WO2014022463A1 - Tire with laminate - Google Patents
Tire with laminate Download PDFInfo
- Publication number
- WO2014022463A1 WO2014022463A1 PCT/US2013/052831 US2013052831W WO2014022463A1 WO 2014022463 A1 WO2014022463 A1 WO 2014022463A1 US 2013052831 W US2013052831 W US 2013052831W WO 2014022463 A1 WO2014022463 A1 WO 2014022463A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- laminate
- tire
- tread
- disposed
- base rubber
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/03—Tread patterns
- B60C11/13—Tread patterns characterised by the groove cross-section, e.g. for buttressing or preventing stone-trapping
- B60C11/1307—Tread patterns characterised by the groove cross-section, e.g. for buttressing or preventing stone-trapping with special features of the groove walls
- B60C11/1346—Tread patterns characterised by the groove cross-section, e.g. for buttressing or preventing stone-trapping with special features of the groove walls covered by a rubber different from the tread rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0008—Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
- B60C2011/0016—Physical properties or dimensions
- B60C2011/0025—Modulus or tan delta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C13/00—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof
- B60C13/04—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof having annular inlays or covers, e.g. white sidewalls
- B60C2013/045—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof having annular inlays or covers, e.g. white sidewalls comprising different sidewall rubber layers
Definitions
- the present disclosure relates to a tire having a laminate disposed thereon and to methods of its preparation. More particularly, the present disclosure relates to a tire with a laminate having different attributes than the base rubber of the tire tread.
- Known tire treads are rubber compositions which contain at least some carbon black reinforcement and are thereby black in color.
- the rubber of a tread may be selected for its material properties, such as its hardness. As the tread wears, the tread rubber maintains the same material properties.
- a tire in one embodiment, includes a pair of sidewalls and a circumferential tread constructed of a base rubber.
- the circumferential tread has a plurality of grooves disposed therein, thereby defining a plurality of tread elements.
- the tire further includes a polymeric laminate disposed on the circumferential tread.
- the polymeric laminate covers at least one of the plurality of grooves, and the polymeric laminate covers a top surface of at least one of the plurality of tread elements.
- the polymeric laminate has greater snow traction than the base rubber.
- a tire in another embodiment, includes a circumferential tread constructed of a base material.
- the circumferential tread has a plurality of tread elements, with each of the plurality of tread elements having a top surface and a plurality of side surfaces.
- the circumferential tread further has a plurality of grooves disposed between the plurality of tread elements.
- a laminate covers at least some of the plurality of tread elements and at least some of the plurality of grooves. The laminate has greater snow traction than the base material.
- a tire in yet another embodiment, includes a pair of sidewalls and a circumferential tread constructed of a base rubber.
- the circumferential tread has a plurality of tread elements, with each of the plurality of tread elements having a top surface and a plurality of side surfaces.
- the circumferential tread further has a plurality of grooves disposed between the plurality of tread elements.
- a laminate is disposed on the circumferential tread, such that the laminate covers at least a portion of the plurality of side surfaces of the plurality of tread elements.
- the base rubber has lower snow traction than the laminate.
- Figure 1 is a perspective view of one embodiment of a tire having a laminate disposed in grooves of the tread;
- Figure 2 is a perspective view of an alternative embodiment of a tire having a laminate disposed thereon;
- Figure 3 is a cross-section of one embodiment of a tire having a laminate disposed on a circumferential tread
- Figure 4 is a cross-section of one embodiment of a tire having a laminate disposed in grooves of a circumferential tread
- Figure 5 is a cross-section of one embodiment of a tire having a laminate disposed on a circumferential tread and a pair of sidewalls;
- Figure 6 is a cross-section of one embodiment of a tire having a laminate disposed on a pair of sidewalls.
- Axial or “axially” refer to a direction that is parallel to the axis of rotation of a tire.
- Bead refers to the part of the tire that contacts the wheel and defines a boundary of the sidewall.
- “Circumferential” and “circumferentially” refer to a direction extending along the perimeter of the surface of the tread perpendicular to the axial direction.
- Equatorial plane refers to the plane that is perpendicular to the tire's axis of rotation and passes through the center of the tire's tread.
- Ring and radially refer to a direction perpendicular to the axis of rotation of a tire.
- Sidewall refers to that portion of the tire between the tread and the bead.
- Tread refers to that portion of the tire that comes into contact with the road under normal inflation and load.
- inward and outwardly refer to a general direction towards the equatorial plane of the tire
- outward and outwardly refer to a general direction away from the equatorial plane of the tire and towards the sidewall of the tire.
- relative directional terms such as “inner” and “outer” are used in connection with an element, the “inner” element is spaced closer to the equatorial plane of the tire than the “outer” element.
- Figures 1-6 show various embodiments of tires having a laminate disposed on at least a portion of the external surface of the tire.
- the laminate may be rubber, or another polymeric material.
- the laminate has a thickness of less than 1.5 millimeters.
- the laminate has a thickness of 1.0 to 1.5 millimeters.
- thicker laminates may be employed.
- the thickness of the laminate may be exaggerated in the drawings for illustrative purposes.
- Figure 1 illustrates a perspective view of one embodiment of a tire 100 having a circumferential tread 110 with grooves 120 disposed therein.
- the tire 100 has a laminate 130 disposed in the grooves 120.
- the circumferential tread 110 includes a plurality of blocks 140.
- the tire may include one or more tread elements such as lugs or solid circumferential ribs. It should be understood that the tire is not limited to having any particular tread design.
- Figure 2 illustrates a perspective view of an alternative embodiment of a tire 200 having a laminate 210 disposed thereon. In the illustrated embodiment, the laminate 210 covers substantially the entire external surface of the tire.
- tire 200 has a circumferential tread 220 with a plurality of lugs 230.
- the tire may include one or more solid circumferential ribs, or one or more blocks. It should be understood that the tire is not limited to having any particular tread design.
- Figure 1 illustrates a tire 100 suitable for a passenger vehicle
- Figure 2 illustrates a tire 200 suitable for an agricultural vehicle
- the laminates described herein may be employed on tires for any vehicle, including without limitation, bicycles, motorcycles, all-terrain vehicles, cars, trucks, tractors and other agricultural vehicles, mining vehicles, airplanes, and all other wheeled vehicles.
- the material properties of the laminate may be varied according to the vehicle type, and the expected use of the tire.
- Figure 3 illustrates a cross-section of one embodiment of a tire 300 having a laminate 310 disposed on a circumferential tread 320.
- the laminate 310 covers both the top surface of the tread 320 and the grooves 330 disposed in the tread 320.
- the laminate 310 may also cover slots, sipes, and other tread elements (not shown).
- Figure 4 illustrates a cross-section of one embodiment of a tire 400 having a laminate 410 disposed on the surface of grooves 420 of a circumferential tread 430.
- the laminate 410 may also cover slots, sipes, and other tread elements (not shown).
- the laminate does not cover the top surface of the circumferential tread 430, i.e. the portion of the circumferential tread that comes into contact with a road or other rolling surface.
- the laminate 410 is first disposed over the entire circumferential tread 430 such that it covers both the top surface of the tread 430 and the grooves 420 disposed therein.
- the laminate 410 on the top surface of the tread 430 is then buffed off or ground away, using an abrasive grinding material.
- the laminate may be recycled after it is ground off the tire.
- the laminate 410 on the top surface of the tread 430 may be worn away during use of the tire 400 on a vehicle.
- the laminate 410 is only disposed on the surface of the grooves 430 and the top surface of the tread 430 is left uncovered by the laminate 410. In such an embodiment, no grinding or wearing of the laminate 410 is necessary.
- Figure 5 illustrates a cross-section of one embodiment of a tire 500 having a laminate 510 disposed on a circumferential tread 520 and a pair of sidewalls 530.
- the laminate 510 covers both the top surface of the tread 520 and the grooves 540 disposed therein.
- the laminate 510 may also cover slots, sipes, and other tread elements (not shown).
- the laminate 510 extends down each sidewall 530 to the heel 550 of the tire 500.
- the laminate may only cover a portion of each sidewall. It should be understood that the coverage of each sidewall need not be the same.
- the laminate may cover an outer sidewall of a tire, but not the inner sidewall of the tire.
- the coverage of the laminate is shown as continuous, it should be understood that gaps may exist.
- the laminate 510 may be disposed on the surface of grooves 540 of a circumferential tread 520, but not on the top surface of the tread 520 in the same manner shown in Figure 4. Additionally, portions of the sidewall 530 may be left uncovered or the laminate may be ground away from portions of the sidewall 530.
- Figure 6 illustrates a cross-section of one embodiment of a tire 600 having laminates 610 disposed on a pair of sidewalls 620.
- the laminate does not cover the circumferential tread 630 of the tire 600. Instead, the laminate 610 extends from a shoulder portion 640 of each sidewall 620 to the heel 650 of the tire 600.
- the laminate may only cover a portion of each sidewall. It should be understood that the coverage of each sidewall need not be the same.
- the laminate may cover an outer sidewall of a tire, but not the inner sidewall of the tire.
- the laminate may be rubber, or another polymeric material.
- the laminate does not include carbon black.
- the laminate may include pigments of any color or combination of colors. Colors may be employed for aesthetic reasons.
- laminates may be colored to display a design, text, logos, brand names, or other pictures or photographs.
- a user may determine that it is aesthetically pleasing to have a color laminate that is disposed only in the grooves, or disposed on both the tread and the grooves. Multiple colors may be employed on a single laminate.
- the laminate may have colors in a camouflage pattern.
- a user may customize the tire by providing an image that is transferred to the laminate.
- the color of the laminate may also be used as an indicator.
- the use of color as an indicator allows the tire to display the same information to an observer, regardless of whether the car is stopped or moving.
- the color may be selected to indicate material properties of the laminate itself.
- the color may be selected to indicate a property of the tire.
- a blue laminate may be employed on a tire that has superior handling in wet conditions.
- a green laminate may be employed to indicate that the tire is fuel efficient, or otherwise environmentally friendly.
- a color laminate may also function as a wear indicator.
- the exposure of the base rubber provides a visual indication of the level of wear of the tire.
- the color may be used to identify a brand.
- a tire brand may be associated with a particular color.
- a car brand, car rental service brand, or non-vehicular service or product may be associated with a particular color.
- Color may also serve as an indicator in a racing environment. For example, a color may be used to designate a racing team. A color may also be used to identify a points leader in a racing series, or the pole position vehicle. Additionally, a color may be used to indicate that a particular type of tire is being used in a race. In one example, the color may be used to indicate a hardness of a compound used in the tire tread.
- the laminate may also be selected for its material properties.
- the laminate is constructed of a material that is harder than the base rubber of the tire.
- Such a laminate may be useful in agricultural tires, and tires for off-road vehicles. As is understood in the art, agricultural tires are susceptible to damage from corn stalks, rocks, and other hard objects. Likewise, tires on off- road vehicles are susceptible to damage from rocks and other hard objects.
- the laminate When the laminate has a greater hardness than the base rubber, the laminate may have a different color than the base rubber. The use of different colors would provide an indicator that the laminate has worn away from the top surface of a tire tread. Alternatively, the laminate may have the same color than the base rubber to provide a uniform appearance.
- the laminate may have material properties that produce greater snow traction, making the laminate more suitable for snow performance than the base rubber.
- the laminate has a low modulus of elasticity, such that the laminate is softer than the base rubber. Such a laminate may perform better in cold weather, which hardens the rubber.
- the laminate may also include sipes or cuts to provide additional traction in snow.
- the sipes may extend through the entire laminate without extending into the base rubber. In an alternative embodiment, the sipes may only extend partially through the laminate. In another alternative embodiment, the sipes may extend through the entire laminate and extend through part of the base rubber.
- the base rubber of the tire may be suited for all seasons. Accordingly, such a tire would have superior winter characteristics initially, for its first season of use, when the top surface of the tread is covered by the laminate (such as shown in Figure 3). When the tire is used, and the laminate wears off the top surface of the tread (such as shown in Figure 4) then the base rubber is exposed, and the tire has all season performance thereafter.
- the thickness of such a laminate could be selected for various wear rates, so that the laminate lasts through the winter and is worn away by the spring.
- the laminate may have a different color than the base rubber.
- the use of different colors would provide an indicator that the laminate has worn away from the top surface of a tire tread.
- the laminate may have the same color than the base rubber to provide a uniform appearance.
- the laminate is made of an ozone resistant material. Such a material would resist cracking in sunlight, and may be particularly useful in the grooves of a tread.
- the laminate is a sealant. Such an embodiment may be particularly useful for tires on mining vehicles.
- the laminate may have air permeability different from the base rubber.
- the use of a laminate on the tread of a tire enhances performance as the tire wears. For example, where a laminate is disposed on the top surface of the tread and in the grooves (such as shown in Figure 3), the laminate on the top surface of the tread wears away during use of the tire, resulting in a tire having laminate only in the grooves of the tire (such as shown in Figure 4).
- the laminate in the grooves is a soft material that improves snow performance.
- Figures 1-6 display the use of a single laminate, it should be understood that more than one laminate may be employed.
- different laminates are employed in different sections of the tire. For example, different laminates may be used on a sidewall, top surface of a tread, and grooves of a tread. Where multiple laminates are disposed on different portion of the tire, different colored laminates may be employed to form a desired pattern. For example, different laminates may be used to form a camouflage pattern on the tire.
- one or more laminates may be layered on top of one another. Where layers of laminates are disposed on the top surface of a tread, each layer is worn away during use of the tire. As the first layer is worn, the second layer becomes exposed. In such a configuration, each laminate in the layer may have a different color. An observer will then be able to visually detect as layers are worn away and other layers are exposed.
- each layer may have a different material property.
- an outer layer may be constructed of a material that exhibits superior snow performance
- an inner layer may be constructed of a material that exhibits superior wet performance
- the remaining compound of the tire may be constructed of a material that exhibits superior dry performance.
- Such a tire may be suitable for geographic locations that have a snowy winter, followed by a wet spring, and a dry summer.
- the thickness of each layer may be selected based on the various wear rates for each weather condition.
- a first layer may be an ozone resistant material and a second layer may be a softer material for cold weather and snow performance. During the curing of the tire, the ozone resistant material may leach from the first layer into the second layer.
- the laminate may be applied to the tire in a number of different ways.
- the laminate is disposed on the tire by co-extruding the laminate with the rubber of the tire.
- the laminate is disposed on the tire by forming a thin sheet of material and separately building a green tire. The laminate may then be placed on a desired location of the green tire, and the green tire and laminate are cured. In one embodiment, the laminate is a sheet that is placed on the green tire. In an alternative embodiment, the laminate is a ribbon that is wound about the green tire, or is disposed only in the grooves of the tire. In either embodiment, the laminate may be pressed onto the green tire with one or more rollers. Such a process may be referred to as "stitching" and may expel air or other gasses that become trapped between the laminate and the green tire. [0055] In another alternative embodiment, the laminate is disposed on a cured tire.
- Such a laminate may be applied to the tire using a vacuum process.
- the laminate is a sheet that is placed on the cured tire.
- the laminate is a ribbon that is wound about the cured tire, or is disposed only in the grooves of the tire.
- the laminate is applied to a new tread during a tire re-treading process.
- the laminate may be applied to the new tread in the same manners described above.
- the laminate may be co-extruded with the new tread.
- the laminate may be place as a sheet on the new tread or wound around the new tread.
- the laminate may be "stitched" to the new tread by using rollers.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Tires In General (AREA)
- Ropes Or Cables (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020157001847A KR101756414B1 (en) | 2012-07-31 | 2013-07-31 | Tire with laminate |
MX2015001483A MX2015001483A (en) | 2012-07-31 | 2013-07-31 | Tire with laminate. |
CA2879644A CA2879644A1 (en) | 2012-07-31 | 2013-07-31 | Tire with laminate |
RU2015102921A RU2616479C2 (en) | 2012-07-31 | 2013-07-31 | Tire with laminated layer |
CN201380040814.1A CN104540688B (en) | 2012-07-31 | 2013-07-31 | Tire with laminates |
BR112015002013A BR112015002013A2 (en) | 2012-07-31 | 2013-07-31 | laminated tire |
IN249DEN2015 IN2015DN00249A (en) | 2012-07-31 | 2013-07-31 | |
EP13825414.9A EP2879887A4 (en) | 2012-07-31 | 2013-07-31 | Tire with laminate |
JP2015524507A JP6154901B2 (en) | 2012-07-31 | 2013-07-31 | Tire with laminate |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261678075P | 2012-07-31 | 2012-07-31 | |
US61/678,075 | 2012-07-31 | ||
US13/895,149 | 2013-05-15 | ||
US13/895,149 US20140034199A1 (en) | 2012-07-31 | 2013-05-15 | Tire with laminate |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014022463A1 true WO2014022463A1 (en) | 2014-02-06 |
Family
ID=50024307
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2013/052098 WO2014022199A1 (en) | 2012-07-31 | 2013-07-25 | Tire with laminate |
PCT/US2013/052831 WO2014022463A1 (en) | 2012-07-31 | 2013-07-31 | Tire with laminate |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2013/052098 WO2014022199A1 (en) | 2012-07-31 | 2013-07-25 | Tire with laminate |
Country Status (12)
Country | Link |
---|---|
US (1) | US20140034199A1 (en) |
EP (4) | EP3176007B1 (en) |
JP (2) | JP6346608B2 (en) |
KR (1) | KR101756414B1 (en) |
CN (2) | CN104507709B (en) |
AR (1) | AR091943A1 (en) |
BR (2) | BR112015002093A2 (en) |
CA (1) | CA2879644A1 (en) |
IN (2) | IN2015DN00250A (en) |
MX (1) | MX2015001483A (en) |
RU (1) | RU2616479C2 (en) |
WO (2) | WO2014022199A1 (en) |
Families Citing this family (8)
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JP6204730B2 (en) * | 2013-07-11 | 2017-09-27 | 株式会社ブリヂストン | Pneumatic tire |
WO2015100029A1 (en) | 2013-12-23 | 2015-07-02 | Bridgestone Americas Tire Operations, Llc | Tire with reinforced tread |
FR3020990B1 (en) * | 2014-05-13 | 2016-12-09 | Michelin & Cie | TIRE TREAD FOR A VEHICLE FOR AGRICULTURAL USE |
CA2968822C (en) | 2014-12-22 | 2018-07-24 | Bridgestone Americas Tire Operations, Llc | Method of applying a post cure laminate to a tire |
JP6567397B2 (en) * | 2015-11-20 | 2019-08-28 | 株式会社ブリヂストン | tire |
JP6523147B2 (en) * | 2015-11-20 | 2019-05-29 | 株式会社ブリヂストン | Tire and method of manufacturing the same |
IT201600096381A1 (en) * | 2016-09-26 | 2018-03-26 | Bridgestone Europe N V | MANUFACTURING METHOD OF A TIRE TREAD |
CN110799351B (en) * | 2017-06-30 | 2023-01-31 | 米其林集团总公司 | Rolling assembly with rim whose flanges form a support of increased axial width |
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- 2013-05-15 US US13/895,149 patent/US20140034199A1/en not_active Abandoned
- 2013-07-25 WO PCT/US2013/052098 patent/WO2014022199A1/en active Application Filing
- 2013-07-25 JP JP2015524454A patent/JP6346608B2/en not_active Expired - Fee Related
- 2013-07-25 EP EP17152422.6A patent/EP3176007B1/en active Active
- 2013-07-25 BR BR112015002093A patent/BR112015002093A2/en not_active IP Right Cessation
- 2013-07-25 EP EP13826042.7A patent/EP2879888B1/en active Active
- 2013-07-25 EP EP17152423.4A patent/EP3176008B1/en active Active
- 2013-07-25 IN IN250DEN2015 patent/IN2015DN00250A/en unknown
- 2013-07-25 CN CN201380040469.1A patent/CN104507709B/en not_active Expired - Fee Related
- 2013-07-31 EP EP13825414.9A patent/EP2879887A4/en not_active Withdrawn
- 2013-07-31 CN CN201380040814.1A patent/CN104540688B/en not_active Expired - Fee Related
- 2013-07-31 BR BR112015002013A patent/BR112015002013A2/en not_active IP Right Cessation
- 2013-07-31 JP JP2015524507A patent/JP6154901B2/en not_active Expired - Fee Related
- 2013-07-31 IN IN249DEN2015 patent/IN2015DN00249A/en unknown
- 2013-07-31 MX MX2015001483A patent/MX2015001483A/en unknown
- 2013-07-31 AR ARP130102714A patent/AR091943A1/en unknown
- 2013-07-31 WO PCT/US2013/052831 patent/WO2014022463A1/en active Application Filing
- 2013-07-31 RU RU2015102921A patent/RU2616479C2/en not_active IP Right Cessation
- 2013-07-31 CA CA2879644A patent/CA2879644A1/en not_active Abandoned
- 2013-07-31 KR KR1020157001847A patent/KR101756414B1/en active IP Right Grant
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Also Published As
Publication number | Publication date |
---|---|
BR112015002013A2 (en) | 2017-07-04 |
CN104540688A (en) | 2015-04-22 |
IN2015DN00250A (en) | 2015-06-12 |
KR20150024911A (en) | 2015-03-09 |
CN104540688B (en) | 2017-07-28 |
RU2616479C2 (en) | 2017-04-17 |
JP6346608B2 (en) | 2018-06-20 |
JP2015523277A (en) | 2015-08-13 |
CN104507709B (en) | 2017-07-28 |
KR101756414B1 (en) | 2017-07-11 |
EP3176008A1 (en) | 2017-06-07 |
EP2879887A1 (en) | 2015-06-10 |
EP2879888A4 (en) | 2016-03-02 |
BR112015002093A2 (en) | 2017-07-04 |
MX2015001483A (en) | 2015-04-09 |
WO2014022199A1 (en) | 2014-02-06 |
RU2015102921A (en) | 2016-09-20 |
CA2879644A1 (en) | 2014-02-06 |
EP2879887A4 (en) | 2016-03-30 |
IN2015DN00249A (en) | 2015-06-12 |
EP3176007B1 (en) | 2018-08-29 |
EP3176008B1 (en) | 2020-04-22 |
EP2879888B1 (en) | 2017-03-08 |
CN104507709A (en) | 2015-04-08 |
JP2015530948A (en) | 2015-10-29 |
US20140034199A1 (en) | 2014-02-06 |
JP6154901B2 (en) | 2017-06-28 |
AR091943A1 (en) | 2015-03-11 |
EP3176007A1 (en) | 2017-06-07 |
EP2879888A1 (en) | 2015-06-10 |
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