WO2014019697A3 - Verfahren zur kryogenen abtrennung von methan aus synthesegas, insbesondere oxogas - Google Patents
Verfahren zur kryogenen abtrennung von methan aus synthesegas, insbesondere oxogas Download PDFInfo
- Publication number
- WO2014019697A3 WO2014019697A3 PCT/EP2013/002296 EP2013002296W WO2014019697A3 WO 2014019697 A3 WO2014019697 A3 WO 2014019697A3 EP 2013002296 W EP2013002296 W EP 2013002296W WO 2014019697 A3 WO2014019697 A3 WO 2014019697A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- methane
- synthesis gas
- rich
- mass flow
- oxogas
- Prior art date
Links
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
- F25J3/0223—H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0271—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of H2/CO mixtures, i.e. of synthesis gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/74—Refluxing the column with at least a part of the partially condensed overhead gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
- F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/42—Nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/02—Mixing or blending of fluids to yield a certain product
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/12—External refrigeration with liquid vaporising loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/42—Quasi-closed internal or closed external nitrogen refrigeration cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/90—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
- F25J2270/904—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration by liquid or gaseous cryogen in an open loop
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Die Erfindung betrifft ein Verfahren zur Abtrennung von Methan aus einem Synthesegasstrom, insbesondere Oxogasstrom (21), aufweisend die Schritte: Ankondensieren des Synthesegasstromes (21), so dass eine methanabgereicherte gasförmige Synthesegasfraktion (22) und ein methanangereichertes CO-reiches Kondensat (23) entstehen, Abscheiden des Kondensats (23), und Trennen des Kondensats (23) in einer Kolonne (35) in eine CH4-reichen, flüssigen Stoffstrom (24) und einen methanabgereicherten, CO-reichen, gasförmigen Stoffstrom (25), Abziehen des CO-reichen Stoffstromes (25) aus dem Kopf der Kolonne (35), Verdichten des CO- reichen Stoffstromes (25), und Mischen des CO-reichen Stoffstromes (25) mit der methanabgereicherten Synthesegasfraktion (26).
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2015106944A RU2015106944A (ru) | 2012-08-02 | 2013-08-01 | Способ криогенного выделения метана из синтез-газа, в частности оксо-газа |
EP13745349.4A EP2880388A2 (de) | 2012-08-02 | 2013-08-01 | Verfahren zur kryogenen abtrennung von methan aus synthesegas, insbesondere oxogas |
CN201380040986.9A CN104870921A (zh) | 2012-08-02 | 2013-08-01 | 从合成气,尤其是羰基合成气中低温分离甲烷的方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012015340.6 | 2012-08-02 | ||
DE201210015340 DE102012015340A1 (de) | 2012-08-02 | 2012-08-02 | Verfahren zur kryogenen Abtrennung von Methan aus Synthesegas, insbesondere Oxogas |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2014019697A2 WO2014019697A2 (de) | 2014-02-06 |
WO2014019697A3 true WO2014019697A3 (de) | 2015-06-18 |
Family
ID=48917487
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2013/002296 WO2014019697A2 (de) | 2012-08-02 | 2013-08-01 | Verfahren zur kryogenen abtrennung von methan aus synthesegas, insbesondere oxogas |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2880388A2 (de) |
CN (1) | CN104870921A (de) |
DE (1) | DE102012015340A1 (de) |
RU (1) | RU2015106944A (de) |
WO (1) | WO2014019697A2 (de) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015007529A1 (de) * | 2015-06-12 | 2016-12-15 | Linde Aktiengesellschaft | Verfahren und Anlage zur Abtrennung von Methan aus einem methanhaltigen Synthesegasstrom |
FR3057942B1 (fr) * | 2016-10-21 | 2019-12-27 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et appareil de separation cryogenique d’un gaz de synthese par condensation partielle |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0677483A1 (de) * | 1994-04-13 | 1995-10-18 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Verfahren und Vorrichtung für die Trennung einer Gasmischung |
WO2007018505A1 (en) * | 2005-07-28 | 2007-02-15 | Innovene Usa Llc | Recovery of co-rich product from a mixed gas containing heavy hydrocarbons |
EP2192365A2 (de) * | 2008-11-29 | 2010-06-02 | Linde AG | Prozess zur Minimierung von Rückführgas in einem Kondensationsprozess |
US20100251765A1 (en) * | 2009-04-01 | 2010-10-07 | Air Products And Chemicals, Inc. | Cryogenic Separation of Synthesis Gas |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2030740B2 (de) | 1970-06-23 | 1978-05-11 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Gewinnung von methanfreiem Synthesegas aus dem Spaltgas des Tauchflammverfahrens |
-
2012
- 2012-08-02 DE DE201210015340 patent/DE102012015340A1/de not_active Withdrawn
-
2013
- 2013-08-01 RU RU2015106944A patent/RU2015106944A/ru not_active Application Discontinuation
- 2013-08-01 WO PCT/EP2013/002296 patent/WO2014019697A2/de active Application Filing
- 2013-08-01 CN CN201380040986.9A patent/CN104870921A/zh active Pending
- 2013-08-01 EP EP13745349.4A patent/EP2880388A2/de not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0677483A1 (de) * | 1994-04-13 | 1995-10-18 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Verfahren und Vorrichtung für die Trennung einer Gasmischung |
WO2007018505A1 (en) * | 2005-07-28 | 2007-02-15 | Innovene Usa Llc | Recovery of co-rich product from a mixed gas containing heavy hydrocarbons |
EP2192365A2 (de) * | 2008-11-29 | 2010-06-02 | Linde AG | Prozess zur Minimierung von Rückführgas in einem Kondensationsprozess |
US20100251765A1 (en) * | 2009-04-01 | 2010-10-07 | Air Products And Chemicals, Inc. | Cryogenic Separation of Synthesis Gas |
Also Published As
Publication number | Publication date |
---|---|
EP2880388A2 (de) | 2015-06-10 |
RU2015106944A (ru) | 2016-09-20 |
DE102012015340A1 (de) | 2014-02-06 |
CN104870921A (zh) | 2015-08-26 |
WO2014019697A2 (de) | 2014-02-06 |
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