice grains adhering to it without oil soaking treatment. It was found that a product having no adhesion was obtained. From this, it was found that for low protein steamed rice, it is effective to dip the oil after the enzyme treatment and before steaming.
  • the rice cooked rice which is a dried product of low protein steamed rice, can be obtained in which the rice grains do not adhere to each other by performing an oil immersion treatment. From this, it was found that it is effective to dip the low-protein steamed rice with the oil after the enzyme treatment and before the steaming.
  • Example 10 to 16 Low protein indica prepared by preparing a container containing rapeseed oil (trade name: Nisshin Canola Oil, Nisshin Oillio Group Co., Ltd.) and water (hereinafter referred to as oil-containing immersion water) in the amount shown in Table 23 and draining.
  • rapeseed oil trade name: Nisshin Canola Oil, Nisshin Oillio Group Co., Ltd.
  • oil-containing immersion water water
  • the gold monkey After putting the gold monkey containing rice in a container containing oil-containing immersion water and immersing the rice in oil-containing immersion water, the gold monkey is removed from the container, and the gold monkey is put into the container again, so that the rice is added again. After immersion in oil-containing immersion water, the gold monkey was removed from the container and drained.
  • the low protein Indica rice that had been soaked twice in this manner was steamed and baked in a steam oven at 120 ° C. for 10 minutes, and the Indica rice was turned over and steamed for another 10 minutes to obtain low protein steamed rice.
  • the obtained low protein steamed baked rice was naturally dried to obtain a dried product of low protein steamed baked rice.
  • ⁇ Production of low protein rice (7) As raw raw rice, indica rice was used to produce low protein steamed baked rice and its dried product. First, 0.5% by mass of a protease (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer solution to prepare a reaction solution. The reaction solution was added to the amount of Indica rice shown in Table 24, and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 24 hours. A pH 4.0 buffer was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed.
  • a protease Protease M, manufactured by Amano Enzyme Co., Ltd.
  • Example 17 to 27 (After immersion in oil-containing immersion water, steamed and dried) Under the conditions shown in Table 24 or 25, low protein steamed baked rice and its dried product were produced in the same manner as in Example 10.
  • the protein content in the dried product of the low protein steamed rice obtained in Example 25 was measured by the Kjeldahl method, the value was 0.81% by mass.
  • the low protein rice was produced by this treatment. It was confirmed that
  • Example 28 Manufacture of emulsified immersion liquid
  • An emulsified immersion liquid was prepared by the following method with the formulation shown in Table 26.
  • Paste lecithin product name: lecithin DX, manufactured by Nisshin Oillio Group
  • vegetable oil product name: Nisshin Canola Oil, manufactured by Nisshin Oillio Group Co., Ltd.
  • lecithin was dissolved in the vegetable oil to obtain a lecithin-containing vegetable oil.
  • Low protein rice was produced using Indica rice as raw raw rice.
  • 0.5 mass% of proteolytic enzyme (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer to prepare a reaction solution.
  • 4.0 L of the reaction solution was added to 1100 g of the Indica rice (raw rice), and the enzyme treatment was performed while stirring with a stirrer at 40 ° C. for 20 hours.
  • 4 L of water was added to the enzyme-treated rice and stirred with a stirrer for 10 minutes for washing.
  • the washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein steamed rice of Indica rice and its dried product.
  • Example 29 Manufacture of emulsified immersion liquid
  • An emulsified immersion liquid was produced by the following method using the formulation shown in Table 27.
  • Paste lecithin product name: lecithin DX, manufactured by Nisshin Oillio Group
  • vegetable oil product name: Nisshin Canola Oil, manufactured by Nisshin Oillio Group Co., Ltd.
  • lecithin was dissolved in the vegetable oil to obtain a lecithin-containing vegetable oil.
  • the low-protein rice obtained by proteolytic treatment and washing of raw rice is immersed in an emulsion emulsified with oil before steaming and baking. It was found to have an effect.
  • the present invention can provide a method for producing low-protein rice that is less likely to disintegrate during distribution and rice cooking and has less adhesion of rice grains during rice cooking. Further, according to the production method of the present invention, low protein rice having a rich taste and high energy can be produced, and therefore it can be suitably used in the field of food production.

Abstract

A method for manufacturing a low-protein rice, said method comprising degrading protein in uncooked rice, washing the thus treated rice, then sticking oil to the rice and gelatinizing the rice. According to the present invention, a high-energy and low-protein rice that is suitable for distribution can be provided to protein-restricted patients with kidney diseases, etc.

Description

低蛋白質米の製造方法及び低蛋白質米を用いた食品Method for producing low protein rice and food using low protein rice
 本発明は、低蛋白質米の製造方法、及びかかる製造方法により得られた低蛋白質米を調理して得られる食品に関する。
 本願は、2012年8月8日に日本に出願された、特願2012-176505号、及び2012年10月5日に日本に出願された、特願2012-223444号に基づき優先権を主張し、その内容をここに援用する。
The present invention relates to a method for producing low protein rice and a food obtained by cooking low protein rice obtained by such production method.
This application claims priority based on Japanese Patent Application No. 2012-176505 filed in Japan on August 8, 2012 and Japanese Patent Application No. 2012-223444 filed in Japan on October 5, 2012. , The contents of which are incorporated herein.
 腎臓病により、腎臓での尿素窒素の排出機能が低下した人は、体内での蛋白質分解による尿素窒素の生成を抑制するために、蛋白質の摂取量を制限しなければならない。
 蛋白質の摂取を制限する食事は、通常、食事の量そのものを少なくしたり、摂取する食事の種類を制限するため、摂取エネルギーの低下や、栄養素の摂取不足の原因となる。
Persons whose kidney nitrogen excretion function has decreased due to kidney disease must limit protein intake in order to suppress urea nitrogen production due to protein degradation in the body.
A diet that restricts protein intake usually reduces the amount of energy consumed or causes a shortage of nutrient intake because the amount of the meal itself is reduced or the type of meal that is consumed is restricted.
 近年、主に腎臓病患者を対象として、蛋白質の含量を低減させた米、いわゆる低蛋白質米が提案されている。しかし、蛋白質分解酵素を作用させて得られた低蛋白質米を乾燥して得られる低蛋白質乾燥米は、米粒が脆く、流通時に米粒が崩壊してしまうという問題が生じてしまうことがあった。
 そこで、レトルトパックされた低蛋白質米が開発されているが、低蛋白質米は蛋白質含量が少なくなっているため味にコクがなく、また、レトルトパックされた低蛋白質米は、長期の保存性には優れるものの、あらかじめパックされた米の量が決まっているため、必要な量を量り取って使用するということができないという問題があった。さらに、レトルトパックされた低蛋白質米は、かなりの量の水分を含有し、容量及び重量も大きくなってしまうことから、生米と同じ量の米を流通させようとした場合に、物流コストが高くなってしまうという問題があった。
 かかる欠点を解消する手段として、特許文献1に、原料米に含まれる蛋白質を蛋白質分解酵素で分解し、得られた低蛋白質米を蒸してから乾燥するという方法が開示されている。
In recent years, rice having a reduced protein content, so-called low protein rice, has been proposed mainly for patients with kidney disease. However, the low protein dry rice obtained by drying the low protein rice obtained by the action of the proteolytic enzyme may cause a problem that the rice grains are brittle and the rice grains collapse during distribution.
Therefore, retort-packed low-protein rice has been developed, but low-protein rice has a low protein content, so the taste is not rich, and retort-packed low-protein rice has long-term storage stability. However, because the amount of pre-packed rice is fixed, there is a problem that the necessary amount cannot be measured and used. Furthermore, retort-packed low protein rice contains a significant amount of moisture and increases its capacity and weight, so if you try to distribute the same amount of rice as raw rice, the distribution cost is low. There was a problem of becoming high.
As a means for eliminating such drawbacks, Patent Document 1 discloses a method in which a protein contained in raw rice is decomposed with a proteolytic enzyme, and the resulting low protein rice is steamed and dried.
特開平8-38077号公報JP-A-8-38077
 しかしながら、酵素反応により得られた低蛋白質米を蒸してから乾燥することにより得られた低蛋質米は、米粒が流通時に崩壊しにくくなるものの、炊飯時に米粒の一部が崩壊したり、数粒の米粒が付着したものが多く存在してしまうという問題が生じることがあった。 However, low protein rice obtained by steaming and drying low protein rice obtained by enzymatic reaction is difficult to disintegrate during distribution, but some rice grains disintegrate during cooking, There may be a problem that many rice grains are attached.
 本発明は、上記事情に鑑みてなされたものであり、流通時及び炊飯時に米粒が崩壊しにくく、炊飯時に米粒の付着が少ない低蛋白質米の製造方法、及びかかる製造方法により得られた低蛋白質米を用いた食品を提供することを課題とする。 The present invention has been made in view of the above circumstances, and a method for producing low protein rice that is less likely to disintegrate during distribution and rice cooking and has less rice grain adhesion during rice cooking, and a low protein obtained by such a production method. It is an object to provide food using rice.
 本発明者らは、かかる課題を解決するため鋭意検討した結果、本発明を完成するに至った。
 本発明は、例えば下記の態様を有する。
As a result of intensive studies to solve such problems, the present inventors have completed the present invention.
The present invention has, for example, the following aspects.
 すなわち、本発明の第一の態様は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げることを特徴とする低蛋白質米の製造方法である。 That is, the first aspect of the present invention is a method for producing low protein rice, characterized in that raw rice is proteolytically treated, and the resulting treated rice is washed and then fried in oil.
 本発明の第一の態様において、前記油で揚げる条件は、100℃以上150℃未満で60~300秒間、又は150℃以上185℃以下で20~50秒間揚げることが好ましい。 In the first aspect of the present invention, it is preferable that the condition of frying with oil is fried at 100 ° C. or higher and lower than 150 ° C. for 60 to 300 seconds, or fried at 150 ° C. or higher and 185 ° C. or lower for 20 to 50 seconds.
 本発明の第二の態様は、第一の態様の製造方法により得られる低蛋白質米を調理して得られる、炊飯米やチャーハンなどの食品である。 The second aspect of the present invention is a food such as cooked rice or fried rice obtained by cooking low protein rice obtained by the production method of the first aspect.
 本発明の第三の態様は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げることを特徴とする低蛋白質揚げ米の製造方法である。 The third aspect of the present invention is a method for producing low protein fried rice, characterized in that raw rice is proteolytically processed, and the resulting treated rice is washed and then fried in oil.
 本発明の第三の態様において、前記油で揚げる条件は、100℃以上150℃未満で60~600秒間、又は150℃以上185℃以下で20~50秒間揚げることが好ましい。 In the third aspect of the present invention, it is preferable that the oil is fried at 60 ° C. to 150 ° C. for 60 to 600 seconds or 150 ° C. to 185 ° C. for 20 to 50 seconds.
 本発明の第三の態様において、処理米を洗浄後、米を90℃以下の油に浸漬して水を除去し、その後油で揚げても良い。 In the third aspect of the present invention, after washing the treated rice, the rice may be immersed in oil of 90 ° C. or less to remove water, and then fried in oil.
 本発明の第三の態様において、浸漬する90℃以下の油は、5~75℃の油であることが好ましい。 In the third embodiment of the present invention, the oil of 90 ° C. or less to be immersed is preferably an oil of 5 to 75 ° C.
 本発明の第四の態様は、第三の態様の製造方法により得られる低蛋白質揚げ米を調理して得られる、炊飯米やチャーハンなどの食品である。 The fourth aspect of the present invention is food such as cooked rice or fried rice obtained by cooking the low protein fried rice obtained by the production method of the third aspect.
 本発明の第五の態様は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米を90℃以下の油に浸漬して水を除去し、その後蒸し処理をすることを特徴とする低蛋白質蒸し米の製造方法である。 In the fifth aspect of the present invention, the raw rice is subjected to proteolytic treatment, the treated rice obtained is washed, the rice is immersed in oil of 90 ° C. or less to remove water, and then steamed. This is a method for producing low protein steamed rice.
 本発明の第五の態様において、浸漬する90℃以下の油は、5~75℃の油であることが好ましい。 In the fifth aspect of the present invention, the oil of 90 ° C. or lower to be immersed is preferably an oil of 5 to 75 ° C.
 本発明の第六の態様は、第五の態様の製造方法により得られる低蛋白質蒸し米を調理して得られる、おにぎりやチャーハンなどの食品である。 The sixth aspect of the present invention is food such as rice balls and fried rice obtained by cooking low protein steamed rice obtained by the production method of the fifth aspect.
 本発明の第七の態様は、第五の態様の製造方法により得られる低蛋白質蒸し米を乾燥することを特徴とする低蛋白質蒸し米の乾燥品の製造方法である。 A seventh aspect of the present invention is a method for producing a dried product of low protein steamed rice, characterized in that the low protein steamed rice obtained by the method of the fifth aspect is dried.
 本発明の第八の態様は、第七の態様の製造方法により得られる低蛋白質蒸し米の乾燥品を調理して得られる、炊飯米やチャーハンなどの食品である。 The eighth aspect of the present invention is food such as cooked rice or fried rice obtained by cooking a dried product of low protein steamed rice obtained by the production method of the seventh aspect.
 本発明の第九の態様は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げることにより製造される低蛋白質揚げ米である。 The ninth aspect of the present invention is low protein fried rice produced by proteolytically treating raw rice, washing the resulting treated rice, and then frying in oil.
 本発明の第九の態様において、前記油で揚げる条件は、100℃以上150℃未満で60~600秒間、又は150℃以上185℃以下で20~50秒間であることが好ましい。 In the ninth aspect of the present invention, the oil frying condition is preferably 100 ° C. or higher and lower than 150 ° C. for 60 to 600 seconds, or 150 ° C. or higher and 185 ° C. or lower for 20 to 50 seconds.
 本発明の第九の態様において、前記洗浄後に、米を90℃以下の油に浸漬して水を除去し、その後油で揚げてもよい。 In the ninth aspect of the present invention, after the washing, the rice may be immersed in oil of 90 ° C. or less to remove water, and then fried in oil.
 本発明の第九の態様において、浸漬する90℃以下の油は、5~75℃の油であることが好ましい。 In the ninth aspect of the present invention, the oil of 90 ° C. or lower to be immersed is preferably an oil of 5 to 75 ° C.
 本発明の第十の態様は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米を90℃以下の油に浸漬して水を除去し、その後蒸し処理をすることにより製造される低蛋白質蒸し米である。 In a tenth aspect of the present invention, the raw rice is subjected to proteolytic treatment, and the resulting treated rice is washed, and then the rice is immersed in oil of 90 ° C. or less to remove water, and then steamed. Low protein steamed rice produced.
 本発明の第十の態様において、前記90℃以下の油は、5~75℃の油であることが好ましい。 In the tenth aspect of the present invention, the oil of 90 ° C. or lower is preferably an oil of 5 to 75 ° C.
 本発明の第十一の態様は、第十の態様の低蛋白質蒸し米を乾燥することにより製造される低蛋白質蒸し米の乾燥品である。 The eleventh aspect of the present invention is a dried product of low protein steamed rice produced by drying the low protein steamed rice of the tenth aspect.
 また、本発明は以下の側面を有する。
(1)生米を蛋白質分解処理し、得られた処理米を洗浄した後、米へ油を付着させること、及び油が付着した前記米を糊化することを含む、低蛋白質米の製造方法、
(2)前記米へ油を付着させることが、油に米を浸漬させること、油を含有する油含有浸漬水に米を浸漬させること、油含有乳化液浸漬液に米を浸漬させること、及び米に油を塗布した後に水で洗浄することからなる群より選ばれる少なくとも1の工程である、(1)に記載の低蛋白質米の製造方法、
(3)前記米を糊化することが、米を油で揚げること、米を蒸し処理すること、及び米をレトルト処理することからなる群より選ばれる少なくとも1の工程である、(1)又は(2)に記載の低蛋白質米の製造方法、
(4)前記米へ油を付着させること、及び米を糊化することを、米を油で揚げることにより行う、(1)に記載の低蛋白質米の製造方法、
(5)前記米を糊化することの後に、さらに、米を乾燥させることを含む、(1)又は(2)に記載の低蛋白質米の製造方法、
(6)(1)~(5)のいずれか1項に記載の製造方法で得られる低蛋白質米を調理して得られる食品、
(7)生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げることを特徴とする低蛋白質揚げ米の製造方法、
(8)(7)に記載の製造方法で得られる低蛋白質揚げ米を調理して得られる食品、
(9)生米を蛋白質分解処理し、得られた処理米を洗浄した後、米を90℃以下の油に浸漬して水を除去し、その後蒸し処理をすることを特徴とする低蛋白質蒸し処理米の製造方法、
(10)(9)に記載の製造方法により得られる低蛋白質蒸し処理米を調理して得られる食品、
(11)(9)に記載の製造方法により得られる低蛋白質蒸し処理米を乾燥することを特徴とする低蛋白質蒸し処理米の乾燥品の製造方法、
(12)(11)に記載の製造方法により得られる低蛋白質蒸し処理米の乾燥品を調理して得られる食品、
(13)生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げることにより製造される低蛋白質揚げ米、
(14)生米を蛋白質分解処理し、得られた処理米を洗浄した後、米を90℃以下の油に浸漬して水を除去し、その後蒸し処理をすることにより製造される低蛋白質蒸し処理米、及び
(15)(14)に記載の低蛋白質蒸し処理米を乾燥することにより製造される低蛋白質蒸し処理米の乾燥品。
The present invention has the following aspects.
(1) Proteolytic treatment of raw rice, washing the resulting treated rice, and then attaching oil to the rice, and gelatinizing the rice to which the oil has adhered ,
(2) attaching oil to the rice, immersing rice in oil, immersing rice in oil-containing immersion water containing oil, immersing rice in oil-containing emulsion immersion liquid; and The method for producing low-protein rice according to (1), which is at least one step selected from the group consisting of washing with water after applying oil to rice,
(3) Gelatinizing the rice is at least one step selected from the group consisting of frying rice with oil, steaming the rice, and retorting the rice, (1) or (2) the method for producing low-protein rice according to
(4) The method for producing low-protein rice according to (1), wherein the oil is attached to the rice and the rice is gelatinized by frying the rice with oil,
(5) The method for producing a low protein rice according to (1) or (2), further comprising drying the rice after gelatinizing the rice,
(6) A food obtained by cooking low protein rice obtained by the production method according to any one of (1) to (5),
(7) A method for producing low protein fried rice characterized by proteolytically treating raw rice, washing the resulting treated rice, and then frying with oil,
(8) A food obtained by cooking low protein fried rice obtained by the production method according to (7),
(9) Proteolytic treatment of raw rice, washing the resulting treated rice, immersing the rice in oil at 90 ° C. or less to remove water, and then steaming, Manufacturing method of treated rice,
(10) A food obtained by cooking low protein steamed rice obtained by the production method according to (9),
(11) A method for producing a dried product of low protein steamed rice, characterized by drying the low protein steamed rice obtained by the production method according to (9),
(12) A food obtained by cooking a dried product of low protein steamed rice obtained by the production method according to (11),
(13) Low protein fried rice produced by proteolytically treating raw rice, washing the resulting treated rice, and then frying in oil;
(14) Steaming low protein produced by proteolytically treating raw rice, washing the resulting treated rice, immersing the rice in oil at 90 ° C. or less to remove water, and then steaming Processed rice, and dried product of low protein steamed rice produced by drying the low protein steamed rice described in (15) and (14).
 本発明により、流通時及び炊飯時に米粒が崩壊しにくく、炊飯時に米粒の付着が少ない低蛋白質米(低蛋白質揚げ米、及び低蛋白質蒸し処理米の乾燥品)の製造方法を提供することができる。したがって、本発明の製造方法で得られる低蛋白質揚げ米、及び低蛋白質蒸し処理米の乾燥品を用いると、低蛋白質米を、レトルトパックされた米ではなく、生米と同じように流通させることができる。同じ量の米であっても、水分を多く含むレトルトパックされた低蛋白質米に比べて容量及び重量が小さくなることから、物流面で有利となる。
 また、本発明の製造方法で得られる低蛋白質揚げ米、及び低蛋白質蒸し処理米の乾燥品は、生米と同じような形態であるから、レトルトパックされた米と違って米の使用量を自由に調整することができ、使いやすく、種々の料理に広く使用することができる。
 さらに、本発明の製造方法によれば、味にコクがあり、かつエネルギーが高い低蛋白質米を製造することができる。蛋白質含量を低減していない通常の米と比較して、エネルギーが高いので、腎臓病患者が、本発明の製造方法で得られた低蛋白質米を摂取することで、摂取エネルギーの低下を防止することができる。
 また、本発明の製造方法で得られた低蛋白質揚げ米、及び低蛋白質蒸し処理米の乾燥品は、水分が少ないことから衛生性が高くなる。
INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide a method for producing low protein rice (dried product of low protein fried rice and low protein steamed rice) in which rice grains are less likely to disintegrate during distribution and rice cooking, and less sticky to rice grains during rice cooking. . Therefore, when using the low protein fried rice obtained by the production method of the present invention and the dried product of the low protein steamed rice, the low protein rice is distributed in the same manner as raw rice, not retort packed rice. Can do. Even the same amount of rice is advantageous in terms of physical distribution because it has a smaller capacity and weight than retort packed low protein rice containing a lot of water.
In addition, the low protein fried rice obtained by the production method of the present invention and the dried product of low protein steamed rice have the same form as raw rice, so the amount of rice used is different from that of retort packed rice. It can be freely adjusted, is easy to use, and can be widely used in various dishes.
Furthermore, according to the production method of the present invention, low protein rice having a rich taste and high energy can be produced. Since energy is higher than normal rice that does not reduce the protein content, patients with kidney disease prevent the reduction of energy intake by ingesting low protein rice obtained by the production method of the present invention. be able to.
Moreover, the low protein fried rice obtained by the production method of the present invention and the dried product of the low protein steamed rice have high hygiene due to low water content.
 本発明における低蛋白質米とは、蛋白質分解処理、洗浄処理、及び糊化処理を経た米で、生米よりも蛋白質含量が少なくなった米のことである。その形態としては、揚げ米、蒸し処理米及びその乾燥品、レトルト処理米等が挙げられる。
 ここで、蒸し処理米とは、米を蒸し処理することにより得られる米のことであり、蒸し処理米の乾燥品とは、蒸し処理米を乾燥して得られる乾燥米のことである。米の蒸し処理の方法として、米を蒸すこと、米を蒸し焼きにすること、米に加熱水蒸気を当てること等が挙げられる。このような蒸し処理によって得られる蒸し処理米としては、蒸し米、蒸し焼き米、加熱水蒸気処理米等が挙げられ、蒸し処理米の乾燥品としては、蒸し米の乾燥品、蒸し焼き米の乾燥品、加熱水蒸気処理米の乾燥品等が挙げられる。
 なお、明細書において、わかりやすく説明するために、低蛋白質米について、蛋白質分解処理及び洗浄処理した米を油で揚げることにより糊化したものを「低蛋白質揚げ米」、蛋白質分解処理及び洗浄処理した米を蒸し処理することにより糊化したものを「低蛋白質蒸し処理米」、低蛋白質蒸し処理米を乾燥したものを「低蛋白質蒸し処理米の乾燥品」、蛋白質分解処理及び洗浄処理した米を蒸すことにより糊化したものを「低蛋白質蒸し米」、低蛋白質蒸し米を乾燥したものを「低蛋白質蒸し米の乾燥品」、蛋白質分解処理及び洗浄処理した米を蒸し焼きすることにより糊化したものを「低蛋白質蒸し焼き米」、低蛋白質蒸し焼き米を乾燥したものを「低蛋白質蒸し焼き米の乾燥品」、蛋白質分解処理及び洗浄処理した米に加熱水蒸気を当てることにより糊化したものを「低蛋白質加熱水蒸気処理米」、低蛋白質加熱水蒸気処理米を乾燥したものを「低蛋白質加熱水蒸気処理米の乾燥品」、蛋白質分解処理及び洗浄処理した米をレトルト処理することにより糊化したものを「低蛋白質レトルト処理米」と言うことがある。
 本発明における低蛋白質米としては、蛋白質含量が0.1~4質量%であることが好ましく、0.1~2質量%がより好ましく、0.1~1質量%がさらに好ましい。
 本発明の1つの側面の低蛋白質米の製造方法は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米へ油を付着させること、及び油が付着した米を糊化することを含む、低蛋白質米の製造方法である。
The low protein rice in the present invention is rice that has undergone proteolytic treatment, washing treatment, and gelatinization treatment, and has a protein content less than that of raw rice. Examples of the form include fried rice, steamed rice, dried products thereof, and retort-treated rice.
Here, the steamed rice is rice obtained by steaming the rice, and the steamed rice dry product is dry rice obtained by drying the steamed rice. Examples of methods for steaming rice include steaming rice, steaming rice, and applying heated steam to the rice. Steamed rice obtained by such steaming treatment includes steamed rice, steamed baked rice, heated steamed rice, etc., and as steamed rice dried products, steamed rice dried products, steamed baked rice dried products, Examples include dried products of heat steamed rice.
In addition, in the specification, for easy understanding, low protein rice, which has been gelatinized by frying rice that has been subjected to proteolytic treatment and washing treatment with oil, is referred to as “low protein fried rice”, proteolysis treatment and washing treatment. The rice that has been gelatinized by steaming the processed rice is "low-protein steamed rice", the dried low-protein steamed rice is "dried low-protein steamed rice", rice that has been proteolytically processed and washed Steamed rice is "low protein steamed rice", dried low protein steamed rice is "low protein steamed rice dry product", gelatinized by steaming and baking rice that has been proteolytically treated and washed The low-protein steamed and baked rice is dried, and the low-protein steamed and baked rice is dried and the low-protein steamed and baked rice is dried. The low-protein heated steam-treated rice is gelatinized and the low-protein heated steam-treated rice is dried. The dried low-protein steamed rice is retorted. What was gelatinized by processing may be called "low protein retort processing rice".
The low protein rice in the present invention preferably has a protein content of 0.1 to 4% by mass, more preferably 0.1 to 2% by mass, and even more preferably 0.1 to 1% by mass.
The method for producing low protein rice according to one aspect of the present invention comprises subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, and gelatinizing the rice to which the oil has adhered. A method for producing low protein rice.
 本発明において、生米の種類は特に限定されるものではなく、インディカ米、ジャポニカ米等を使用することができる。特に、本発明は、蛋白質分解処理後に米粒が崩壊しやすいインディカ米に対し効果を発揮することができる。 In the present invention, the type of raw rice is not particularly limited, and indica rice, japonica rice and the like can be used. In particular, the present invention can exert an effect on Indica rice in which rice grains are likely to disintegrate after proteolytic treatment.
 本発明における蛋白質分解処理とは、米中の蛋白質を分解することである。
 本発明において、蛋白質分解処理は、特に限定されるものではなく、蛋白質分解酵素による蛋白質分解処理や乳酸菌による発酵処理等、公知の方法を使用することができる。
The proteolytic treatment in the present invention is to decompose proteins in rice.
In the present invention, the proteolytic treatment is not particularly limited, and known methods such as proteolytic treatment with a proteolytic enzyme and fermentation treatment with lactic acid bacteria can be used.
 蛋白質分解酵素は、市販のものを使用することができ、例えば、プロテアーゼM(天野エンザイム(株)製)を使用することができる。 A commercially available proteolytic enzyme can be used, for example, protease M (manufactured by Amano Enzyme Co., Ltd.) can be used.
 酵素による蛋白質分解反応は、pH3~6の溶液で行うのが好ましく、pH4~5の溶液で行うのがより好ましい。かかる溶液として、酢酸緩衝液やクエン酸緩衝液等の緩衝液を用いることができるが、これらに限定されない。 The proteolytic reaction by the enzyme is preferably performed with a solution having a pH of 3 to 6, more preferably with a solution having a pH of 4 to 5. As such a solution, a buffer solution such as an acetate buffer solution or a citrate buffer solution can be used, but is not limited thereto.
 蛋白質分解処理をする反応液は、前記pHの溶液に蛋白質分解酵素を添加することにより調製することができ、反応液中の蛋白質分解酵素の含量は、好ましくは0.01~2質量%、より好ましくは0.1~1質量%、最も好ましくは0.3~0.7質量%である。 The reaction solution for proteolytic treatment can be prepared by adding a proteolytic enzyme to the solution having the above pH, and the content of the proteolytic enzyme in the reaction solution is preferably 0.01 to 2% by mass. The content is preferably 0.1 to 1% by mass, and most preferably 0.3 to 0.7% by mass.
 蛋白質分解処理をする反応液の量は、原料の生米の質量の1.5~10倍量の質量であることが好ましく、3~7倍量の質量であることがより好ましく、4~6倍量の質量であることが最も好ましい。 The amount of the reaction solution for proteolytic treatment is preferably 1.5 to 10 times the mass of the raw rice raw material, more preferably 3 to 7 times the mass, and 4 to 6 is preferred. Most preferably it is double the mass.
 前記蛋白質分解処理としては、20℃~60℃で、2時間~50時間、生米を前記反応液に浸漬させることが好ましく、30℃~50℃で10時間~40時間、生米を前記反応液に浸漬させることがより好ましく、40℃~45℃で15時間~30時間、生米を前記反応液に浸漬させることが特に好ましい。 As the proteolytic treatment, it is preferable to immerse raw rice in the reaction solution at 20 ° C. to 60 ° C. for 2 hours to 50 hours, and to react the raw rice at 30 ° C. to 50 ° C. for 10 hours to 40 hours. It is more preferable to immerse in the liquid, and it is particularly preferable to immerse the raw rice in the reaction liquid at 40 to 45 ° C. for 15 to 30 hours.
 原料の生米に対して上記蛋白質分解処理を行うことで、米中の蛋白質含量を0.1~2g/100g、好ましくは0.1~1g/100gに調整することができる。したがって、蛋白質含量を、原料の生米中の蛋白質含量の1/10~1/30程度に減少させた低蛋白質米を製造することができる。米中の蛋白質含量は、ケルダール法で測定することができる。 By performing the above-mentioned proteolytic treatment on raw raw rice, the protein content in the rice can be adjusted to 0.1 to 2 g / 100 g, preferably 0.1 to 1 g / 100 g. Therefore, it is possible to produce low protein rice in which the protein content is reduced to about 1/10 to 1/30 of the protein content in raw raw rice. The protein content in rice can be measured by the Kjeldahl method.
 本発明において、蛋白質分解処理をする際、反応液に乳化剤を添加してもよい。乳化剤を添加することにより、米からのデンプンの流出を抑えることができると考えられる。
 乳化剤としては、一般的に用いられるものであれば特に限定されるものではないが、例えば、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、レシチン等が挙げられ、レシチンが好ましい。
In the present invention, an emulsifier may be added to the reaction solution when proteolytic treatment is performed. It is thought that the outflow of starch from rice can be suppressed by adding an emulsifier.
The emulsifier is not particularly limited as long as it is generally used, and examples thereof include glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, and lecithin, and lecithin is preferable.
 蛋白質分解処理後、米を洗浄することが好ましい。洗浄により、米から蛋白質分解物を除去することができる。洗浄時に米粒の形状をより維持させておくために、洗浄水には、先に説明をした緩衝液、又は緩衝液として汎用する塩の水溶液を用いることが好ましい。 It is preferable to wash the rice after the proteolytic treatment. By washing, protein degradation products can be removed from the rice. In order to maintain the shape of the rice grains at the time of washing, it is preferable to use the buffer solution described above or an aqueous salt solution generally used as the buffer solution for washing water.
 処理米を洗浄後、金ザル等で米を水切りすることが好ましい。水切りの時間は、10分間~60分間が好ましい。 It is preferable to drain the rice with a gold colander after washing the treated rice. The draining time is preferably 10 minutes to 60 minutes.
 前記米へ油を付着させることは、油に米を浸漬させること、油を含有する油含有浸漬水に米を浸漬させること、油含有乳化液浸漬液に米を浸漬させること、及び米に油を塗布した後に水で洗浄することからなる群より選ばれる少なくとも1の工程であることが好ましい。 The attaching of oil to the rice includes immersing rice in oil, immersing rice in oil-containing immersion water containing oil, immersing rice in oil-containing emulsion immersion liquid, and oil in rice It is preferably at least one step selected from the group consisting of washing with water after coating.
 前記油に米を浸漬させることにおいて使用する油は、浸漬時に液体状態の油であれば良く、植物油や動物油を使用することができ、具体的には、大豆油、菜種油、コーン油、麺実油、紅花油、オリーブ油、米油、パーム油、パーム分別油、これらの油の水添油、前記何れかの油のエステル交換油等から選ばれる1種又は2種以上を使用することができ、これらの中でも、菜種油、大豆油が好ましい。例えば、融点50℃のパーム水添油や融点26℃のヤシ油を使用する場合は、25℃では固体なので、使用する油が液体状態となる温度で浸漬処理を行うことが好ましい。例えば、パーム水添油を使用する場合は50~90℃、ヤシ油を使用する場合は26~90℃で浸漬処理を行うことが好ましい。
 前記油に米を浸漬させることにおける浸漬する油の温度及び浸漬の時間は、5~90℃で5秒間~60分間であることが好ましく、5~80℃で5秒間~30分間がより好ましく、10~70℃で5秒間~30分間がさらに好ましい。
The oil used in immersing rice in the oil may be any oil that is in a liquid state at the time of immersion, and vegetable oil and animal oil can be used. Specifically, soybean oil, rapeseed oil, corn oil, noodles One or more selected from oil, safflower oil, olive oil, rice oil, palm oil, palm fractionated oil, hydrogenated oil of these oils, transesterified oil of any of the above oils, etc. can be used. Of these, rapeseed oil and soybean oil are preferred. For example, when using a palm hydrogenated oil having a melting point of 50 ° C. or a palm oil having a melting point of 26 ° C., it is solid at 25 ° C. Therefore, it is preferable to perform the dipping treatment at a temperature at which the oil used is in a liquid state. For example, the immersion treatment is preferably performed at 50 to 90 ° C. when palm hydrogenated oil is used, and at 26 to 90 ° C. when palm oil is used.
The temperature of the soaking oil and the soaking time in soaking rice in the oil is preferably 5 to 90 ° C. for 5 seconds to 60 minutes, more preferably 5 to 80 ° C. for 5 seconds to 30 minutes, More preferably, the temperature is 10 to 70 ° C. for 5 seconds to 30 minutes.
 油への浸漬処理は、米に付着した水のほとんどが除去できる条件であれば良く、具体的には5秒間以上の浸漬を1回以上行うのが好ましく、10秒間~24時間の浸漬を1回以上行うのがより好ましく、2回~10回行うのがさらにより好ましい。比較的短い製造時間で効率よく水を除去したい場合、例えば、浸漬させるお米に物理的な振動を与えながら5秒間~10分間の浸漬を1回~10回行うことが好ましい。また、製造の作業効率を高めるために、人が作業をしない時間帯、具体的には、蛋白質分解処理後1晩~1日間(16~24時間)、油への浸漬を1回行ってもよい。 The dipping treatment in oil may be performed under the condition that most of the water adhering to the rice can be removed. Specifically, the dipping for 5 seconds or more is preferably performed once or more, and the dipping for 10 seconds to 24 hours is 1 More preferably, it is more than once, more preferably 2 to 10 times. When it is desired to efficiently remove water in a relatively short production time, for example, it is preferable to perform immersion for 1 to 10 times for 5 seconds to 10 minutes while applying physical vibration to the rice to be immersed. Further, in order to increase the work efficiency of the production, even when the human is not working, specifically, for one night to one day (16 to 24 hours) after the proteolytic treatment, the oil may be immersed once. Good.
 前記油含有浸漬水は、油及び水を含む。油含有浸漬水に含まれる油としては前述のものが挙げられ、菜種油、大豆油が好ましい。
 前記油含有浸漬水における油の量としては、原料の生米1gに対して、0.17ml以上が好ましく、0.17~2.5mlがより好ましく、0.18~1.5mlがさらに好ましく、0.18~1mlが特に好ましく、0.18~0.7mlが最も好ましい。
 前記油含有浸漬水における油の含量は、原料の生米1gに対する油の量が上記範囲内であれば特に限定されないが、前記油含有浸漬水中、4~50%(vol./vol.)が好ましく、4~30%(vol./vol.)がより好ましく、4~20%(vol./vol.)がさらに好ましく、4~10%(vol./vol.)が特に好ましい。
 前記油含有浸漬水における水の含量は、原料の生米1gに対する油の量が上記範囲内であれば特に限定されないが、前記油含有浸漬水中、50~96%(vol./vol.)が好ましく、70~96%(vol./vol.)がより好ましく、80~96%(vol./vol.)さらに好ましく、90~96%(vol./vol.)が特に好ましい。
 生米100質量部に対する前記油含有浸漬水の量は、原料の生米1gに対する油の量が上記範囲内であれば特に限定されないが、生米100質量部に対し、100~1000質量部が好ましく、200~800質量部がより好ましく、300~700質量部がさらに好ましく、400~600質量部が特に好ましい。
The oil-containing immersion water includes oil and water. Examples of the oil contained in the oil-containing immersion water include those described above, and rapeseed oil and soybean oil are preferred.
The amount of oil in the oil-containing immersion water is preferably 0.17 ml or more, more preferably 0.17 to 2.5 ml, further preferably 0.18 to 1.5 ml, with respect to 1 g of raw raw rice. 0.18 to 1 ml is particularly preferred, and 0.18 to 0.7 ml is most preferred.
The oil content in the oil-containing immersion water is not particularly limited as long as the amount of oil relative to 1 g of raw raw rice is within the above range, but the oil-containing immersion water is 4 to 50% (vol./vol.). Preferably, 4 to 30% (vol./vol.) Is more preferable, 4 to 20% (vol./vol.) Is more preferable, and 4 to 10% (vol./vol.) Is particularly preferable.
The water content in the oil-containing immersion water is not particularly limited as long as the amount of oil relative to 1 g of raw raw rice is within the above range, but 50 to 96% (vol./vol.) In the oil-containing immersion water is It is preferably 70 to 96% (vol./vol.), More preferably 80 to 96% (vol./vol.), And particularly preferably 90 to 96% (vol./vol.).
The amount of the oil-containing immersion water with respect to 100 parts by mass of raw rice is not particularly limited as long as the amount of oil with respect to 1 g of raw rice is within the above range, but is 100 to 1000 parts by mass with respect to 100 parts by mass of raw rice. It is preferably 200 to 800 parts by mass, more preferably 300 to 700 parts by mass, and particularly preferably 400 to 600 parts by mass.
 前記油含有浸漬水に米を浸漬させることにおける、油含有浸漬水の温度及び浸漬の時間は、5~90℃で5秒間~60分間であることが好ましく、5~80℃で5秒間~30分間がより好ましく、10~70℃で5秒間~30分間がさらに好ましい。 In immersing the rice in the oil-containing immersion water, the temperature and the immersion time of the oil-containing immersion water are preferably 5 to 90 ° C. for 5 seconds to 60 minutes, and 5 to 80 ° C. for 5 seconds to 30 minutes. More preferably, the time is more preferably 10 to 70 ° C. for 5 seconds to 30 minutes.
 油含有浸漬水に米を浸漬させる方法としては、米が入った金ザルを、油含有浸漬水を入れた容器に入れて、米を油含有浸漬水に浸漬させる方法が挙げられる。
 金ザルとしては、ステンレスザルを使用することができ、また、その形は特に限定されず、丸型であっても、角型であっても良い。
 使用する金ザルの大きさは、低蛋白質米の製造スケールによって異なってくるが、金ザルに原料生米を入れたときに、原料生米が金ザルの容積の1~80%を占めるような大きさのものを使用することが好ましく、10~70%を占めるような大きさのものを使用することがより好ましい。使用する金ザルの大きさは、上記の範囲以外の大きさのものも使用できるが、浸漬作業の効率の点から、上記範囲の大きさが好ましい。
 具体的には、生米の重量が15~25g程度の場合、直径50~60mm、深さ35~45mmのステンレス丸型ザルを使用することができる。また、生米の重量が150~350g程度の場合、直径150~180mm、深さ65~75mmのステンレス丸型ザルを使用することができる。また、生米の重量が1000~2000g程度の場合、縦220~260mm、横300~350mm、高さ70~90mmのステンレス角型ザルを使用することができる。
 また、油含有浸漬水を入れる容器は、プラスチック製容器、ステンレス製容器等各種素材のものを使用することができ、また、その形は特に限定されず、丸型であっても、角型であっても良いが、ザルと同じ型のものを使用すると効率が良い。
 使用する容器の大きさは、低蛋白質米の製造スケールによって異なってくるが、容器に入れる金ザルの容積の1.05~3倍の容積のものが好ましく、1.1~2倍の容積のものがより好ましい。使用する容器の大きさは、上記の範囲以外の大きさのものも使用できるが、浸漬作業の効率の点から、上記範囲の大きさが好ましい。
 具体的には、直径50~60mm、深さ30~40mmのステンレス丸型ザルを使用する場合、直径55~65mm、深さ35~45mmのプラスチック丸型容器を使用することができる。また、直径150~180mm、深さ65~75mmのステンレス丸型ザルを使用する場合、直径160~200mm、深さ70~90mmのステンレス丸型容器を使用することができる。また、縦260~280mm、横340~360mm、高さ80~110mmのステンレス角型ザルを使用する場合、縦300~360mm、横400~500mm、高さ120~160mmのプラスチック角型容器を使用することができる。
Examples of the method for immersing rice in oil-containing immersion water include a method in which a gold monkey containing rice is placed in a container containing oil-containing immersion water, and the rice is immersed in oil-containing immersion water.
As the gold colander, a stainless colander can be used, and its shape is not particularly limited, and may be round or square.
The size of the gold monkey used varies depending on the production scale of low protein rice, but when raw raw rice is added to the gold monkey, the raw raw rice occupies 1 to 80% of the volume of the gold monkey. It is preferable to use a large size, and it is more preferable to use a size that occupies 10 to 70%. The size of the gold monkey to be used can be other than the above range, but the above range is preferable from the viewpoint of the efficiency of the dipping operation.
Specifically, when the weight of raw rice is about 15 to 25 g, a stainless round colander having a diameter of 50 to 60 mm and a depth of 35 to 45 mm can be used. Further, when the weight of raw rice is about 150 to 350 g, a stainless round colander having a diameter of 150 to 180 mm and a depth of 65 to 75 mm can be used. When the weight of raw rice is about 1000 to 2000 g, a stainless square monkey having a length of 220 to 260 mm, a width of 300 to 350 mm, and a height of 70 to 90 mm can be used.
In addition, the container containing the oil-containing immersion water can be made of various materials such as a plastic container and a stainless steel container, and the shape thereof is not particularly limited. It may be, but it is efficient to use the same type as the monkey.
The size of the container to be used varies depending on the production scale of the low protein rice, but it is preferably 1.05 to 3 times the volume of the gold monkey to be put in the container, and 1.1 to 2 times the volume. More preferred. Although the thing of the magnitude | size outside the said range can also be used for the magnitude | size of the container to be used, the magnitude | size of the said range is preferable from the point of the efficiency of immersion work.
Specifically, when a stainless round colander having a diameter of 50 to 60 mm and a depth of 30 to 40 mm is used, a plastic round container having a diameter of 55 to 65 mm and a depth of 35 to 45 mm can be used. When a stainless round colander having a diameter of 150 to 180 mm and a depth of 65 to 75 mm is used, a stainless round container having a diameter of 160 to 200 mm and a depth of 70 to 90 mm can be used. In addition, when using a stainless steel square colander with a length of 260 to 280 mm, a width of 340 to 360 mm, and a height of 80 to 110 mm, use a plastic square container with a length of 300 to 360 mm, a width of 400 to 500 mm, and a height of 120 to 160 mm. be able to.
 前記油含有乳化液浸漬液は、水、油及び乳化剤を含む。前記油含有乳化液浸漬液に含まれる油としては前述のものが挙げられ、菜種油が好ましい。前記乳化剤としては、例えば、レシチン、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル等が挙げられ、これらから選択される少なくとも1の乳化剤が好ましく、レシチンがより好ましい。
 前記油含有乳化液浸漬液中の油の含量は、1~50質量%が好ましく、2~30質量%がより好ましく、3~20質量%がさらに好ましい。
 前記油含有乳化液浸漬液中の乳化剤の含量は、0.01~10質量%が好ましく、0.02~5質量%がより好ましく、0.03~5質量%がさらに好ましい。
 前記油含有乳化液浸漬液中の水の含量は、40~98.99質量%が好ましく、65~97.98質量%がより好ましく、77~96.97質量%がさらに好ましい。
 生米100質量部に対する前記油含有乳化液浸漬液の量は、100~1000質量部が好ましく、150~500質量部がより好ましく、150~300質量部がさらに好ましい。
The oil-containing emulsion immersion liquid contains water, oil, and an emulsifier. Examples of the oil contained in the oil-containing emulsion immersion liquid include those described above, and rapeseed oil is preferred. Examples of the emulsifier include lecithin, glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, and the like. At least one emulsifier selected from these is preferable, and lecithin is more preferable.
The oil content in the oil-containing emulsion immersion liquid is preferably 1 to 50% by mass, more preferably 2 to 30% by mass, and even more preferably 3 to 20% by mass.
The content of the emulsifier in the oil-containing emulsion immersion liquid is preferably 0.01 to 10% by mass, more preferably 0.02 to 5% by mass, and further preferably 0.03 to 5% by mass.
The water content in the oil-containing emulsion immersion liquid is preferably 40 to 99.99% by mass, more preferably 65 to 97.98% by mass, and even more preferably 77 to 96.97% by mass.
The amount of the oil-containing emulsion immersion liquid to 100 parts by mass of raw rice is preferably 100 to 1000 parts by mass, more preferably 150 to 500 parts by mass, and even more preferably 150 to 300 parts by mass.
 前記油含有乳化液浸漬液に米を浸漬させることにおける、油含有乳化液浸漬液の温度及び浸漬の時間は、5~50℃で1~60分間であることが好ましく、5~40℃で1~30分間がより好ましく、10~40℃で1~30分間がさらに好ましい。 The temperature of the oil-containing emulsion immersion liquid and the immersion time in immersing rice in the oil-containing emulsion immersion liquid are preferably 5 to 50 ° C. for 1 to 60 minutes, and 1 to 5 to 40 ° C. for 1 hour. More preferred is ˜30 minutes, and further more preferred is 10 to 40 ° C. for 1 to 30 minutes.
 米に油を塗布する方法としては、米に油を噴霧する(すなわちスプレーする)方法が好ましい。また、米に油を塗布した後は、米を水で洗浄することが好ましい。
 米を洗浄する際の水の温度及び時間は、5~90℃で5秒間~60分間であることが好ましく、5~80℃で5秒間~30分間がより好ましく、10~70℃で5秒間~30分間がさらに好ましい。
As a method of applying oil to rice, a method of spraying (that is, spraying) oil on rice is preferable. Moreover, after apply | coating oil to rice, it is preferable to wash | clean rice with water.
The temperature and time of washing the rice is preferably 5 to 90 ° C. for 5 seconds to 60 minutes, more preferably 5 to 80 ° C. for 5 seconds to 30 minutes, and more preferably 10 to 70 ° C. for 5 seconds. More preferred is ˜30 minutes.
 本発明の別の側面の低蛋白質米の製造方法は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米へ油を付着させること、及び米を糊化することを含む、低蛋白質米の製造方法であって、前記米を糊化することが、米を油で揚げること、米を蒸し処理すること、及び米をレトルト処理することからなる群より選ばれる少なくとも1の工程であることが好ましい。
 前記米を蒸し処理する方法としては、米を蒸すこと、米を蒸し焼きにすること、米に加熱水蒸気を当てること等が挙げられる。
 ここで、糊化とは、水が共存した状態での加熱により澱粉が糊状になることをいう。
The method for producing low protein rice according to another aspect of the present invention includes subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, and gelatinizing the rice. And a method for producing low protein rice, wherein the gelatinization of the rice comprises at least one selected from the group consisting of frying rice with oil, steaming the rice, and retorting the rice. It is preferable that it is a process.
Examples of the method for steaming the rice include steaming the rice, steaming the rice, and applying heated steam to the rice.
Here, gelatinization means that starch becomes pasty by heating in a state where water coexists.
 米を蒸す方法としては、沸騰水と米を入れた容器を常用の蒸し器に入れて蒸すこと等が挙げられる。米を蒸す時間は、1~120分間が好ましく、5~60分間がより好ましく、5~30分間がさらに好ましい。 As a method of steaming rice, a container containing boiling water and rice is put in a regular steamer and steamed. The time for steaming the rice is preferably 1 to 120 minutes, more preferably 5 to 60 minutes, and even more preferably 5 to 30 minutes.
 米を蒸し焼きにする方法としては、スチームオーブンを使用する方法等が挙げられる。
 米を蒸し焼きにする際の温度及び時間は、100~180℃で3~30分間が好ましく、100~160℃で3~30分間がより好ましく、100~140℃で3~30分間がさらに好ましい。
Examples of the method for steaming the rice include a method using a steam oven.
The temperature and time for steaming the rice is preferably 100 to 180 ° C. for 3 to 30 minutes, more preferably 100 to 160 ° C. for 3 to 30 minutes, and even more preferably 100 to 140 ° C. for 3 to 30 minutes.
 米に加熱水蒸気を当てる方法としては、米に加熱水蒸気を吹きかけて蒸すこと等が挙げられる。米に加熱水蒸気を当てることにおける水蒸気の温度及び水蒸気を当てる時間は100~500℃で1秒間~60分間が好ましく、150~450℃で1秒間~30分間がより好ましく、200~400℃で1秒間~15分間がさらに好ましい。 As a method of applying heated steam to the rice, steaming by spraying heated steam on the rice can be mentioned. The temperature of the water vapor and the time for which the water vapor is applied to the rice is preferably 100 to 500 ° C. for 1 second to 60 minutes, more preferably 150 to 450 ° C. for 1 second to 30 minutes, and 200 to 400 ° C. for 1 hour. More preferably, the second to 15 minutes.
 本発明における米のレトルト処理とは、米を炊飯後包装すること、米を包装後に加熱する、又は米を包装後に加圧及び加熱することである。 The retort treatment of rice in the present invention is to wrap rice after cooking, to heat the rice after packaging, or to pressurize and heat the rice after packaging.
 本発明の別の側面の低蛋白質米の製造方法は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米に油を付着させること、油が付着した米を糊化させること、及び糊化した米を乾燥させることを含む。この場合、前記米を糊化することが、米を蒸すこと、米を蒸し焼きにすること、米に加熱水蒸気を当てること、及び米をレトルト処理することからなる群より選ばれる少なくとも1つの工程であることが好ましい。 According to another aspect of the present invention, there is provided a method for producing low protein rice, comprising subjecting raw rice to proteolytic treatment, washing the resulting treated rice, and then attaching oil to the rice, or gelatinizing the rice to which the oil has adhered. And drying the gelatinized rice. In this case, the gelatinization of the rice is at least one step selected from the group consisting of steaming the rice, steaming the rice, applying heated steam to the rice, and retorting the rice. Preferably there is.
 本発明の別の側面の低蛋白質米の製造方法は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米に油を付着させること、及び油が付着した米を糊化させることを含む。この場合、前記米に油を付着させること及び油が付着した米を糊化させることを、油で揚げることにより行うことが好ましい。これは、本発明の第一の態様の低蛋白質米の製造方法、すなわち、生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げることを特徴とする、低蛋白質米、すなわち低蛋白質揚げ米、の製造方法である。
 米を油で揚げるという1つの処理で、米に油を付着させ、また、油が付着した米を糊化するという2つのことを行うことができる。そして、米を油で揚げた場合、米の中の水分含量が減少するため、その後さらに、米を乾燥しなくても良い。
 使用する油としては、通常揚げ処理に使用される植物油や動物油を使用することができ、具体的には、大豆油、菜種油、コーン油、麺実油、紅花油、オリーブ油、米油、パーム油、パーム分別油、牛脂、豚脂、これらの油の水添油、前記何れかの油のエステル交換油等から選ばれる1種又は2種以上を使用することができ、これらの中でも、菜種油、大豆油が好ましい。
The method for producing low protein rice according to another aspect of the present invention comprises subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, and gelatinizing the rice to which the oil has adhered Including. In this case, it is preferable that oil is attached to the rice and the rice to which the oil is attached is gelatinized by frying. This is a method for producing low-protein rice according to the first aspect of the present invention, that is, low-protein rice characterized by subjecting raw rice to proteolytic treatment, washing the resulting treated rice, and then frying it with oil. That is, a method for producing low protein fried rice.
In one process of frying rice with oil, two things can be done: attaching the oil to the rice and gelatinizing the rice with the oil attached. And when rice is fried with oil, since the moisture content in rice decreases, it is not necessary to dry rice after that.
As the oil to be used, vegetable oils and animal oils usually used for frying can be used. Specifically, soybean oil, rapeseed oil, corn oil, noodle seed oil, safflower oil, olive oil, rice oil, palm oil 1 or 2 kinds selected from palm fractionated oil, beef tallow, lard, hydrogenated oil of these oils, transesterified oil of any of the above oils, among these, rapeseed oil, Soybean oil is preferred.
 米を揚げる時の油の温度及び揚げ時間の条件は、米の水分を減少させ、かつ、米が焦げない条件であれば良い。具体的には、100℃以上150℃未満の低温揚げ処理の場合、60~600秒間揚げるのが好ましく、60~420秒間揚げるのがより好ましく、60~300秒間揚げるのがさらに好ましく、70~250秒間揚げるのが特に好ましく、80~250秒間揚げるのが最も好ましい。
 また、150℃以上185℃以下の高温揚げ処理では、20~50秒間揚げるのが好ましく、20~40秒間揚げるのがより好ましく、25~35秒間揚げるのが最も好ましい。
The conditions of the temperature and frying time of the oil when frying rice may be any conditions that reduce the moisture of the rice and do not burn the rice. Specifically, in the case of a low-temperature frying treatment at 100 ° C. or more and less than 150 ° C., it is preferably fried for 60 to 600 seconds, more preferably 60 to 420 seconds, even more preferably 60 to 300 seconds, and 70 to 250 It is particularly preferred to fry for a second, most preferably fried for 80 to 250 seconds.
Further, in the high-temperature frying treatment at 150 ° C. or higher and 185 ° C. or lower, it is preferably fried for 20 to 50 seconds, more preferably fried for 20 to 40 seconds, and most preferably fried for 25 to 35 seconds.
 また、低温揚げ処理、及び高温揚げ処理の両方を行っても良い。低温揚げ処理と高温揚げ処理の両方を行う場合は、どちらを先に行ってもよいが、最初に低温揚げ処理をすることが好ましい。 Also, both low temperature frying processing and high temperature frying processing may be performed. When both the low-temperature fried treatment and the high-temperature fried treatment are performed, whichever may be performed first, it is preferable to perform the low-temperature fried treatment first.
 このように、蛋白質分解処理した生米を揚げ処理することで、米の水分含量を、3~15質量%、好ましくは3~10質量%に減らすことができる。米の保存性や衛生性の観点から、米の水分含量を3~10質量%に減少させることが好ましい。 As described above, by frying the proteolytically treated raw rice, the water content of the rice can be reduced to 3 to 15% by mass, preferably 3 to 10% by mass. From the viewpoint of rice storage stability and hygiene, it is preferable to reduce the water content of rice to 3 to 10% by mass.
 上記のようにして得られる低蛋白質揚げ米は、一度に多量の米を揚げて製造する場合、揚げ処理後に、米同士が付着してしまう傾向にある。揚げ処理後に米同士が付着したお米であっても、その後、炊飯や蒸し調理により米はばらばらになるため、味にはまったく問題なく使用することができる。
 揚げ処理後に、米同士の付着のない、ばらばらの状態の低蛋白質揚げ米を得たい場合には、洗浄した米に付着した水分を除去することが好ましい。洗浄した米に付着した水分を除去する方法としては、例えば、酵素処理した米を洗浄後、油で揚げる前に、ウエス等で、米に付着した水分を除去するという方法が挙げられる。効率的に米に付着した水分を除去するためには、酵素処理した米を洗浄後、油で揚げる前に、米を90℃以下の油、好ましくは5~75℃の油、より好ましくは15~65℃の油、最も好ましくは25~45℃の油に浸漬して水を除去することが好ましい。
When the low protein fried rice obtained as described above is produced by frying a large amount of rice at a time, the rice tends to adhere to each other after the frying process. Even if the rice adheres to each other after the frying process, the rice is then separated by cooking or steaming, so that it can be used without any problem in taste.
When it is desired to obtain a low-protein fried rice in a loose state with no adhesion between rice after the frying treatment, it is preferable to remove the water adhering to the washed rice. Examples of a method for removing water adhering to the washed rice include a method of removing water adhering to the rice with a waste cloth after washing the enzyme-treated rice and before frying it with oil. In order to efficiently remove the water adhering to the rice, after washing the enzyme-treated rice and before frying it with oil, the rice is oil of 90 ° C. or less, preferably 5 to 75 ° C., more preferably 15 It is preferred to remove the water by immersing in an oil at ˜65 ° C., most preferably at 25 ° -45 ° C.
 本発明の別の側面の低蛋白質米の製造方法は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米へ油を付着させること、及び米を糊化することを含む。そして、前記米へ油を付着させることが、油に米を浸漬させること、油を含有する油含有浸漬水に米を浸漬させること、油含有乳化液浸漬液に米を浸漬させること、及び米に油を塗布した後に水で洗浄することからなる群より選ばれる少なくとも1つの工程であり、前記米を糊化することの後に、さらに、米を乾燥させることを含むことが好ましい。
 米を乾燥させる方法としては、棚式乾燥機、平型乾燥機、コンベア式乾燥機、ドラム式乾燥機などを用いた方法が挙げられ、棚式乾燥機を用いた方法が好ましい。
 米を乾燥させる時の温度及び時間は、20~90℃で0.1~8時間が好ましく、40~90℃で0.5~6時間がより好ましく、60~80℃で1~4時間がさらに好ましい。
 ただし、レトルト処理により米を糊化させる場合、レトルト食品は通常の場合、商品として乾燥品よりも水分を多く含むものであることから、レトルト処理後は米の乾燥を行わなくてもよい。
The method for producing low protein rice according to another aspect of the present invention includes subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, and gelatinizing the rice. . And attaching oil to the rice, immersing rice in oil, immersing rice in oil-containing immersion water containing oil, immersing rice in oil-containing emulsion immersion liquid, and rice It is at least one step selected from the group consisting of washing with water after applying oil to the paste, and preferably further comprising drying the rice after gelatinizing the rice.
Examples of the method for drying rice include a method using a shelf dryer, a flat dryer, a conveyor dryer, a drum dryer, and the like, and a method using a shelf dryer is preferable.
The temperature and time for drying rice is preferably 20 to 90 ° C. for 0.1 to 8 hours, 40 to 90 ° C. for 0.5 to 6 hours, more preferably 60 to 80 ° C. for 1 to 4 hours. Further preferred.
However, when the rice is gelatinized by retort treatment, since the retort food usually contains more water than the dried product as a product, the rice does not need to be dried after the retort treatment.
 また、このように、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米へ油を付着させ、米を蒸し処理した後に、米を乾燥させることを含む本発明の低蛋白質米の製造方法により製造された低蛋白質蒸し処理米の乾燥品や、生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げるという本発明の低蛋白質米の製造方法により製造された低蛋白質揚げ米は、低蛋白質米が固化し、米の崩壊を防止することができる。その結果、低蛋白質米を、レトルトパックされた米ではなく、生米と同じように流通させることができる。同じ量の米であっても、水分を多く含むレトルトパックされた低蛋白質米に比べて容量及び重量が小さくなることから、物流面で有利となる。
 また、本発明の製造方法で得られた低蛋白質揚げ米、及び低蛋白質蒸し処理米の乾燥品は、生米と同じような形態であるから、レトルトパックされた米と違って米の使用量を自由に調整することができ、使いやすく、種々の料理に広く使用することができる。
In addition, the low protein of the present invention comprising subjecting raw rice to proteolytic treatment, washing the resulting treated rice, attaching oil to the rice, steaming the rice, and then drying the rice According to the method for producing low protein rice of the present invention, the dried product of low protein steamed rice produced by the rice production method or the proteolytic treatment of raw rice, washing the resulting treated rice, and then frying in oil The produced low protein fried rice can solidify the low protein rice and prevent the rice from collapsing. As a result, low protein rice can be distributed in the same way as raw rice, not retort packed rice. Even the same amount of rice is advantageous in terms of physical distribution because it has a smaller capacity and weight than retort packed low protein rice containing a lot of water.
Further, the low protein fried rice obtained by the production method of the present invention and the dried product of the low protein steamed rice have the same form as raw rice, so the amount of rice used is different from that of retort packed rice. Can be adjusted freely, is easy to use, and can be widely used in various dishes.
 本発明の製造方法によれば、味にコクがあり、かつエネルギーが高い低蛋白質米を製造することができる。蛋白質含量を低減していない通常の米と比較して、米のエネルギーが高いので、腎臓病患者が、本発明の製造方法で得られた低蛋白質米を摂取することで、摂取エネルギーの低下を防止することができる。 According to the production method of the present invention, low protein rice having a rich taste and high energy can be produced. Compared with normal rice that does not reduce protein content, the energy of rice is higher, so patients with kidney disease can reduce the intake energy by ingesting the low protein rice obtained by the production method of the present invention. Can be prevented.
 本発明の低蛋白質揚げ米、及び低蛋白質蒸し処理米の乾燥品は、流通時及び炊飯時に米粒が崩壊しにくく、コクがあり、かつエネルギーが高いという特徴が挙げられる。
 酵素処理した米を洗浄後、油で揚げる前に、米を90℃以下の油に浸漬して水を除去すれば、製造時又は炊飯等の調理時に米の米同士の付着のない、ばらばらの状態のお米を得ることができる。
The low-protein fried rice of the present invention and the dried product of low-protein steamed rice have the characteristics that rice grains are difficult to disintegrate during distribution and cooking, are rich, and have high energy.
After washing the enzyme-treated rice and before frying it with oil, if the rice is immersed in oil at 90 ° C or lower to remove water, the rice will not adhere to each other during production or cooking, etc. You can get rice in the state.
 本発明のまた別の側面の食品は、先に説明をした製造方法で得られる低蛋白質米を調理して得られる。そして、特に、低蛋白質米として低蛋白質揚げ米を使用する場合が、前記第四の態様の食品である。
 本発明の低蛋白質米の調理方法としては、例えば、炊飯、蒸し調理等が挙げられる。
 低蛋白質米を、炊飯器を用いて炊飯する場合、米と水の質量の割合は1:0.5~2が好ましく。1:0.7~1.5がより好ましく、1:0.8~1.2が特に好ましい。
The food according to another aspect of the present invention is obtained by cooking low protein rice obtained by the production method described above. And especially the case where low protein fried rice is used as low protein rice is the foodstuff of the said 4th aspect.
Examples of the method for cooking low protein rice of the present invention include rice cooking and steaming cooking.
When low protein rice is cooked using a rice cooker, the mass ratio of rice and water is preferably 1: 0.5-2. The ratio is more preferably 1: 0.7 to 1.5, and particularly preferably 1: 0.8 to 1.2.
 本発明において蒸し調理とは、沸騰水と米を入れた容器を常用の蒸し器に入れて蒸し調理することや、加熱水蒸気を吹きかけて蒸し状態で調理することをいう。本発明の低蛋白質米を蒸し調理する場合、沸騰水と米の質量の割合は、1:0.5~2が好ましく、1:0.7~1.5がより好ましく、1:0.8~1.2が特に好ましい。蒸し調理は、常用の蒸し器に入れて3~15分間程度蒸し処理することが好ましい。 In the present invention, steaming refers to cooking by steaming a container containing boiling water and rice in a regular steamer, or cooking in a steamed state by spraying heated steam. When steaming the low protein rice of the present invention, the ratio of the mass of boiling water and rice is preferably 1: 0.5 to 2, more preferably 1: 0.7 to 1.5, and 1: 0.8. Is particularly preferred. Steamed cooking is preferably carried out in a conventional steamer for about 3 to 15 minutes.
 また、本発明の低蛋白質米は、生米と同じように調理することで各種食品を作ることができる。かかる食品として、例えば、炊飯米、おにぎり、もち、チャーハン、フォー、パン等が挙げられる。 Moreover, the low protein rice of this invention can make various foods by cooking like raw rice. Examples of such foods include cooked rice, rice balls, rice cakes, fried rice, pho, and bread.
 本発明のまた別の側面の低蛋白質蒸し処理米の製造方法は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米を90℃以下の油に浸漬して水を除去し、その後蒸し処理することを特徴とする低蛋白質蒸し処理米の製造方法である。そして、前記低蛋白質蒸し処理米の製造方法において、蒸し処理を、蒸すという方法で行う場合が、前記第五の態様の低蛋白質蒸し米の製造方法である。
 使用する生米は、先に説明をした低蛋白質揚げ米の製造方法で使用するものと同じものを使用することができ、また、蛋白質分解処理の方法、処理米の洗浄の方法、及び水切りの方法についても、先に説明をした低蛋白質揚げ米の製造方法における方法と同じ方法で行うことができる。
Another aspect of the present invention is a method for producing low protein steamed rice, which comprises subjecting raw rice to proteolytic treatment, washing the resulting treated rice, and then immersing the rice in oil of 90 ° C. or less to remove water. And then steaming, a method for producing low protein steamed rice. And in the manufacturing method of the said low protein steamed rice, the case where steaming is performed by the method of steaming is the manufacturing method of the low protein steamed rice of the said 5th aspect.
The raw rice to be used can be the same as that used in the method for producing the low protein fried rice described above, and the proteolytic treatment method, the treated rice washing method, and the draining rice The method can also be performed in the same manner as the method for producing low protein fried rice described above.
 本発明における処理米の油への浸漬処理について説明をする。
 油への浸漬処理は、米に付着した水のほとんどが除去できる条件であれば良く、具体的には5秒間以上の浸漬を1回以上行うのが好ましく、10秒間~24時間の浸漬を1回以上行うのがより好ましく、2回~10回行うのがさらにより好ましい。比較的短い製造時間で効率よく水を除去したい場合、例えば、浸漬させるお米に物理的な振動を与えながら5秒間~10分間の浸漬を1回~10回行う方法を行えば良い。また、製造の作業効率を高めるために、人が作業をしない時間帯、具体的には、蛋白質分解処理後1晩~1日間(16~24時間)、油への浸漬を1回行ってもよい。
 油への浸漬処理を行うことにより、蒸し処理をしても、蒸し処理後の米粒同士の付着がほとんどなくなると考えられる。
The immersion process of the treated rice in oil in the present invention will be described.
The dipping treatment in oil may be performed under the condition that most of the water adhering to the rice can be removed. Specifically, the dipping for 5 seconds or more is preferably performed once or more, and the dipping for 10 seconds to 24 hours is 1 More preferably, it is more than once, more preferably 2 to 10 times. When it is desired to efficiently remove water in a relatively short production time, for example, a method of performing immersion for 1 to 10 times for 5 seconds to 10 minutes while applying physical vibration to the rice to be immersed may be performed. Further, in order to increase the work efficiency of the production, even when the human is not working, specifically, for one night to one day (16 to 24 hours) after the proteolytic treatment, the oil may be immersed once. Good.
By performing the immersion treatment in oil, it is considered that even if steaming is performed, adhesion between the rice grains after steaming is almost eliminated.
 浸漬に使用する油は、浸漬時に液体状態の油であれば良く、具体的には、大豆油、菜種油、コーン油、麺実油、紅花油、オリーブ油、米油、パーム油、パーム分別油、これらの油の水添油、前記何れかの油のエステル交換油等から選ばれる1種又は2種以上を使用することができ、これらの中でも、菜種油、大豆油が好ましい。例えば、融点50℃のパーム水添油や融点26℃のヤシ油を使用する場合は、25℃では固体なので、使用する油が液体状態となる温度で浸漬処理を行うことが好ましい。例えば、パーム水添油を使用する場合は50~90℃、ヤシ油を使用する場合は26~90℃で浸漬処理を行うことが好ましい。 The oil used for the dipping may be an oil in a liquid state at the time of dipping. Specifically, soybean oil, rapeseed oil, corn oil, noodle seed oil, safflower oil, olive oil, rice oil, palm oil, palm fractionated oil, One or two or more selected from hydrogenated oils of these oils and transesterified oils of any of the above oils can be used, and among these, rapeseed oil and soybean oil are preferred. For example, when using a palm hydrogenated oil having a melting point of 50 ° C. or a palm oil having a melting point of 26 ° C., it is solid at 25 ° C. Therefore, it is preferable to perform the dipping treatment at a temperature at which the oil used is in a liquid state. For example, the immersion treatment is preferably performed at 50 to 90 ° C. when palm hydrogenated oil is used, and at 26 to 90 ° C. when palm oil is used.
 本発明における蒸し処理について説明をする。
 本発明における蒸し処理としては、例えば、米を蒸すこと、米を蒸し焼きにすること、米に加熱水蒸気を当てること等が挙げられる。
 米を蒸す方法としては、沸騰水と米を入れた容器を常用の蒸し器に入れて蒸し調理することや、加熱水蒸気を吹きかけて蒸し状態に調理することをいう。蒸し調理する場合、沸騰水と米の質量の割合は、1:0.5~2が好ましく、1:0.7~1.5がより好ましく、1:0.8~1.2が特に好ましい。蒸し調理は、常用の蒸し器に入れて3~15分間程度蒸し処理することが好ましい。
 米を蒸し焼きにする方法としては、スチームオーブンを使用する方法等が挙げられる。
 米を蒸し焼きにする際の温度及び時間は、100~180℃で3~30分間が好ましく、100~160℃で3~30分間がより好ましく、100~140℃で3~30分間がさらに好ましい。
 本発明の製造方法によれば、蒸し処理後に米粒同士の付着がほとんどない低蛋白質蒸し処理米を製造することができる。
The steaming process in this invention is demonstrated.
Examples of the steaming treatment in the present invention include steaming rice, steaming rice, and applying heated steam to the rice.
As a method of steaming rice, it means cooking in a steamer by putting a container containing boiling water and rice in a regular steamer, or cooking in a steamed state by spraying heated steam. In steam cooking, the ratio of the mass of boiling water and rice is preferably 1: 0.5 to 2, more preferably 1: 0.7 to 1.5, and particularly preferably 1: 0.8 to 1.2. . Steamed cooking is preferably carried out in a conventional steamer for about 3 to 15 minutes.
Examples of the method for steaming the rice include a method using a steam oven.
The temperature and time for steaming the rice is preferably 100 to 180 ° C. for 3 to 30 minutes, more preferably 100 to 160 ° C. for 3 to 30 minutes, and even more preferably 100 to 140 ° C. for 3 to 30 minutes.
According to the production method of the present invention, it is possible to produce a low-protein steamed rice having almost no adhesion between rice grains after steaming.
 本発明のまた別の側面の食品は、先に説明をした製造方法で得られる低蛋白質蒸し処理米を調理して得られる、おにぎりやチャーハンなどの食品である。そして、前記低蛋白質蒸し処理米が、第五の態様の製造方法により得られる低蛋白質蒸し米である場合の調理食品が、前記第六の態様のおにぎりやチャーハンなどの食品である。
 本発明の製造方法により得られる低蛋白質蒸し処理米は、そのまま食したり、調理して食品を製造したりすることができ、レトルトパックをして長期保管することもできる。調理の方法としては、成形調理、炒め調理等が挙げられ、例えば、おにぎり、チャーハン等の各種食品を作ることができる。レトルトパックした低蛋白質蒸し米は、電子レンジやお湯等で温めることにより、食することができる。
The food according to another aspect of the present invention is food such as rice balls and fried rice obtained by cooking low protein steamed rice obtained by the production method described above. And the cooked food in case the said low protein steamed rice is the low protein steamed rice obtained by the manufacturing method of a 5th aspect is foodstuffs, such as a rice ball and fried rice of the said 6th aspect.
The low protein steamed rice obtained by the production method of the present invention can be eaten as it is or cooked to produce food, and can be stored for a long time in a retort pack. Examples of the cooking method include molded cooking and fried cooking. For example, various foods such as rice balls and fried rice can be made. Retort-packed low protein steamed rice can be eaten by warming it with a microwave or hot water.
 本発明のまた別の側面の低蛋白質蒸し処理米の乾燥品の製造方法は、先に説明をした製造方法により得られる低蛋白質蒸し処理米を乾燥することを特徴とする低蛋白質蒸し処理米の乾燥品の製造方法である。そして、前記低蛋白質蒸し処理米の乾燥品の製造方法において、低蛋白質蒸し処理米が、前記第五の態様の製造方法により得られる低蛋白質蒸し米である場合が、前記第七の態様の低蛋白質蒸し米の乾燥品の製造方法である。
 低蛋白質蒸し処理米を温風乾燥機等で乾燥することで、低蛋白質蒸し処理米の乾燥品を得ることができる。この低蛋白質蒸し処理米の乾燥品は、油への浸漬処理をしているため、米粒同士の付着がほとんどない。
According to another aspect of the present invention, there is provided a method for producing a dried product of low protein steamed rice, wherein the low protein steamed rice obtained by the production method described above is dried. This is a dry product manufacturing method. And in the manufacturing method of the dried product of the low protein steamed rice, the low protein steamed rice is the low protein steamed rice obtained by the manufacturing method of the fifth aspect. This is a method for producing dried protein steamed rice.
By drying the low protein steamed rice with a warm air dryer or the like, a dried product of the low protein steamed rice can be obtained. Since the dried product of the low protein steamed rice is soaked in oil, there is almost no adhesion between the rice grains.
 本発明のまた別の側面の食品は、先に説明をした製造方法により得られる低蛋白質蒸し処理米の乾燥品を調理して得られる、炊飯米やチャーハンなどの食品である。そして、前記低蛋白質蒸し処理米の乾燥品が、第七の態様の製造方法により得られる低蛋白質蒸し米の乾燥品である場合の調理食品が、前記第八の態様の炊飯米やチャーハンなどの食品である。
 低蛋白質蒸し処理米の乾燥品は、乾燥前の蒸し処理米と違って生米と同じような形態であるから、米の使用量を自由に調整することができ、使いやすく、炊飯米やチャーハン等の食品に広く使用することができる。
The food according to another aspect of the present invention is a food such as cooked rice or fried rice obtained by cooking a dried product of low protein steamed rice obtained by the production method described above. And the cooked food when the dried product of the low protein steamed rice is the dried product of the low protein steamed rice obtained by the production method of the seventh aspect is the cooked rice or fried rice of the eighth aspect. It is food.
The dried product of low-protein steamed rice has the same form as raw rice, unlike steamed rice before drying, so the amount of rice used can be adjusted freely, and it is easy to use. It can be widely used for foods such as.
 本発明のまた別の側面の低蛋白質揚げ米、すなわち前記第九の態様は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げることにより製造される低蛋白質揚げ米である。第九の態様における低蛋白質揚げ米の製造に関する説明は、前記第三の態様の低蛋白質揚げ米の製造方法に関する説明と同様である。 Another aspect of the present invention is a low protein fried rice, that is, the ninth embodiment is a low protein fried rice produced by proteolytically treating raw rice, washing the obtained treated rice, and then frying in oil. Rice. The explanation about the production of the low protein fried rice in the ninth aspect is the same as the explanation about the production method of the low protein fried rice of the third aspect.
 本発明のまた別の側面の低蛋白質蒸し処理米は、生米を蛋白質分解処理し、得られた処理米を洗浄した後、米を90℃以下の油に浸漬して水を除去し、その後蒸し処理をすることにより製造される低蛋白質蒸し処理米である。前記低蛋白質蒸し処理米の製造に関する説明は、先に記載をした低蛋白質蒸し処理米の製造に関する説明と同様である。そして、前記蒸し処理を、蒸すという方法で行って製造される低蛋白質蒸し米が、前記十の態様の低蛋白質蒸し米である。
 第十の態様における低蛋白質蒸し米の製造に関する説明は、前記第五の態様の低蛋白質蒸し米の製造に関する説明と同様である。
In another aspect of the present invention, the low protein steamed rice is obtained by subjecting raw rice to proteolytic treatment, washing the resulting treated rice, immersing the rice in 90 ° C. or lower oil, and removing water. A low protein steamed rice produced by steaming. The explanation about the production of the low protein steamed rice is the same as the explanation about the production of the low protein steamed rice described above. And the low protein steamed rice manufactured by performing the steaming process by the method of steaming is the low protein steamed rice of the tenth aspect.
The description related to the production of the low protein steamed rice in the tenth aspect is the same as the description related to the manufacture of the low protein steamed rice in the fifth aspect.
 本発明のまた別の側面の低蛋白質蒸し処理米の乾燥品は、先に説明をした低蛋白質蒸し処理米を乾燥することにより製造される低蛋白質蒸し処理米の乾燥品である。低蛋白質蒸し処理米の乾燥品の製造に関する説明は、先に記載をした低蛋白質蒸し処理米の乾燥品の製造方法に関する説明と同様である。そして、前記低蛋白質蒸し処理米の乾燥品において、低蛋白質蒸し処理米が、前記第十の態様の製造方法により得られる低蛋白質蒸し米である場合が、前記第十一の態様の低蛋白質蒸し米の乾燥品である。
 第十一の態様の低蛋白質蒸し米の乾燥品の製造に関する説明は、前記第七の態様の乾燥品の製造方法に関する説明と同様である。
The dried product of low protein steamed rice according to another aspect of the present invention is a dried product of low protein steamed rice produced by drying the low protein steamed rice described above. The explanation about the production of the dried product of the low protein steamed rice is the same as the explanation about the method for producing the dried product of the low protein steamed rice described above. And in the dried product of the low protein steamed rice, when the low protein steamed rice is the low protein steamed rice obtained by the production method of the tenth aspect, the low protein steamed rice of the eleventh aspect is used. It is a dried rice product.
The description relating to the production of the dried product of the low protein steamed rice of the eleventh aspect is the same as the explanation relating to the method for producing the dried product of the seventh aspect.
 本発明のまた別の側面の低蛋白質米の製造方法は、
 生米を蛋白質分解処理し、得られた処理米を洗浄した後、米へ油を付着させること、
 油が付着した前記米を糊化すること、及び
 前記米を糊化することの後に、さらに、米を乾燥させることを含み、
 前記米へ油を付着させることが、油を含有する油含有浸漬水に米を浸漬させることであり、
 前記米を糊化することが、米を蒸し焼きにすることであり、
 前記油含有浸漬水は、水及び油を含み、
 前記油が大豆油、菜種油、コーン油、麺実油、紅花油、オリーブ油、米油、パーム油、パーム分別油、これらの油の水添油、及び前記何れかの油のエステル交換油からなる群より選択される少なくとも1の油であり、
 前記油含有浸漬水中の油の含量が、前記生米1gに対して0.17~2.5mlであり、
 前記油含有浸漬水中の油の含量が、4~50%(vol./vol.)であり、
 前記油含有浸漬水中の水の含量が、50~96%(vol./vol.)であり、
 生米100質量部に対する前記油含有浸漬水の量が、100~1000質量部であることが好ましい。
Another aspect of the present invention provides a method for producing low protein rice,
Proteolytic treatment of raw rice, washing the resulting treated rice, and attaching oil to the rice,
Gelatinizing the rice to which oil has adhered, and after gelatinizing the rice, further comprising drying the rice,
To attach oil to the rice is to immerse the rice in oil-containing immersion water containing oil,
Gelatinizing the rice is steaming the rice,
The oil-containing immersion water includes water and oil,
The oil comprises soybean oil, rapeseed oil, corn oil, noodle seed oil, safflower oil, olive oil, rice oil, palm oil, palm fractionated oil, hydrogenated oil of these oils, and transesterified oil of any of the above oils At least one oil selected from the group;
The oil content in the oil-containing immersion water is 0.17 to 2.5 ml with respect to 1 g of the raw rice,
The oil content in the oil-containing immersion water is 4 to 50% (vol./vol.)
The water content in the oil-containing immersion water is 50 to 96% (vol./vol.)
The amount of the oil-containing immersion water relative to 100 parts by mass of raw rice is preferably 100 to 1000 parts by mass.
 本発明のまた別の側面の低蛋白質米の製造方法は、
 生米を蛋白質分解処理し、得られた処理米を洗浄した後、米へ油を付着させること、
 油が付着した前記米を糊化すること、及び
 前記米を糊化することの後に、さらに、米を乾燥させることを含み、
 前記米へ油を付着させることが、油含有乳化液浸漬液に米を浸漬させることであり、
 前記米を糊化することが、米を蒸し焼きにすることであり、
 前記油含有乳化液浸漬液は、水、油及び乳化剤を含み、
 前記油が大豆油、菜種油、コーン油、麺実油、紅花油、オリーブ油、米油、パーム油、パーム分別油、これらの油の水添油、及び前記何れかの油のエステル交換油からなる群より選択される少なくとも1の油であり、
 前記乳化剤がレシチン、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、及びソルビタン脂肪酸エステルからなる群より選択される少なくとも1の乳化剤であり、
 前記油含有乳化液浸漬液中の油の含量が、1~50質量%であり、
 前記油含有乳化液浸漬液中の乳化剤の含量が、0.01~10質量%であり、
 前記油含有乳化液浸漬液中の水の含量が、40~98.99質量%であり、
 前記生米100質量部に対する前記油含有乳化液浸漬液の量が、100~1000質量部であり、
 前記米を蒸し焼きにすることが、100~180℃の水蒸気を3~30分間当てることであることが好ましい。
Another aspect of the present invention provides a method for producing low protein rice,
Proteolytic treatment of raw rice, washing the resulting treated rice, and attaching oil to the rice,
Gelatinizing the rice to which oil has adhered, and after gelatinizing the rice, further comprising drying the rice,
To attach the oil to the rice is to immerse the rice in the oil-containing emulsion immersion liquid,
Gelatinizing the rice is steaming the rice,
The oil-containing emulsion immersion liquid contains water, oil and an emulsifier,
The oil comprises soybean oil, rapeseed oil, corn oil, noodle seed oil, safflower oil, olive oil, rice oil, palm oil, palm fractionated oil, hydrogenated oil of these oils, and transesterified oil of any of the above oils At least one oil selected from the group;
The emulsifier is at least one emulsifier selected from the group consisting of lecithin, glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, and sorbitan fatty acid ester;
The oil content in the oil-containing emulsion immersion liquid is 1 to 50% by mass,
The content of the emulsifier in the oil-containing emulsion immersion liquid is 0.01 to 10% by mass,
The water content in the oil-containing emulsion immersion liquid is 40 to 99.99% by mass,
The amount of the oil-containing emulsion immersion liquid with respect to 100 parts by mass of the raw rice is 100 to 1000 parts by mass,
The steaming of the rice is preferably performed by applying steam at 100 to 180 ° C. for 3 to 30 minutes.
 以下、実施例により本発明をより具体的に説明するが、本発明は以下の実施例に限定されるものではない。 Hereinafter, the present invention will be described more specifically by way of examples. However, the present invention is not limited to the following examples.
≪低蛋白質米の製造(1)≫
 原料の生米としてインディカ米を使用して各種低蛋白質米を製造した。
 まず、pH4.0の緩衝液に、蛋白質分解酵素(プロテアーゼM、天野エンザイム(株)製)0.5質量%、及び乳化剤製剤(商品名:リョートーエステルSMO、三菱化学フーズ(株)製、組成:ショ糖脂肪酸エステル3.5%、グリセリン脂肪酸エステル3.5%、オリゴ糖43%、水50%)2質量%を溶解し、反応液を調製した。インディカ米(生米)75gに反応液350mlを添加し、42℃で24時間スターラー撹拌をしながら酵素処理を行った。酵素処理した米に、水350mlを添加し、10分間スターラーで撹拌し、洗浄をした。洗浄した米を金ザルに入れて約30分間水切りをした後、以下の処理を行うことによりインディカ米の低蛋白質米を製造した。
≪Production of low protein rice (1) ≫
Various low protein rice was produced using indica rice as raw raw rice.
First, in a pH 4.0 buffer solution, 0.5% by mass of proteolytic enzyme (Protease M, Amano Enzyme Co., Ltd.) and emulsifier preparation (trade name: Ryoto Ester SMO, manufactured by Mitsubishi Chemical Foods Co., Ltd., composition: 2% by mass of sucrose fatty acid ester 3.5%, glycerin fatty acid ester 3.5%, oligosaccharide 43%, water 50%) was dissolved to prepare a reaction solution. 350 ml of the reaction solution was added to 75 g of Indica rice (raw rice), and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 24 hours. 350 ml of water was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed. The washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein rice of Indica rice.
 [比較例1]
(インディカ米風乾処理)
 水切りしたインディカ米を70℃で90分間風乾することで乾燥をし、低蛋白質インディカ米を得た。
 [比較例2]
(インディカ米蒸し処理)
 水切りしたインディカ米を蒸し器に入れて5分間蒸し、その後、70℃で90分間風乾することで乾燥をし、低蛋白質インディカ米を得た。
 [実施例1]
(インディカ米揚げ処理)
 水切りしたインディカ米を180℃のコーン油(商品名:日清コーン油、日清オイリオグループ(株)製)で30秒間揚げ、低蛋白質インディカ米(低蛋白質インディカ揚げ米)を得た。
[Comparative Example 1]
(Indica rice drying process)
The dried indica rice was dried by air drying at 70 ° C. for 90 minutes to obtain low protein indica rice.
[Comparative Example 2]
(Indica rice steaming treatment)
Drained indica rice was put in a steamer and steamed for 5 minutes, and then dried by air drying at 70 ° C. for 90 minutes to obtain low protein Indica rice.
[Example 1]
(Indica rice fried processing)
The drained indica rice was fried for 30 seconds with 180 ° C. corn oil (trade name: Nisshin Corn Oil, manufactured by Nisshin Oilio Group Co., Ltd.) to obtain low protein Indica rice (low protein Indica fried rice).
<米の水分含量の測定>
 米の水分含量を、水分計(SMART SYSTEM 5,CEM Corporation製)を用いて測定した。その結果を表1に示す。
<Measurement of water content of rice>
The moisture content of the rice was measured using a moisture meter (SMART SYSTEM 5, manufactured by CEM Corporation). The results are shown in Table 1.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 本発明の製造方法により、水分含量が10質量%以下の保存性の良い低蛋白質米を得ることができた。 By the production method of the present invention, low protein rice having a water content of 10% by mass or less and having good storage stability could be obtained.
<米の蛋白質含量の測定>
 米の乾燥物中の蛋白質含量を、ケルダール法で測定した。その結果を表2に示す。
<Measurement of protein content in rice>
The protein content in the dried rice was measured by the Kjeldahl method. The results are shown in Table 2.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 蛋白質分解酵素による蛋白質分解処理を行うことによって、原料米の1/10程度まで蛋白質含量を低減させることができた。蛋白質含量は、100g乾燥重量当たりの量を算出しているため、水切りした米を、風乾、蒸し処理、又は揚げ処理した後の米(比較例1、2の米、又は実施例1の米)の蛋白質含量は、表2に示す水切りした米の蛋白質含量と同じ含量であると考えられる。 The protein content could be reduced to about 1/10 of the raw rice by performing proteolytic treatment with proteolytic enzymes. Since the protein content is calculated based on the dry weight of 100 g, the rice after drained, air-dried, steamed or fried (rice in Comparative Examples 1 and 2 or rice in Example 1) The protein content of is considered to be the same as the protein content of drained rice shown in Table 2.
<米の崩壊性の評価>
 米10gを、目開き1400μmのふるいをセットした振とう器(ミニふるい振とう器 MVS-1,アズワン製)を用いて、振とうを3分間行った。3分後、ふるい上で米粒の崩壊状態を目視で確認した。振とう後、米粒が崩壊しておらず、米粒の形状を維持していた場合にはA、振とう後、米粒が崩壊し、米粒の形状を維持していなかった場合にはBと評価した。その結果を表3に示す。
<Evaluation of disintegration of rice>
10 g of rice was shaken for 3 minutes using a shaker (mini sieve shaker MVS-1, manufactured by ASONE) set with a sieve having an opening of 1400 μm. Three minutes later, the collapsed state of the rice grains was visually confirmed on the sieve. After shaking, the rice grains were evaluated as A when the rice grains were not collapsed and maintained the shape of the rice grains, and as B when the rice grains were collapsed and the shape of the rice grains were not maintained after the shaking. . The results are shown in Table 3.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 米をふるいにかけて、物理的な負荷を加えると、比較例1と比較例2の米粒は崩壊したが、実施例1と実施例2の米粒は崩壊しなかった。このことから、揚げ処理を行うことにより、低蛋白質処理をした米粒の物理的強度を高めることができ、その結果、流通時に米粒が崩壊しにくい低蛋白質米が得られることがわかった。 When sieving the rice and applying a physical load, the rice grains of Comparative Example 1 and Comparative Example 2 collapsed, but the rice grains of Example 1 and Example 2 did not collapse. From this, it was found that by performing the frying treatment, the physical strength of the low-protein-treated rice grains can be increased, and as a result, low-protein rice is obtained in which the rice grains do not easily collapse during distribution.
<炊飯米及び蒸し調理米のかたさの評価>
 原料インディカ米(生米)又は実施例1の米を炊飯器(三菱IHジャー炊飯器NJ-KH10S形、三菱電機ホーム機器(株)製)で炊飯し、炊飯米を作った。炊飯方法は、鈴木らの方法(日本栄養・食糧学会誌36(5),389-392,1983)を参考に行った。炊飯器に水を200mL入れ、米10gに対し、水10gを入れた金属製プリンカップをその釜に入れ、「白米、お急ぎ」のモードで炊飯を行い、炊飯米を得た。
 また、炊飯と同じ割合の沸騰水を実施例1の米に入れ、蒸し器で蒸し調理を行い、蒸し調理米を作った。得られた炊飯米及び蒸し調理米について、以下の方法により、かたさを測定した。
 炊飯米及び蒸し調理米を、それぞれ直径40mm、高さ15mmの容器に10g充填したものについて、直線運動により物質の圧縮応力を測定する装置(RE-33005 RHEONER、YAMADEN製)により、かたさを測定した。測定は、直径20mm、高さ8mmの樹脂製のプランジャーを用いて、圧縮速度10mm/s、クリアランス5mmで2回圧縮により行った。
 その結果を表4に示す。
<Evaluation of hardness of cooked rice and steamed cooked rice>
Raw rice indica rice (raw rice) or rice from Example 1 was cooked with a rice cooker (Mitsubishi IH Jar Rice Cooker Model NJ-KH10S, manufactured by Mitsubishi Electric Home Equipment Co., Ltd.) to prepare cooked rice. The rice cooking method was performed with reference to the method of Suzuki et al. (Journal of Japanese Society of Nutrition and Food 36 (5), 389-392, 1983). 200 mL of water was put into a rice cooker, and a metal pudding cup containing 10 g of water was put into the kettle for 10 g of rice, and cooked in the mode of “white rice, hurry” to obtain cooked rice.
Moreover, the boiling water of the same ratio as cooked rice was put into the rice of Example 1, steamed cooking was performed with a steamer, and steamed cooked rice was made. The hardness of the obtained cooked rice and steamed cooked rice was measured by the following method.
Hardness was measured with a device (RE-33005 RHEONER, manufactured by YAMADEN) that measures the compressive stress of a substance by linear motion for 10 g of cooked rice and steamed cooked rice filled in a container with a diameter of 40 mm and a height of 15 mm, respectively. . The measurement was performed by compression twice using a resin plunger having a diameter of 20 mm and a height of 8 mm at a compression speed of 10 mm / s and a clearance of 5 mm.
The results are shown in Table 4.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
 実施例1の炊飯米は、原料生米の炊飯米よりかたさ荷重が小さく、実施例1の米の蒸し調理米は、原料米の炊飯米よりかたさ荷重が大きかったが、両方とも食するには問題のないかたさであった。 The cooked rice of Example 1 had a lower hardness load than cooked rice of raw raw rice, and the steamed cooked rice of Example 1 had a greater hardness load than cooked rice of raw rice, There was no problem.
<炊飯米の官能評価>
 かたさの評価で記載した炊飯方法と同じ方法で、比較例1、2、及び実施例1、2の米を炊飯し、4名のパネルにて、外観、やわらかさ、コク、及びおいしさ(好み)について官能評価を行った。各項目について、以下の評価基準で評価を行った。その結果を表5~7に示す。
〔外観(1)〕
A:米粒の形状を維持している。
B:全体の1/3~1/2の米粒が崩壊している。
C:米粒が崩壊し、米粒の形状を維持していない。
〔外観(2)〕
A:原料インディカ米(生米)と同程度の白さである。
B:原料インディカ米(生米)より白く違和感がある。
〔やわらかさの程度〕
A:ちょうど良いやわらかさである。
B:Aよりやわらかい。
C:非常にやわらかい。
〔コク〕
A:味にコクがある。
B:味にコクがない(市販の低蛋白質米と同様)。
〔おいしさ又は好み〕
A:総合的に評価しておいしい、又は好みである。
B:総合的に評価して、AとCの中間である。
C:総合的に評価しておいしくない、又は好みでない。
<Sensory evaluation of cooked rice>
The rice of Comparative Examples 1 and 2 and Examples 1 and 2 was cooked in the same manner as the rice cooking method described in the evaluation of hardness, and the appearance, softness, richness, and deliciousness (preference) on the panel of 4 people ) Was subjected to sensory evaluation. Each item was evaluated according to the following evaluation criteria. The results are shown in Tables 5-7.
[Appearance (1)]
A: The shape of rice grains is maintained.
B: 1/3 to 1/2 rice grains as a whole are disintegrated.
C: The rice grain has collapsed and the shape of the rice grain is not maintained.
[Appearance (2)]
A: It is whiteness comparable to raw material indica rice (raw rice).
B: It is whiter and uncomfortable than the raw material Indica rice (raw rice).
[Degree of softness]
A: Just the right softness.
B: Softer than A.
C: Very soft.
[Body]
A: There is a rich taste.
B: Rich in taste (similar to commercially available low protein rice).
[Taste or taste]
A: Overall evaluation is delicious or liking.
B: Overall evaluation is between A and C.
C: The evaluation is not comprehensive or unfavorable.
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007
 比較例1の米の炊飯米は、外観は悪く、非常にやわらかいので、おいしくないという評価であった。一方、実施例1の米の炊飯米は、色及び米粒の形状の点では、インディカ米の炊飯米とほぼ同じで、味の点では市販の低蛋白質米よりもコクがあり、おいしいという評価であった。また、比較例2の米の炊飯米は、全体の1/3~1/2の米粒が崩壊し、実施例1の米の炊飯米に比べやわらかく、おいしいという評価ではなかった。 The rice cooked rice of Comparative Example 1 was evaluated as not delicious because it had a poor appearance and was very soft. On the other hand, the cooked rice of the rice of Example 1 is almost the same as the cooked rice of Indica rice in terms of color and shape of rice grains, and in terms of taste, it is richer than commercially available low protein rice, and is evaluated to be delicious. there were. In addition, the rice cooked rice of Comparative Example 2 was not evaluated as soft and delicious compared to the rice cooked rice of Example 1 because 1/3 to 1/2 of the whole rice grains collapsed.
≪低蛋白質米の製造(2)≫
 原料の生米として、インディカ米又はジャポニカ米を使用して低蛋白質米を製造した。
 まず、pH4.0の緩衝液に、蛋白質分解酵素(プロテアーゼM、天野エンザイム(株)製)を0.5質量%溶解し、反応液を調製した。インディカ米15gに反応液80mlを添加し、42℃で16時間スターラー撹拌をしながら酵素処理を行った。酵素処理した米に、pH4.0の緩衝液80mlを添加し、10分間スターラーで撹拌し、洗浄をした。洗浄した米を金ザルに入れて約30分間水切りをした後、以下の処理を行うことによりインディカ米又はジャポニカ米の低蛋白質米を製造した。
≪Production of low protein rice (2) ≫
Low protein rice was produced using indica rice or japonica rice as raw raw rice.
First, 0.5% by mass of a protease (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer solution to prepare a reaction solution. 80 ml of the reaction solution was added to 15 g of Indica rice, and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 16 hours. 80 ml of pH 4.0 buffer solution was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed. The washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein rice such as indica rice or japonica rice.
[比較例3]
(インディカ米風乾処理)
 水切りしたインディカ米を室温で30分間風乾することで乾燥をし、低蛋白質インディカ米を得た。
[比較例4]
(ジャポニカ米風乾処理)
 水切りしたジャポニカ米を室温にて30分間風乾することで乾燥をし、低蛋白質ジャポニカ米を得た。
[実施例2]
(インディカ米揚げ処理)
 水切りしたインディカ米を180℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))で30秒間揚げ、低蛋白質インディカ米(低蛋白質インディカ揚げ米)を得た。
[実施例3]
(ジャポニカ米揚げ処理)
 水切りしたジャポニカ米を180℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))で30秒間揚げ、低蛋白質ジャポニカ米(低蛋白質ジャポニカ揚げ米)を得た。
[Comparative Example 3]
(Indica rice drying process)
The dried indica rice was dried by air drying at room temperature for 30 minutes to obtain low protein indica rice.
[Comparative Example 4]
(Japonica rice air-dried)
Dried japonica rice was dried by air drying at room temperature for 30 minutes to obtain low protein japonica rice.
[Example 2]
(Indica rice fried processing)
Drained indica rice was fried for 30 seconds with rapeseed oil (trade name: Nisshin Canola Oil, manufactured by Nisshin Oilio Group Co., Ltd.) at 180 ° C. to obtain low protein indica rice (low protein indica rice).
[Example 3]
(Japonica rice fried processing)
The drained japonica rice was fried for 30 seconds with rapeseed oil at 180 ° C. (trade name: Nissin Canola Oil, Nissin Oilio Group Co., Ltd.) to obtain low protein japonica rice (low protein japonica rice).
<米の水分含量の測定>
 米の水分含量を、加熱乾燥式水分計(MS-70、A&D(株)製)を用いて測定した。その結果を表8に示す。
<Measurement of water content of rice>
The moisture content of the rice was measured using a heat drying moisture meter (MS-70, manufactured by A & D Co., Ltd.). The results are shown in Table 8.
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000008
 本発明の製造方法により、水分含量が10質量%以下の保存性の良い低蛋白質米を得ることができた。 By the production method of the present invention, low protein rice having a water content of 10% by mass or less and having good storage stability could be obtained.
<米の蛋白質含量の測定>
 米の乾燥物中の蛋白質含量を、ケルダール法で測定した。その結果を表9に示す。
<Measurement of protein content in rice>
The protein content in the dried rice was measured by the Kjeldahl method. The results are shown in Table 9.
Figure JPOXMLDOC01-appb-T000009
Figure JPOXMLDOC01-appb-T000009
 蛋白質分解酵素による蛋白質分解処理を行うことによって、どちらの米種においても原料米の1/25程度まで蛋白質含量を低減させることができた。蛋白質含量は、100g乾燥重量当たりの量を算出しているため、水切りした米を、風乾、又は揚げ処理した後の米(比較例3、4の米、又は実施例2、3の米)の蛋白質含量は、表9に示す水切りした米の蛋白質含量と同じ含量であると考えられる。 By performing proteolytic treatment with a proteolytic enzyme, the protein content could be reduced to about 1/25 of the raw rice in both rice varieties. Since the protein content is calculated based on the dry weight of 100 g, the rice after drained or air-dried rice (rice in Comparative Examples 3 and 4 or rice in Examples 2 and 3) The protein content is considered to be the same as the protein content of drained rice shown in Table 9.
<米の崩壊性の評価>
 先に記載した評価方法と同じ方法で、原料の生米及び製造した低蛋白質米の米粒の崩壊状態を評価した。その結果を表10に示す。
<Evaluation of disintegration of rice>
By the same method as the evaluation method described above, the collapsed state of the raw rice grains and the produced low protein rice grains were evaluated. The results are shown in Table 10.
Figure JPOXMLDOC01-appb-T000010
Figure JPOXMLDOC01-appb-T000010
 米をふるいにかけて、物理的な負荷を加えると、比較例3と比較例4の米粒は崩壊したが、実施例2と実施例3の米粒は崩壊しなかった。したがって、揚げ処理を行うことにより、低蛋白質処理をした米粒の物理的強度を高めることができ、その結果、流通時に米粒が崩壊しにくい低蛋白質米が得られることがわかった。 When sieving the rice and applying a physical load, the rice grains of Comparative Example 3 and Comparative Example 4 collapsed, but the rice grains of Example 2 and Example 3 did not collapse. Therefore, it was found that by performing the frying treatment, the physical strength of the low-protein-treated rice grains can be increased, and as a result, low-protein rice that does not easily collapse during distribution can be obtained.
<炊飯米の官能評価>
 かたさの評価で記載した炊飯方法と同じ方法で、比較例3、4、及び実施例2、3の米を炊飯し、4名のパネルにて、外観、やわらかさ、コク、及びおいしさ(好み)について官能評価を行った。各項目について、以下に記載する外観(2)以外は、先に記載した評価基準と同じ評価基準で評価を行った。
〔外観(2)〕
 比較例3、及び実施例2について
A:原料インディカ米(生米)と同程度の白さである。
B:原料インディカ米(生米)より白く違和感がある。
 比較例4、及び実施例3について
A:原料ジャポニカ米(生米)と同程度の白さである。
B:原料ジャポニカ米(生米)より白く違和感がある。
 その結果を表11~14に示す。
<Sensory evaluation of cooked rice>
The rice of Comparative Examples 3, 4 and Examples 2 and 3 was cooked in the same manner as the rice cooking method described in the evaluation of hardness, and the appearance, softness, richness, and deliciousness (preference) on the panel of 4 people ) Was subjected to sensory evaluation. About each item, except the external appearance (2) described below, it evaluated by the same evaluation criteria as the evaluation criteria described previously.
[Appearance (2)]
About the comparative example 3 and Example 2, A: It is whiteness comparable as raw material indica rice (raw rice).
B: It is whiter and uncomfortable than the raw material Indica rice (raw rice).
About the comparative example 4 and Example 3, A: It is the whiteness comparable as raw material japonica rice (raw rice).
B: It is whiter and uncomfortable than raw material japonica rice (raw rice).
The results are shown in Tables 11-14.
Figure JPOXMLDOC01-appb-T000011
Figure JPOXMLDOC01-appb-T000011
Figure JPOXMLDOC01-appb-T000012
Figure JPOXMLDOC01-appb-T000012
Figure JPOXMLDOC01-appb-T000013
Figure JPOXMLDOC01-appb-T000013
Figure JPOXMLDOC01-appb-T000014
Figure JPOXMLDOC01-appb-T000014
 比較例3および比較例4の米の炊飯米は、外観は悪く、非常にやわらかいので、おいしくないという評価であった。一方、実施例2及び実施例3の米の炊飯米は、色及び米粒の形状の点では、インディカ米やジャポニカ米の炊飯米とほぼ同じで、味の点では市販の低蛋白質米よりもコクがあり、おいしいという評価であった。 The rice cooked rice of Comparative Example 3 and Comparative Example 4 was evaluated as not delicious because it had a poor appearance and was very soft. On the other hand, the rice cooked rice of Example 2 and Example 3 is almost the same as the cooked rice of Indica rice or Japonica rice in terms of color and shape of rice grains, and in terms of taste, it is richer than commercially available low protein rice There was an evaluation that it was delicious.
≪米のエネルギー、脂質含量、ミネラル類含量の評価≫
 実施例2と比較例3の低蛋白質米のエネルギー、脂質含量、及びミネラル類含量の分析を行った。その結果を表15に示す。脂質は酸分解法で、ナトリウム含量とカリウム含量は原子吸光光度法(定量下限:1mg/100g)で、リン含量はICP発光分析法で、灰分は直接灰化法で測定した。炭水化物量は、試料全体から、水分、蛋白質、脂質、及び灰分の量を控除して得られた量とした。
 さらに、各分析値に栄養表示基準(平成15年厚生労働省告示第176号)によるエネルギー換算係数を乗じて、実施例2の米と比較例3の米のエネルギーを求めた。すなわち、蛋白質については4kcal/g、脂質については9kcal/g、炭水化物については4kcal/gの係数を乗じた。
≪Evaluation of rice energy, lipid content, mineral content≫
The energy, lipid content, and mineral content of the low protein rice of Example 2 and Comparative Example 3 were analyzed. The results are shown in Table 15. Lipids were measured by acid decomposition, sodium and potassium contents were measured by atomic absorption spectrophotometry (lower limit of quantification: 1 mg / 100 g), phosphorus content was measured by ICP emission spectrometry, and ash was measured by direct ashing. The amount of carbohydrate was obtained by subtracting the amount of water, protein, lipid, and ash from the entire sample.
Furthermore, the energy of the rice of Example 2 and the rice of Comparative Example 3 was obtained by multiplying each analytical value by the energy conversion factor according to the nutrition labeling standard (2003 Ministry of Health, Labor and Welfare Notification No. 176). That is, 4 kcal / g for protein, 9 kcal / g for lipid, and 4 kcal / g for carbohydrate were multiplied.
Figure JPOXMLDOC01-appb-T000015
Figure JPOXMLDOC01-appb-T000015
 上記結果より、本発明の製造方法により得られる低蛋白質米は、低蛋白質米を風乾処理して得られた低蛋白質米に比べ、脂質量が多く、それによりエネルギーが高いことが確認できた。 From the above results, it was confirmed that the low protein rice obtained by the production method of the present invention has a higher amount of lipid and thus higher energy than the low protein rice obtained by air-drying the low protein rice.
≪低蛋白質米の製造(3)≫
 原料の生米としてインディカ米を使用して低蛋白質米を製造した。
 まず、pH4.0の緩衝液に、蛋白質分解酵素(プロテアーゼM、天野エンザイム(株)製)を0.65質量%溶解し、反応液を調製した。インディカ米(生米)75gに反応液350mlを添加し、42℃で24時間スターラー撹拌をしながら酵素処理を行った。
 酵素処理した米に、水350mlを添加し、10分間スターラーで撹拌し、洗浄をした。
 洗浄した米を金ザルに入れて約30分間水切りをした後、以下の処理を行うことによりインディカ米の低蛋白質米を製造した。
≪Production of low protein rice (3) ≫
Low protein rice was produced using Indica rice as raw raw rice.
First, 0.65 mass% of proteolytic enzyme (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer solution to prepare a reaction solution. 350 ml of the reaction solution was added to 75 g of Indica rice (raw rice), and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 24 hours.
350 ml of water was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed.
The washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein rice of Indica rice.
[実施例4]
(インディカ米低温揚げ処理)
 水切りしたインディカ米を130℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))で90秒間揚げ、低蛋白質インディカ米(低蛋白質インディカ揚げ米)を得た。
[Example 4]
(Indica rice low-temperature fried processing)
Drained indica rice was fried for 90 seconds with rapeseed oil (trade name: Nisshin Canola Oil, manufactured by Nisshin Oilio Group Co., Ltd.) at 130 ° C. to obtain low protein indica rice (low protein indica rice).
<米の崩壊性の評価>
 先に記載した評価方法と同じ方法で、得られた低蛋白質インディカ米(低蛋白質インディカ揚げ米)の米粒の崩壊状態を評価した。結果を表16に示す。
<Evaluation of disintegration of rice>
The collapse state of the rice grains of the obtained low protein Indica rice (low protein Indica fried rice) was evaluated by the same method as described above. The results are shown in Table 16.
Figure JPOXMLDOC01-appb-T000016
Figure JPOXMLDOC01-appb-T000016
 上記結果より、低温揚げ処理を行っても、低蛋白質処理をした米粒の物理的強度を高めることができ、流通時に米粒が崩壊しにくい低蛋白質米が得られることがわかった。
<炊飯米の官能評価>
 かたさの評価で記載した炊飯方法と同じ方法で、実施例A4の米を炊飯し、4名のパネルにて、外観、やわらかさ、コク、おいしさ(好み)について官能評価を行った。各項目について、先に記載した評価基準と同じ評価基準で評価を行った。その結果を表17に示す。
From the above results, it was found that even when low-temperature fried treatment was performed, the physical strength of rice grains treated with low protein could be increased, and low-protein rice could be obtained in which rice grains would not easily collapse during distribution.
<Sensory evaluation of cooked rice>
The rice of Example A4 was cooked in the same manner as the rice cooking method described in the evaluation of hardness, and sensory evaluation was performed on the appearance, softness, richness, and taste (preference) on four panels. Each item was evaluated based on the same evaluation criteria as described above. The results are shown in Table 17.
Figure JPOXMLDOC01-appb-T000017
Figure JPOXMLDOC01-appb-T000017
 これらの結果から、130℃で90秒間揚げた場合でも、180℃で揚げた場合と同様、米粒が崩壊しにくく、優れた食味の低蛋白質米が得られることがわかった。 From these results, it was found that even when fried at 130 ° C. for 90 seconds, the rice grains are less likely to disintegrate and can be obtained with low protein rice having an excellent taste, as with fried at 180 ° C.
≪低蛋白質米の製造(4)≫
 原料の生米として、インディカ米又はジャポニカ米を使用して、低温で揚げ処理をした低蛋白質揚げ米を製造した。
 まず、pH4.0の緩衝液に、蛋白質分解酵素(プロテアーゼM、天野エンザイム(株)製)を0.5質量%溶解し、反応液を調製した。インディカ米又はジャポニカ米15gに反応液75mlを添加し、42℃で24時間スターラー撹拌をしながら酵素処理を行った。酵素処理した米に、pH4.0の緩衝液80mlを添加し、10分間スターラーで撹拌し、洗浄をした。洗浄した米を金ザルに入れて約30分間水切りをした後、以下の処理を行うことによりインディカ米又はジャポニカ米の低蛋白質揚げ米を製造した。
[実施例5]
(油浸漬処理後低温揚げ処理、インディカ米)
 25℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))75mlを入れた容器を用意し、水切りしたインディカ低蛋白質米(150g)が入った金ザルを、前記菜種油が入った容器に入れて米を油に5秒間浸漬させた。その後容器から金ザルを取り出し、再び金ザルを菜種油が入った容器に入れることで、再度米を油に5秒間浸漬させた。この浸漬操作を繰り返し行い、5秒間の浸漬を計10回行った。この操作により、米に付着していた水が除去され、油の入った容器の底に水滴がたまっていた。浸漬処理した米を、金ザルで油切りをした後、130℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))で240秒間揚げ、低蛋白質インディカ揚げ米(水分10.8質量%)を得た。
[実施例6]
(油浸漬処理後低温揚げ処理、ジャポニカ米)
 水切りしたインディカ米に代えて、水切りしたジャポニカ米を用いて実施例5と同様の製造を行い、低蛋白質ジャポニカ揚げ米(水分12.6質量%)を得た。
[実施例7]
(油浸漬処理後低温揚げ処理、インディカ米)
 25℃の菜種油に代えて、75℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))を用いて、インディカ米について実施例5と同様の製造を行い、低蛋白質インディカ揚げ米(水分10.5質量%)を得た。
[実施例8]
(油浸漬処理せずに低温揚げ処理、インディカ米)
 浸漬処理の有無の効果を確認するために、水切りしたインディカ米を、油の浸漬処理を行わないで、130℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))で240秒間揚げ、低蛋白質インディカ揚げ米(水分10.6質量%)を得た。
≪Production of low protein rice (4) ≫
As raw raw rice, indica rice or japonica rice was used to produce low protein fried rice that had been fried at low temperature.
First, 0.5% by mass of a protease (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer solution to prepare a reaction solution. 75 ml of the reaction solution was added to 15 g of Indica rice or Japonica rice, and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 24 hours. 80 ml of pH 4.0 buffer solution was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed. The washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein fried rice of Indica rice or Japonica rice.
[Example 5]
(Low-temperature fried treatment after oil immersion treatment, Indica rice)
Prepare a container containing 75 ml of rapeseed oil (trade name: Nissin Canola Oil, Nissin Oilio Group Co., Ltd.) at 25 ° C., and drain the gold monkey containing 150 g of Indica low protein rice. The rice was put in oil and immersed in oil for 5 seconds. Thereafter, the gold monkey was taken out from the container, and the gold monkey was again put into a container containing rapeseed oil, so that the rice was again immersed in the oil for 5 seconds. This dipping operation was repeated, and dipping for 5 seconds was performed 10 times in total. By this operation, the water adhering to the rice was removed, and water droplets had accumulated on the bottom of the container filled with oil. The soaked rice is drained with gold colander, then fried for 240 seconds with rapeseed oil (trade name: Nisshin Canola Oil, Nisshin Oilio Group Co., Ltd.) at 130 ° C., and low protein indica fried rice (moisture) 10.8% by mass).
[Example 6]
(Low-temperature fried treatment after oil immersion treatment, japonica rice)
Instead of drained indica rice, drained japonica rice was used in the same manner as in Example 5 to obtain low protein japonica fried rice (moisture 12.6% by mass).
[Example 7]
(Low-temperature fried treatment after oil immersion treatment, Indica rice)
Indica rice was produced in the same manner as Example 5 using rapeseed oil at 75 ° C (trade name: Nisshin Canola Oil, Nisshin Oilio Group Co., Ltd.) instead of rapeseed oil at 25 ° C, and low protein. Indica fried rice (water content 10.5% by mass) was obtained.
[Example 8]
(Low-temperature fried treatment without oil immersion treatment, Indica rice)
In order to confirm the effect of the presence or absence of soaking treatment, drained indica rice without immersing the oil, rapeseed oil at 130 ° C (trade name: Nisshin Canola Oil, Nisshin Oillio Group Co., Ltd.)) And fried for 240 seconds to obtain low protein Indica fried rice (moisture 10.6% by mass).
<米粒の付着状態の観察>
 低温で揚げ処理をすることにより得られた低蛋白質インディカ揚げ米、又は低蛋白質ジャポニカ揚げ米の米粒の付着状態を目視で観察し、以下の評価基準で評価した。結果を表18に示す。
〔米粒の付着状態〕
A:米1粒1粒がばらけており、米粒同士の付着がない、又はほとんどない。
B:数粒の米粒が付着したものが少し存在している。
C:数粒の米粒が付着したものが多く存在している。
<Observation of rice grain adhesion>
The attached state of rice grains of low protein Indica fried rice or low protein Japonica fried rice obtained by fried at low temperature was visually observed and evaluated according to the following evaluation criteria. The results are shown in Table 18.
[Adhesion state of rice grains]
A: One grain of rice is scattered, and there is little or no adhesion between rice grains.
B: Some rice grains to which several grains are adhered are present.
C: Many rice grains to which several grains are attached are present.
Figure JPOXMLDOC01-appb-T000018
Figure JPOXMLDOC01-appb-T000018
 表18の結果からわかるように、130℃の低温で揚げ処理をした場合、浸漬処理を行わない場合よりも、浸漬処理を行った方が、米粒の付着がないことがわかった。ただ、実施例8の米粒の多くが付着した低蛋白質インディカ揚げ米も、物理的な力を加えると、米粒の付着をほぐすことができる程度の付着であった。また、この後に説明をする実験結果からもわかるように、実施例8の米粒の多くが付着した低蛋白質インディカ揚げ米であっても、炊飯をすると、米粒の付着はほとんど認められず、外観及び食感の優れた食味の低蛋白質炊飯米が得られることがわかった。 As can be seen from the results in Table 18, it was found that when the frying treatment was performed at a low temperature of 130 ° C., the rice grains did not adhere when the soaking treatment was performed rather than when the soaking treatment was not performed. However, the low protein Indica fried rice to which many of the rice grains of Example 8 adhered was also adhered to such an extent that the adhesion of the rice grains could be loosened when a physical force was applied. Further, as can be seen from the experimental results to be described later, even when the low protein Indica fried rice to which many of the rice grains of Example 8 were adhered, when rice was cooked, the adhesion of the rice grains was hardly observed, and the appearance and It was found that a low-protein cooked rice with an excellent texture was obtained.
<炊飯米の官能評価>
 実施例5の低蛋白質インディカ揚げ米、実施例6の低蛋白質ジャポニカ揚げ米、実施例7の低蛋白質インディカ揚げ米、及び実施例8の低蛋白質インディカ揚げ米(浸漬処理なし)それぞれを、炊飯器(三菱IHジャー炊飯器NJ-KH10S形、三菱電機ホーム機器(株)製)で炊飯し、炊飯米を作った。炊飯方法は、鈴木らの方法(日本栄養・食糧学会誌36(5),389-392,1983)を参考に行った。炊飯器に水を200mL入れ、米10gに対し、水10gを入れた金属製プリンカップをその釜に入れ、「白米、お急ぎ」のモードで炊飯を行い、炊飯米を得た。得られた炊飯米について、外観、やわらかさ、コク、及びおいしさ(好み)について、以下の官能評価基準で官能評価を行った。
<炊飯米の官能評価基準>
〔外観(1)〕
A:米粒の形状を維持している。
B:全体の1/3~1/2の米粒が崩壊している。
C:米粒が崩壊し、米粒の形状を維持していない。
〔外観(2)〕
 実施例5、実施例7及び実施例8について
A:原料インディカ米(生米)と同程度の白さである。
B:原料インディカ米(生米)より白く違和感がある。
 実施例6について
A:原料ジャポニカ米(生米)と同程度の白さである。
B:原料ジャポニカ米(生米)より白く違和感がある。
〔やわらかさの程度〕
A:ちょうど良いやわらかさである。
B:Aよりやわらかい。
C:非常にやわらかい。
〔コク〕
A:味にコクがある。
B:味にコクがない(市販の低蛋白質米と同様)。
〔おいしさ又は好み〕
A:総合的に評価しておいしい、又は好みである。
B:総合的に評価して、AとCの中間である。
C:総合的に評価しておいしくない、又は好みでない。
<Sensory evaluation of cooked rice>
Each of the low protein indica fried rice of Example 5, the low protein Japonica fried rice of Example 6, the low protein Indica fried rice of Example 7, and the low protein Indica fried rice of Example 8 (without soaking treatment) was used as a rice cooker. (Mitsubishi IH Jar Rice Cooker NJ-KH10S, manufactured by Mitsubishi Electric Home Equipment Co., Ltd.) was used to cook rice. The rice cooking method was performed with reference to the method of Suzuki et al. (Journal of Japanese Society of Nutrition and Food 36 (5), 389-392, 1983). 200 mL of water was put into a rice cooker, and a metal pudding cup containing 10 g of water was put into the kettle for 10 g of rice, and cooked in the mode of “white rice, hurry” to obtain cooked rice. About the obtained cooked rice, about the external appearance, softness, richness, and deliciousness (preference), sensory evaluation was performed on the following sensory evaluation criteria.
<Sensory evaluation criteria for cooked rice>
[Appearance (1)]
A: The shape of rice grains is maintained.
B: 1/3 to 1/2 rice grains as a whole are disintegrated.
C: The rice grain has collapsed and the shape of the rice grain is not maintained.
[Appearance (2)]
About Example 5, Example 7, and Example 8 A: It is whiteness comparable as raw material indica rice (raw rice).
B: It is whiter and uncomfortable than the raw material Indica rice (raw rice).
About Example 6 A: It is whiteness comparable as raw material japonica rice (raw rice).
B: It is whiter and uncomfortable than raw material japonica rice (raw rice).
[Degree of softness]
A: Just the right softness.
B: Softer than A.
C: Very soft.
[Body]
A: There is a rich taste.
B: Rich in taste (similar to commercially available low protein rice).
[Taste or taste]
A: Overall evaluation is delicious or liking.
B: Overall evaluation is between A and C.
C: The evaluation is not comprehensive or unfavorable.
Figure JPOXMLDOC01-appb-T000019
Figure JPOXMLDOC01-appb-T000019
 これらの結果から、揚げ処理をする前に油への浸漬処理をしなかった実施例8では、数粒の米粒が付着したものが多く存在していたが、炊飯すると、米粒の付着はほとんど認められず、外観及び食感の優れた食味の低蛋白質炊飯米が得られることがわかった。また、揚げ処理をする前に浸漬処理をした実施例5~7は、浸漬処理をしない場合と同様、外観及び食感の優れた食味の低蛋白質米が得られることがわかった。
 ジャポニカ米についても、インディカ米と同様、外観及び食感の優れた食味の低蛋白質米が得られることがわかった。
From these results, in Example 8 where the immersion treatment in oil was not performed before the frying treatment, many rice grains adhered were present, but when rice was cooked, adhesion of the rice grains was almost recognized. In other words, it was found that low protein cooked rice with an excellent appearance and texture was obtained. In addition, it was found that Examples 5-7, which were soaked before the frying treatment, yielded a low-protein rice with an excellent appearance and texture, as in the case of no soaking treatment.
As for Japonica rice, it was found that low protein rice with excellent appearance and texture was obtained as in Indica rice.
≪油浸漬回数による水の除去状況の確認≫
 先に説明をした低蛋白質米の製造(4)で得られた水切り前の低蛋白質インディカ米を用いて、油浸漬処理による水の除去状況を確認した。
 まず、水切り前の低蛋白質インディカ米15gを金ザルに入れて水切りし、除去した水の量を測定した(測定値:3603μl)。次に、水切りをした低蛋白質インディカ米を、25℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))200mlを入れた容器に入れて5秒間浸漬した後、容器から金ザルを取り出し、油を切った。
 このとき使用した浸漬油を遠心管に入れ、遠心処理(条件:3000rpm、10分間)をして水を分離させた。遠心管の底にたまった水をマイクロピペットで定量し、その水の量を、浸漬回数1回の米から除去した水の量とした。続いて、油切をした米を、別の25℃の菜種油200mlを入れた容器に入れて再度5秒間浸漬した後、容器から金ザルを取り出し油を切った。このとき使用した浸漬油を遠心管に入れ、遠心処理(条件:3000rpm、10分間)をして水を分離させた。遠心管の底にたまった水をマイクロピペットで定量し、その水の量を、浸漬回数2回の米から除去した水の量とした。同様にして、菜種油への浸漬を計9回行い、各浸漬処理ごとに米から除去した水の量を定量した。除去した水の量を表20に示す。
≪Confirmation of water removal status by the number of oil immersions≫
Using the low protein Indica rice before draining obtained in the production of low protein rice (4) described above, the water removal status by the oil immersion treatment was confirmed.
First, 15 g of low protein Indica rice before draining was poured into a gold monkey and drained, and the amount of removed water was measured (measured value: 3603 μl). Next, drained low protein Indica rice is put into a container containing 200 ml of rapeseed oil (trade name: Nisshin Canola Oil, Nisshin Oilio Group Co., Ltd.) at 25 ° C. and immersed for 5 seconds. The gold colander was taken out from and drained.
The immersion oil used at this time was put into a centrifuge tube, and centrifuged (condition: 3000 rpm, 10 minutes) to separate water. Water accumulated in the bottom of the centrifuge tube was quantified with a micropipette, and the amount of water was defined as the amount of water removed from the rice that had been immersed once. Subsequently, the drained rice was put in another container containing 200 ml of rapeseed oil at 25 ° C. and immersed again for 5 seconds, and then the gold monkey was taken out from the container and drained. The immersion oil used at this time was put into a centrifuge tube, and centrifuged (condition: 3000 rpm, 10 minutes) to separate water. Water accumulated at the bottom of the centrifuge tube was quantified with a micropipette, and the amount of the water was taken as the amount of water removed from the rice that had been immersed twice. Similarly, the immersion in rapeseed oil was performed a total of 9 times, and the amount of water removed from the rice for each immersion treatment was quantified. The amount of water removed is shown in Table 20.
 得られた各サンプル米を、130℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))で240秒間揚げ、低蛋白質インディカ揚げ米を得た。
<米粒の付着状態の観察>
 得られた低蛋白質インディカ揚げ米の米粒の付着状態を目視で観察し、実施例5~8と同じ評価基準で評価した。結果を表20に示す。
Each sample rice obtained was fried for 240 seconds with rapeseed oil (trade name: Nisshin Canola Oil, manufactured by Nisshin Oillio Group Co., Ltd.) at 130 ° C. to obtain fried rice with low protein Indica.
<Observation of rice grain adhesion>
The attached state of the rice grains of the obtained low protein Indica fried rice was visually observed and evaluated according to the same evaluation criteria as in Examples 5-8. The results are shown in Table 20.
Figure JPOXMLDOC01-appb-T000020
Figure JPOXMLDOC01-appb-T000020
 表20の結果から、水切りした米について5秒間の油浸漬を1回行えば、米の付着水の大部分が除去でき、揚げ処理後の米粒の付着も減少することがわかった。また、水切りした米について5秒間の油浸漬を2回以上行えば、揚げ処理後の米粒の付着がないことがわかった。水切りした米について、5秒間の油浸漬を6回以上行った場合、除去される水がほとんどなかったことから、5秒間の油浸漬を5回行うことで、米の付着水のほとんどが除去されたと考えられる。 From the results shown in Table 20, it was found that, when the oil was drained once for 5 seconds, most of the water adhering to the rice could be removed and the adhesion of the rice grains after frying was reduced. In addition, it was found that if the rice that had been drained was immersed in oil for 5 seconds twice or more, there was no adhesion of rice grains after frying. When drained rice was immersed in oil for 5 seconds 6 times or more, there was almost no water to be removed. By soaking oil for 5 seconds 5 times, most of the adhered water in the rice was removed. It is thought.
≪低蛋白質米の製造(5)≫
 原料の生米として、インディカ米を使用して低蛋白質蒸し米、及びその乾燥品を製造した。
 まず、pH4.0の緩衝液に、蛋白質分解酵素(プロテアーゼM、天野エンザイム(株)製)を0.5質量%溶解し、反応液を調製した。インディカ米15gに反応液75mlを添加し、42℃で24時間スターラー撹拌をしながら酵素処理を行った。酵素処理した米に、pH4.0の緩衝液80mlを添加し、10分間スターラーで撹拌し、洗浄をした。洗浄した米を金ザルに入れて約30分間水切りをした後、以下の処理を行うことによりインディカ米の低蛋白質蒸し米及びその乾燥品を製造した。
[実施例9]
(油浸漬処理後、蒸し処理、乾燥)
 25℃の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))75mlを入れた容器を用意し、水切りしたインディカ低蛋白質米(15g)が入った金ザルを、菜種油が入った容器に入れて米を油に5秒間浸漬した後、容器から金ザルを取り出し、再び金ザルを容器に入れることで、再度米を油に5秒間浸漬させた。この浸漬操作を繰り返し行い、5秒間の浸漬を計10回行った。この操作により、米に付着していた水が除去され、油の入った容器の底に水滴がたまっていた。浸漬処理した米を、金ザルで油切りをした後、市販の蒸し器で5分間蒸し処理をし、低蛋白質インディカ蒸し米を得た。得られた低蛋白質インディカ蒸し米を、乾燥機(製品名:DN-62、ヤマト科学株式会社製)を用いて65℃で2時間乾燥し、低蛋白質インディカ蒸し米の乾燥品(水分11.4質量%)を得た。乾燥米は、水分が少ないため、生のお米のように硬い米粒であった。
[比較例5]
(油浸漬処理せずに蒸し処理、乾燥)
 浸漬処理の有無の効果を確認するために、水切りしたインディカ米を、油の浸漬処理をせずに、市販の蒸し器で5分間蒸し処理をし、低蛋白質インディカ蒸し米を得た。得られた低蛋白質インディカ蒸し米を、65℃で2時間乾燥し、低蛋白質インディカ蒸し米の乾燥品(水分11.3質量%)を得た。乾燥米は、水分が少ないため、生のお米のように硬い米粒であった。
≪Production of low protein rice (5) ≫
Low-protein steamed rice and its dried product were produced using indica rice as raw raw rice.
First, 0.5% by mass of a protease (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer solution to prepare a reaction solution. 75 ml of the reaction solution was added to 15 g of Indica rice, and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 24 hours. 80 ml of pH 4.0 buffer solution was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed. The washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein steamed rice of Indica rice and its dried product.
[Example 9]
(After oil immersion treatment, steaming treatment, drying)
Prepare a container containing 75 ml of rapeseed oil (trade name: Nisshin Canola Oil, Nissin Oilio Group Co., Ltd.) at 25 ° C., and rapeseed oil containing gold monkey containing 15 g of indica low protein rice drained. After putting the rice in the container and immersing the rice in oil for 5 seconds, the gold colander was taken out of the container, and the gold colander was again put in the container, so that the rice was again immersed in the oil for 5 seconds. This dipping operation was repeated, and dipping for 5 seconds was performed 10 times in total. By this operation, the water adhering to the rice was removed, and water droplets had accumulated on the bottom of the container filled with oil. The soaked rice was degreased with a gold colander and then steamed with a commercially available steamer for 5 minutes to obtain low protein Indica steamed rice. The obtained low protein Indica steamed rice was dried at 65 ° C. for 2 hours using a dryer (product name: DN-62, manufactured by Yamato Kagaku Co., Ltd.). Mass%). Dry rice was a hard rice grain like raw rice because of its low water content.
[Comparative Example 5]
(Steaming without oil immersion, drying)
In order to confirm the effect of the presence or absence of the soaking treatment, the drained indica rice was steamed for 5 minutes with a commercially available steamer without the oil soaking treatment, and low protein Indica steamed rice was obtained. The obtained low protein Indica steamed rice was dried at 65 ° C. for 2 hours to obtain a dried product of low protein Indica steamed rice (moisture 11.3 mass%). Dry rice was a hard rice grain like raw rice because of its low water content.
<米粒の付着状態の観察>
 得られた低蛋白質インディカ蒸し米の乾燥品の米粒の付着状態を目視で観察し、以下の評価基準で評価した。結果を表21に示す。
A:米1粒1粒がばらけており、米粒同士の付着がない、又はほとんどない。
B:数粒の米粒が付着したものが少し存在している。
C:数粒の米粒が付着したものが多く存在している。
D:米粒から澱粉が溶出し、ほとんどの米粒が付着して塊状となっている。
<Observation of rice grain adhesion>
The attached state of the rice grains of the dried low protein Indica steamed rice obtained was visually observed and evaluated according to the following evaluation criteria. The results are shown in Table 21.
A: One grain of rice is scattered, and there is little or no adhesion between rice grains.
B: Some rice grains to which several grains are adhered are present.
C: Many rice grains to which several grains are attached are present.
D: Starch is eluted from the rice grains, and most of the rice grains are attached to form a lump.
Figure JPOXMLDOC01-appb-T000021
Figure JPOXMLDOC01-appb-T000021
 表21の結果からわかるように、低蛋白質蒸し米は、油の浸漬処理を行わないと、数粒の米粒が付着したものが多く存在していたが、油の浸漬処理を行うと、米粒同士の付着がないものが得られることがわかった。
 このことから、低蛋白質蒸し米については、酵素処理後、蒸す前に、油で浸漬処理をすることが有効であることがわかった。
As can be seen from the results in Table 21, the low-protein steamed rice had many rice grains adhering to it without oil soaking treatment. It was found that a product having no adhesion was obtained.
From this, it was found that for low protein steamed rice, it is effective to dip the oil after the enzyme treatment and before steaming.
<炊飯米の官能評価>
 実施例9の低蛋白質インディカ蒸し米の乾燥品、及び比較例5の低蛋白質インディカ蒸し米の乾燥品を、炊飯器(三菱IHジャー炊飯器NJ-KH10S形、三菱電機ホーム機器(株)製)で炊飯し、炊飯米を作った。炊飯方法は、鈴木らの方法(日本栄養・食糧学会誌36(5),389-392,1983)を参考に行った。炊飯器に水を200mL入れ、米10gに対し、水10gを入れた金属製プリンカップをその釜に入れ、「白米、お急ぎ」のモードで炊飯を行い、炊飯米を得た。得られた炊飯米の外観、やわらかさ、コク、おいしさ(好み)について、以下の官能評価基準で官能評価を行った。結果を表22に示す。
〔外観(1)〕
A:米粒の形状を維持している。
B:全体の1/3~1/2の米粒が崩壊している。
C:米粒が崩壊し、米粒の形状を維持していない。
〔外観(2)〕
A:原料インディカ米(生米)と同程度の白さである。
B:原料インディカ米(生米)より白く違和感がある。
〔やわらかさの程度〕
A:ちょうど良いやわらかさである。
B:Aよりやわらかい。
C:非常にやわらかい。
〔コク〕
A:味にコクがある。
B:味にコクがない(市販の低蛋白質米と同様)。
〔おいしさ又は好み〕
A:総合的に評価しておいしい、又は好みである。
B:総合的に評価して、AとCの中間である。
C:総合的に評価しておいしくない、又は好みでない。
<Sensory evaluation of cooked rice>
The dried product of steamed low protein Indica rice of Example 9 and the dried product of steamed low protein Indica rice of Comparative Example 5 were cooked (Mitsubishi IH Jar Rice Cooker NJ-KH10S, manufactured by Mitsubishi Electric Home Equipment Co., Ltd.). I cooked rice and made cooked rice. The rice cooking method was performed with reference to the method of Suzuki et al. (Journal of Japanese Society of Nutrition and Food 36 (5), 389-392, 1983). 200 mL of water was put into a rice cooker, and a metal pudding cup containing 10 g of water was put into the kettle for 10 g of rice, and cooked in the mode of “white rice, hurry” to obtain cooked rice. The appearance, softness, richness, and taste (preference) of the obtained cooked rice were subjected to sensory evaluation according to the following sensory evaluation criteria. The results are shown in Table 22.
[Appearance (1)]
A: The shape of rice grains is maintained.
B: 1/3 to 1/2 rice grains as a whole are disintegrated.
C: The rice grain has collapsed and the shape of the rice grain is not maintained.
[Appearance (2)]
A: It is whiteness comparable to raw material indica rice (raw rice).
B: It is whiter and uncomfortable than the raw material Indica rice (raw rice).
[Degree of softness]
A: Just the right softness.
B: Softer than A.
C: Very soft.
[Body]
A: There is a rich taste.
B: Rich in taste (similar to commercially available low protein rice).
[Taste or taste]
A: Overall evaluation is delicious or liking.
B: Overall evaluation is between A and C.
C: The evaluation is not comprehensive or unfavorable.
Figure JPOXMLDOC01-appb-T000022
Figure JPOXMLDOC01-appb-T000022
 表22の結果からわかるように、低蛋白質蒸し米の乾燥品の炊飯米は、油の浸漬処理を行うことにより、米粒同士の付着がないものが得られることがわかった。
 このことから、低蛋白質蒸し米の乾燥品については、酵素処理後、蒸す前に、油で浸漬処理をすることが有効であることがわかった。
As can be seen from the results in Table 22, it was found that the rice cooked rice, which is a dried product of low protein steamed rice, can be obtained in which the rice grains do not adhere to each other by performing an oil immersion treatment.
From this, it was found that it is effective to dip the low-protein steamed rice with the oil after the enzyme treatment and before the steaming.
≪低蛋白質米の製造(6)≫
 原料の生米として、インディカ米を使用して低蛋白質蒸し焼き米、およびその乾燥品を製造した。
 まず、pH4.0の緩衝液に、蛋白質分解酵素(プロテアーゼM、天野エンザイム(株)製)を0.5質量%溶解し、反応液を調製した。インディカ米15gに反応液75mlを添加し、42℃で24時間スターラー撹拌をしながら酵素処理を行った。酵素処理した米に、pH4.0の緩衝液80mlを添加し、10分間スターラーで撹拌し、洗浄をした。洗浄した米を金ザルに入れて約30分間水切りをした後、以下の処理を行うことによりインディカ米の低蛋白質蒸し焼き米及びその乾燥品を製造した。
[実施例10~16]
(油含有浸漬水に浸漬処理後、蒸し焼き処理、乾燥)
 表23に示す量の菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製))及び水(以下、油含有浸漬水という)を入れた容器を用意し、水切りした低蛋白質インディカ米が入った金ザルを、油含有浸漬水が入った容器に入れて米を油含有浸漬水に浸漬した後、容器から金ザルを取り出し、再び金ザルを容器に入れることで、再度米を油含有浸漬水に浸漬後、容器から金ザルを取り出し水切りをした。このようにして2回の浸漬処理をした低蛋白質インディカ米を、120℃のスチームオーブンで10分間蒸し焼きし、インディカ米をひっくり返してさらに10分間蒸し焼きし、低蛋白質蒸し焼き米を得た。得られた低蛋白質蒸し焼き米を自然乾燥することで、低蛋白質蒸し焼き米の乾燥品を得た。
≪Production of low protein rice (6) ≫
As raw raw rice, indica rice was used to produce low protein steamed baked rice and its dried product.
First, 0.5% by mass of a protease (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer solution to prepare a reaction solution. 75 ml of the reaction solution was added to 15 g of Indica rice, and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 24 hours. 80 ml of pH 4.0 buffer solution was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed. The washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein steamed rice of Indica rice and its dried product.
[Examples 10 to 16]
(After immersion in oil-containing immersion water, steamed and dried)
Low protein indica prepared by preparing a container containing rapeseed oil (trade name: Nisshin Canola Oil, Nisshin Oillio Group Co., Ltd.) and water (hereinafter referred to as oil-containing immersion water) in the amount shown in Table 23 and draining. After putting the gold monkey containing rice in a container containing oil-containing immersion water and immersing the rice in oil-containing immersion water, the gold monkey is removed from the container, and the gold monkey is put into the container again, so that the rice is added again. After immersion in oil-containing immersion water, the gold monkey was removed from the container and drained. The low protein Indica rice that had been soaked twice in this manner was steamed and baked in a steam oven at 120 ° C. for 10 minutes, and the Indica rice was turned over and steamed for another 10 minutes to obtain low protein steamed rice. The obtained low protein steamed baked rice was naturally dried to obtain a dried product of low protein steamed baked rice.
<外観観察>
 得られた低蛋白質蒸し焼き米の乾燥品の外観を目視で観察し、米粒の付着状態及び未糊化米の程度について、以下の評価基準で評価をした。結果を表23に示す。
〔米粒の付着状態〕
無し:米1粒1粒がばらけており、米粒同士の付着がない、又はほとんどない。
有り:数粒の米粒が付着したものが存在している。
〔未糊化米の程度〕
無し:原料(生米)と同程度の白さである。
有り:原料(生米)より白く違和感がある。
<Appearance observation>
The appearance of the dried product of the obtained low protein steamed baked rice was visually observed, and the adhesion state of the rice grains and the degree of ungelatinized rice were evaluated according to the following evaluation criteria. The results are shown in Table 23.
[Adhesion state of rice grains]
None: One grain of rice is scattered, and there is little or no adhesion between rice grains.
Yes: Some rice grains are attached.
[Degree of ungelatinized rice]
None: Whiteness similar to that of the raw material (raw rice).
Yes: Whiter than the raw material (raw rice).
 表23の米粒の付着状態の観察結果からわかるように、低蛋白質蒸し焼き米は、酵素処理後、蒸し焼きをする前に、油含有浸漬水に浸漬処理をすると、米が付着せず、未糊化米も発生しないことがわかった。 As can be seen from the observation results of the adhesion state of rice grains in Table 23, the low protein steamed baked rice is not gelatinized when it is immersed in oil-containing immersion water after the enzyme treatment and before steaming. It turns out that rice is not generated either.
<炊飯米の官能評価>
 実施例10~16で得られたインディカ米の低蛋白質蒸し焼き米の乾燥品を、炊飯器(三菱IHジャー炊飯器NJ-KH10S形、三菱電機ホーム機器(株)製)を用いて実施例9の炊飯米と同じ方法で炊飯し、炊飯米を得た。得られた炊飯米について、以下の官能評価基準で官能評価を行った。結果を表23に示す。
〔炊飯米の官能評価基準〕
A:炊飯米には、つや、透明感、粘り、こくがあり、インディカ米の炊飯米と同程度の食感。
B:こくはあるが、つや、透明感、粘りがない。
C:つや、透明感がなく、こくもなく、パサパサした食感。
<Sensory evaluation of cooked rice>
Using the rice cooker (Mitsubishi IH Jar Rice Cooker NJ-KH10S, manufactured by Mitsubishi Electric Home Equipment Co., Ltd.), the dried product of low protein steamed baked rice of Indica rice obtained in Examples 10 to 16 was used. Cooked rice was cooked in the same way as cooked rice to obtain cooked rice. About the obtained cooked rice, sensory evaluation was performed on the following sensory evaluation criteria. The results are shown in Table 23.
[Sensory evaluation criteria for cooked rice]
A: Cooked rice has gloss, transparency, stickiness, and richness, and has the same texture as cooked rice of Indica rice.
B: There is a lot, but there is no gloss, transparency, or stickiness.
C: Glossy, non-transparent, crisp and crunchy texture.
Figure JPOXMLDOC01-appb-T000023
Figure JPOXMLDOC01-appb-T000023
≪低蛋白質米の製造(7)≫
 原料の生米として、インディカ米を使用して低蛋白質蒸し焼き米、及びその乾燥品を製造した。
 まず、pH4.0の緩衝液に、蛋白質分解酵素(プロテアーゼM、天野エンザイム(株)製)を0.5質量%溶解し、反応液を調製した。表24に示す量のインディカ米に反応液を添加し、42℃で24時間スターラー撹拌をしながら酵素処理を行った。酵素処理した米に、pH4.0の緩衝液を添加し、10分間スターラーで撹拌し、洗浄をした。洗浄した米を金ザルに入れて約30分間水切りをした後、以下の処理を行うことによりインディカ米の低蛋白質蒸し焼き米、及びその乾燥品を製造した。
[実施例17~27]
(油含有浸漬水に浸漬処理後、蒸し焼き処理、乾燥)
 表24又は表25に示す条件で、実施例10と同様にして、低蛋白質蒸し焼き米、及びその乾燥品の製造を行った。実施例25で得られた低蛋白質蒸し焼き米の乾燥品中の蛋白質含量をケルダール法で測定すると、その値は0.81質量%であったことから、今回の処理により低蛋白質米が製造されていることが確認できた。
≪Production of low protein rice (7) ≫
As raw raw rice, indica rice was used to produce low protein steamed baked rice and its dried product.
First, 0.5% by mass of a protease (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer solution to prepare a reaction solution. The reaction solution was added to the amount of Indica rice shown in Table 24, and the enzyme treatment was performed while stirring with a stirrer at 42 ° C. for 24 hours. A pH 4.0 buffer was added to the enzyme-treated rice, and the mixture was stirred for 10 minutes with a stirrer and washed. The washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein steamed rice of Indica rice and its dried product.
[Examples 17 to 27]
(After immersion in oil-containing immersion water, steamed and dried)
Under the conditions shown in Table 24 or 25, low protein steamed baked rice and its dried product were produced in the same manner as in Example 10. When the protein content in the dried product of the low protein steamed rice obtained in Example 25 was measured by the Kjeldahl method, the value was 0.81% by mass. Thus, the low protein rice was produced by this treatment. It was confirmed that
<外観観察>
 得られた低蛋白質蒸し焼き米の乾燥品の外観を目視で観察し、米粒の付着状態及び未糊化米の程度について、以下の評価基準で評価をした。結果を表24又は25に示す。
〔米粒の付着状態〕
無し:米1粒1粒がばらけており、米粒同士の付着がない、又はほとんどない。
有り:数粒の米粒が付着したものが存在している。
〔未糊化米の程度〕
無し:原料(生米)と同程度の白さである。
有り:原料(生米)より白く違和感がある。
<Appearance observation>
The appearance of the dried product of the obtained low protein steamed baked rice was visually observed, and the adhesion state of the rice grains and the degree of ungelatinized rice were evaluated according to the following evaluation criteria. The results are shown in Table 24 or 25.
[Adhesion state of rice grains]
None: One grain of rice is scattered, and there is little or no adhesion between rice grains.
Yes: Some rice grains are attached.
[Degree of ungelatinized rice]
None: Whiteness similar to that of the raw material (raw rice).
Yes: Whiter than the raw material (raw rice).
 表24及び表25の米粒の付着状態の観察結果からわかるように、低蛋白質蒸し焼き米は、酵素処理後、蒸し焼きをする前に、油含有浸漬水に浸漬処理をすると、米が付着せず、未糊化米も発生しないことがわかった。 As can be seen from the observation results of the adhesion state of the rice grains in Table 24 and Table 25, when the low protein steamed baked rice is immersed in oil-containing immersion water after the enzyme treatment and before steaming, the rice does not adhere, It was found that ungelatinized rice was not generated.
<炊飯米の官能評価>
 実施例17~27で得られたインディカ米の低蛋白質蒸し焼き米の乾燥品を、炊飯器(三菱IHジャー炊飯器NJ-KH10S形、三菱電機ホーム機器(株)製)を用いて実施例9の炊飯米と同じ方法で炊飯し、炊飯米を得た。得られた炊飯米について、以下の官能評価基準で官能評価を行った。結果を表24又は25に示す。
〔炊飯米の官能評価基準〕
A:炊飯米には、つや、透明感、粘り、こくがあり、インディカ米の炊飯米と同程度の食感。
B:こくはあるが、つや、透明感、粘りがない。
C:つや、透明感がなく、こくもなく、パサパサした食感。
<Sensory evaluation of cooked rice>
Using the rice cooker (Mitsubishi IH Jar Rice Cooker NJ-KH10S, manufactured by Mitsubishi Electric Home Equipment Co., Ltd.), the dried product of low protein steamed baked rice of Indica rice obtained in Examples 17 to 27 was used. Cooked rice was cooked in the same way as cooked rice to obtain cooked rice. About the obtained cooked rice, sensory evaluation was performed on the following sensory evaluation criteria. The results are shown in Table 24 or 25.
[Sensory evaluation criteria for cooked rice]
A: Cooked rice has gloss, transparency, stickiness, and richness, and has the same texture as cooked rice of Indica rice.
B: There is a lot, but there is no gloss, transparency, or stickiness
C: Glossy, non-transparent, crisp and crunchy texture.
Figure JPOXMLDOC01-appb-T000024
Figure JPOXMLDOC01-appb-T000024
Figure JPOXMLDOC01-appb-T000025
Figure JPOXMLDOC01-appb-T000025
≪低蛋白質米の製造(8)≫
 原料の生米としてインディカ米を使用して低蛋白質蒸し焼き米、及びその乾燥品を製造した。
 まず、pH4.0の緩衝液に、蛋白質分解酵素(プロテアーゼM、天野エンザイム(株)製)0.5質量%を溶解し、反応液を調製した。前記インディカ米(生米)1200gに前記反応液4.0Lを添加し、40℃で24時間スターラー撹拌をしながら酵素処理を行った。酵素処理した米に、水4Lを添加し、10分間スターラーで撹拌し、洗浄をした。洗浄した米を金ザルに入れて約30分間水切りをした後、以下の処理を行うことによりインディカ米の低蛋白質蒸し焼き米及びその乾燥品を製造した。
≪Production of low protein rice (8) ≫
Low protein steamed rice and its dried product were produced using indica rice as raw raw rice.
First, 0.5 mass% of proteolytic enzyme (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer to prepare a reaction solution. 4.0 L of the reaction solution was added to 1200 g of the indica rice (raw rice), and the enzyme treatment was performed while stirring with a stirrer at 40 ° C. for 24 hours. 4 L of water was added to the enzyme-treated rice and stirred with a stirrer for 10 minutes for washing. The washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein steamed rice of Indica rice and its dried product.
[実施例28]
(乳化浸漬液の製造)
 表26に示す配合にて乳化浸漬液を以下の方法で製造した。植物油(商品名:日清キャノーラ油、日清オイリオグループ(株)製)にペースト状レシチン(商品名:レシチンDX、日清オイリオグループ(株)製)を添加し、湯浴で80℃に加熱することで、レシチンを植物油に溶かし、レシチン含有植物油を得た。常温の水に、室温に戻した前記レシチン含有植物油を添加し、ミキサー(装置名:VITA-PREP3、VITA-MIX社(米国)製)を用いて、1分間撹拌して乳化をすることで、乳化浸漬液を得た。
[Example 28]
(Manufacture of emulsified immersion liquid)
An emulsified immersion liquid was prepared by the following method with the formulation shown in Table 26. Paste lecithin (product name: lecithin DX, manufactured by Nisshin Oillio Group) is added to vegetable oil (product name: Nisshin Canola Oil, manufactured by Nisshin Oillio Group Co., Ltd.) and heated to 80 ° C in a hot water bath. As a result, lecithin was dissolved in the vegetable oil to obtain a lecithin-containing vegetable oil. By adding the lecithin-containing vegetable oil returned to room temperature to room temperature water, and emulsifying by stirring for 1 minute using a mixer (device name: VITA-PREP3, manufactured by VITA-MIX (USA)), An emulsified immersion liquid was obtained.
Figure JPOXMLDOC01-appb-T000026
Figure JPOXMLDOC01-appb-T000026
(インディカ米の乳化浸漬液による浸漬処理後、蒸し焼き、乾燥)
 前記乳化浸漬液2Lを入れたステンレストレーに、酵素処理し水切りしたインディカ米が入った金ザルを入れ、前記インディカ米を乳化浸漬液に5分間浸漬した。乳化浸漬液から前記インディカ米が入った金ザルを取出し、乳化浸漬液を良く切った。その後、インディカ米を120℃のスチームオーブンで10分間蒸し焼きし、インディカ米をひっくり返してさらに10分間蒸し焼きし、低蛋白質蒸し焼き米を得た。その後、低蛋白質蒸し焼き米を70℃で2時間乾燥させ、低蛋白質蒸し焼き米の乾燥品を得た。
(After soaking with indica rice emulsified soaking solution, steamed and dried)
A gold monkey containing indica rice that had been treated with an enzyme and drained was placed in a stainless steel tray containing 2 L of the emulsified soaking liquid, and the indica rice was soaked in the emulsifying soaking liquid for 5 minutes. The gold monkey containing the indica rice was taken out from the emulsified soaking solution, and the emulsifying soaking solution was cut well. Thereafter, the indica rice was steamed and baked in a steam oven at 120 ° C. for 10 minutes, and the indica rice was turned over and steamed for another 10 minutes to obtain low protein steamed rice. Thereafter, the low protein steamed baked rice was dried at 70 ° C. for 2 hours to obtain a dried product of low protein steamed baked rice.
≪低蛋白質米の製造(9)≫
 原料の生米としてインディカ米を使用して低蛋白質米を製造した。
 まず、pH4.0の緩衝液に、蛋白質分解酵素(プロテアーゼM、天野エンザイム(株)製)0.5質量%を溶解し、反応液を調製した。前記インディカ米(生米)1100gに前記反応液4.0Lを添加し、40℃で20時間スターラー撹拌をしながら酵素処理を行った。酵素処理した米に、水4Lを添加し、10分間スターラーで撹拌し、洗浄をした。洗浄した米を金ザルに入れて約30分間水切りをした後、以下の処理を行うことによりインディカ米の低蛋白質蒸し焼き米及びその乾燥品を製造した。
≪Production of low protein rice (9) ≫
Low protein rice was produced using Indica rice as raw raw rice.
First, 0.5 mass% of proteolytic enzyme (Protease M, manufactured by Amano Enzyme Co., Ltd.) was dissolved in a pH 4.0 buffer to prepare a reaction solution. 4.0 L of the reaction solution was added to 1100 g of the Indica rice (raw rice), and the enzyme treatment was performed while stirring with a stirrer at 40 ° C. for 20 hours. 4 L of water was added to the enzyme-treated rice and stirred with a stirrer for 10 minutes for washing. The washed rice was put into a gold colander, drained for about 30 minutes, and then subjected to the following treatment to produce low protein steamed rice of Indica rice and its dried product.
[実施例29]
(乳化浸漬液の製造)
 表27に示す配合にて乳化浸漬液を以下の方法で製造した。植物油(商品名:日清キャノーラ油、日清オイリオグループ(株)製)にペースト状レシチン(商品名:レシチンDX、日清オイリオグループ(株)製)を添加し、湯浴で80℃に加熱することで、レシチンを植物油に溶かし、レシチン含有植物油を得た。常温の水に、室温に戻した前記レシチン含有植物油を添加し、ミキサー(装置名:VITA-PREP3、VITA-MIX社(米国)製)を用いて、1分間撹拌して乳化をすることで、乳化浸漬液を得た。
[Example 29]
(Manufacture of emulsified immersion liquid)
An emulsified immersion liquid was produced by the following method using the formulation shown in Table 27. Paste lecithin (product name: lecithin DX, manufactured by Nisshin Oillio Group) is added to vegetable oil (product name: Nisshin Canola Oil, manufactured by Nisshin Oillio Group Co., Ltd.) and heated to 80 ° C in a hot water bath. As a result, lecithin was dissolved in the vegetable oil to obtain a lecithin-containing vegetable oil. By adding the lecithin-containing vegetable oil returned to room temperature to room temperature water, and emulsifying by stirring for 1 minute using a mixer (device name: VITA-PREP3, manufactured by VITA-MIX (USA)), An emulsified immersion liquid was obtained.
Figure JPOXMLDOC01-appb-T000027
Figure JPOXMLDOC01-appb-T000027
(インディカ米の乳化浸漬液による浸漬処理後、蒸し焼き、乾燥)
 前記乳化浸漬液2Lを入れたステンレストレーに、酵素処理し水切りしたインディカ米が入った金ザルを入れ、前記インディカ米を乳化浸漬液に5分間浸漬した。乳化浸漬液から前記インディカ米が入った金ザルを取出し、乳化浸漬液を良く切った。その後、インディカ米を120℃のスチームオーブンで10分間蒸し焼きし、低蛋白質蒸し焼き米を得た。その後、低蛋白質蒸し焼き米を70℃で2時間乾燥させ、低蛋白質蒸し焼き米の乾燥品を得た。
(After soaking with indica rice emulsified soaking solution, steamed and dried)
A gold monkey containing indica rice that had been treated with an enzyme and drained was placed in a stainless steel tray containing 2 L of the emulsified soaking liquid, and the indica rice was soaked in the emulsifying soaking liquid for 5 minutes. The gold monkey containing the indica rice was taken out from the emulsified soaking solution, and the emulsifying soaking solution was cut well. Then, indica rice was steamed and baked in a steam oven at 120 ° C. for 10 minutes to obtain low protein steamed rice. Thereafter, the low protein steamed baked rice was dried at 70 ° C. for 2 hours to obtain a dried product of low protein steamed baked rice.
<米の水分含量の測定>
 実施例28及び29の米の水分含量を、実施例1と同様の方法で測定した。その結果を表28に示す。
<Measurement of water content of rice>
The water content of the rice of Examples 28 and 29 was measured in the same manner as in Example 1. The results are shown in Table 28.
<米の蛋白質含量の測定>
 原料のインディカ米並びに実施例28及び29で得られた低蛋白質蒸し焼き米の乾燥品中の蛋白質含量を、ケルダール法で測定した。その結果を表28に示す。
<Measurement of protein content in rice>
The protein content in the dried product of the raw material Indica rice and the low protein steamed rice obtained in Examples 28 and 29 was measured by the Kjeldahl method. The results are shown in Table 28.
<炊飯米の官能評価>
 実施例28及び29で得られた低蛋白質蒸し焼き米の乾燥品を実施例1と同じ方法で炊飯し、実施例1の「外観(1)」及び「おいしさ又は好み」と同じ評価基準で官能評価を行った。その結果を表28に示す。
<Sensory evaluation of cooked rice>
The low-protein steamed baked rice obtained in Examples 28 and 29 was cooked in the same manner as in Example 1, and sensory with the same evaluation criteria as “Appearance (1)” and “Taste or Preference” in Example 1. Evaluation was performed. The results are shown in Table 28.
Figure JPOXMLDOC01-appb-T000028
Figure JPOXMLDOC01-appb-T000028
 生米を蛋白質分解処理、洗浄することにより得られた低蛋白質米を、蒸し焼きにする前に、油を乳化した乳化液に浸漬することで、低蛋白質米の固化及び炊飯後の味にさらに良い影響を与えることがわかった。 The low-protein rice obtained by proteolytic treatment and washing of raw rice is immersed in an emulsion emulsified with oil before steaming and baking. It was found to have an effect.
 本発明は、流通時及び炊飯時に米粒が崩壊しにくく、炊飯時に米粒の付着が少ない低蛋白質米の製造方法を提供することができる。また、本発明の製造方法によれば、味にコクがあり、かつエネルギーが高い低蛋白質米を製造することができるので、食品の製造の分野において好適に利用できる。 The present invention can provide a method for producing low-protein rice that is less likely to disintegrate during distribution and rice cooking and has less adhesion of rice grains during rice cooking. Further, according to the production method of the present invention, low protein rice having a rich taste and high energy can be produced, and therefore it can be suitably used in the field of food production.

Claims (15)

  1.  生米を蛋白質分解処理し、得られた処理米を洗浄した後、米へ油を付着させること、及び油が付着した前記米を糊化することを含む、低蛋白質米の製造方法。 A method for producing low protein rice, comprising subjecting raw rice to proteolytic treatment, washing the resulting treated rice, and attaching oil to the rice, and gelatinizing the rice to which the oil has adhered.
  2.  前記米へ油を付着させることが、油に米を浸漬させること、油を含有する油含有浸漬水に米を浸漬させること、油含有乳化液浸漬液に米を浸漬させること、及び米に油を塗布した後に水で洗浄することからなる群より選ばれる少なくとも1の工程である、請求項1に記載の低蛋白質米の製造方法。 Attaching the oil to the rice, immersing the rice in the oil, immersing the rice in the oil-containing immersion water containing the oil, immersing the rice in the oil-containing emulsion immersion liquid, and the oil in the rice The method for producing low protein rice according to claim 1, wherein the method is at least one step selected from the group consisting of washing with water after coating.
  3.  前記米を糊化することが、米を油で揚げること、米を蒸し処理すること、及び米をレトルト処理することからなる群より選ばれる少なくとも1の工程である、請求項1又は2に記載の低蛋白質米の製造方法。 The gelatinization of the rice is at least one step selected from the group consisting of frying rice with oil, steaming the rice, and retorting the rice. Of low protein rice.
  4.  前記米へ油を付着させること、及び米を糊化することを、米を油で揚げることにより行う、請求項1に記載の低蛋白質米の製造方法。 The method for producing low-protein rice according to claim 1, wherein the oil is attached to the rice and the rice is gelatinized by frying the rice with oil.
  5.  前記米を糊化することの後に、さらに、米を乾燥させることを含む、請求項1又は2に記載の低蛋白質米の製造方法。 The method for producing low-protein rice according to claim 1 or 2, further comprising drying the rice after gelatinizing the rice.
  6.  請求項1~5のいずれか1項に記載の製造方法で得られる低蛋白質米を調理して得られる食品。 A food obtained by cooking low-protein rice obtained by the production method according to any one of claims 1 to 5.
  7.  生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げることを特徴とする低蛋白質揚げ米の製造方法。 A method for producing low protein fried rice, characterized in that raw rice is proteolytically processed, and the resulting treated rice is washed and then fried in oil.
  8.  請求項7に記載の製造方法で得られる低蛋白質揚げ米を調理して得られる食品。 A food obtained by cooking low protein fried rice obtained by the production method according to claim 7.
  9.  生米を蛋白質分解処理し、得られた処理米を洗浄した後、米を90℃以下の油に浸漬して水を除去し、その後蒸し処理することを特徴とする低蛋白質蒸し処理米の製造方法。 Production of low-protein steamed rice characterized by proteolytically treating raw rice, washing the resulting treated rice, immersing the rice in oil at 90 ° C. or less to remove water, and then steaming Method.
  10.  請求項9に記載の製造方法により得られる低蛋白質蒸し処理米を調理して得られる食品。 A food obtained by cooking low protein steamed rice obtained by the production method according to claim 9.
  11.  請求項9に記載の製造方法により得られる低蛋白質蒸し処理米を乾燥することを特徴とする低蛋白質蒸し処理米の乾燥品の製造方法。 A method for producing a dried product of low protein steamed rice, characterized in that the low protein steamed rice obtained by the production method according to claim 9 is dried.
  12.  請求項11に記載の製造方法により得られる低蛋白質蒸し処理米の乾燥品を調理して得られる食品。 A food obtained by cooking a dried product of low protein steamed rice obtained by the production method according to claim 11.
  13.  生米を蛋白質分解処理し、得られた処理米を洗浄した後、油で揚げることにより製造される低蛋白質揚げ米。 Low protein fried rice produced by proteolytically treating raw rice, washing the resulting treated rice, and then frying in oil.
  14.  生米を蛋白質分解処理し、得られた処理米を洗浄した後、米を90℃以下の油に浸漬して水を除去し、その後蒸し処理をすることにより製造される低蛋白質蒸し処理米。 A low protein steamed rice produced by proteolytically treating raw rice, washing the resulting treated rice, immersing the rice in oil at 90 ° C. or less to remove water, and then steaming.
  15.  請求項14に記載の低蛋白質蒸し処理米を乾燥することにより製造される低蛋白質蒸し処理米の乾燥品。 A dried product of low protein steamed rice produced by drying the low protein steamed rice of claim 14.
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