WO2014014337A3 - Eco-friendly plasticizer for poly(vinyl chloride) - Google Patents

Eco-friendly plasticizer for poly(vinyl chloride) Download PDF

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Publication number
WO2014014337A3
WO2014014337A3 PCT/MY2013/000121 MY2013000121W WO2014014337A3 WO 2014014337 A3 WO2014014337 A3 WO 2014014337A3 MY 2013000121 W MY2013000121 W MY 2013000121W WO 2014014337 A3 WO2014014337 A3 WO 2014014337A3
Authority
WO
WIPO (PCT)
Prior art keywords
mcl
pha
poly
vinyl chloride
eco
Prior art date
Application number
PCT/MY2013/000121
Other languages
French (fr)
Other versions
WO2014014337A2 (en
Inventor
Irene Kit Ping TAN
Seng Neon Gan
Mohamad Suffian Bin Mohamad ANNUAR
Mei Chan SIN
Original Assignee
University Of Malaya
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University Of Malaya filed Critical University Of Malaya
Priority to CN201380046379.3A priority Critical patent/CN104822835A/en
Publication of WO2014014337A2 publication Critical patent/WO2014014337A2/en
Publication of WO2014014337A3 publication Critical patent/WO2014014337A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/20—Bacteria; Culture media therefor
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/62—Carboxylic acid esters
    • C12P7/625—Polyesters of hydroxy carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Genetics & Genomics (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Microbiology (AREA)
  • Biochemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Virology (AREA)
  • Biomedical Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

The present invention disclosed a medium-chain-length poly(3 -hydroxy alkanoates) (mcl-PHA) for use as natural based eco-friendly plasticizer for Poly(vinyl chloride) (PVC). In the present invention, mcl-PHA was bio synthesized by Pseudomonas putida PGAl via fermentation using oleic acid and palm kernel oil as renewable carbon source. Mcl-PHA is a source of green natural polymers which can be used to improve material properties of PVC. Compare with the conventional petrochemical based plasticizer, mcl-PHA would not be hazardous to human health and the environment due to the non-toxic, biodegradable and biocompatible properties.
PCT/MY2013/000121 2012-07-19 2013-06-24 Eco-friendly plasticizer for poly(vinyl chloride) WO2014014337A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201380046379.3A CN104822835A (en) 2012-07-19 2013-06-24 Eco-friendly plasticizer for poly(vinyl chloride)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
MYPI2012003273 MY151111A (en) 2012-07-19 2012-07-19 Eco-friendly plasticizer for poly (vinyl chloride)
MYPI2012003273 2012-07-19

Publications (2)

Publication Number Publication Date
WO2014014337A2 WO2014014337A2 (en) 2014-01-23
WO2014014337A3 true WO2014014337A3 (en) 2014-03-13

Family

ID=49949326

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/MY2013/000121 WO2014014337A2 (en) 2012-07-19 2013-06-24 Eco-friendly plasticizer for poly(vinyl chloride)

Country Status (3)

Country Link
CN (1) CN104822835A (en)
MY (1) MY151111A (en)
WO (1) WO2014014337A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10611903B2 (en) * 2014-03-27 2020-04-07 Cj Cheiljedang Corporation Highly filled polymer systems
US9676924B2 (en) 2014-11-26 2017-06-13 Polymer Additives Inc. Triesters from alpha-and-beta-hydroxyesters
CN114354777A (en) * 2021-12-06 2022-04-15 宜宾海丰和锐有限公司 Method for detecting residual vinyl chloride monomer in medical PVC resin

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110008857A1 (en) * 2009-07-10 2011-01-13 University College Dublin, National University Of Ireland, Dublin Method for Producing Polyhydroxyalkanoate
US20110166318A1 (en) * 2009-12-07 2011-07-07 Xuan Jiang Medium Chain Length Polyhydroxyalkanoate Polymer and Method of Making Same

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4477654A (en) * 1981-07-07 1984-10-16 Imperial Chemical Industries Plc 3-Hydroxybutyrate polymers
WO2008090590A1 (en) * 2007-01-26 2008-07-31 Seed Company Ltd. Elastomer composition, method for producing the same, and eraser using the composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110008857A1 (en) * 2009-07-10 2011-01-13 University College Dublin, National University Of Ireland, Dublin Method for Producing Polyhydroxyalkanoate
US20110166318A1 (en) * 2009-12-07 2011-07-07 Xuan Jiang Medium Chain Length Polyhydroxyalkanoate Polymer and Method of Making Same

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
ANNUAR, M.S.M ET AL.: "Production of medium-chain-length poly(3-hydroxyalkanoates) from saponified palm kernel oil by Pseudomonas putida: kinetics of batch and fed-batch fermentations", MALAYSIAN JOURNAL OF MICROBIOLOGY, vol. 2, no. 2, 2006, pages 1 - 9 *
ANNUAR, M.S.M. ET AL.: "A kinetic model for growth and biosynthesis of medium-chain-length poly-(3-hydroxyalkanoates) in Pseudomonas putida", BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING, vol. 25, no. 2, April 2008 (2008-04-01), pages 217 - 228 *
ANNUAR, M.S.M. ET AL.: "Evaluation of nitrogen sources for growth and production of medium-chain-length poly-(3-hydroxyalkanoates) from palm kernel oil by Pseudomonas putida PGA1", ASIA PACIFIC JOURNAL OF MOLECULAR BIOLOGY AND OIOTECHNOLOGY, vol. 16, no. 1, 2008, pages 11 - 15 *
SIN, MEI CHAN ET AL.: "Thermal behaviour and thermodegradation kinetics of poly(vinyl chloride) plasticized with polymeric and oligomeric medium-chain- length poly(3-hydroxyalkanoates)", POLYMER DEGRADATION AND STABILITY, vol. 97, no. 11, 7 September 2012 (2012-09-07), pages 2118 - 2127 *
SIN, MEI CHAN ET AL.: "Thermodegradation of medium-chain-length poly(3-hydroxyalkanoates) produced by Pseudomonas putida from oleic acid", POLYMER DEGRADATION AND STABILITY, vol. 95, no. 12, 18 September 2010 (2010-09-18), pages 2334 - 2342 *
TAN, I.K.P ET AL.: "Saponified palm kernel oil and its major free fatty acids as carbon substrates for the production of polyhydroxyalkanoates in Pseudomonas putida PGA1", APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, vol. 747, no. 3, March 1997 (1997-03-01), pages 207 - 211 *

Also Published As

Publication number Publication date
MY151111A (en) 2014-04-10
WO2014014337A2 (en) 2014-01-23
CN104822835A (en) 2015-08-05

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