WO2014013744A1 - Method for providing plants with resistance to stress - Google Patents
Method for providing plants with resistance to stress Download PDFInfo
- Publication number
- WO2014013744A1 WO2014013744A1 PCT/JP2013/004430 JP2013004430W WO2014013744A1 WO 2014013744 A1 WO2014013744 A1 WO 2014013744A1 JP 2013004430 W JP2013004430 W JP 2013004430W WO 2014013744 A1 WO2014013744 A1 WO 2014013744A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- formula
- unsubstituted
- substituted
- compound represented
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000000126 substance Substances 0.000 claims abstract description 84
- 150000001875 compounds Chemical class 0.000 claims abstract description 53
- 150000003839 salts Chemical class 0.000 claims abstract description 40
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 31
- 125000003147 glycosyl group Chemical group 0.000 claims abstract description 20
- 241000196324 Embryophyta Species 0.000 claims description 60
- 239000000203 mixture Substances 0.000 claims description 26
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 claims description 18
- 231100000674 Phytotoxicity Toxicity 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 125000003342 alkenyl group Chemical group 0.000 claims description 17
- 125000000739 C2-C30 alkenyl group Chemical group 0.000 claims description 16
- 241000607479 Yersinia pestis Species 0.000 claims description 13
- 239000002917 insecticide Substances 0.000 claims description 13
- 230000001603 reducing effect Effects 0.000 claims description 13
- 239000003905 agrochemical Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 125000001424 substituent group Chemical group 0.000 claims description 9
- 230000003032 phytopathogenic effect Effects 0.000 claims description 8
- 239000000417 fungicide Substances 0.000 claims description 7
- 239000004009 herbicide Substances 0.000 claims description 7
- 241000700605 Viruses Species 0.000 claims description 6
- 241000233866 Fungi Species 0.000 claims description 5
- 239000005648 plant growth regulator Substances 0.000 claims description 5
- 241000894006 Bacteria Species 0.000 claims description 4
- 229910001385 heavy metal Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 230000000855 fungicidal effect Effects 0.000 claims description 2
- 230000002363 herbicidal effect Effects 0.000 claims description 2
- 239000000575 pesticide Substances 0.000 abstract description 9
- 229910018828 PO3H2 Inorganic materials 0.000 abstract 1
- 229910006069 SO3H Inorganic materials 0.000 abstract 1
- 230000009931 harmful effect Effects 0.000 abstract 1
- 125000005017 substituted alkenyl group Chemical group 0.000 abstract 1
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 1
- -1 vicyanose Chemical compound 0.000 description 92
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 53
- 230000006378 damage Effects 0.000 description 39
- 238000012360 testing method Methods 0.000 description 38
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 37
- 230000035882 stress Effects 0.000 description 36
- 230000009467 reduction Effects 0.000 description 25
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 22
- 201000010099 disease Diseases 0.000 description 20
- 235000010323 ascorbic acid Nutrition 0.000 description 18
- 239000011668 ascorbic acid Substances 0.000 description 18
- 229960005070 ascorbic acid Drugs 0.000 description 18
- 239000000243 solution Substances 0.000 description 18
- 240000008067 Cucumis sativus Species 0.000 description 16
- 240000003768 Solanum lycopersicum Species 0.000 description 16
- 230000000694 effects Effects 0.000 description 16
- 239000002689 soil Substances 0.000 description 16
- 238000005507 spraying Methods 0.000 description 16
- 239000004563 wettable powder Substances 0.000 description 16
- 238000011156 evaluation Methods 0.000 description 15
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 14
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 14
- 239000002904 solvent Substances 0.000 description 14
- QAQJMLQRFWZOBN-LAUBAEHRSA-N L-ascorbyl-6-palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QAQJMLQRFWZOBN-LAUBAEHRSA-N 0.000 description 13
- 239000003337 fertilizer Substances 0.000 description 13
- 238000009472 formulation Methods 0.000 description 13
- 239000008187 granular material Substances 0.000 description 13
- 239000011786 L-ascorbyl-6-palmitate Substances 0.000 description 12
- 239000005869 Pyraclostrobin Substances 0.000 description 12
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 description 12
- 235000013399 edible fruits Nutrition 0.000 description 10
- 239000008399 tap water Substances 0.000 description 10
- 235000020679 tap water Nutrition 0.000 description 10
- 241000254173 Coleoptera Species 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 235000010385 ascorbyl palmitate Nutrition 0.000 description 8
- 230000001629 suppression Effects 0.000 description 8
- 244000068988 Glycine max Species 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 240000007594 Oryza sativa Species 0.000 description 6
- 235000007164 Oryza sativa Nutrition 0.000 description 6
- 238000003973 irrigation Methods 0.000 description 6
- 230000002262 irrigation Effects 0.000 description 6
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 235000009566 rice Nutrition 0.000 description 6
- 241000239290 Araneae Species 0.000 description 5
- 241000258937 Hemiptera Species 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 241001414989 Thysanoptera Species 0.000 description 5
- 239000000642 acaricide Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 5
- 238000007605 air drying Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 241000255925 Diptera Species 0.000 description 4
- 235000010469 Glycine max Nutrition 0.000 description 4
- 235000000072 L-ascorbyl-6-palmitate Nutrition 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 235000002595 Solanum tuberosum Nutrition 0.000 description 4
- 244000061456 Solanum tuberosum Species 0.000 description 4
- 241000209140 Triticum Species 0.000 description 4
- 235000021307 Triticum Nutrition 0.000 description 4
- 208000027418 Wounds and injury Diseases 0.000 description 4
- 230000000895 acaricidal effect Effects 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 206010016165 failure to thrive Diseases 0.000 description 4
- 208000014674 injury Diseases 0.000 description 4
- 238000011081 inoculation Methods 0.000 description 4
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 230000008635 plant growth Effects 0.000 description 4
- 239000003375 plant hormone Substances 0.000 description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 230000003612 virological effect Effects 0.000 description 4
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 3
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 description 3
- HOKKPVIRMVDYPB-UVTDQMKNSA-N (Z)-thiacloprid Chemical compound C1=NC(Cl)=CC=C1CN1C(=N/C#N)/SCC1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 description 3
- 0 *OC(CO)C(C(O)=C1O*)OC1=O Chemical compound *OC(CO)C(C(O)=C1O*)OC1=O 0.000 description 3
- 239000005875 Acetamiprid Substances 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 3
- 241000207199 Citrus Species 0.000 description 3
- 239000005888 Clothianidin Substances 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 235000003228 Lactuca sativa Nutrition 0.000 description 3
- 240000008415 Lactuca sativa Species 0.000 description 3
- 241000209504 Poaceae Species 0.000 description 3
- 239000005940 Thiacloprid Substances 0.000 description 3
- 239000005941 Thiamethoxam Substances 0.000 description 3
- 241000702308 Tomato yellow leaf curl virus Species 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 206010025482 malaise Diseases 0.000 description 3
- 230000000116 mitigating effect Effects 0.000 description 3
- 230000017074 necrotic cell death Effects 0.000 description 3
- 235000012015 potatoes Nutrition 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 208000024891 symptom Diseases 0.000 description 3
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- JLIDBLDQVAYHNE-YKALOCIXSA-N (+)-Abscisic acid Chemical compound OC(=O)/C=C(/C)\C=C\[C@@]1(O)C(C)=CC(=O)CC1(C)C JLIDBLDQVAYHNE-YKALOCIXSA-N 0.000 description 2
- CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 description 2
- 108091032973 (ribonucleotides)n+m Proteins 0.000 description 2
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 2
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 description 2
- 244000291564 Allium cepa Species 0.000 description 2
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 2
- 241000219317 Amaranthaceae Species 0.000 description 2
- 239000005730 Azoxystrobin Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 241001498622 Cixius wagneri Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241000254171 Curculionidae Species 0.000 description 2
- 108020004414 DNA Proteins 0.000 description 2
- 102000053602 DNA Human genes 0.000 description 2
- 208000035240 Disease Resistance Diseases 0.000 description 2
- 241000221785 Erysiphales Species 0.000 description 2
- 241000511010 Eustoma Species 0.000 description 2
- 239000005657 Fenpyroximate Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005906 Imidacloprid Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000131091 Lucanus cervus Species 0.000 description 2
- 235000011430 Malus pumila Nutrition 0.000 description 2
- 244000070406 Malus silvestris Species 0.000 description 2
- 235000015103 Malus silvestris Nutrition 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- 244000061176 Nicotiana tabacum Species 0.000 description 2
- 241000238814 Orthoptera Species 0.000 description 2
- 241000237509 Patinopecten sp. Species 0.000 description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000005925 Pymetrozine Substances 0.000 description 2
- 239000005663 Pyridaben Substances 0.000 description 2
- 235000014443 Pyrus communis Nutrition 0.000 description 2
- 240000001987 Pyrus communis Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 235000003953 Solanum lycopersicum var cerasiforme Nutrition 0.000 description 2
- 240000003040 Solanum lycopersicum var. cerasiforme Species 0.000 description 2
- 244000061458 Solanum melongena Species 0.000 description 2
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 2
- 241000736285 Sphagnum Species 0.000 description 2
- 229930182692 Strobilurin Natural products 0.000 description 2
- 241001454295 Tetranychidae Species 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 239000005857 Trifloxystrobin Substances 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 description 2
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 230000034994 death Effects 0.000 description 2
- 208000035475 disorder Diseases 0.000 description 2
- 125000005066 dodecenyl group Chemical group C(=CCCCCCCCCCC)* 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 235000018927 edible plant Nutrition 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- YYJNOYZRYGDPNH-MFKUBSTISA-N fenpyroximate Chemical compound C=1C=C(C(=O)OC(C)(C)C)C=CC=1CO/N=C/C=1C(C)=NN(C)C=1OC1=CC=CC=C1 YYJNOYZRYGDPNH-MFKUBSTISA-N 0.000 description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- SEEGHKWOBVVBTQ-NFMPGMCNSA-N gibberellin A7 Chemical compound C([C@@H]1C[C@]2(CC1=C)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 SEEGHKWOBVVBTQ-NFMPGMCNSA-N 0.000 description 2
- 239000003630 growth substance Substances 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- KGVPNLBXJKTABS-UHFFFAOYSA-N hymexazol Chemical compound CC1=CC(O)=NO1 KGVPNLBXJKTABS-UHFFFAOYSA-N 0.000 description 2
- 229940056881 imidacloprid Drugs 0.000 description 2
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000000411 inducer Substances 0.000 description 2
- 230000003902 lesion Effects 0.000 description 2
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002772 monosaccharides Chemical class 0.000 description 2
- 125000001802 myricyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229940105132 myristate Drugs 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229940079888 nitenpyram Drugs 0.000 description 2
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000005064 octadecenyl group Chemical group C(=CCCCCCCCCCCCCCCCC)* 0.000 description 2
- 229920001542 oligosaccharide Polymers 0.000 description 2
- 150000002482 oligosaccharides Chemical class 0.000 description 2
- 230000003071 parasitic effect Effects 0.000 description 2
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 230000035790 physiological processes and functions Effects 0.000 description 2
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 description 2
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 2
- QJBZDBLBQWFTPZ-UHFFFAOYSA-N pyrrolnitrin Chemical compound [O-][N+](=O)C1=C(Cl)C=CC=C1C1=CNC=C1Cl QJBZDBLBQWFTPZ-UHFFFAOYSA-N 0.000 description 2
- FBQQHUGEACOBDN-UHFFFAOYSA-N quinomethionate Chemical compound N1=C2SC(=O)SC2=NC2=CC(C)=CC=C21 FBQQHUGEACOBDN-UHFFFAOYSA-N 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 230000000241 respiratory effect Effects 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 235000020637 scallop Nutrition 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000009331 sowing Methods 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 238000001308 synthesis method Methods 0.000 description 2
- 125000005063 tetradecenyl group Chemical group C(=CCCCCCCCCCCCC)* 0.000 description 2
- 125000005040 tridecenyl group Chemical group C(=CCCCCCCCCCCC)* 0.000 description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 2
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 1
- YNWVFADWVLCOPU-MDWZMJQESA-N (1E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MDWZMJQESA-N 0.000 description 1
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- VIXCLRUCUMWJFF-KGLIPLIRSA-N (1R,5S)-benzobicyclon Chemical compound CS(=O)(=O)c1ccc(C(=O)C2=C(Sc3ccccc3)[C@H]3CC[C@H](C3)C2=O)c(Cl)c1 VIXCLRUCUMWJFF-KGLIPLIRSA-N 0.000 description 1
- FHNKBSDJERHDHZ-UHFFFAOYSA-N (2,4-dimethylphenyl)methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=C(C)C=C1C FHNKBSDJERHDHZ-UHFFFAOYSA-N 0.000 description 1
- RYAUSSKQMZRMAI-ALOPSCKCSA-N (2S,6R)-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1C[C@H](C)O[C@H](C)C1 RYAUSSKQMZRMAI-ALOPSCKCSA-N 0.000 description 1
- LZTIMERBDGGAJD-SNAWJCMRSA-N (2e)-2-(nitromethylidene)-1,3-thiazinane Chemical compound [O-][N+](=O)\C=C1/NCCCS1 LZTIMERBDGGAJD-SNAWJCMRSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- CXNPLSGKWMLZPZ-GIFSMMMISA-N (2r,3r,6s)-3-[[(3s)-3-amino-5-[carbamimidoyl(methyl)amino]pentanoyl]amino]-6-(4-amino-2-oxopyrimidin-1-yl)-3,6-dihydro-2h-pyran-2-carboxylic acid Chemical compound O1[C@@H](C(O)=O)[C@H](NC(=O)C[C@@H](N)CCN(C)C(N)=N)C=C[C@H]1N1C(=O)N=C(N)C=C1 CXNPLSGKWMLZPZ-GIFSMMMISA-N 0.000 description 1
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 1
- SODPIMGUZLOIPE-UHFFFAOYSA-N (4-chlorophenoxy)acetic acid Chemical compound OC(=O)COC1=CC=C(Cl)C=C1 SODPIMGUZLOIPE-UHFFFAOYSA-N 0.000 description 1
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 description 1
- PCKNFPQPGUWFHO-SXBRIOAWSA-N (Z)-flucycloxuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1)=CC=C1CO\N=C(C=1C=CC(Cl)=CC=1)\C1CC1 PCKNFPQPGUWFHO-SXBRIOAWSA-N 0.000 description 1
- CKPCAYZTYMHQEX-NBVRZTHBSA-N (e)-1-(2,4-dichlorophenyl)-n-methoxy-2-pyridin-3-ylethanimine Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=N/OC)/CC1=CC=CN=C1 CKPCAYZTYMHQEX-NBVRZTHBSA-N 0.000 description 1
- 102000040650 (ribonucleotides)n+m Human genes 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- XUHGTGGPZFJRMF-UHFFFAOYSA-N 1,3-dihydropyrazole-2-carboxylic acid Chemical compound OC(=O)N1CC=CN1 XUHGTGGPZFJRMF-UHFFFAOYSA-N 0.000 description 1
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 1
- ZZVVDIVWGXTDRQ-UHFFFAOYSA-N 1-[(4-tert-butylphenyl)methylsulfanyl]-1-butylsulfanyl-n-pyridin-3-ylmethanimine Chemical compound C=1C=CN=CC=1N=C(SCCCC)SCC1=CC=C(C(C)(C)C)C=C1 ZZVVDIVWGXTDRQ-UHFFFAOYSA-N 0.000 description 1
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 1
- 125000004973 1-butenyl group Chemical group C(=CCC)* 0.000 description 1
- 125000006039 1-hexenyl group Chemical group 0.000 description 1
- 125000006028 1-methyl-2-butenyl group Chemical group 0.000 description 1
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 description 1
- 125000005978 1-naphthyloxy group Chemical group 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- 125000006023 1-pentenyl group Chemical group 0.000 description 1
- 125000006017 1-propenyl group Chemical group 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- 125000004797 2,2,2-trichloroethoxy group Chemical group ClC(CO*)(Cl)Cl 0.000 description 1
- KNGWEAQJZJKFLI-UHFFFAOYSA-N 2,2-dimethyl-4h-1,3-benzodioxine-6-carbaldehyde Chemical class O=CC1=CC=C2OC(C)(C)OCC2=C1 KNGWEAQJZJKFLI-UHFFFAOYSA-N 0.000 description 1
- YTOPFCCWCSOHFV-UHFFFAOYSA-N 2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1CC(C)OC(C)C1 YTOPFCCWCSOHFV-UHFFFAOYSA-N 0.000 description 1
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 description 1
- CLQMBPJKHLGMQK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=CC=C1C(O)=O CLQMBPJKHLGMQK-UHFFFAOYSA-N 0.000 description 1
- CZWJCQXZZJHHRH-YCRXJPFRSA-N 2-[(1r,2r,3s,4r,5r,6s)-3-(diaminomethylideneamino)-4-[(2r,3r,4r,5s)-3-[(2s,3s,4s,5r,6s)-4,5-dihydroxy-6-(hydroxymethyl)-3-(methylamino)oxan-2-yl]oxy-4-hydroxy-4-(hydroxymethyl)-5-methyloxolan-2-yl]oxy-2,5,6-trihydroxycyclohexyl]guanidine;sulfuric acid Chemical compound OS(O)(=O)=O.OS(O)(=O)=O.OS(O)(=O)=O.CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](CO)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](N=C(N)N)[C@H](O)[C@@H](N=C(N)N)[C@H](O)[C@H]1O.CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](CO)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](N=C(N)N)[C@H](O)[C@@H](N=C(N)N)[C@H](O)[C@H]1O CZWJCQXZZJHHRH-YCRXJPFRSA-N 0.000 description 1
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 description 1
- CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 description 1
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 description 1
- SCVJRXQHFJXZFZ-KVQBGUIXSA-N 2-amino-9-[(2r,4s,5r)-4-hydroxy-5-(hydroxymethyl)oxolan-2-yl]-3h-purine-6-thione Chemical compound C1=2NC(N)=NC(=S)C=2N=CN1[C@H]1C[C@H](O)[C@@H](CO)O1 SCVJRXQHFJXZFZ-KVQBGUIXSA-N 0.000 description 1
- 125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 1
- JLYFCTQDENRSOL-UHFFFAOYSA-N 2-chloro-N-(2,4-dimethylthiophen-3-yl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound COCC(C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-UHFFFAOYSA-N 0.000 description 1
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 description 1
- 125000006012 2-chloroethoxy group Chemical group 0.000 description 1
- 125000006040 2-hexenyl group Chemical group 0.000 description 1
- 125000006029 2-methyl-2-butenyl group Chemical group 0.000 description 1
- 125000004493 2-methylbut-1-yl group Chemical group CC(C*)CC 0.000 description 1
- 125000006024 2-pentenyl group Chemical group 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 description 1
- YHRJAJWWHFGBMV-UHFFFAOYSA-N 3-(1-methylpyrrolidin-2-yl)pyridine;sulfuric acid Chemical compound OS(O)(=O)=O.CN1CCCC1C1=CC=CN=C1 YHRJAJWWHFGBMV-UHFFFAOYSA-N 0.000 description 1
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 description 1
- 125000006041 3-hexenyl group Chemical group 0.000 description 1
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 1
- RQDJADAKIFFEKQ-UHFFFAOYSA-N 4-(4-chlorophenyl)-2-phenyl-2-(1,2,4-triazol-1-ylmethyl)butanenitrile Chemical compound C1=CC(Cl)=CC=C1CCC(C=1C=CC=CC=1)(C#N)CN1N=CN=C1 RQDJADAKIFFEKQ-UHFFFAOYSA-N 0.000 description 1
- 125000006042 4-hexenyl group Chemical group 0.000 description 1
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- 125000006043 5-hexenyl group Chemical group 0.000 description 1
- FFISWZPYNKWIRR-UHFFFAOYSA-N 5-oxidophenazin-5-ium Chemical compound C1=CC=C2[N+]([O-])=C(C=CC=C3)C3=NC2=C1 FFISWZPYNKWIRR-UHFFFAOYSA-N 0.000 description 1
- 239000005660 Abamectin Substances 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 description 1
- 241001600124 Acidovorax avenae Species 0.000 description 1
- 239000005652 Acrinathrin Substances 0.000 description 1
- 241000256173 Aedes albopictus Species 0.000 description 1
- 241000743339 Agrostis Species 0.000 description 1
- 241000218473 Agrotis Species 0.000 description 1
- XKJMBINCVNINCA-UHFFFAOYSA-N Alfalone Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XKJMBINCVNINCA-UHFFFAOYSA-N 0.000 description 1
- 235000005254 Allium ampeloprasum Nutrition 0.000 description 1
- 240000006108 Allium ampeloprasum Species 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 244000036975 Ambrosia artemisiifolia Species 0.000 description 1
- 235000003129 Ambrosia artemisiifolia var elatior Nutrition 0.000 description 1
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical compound NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical class [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 235000003840 Amygdalus nana Nutrition 0.000 description 1
- 244000296825 Amygdalus nana Species 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 241001425390 Aphis fabae Species 0.000 description 1
- 241001600408 Aphis gossypii Species 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 240000005528 Arctium lappa Species 0.000 description 1
- 235000003130 Arctium lappa Nutrition 0.000 description 1
- 235000008078 Arctium minus Nutrition 0.000 description 1
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 1
- 240000006891 Artemisia vulgaris Species 0.000 description 1
- 241000238421 Arthropoda Species 0.000 description 1
- 244000003416 Asparagus officinalis Species 0.000 description 1
- 235000005340 Asparagus officinalis Nutrition 0.000 description 1
- 241000208838 Asteraceae Species 0.000 description 1
- 229930192334 Auxin Natural products 0.000 description 1
- 235000000832 Ayote Nutrition 0.000 description 1
- 208000035143 Bacterial infection Diseases 0.000 description 1
- 241000254127 Bemisia tabaci Species 0.000 description 1
- 239000005471 Benfluralin Substances 0.000 description 1
- 239000005472 Bensulfuron methyl Substances 0.000 description 1
- RRNIZKPFKNDSRS-UHFFFAOYSA-N Bensulide Chemical compound CC(C)OP(=S)(OC(C)C)SCCNS(=O)(=O)C1=CC=CC=C1 RRNIZKPFKNDSRS-UHFFFAOYSA-N 0.000 description 1
- 239000005476 Bentazone Substances 0.000 description 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 239000005653 Bifenazate Substances 0.000 description 1
- 241001450781 Bipolaris oryzae Species 0.000 description 1
- 239000005740 Boscalid Substances 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 241000256593 Brachycaudus schwartzi Species 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000005489 Bromoxynil Substances 0.000 description 1
- 239000005885 Buprofezin Substances 0.000 description 1
- 241000589638 Burkholderia glumae Species 0.000 description 1
- 241000134107 Burkholderia plantarii Species 0.000 description 1
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 239000005745 Captan Substances 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 241000701489 Cauliflower mosaic virus Species 0.000 description 1
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
- RAPBNVDSDCTNRC-UHFFFAOYSA-N Chlorobenzilate Chemical compound C=1C=C(Cl)C=CC=1C(O)(C(=O)OCC)C1=CC=C(Cl)C=C1 RAPBNVDSDCTNRC-UHFFFAOYSA-N 0.000 description 1
- 239000005747 Chlorothalonil Substances 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- 239000005887 Chromafenozide Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 241000395107 Cladosporium cucumerinum Species 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- 241000222235 Colletotrichum orbiculare Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000609455 Corynespora cassiicola Species 0.000 description 1
- 241000270722 Crocodylidae Species 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 235000009849 Cucumis sativus Nutrition 0.000 description 1
- 241000219122 Cucurbita Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 239000005889 Cyantraniliprole Substances 0.000 description 1
- DFCAFRGABIXSDS-UHFFFAOYSA-N Cycloate Chemical compound CCSC(=O)N(CC)C1CCCCC1 DFCAFRGABIXSDS-UHFFFAOYSA-N 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 239000005757 Cyproconazole Substances 0.000 description 1
- 239000005758 Cyprodinil Substances 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 1
- 240000004585 Dactylis glomerata Species 0.000 description 1
- 239000005975 Daminozide Substances 0.000 description 1
- NOQGZXFMHARMLW-UHFFFAOYSA-N Daminozide Chemical compound CN(C)NC(=O)CCC(O)=O NOQGZXFMHARMLW-UHFFFAOYSA-N 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- 239000005644 Dazomet Substances 0.000 description 1
- SBJKKFFYIZUCET-JLAZNSOCSA-N Dehydro-L-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(=O)C1=O SBJKKFFYIZUCET-JLAZNSOCSA-N 0.000 description 1
- SBJKKFFYIZUCET-UHFFFAOYSA-N Dehydroascorbic acid Natural products OCC(O)C1OC(=O)C(=O)C1=O SBJKKFFYIZUCET-UHFFFAOYSA-N 0.000 description 1
- 239000005892 Deltamethrin Substances 0.000 description 1
- 241000489975 Diabrotica Species 0.000 description 1
- 239000005504 Dicamba Substances 0.000 description 1
- URDNHJIVMYZFRT-UHFFFAOYSA-N Diclobutrazol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)CC1=CC=C(Cl)C=C1Cl URDNHJIVMYZFRT-UHFFFAOYSA-N 0.000 description 1
- LWLJUMBEZJHXHV-UHFFFAOYSA-N Dienochlor Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C1(Cl)C1(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LWLJUMBEZJHXHV-UHFFFAOYSA-N 0.000 description 1
- 239000005760 Difenoconazole Substances 0.000 description 1
- 239000005893 Diflubenzuron Substances 0.000 description 1
- 239000005507 Diflufenican Substances 0.000 description 1
- 239000005947 Dimethoate Substances 0.000 description 1
- 239000005761 Dimethomorph Substances 0.000 description 1
- QAHFOPIILNICLA-UHFFFAOYSA-N Diphenamid Chemical compound C=1C=CC=CC=1C(C(=O)N(C)C)C1=CC=CC=C1 QAHFOPIILNICLA-UHFFFAOYSA-N 0.000 description 1
- 239000005764 Dithianon Substances 0.000 description 1
- YUBJPYNSGLJZPQ-UHFFFAOYSA-N Dithiopyr Chemical compound CSC(=O)C1=C(C(F)F)N=C(C(F)(F)F)C(C(=O)SC)=C1CC(C)C YUBJPYNSGLJZPQ-UHFFFAOYSA-N 0.000 description 1
- 239000005510 Diuron Substances 0.000 description 1
- 244000058871 Echinochloa crus-galli Species 0.000 description 1
- 239000005894 Emamectin Substances 0.000 description 1
- 241001125671 Eretmochelys imbricata Species 0.000 description 1
- 241000221787 Erysiphe Species 0.000 description 1
- BXEHUCNTIZGSOJ-UHFFFAOYSA-N Esprocarb Chemical compound CC(C)C(C)N(CC)C(=O)SCC1=CC=CC=C1 BXEHUCNTIZGSOJ-UHFFFAOYSA-N 0.000 description 1
- 239000005896 Etofenprox Substances 0.000 description 1
- 239000005897 Etoxazole Substances 0.000 description 1
- 239000005775 Fenbuconazole Substances 0.000 description 1
- HMIBKHHNXANVHR-UHFFFAOYSA-N Fenothiocarb Chemical compound CN(C)C(=O)SCCCCOC1=CC=CC=C1 HMIBKHHNXANVHR-UHFFFAOYSA-N 0.000 description 1
- 239000005778 Fenpropimorph Substances 0.000 description 1
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 1
- 239000005899 Fipronil Substances 0.000 description 1
- 239000005780 Fluazinam Substances 0.000 description 1
- LXMQMMSGERCRSU-UHFFFAOYSA-N Fluotrimazole Chemical compound FC(F)(F)C1=CC=CC(C(C=2C=CC=CC=2)(C=2C=CC=CC=2)N2N=CN=C2)=C1 LXMQMMSGERCRSU-UHFFFAOYSA-N 0.000 description 1
- AOQMRUTZEYVDIL-UHFFFAOYSA-N Flupoxam Chemical compound C=1C=C(Cl)C(COCC(F)(F)C(F)(F)F)=CC=1N1N=C(C(=O)N)N=C1C1=CC=CC=C1 AOQMRUTZEYVDIL-UHFFFAOYSA-N 0.000 description 1
- 239000005786 Flutolanil Substances 0.000 description 1
- AIKKULXCBHRFOS-UHFFFAOYSA-N Formothion Chemical compound COP(=S)(OC)SCC(=O)N(C)C=O AIKKULXCBHRFOS-UHFFFAOYSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 241000221778 Fusarium fujikuroi Species 0.000 description 1
- 241000223195 Fusarium graminearum Species 0.000 description 1
- 241000223221 Fusarium oxysporum Species 0.000 description 1
- 241000702463 Geminiviridae Species 0.000 description 1
- 229930191978 Gibberellin Natural products 0.000 description 1
- RSQSQJNRHICNNH-UHFFFAOYSA-N Gibberellin A4 Natural products OC(=O)C1C2(CC3=C)CC3CCC2C2(OC3=O)C1C3(C)C(O)CC2 RSQSQJNRHICNNH-UHFFFAOYSA-N 0.000 description 1
- HHDWSDSMWJQURA-UHFFFAOYSA-N Gibberellin A51 Natural products C12CCC(C3)C(=C)CC23C(C(O)=O)C2C3(C)C(=O)OC21CC(O)C3 HHDWSDSMWJQURA-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000005561 Glufosinate Substances 0.000 description 1
- 239000005562 Glyphosate Substances 0.000 description 1
- PDYXIVPKOMYDOK-UHFFFAOYSA-N Glyphosate-monoammonium Chemical class [NH4+].OC(=O)CNCP(O)([O-])=O PDYXIVPKOMYDOK-UHFFFAOYSA-N 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- CAWXEEYDBZRFPE-UHFFFAOYSA-N Hexazinone Chemical compound O=C1N(C)C(N(C)C)=NC(=O)N1C1CCCCC1 CAWXEEYDBZRFPE-UHFFFAOYSA-N 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 235000008694 Humulus lupulus Nutrition 0.000 description 1
- 244000025221 Humulus lupulus Species 0.000 description 1
- 239000005981 Imazaquin Substances 0.000 description 1
- 239000005567 Imazosulfuron Substances 0.000 description 1
- NAGRVUXEKKZNHT-UHFFFAOYSA-N Imazosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N3C=CC=CC3=NC=2Cl)=N1 NAGRVUXEKKZNHT-UHFFFAOYSA-N 0.000 description 1
- 239000005907 Indoxacarb Substances 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 239000005867 Iprodione Substances 0.000 description 1
- JLLJHQLUZAKJFH-UHFFFAOYSA-N Isouron Chemical compound CN(C)C(=O)NC=1C=C(C(C)(C)C)ON=1 JLLJHQLUZAKJFH-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FAIXYKHYOGVFKA-UHFFFAOYSA-N Kinetin Natural products N=1C=NC=2N=CNC=2C=1N(C)C1=CC=CO1 FAIXYKHYOGVFKA-UHFFFAOYSA-N 0.000 description 1
- 150000000996 L-ascorbic acids Chemical class 0.000 description 1
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 description 1
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- 241001177117 Lasioderma serricorne Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000258916 Leptinotarsa decemlineata Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 239000005573 Linuron Substances 0.000 description 1
- 241000209082 Lolium Species 0.000 description 1
- 239000005574 MCPA Substances 0.000 description 1
- 241001330975 Magnaporthe oryzae Species 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 239000005802 Mancozeb Substances 0.000 description 1
- 239000005805 Mepanipyrim Substances 0.000 description 1
- 239000005578 Mesotrione Substances 0.000 description 1
- 239000005807 Metalaxyl Substances 0.000 description 1
- 239000005956 Metaldehyde Substances 0.000 description 1
- 239000005918 Milbemectin Substances 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- HRYILSDLIGTCOP-UHFFFAOYSA-N N-benzoylurea Chemical compound NC(=O)NC(=O)C1=CC=CC=C1 HRYILSDLIGTCOP-UHFFFAOYSA-N 0.000 description 1
- NWBJYWHLCVSVIJ-UHFFFAOYSA-N N-benzyladenine Chemical compound N=1C=NC=2NC=NC=2C=1NCC1=CC=CC=C1 NWBJYWHLCVSVIJ-UHFFFAOYSA-N 0.000 description 1
- 244000187664 Nerium oleander Species 0.000 description 1
- 241001556089 Nilaparvata lugens Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 241000346285 Ostrinia furnacalis Species 0.000 description 1
- 241001147398 Ostrinia nubilalis Species 0.000 description 1
- CHNUNORXWHYHNE-UHFFFAOYSA-N Oxadiazon Chemical compound C1=C(Cl)C(OC(C)C)=CC(N2C(OC(=N2)C(C)(C)C)=O)=C1Cl CHNUNORXWHYHNE-UHFFFAOYSA-N 0.000 description 1
- KYGZCKSPAKDVKC-UHFFFAOYSA-N Oxolinic acid Chemical compound C1=C2N(CC)C=C(C(O)=O)C(=O)C2=CC2=C1OCO2 KYGZCKSPAKDVKC-UHFFFAOYSA-N 0.000 description 1
- JAYZFNIOOYPIAH-UHFFFAOYSA-N Oxydeprofos Chemical compound CCS(=O)CC(C)SP(=O)(OC)OC JAYZFNIOOYPIAH-UHFFFAOYSA-N 0.000 description 1
- 241000736122 Parastagonospora nodorum Species 0.000 description 1
- 241000222291 Passalora fulva Species 0.000 description 1
- 241000588701 Pectobacterium carotovorum Species 0.000 description 1
- 239000005813 Penconazole Substances 0.000 description 1
- 239000005591 Pendimethalin Substances 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 241001608567 Phaedon cochleariae Species 0.000 description 1
- XPFRXWCVYUEORT-UHFFFAOYSA-N Phenacemide Chemical compound NC(=O)NC(=O)CC1=CC=CC=C1 XPFRXWCVYUEORT-UHFFFAOYSA-N 0.000 description 1
- 239000005921 Phosmet Substances 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 241001270527 Phyllosticta citrullina Species 0.000 description 1
- 241000233622 Phytophthora infestans Species 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 241000758706 Piperaceae Species 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 206010035148 Plague Diseases 0.000 description 1
- 244000134552 Plantago ovata Species 0.000 description 1
- 235000003421 Plantago ovata Nutrition 0.000 description 1
- 241000317981 Podosphaera fuliginea Species 0.000 description 1
- 229930182764 Polyoxin Natural products 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000005820 Prochloraz Substances 0.000 description 1
- RSVPPPHXAASNOL-UHFFFAOYSA-N Prodiamine Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C(N)=C1[N+]([O-])=O RSVPPPHXAASNOL-UHFFFAOYSA-N 0.000 description 1
- 239000005821 Propamocarb Substances 0.000 description 1
- 239000005823 Propineb Substances 0.000 description 1
- 239000005601 Propoxycarbazone Substances 0.000 description 1
- 239000005604 Prosulfuron Substances 0.000 description 1
- LTUNNEGNEKBSEH-UHFFFAOYSA-N Prosulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)CCC(F)(F)F)=N1 LTUNNEGNEKBSEH-UHFFFAOYSA-N 0.000 description 1
- 239000005825 Prothioconazole Substances 0.000 description 1
- 235000011432 Prunus Nutrition 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 241000521936 Pseudomonas amygdali pv. lachrymans Species 0.000 description 1
- 239000009223 Psyllium Substances 0.000 description 1
- 241000737257 Pteris <genus> Species 0.000 description 1
- 241001123569 Puccinia recondita Species 0.000 description 1
- BGNQYGRXEXDAIQ-UHFFFAOYSA-N Pyrazosulfuron-ethyl Chemical group C1=NN(C)C(S(=O)(=O)NC(=O)NC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OCC BGNQYGRXEXDAIQ-UHFFFAOYSA-N 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- 239000005926 Pyridalyl Substances 0.000 description 1
- 239000005606 Pyridate Substances 0.000 description 1
- JTZCTMAVMHRNTR-UHFFFAOYSA-N Pyridate Chemical compound CCCCCCCCSC(=O)OC1=CC(Cl)=NN=C1C1=CC=CC=C1 JTZCTMAVMHRNTR-UHFFFAOYSA-N 0.000 description 1
- 239000005927 Pyriproxyfen Substances 0.000 description 1
- CNILNQMBAHKMFS-UHFFFAOYSA-M Pyrithiobac-sodium Chemical compound [Na+].COC1=CC(OC)=NC(SC=2C(=C(Cl)C=CC=2)C([O-])=O)=N1 CNILNQMBAHKMFS-UHFFFAOYSA-M 0.000 description 1
- 244000088415 Raphanus sativus Species 0.000 description 1
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 1
- 241000125167 Rhopalosiphum padi Species 0.000 description 1
- 239000005616 Rimsulfuron Substances 0.000 description 1
- OVVGHDNPYGTYIT-VHBGUFLRSA-N Robinobiose Natural products O(C[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)O1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](C)O1 OVVGHDNPYGTYIT-VHBGUFLRSA-N 0.000 description 1
- PNAAEIYEUKNTMO-UHFFFAOYSA-N S-Seven Chemical compound C=1C=CC=CC=1P(=S)(OCC)OC1=CC=C(Cl)C=C1Cl PNAAEIYEUKNTMO-UHFFFAOYSA-N 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 101000984731 Salvia officinalis (+)-bornyl diphosphate synthase, chloroplastic Proteins 0.000 description 1
- 235000010842 Sarcandra glabra Nutrition 0.000 description 1
- 240000004274 Sarcandra glabra Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 244000040738 Sesamum orientale Species 0.000 description 1
- 108020004682 Single-Stranded DNA Proteins 0.000 description 1
- 241000254152 Sitophilus oryzae Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 240000003829 Sorghum propinquum Species 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- 235000009337 Spinacia oleracea Nutrition 0.000 description 1
- 244000300264 Spinacia oleracea Species 0.000 description 1
- 239000005930 Spinosad Substances 0.000 description 1
- 239000005664 Spirodiclofen Substances 0.000 description 1
- 241000208000 Striga Species 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 235000021536 Sugar beet Nutrition 0.000 description 1
- 239000005839 Tebuconazole Substances 0.000 description 1
- 239000005937 Tebufenozide Substances 0.000 description 1
- 239000005658 Tebufenpyrad Substances 0.000 description 1
- 241000488589 Tetranychus kanzawai Species 0.000 description 1
- QHTQREMOGMZHJV-UHFFFAOYSA-N Thiobencarb Chemical compound CCN(CC)C(=O)SCC1=CC=C(Cl)C=C1 QHTQREMOGMZHJV-UHFFFAOYSA-N 0.000 description 1
- 239000005842 Thiophanate-methyl Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 241000723873 Tobacco mosaic virus Species 0.000 description 1
- 241000710145 Tomato bushy stunt virus Species 0.000 description 1
- 241000543828 Tomato yellow leaf curl Sardinia virus Species 0.000 description 1
- 241001271990 Tomicus piniperda Species 0.000 description 1
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 description 1
- 239000005846 Triadimenol Substances 0.000 description 1
- NHTFLYKPEGXOAN-UHFFFAOYSA-N Trichlamide Chemical compound CCCCOC(C(Cl)(Cl)Cl)NC(=O)C1=CC=CC=C1O NHTFLYKPEGXOAN-UHFFFAOYSA-N 0.000 description 1
- 239000005942 Triflumuron Substances 0.000 description 1
- 244000042324 Trifolium repens Species 0.000 description 1
- 235000013540 Trifolium repens var repens Nutrition 0.000 description 1
- 241000233791 Ustilago tritici Species 0.000 description 1
- 229930195482 Validamycin Natural products 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 241001272684 Xanthomonas campestris pv. oryzae Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 241001360088 Zymoseptoria tritici Species 0.000 description 1
- BZMIHNKNQJJVRO-LVZFUZTISA-N [(e)-c-(3-chloro-2,6-dimethoxyphenyl)-n-ethoxycarbonimidoyl] benzoate Chemical compound COC=1C=CC(Cl)=C(OC)C=1C(=N/OCC)\OC(=O)C1=CC=CC=C1 BZMIHNKNQJJVRO-LVZFUZTISA-N 0.000 description 1
- FSAVDKDHPDSCTO-WQLSENKSSA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] diethyl phosphate Chemical compound CCOP(=O)(OCC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl FSAVDKDHPDSCTO-WQLSENKSSA-N 0.000 description 1
- QSGNQELHULIMSJ-POHAHGRESA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] dimethyl phosphate Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl QSGNQELHULIMSJ-POHAHGRESA-N 0.000 description 1
- INISTDXBRIBGOC-CGAIIQECSA-N [cyano-(3-phenoxyphenyl)methyl] (2s)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate Chemical compound N([C@@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-CGAIIQECSA-N 0.000 description 1
- 230000036579 abiotic stress Effects 0.000 description 1
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 1
- YLFSVIMMRPNPFK-WEQBUNFVSA-N acrinathrin Chemical compound CC1(C)[C@@H](\C=C/C(=O)OC(C(F)(F)F)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YLFSVIMMRPNPFK-WEQBUNFVSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- QGLZXHRNAYXIBU-WEVVVXLNSA-N aldicarb Chemical compound CNC(=O)O\N=C\C(C)(C)SC QGLZXHRNAYXIBU-WEVVVXLNSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229960002587 amitraz Drugs 0.000 description 1
- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- IMHBYKMAHXWHRP-UHFFFAOYSA-N anilazine Chemical compound ClC1=CC=CC=C1NC1=NC(Cl)=NC(Cl)=N1 IMHBYKMAHXWHRP-UHFFFAOYSA-N 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 235000003484 annual ragweed Nutrition 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 125000001769 aryl amino group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 1
- 239000002363 auxin Substances 0.000 description 1
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 1
- 244000269888 azena Species 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- SMDHCQAYESWHAE-UHFFFAOYSA-N benfluralin Chemical compound CCCCN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O SMDHCQAYESWHAE-UHFFFAOYSA-N 0.000 description 1
- FYZBOYWSHKHDMT-UHFFFAOYSA-N benfuracarb Chemical compound CCOC(=O)CCN(C(C)C)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 FYZBOYWSHKHDMT-UHFFFAOYSA-N 0.000 description 1
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 description 1
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 description 1
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 description 1
- ZOMSMJKLGFBRBS-UHFFFAOYSA-N bentazone Chemical compound C1=CC=C2NS(=O)(=O)N(C(C)C)C(=O)C2=C1 ZOMSMJKLGFBRBS-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- 229960001950 benzethonium chloride Drugs 0.000 description 1
- CNBGNNVCVSKAQZ-UHFFFAOYSA-N benzidamine Natural products C12=CC=CC=C2C(OCCCN(C)C)=NN1CC1=CC=CC=C1 CNBGNNVCVSKAQZ-UHFFFAOYSA-N 0.000 description 1
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000000853 biopesticidal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- OIPMQULDKWSNGX-UHFFFAOYSA-N bis[[ethoxy(oxo)phosphaniumyl]oxy]alumanyloxy-ethoxy-oxophosphanium Chemical compound [Al+3].CCO[P+]([O-])=O.CCO[P+]([O-])=O.CCO[P+]([O-])=O OIPMQULDKWSNGX-UHFFFAOYSA-N 0.000 description 1
- FUHMZYWBSHTEDZ-UHFFFAOYSA-M bispyribac-sodium Chemical compound [Na+].COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C([O-])=O)=N1 FUHMZYWBSHTEDZ-UHFFFAOYSA-M 0.000 description 1
- CXNPLSGKWMLZPZ-UHFFFAOYSA-N blasticidin-S Natural products O1C(C(O)=O)C(NC(=O)CC(N)CCN(C)C(N)=N)C=CC1N1C(=O)N=C(N)C=C1 CXNPLSGKWMLZPZ-UHFFFAOYSA-N 0.000 description 1
- 229940118790 boscalid Drugs 0.000 description 1
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 description 1
- 150000001647 brassinosteroids Chemical class 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- FOANIXZHAMJWOI-UHFFFAOYSA-N bromopropylate Chemical compound C=1C=C(Br)C=CC=1C(O)(C(=O)OC(C)C)C1=CC=C(Br)C=C1 FOANIXZHAMJWOI-UHFFFAOYSA-N 0.000 description 1
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 1
- 235000006263 bur ragweed Nutrition 0.000 description 1
- VAIZTNZGPYBOGF-UHFFFAOYSA-N butyl 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoate Chemical group C1=CC(OC(C)C(=O)OCCCC)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 VAIZTNZGPYBOGF-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 229940117949 captan Drugs 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- RXDMAYSSBPYBFW-PKFCDNJMSA-N carpropamide Chemical compound N([C@@H](C)C=1C=CC(Cl)=CC=1)C(=O)[C@@]1(CC)[C@H](C)C1(Cl)Cl RXDMAYSSBPYBFW-PKFCDNJMSA-N 0.000 description 1
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 1
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 1
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 1
- WYKYKTKDBLFHCY-UHFFFAOYSA-N chloridazon Chemical compound O=C1C(Cl)=C(N)C=NN1C1=CC=CC=C1 WYKYKTKDBLFHCY-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- HPNSNYBUADCFDR-UHFFFAOYSA-N chromafenozide Chemical compound CC1=CC(C)=CC(C(=O)N(NC(=O)C=2C(=C3CCCOC3=CC=2)C)C(C)(C)C)=C1 HPNSNYBUADCFDR-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 235000003488 common ragweed Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- DVBUIBGJRQBEDP-UHFFFAOYSA-N cyantraniliprole Chemical compound CNC(=O)C1=CC(C#N)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl DVBUIBGJRQBEDP-UHFFFAOYSA-N 0.000 description 1
- ACMXQHFNODYQAT-UHFFFAOYSA-N cyflufenamid Chemical compound FC1=CC=C(C(F)(F)F)C(C(NOCC2CC2)=NC(=O)CC=2C=CC=CC=2)=C1F ACMXQHFNODYQAT-UHFFFAOYSA-N 0.000 description 1
- 229960001591 cyfluthrin Drugs 0.000 description 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 1
- WCMMILVIRZAPLE-UHFFFAOYSA-M cyhexatin Chemical compound C1CCCCC1[Sn](C1CCCCC1)(O)C1CCCCC1 WCMMILVIRZAPLE-UHFFFAOYSA-M 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- HAORKNGNJCEJBX-UHFFFAOYSA-N cyprodinil Chemical compound N=1C(C)=CC(C2CC2)=NC=1NC1=CC=CC=C1 HAORKNGNJCEJBX-UHFFFAOYSA-N 0.000 description 1
- 239000004062 cytokinin Substances 0.000 description 1
- UQHKFADEQIVWID-UHFFFAOYSA-N cytokinin Natural products C1=NC=2C(NCC=C(CO)C)=NC=NC=2N1C1CC(O)C(CO)O1 UQHKFADEQIVWID-UHFFFAOYSA-N 0.000 description 1
- QAYICIQNSGETAS-UHFFFAOYSA-N dazomet Chemical compound CN1CSC(=S)N(C)C1 QAYICIQNSGETAS-UHFFFAOYSA-N 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- 125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000020960 dehydroascorbic acid Nutrition 0.000 description 1
- 239000011615 dehydroascorbic acid Substances 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- LNNWVNGFPYWNQE-GMIGKAJZSA-N desomorphine Chemical compound C1C2=CC=C(O)C3=C2[C@]24CCN(C)[C@H]1[C@@H]2CCC[C@@H]4O3 LNNWVNGFPYWNQE-GMIGKAJZSA-N 0.000 description 1
- FCRACOPGPMPSHN-UHFFFAOYSA-N desoxyabscisic acid Natural products OC(=O)C=C(C)C=CC1C(C)=CC(=O)CC1(C)C FCRACOPGPMPSHN-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 229950001327 dichlorvos Drugs 0.000 description 1
- UOAMTSKGCBMZTC-UHFFFAOYSA-N dicofol Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)(Cl)Cl)(O)C1=CC=C(Cl)C=C1 UOAMTSKGCBMZTC-UHFFFAOYSA-N 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 1
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 description 1
- 229940019503 diflubenzuron Drugs 0.000 description 1
- WYEHFWKAOXOVJD-UHFFFAOYSA-N diflufenican Chemical compound FC1=CC(F)=CC=C1NC(=O)C1=CC=CN=C1OC1=CC=CC(C(F)(F)F)=C1 WYEHFWKAOXOVJD-UHFFFAOYSA-N 0.000 description 1
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 description 1
- 229960001162 dihydrostreptomycin sulfate Drugs 0.000 description 1
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
- SPCNPOWOBZQWJK-UHFFFAOYSA-N dimethoxy-(2-propan-2-ylsulfanylethylsulfanyl)-sulfanylidene-$l^{5}-phosphane Chemical compound COP(=S)(OC)SCCSC(C)C SPCNPOWOBZQWJK-UHFFFAOYSA-N 0.000 description 1
- FBOUIAKEJMZPQG-BLXFFLACSA-N diniconazole-M Chemical compound C1=NC=NN1/C([C@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-BLXFFLACSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 150000002016 disaccharides Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- PYZSVQVRHDXQSL-UHFFFAOYSA-N dithianon Chemical compound S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O PYZSVQVRHDXQSL-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 1
- AWZOLILCOUMRDG-UHFFFAOYSA-N edifenphos Chemical compound C=1C=CC=CC=1SP(=O)(OCC)SC1=CC=CC=C1 AWZOLILCOUMRDG-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- RDYMFSUJUZBWLH-UHFFFAOYSA-N endosulfan Chemical compound C12COS(=O)OCC2C2(Cl)C(Cl)=C(Cl)C1(Cl)C2(Cl)Cl RDYMFSUJUZBWLH-UHFFFAOYSA-N 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- RIZMRRKBZQXFOY-UHFFFAOYSA-N ethion Chemical compound CCOP(=S)(OCC)SCSP(=S)(OCC)OCC RIZMRRKBZQXFOY-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000004705 ethylthio group Chemical group C(C)S* 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 1
- HJUFTIJOISQSKQ-UHFFFAOYSA-N fenoxycarb Chemical compound C1=CC(OCCNC(=O)OCC)=CC=C1OC1=CC=CC=C1 HJUFTIJOISQSKQ-UHFFFAOYSA-N 0.000 description 1
- WDQNIWFZKXZFAY-UHFFFAOYSA-M fentin acetate Chemical compound CC([O-])=O.C1=CC=CC=C1[Sn+](C=1C=CC=CC=1)C1=CC=CC=C1 WDQNIWFZKXZFAY-UHFFFAOYSA-M 0.000 description 1
- BFWMWWXRWVJXSE-UHFFFAOYSA-M fentin hydroxide Chemical compound C=1C=CC=CC=1[Sn](C=1C=CC=CC=1)(O)C1=CC=CC=C1 BFWMWWXRWVJXSE-UHFFFAOYSA-M 0.000 description 1
- 229940013764 fipronil Drugs 0.000 description 1
- UZCGKGPEKUCDTF-UHFFFAOYSA-N fluazinam Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=C(Cl)C([N+]([O-])=O)=C1NC1=NC=C(C(F)(F)F)C=C1Cl UZCGKGPEKUCDTF-UHFFFAOYSA-N 0.000 description 1
- GINFBXXYGUODAT-UHFFFAOYSA-N flucarbazone Chemical compound O=C1N(C)C(OC)=NN1C(=O)NS(=O)(=O)C1=CC=CC=C1OC(F)(F)F GINFBXXYGUODAT-UHFFFAOYSA-N 0.000 description 1
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 1
- FOUWCSDKDDHKQP-UHFFFAOYSA-N flumioxazin Chemical compound FC1=CC=2OCC(=O)N(CC#C)C=2C=C1N(C1=O)C(=O)C2=C1CCCC2 FOUWCSDKDDHKQP-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- IPENDKRRWFURRE-UHFFFAOYSA-N fluoroimide Chemical compound C1=CC(F)=CC=C1N1C(=O)C(Cl)=C(Cl)C1=O IPENDKRRWFURRE-UHFFFAOYSA-N 0.000 description 1
- 125000004785 fluoromethoxy group Chemical group [H]C([H])(F)O* 0.000 description 1
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 description 1
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 125000002519 galactosyl group Chemical group C1([C@H](O)[C@@H](O)[C@@H](O)[C@H](O1)CO)* 0.000 description 1
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 description 1
- 239000003448 gibberellin Substances 0.000 description 1
- RSQSQJNRHICNNH-NFMPGMCNSA-N gibberellin A4 Chemical compound C([C@@H]1C[C@]2(CC1=C)[C@H]1C(O)=O)C[C@H]2[C@@]2(OC3=O)[C@H]1[C@@]3(C)[C@@H](O)CC2 RSQSQJNRHICNNH-NFMPGMCNSA-N 0.000 description 1
- SEEGHKWOBVVBTQ-UHFFFAOYSA-N gibberellin GA7 Natural products OC(=O)C1C2(CC3=C)CC3CCC2C2(C=CC3O)C1C3(C)C(=O)O2 SEEGHKWOBVVBTQ-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000001279 glycosylating effect Effects 0.000 description 1
- 229940097068 glyphosate Drugs 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000000755 henicosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 1
- 230000003054 hormonal effect Effects 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 239000003501 hydroponics Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- AGKSTYPVMZODRV-UHFFFAOYSA-N imibenconazole Chemical compound C1=CC(Cl)=CC=C1CSC(CN1N=CN=C1)=NC1=CC=C(Cl)C=C1Cl AGKSTYPVMZODRV-UHFFFAOYSA-N 0.000 description 1
- RONFGUROBZGJKP-UHFFFAOYSA-N iminoctadine Chemical compound NC(N)=NCCCCCCCCNCCCCCCCCN=C(N)N RONFGUROBZGJKP-UHFFFAOYSA-N 0.000 description 1
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- NRXQIUSYPAHGNM-UHFFFAOYSA-N ioxynil Chemical compound OC1=C(I)C=C(C#N)C=C1I NRXQIUSYPAHGNM-UHFFFAOYSA-N 0.000 description 1
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- 125000002510 isobutoxy group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])O* 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- HOQADATXFBOEGG-UHFFFAOYSA-N isofenphos Chemical compound CCOP(=S)(NC(C)C)OC1=CC=CC=C1C(=O)OC(C)C HOQADATXFBOEGG-UHFFFAOYSA-N 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 description 1
- PVTHJAPFENJVNC-MHRBZPPQSA-N kasugamycin Chemical compound N[C@H]1C[C@H](NC(=N)C(O)=O)[C@@H](C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O PVTHJAPFENJVNC-MHRBZPPQSA-N 0.000 description 1
- QANMHLXAZMSUEX-UHFFFAOYSA-N kinetin Chemical compound N=1C=NC=2N=CNC=2C=1NCC1=CC=CO1 QANMHLXAZMSUEX-UHFFFAOYSA-N 0.000 description 1
- 229960001669 kinetin Drugs 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 239000008155 medical solution Substances 0.000 description 1
- XIGAUIHYSDTJHW-UHFFFAOYSA-N mefenacet Chemical compound N=1C2=CC=CC=C2SC=1OCC(=O)N(C)C1=CC=CC=C1 XIGAUIHYSDTJHW-UHFFFAOYSA-N 0.000 description 1
- CIFWZNRJIBNXRE-UHFFFAOYSA-N mepanipyrim Chemical compound CC#CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 CIFWZNRJIBNXRE-UHFFFAOYSA-N 0.000 description 1
- BCTQJXQXJVLSIG-UHFFFAOYSA-N mepronil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C)=C1 BCTQJXQXJVLSIG-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 description 1
- GKKDCARASOJPNG-UHFFFAOYSA-N metaldehyde Chemical compound CC1OC(C)OC(C)OC(C)O1 GKKDCARASOJPNG-UHFFFAOYSA-N 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- MEBQXILRKZHVCX-UHFFFAOYSA-N methidathion Chemical compound COC1=NN(CSP(=S)(OC)OC)C(=O)S1 MEBQXILRKZHVCX-UHFFFAOYSA-N 0.000 description 1
- 229950003442 methoprene Drugs 0.000 description 1
- 229930002897 methoprene Natural products 0.000 description 1
- JTHMVYBOQLDDIY-UHFFFAOYSA-N methyl 2-[(4-methyl-5-oxo-3-propoxy-1,2,4-triazole-1-carbonyl)sulfamoyl]benzoate Chemical compound O=C1N(C)C(OCCC)=NN1C(=O)NS(=O)(=O)C1=CC=CC=C1C(=O)OC JTHMVYBOQLDDIY-UHFFFAOYSA-N 0.000 description 1
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- VOEYXMAFNDNNED-UHFFFAOYSA-N metolcarb Chemical compound CNC(=O)OC1=CC=CC(C)=C1 VOEYXMAFNDNNED-UHFFFAOYSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- ZLBGSRMUSVULIE-GSMJGMFJSA-N milbemycin A3 Chemical compound O1[C@H](C)[C@@H](C)CC[C@@]11O[C@H](C\C=C(C)\C[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 ZLBGSRMUSVULIE-GSMJGMFJSA-N 0.000 description 1
- DEDOPGXGGQYYMW-UHFFFAOYSA-N molinate Chemical compound CCSC(=O)N1CCCCCC1 DEDOPGXGGQYYMW-UHFFFAOYSA-N 0.000 description 1
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 1
- 125000006606 n-butoxy group Chemical group 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003506 n-propoxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- OIXVKQDWLFHVGR-WQDIDPJDSA-N neomycin B sulfate Chemical compound OS(O)(=O)=O.N[C@@H]1[C@@H](O)[C@H](O)[C@H](CN)O[C@@H]1O[C@H]1[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](N)C[C@@H](N)[C@@H]2O)O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CN)O2)N)O[C@@H]1CO OIXVKQDWLFHVGR-WQDIDPJDSA-N 0.000 description 1
- 229940053050 neomycin sulfate Drugs 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 125000005187 nonenyl group Chemical group C(=CCCCCCCC)* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UWVQIROCRJWDKL-UHFFFAOYSA-N oxadixyl Chemical compound CC=1C=CC=C(C)C=1N(C(=O)COC)N1CCOC1=O UWVQIROCRJWDKL-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229960000321 oxolinic acid Drugs 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- RLBIQVVOMOPOHC-UHFFFAOYSA-N parathion-methyl Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C=C1 RLBIQVVOMOPOHC-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 description 1
- LKPLKUMXSAEKID-UHFFFAOYSA-N pentachloronitrobenzene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LKPLKUMXSAEKID-UHFFFAOYSA-N 0.000 description 1
- JZPKLLLUDLHCEL-UHFFFAOYSA-N pentoxazone Chemical compound O=C1C(=C(C)C)OC(=O)N1C1=CC(OC2CCCC2)=C(Cl)C=C1F JZPKLLLUDLHCEL-UHFFFAOYSA-N 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960003396 phenacemide Drugs 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- XAMUDJHXFNRLCY-UHFFFAOYSA-N phenthoate Chemical compound CCOC(=O)C(SP(=S)(OC)OC)C1=CC=CC=C1 XAMUDJHXFNRLCY-UHFFFAOYSA-N 0.000 description 1
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- LMNZTLDVJIUSHT-UHFFFAOYSA-N phosmet Chemical compound C1=CC=C2C(=O)N(CSP(=S)(OC)OC)C(=O)C2=C1 LMNZTLDVJIUSHT-UHFFFAOYSA-N 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 230000008832 photodamage Effects 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 1
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 1
- MFOUDYKPLGXPGO-UHFFFAOYSA-N propachlor Chemical compound ClCC(=O)N(C(C)C)C1=CC=CC=C1 MFOUDYKPLGXPGO-UHFFFAOYSA-N 0.000 description 1
- WZZLDXDUQPOXNW-UHFFFAOYSA-N propamocarb Chemical compound CCCOC(=O)NCCCN(C)C WZZLDXDUQPOXNW-UHFFFAOYSA-N 0.000 description 1
- PWYIUEFFPNVCMW-UHFFFAOYSA-N propaphos Chemical compound CCCOP(=O)(OCCC)OC1=CC=C(SC)C=C1 PWYIUEFFPNVCMW-UHFFFAOYSA-N 0.000 description 1
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 description 1
- WJNRPILHGGKWCK-UHFFFAOYSA-N propazine Chemical compound CC(C)NC1=NC(Cl)=NC(NC(C)C)=N1 WJNRPILHGGKWCK-UHFFFAOYSA-N 0.000 description 1
- VXPLXMJHHKHSOA-UHFFFAOYSA-N propham Chemical compound CC(C)OC(=O)NC1=CC=CC=C1 VXPLXMJHHKHSOA-UHFFFAOYSA-N 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 235000014774 prunus Nutrition 0.000 description 1
- 229940070687 psyllium Drugs 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- AEHJMNVBLRLZKK-UHFFFAOYSA-N pyridalyl Chemical group N1=CC(C(F)(F)F)=CC=C1OCCCOC1=C(Cl)C=C(OCC=C(Cl)Cl)C=C1Cl AEHJMNVBLRLZKK-UHFFFAOYSA-N 0.000 description 1
- CXJSOEPQXUCJSA-UHFFFAOYSA-N pyridaphenthion Chemical compound N1=C(OP(=S)(OCC)OCC)C=CC(=O)N1C1=CC=CC=C1 CXJSOEPQXUCJSA-UHFFFAOYSA-N 0.000 description 1
- ITKAIUGKVKDENI-UHFFFAOYSA-N pyrimidifen Chemical compound CC1=C(C)C(CCOCC)=CC=C1OCCNC1=NC=NC(CC)=C1Cl ITKAIUGKVKDENI-UHFFFAOYSA-N 0.000 description 1
- USSIUIGPBLPCDF-KEBDBYFISA-N pyriminobac-methyl Chemical group CO\N=C(/C)C1=CC=CC(OC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OC USSIUIGPBLPCDF-KEBDBYFISA-N 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
- 229960002132 pyrrolnitrin Drugs 0.000 description 1
- FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 description 1
- 235000009736 ragweed Nutrition 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- MEFOUWRMVYJCQC-UHFFFAOYSA-N rimsulfuron Chemical compound CCS(=O)(=O)C1=CC=CN=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 MEFOUWRMVYJCQC-UHFFFAOYSA-N 0.000 description 1
- 229940080817 rotenone Drugs 0.000 description 1
- JUVIOZPCNVVQFO-UHFFFAOYSA-N rotenone Natural products O1C2=C3CC(C(C)=C)OC3=CC=C2C(=O)C2C1COC1=C2C=C(OC)C(OC)=C1 JUVIOZPCNVVQFO-UHFFFAOYSA-N 0.000 description 1
- OVVGHDNPYGTYIT-BNXXONSGSA-N rutinose Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)O1 OVVGHDNPYGTYIT-BNXXONSGSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- VMSRVIHUFHQIAL-UHFFFAOYSA-M sodium;n,n-dimethylcarbamodithioate Chemical compound [Na+].CN(C)C([S-])=S VMSRVIHUFHQIAL-UHFFFAOYSA-M 0.000 description 1
- 229940014213 spinosad Drugs 0.000 description 1
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 1
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 239000004308 thiabendazole Substances 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- 229960004546 thiabendazole Drugs 0.000 description 1
- 125000004305 thiazinyl group Chemical group S1NC(=CC=C1)* 0.000 description 1
- SRVJKTDHMYAMHA-WUXMJOGZSA-N thioacetazone Chemical group CC(=O)NC1=CC=C(\C=N\NC(N)=S)C=C1 SRVJKTDHMYAMHA-WUXMJOGZSA-N 0.000 description 1
- 229960003231 thioacetazone Drugs 0.000 description 1
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- 125000005065 undecenyl group Chemical group C(=CCCCCCCCCC)* 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/62—Three oxygen atoms, e.g. ascorbic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6558—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing at least two different or differently substituted hetero rings neither condensed among themselves nor condensed with a common carbocyclic ring or ring system
- C07F9/65586—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing at least two different or differently substituted hetero rings neither condensed among themselves nor condensed with a common carbocyclic ring or ring system at least one of the hetero rings does not contain nitrogen as ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H15/00—Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
- C07H15/26—Acyclic or carbocyclic radicals, substituted by hetero rings
Definitions
- the present invention relates to a method for imparting resistance to stress to plants. More particularly, the present invention relates to a method of imparting to plants resistance to biological, physical or chemical stress that affects plant growth.
- Plants grown in farmland or ordinary households are always exposed to various biological and abiotic stresses. Cultivated crops generally tend to be less resistant to these stresses. Agricultural chemicals such as bactericides, insecticides and herbicides are used to reduce biological stress such as pests and weeds and maintain yield. However, the effects of pesticides are insufficient, if they are used incorrectly, they cause phytotoxicity, pests and weeds develop resistance to pesticides, and there are concerns about the safety of environmental organisms. In addition, environmental stresses such as temperature, moisture, illuminance, soil pH, and salt concentration are dealt with by appropriate cultivation, breeding improvement, irrigation, greenhouse and soil improvement. Attempts to impart stress resistance with plant growth regulators have been made, but the effect is not sufficient. In addition, plant viral diseases cause serious damage to important crops such as cereals, vegetables and fruit trees. However, until now no drug has been found that sufficiently exerts a practical effect on plant viral diseases.
- Non-Patent Document 1 reports that ascorbic acid is involved in disease resistance, hormonal action, etc.
- Non-Patent Document 2 reports that ascorbic acid affects plant aging.
- ascorbic acid is present in a high concentration in the plant body, even if ascorbic acid is given to the plant from the outside, its physiological influence is slight and there is almost no practical effect.
- Patent Document 1 proposes that certain derivatives of ascorbic acid are applied to plants as having a preventive and therapeutic effect on viral diseases of plants.
- Patent Document 2 discloses a composition containing an antibacterial antibiotic such as neomycin sulfate and ascorbic acid, and states that plant diseases can be suppressed by this composition.
- Vitamin 79 (2): 116-117 (2005) Horticultural studies 6 (2): 169-175
- An object of the present invention is to provide a method of imparting resistance to biological stress, physical stress or chemical stress that affects plant growth.
- R 1 ⁇ R 4 are each independently a hydrogen atom, -SO 3 H, -PO 3 H 2, a glycosyl group, or -COR 11.
- R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group.
- R 5 and R 6 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 .
- R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group.
- the substance (A) is represented by the formula (I) [However, not all R 1 to R 4 are hydrogen atoms at the same time. Or a salt thereof.
- material (A) has the formula (I) [provided that at least one of R 1 ⁇ R 4 represents a -COR 11, R 11 are, C12 ⁇ 30 alkyl group having an unsubstituted or substituted Or an unsubstituted or substituted C12-30 alkenyl group. Or a salt thereof.
- material (A) has the formula (I) [provided that at least one of R 1 ⁇ R 4 represents a -COR 11, R 11 are, C12 ⁇ 30 alkyl group having an unsubstituted or substituted Or an unsubstituted or substituted C12-30 alkenyl group. Or a salt thereof.
- R 11 are, C12 ⁇ 30 alkyl group having an unsubstituted or substituted Or an unsubstituted or substituted C12-30 alkenyl group.
- the substance (A) is represented by the formula (I) [wherein R 1 to R 4 each independently represents a hydrogen atom or —COR 11 , and at least one of R 1 to R 4 is — COR 11 is shown.
- R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group.
- At least one of -COR 11 represents R 11 therein, a C12 ⁇ 30 alkenyl group having C12 ⁇ 30 alkyl group or an unsubstituted or substituted group having an unsubstituted or substituted group. Or a salt thereof.
- the substance (A) is a water-soluble substance (A1) selected from the group consisting of a compound represented by the formula (I), a compound represented by the formula (II), and a salt thereof (A1) And a fat-soluble composition (A2) selected from the group consisting of a compound represented by formula (I), a compound represented by formula (II), and a salt thereof.
- A1 water-soluble substance selected from the group consisting of a compound represented by the formula (I), a compound represented by the formula (II), and a salt thereof.
- the stress is a biological stress caused by plant viruses, phytopathogenic bacteria, phytopathogenic fungi, pests or weeds; or high temperature, low temperature, high illuminance, low illuminance, excessive humidity, drying, salinity, acidity, pesticides,
- a composition for imparting stress resistance to plants comprising at least two substances (A) selected from the group consisting of a compound represented by formula (I), a compound represented by formula (II), and salts thereof object.
- R 1 to R 4 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 .
- R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group.
- R 5 and R 6 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 .
- R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group.
- One substance (A) is a water-soluble substance selected from the group consisting of a compound represented by formula (I), a compound represented by formula (II), and a salt thereof (A1
- the other one substance (A) is a fat-soluble substance selected from the group consisting of the compound represented by the formula (I), the compound represented by the formula (II), and a salt thereof.
- a plant stress resistance imparting agent composition comprising at least one fat-soluble substance (A2) selected from the group consisting of a compound represented by the formula (Ib), a compound represented by the formula (IIb), and a salt thereof. object.
- R 1a to R 4a each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , or a glycosyl group.
- R 5a and R 6a each independently represent a hydrogen atom, —SO 3 H, —PO 3 H 2 , or a glycosyl group.
- R 1b to R 4b each independently represents a hydrogen atom or —COR 11 . At least one of R 1b ⁇ R 4b represents a -COR 11, R 11 represents a C2 ⁇ 30 alkenyl group having C1 ⁇ 30 alkyl group or an unsubstituted or substituted group having an unsubstituted or substituted . ]
- R 5b and R 6b each independently represent a hydrogen atom or —COR 11 . At least one of R 5b and R 6b represents a -COR 11, R 11 represents a C2 ⁇ 30 alkenyl group having C1 ⁇ 30 alkyl group or an unsubstituted or substituted group having an unsubstituted or substituted . ]
- a method for reducing plant phytotoxicity caused by agricultural chemicals comprising imparting resistance to stress to a plant by the method according to any one of [1] to [6].
- the method for reducing plant phytotoxicity caused by the agricultural chemical according to [10] wherein the agricultural chemical comprises at least one selected from the group consisting of a fungicide, an insecticide, a plant growth regulator, and a herbicide.
- the method of the present invention it is possible to impart resistance to biological stress, physical stress, or chemical stress, which affects plant growth, to a plant.
- it is possible to reduce phytotoxicity caused by agricultural chemicals including substances that affect the physiological function of plants, and to reduce damage of plant diseases including viral diseases.
- it is possible to prevent a decrease in yield and quality even under poor environmental conditions such as high temperature, low temperature, drying, and soil conditions.
- the method for imparting resistance to stress according to the present invention to a plant includes applying the substance (A) to the plant.
- the substance (A) is at least one selected from the group consisting of a compound represented by the formula (I), a compound represented by the formula (II), and a salt thereof.
- R 1 to R 4 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 .
- R 5 and R 6 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 .
- the glycosyl group is a sugar residue such as a monosaccharide or a low molecular weight oligosaccharide (specifically, a partial structure of a molecule in which the hemiacetal hydroxy group of the sugar moiety is removed to form a binding position).
- monosaccharides include glucose, galactose, fructose, and rhamnose.
- oligosaccharides include rutinose, vicyanose, lactose, maltose, and sucrose.
- the glycosyl group includes, for example, a glucosyl group, a galactosyl group, a fructosyl group, a rhamnosyl group, and the like.
- the glycosyl group also includes a group in which any combination of these groups is bonded by a 1 ⁇ 2 bond, a 1 ⁇ 3 bond, a 1 ⁇ 4 bond, or a 1 ⁇ 6 bond to form a disaccharide.
- R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group.
- the term “unsubstituted” means that the group is only a group serving as a mother nucleus.
- the term “having a substituent” means that any hydrogen atom of a group serving as a mother nucleus is substituted with a group having a structure different from or the same as that of the mother nucleus.
- the “substituent” is another group substituted with a group serving as a mother nucleus.
- the number of substituents may be one, or two or more. Two or more substituents may be the same or different.
- a C1-30 alkyl group having a substituent is a group in which the parent nucleus is a C1-30 alkyl group, and any one of these hydrogen atoms is substituted with a group having a different structure (“substituent") It is.
- the “C1-30 alkyl group” in R 11 is a saturated hydrocarbon group composed of 1 to 30 carbon atoms.
- the C1-30 alkyl group may be linear or branched.
- Examples of the C1-30 alkyl group include methyl group, ethyl group, n-propyl group, n-butyl group, n-pentyl group, n-hexyl group, n-heptyl group, n-octyl group, i-propyl group, i -Butyl group, s-butyl group, t-butyl group, i-pentyl group, neopentyl group, 2-methylbutyl group, 2,2-dimethylpropyl group, i-hexyl group, heptyl group, octyl, nonyl group, decyl group , Undecyl group, dodecyl group, tridecyl group, tetradec
- the “C2-30 alkenyl group” in R 11 is an unsaturated hydrocarbon group composed of 2 to 30 carbon atoms having at least one carbon-carbon double bond.
- the C2-30 alkenyl group may be linear or branched.
- C2-30 alkenyl groups include vinyl, 1-propenyl, isopropenyl, allyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-pentenyl, 2-pentenyl, 3- Pentenyl group, 4-pentenyl group, 1-hexenyl group, 2-hexenyl group, 3-hexenyl group, 4-hexenyl group, 5-hexenyl group, 1-heptenyl group, 6-heptenyl group, 1-octenyl group, 7- Octenyl group, 1-methyl-allyl group, 2-methyl-allyl group, 1-methyl-2-butenyl group, 2-methyl-2-butenyl group, octenyl group, nonenyl group,
- Examples of a group that can be a “substituent” of a C1-30 alkyl group or a C2-30 alkenyl group include a hydroxyl group; a mercapto group; an amino group; a nitro group; a halogen atom such as a chlorine atom, a fluorine atom, and a bromine atom; Alkoxy groups such as ethoxy group, isopropoxy group, n-propoxy group, n-butoxy group, isobutoxy group, s-butoxy group and t-butoxy group; aryloxy groups such as phenoxy group and 1-naphthyloxy group; fluoromethoxy Groups, difluoromethoxy groups, trifluoromethoxy groups, 2-chloroethoxy groups, 2,2,2-trichloroethoxy groups, 1,1,1,3,3,3-hexafluoro-2-propoxy groups, etc.
- alkylthio group such as methylthio group and ethylthio group
- aryl such as phenylthio group and 1-naphthylthio group Thio
- anilino group an arylamino group such as a 1-naphthylamino group
- methylamino group, an alkylamino group such as a diethylamino group can be exemplified such as cyano group.
- R 11 is preferably an unsubstituted or substituted C8-20 alkyl group or an unsubstituted or substituted C8-20 alkenyl group.
- the substance (A) is preferably a compound represented by the formula (I) or a salt thereof. Further, it is preferable that R 1 to R 4 in formula (I) are not hydrogen atoms at the same time.
- the substance (A) is represented by the formula (I) [at least one of R 1 to R 4 represents —COR 11 .
- R 11 represents an unsubstituted or substituted C12-30 alkyl group or an unsubstituted or substituted C12-30 alkenyl group. ] Or a salt thereof is preferable.
- C12-30 alkyl group examples include dodecyl group, tridecyl group, tetradecyl group (myristyl group), pentadecyl group, hexadecyl group (cetyl group, palmityl group), heptadecyl group, octadecyl group (stearyl group), Nonadecyl group, icosyl group, henicosyl group, triacontyl group and the like can be mentioned.
- substituted C12-30 alkyl group examples include 2-hydroxytridecyl group, 1-hydroxypentadecyl group, 11-hydroxyheptadecyl group, 1-aminoheptadecyl group and the like.
- Examples of the “C12-30 alkenyl group” include a dodecenyl group, a tridecenyl group, a tetradecenyl group, a pentadecenyl group, a hexadecenyl group, a heptadecenyl group, an octadecenyl group, a nonadecenyl group, an icosenyl group, a henicocenyl group, a triaconenyl group, and the like. .
- Examples of the “substituted C12-30 alkenyl group” include 7-hydroxy-8-pentadecenyl group, 1-hydroxy-8-peptadecenyl group, 1-amino-8-heptadecenyl group and the like.
- the substance (A) has the formula (I) [R 1 to R 4 each independently represents a hydrogen atom or —COR 11, and at least one of R 1 to R 4 represents —COR 11 .
- R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group, and at least one of —COR 11 is R 11 therein.
- substance (A) examples include ascorbic acid 6-myristate, ascorbic acid 6-palmitate, ascorbic acid 6-stearate, ascorbic acid 2-myristate, ascorbic acid 2-palmitate, ascorbic acid 2 -Stearate, ascorbic acid 2,6-dimyristate, ascorbic acid 2,6-dipalmitate, ascorbic acid 2,6-distearate and the like.
- the salt of the compound represented by the formula (I) and the salt of the compound represented by the formula (II) used in the present invention are not particularly limited as long as they are agro-horticulturally acceptable salts. Examples thereof include alkali metal salts such as sodium salt and potassium salt; alkaline earth metal salts such as calcium salt and magnesium salt.
- the substance (A) used in the present invention can be obtained by a known synthesis method.
- R 1 ⁇ esterification reaction of fatty acid compounds and ascorbic acid for introducing -COR 11 to one of R 4, phosphorus either to introduce -PO 3 H 2 of R 1 ⁇ R 4 Synthesis using an esterification reaction between an acid compound and ascorbic acid, an esterification reaction between a sulfuric acid compound and ascorbic acid for introducing —SO 3 H into any of R 1 to R 4 , and other known reactions can do.
- the substance (A) obtained by the said synthesis method can be refine
- the substances (A) used in the present invention are commercially available, they can also be used.
- the structure of the substance (A) can be identified and confirmed by known analysis means such as IR spectrum, NMR spectrum, mass spectrum, and elemental analysis.
- the substance (A) may be used alone, but is preferably used in combination of at least two.
- the substance (A) is a water-soluble substance selected from the group consisting of a compound represented by the formula (I), a compound represented by the formula (II), and a salt thereof.
- the substance (A) is at least one selected from the group consisting of a compound represented by the formula (Ia), a compound represented by the formula (IIa), and a salt thereof.
- a compound represented by the formula (Ia) a compound represented by the formula (IIa)
- a salt thereof a compound represented by the formula (IIa)
- R 1a to R 4a each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , or a glycosyl group.
- each R 5a and R 6a independently represent a hydrogen atom, -SO 3 H, a -PO 3 H 2 or glycosyl groups.
- R 1b to R 4b each independently represents a hydrogen atom or —COR 11 . At least one of R 1b ⁇ R 4b represents a -COR 11, R 11 is a C2 ⁇ 30 alkenyl group having C1 ⁇ 30 alkyl group or an unsubstituted or substituted group having an unsubstituted or substituted, Preferably, it is an unsubstituted or substituted C12-30 alkyl group or an unsubstituted or substituted C12-30 alkenyl group. ]
- R 5b and R 6b each independently represent a hydrogen atom or —COR 11 . At least one of R 5b and R 6b represents a -COR 11, R 11 is a C2 ⁇ 30 alkenyl group having C1 ⁇ 30 alkyl group or an unsubstituted or substituted group having an unsubstituted or substituted, Preferably, it is an unsubstituted or substituted C12-30 alkyl group or an unsubstituted or substituted C12-30 alkenyl group. ]
- the mass ratio of the fat-soluble substance (A2) to the water-soluble substance (A1) is usually 0.001 to 1000, preferably 0.1 to 10.
- Substance (A) can be prepared into preparations such as wettable powders, emulsions, aqueous solvents, granular wettable powders, powders and tablets.
- the preparation method to a formulation is not specifically limited, A well-known preparation method can be employ
- the method of applying the substance (A) to the plant is not particularly limited, and a known application method can be adopted in the field of agriculture and horticulture. Moreover, the method of application to a plant can be appropriately determined according to the type of plant to be targeted. For example, application by foliage spraying, dipping treatment, soil irrigation, seed treatment, hydroponic solution treatment, smoking treatment, room temperature fuming treatment, etc. can be mentioned as preferred.
- the method of this invention can be used without being restrict
- the application amount of the substance (A) in the method of the present invention can be appropriately determined according to weather conditions, formulation form, application time, application method, application location, disease to be controlled, target crop, and the like.
- the plant to which the method of the present invention is applicable is not particularly limited and may be either an edible plant or a non-edible plant.
- grains such as rice, wheat, corn, beans such as soybean, adzuki, peanut, fruits such as citrus, apple, pear, grape, peach, vegetables such as tomato, lettuce, cabbage, onion, leek, peppers, Cucumbers, watermelons, melons, pumpkins and other potatoes, potatoes, sweet potatoes, potatoes, carrots, radish and other root vegetables, cotton, sugar beet, hops, sugar cane, rubber, coffee, tobacco, tea and other crops for processing, ryegrass, Examples include grasses such as timosi and orchardgrass, and grasses such as bentgrass and mulberry.
- the stress include plant viruses, phytopathogenic bacteria, phytopathogenic fungi, pests, weeds, microorganisms used as biopesticides, arthropods, etc .; high temperature, low temperature, high illuminance, low illuminance, excessive humidity , Physical stress or chemical stress due to dryness, salinity, acidity, pesticides, chemicals or heavy metals.
- the plant virus that causes stress is not particularly limited.
- geminiviruses with single-stranded DNA as genome cauliflower mosaic virus with double-stranded DNA as genome, tobacco mosaic virus with single-stranded RNA as genome, tomato bushy stunt virus, double-stranded RNA as genome
- the rice rug stunt virus etc. which it has can be mentioned as a preferable thing.
- Phytopathogenic bacteria that cause stress are not particularly limited.
- rice seedling blight (Burkholderia plantarii), brown streak (Acidovorax avenae), blight blight (Burkholderia glumae), leaf blight (Xanthomonas campestris pv. Oryzae), cucumber spotted bacterial disease (Pseudomonas lachrymans) And Chinese cabbage soft rot (Erwinia carotovora).
- Phytopathogenic fungi causing stress are not particularly limited.
- rice blast (Pyricularia oryzae), idiot seedling (Gibberella fujikuroi), sesame leaf blight (Cochliobolus miyabeanus), wheat powdery mildew (Erysiphe graminisspf.sp.tritici), red mold (Gibberella zeae) , Red rust (Puccinia recondita), leaf blight (Septoria tritici), blight (Leptosphaeria nodorum), barley bare smut (Ustilago tritici), cucumber powdery mildew (Sphaerotheca fuliginea), downy mildew (Pseudoperonosp) ), Vine blight (Mycosphaerella melonis), vine split disease (Fusarium oxysporum), gray mold (Botrytis cinerea), anthracnose (Colle
- the pests that cause stress are not particularly limited. , Corn borer, European corn borer, white-faced butterfly, genus Heliotis, genus Helicoberpa, agrotis, iga, scallop, white butterfly, tobacco bad worm, stag beetle, scallop Hemiptera pests, for example, aphids such as phantom aphid, wheat aphid, peach aphid, cotton aphid, bean aphid; whitefly, tobacco whitefly, white leaf whitefly, whitefly Hawksbill beetle, sorghum scale, stag beetle, pterfly lice, pear beetle, flying planthopper, brown planthopper, white planthopper, leafhopper, etc .;
- aphids such as phantom aphid, wheat aphid, peach aphid, cotton aphid, bean aphid
- whitefly tobacco whitefly, white leaf
- Coleopterous pests e.g., Kizunami beetle, cucumber potato beetle, Colorado potato beetle, mustard beetle, rice weevil, weevil, azuki beetle, beetle, beetle, corn rootworm, diabrotica, tobacco beetle, winged beetle, pine beetle, Nijuya Hoshi Tento, Kokunust, Cotton weevil, etc .; Straight-eyed pests, such as locusts and locusts; Thrips-like pests, such as Southern thrips, Canopy thrips, Negia thrips, Thrips thrips, etc .; Diptera pests, for example, cucumber flies, citrus flies, rice flies, etc .; Mites, for example, spider mite, spider mite, kanzawa spider mite, citrus spider mite, apple spider mite, spider spider mite, and other spider mit
- Weeds that cause stress are not particularly limited, but grasses such as Inobie, Yasei Sorghum, Akino no Ezologosa, Enocologosa, Aedes albopictus, Prunus terrestris, Barnyard grass, Oshiba, Suzunokatabira, Inobie, etc., Onamomi, Ragosa Pteris arena, weeping weeds such as oleander, crocodile, chitinose, sendangusa, mugwort, butterflies, psyllium, tadpole, tuna, red-footed beetle, yamgra, ichibi, chimemegusa, red-footed moth, red-footed moth, red-footed moth, red-footed moth American King Deer, White clover, Ebisu rush, Firefly, Matsubai, Sphagnum, Kogi, Azena, Mizohakobe,
- glyphosate-tolerant weeds include Amaranthaceae (Amaranthaceae), Ragweed (Asteraceae) and Kenashihimemukashimugigi.
- ⁇ High and low temperatures that cause stress are not particularly limited.
- high-temperature damage and low-temperature damage that reduce the growth and quality of rice high-temperature damage that reduces the fruiting rate of solanaceous crops such as tomatoes
- high-temperature damage that tends to occur especially in tunnel and greenhouse cultivation such as lettuce
- Western turf High-temperature damage that inhibits the growth of fruit
- frost and frost damage of fruit trees such as tea and citrus fruits.
- ⁇ Overhumidity and drying that cause stress are not particularly limited.
- crop growth failure due to excessive rainfall, irrigation, or excessive moisture due to poorly drained soil, reduced resistance to disease, or lack of rainfall, irrigation, or drying due to sandy soil Such as wilting.
- ⁇ Soil properties that cause stress are not particularly limited.
- crop growth failure in soil containing salt, acidic soil or alkaline soil are not particularly limited.
- the effects on growth failure in salt-containing soil and acidic soil, especially on the growth failure of crops that are vulnerable to acidic soil such as spinach, pea, broad bean, onion, asparagus, lettuce, burdock, etc. has the effect of improving the yield and quality.
- Chemical substances that cause stress are not particularly limited, but herbicides, growth regulators, plant hormones, disease resistance inducers, fungicides such as fungicides, insecticides, acaricides, fertilizers, surfactants, other Examples include at least one compound selected from allelopathic substances produced by plants and affecting crops.
- the pesticide that causes stress is not particularly limited, and examples thereof include those exemplified as substances that affect the physiological functions of plants.
- the phytotoxicity causing stress is, for example, phytotoxicity that occurs when the concentration exceeds the standard of use or when it is applied to non-applicable crops, and phytotoxicity that occurs under high temperature conditions or strong light conditions. By suppressing these phytotoxicity by this invention, it is also possible to make the application range of an agrochemical wider than what was applied conventionally.
- the heavy metal that causes stress is not particularly limited, and examples thereof include iron, zinc, copper, manganese, nickel, cobalt, tin, chromium, lead, cadmium, mercury, and arsenic.
- Pesticides include herbicides, growth regulators, plant hormones, pathogen-resistant agents, fungicides, insecticides, acaricides, repellents, fertilizers, surfactants, etc. that show phytotoxicity at higher concentrations. It is done. Of these, at least one selected from the group consisting of fungicides, insecticides, plant growth regulators, and herbicides is preferred.
- the agrochemical is preferably a respiratory inhibitor.
- the pesticide is preferably a strobilurin compound.
- Bactericides include captan, folpette, thiuram, diram, dineb, mannebu, mancozeb, propineb, polycarbamate, chlorothalonil, quintozen, captaphor, iprodione, procymidone, fluoroimide, mepronil, flutolanil, pencyclon, oxycarboxyl, fosetyl aluminum , Propamocarb, hexaconazole, imibenconazole, tebuconazole, difenoconazole, prothioconazole, fenbuconazole, diclobutrazole, vitertanol, microbutanyl, flusilazole, hexaconazole, ethaconazole, fluotrimazole, triadimethone, triadimenol, Flutriaphen, penconazole, diniconazole, cyproconazole, phenalimol, tri
- Pesticides include fenthion, fenitrothion, diazinon, chlorpyrifos, ESP, bamidthione, phentoate, dimethoate, formothion, marathon, trichlorphone, thiomethone, phosmet, dichlorvos, acephate, EPBP, methyl parathion, oxydimethone methyl, ethion, salithione, , Pyridafenthion, hosalon, methidathion, sulprophos, chlorfenvinphos, tetrachlorbinphos, dimethylvinphos, propaphos, isofenphos, ethylthiomethone, propenofos, pyracrophos, monocrotophos, azinephosmethyl, aldicarb, mesomil, thiodicarb, carbofuran, carbofuran , Benfuracarb, Frathiocarb, propoxy Organic phosphorus
- Plant hormones include gibberellins (eg, gibberellin A3, gibberellin A4, gibberellin A7, etc.), auxins (eg, 2,4-D, IAA, NAA, etc.), cytokinins (eg, kinetin, benzyladenine, etc.), abscisic acid, Examples include jasmonic acids, brassinosteroids, strigolactones, salicylic acid and the like.
- Plant growth regulators include, in addition to the above plant hormones, hymexazole, uniconazole, trinexapack, daminozide, cyanamide and the like.
- Fertilizers include nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, calcareous fertilizer, mafic fertilizer, siliceous fertilizer, trace element fertilizer, moving substance fertilizer, plant fertilizer and the like. If the concentration of water-soluble components in the fertilizer is too high, the plant may be damaged by fertilizers such as roots and leaves withering and withering. In addition, when a large amount of a specific type of fertilizer such as ammonium sulfate is used, plant growth may be damaged through acidification of the soil.
- Surfactant is used as an auxiliary component for agricultural chemical preparations, as an active ingredient for some insecticides and acaricides, or as a spreading agent.
- Surfactants include alkylphenyl ethers added with polyoxyethylene, alkyl ethers added with polyoxyethylene, higher fatty acid esters added with polyoxyethylene, sorbitan higher fatty acid esters added with polyoxyethylene, and polyoxyethylene.
- Nonionic surfactants such as added tristyrylphenyl ether; sulfates of alkylphenyl ethers added with polyoxyethylene, alkylbenzene sulfonates, sulfates of higher alcohols, alkylnaphthalene sulfonates, polycarboxylic acids
- Anionic surfactants such as salts, lignin sulfonates, alkylnaphthalene sulfonate formaldehyde condensates, isobutylene-maleic anhydride copolymers; Id, methyl, polyoxyethylene, alkylammonium chloride, alkyl, N-methylpyridium bromide, mono- or dialkylmethylated ammonium chloride, alkylpentamethylpropylenediamine dichloride, alkyldimethylbenzalkonium chloride, benzethonium chloride, etc.
- amphoteric surfactants such as dialkyldiaminoethylbetaine, alkyldimethylbenzylbetaine, dialkyldiaminoethylglycine, and alkyldimethylbenzylglycine;
- the formulation of the preparation is not limited to the examples of the preparation, and can be changed in a wide range.
- the part in a formulation example shows a weight part.
- Test Example 1 Evaluation Test for Reducing Effect of High Temperature Damage on Tomato An N, N-dimethylformamide solution was prepared according to the formulation shown in Table 3 and used as a test chemical.
- Tomato seedlings variety: Momotaro
- the above chemical solution was sprayed onto the stem and leaves of the tomato seedlings, and then air-dried.
- the plants were grown at 30 ° C. under conditions of 16 hours in the light and 8 hours in the dark for 2 days. Thereafter, the cells were grown for 6 days under the conditions of 16 hours of light at 40 ° C. and 8 hours of dark at 30 ° C.
- Test Example 3 Evaluation Test for Reduction Effect of Low Temperature Damage on Cucumber An N, N-dimethylformamide solution was prepared according to the formulation shown in Table 5 and used as a test chemical.
- Cucumber seedlings (variety: Sagamihanjiro) grown to 1.5 leaf stage in a greenhouse were prepared.
- the chemical solution was sprayed on the stems and leaves of the cucumber seedling so that the solution dripped, and then air-dried.
- the plants were grown at 25 ° C. under conditions of 16 hours in the light and 8 hours in the dark for 2 days. Thereafter, the cells were grown for 9 days under the conditions of 16 hours of light at 10 ° C and 8 hours of darkness at 7 ° C.
- the low-temperature damage alleviation rate was calculated according to the following equation compared with the treatment group (chemical solution 3) containing only the solvent DMF.
- Low temperature damage reduction rate ((solvent index of solvent only treatment area)-(failure index of each treatment area)) / (Disability index of solvent-only treatment zone) x 100 The results are shown in Table 5.
- Test Example 4 Evaluation Test for Reducing Effect of Low Temperature Damage on Eggplant Eggplants (variety: Senryo 2 and 3) grown to 4-6 leaf stage in a greenhouse were prepared. Ascorbic acid palmitate 30% granule wettable powder and pyraclostrobin dissolved in 40% with N, N-dimethylformamide are diluted with tap water to the concentrations shown in Table 6 and sufficient for the whole seedling. Sprayed. After air drying, the cells were grown for 1 day at 18 ° C in a light place for 16 hours and at 13 ° C in a dark place for 8 hours, and then grown at 13 ° C in a light place for 16 hours and at 8 ° C in a dark place for 8 hours. It was.
- the degree of disability was investigated 15 days after the spraying treatment.
- the obstacle is the area of the discolored portion of the developed leaf after processing: 0 (no discoloration), 1 (discolored to 1/4 of the whole), 2 (discolored to 1/2 of the whole), 3 (1/2 of the whole) Evaluation was made using the four-level disability index.
- Disability reduction rate ((Disability index for untreated areas)-(Disability index for each treated area)) / (Disability index of untreated area) x 100 The results are shown in Table 6.
- Test example 6 Evaluation test for the effect of reducing high temperature damage to Eustoma Ascorbic acid at the time when the latter half of the seeding emerged using Eustoma (variety King of Snow) grown in a cell tray indoors at a temperature of 22 ° C. and 16 hours light
- a 30% granular wettable powder of palmitate was diluted with distilled water to a predetermined concentration, and a sufficient amount thereof was sprayed on the entire seedling. Thereafter, spraying by the same method was performed twice a week for a total of 10 times including the first time. In the meantime, 3 weeks after sowing, the leaves were transferred to a pair of leaves at the time of development at 35 ° C. for 16 hours in the light and 15 ° C.
- Test Example 8 Evaluation Test for Mitigating Drug Damage to Tomato An N, N-dimethylformamide solution was prepared according to the formulation shown in Table 10 and used as a test drug solution.
- Tomato seedlings variety: Momotaro
- the above chemical solution was sprayed onto the stem and leaves of the tomato seedlings, and then air-dried. It was grown for 7 days under normal temperature and humidity conditions in March of Japan.
- phytotoxicity such as leaf browning and elongation suppression was investigated. The phytotoxicity was evaluated with 11 phytotoxicity indices ranging from 0 (no injury) to 10 (dead).
- Test Example 9 Green maintenance (high temperature damage reduction) effect test on wheat Using wheat grown in the field (variety Norin 61, 15 strains / m 2 / ku, 2 stations), 7 days from the day after the heading date in August At intervals, the amount of ascorbyl palmitate 30% granule wettable powder described in Table 11 was applied to the strain 4 times.
- the leaf color index of the top 4 to 5 leaves of each strain in the treated area was investigated, and the effect of maintaining the leaf color on the untreated area was evaluated. The leaf color is 1 (less than 1/4 of the total color), 2 (less than 1/2 of the total color), 3 (less than 3/4 of the total color), 4 (over 3/4 of the total color)
- the four-stage leaf color index was evaluated.
- Green maintenance effect ((Leaf color index of untreated section)-(Leaf color index of each treated section)) / (Leaf color index of untreated zone) x 100 The results are shown in Table 11.
- Test Example 10 Evaluation Test for Mitigating Submergence Damage to Cucumber A cucumber (variety: Sagami Hansakusei, 2) grown in the greenhouse until the second leaf stage was prepared. Ascorbic acid palmitate 30% granule wettable powder and pyraclostrobin adjusted to 40% with N, N-dimethylformamide were diluted with tap water to a predetermined concentration and sprayed in sufficient amounts. After 2 days from the spraying treatment, the mixture was flooded from just below the cotyledon, and 11 days after the spraying treatment, the fresh weight of the above-ground part and root part of the cucumber was measured. The failure reduction rate was calculated from the following equation. Submergence damage reduction rate ((raw weight of each treated area)-(raw weight of untreated area)) / (Raw weight of untreated area) ⁇ 100 The results are shown in Table 12.
- Test Example 12 Evaluation Test for Reducing Effect of Acidic Damage on Cucumber Cucumber (variety: Sagami Hansakusei, 2 series) that was hydroponically grown up to the second leaf stage with 100 ml of Kolben was prepared.
- a 30% granule wettable powder of ascorbyl palmitate and pyraclostrobin adjusted to 40% with N, N-dimethylformamide were diluted to a predetermined concentration with tap water, and a sufficient amount was sprayed over the entire seedling.
- the hydroponic solution was adjusted to pH 4 with 1N hydrochloric acid and the cucumber was continuously hydroponically grown.
- the cucumber leaf age was investigated 17 days after the spraying treatment.
- the failure reduction rate was calculated from the following equation.
- Reduction rate of acid damage ((leaf age of each treated area)-(leaf age of untreated area)) / (Leaf age of untreated section) x 100 The results are shown in Table 14.
- Test Example 13 Evaluation Test for Reducing Effect of Acidic Damage on Soybean Soybean (cultivar: Enrei, 2 series) that was hydroponically grown up to the second leaf stage with 100 ml of Kolben was prepared.
- a 30% granule wettable powder of ascorbyl palmitate and pyraclostrobin dissolved in 40% with N, N-dimethylformamide were diluted to a predetermined concentration with tap water, and a sufficient amount was sprayed over the entire seedling.
- the hydroponic solution was adjusted to pH 4 with 1N hydrochloric acid, and the soybean was continuously hydroponically grown. The soybean damage was investigated 11 days after the spraying treatment.
- Test Example 16 Symptom-reducing effect test for tomato yellow leaf curl virus disease An N, N-dimethylformamide solution was prepared according to the formulation shown in Table 18 to obtain a test drug solution.
- Tomato seedlings (variety: Momotaro) grown to the 8th leaf stage in the greenhouse were prepared.
- Tomato seedlings afflicted with tomato yellow leaf curl virus (TYLCV) were used as the inoculation source.
- the stems of diseased strains were cut diagonally and inoculated to tomato seedlings.
- parafilm was wrapped around the grafted portion to protect it. After grafting inoculation, the chemical solution was sprayed onto the tomato seedlings.
- the chemical solution was sprayed three times in such an amount that the solution dripped at about one week intervals.
- the symptoms of tomato yellow leaf curl disease were investigated. Symptoms were evaluated with a 5-stage disease index from 0 (no disease) to 4 (severe illness).
- medical solution 3) only of solvent DMF was computed by following Formula.
- Disease control rate ((Sickness index of solvent-only treatment section)-(Sickness index of each treatment section)) / (Sickness index of solvent only treatment area) x 100
- the expected value of the disease suppression rate was calculated based on the Colby equation.
- E is the expected value (%) of the disease suppression rate
- M is the disease suppression rate (%) calculated from the measurement when the substance (A1) is used alone
- N is the measurement when the substance (A2) is used alone.
- the disease suppression rate (%) calculated from The results are shown in Table 18.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- Genetics & Genomics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cultivation Of Plants (AREA)
Abstract
Description
〔1〕 式(I)で表される化合物、式(II)で表される化合物およびそれらの塩からなる群から選ばれる少なくとも一つの物質(A)を植物に施用することを含む、ストレスに対する抵抗性を植物に付与する方法。 As a result of intensive studies to achieve the above object, the present inventors have completed the invention of the following aspect.
[1] Applying to a plant at least one substance (A) selected from the group consisting of a compound represented by formula (I), a compound represented by formula (II) and a salt thereof, against stress A method of imparting resistance to plants.
〔3〕 物質(A)が、式(I)[ただし、R1~R4のうち少なくとも一つは-COR11を示し、R11は、無置換の若しくは置換基を有するC12~30アルキル基または無置換の若しくは置換基を有するC12~30アルケニル基を示す。]で表される化合物またはその塩である、〔1〕に記載の方法。 [2] The substance (A) is represented by the formula (I) [However, not all R 1 to R 4 are hydrogen atoms at the same time. Or a salt thereof. The method according to [1].
[3] material (A) has the formula (I) [provided that at least one of R 1 ~ R 4 represents a -COR 11, R 11 are, C12 ~ 30 alkyl group having an unsubstituted or substituted Or an unsubstituted or substituted C12-30 alkenyl group. Or a salt thereof. The method according to [1].
〔6〕 前記ストレスが、植物ウイルス、植物病原細菌、植物病原糸状菌、害虫若しくは雑草による生物的ストレス;または、高温、低温、高照度、低照度、過湿、乾燥、塩分、酸性、農薬、化学物質若しくは重金属による物理的若しくは化学的ストレスである、〔1〕~〔5〕のいずれか一つに記載の方法。 [5] The substance (A) is a water-soluble substance (A1) selected from the group consisting of a compound represented by the formula (I), a compound represented by the formula (II), and a salt thereof (A1) And a fat-soluble composition (A2) selected from the group consisting of a compound represented by formula (I), a compound represented by formula (II), and a salt thereof. The method according to [1].
[6] The stress is a biological stress caused by plant viruses, phytopathogenic bacteria, phytopathogenic fungi, pests or weeds; or high temperature, low temperature, high illuminance, low illuminance, excessive humidity, drying, salinity, acidity, pesticides, The method according to any one of [1] to [5], which is a physical or chemical stress caused by a chemical substance or heavy metal.
式(Ib)で表される化合物、式(IIb)で表される化合物およびそれらの塩からなる群から選ばれる少なくとも一つの脂溶性物質(A2)とを含有する植物用ストレス抵抗性付与剤組成物。 [9] At least one water-soluble substance (A1) selected from the group consisting of a compound represented by the formula (Ia), a compound represented by the formula (IIa), and a salt thereof;
A plant stress resistance imparting agent composition comprising at least one fat-soluble substance (A2) selected from the group consisting of a compound represented by the formula (Ib), a compound represented by the formula (IIb), and a salt thereof. object.
〔11〕 農薬が、殺菌剤、殺虫剤、植物成長調整剤、および除草剤からなる群から選ばれる少なくとも一つを含むものである、〔10〕に記載の農薬による植物の薬害を軽減する方法。 [10] A method for reducing plant phytotoxicity caused by agricultural chemicals, comprising imparting resistance to stress to a plant by the method according to any one of [1] to [6].
[11] The method for reducing plant phytotoxicity caused by the agricultural chemical according to [10], wherein the agricultural chemical comprises at least one selected from the group consisting of a fungicide, an insecticide, a plant growth regulator, and a herbicide.
物質(A)は、式(I)で表される化合物、式(II)で表される化合物、およびそれらの塩からなる群から選ばれる少なくとも一つである。
式(I)中、R1~R4はそれぞれ独立して、水素原子、-SO3H、-PO3H2、グリコシル基または-COR11を示す。
式(II)中、R5およびR6はそれぞれ独立して、水素原子、-SO3H、-PO3H2、グリコシル基または-COR11を示す。 (Substance (A))
The substance (A) is at least one selected from the group consisting of a compound represented by the formula (I), a compound represented by the formula (II), and a salt thereof.
In formula (I), R 1 to R 4 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 .
In formula (II), R 5 and R 6 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 .
ここで、「無置換の」の用語は、該基が母核となる基のみであることを意味する。なお、「置換基を有する」との記載がなく母核となる基の名称のみで記載しているときは、別段の断りがない限り「無置換の」の意味である。
一方、「置換基を有する」の用語は、母核となる基のいずれかの水素原子が、母核と異なる若しくは同じ構造の基で置換されていることを意味する。従って、「置換基」は、母核となる基に置換された他の基である。置換基は一つであってもよいし、二つ以上であってもよい。二つ以上の置換基は同じものであってもよいし、異なるものであってもよい。例えば、置換基を有するC1~30アルキル基は、母核となる基がC1~30アルキル基で、これのいずれかの水素原子が異なる構造の基(「置換基」)で置換されているものである。 In —COR 11 , R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group.
Here, the term “unsubstituted” means that the group is only a group serving as a mother nucleus. In addition, when there is no description of “having a substituent” and only the name of the group serving as a mother nucleus is described, it means “unsubstituted” unless otherwise specified.
On the other hand, the term “having a substituent” means that any hydrogen atom of a group serving as a mother nucleus is substituted with a group having a structure different from or the same as that of the mother nucleus. Therefore, the “substituent” is another group substituted with a group serving as a mother nucleus. The number of substituents may be one, or two or more. Two or more substituents may be the same or different. For example, a C1-30 alkyl group having a substituent is a group in which the parent nucleus is a C1-30 alkyl group, and any one of these hydrogen atoms is substituted with a group having a different structure ("substituent") It is.
上記R11は、無置換の若しくは置換基を有するC8~20アルキル基または無置換の若しくは置換基を有するC8~20アルケニル基が好ましい。 Examples of a group that can be a “substituent” of a C1-30 alkyl group or a C2-30 alkenyl group include a hydroxyl group; a mercapto group; an amino group; a nitro group; a halogen atom such as a chlorine atom, a fluorine atom, and a bromine atom; Alkoxy groups such as ethoxy group, isopropoxy group, n-propoxy group, n-butoxy group, isobutoxy group, s-butoxy group and t-butoxy group; aryloxy groups such as phenoxy group and 1-naphthyloxy group; fluoromethoxy Groups, difluoromethoxy groups, trifluoromethoxy groups, 2-chloroethoxy groups, 2,2,2-trichloroethoxy groups, 1,1,1,3,3,3-hexafluoro-2-propoxy groups, etc. Group: alkylthio group such as methylthio group and ethylthio group; aryl such as phenylthio group and 1-naphthylthio group Thio; anilino group, an arylamino group such as a 1-naphthylamino group; methylamino group, an alkylamino group such as a diethylamino group can be exemplified such as cyano group.
R 11 is preferably an unsubstituted or substituted C8-20 alkyl group or an unsubstituted or substituted C8-20 alkenyl group.
また、物質(A)は、式(I)[R1~R4のうち少なくとも一つは-COR11を示す。R11は、無置換の若しくは置換基を有するC12~30アルキル基または無置換の若しくは置換基を有するC12~30アルケニル基を示す。]で表される化合物またはその塩であることが好ましい。
なお、「C12~30アルキル基」としては、例えば、ドデシル基、トリデシル基、テトラデシル基(ミリスチル基)、ペンタデシル基、ヘキサデシル基(セチル基、パルミチル基)、ヘプタデシル基、オクタデシル基(ステアリル基)、ノナデシル基、イコシル基、ヘンイコシル基、トリアコンチル基などが挙げられる。
「置換基を有するC12~30アルキル基」としては、例えば、2-ヒドロキシトリデシル基、1-ヒドロキシペンタデシル基、11-ヒドロキシヘプタデシル基、1-アミノヘプタデシル基などが挙げられる。 The substance (A) is preferably a compound represented by the formula (I) or a salt thereof. Further, it is preferable that R 1 to R 4 in formula (I) are not hydrogen atoms at the same time.
The substance (A) is represented by the formula (I) [at least one of R 1 to R 4 represents —COR 11 . R 11 represents an unsubstituted or substituted C12-30 alkyl group or an unsubstituted or substituted C12-30 alkenyl group. ] Or a salt thereof is preferable.
Examples of the “C12-30 alkyl group” include dodecyl group, tridecyl group, tetradecyl group (myristyl group), pentadecyl group, hexadecyl group (cetyl group, palmityl group), heptadecyl group, octadecyl group (stearyl group), Nonadecyl group, icosyl group, henicosyl group, triacontyl group and the like can be mentioned.
Examples of the “substituted C12-30 alkyl group” include 2-hydroxytridecyl group, 1-hydroxypentadecyl group, 11-hydroxyheptadecyl group, 1-aminoheptadecyl group and the like.
「置換基を有するC12~30アルケニル基」としては、例えば、7-ヒドロキシ-8-ペンタデセニル基、1-ヒドロキシ-8-ペプタデセニル基、1-アミノ-8-ヘプタデセニル基などが挙げられる。 Examples of the “C12-30 alkenyl group” include a dodecenyl group, a tridecenyl group, a tetradecenyl group, a pentadecenyl group, a hexadecenyl group, a heptadecenyl group, an octadecenyl group, a nonadecenyl group, an icosenyl group, a henicocenyl group, a triaconenyl group, and the like. .
Examples of the “substituted C12-30 alkenyl group” include 7-hydroxy-8-pentadecenyl group, 1-hydroxy-8-peptadecenyl group, 1-amino-8-heptadecenyl group and the like.
なお、物質(A)の構造は、IRスペクトル、NMRスペクトル、マススペクトル、元素分析等の公知の分析手段により、同定、確認することができる。 The substance (A) used in the present invention can be obtained by a known synthesis method. For example, R 1 ~ esterification reaction of fatty acid compounds and ascorbic acid for introducing -COR 11 to one of R 4, phosphorus either to introduce -PO 3 H 2 of R 1 ~ R 4 Synthesis using an esterification reaction between an acid compound and ascorbic acid, an esterification reaction between a sulfuric acid compound and ascorbic acid for introducing —SO 3 H into any of R 1 to R 4 , and other known reactions can do. Moreover, the substance (A) obtained by the said synthesis method can be refine | purified by well-known methods, such as extraction, distillation, and a chromatograph. In addition, since many of the substances (A) used in the present invention are commercially available, they can also be used.
In addition, the structure of the substance (A) can be identified and confirmed by known analysis means such as IR spectrum, NMR spectrum, mass spectrum, and elemental analysis.
鱗翅目害虫、例えば、ヨトウガ、アワヨトウ、ハスモンヨトウ、タマナヤガ、チャノコカクモンハマキ、チャハマキ、モモシンクイガ、ナシヒメシンクイ、ミカンハモグリガ、チャノホソガ、キンモンホソガ、マイマイガ、チャドクガ、ニカメイガ、コブノメイガ、ヨーロピアンコーンボーラー、アメリカシロヒトリ、スジマダラメイガ、ヘリオティス属、ヘリコベルパ属、アグロティス属、イガ、アワノメイガ、オオモンシロチョウ、タバコバッドワーム、コナガ、ネキリムシ(ヤガ科の一種)など;
半翅目害虫、例えば、ニセダイコンアブラムシ、ムギクビレアブラムシ、モモアカアブラムシ、ワタアブラムシ、マメクロアブラムシ等のアブラムシ類;オンシツコナジラミ、タバココナジラミ、シルバーリーフコナジラミ等のコナジラミ類;ホシカメムシ、ホソヘリカメムシ、アオクサカメムシ、ヤノネカイガラムシ、クワコナカイガラムシ、ナシキジラミ、ナシグンバイムシ、トビイロウンカ、ヒメトビウンカ、セジロウンカ、ツマグロヨコバイなど; The pests that cause stress are not particularly limited. , Corn borer, European corn borer, white-faced butterfly, genus Heliotis, genus Helicoberpa, agrotis, iga, scallop, white butterfly, tobacco bad worm, stag beetle, scallop
Hemiptera pests, for example, aphids such as phantom aphid, wheat aphid, peach aphid, cotton aphid, bean aphid; whitefly, tobacco whitefly, white leaf whitefly, whitefly Hawksbill beetle, sorghum scale, stag beetle, pterfly lice, pear beetle, flying planthopper, brown planthopper, white planthopper, leafhopper, etc .;
直翅目害虫、例えば、イナゴ、トノサマバッタなど;
アザミウマ目害虫、例えば、ミナミキイロアザミウマ、チャノキイロアザミウマ、ネギアザミウマ、ヒラズハナアザミウマなど;
双翅目害虫、例えば、ウリミバエ、ミカンコミバエ、イネハモグリバエなど;
ダニ類、例えば、ナミハダニ、ニセナミハダニ、カンザワハダニ、ミカンハダニ、リンゴハダニ、ヒメハダニ等のハダニ類;ミカンサビダニ、リンゴサビダニ、チャノホコリダニ、ロビンネダニなど;
等が挙げられる。この中で適用が特に好ましい害虫としては、植物ウイルスを媒介するアブラムシ類、コナジラミ類、アザミウマ類、ハダニ類などが挙げられる。 Coleopterous pests, e.g., Kizunami beetle, cucumber potato beetle, Colorado potato beetle, mustard beetle, rice weevil, weevil, azuki beetle, beetle, beetle, corn rootworm, diabrotica, tobacco beetle, winged beetle, pine beetle, Nijuya Hoshi Tento, Kokunust, Cotton weevil, etc .;
Straight-eyed pests, such as locusts and locusts;
Thrips-like pests, such as Southern thrips, Canopy thrips, Negia thrips, Thrips thrips, etc .;
Diptera pests, for example, cucumber flies, citrus flies, rice flies, etc .;
Mites, for example, spider mite, spider mite, kanzawa spider mite, citrus spider mite, apple spider mite, spider spider mite, and other spider mites;
Etc. Among these pests that are particularly preferred to be applied, aphids, whiteflies, thrips, spider mites and the like that mediate plant viruses are exemplified.
ストレスの原因になる農薬は特に限定されず、例えば、植物の生理作用に影響を及ぼす物質として例示したものが挙げられる。
ストレスの原因になる薬害は、例えば、使用規準を超えた濃度や適用外の作物に処理した場合の薬害、さらに高温条件や強光条件下で生じる薬害などである。本発明によりこれらの薬害が抑制されることで、農薬の適用範囲を従来適用されていたものより広くすることも可能である。 Chemical substances that cause stress are not particularly limited, but herbicides, growth regulators, plant hormones, disease resistance inducers, fungicides such as fungicides, insecticides, acaricides, fertilizers, surfactants, other Examples include at least one compound selected from allelopathic substances produced by plants and affecting crops.
The pesticide that causes stress is not particularly limited, and examples thereof include those exemplified as substances that affect the physiological functions of plants.
The phytotoxicity causing stress is, for example, phytotoxicity that occurs when the concentration exceeds the standard of use or when it is applied to non-applicable crops, and phytotoxicity that occurs under high temperature conditions or strong light conditions. By suppressing these phytotoxicity by this invention, it is also possible to make the application range of an agrochemical wider than what was applied conventionally.
このうちで、クレソキシムメチル、トリフロキシストロビン、アゾキシストロビン、ピラクロストロビン、オリサストロビン等のストロビルリン系殺菌剤が特に好ましい。 Bactericides include captan, folpette, thiuram, diram, dineb, mannebu, mancozeb, propineb, polycarbamate, chlorothalonil, quintozen, captaphor, iprodione, procymidone, fluoroimide, mepronil, flutolanil, pencyclon, oxycarboxyl, fosetyl aluminum , Propamocarb, hexaconazole, imibenconazole, tebuconazole, difenoconazole, prothioconazole, fenbuconazole, diclobutrazole, vitertanol, microbutanyl, flusilazole, hexaconazole, ethaconazole, fluotrimazole, triadimethone, triadimenol, Flutriaphen, penconazole, diniconazole, cyproconazole, phenalimol, triflu Sol, prochloraz, imazalyl, cresoxime methyl, trifloxystrobin, azoxystrobin, pyraclostrobin, orissastrobin, pefazoate, tridemorph, fenpropimorph, triphorin, butiobate, pyrifenox, anilazine, polyoxin, metalaxyl, oxadixyl, fulaxyl, Isoprothiolane, probenazole, pyrrolnitrin, blasticidin S, kasugamycin, validamycin, dihydrostreptomycin sulfate, benomyl, carbendazim, thiophanate methyl, hymexazole, basic copper chloride, basic copper sulfate, fentin acetate, triphenyltin hydroxide, Dietofencarb, quinomethionate, binapacril, lecithin, baking soda, dithianon, zinocup, Enaminosulfur, dichromedin, guazatine, dozin, IBP, edifenphos, mepanipyrim, fermzone, trichlamide, metasulfocarb, fluazinam, etokinolac, dimethomorph, pyroxylone, teclophthalam, fusalide, phenazine oxide, thiabendazole, tricyclazole vinclomopagin Bactericides such as hydrochloride, oxolinic acid, cyflufenamide, iminotazine, triazine, phenhexamide, cyazofamide, cyprodinil, carpropamide, boscalid; and resistance inducers against pathogenic bacteria such as probenazole and thiazinyl.
Of these, strobilurin fungicides such as cresoxime methyl, trifloxystrobin, azoxystrobin, pyraclostrobin, orisatrobin are particularly preferred.
このうちで、イミダクロプリド、アセタミプリド、ニテンピラム、チアクロプリド、クロチアニジン、チアメトキサム、ジノテフラン、ニチアジン等のネオニコチノイド系殺虫剤、およびクロルフェナピル、ピメトロジン、ピリダベン、フェンピロキシメート、トルフェンピラド、テブフェンピラド、シエノピラフェン、シフルメトフェン、フルアクリピリム、アセキノシル、フェナザキン等の呼吸阻害効果を有する殺虫剤若しくは殺ダニ剤が特に好ましい。 Pesticides include fenthion, fenitrothion, diazinon, chlorpyrifos, ESP, bamidthione, phentoate, dimethoate, formothion, marathon, trichlorphone, thiomethone, phosmet, dichlorvos, acephate, EPBP, methyl parathion, oxydimethone methyl, ethion, salithione, , Pyridafenthion, hosalon, methidathion, sulprophos, chlorfenvinphos, tetrachlorbinphos, dimethylvinphos, propaphos, isofenphos, ethylthiomethone, propenofos, pyracrophos, monocrotophos, azinephosmethyl, aldicarb, mesomil, thiodicarb, carbofuran, carbofuran , Benfuracarb, Frathiocarb, propoxy Organic phosphorus insecticides and carbamate insecticides such as BPMC, MTMC, MIPC, carbaryl, pyrimicarb, etiophencarb, phenoxycarb, cartap, thiocyclam, bensultap; permethrin, cypermethrin, deltamethrin, fenvalerate, fenpropatoline, pyrethrin, Pyrethroid insecticides such as allethrin, tetramethrin, resmethrin, dimethrin, propraslin, phenothrin, protorin, fluvalinate, cyfluthrin, cyhalothrin, flucitrinate, etofenprox, cycloprotorin, tralomethrin, silafluophene, acrinathrin, etc .; imidacloprid, acetamiprid , Thiacloprid, clothianidin, thiamethoxam, dinotefuran, nichia Neonicotinoid insecticides such as diflubenzuron, chlorfluazuron, hexaflumuron, triflumuron, flufenoxuron, flucycloxuron, buprofezin, pyriproxyfen, methoprene, benzoepin, diafenthiuron, fipronil, sulfuric acid Nicotine, rotenone, metaldehyde, acetamiprid, chlorfenapyr, nitenpyram, thiacloprid, clothianidin, thiamethoxam, dinotefuran, indoxacarb, pymetrozine, spinosad, emamectin, pyridalyl, tebufenozide, chromafenozide, flufenandropiranide, tolfenopiramide Benzoylurea and other insecticides such as cyantraniliprole; phenamifos, phostiazates, Nematicides such as kazusafos; chlorbenzilate, phenisobromolate, dicofol, amitraz, BPPS, benzomate, hexothiazox, fenbutazin oxide, polynactin, quinomethionate, CPCBS, tetradiphone, avermectin, milbemectin, clofentedine, cyhexatin, pyridaben, And miticides such as fenpyroximate, tebufenpyrad, sienopyrafen, ciflumethofene, pyrimidifen, phenothiocarb, dienochlor, fluacrylpyrim, acequinosyl, bifenazate, etoxazole, spirodiclofen, phenazaquin; and microbial agents such as BT;
Among these, neonicotinoid insecticides such as imidacloprid, acetamiprid, nitenpyram, thiacloprid, clothianidin, thiamethoxam, dinotefuran, nithiazine, and chlorfenapir, pymetrozine, pyridaben, fenpyroximate, tolfenpyrado, flufenapyrazide, flumetofenafenafluaza Particularly preferred are insecticides or acaricides having a respiratory inhibitory effect.
アスコルビン酸、イソアスコルビン酸またはデヒドロアスコルビン酸を公知の反応によってエステル化、グリコシル化、または酸化させることによって、各種の物質(A)を合成した。合成した物質(A)の一部を表1および表2に示す。表1中のR1~R4は、式(I)中のR1~R4に対応するものである。表2中のR5およびR6は、式(II)中のR5およびR6に対応するものである。 EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the scope of the present invention is not limited by these examples.
Various substances (A) were synthesized by esterifying, glycosylating or oxidizing ascorbic acid, isoascorbic acid or dehydroascorbic acid by a known reaction. A part of the synthesized substance (A) is shown in Tables 1 and 2. Table 1 R 1 ~ R 4 in is the counterpart to the R 1 ~ R 4 in formula (I). Table R 5 and R 6 in 2, which corresponds to R 5 and R 6 in the formula (II).
物質(A) 20部
ホワイトカーボン 20部
ケイソウ土 52部
アルキル硫酸ソーダ 8部
以上を均一に混合、微細に粉砕して、水和剤を得る。 (Formulation Example 1) Wetting agent Substance (A) 20 parts White carbon 20 parts Diatomaceous earth 52 parts Sodium alkyl sulfate 8 parts or more are uniformly mixed and finely pulverized to obtain a wettable powder.
物質(A) 20部
キシレン 55部
ジメチルホルムアミド 15部
ポリオキシエチレンフェニルエーテル 10部
以上を混合、溶解して乳剤を得る。 (Formulation Example 2) Emulsion Substance (A) 20 parts Xylene 55 parts Dimethylformamide 15 parts Polyoxyethylene phenyl ether 10 parts or more are mixed and dissolved to obtain an emulsion.
物質(A) 10部
タルク 37部
クレー 36部
ベントナイト 10部
アルキル硫酸ソーダ 7部
以上を均一に混合して微細に粉砕後、造粒して粒剤を得る。 (Formulation Example 3) Granules Substance (A) 10 parts Talc 37 parts Clay 36 parts Bentonite 10 parts Sodium alkyl sulfate 7 parts or more are uniformly mixed, finely pulverized, and granulated to obtain granules.
物質(A) 10部
ポリオキシエチレンアリールフェニルエーテルエーテル 2部
ジアルキルスルホサクシネートナトリウム塩 0.5部
グリセリン 5部
キサンタンガム 0.3部
水 82.2部
以上を混合し、湿式粉砕して、フロアブル剤を得る。 (Formulation Example 4) Flowable agent Substance (A) 10 parts Polyoxyethylene aryl phenyl ether ether 2 parts Dialkyl sulfosuccinate sodium salt 0.5 part Glycerin 5 parts Xanthan gum 0.3 part Water 82.2 parts or more , Wet pulverization to obtain a flowable agent.
物質(A) 30部
無機担体 70部
以上を均一に混合して微細に粉砕後、造粒して顆粒水和剤を得る。 (Formulation Example 5) Granule wettable powder Substance (A) 30 parts Inorganic carrier 70 parts or more are uniformly mixed, finely pulverized, and granulated to obtain a granule wettable powder.
表3に示す処方にてN,N-ジメチルホルムアミド溶液を調製し、試験用の薬液とした。
温室内で2.5葉期まで育成したトマト苗(品種:桃太郎)を用意した。
該トマト苗の茎葉部に、液が垂れ落ちる程の量の上記薬液を散布し、次いで風乾した。30℃で明所16時間および暗所8時間の条件下で2日間生育させた。その後、40℃の明所16時間および30℃の暗所8時間の条件下で6日間生育させた。
次いで、葉の褐変程度や伸長抑制などを観察し高温障害の状況を調査した。
障害は0(障害なし)~10(枯死)の11段階の障害指数で評価した。
溶媒DMFのみの処理区(薬液3)と比較した高温障害軽減率を次式により算出した。
高温障害軽減率=((溶媒のみ処理区の障害指数)-(各処理区の障害指数))
/(溶媒のみ処理区の障害指数) ×100
その結果を表3に示す。 Test Example 1 Evaluation Test for Reducing Effect of High Temperature Damage on Tomato An N, N-dimethylformamide solution was prepared according to the formulation shown in Table 3 and used as a test chemical.
Tomato seedlings (variety: Momotaro) grown to 2.5 leaf stage in a greenhouse were prepared.
The above chemical solution was sprayed onto the stem and leaves of the tomato seedlings, and then air-dried. The plants were grown at 30 ° C. under conditions of 16 hours in the light and 8 hours in the dark for 2 days. Thereafter, the cells were grown for 6 days under the conditions of 16 hours of light at 40 ° C. and 8 hours of dark at 30 ° C.
Next, we observed the degree of browning of the leaves and the suppression of elongation, and investigated the situation of high temperature damage.
Disorders were evaluated with an 11-step disability index ranging from 0 (no disability) to 10 (dead).
The high-temperature damage alleviation rate was calculated according to the following equation compared with the treatment zone (chemical solution 3) containing only the solvent DMF.
High-temperature damage reduction rate = ((solvent index for solvent only treatment area)-(failure index for each treatment area))
/ (Disability index of solvent-only treatment zone) x 100
The results are shown in Table 3.
温室内で育成したミニトマト(品種:レジナ、5連)を用意した。
第一花房開花期の8月24日に4-クロロフェノキシ酢酸0.15%を散布し、さらに7日間隔で、表4に記載した量のアスコルビン酸パルミテート30%顆粒水和剤を株元に2回施用した。9月28日に全果実を収穫し、果実の色(赤色および緑色に分類する。)、果実重量および粒数を調査し、1果実当たりの重量および赤色果実率(%)を求めた。
その結果を表4に示す。 Test Example 2 Evaluation test for reducing effects of high temperature damage on cherry tomato fruits Cherry tomatoes (variety: Resina, 5 series) grown in a greenhouse were prepared.
4-chlorophenoxyacetic acid 0.15% was sprayed on August 24 at the first flowering stage, and the amount of ascorbyl palmitate 30% granule wettable powder in the amount shown in Table 4 was added to the stock at intervals of 7 days. Applied twice. All the fruits were harvested on September 28, and the color of the fruits (classified as red and green), the weight of the fruits and the number of grains were examined, and the weight per fruit and the percentage of red fruits (%) were obtained.
The results are shown in Table 4.
表5に示す処方にてN,N-ジメチルホルムアミド溶液を調製し、試験用の薬液とした。
温室内で1.5葉期まで育成したキュウリ苗(品種:相模半白)を用意した。
該キュウリ苗の茎葉部に、液が垂れ落ちる程の量の前記薬液を散布し、次いで風乾した。25℃で明所16時間および暗所8時間の条件下で2日間生育させた。その後、10℃の明所16時間および7℃の暗所8時間の条件下で9日間生育させた。
次いで、葉の褐変程度や伸長抑制などを観察し低温障害の状況を調査した。
障害は0(障害なし)~10(枯死)の11段階の障害指数で評価した。
溶媒DMFのみの処理区(薬液3)と比較した低温障害軽減率を次式により算出した。
低温障害軽減率=((溶媒のみ処理区の障害指数)-(各処理区の障害指数))
/(溶媒のみ処理区の障害指数) ×100
その結果を表5に示す。 Test Example 3 Evaluation Test for Reduction Effect of Low Temperature Damage on Cucumber An N, N-dimethylformamide solution was prepared according to the formulation shown in Table 5 and used as a test chemical.
Cucumber seedlings (variety: Sagamihanjiro) grown to 1.5 leaf stage in a greenhouse were prepared.
The chemical solution was sprayed on the stems and leaves of the cucumber seedling so that the solution dripped, and then air-dried. The plants were grown at 25 ° C. under conditions of 16 hours in the light and 8 hours in the dark for 2 days. Thereafter, the cells were grown for 9 days under the conditions of 16 hours of light at 10 ° C and 8 hours of darkness at 7 ° C.
Next, the degree of low temperature damage was investigated by observing the degree of browning of leaves and suppression of elongation.
Disorders were evaluated with an 11-step disability index ranging from 0 (no disability) to 10 (dead).
The low-temperature damage alleviation rate was calculated according to the following equation compared with the treatment group (chemical solution 3) containing only the solvent DMF.
Low temperature damage reduction rate = ((solvent index of solvent only treatment area)-(failure index of each treatment area))
/ (Disability index of solvent-only treatment zone) x 100
The results are shown in Table 5.
温室内で4-6葉期まで育成したナス(品種:千両2号、3連)を用意した。
アスコルビン酸パルミテート30%顆粒水和剤と、N,N-ジメチルホルムアミドで40%に溶解したピラクロストロビンとを、水道水で表6に記載した濃度となるように希釈して苗全体に十分量を散布した。風乾後、18℃で明所16時間および13℃で暗所8時間の条件下で1日間生育させた後、13℃で明所16時間および8℃で暗所8時間の条件下で生育させた。散布処理15日後に障害程度を調査した。
障害は処理後の展開葉で変色した部分の面積を、0(変色なし)、1(全体の1/4まで変色)、2(全体の1/2まで変色)、3(全体の1/2以上変色)の4段階の障害指数で評価した。
障害軽減率=((無処理区の障害指数)-(各処理区の障害指数))
/(無処理区の障害指数) ×100
その結果を表6に示す。 Test Example 4 Evaluation Test for Reducing Effect of Low Temperature Damage on Eggplant Eggplants (variety: Senryo 2 and 3) grown to 4-6 leaf stage in a greenhouse were prepared.
Ascorbic acid palmitate 30% granule wettable powder and pyraclostrobin dissolved in 40% with N, N-dimethylformamide are diluted with tap water to the concentrations shown in Table 6 and sufficient for the whole seedling. Sprayed. After air drying, the cells were grown for 1 day at 18 ° C in a light place for 16 hours and at 13 ° C in a dark place for 8 hours, and then grown at 13 ° C in a light place for 16 hours and at 8 ° C in a dark place for 8 hours. It was. The degree of disability was investigated 15 days after the spraying treatment.
The obstacle is the area of the discolored portion of the developed leaf after processing: 0 (no discoloration), 1 (discolored to 1/4 of the whole), 2 (discolored to 1/2 of the whole), 3 (1/2 of the whole) Evaluation was made using the four-level disability index.
Disability reduction rate = ((Disability index for untreated areas)-(Disability index for each treated area))
/ (Disability index of untreated area) x 100
The results are shown in Table 6.
温室内で3.5葉期まで育成したトマト(品種:麗容、4連)を用意した。
アスコルビン酸パルミテートの30%顆粒水和剤と、N,N-ジメチルホルムアミドで40%に溶解したピラクロストロビンとを、水道水で表7に記載した濃度となるように希釈して苗全体に十分量を散布した。風乾後夜間の平均気温が0.5℃の温室外に搬出し、翌朝に低温による障害程度を調査した。
障害は、0(障害なし)~4(完全萎れ)の5段階の障害指数で評価した。これから次式により障害軽減率を算出した。
低温障害軽減率=(無処理区の障害指数)-(各処理区の障害指数))
/(無処理区の障害指数) ×100
その結果を表7に示す。 Test Example 5 Evaluation test for reducing effects of low-temperature injury on tomatoes Tomatoes (variety: Rei, 4 series) grown to 3.5 leaf stage in a greenhouse were prepared.
Dilute 30% granule wettable powder of ascorbyl palmitate and pyraclostrobin dissolved in 40% with N, N-dimethylformamide to the concentration shown in Table 7 with tap water to make it adequate for the whole seedling. The amount was sprayed. After air drying, the average temperature at night was taken out of the greenhouse with a temperature of 0.5 ° C.
Disability was evaluated with a five-point disability index from 0 (no disability) to 4 (complete wilt). The failure reduction rate was calculated from the following equation.
Low-temperature damage reduction rate = (Failure index for untreated areas)-(Failure index for each treated area))
/ (Disability index of untreated area) x 100
The results are shown in Table 7.
温度22℃、明所16時間の室内でセルトレイにて育成したトルコギキョウ(品種キングオブスノー)を用い、播種後半数程度が出芽した時点で、アスコルビン酸パルミテートの30%顆粒水和剤を蒸留水で所定濃度に希釈し、苗全体にその十分量を散布した。その後同じ方法による散布を週2回で初回を含め計10回行った。その間に、播種3週間後の本葉1対展開時期に明所16時間35℃・暗所8時間15℃の条件下に移し2週間育成した。さらにガラス温室に移して育成し、播種8週間後の本葉2対展開時に鉢上げを行い、そのまま温室にて育成し、その後、抽苔した株のうち開花した株の数を調査した。
その結果を表8に示す。 Test example 6 Evaluation test for the effect of reducing high temperature damage to Eustoma Ascorbic acid at the time when the latter half of the seeding emerged using Eustoma (variety King of Snow) grown in a cell tray indoors at a temperature of 22 ° C. and 16 hours light A 30% granular wettable powder of palmitate was diluted with distilled water to a predetermined concentration, and a sufficient amount thereof was sprayed on the entire seedling. Thereafter, spraying by the same method was performed twice a week for a total of 10 times including the first time. In the meantime, 3 weeks after sowing, the leaves were transferred to a pair of leaves at the time of development at 35 ° C. for 16 hours in the light and 15 ° C. for 8 hours in the dark and grown for 2 weeks. Further, the plants were transferred to a glass greenhouse and grown. The plants were raised when two pairs of true leaves were developed 8 weeks after sowing. The plants were grown in the greenhouse as they were, and then the number of flowering strains among the extracted strains was investigated.
The results are shown in Table 8.
温室内で2葉期まで育成したトマト(品種:麗容、2連)を用意した。
アスコルビン酸パルミテート30%顆粒水和剤とN,N-ジメチルホルムアミドで40%に溶解したピラクロストロビンを、各々水道水で表9に記載した濃度に希釈して苗全体に十分量を散布し、風乾後、夏季炎天下の強光に当てた。散布4日後に障害程度を調査した。
障害は光による影響で生じた壊死の程度を、0(壊死なし)~10(枯死)の11段階の障害指数で評価した。これから次式により障害軽減率を算出した。
障害軽減率=((無処理区の障害指数)-(各処理区の障害指数))
/(無処理区の障害指数) ×100
その結果を表9に示す。 Test Example 7 Evaluation test for reduction effect of strong light damage on tomatoes Tomatoes (variety: Rei, 2 series) grown to the second leaf stage in a greenhouse were prepared.
Ascorbic acid palmitate 30% granule wettable powder and pyraclostrobin dissolved in 40% with N, N-dimethylformamide were each diluted with tap water to the concentrations shown in Table 9 and sprayed in sufficient amounts throughout the seedling. After air drying, it was exposed to the strong light under the hot summer sun. The degree of disability was investigated 4 days after spraying.
The degree of necrosis caused by the influence of light was evaluated based on an 11-degree disability index from 0 (no necrosis) to 10 (death). The failure reduction rate was calculated from the following equation.
Disability reduction rate = ((Disability index for untreated areas)-(Disability index for each treated area))
/ (Disability index of untreated area) x 100
The results are shown in Table 9.
表10に示す処方にてN,N-ジメチルホルムアミド溶液を調製し、試験用の薬液とした。
温室内で4葉期まで育成したトマト苗(品種:桃太郎)を用意した。
該トマト苗の茎葉部に、液が垂れ落ちる程の量の上記薬液を散布し、次いで風乾した。日本の3月の平年の温湿度条件下において7日間生育させた。
次いで葉の褐変程度や伸長抑制などの薬害を調査した。
薬害は0(障害なし)~10(枯死)の11段階の薬害指数で評価した。
溶媒DMFのみの処理区と比較した薬害軽減率を次式により算出した。
薬害軽減率=((溶媒のみ処理区の薬害指数)-(各処理区の薬害指数))
/(溶媒のみ処理区の薬害指数) ×100
その結果を表10に示す。 Test Example 8 Evaluation Test for Mitigating Drug Damage to Tomato An N, N-dimethylformamide solution was prepared according to the formulation shown in Table 10 and used as a test drug solution.
Tomato seedlings (variety: Momotaro) grown to the 4th leaf stage in the greenhouse were prepared.
The above chemical solution was sprayed onto the stem and leaves of the tomato seedlings, and then air-dried. It was grown for 7 days under normal temperature and humidity conditions in March of Japan.
Next, phytotoxicity such as leaf browning and elongation suppression was investigated.
The phytotoxicity was evaluated with 11 phytotoxicity indices ranging from 0 (no injury) to 10 (dead).
The phytotoxicity reduction rate compared with the treatment section of only solvent DMF was calculated by the following formula.
Chemical hazard reduction rate = ((chemical hazard index of solvent only treatment area)-(phytotoxicity index of each treatment area))
/ (Phytotoxicity index of solvent-only treatment zone) x 100
The results are shown in Table 10.
圃場で生育させたコムギ(品種農林61号、15株/m2/区、2連)を用い、8月の出穂日の翌日から7日間間隔で、表11に記載した量のアスコルビン酸パルミテート30%顆粒水和剤を株元に4回施用した。9月6日に処理区内の各株の上位4~5葉の葉色指数を調査し、無処理区に対する葉色の維持効果を評価した。
葉色は、1(全体の1/4以下が変色)、2(全体の1/2以下が変色)、3(全体の3/4以下が変色)、4(全体の3/4以上が変色)の4段階の葉色指数で評価した。これから、平均葉色指数、および次式による緑色維持効果を算出した。
緑色維持効果=((無処理区の葉色指数)-(各処理区の葉色指数))
/(無処理区の葉色指数) ×100
その結果を表11に示す。 Test Example 9 Green maintenance (high temperature damage reduction) effect test on wheat Using wheat grown in the field (variety Norin 61, 15 strains / m 2 / ku, 2 stations), 7 days from the day after the heading date in August At intervals, the amount of ascorbyl palmitate 30% granule wettable powder described in Table 11 was applied to the strain 4 times. On September 6, the leaf color index of the top 4 to 5 leaves of each strain in the treated area was investigated, and the effect of maintaining the leaf color on the untreated area was evaluated.
The leaf color is 1 (less than 1/4 of the total color), 2 (less than 1/2 of the total color), 3 (less than 3/4 of the total color), 4 (over 3/4 of the total color) The four-stage leaf color index was evaluated. From this, the average leaf color index and the green maintenance effect by the following formula were calculated.
Green maintenance effect = ((Leaf color index of untreated section)-(Leaf color index of each treated section))
/ (Leaf color index of untreated zone) x 100
The results are shown in Table 11.
温室内で2葉期まで育成したキュウリ(品種:相模半白節成、2連)を用意した。
アスコルビン酸パルミテートの30%顆粒水和剤と、N,N-ジメチルホルムアミドで40%に調整したピラクロストロビンを水道水で所定濃度に希釈して十分量を散布した。散布処理2日後から子葉の直下まで湛水状態にし、散布処理11日後にキュウリの地上部と根部それぞれの生重量を測定した。これから次式により障害軽減率を算出した。
冠水障害軽減率=((各処理区の生重量)-(無処理区の生重量))
/(無処理区の生重量) ×100
結果を表12に示す。 Test Example 10 Evaluation Test for Mitigating Submergence Damage to Cucumber A cucumber (variety: Sagami Hansakusei, 2) grown in the greenhouse until the second leaf stage was prepared.
Ascorbic acid palmitate 30% granule wettable powder and pyraclostrobin adjusted to 40% with N, N-dimethylformamide were diluted with tap water to a predetermined concentration and sprayed in sufficient amounts. After 2 days from the spraying treatment, the mixture was flooded from just below the cotyledon, and 11 days after the spraying treatment, the fresh weight of the above-ground part and root part of the cucumber was measured. The failure reduction rate was calculated from the following equation.
Submergence damage reduction rate = ((raw weight of each treated area)-(raw weight of untreated area))
/ (Raw weight of untreated area) × 100
The results are shown in Table 12.
温室内で2葉期まで育成したダイズ(品種:エンレイ、2連)を用意した。
アスコルビン酸パルミテートの30%顆粒水和剤と、N,N-ジメチルホルムアミドで40%に調整したピラクロストロビンを水道水で所定濃度に希釈して十分量を散布した。散布処理2日後から子葉の直下まで湛水状態にし、散布処理11日後にダイズの地上部と根部それぞれの生重量を測定した。これから次式により障害軽減率を算出した。
冠水障害軽減率=((各処理区の生重量)-(無処理区の生重量))
/(無処理区の生重量) ×100
結果を表13に示す。 Test Example 11 Evaluation Test for Mitigating Flooding Damage to Soybeans Soybeans (variety: Enrei, 2 series) grown to the second leaf stage in a greenhouse were prepared.
Ascorbic acid palmitate 30% granule wettable powder and pyraclostrobin adjusted to 40% with N, N-dimethylformamide were diluted with tap water to a predetermined concentration and sprayed in sufficient amounts. After 2 days from the spraying treatment, the soil was flooded from just below the cotyledon, and 11 days after the spraying treatment, the fresh weight of the above-ground part and root part of soybean was measured. The failure reduction rate was calculated from the following equation.
Submergence damage reduction rate = ((raw weight of each treated area)-(raw weight of untreated area))
/ (Raw weight of untreated area) × 100
The results are shown in Table 13.
100mlのコルベンにて2葉期まで水耕育成したキュウリ(品種:相模半白節成、2連)を用意した。
アスコルビン酸パルミテートの30%顆粒水和剤と、N,N-ジメチルホルムアミドで40%に調整したピラクロストロビンとを、水道水で所定濃度に希釈して苗全体に十分量を散布した。散布処理2日後に水耕液を1N塩酸でpH4に調整し該キュウリを継続して水耕育成した。散布処理17日後にキュウリの葉齢を調査した。これから次式により障害軽減率を算出した。
酸性障害軽減率=((各処理区の葉齢)-(無処理区の葉齢))
/(無処理区の葉齢) ×100
結果を表14に示す。 Test Example 12 Evaluation Test for Reducing Effect of Acidic Damage on Cucumber Cucumber (variety: Sagami Hansakusei, 2 series) that was hydroponically grown up to the second leaf stage with 100 ml of Kolben was prepared.
A 30% granule wettable powder of ascorbyl palmitate and pyraclostrobin adjusted to 40% with N, N-dimethylformamide were diluted to a predetermined concentration with tap water, and a sufficient amount was sprayed over the entire seedling. Two days after the spraying treatment, the hydroponic solution was adjusted to pH 4 with 1N hydrochloric acid and the cucumber was continuously hydroponically grown. The cucumber leaf age was investigated 17 days after the spraying treatment. The failure reduction rate was calculated from the following equation.
Reduction rate of acid damage = ((leaf age of each treated area)-(leaf age of untreated area))
/ (Leaf age of untreated section) x 100
The results are shown in Table 14.
100mlのコルベンにて2葉期まで水耕育成したダイズ(品種:エンレイ、2連)を用意した。
アスコルビン酸パルミテートの30%顆粒水和剤と、N,N-ジメチルホルムアミドで40%に溶解したピラクロストロビンとを、水道水で所定濃度に希釈して苗全体に十分量を散布した。散布処理2日後に水耕液を1N塩酸でpH4に調整し該ダイズを継続して水耕育成した。散布処理11日後にダイズの障害を調査した。
障害は壊死の程度を、0(壊死なし)~10(枯死)の11段階の障害指数で評価した。これから次式により障害軽減率を算出した。
酸性障害軽減率=((無処理区の障害指数)-(各処理区の障害指数))
/(無処理区の障害指数) ×100
結果を表15に示す。 Test Example 13 Evaluation Test for Reducing Effect of Acidic Damage on Soybean Soybean (cultivar: Enrei, 2 series) that was hydroponically grown up to the second leaf stage with 100 ml of Kolben was prepared.
A 30% granule wettable powder of ascorbyl palmitate and pyraclostrobin dissolved in 40% with N, N-dimethylformamide were diluted to a predetermined concentration with tap water, and a sufficient amount was sprayed over the entire seedling. Two days after the spraying treatment, the hydroponic solution was adjusted to pH 4 with 1N hydrochloric acid, and the soybean was continuously hydroponically grown. The soybean damage was investigated 11 days after the spraying treatment.
The degree of injury was evaluated by an 11-level injury index ranging from 0 (no necrosis) to 10 (death). The failure reduction rate was calculated from the following equation.
Reduction rate of acid damage = ((Disability index of untreated area)-(Disability index of each treatment area))
/ (Disability index of untreated area) x 100
The results are shown in Table 15.
温室内で2葉期まで水耕育成したキュウリ(品種:相模半白節成、2連)を用意した。
アスコルビン酸パルミテートの30%顆粒水和剤と、N,N-ジメチルホルムアミドで40%に調整したピラクロストロビンとを、水道水で所定濃度に希釈して苗全体に十分量を散布し、風乾後、温室で通常の潅水で栽培した。その後、散布2日後から2cm深の0.1%塩化ナトリウム水溶液の湛水状態に切り替えて散布処理11日後まで栽培し、地上部および根部それぞれの生重量を測定した。これから次式により障害軽減率を算出した。
塩障害軽減率=((各処理区の生重量)-(無処理区の生重量))
/(無処理区の生重量) ×100
結果を表16に示す。 Test Example 14 Evaluation test for reducing salt damage to cucumber A cucumber (cultivar: Sagami Hansakusei, 2 series) that was hydroponically grown to the second leaf stage in a greenhouse was prepared.
30% granular wettable powder of ascorbyl palmitate and pyraclostrobin adjusted to 40% with N, N-dimethylformamide are diluted with tap water to a predetermined concentration and sprayed to the whole seedling, and after air drying Cultivated in a greenhouse with normal irrigation. Then, it switched to the flooded state of the 0.1-% sodium chloride aqueous solution of 2 cm depth from 2 days after spraying, and it was cultivated until 11 days after the spraying process, and measured the fresh weight of each above-ground part and a root part. The failure reduction rate was calculated from the following equation.
Reduction rate of salt damage = ((raw weight of each treated section)-(raw weight of untreated section))
/ (Raw weight of untreated area) × 100
The results are shown in Table 16.
温室内で2葉期まで水耕育成したダイズ(品種:エンレイ、2連)を用意した。
アスコルビン酸パルミテートの30%顆粒水和剤と、N,N-ジメチルホルムアミドで40%に調整したピラクロストロビンとを、水道水で所定濃度に希釈して苗全体に十分量を散布し、風乾後、温室で通常の潅水で栽培した。その後、散布2日後から2cm深の0.1%塩化ナトリウム水溶液の湛水状態に切り替えて散布処理11日後まで栽培し、地上部および根部それぞれの生重量を測定した。これから次式により障害軽減率を算出した。
塩障害軽減率=((各処理区の生重量)-(無処理区の生重量))
/(無処理区の生重量) ×100
結果を表17に示す。 Test Example 15 Evaluation Test for Reduction of Salt Damage to Soybean Soybean (cultivar: Enrei, 2 series) that was hydroponically grown to the second leaf stage in a greenhouse was prepared.
30% granular wettable powder of ascorbyl palmitate and pyraclostrobin adjusted to 40% with N, N-dimethylformamide are diluted with tap water to a predetermined concentration and sprayed to the whole seedling, and after air drying Cultivated in a greenhouse with normal irrigation. Then, it switched to the flooded state of the 0.1-% sodium chloride aqueous solution of 2 cm depth from 2 days after spraying, and it was cultivated until 11 days after the spraying process, and measured the fresh weight of each above-ground part and a root part. The failure reduction rate was calculated from the following equation.
Reduction rate of salt damage = ((raw weight of each treated section)-(raw weight of untreated section))
/ (Raw weight of untreated area) × 100
The results are shown in Table 17.
表18に示す処方にてN,N-ジメチルホルムアミド溶液を調製し、試験用の薬液を得た。
温室内で8葉期まで育成したトマト苗(品種:桃太郎)を用意した。
トマト黄化葉巻ウイルス(TYLCV)に罹病したトマト苗を接種源とした。
罹病株の茎を斜めに輪切りして、トマト苗に接木接種した。乾燥を防ぐためパラフィルムを接木部分に巻きつけて保護した。
接木接種後、トマト苗の茎葉部に、液が垂れ落ちる程の量の前記薬液を散布した。その後、約1週間間隔で液が垂れ落ちる程の量の前記薬液を3回散布した。接種から25日経過時にトマト黄化葉巻病の病徴を調査した。
病徴は0(発病なし)~4(激症)の5段階の発病指数で評価した。
溶媒DMFのみの処理区(薬液3)と比較した発病抑制率を次式により算出した。
発病抑制率=((溶媒のみ処理区の発病指数)-(各処理区の発病指数))
/(溶媒のみ処理区の発病指数) ×100
また、コルビーの式に基づいて発病抑制率の期待値を算出した。
なお、コルビーの式は、 E=M+N-MN/100 である。ここで、Eは発病抑制率の期待値(%)、Mは物質(A1)の単独使用時の測定から算出された発病抑制率(%)、Nは物質(A2)の単独使用時の測定から算出された発病抑制率(%)を示す。
その結果を表18に示す。 Test Example 16 Symptom-reducing effect test for tomato yellow leaf curl virus disease An N, N-dimethylformamide solution was prepared according to the formulation shown in Table 18 to obtain a test drug solution.
Tomato seedlings (variety: Momotaro) grown to the 8th leaf stage in the greenhouse were prepared.
Tomato seedlings afflicted with tomato yellow leaf curl virus (TYLCV) were used as the inoculation source.
The stems of diseased strains were cut diagonally and inoculated to tomato seedlings. In order to prevent drying, parafilm was wrapped around the grafted portion to protect it.
After grafting inoculation, the chemical solution was sprayed onto the tomato seedlings. Thereafter, the chemical solution was sprayed three times in such an amount that the solution dripped at about one week intervals. At 25 days after inoculation, the symptoms of tomato yellow leaf curl disease were investigated.
Symptoms were evaluated with a 5-stage disease index from 0 (no disease) to 4 (severe illness).
The disease suppression rate compared with the treatment area (chemical | medical solution 3) only of solvent DMF was computed by following Formula.
Disease control rate = ((Sickness index of solvent-only treatment section)-(Sickness index of each treatment section))
/ (Sickness index of solvent only treatment area) x 100
Moreover, the expected value of the disease suppression rate was calculated based on the Colby equation.
The Colby equation is E = M + N−MN / 100. Here, E is the expected value (%) of the disease suppression rate, M is the disease suppression rate (%) calculated from the measurement when the substance (A1) is used alone, and N is the measurement when the substance (A2) is used alone. The disease suppression rate (%) calculated from
The results are shown in Table 18.
イネ(品種:コシヒカリ、10連)の苗を用意した。アスコルビン酸パルミテートの30%顆粒水和剤と、N,N-ジメチルホルムアミドで5%に調整したピラクロストロビンとを、水道水で所定濃度に希釈し、これらの十分量を苗全体に散布し風乾した。その翌日にいもち病菌を接種し、接種の11日後にいもち病斑数を調査し、これから防除価を次式により算出した。
防除価=((無処理区の病斑数)-(各処理区の病斑数))
/(無処理区の病斑数) ×100
その結果を表19に示す。 Test Example 17 Disease Stress Reducing Effect Test for Rice Rice (cultivar: Koshihikari, 10 series) seedlings were prepared. 30% granular wettable powder of ascorbyl palmitate and pyraclostrobin adjusted to 5% with N, N-dimethylformamide are diluted with tap water to a predetermined concentration. did. The next day, the blast fungus was inoculated, and the number of blast spots was investigated 11 days after the inoculation, and the control value was calculated from the following formula.
Control value = ((number of lesions in untreated section)-(number of spots in each treated section))
/ (Number of lesions in untreated area) x 100
The results are shown in Table 19.
Claims (11)
- 式(I):
[式(I)中、R1~R4はそれぞれ独立して、水素原子、-SO3H、-PO3H2、グリコシル基または-COR11を示す。R11は、無置換の若しくは置換基を有するC1~30アルキル基または無置換の若しくは置換基を有するC2~30アルケニル基を示す。]で表される化合物、
式(II):
[式(II)中、R5およびR6はそれぞれ独立して、水素原子、-SO3H、-PO3H2、グリコシル基または-COR11を示す。R11は、無置換の若しくは置換基を有するC1~30アルキル基または無置換の若しくは置換基を有するC2~30アルケニル基を示す。]で表される化合物およびそれらの塩からなる群から選ばれる少なくとも一つの物質(A)を植物に施用することを含む、ストレスに対する抵抗性を植物に付与する方法。 Formula (I):
[In the formula (I), R 1 to R 4 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 . R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group. A compound represented by
Formula (II):
[In the formula (II), R 5 and R 6 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 . R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group. A method for imparting stress resistance to a plant, comprising applying to the plant at least one substance (A) selected from the group consisting of a compound represented by the formula: - 物質(A)が、式(I)[ただし、すべてのR1~R4が同時に水素原子であることはない。]で表される化合物またはその塩である、請求項1に記載の方法。 The substance (A) is represented by the formula (I) [wherein all R 1 to R 4 are not hydrogen atoms at the same time. The method of Claim 1 which is a compound represented by these, or its salt.
- 物質(A)が、式(I)[ただし、R1~R4のうち少なくとも一つは-COR11を示し、R11は、無置換の若しくは置換基を有するC12~30アルキル基または無置換の若しくは置換基を有するC12~30アルケニル基を示す。]で表される化合物またはその塩である、請求項1に記載の方法。 Material (A) has the formula (I) [provided that at least one of R 1 ~ R 4 represents a -COR 11, R 11 are, C12 ~ 30 alkyl group or unsubstituted having unsubstituted or substituted Or a C12-30 alkenyl group having a substituent. The method of Claim 1 which is a compound represented by these, or its salt.
- 物質(A)が、式(I)[ただし、R1~R4はそれぞれ独立して、水素原子、または-COR11を示し、且つR1~R4のうち少なくとも一つは-COR11を示す。R11は、無置換の若しくは置換基を有するC1~30アルキル基または無置換の若しくは置換基を有するC2~30アルケニル基を示す。-COR11のうち少なくとも一つはその中のR11が無置換の若しくは置換基を有するC12~30アルキル基または無置換の若しくは置換基を有するC12~30アルケニル基を示す。]で表される化合物またはその塩である、請求項1に記載の方法。 Material (A) has the formula (I) [where independently R 1 ~ R 4 each represents a hydrogen atom or -COR 11,, and at least one -COR 11 of R 1 ~ R 4 Show. R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group. At least one of -COR 11 indicates the C12 ~ 30 alkenyl group having C12 ~ 30 alkyl group or an unsubstituted or substituted radical having R 11 is an unsubstituted or substituted group therein. The method of Claim 1 which is a compound represented by these, or its salt.
- 物質(A)が、式(I)で表される化合物、式(II)で表される化合物、およびそれらの塩からなる群から選ばれる物質のうちの水溶性のもの(A1)と、式(I)で表される化合物、式(II)で表される化合物、およびそれらの塩からなる群から選ばれる物質のうちの脂溶性のもの(A2)とを含有する組成物である、請求項1に記載の方法。 The substance (A) is a water-soluble substance (A1) selected from the group consisting of a compound represented by the formula (I), a compound represented by the formula (II), and a salt thereof; A composition comprising a compound represented by (I), a compound represented by formula (II), and a fat-soluble substance (A2) among substances selected from the group consisting of salts thereof, Item 2. The method according to Item 1.
- 前記ストレスが、植物ウイルス、植物病原細菌、植物病原糸状菌、害虫若しくは雑草による生物的ストレス;または、高温、低温、高照度、低照度、過湿、乾燥、塩分、酸性、農薬、化学物質若しくは重金属による物理的若しくは化学的ストレスのいずれか少なくとも一つである、請求項1~5のいずれか一つに記載の方法。 The stress is a biological stress caused by plant viruses, phytopathogenic bacteria, phytopathogenic fungi, pests or weeds; The method according to any one of claims 1 to 5, wherein the method is at least one of physical and chemical stresses caused by heavy metals.
- 式(I):
[式(I)中、R1~R4はそれぞれ独立して、水素原子、-SO3H、-PO3H2、グリコシル基または-COR11を示す。R11は、無置換の若しくは置換基を有するC1~30アルキル基または無置換の若しくは置換基を有するC2~30アルケニル基を示す。]で表される化合物、
式(II):
[式(II)中、R5およびR6はそれぞれ独立して、水素原子、-SO3H、-PO3H2、グリコシル基または-COR11を示す。R11は、無置換の若しくは置換基を有するC1~30アルキル基または無置換の若しくは置換基を有するC2~30アルケニル基を示す。]で表される化合物およびそれらの塩からなる群から選ばれる少なくとも二つの物質(A)を含有する植物用ストレス抵抗性付与剤組成物。 Formula (I):
[In the formula (I), R 1 to R 4 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 . R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group. A compound represented by
Formula (II):
[In the formula (II), R 5 and R 6 each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , a glycosyl group or —COR 11 . R 11 represents an unsubstituted or substituted C1-30 alkyl group or an unsubstituted or substituted C2-30 alkenyl group. ] The stress resistance imparting agent composition for plants containing the at least 2 substance (A) chosen from the group which consists of the compound represented by these, and those salts. - 一つの物質(A)が式(I)で表される化合物、式(II)で表される化合物、およびそれらの塩からなる群から選ばれる物質のうちの水溶性のもの(A1)であり、他の一つの物質(A)が式(I)で表される化合物、式(II)で表される化合物、およびそれらの塩からなる群から選ばれる物質のうちの脂溶性のもの(A2)である、請求項7に記載の組成物。 One substance (A) is a water-soluble substance (A1) selected from the group consisting of a compound represented by formula (I), a compound represented by formula (II), and a salt thereof. In addition, the other one substance (A) is a fat-soluble substance (A2) selected from the group consisting of a compound represented by formula (I), a compound represented by formula (II), and a salt thereof (A2) The composition according to claim 7, wherein
- 式(Ia):
[式(Ia)中、R1a~R4aはそれぞれ独立して、水素原子、-SO3H、-PO3H2、またはグリコシル基を示す。]で表される化合物、
式(IIa):
[式(IIa)中、R5aおよびR6aはそれぞれ独立して、水素原子、-SO3H、-PO3H2、またはグリコシル基を示す。]で表される化合物およびそれらの塩からなる群から選ばれる少なくとも一つの水溶性物質(A1)と、
式(Ib):
[式(Ib)中、R1b~R4bはそれぞれ独立して、水素原子、または-COR11を示す。R1b~R4bのうち少なくとも一つは-COR11を示し、R11は、無置換の若しくは置換基を有するC1~30アルキル基または無置換の若しくは置換基を有するC2~30アルケニル基を示す。]で表される化合物、
式(IIb):
[式(IIb)中、R5bおよびR6bはそれぞれ独立して、水素原子、または-COR11を示す。R5bおよびR6bのうち少なくとも一つは-COR11を示し、R11は、無置換の若しくは置換基を有するC1~30アルキル基または無置換の若しくは置換基を有するC2~30アルケニル基を示す。]で表される化合物およびそれらの塩からなる群から選ばれる少なくとも一つの脂溶性物質(A2)とを含有する植物用ストレス抵抗性付与剤組成物。 Formula (Ia):
[In Formula (Ia), R 1a to R 4a each independently represents a hydrogen atom, —SO 3 H, —PO 3 H 2 , or a glycosyl group. A compound represented by
Formula (IIa):
[In Formula (IIa), R 5a and R 6a each independently represent a hydrogen atom, —SO 3 H, —PO 3 H 2 , or a glycosyl group. At least one water-soluble substance (A1) selected from the group consisting of compounds represented by the formula:
Formula (Ib):
[In the formula (Ib), R 1b to R 4b each independently represents a hydrogen atom or —COR 11 . At least one of R 1b ~ R 4b represents a -COR 11, R 11 represents a C2 ~ 30 alkenyl group having C1 ~ 30 alkyl group or an unsubstituted or substituted group having an unsubstituted or substituted . A compound represented by
Formula (IIb):
[In the formula (IIb), R 5b and R 6b each independently represent a hydrogen atom or —COR 11 . At least one of R 5b and R 6b represents a -COR 11, R 11 represents a C2 ~ 30 alkenyl group having C1 ~ 30 alkyl group or an unsubstituted or substituted group having an unsubstituted or substituted . ] The stress resistance imparting agent composition for plants containing the at least 1 fat-soluble substance (A2) chosen from the group which consists of the compound represented by these, and those salts. - 請求項1~6のいずれか一つに記載の方法によって植物にストレスに対する抵抗性を付与することを含む、農薬による植物の薬害を軽減する方法。 A method for reducing the phytotoxicity of plants caused by agricultural chemicals, comprising imparting resistance to stress to plants by the method according to any one of claims 1 to 6.
- 農薬が、殺菌剤、殺虫剤、植物成長調整剤、および除草剤からなる群から選ばれる少なくとも一つを含むものである、請求項10に記載の農薬による植物の薬害を軽減する方法。 The method for reducing plant phytotoxicity caused by an agrochemical according to claim 10, wherein the agrochemical includes at least one selected from the group consisting of a fungicide, an insecticide, a plant growth regulator, and a herbicide.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR112015001016A BR112015001016A2 (en) | 2012-07-20 | 2013-07-19 | METHODS FOR PROVIDING A PLANT WITH STRESS RESISTANCE, AND FOR REDUCING PHYTOXICITY OF A PLANT DUE TO AN AGRICULTURAL CHEMICAL, AND COMPOSITION THAT CONFERS STRESS RESISTANCE TO A PLANT |
AU2013291440A AU2013291440B2 (en) | 2012-07-20 | 2013-07-19 | Method of providing plant with stress resistance |
CA2879519A CA2879519A1 (en) | 2012-07-20 | 2013-07-19 | Method of providing plants with stress resistance by applying an ascorbic acid derived compound |
US14/415,285 US20150126368A1 (en) | 2012-07-20 | 2013-07-19 | Method of providing plant with stress resistance |
EP13820583.6A EP2875730A4 (en) | 2012-07-20 | 2013-07-19 | Method for providing plants with resistance to stress |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012-161898 | 2012-07-20 | ||
JP2012161898 | 2012-07-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014013744A1 true WO2014013744A1 (en) | 2014-01-23 |
Family
ID=49948582
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2013/004430 WO2014013744A1 (en) | 2012-07-20 | 2013-07-19 | Method for providing plants with resistance to stress |
Country Status (7)
Country | Link |
---|---|
US (1) | US20150126368A1 (en) |
EP (1) | EP2875730A4 (en) |
JP (1) | JP2014037407A (en) |
AU (1) | AU2013291440B2 (en) |
BR (1) | BR112015001016A2 (en) |
CA (1) | CA2879519A1 (en) |
WO (1) | WO2014013744A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2524857A (en) * | 2013-11-01 | 2015-10-07 | Innospec Ltd | Detergent compositions |
WO2016063896A1 (en) * | 2014-10-21 | 2016-04-28 | サントリーホールディングス株式会社 | Ascorbic acid derivative and glycoside production method using same |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2875729A4 (en) * | 2012-07-20 | 2016-03-09 | Nippon Soda Co | Drug composition for reducing stress on plants |
WO2019104210A1 (en) * | 2017-11-21 | 2019-05-31 | Advanced Biological Marketing, Inc. | Compositions and methods for inducing crop changes by leveraging the effects of an applied agricultural chemical |
CN114828633A (en) * | 2019-12-20 | 2022-07-29 | 根特大学 | Use of dehydroascorbic acid against nematode infection in plants |
JP2023164255A (en) * | 2022-04-28 | 2023-11-10 | 花王株式会社 | Root nodule activity promoting agent |
CN114903057B (en) * | 2022-06-24 | 2023-09-05 | 西北农林科技大学 | Plant regulator for improving stress resistance of crops |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04342507A (en) * | 1991-05-17 | 1992-11-30 | Meiji Seika Kaisha Ltd | Plant growth controller and method for enhancing stress resistance of plant |
JP2001508808A (en) | 1996-02-20 | 2001-07-03 | エイ. バダワイ、モハメッド | How to increase the antibacterial properties of antibacterial antibiotics |
JP2008538566A (en) * | 2005-04-21 | 2008-10-30 | グレン エー. ゴールドスタイン, | N-acetylcysteine amide (NAC amide) to promote plant resistance and tolerance to environmental stress |
WO2011030816A1 (en) | 2009-09-14 | 2011-03-17 | 国立大学法人北海道大学 | Anti-plant-virus agent |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3973032A (en) * | 1975-09-19 | 1976-08-03 | Board Of Regents, State Of Florida For And On Behalf Of The University Of Florida | Treatment of citrus tree diseases |
US5004493A (en) * | 1988-06-10 | 1991-04-02 | Norris Dale M | Method for inducing resistance in plants using environmentally safe antioxidants |
JPH05170605A (en) * | 1991-12-20 | 1993-07-09 | Iseki & Co Ltd | Spray for tomato leaf |
CA2471999C (en) * | 2002-01-04 | 2011-04-26 | University Of Guelph | Compositions for the preservation of fruits and vegetables |
WO2004095926A2 (en) * | 2003-04-28 | 2004-11-11 | Monsanto Technology, Llc | Treatment of plants and plant propagation materials with an antioxidant to improve plant health and/or yield |
EP2468097A1 (en) * | 2010-12-21 | 2012-06-27 | Bayer CropScience AG | Use of Isothiazolecarboxamides to create latent host defenses in a plant |
CN104080333B (en) * | 2011-12-22 | 2017-06-23 | 维弗作物保护公司 | Strobilurins preparation |
-
2013
- 2013-07-19 JP JP2013151151A patent/JP2014037407A/en active Pending
- 2013-07-19 EP EP13820583.6A patent/EP2875730A4/en not_active Withdrawn
- 2013-07-19 US US14/415,285 patent/US20150126368A1/en not_active Abandoned
- 2013-07-19 AU AU2013291440A patent/AU2013291440B2/en not_active Ceased
- 2013-07-19 CA CA2879519A patent/CA2879519A1/en not_active Abandoned
- 2013-07-19 BR BR112015001016A patent/BR112015001016A2/en not_active IP Right Cessation
- 2013-07-19 WO PCT/JP2013/004430 patent/WO2014013744A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04342507A (en) * | 1991-05-17 | 1992-11-30 | Meiji Seika Kaisha Ltd | Plant growth controller and method for enhancing stress resistance of plant |
JP2001508808A (en) | 1996-02-20 | 2001-07-03 | エイ. バダワイ、モハメッド | How to increase the antibacterial properties of antibacterial antibiotics |
JP2008538566A (en) * | 2005-04-21 | 2008-10-30 | グレン エー. ゴールドスタイン, | N-acetylcysteine amide (NAC amide) to promote plant resistance and tolerance to environmental stress |
WO2011030816A1 (en) | 2009-09-14 | 2011-03-17 | 国立大学法人北海道大学 | Anti-plant-virus agent |
Non-Patent Citations (3)
Title |
---|
See also references of EP2875730A4 |
THE HORTICULTURE JOURNAL, vol. 6, no. 2, pages 169 - 175 |
VITAMINS, vol. 79, no. 2, 2005, pages 116 - 117 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2524857A (en) * | 2013-11-01 | 2015-10-07 | Innospec Ltd | Detergent compositions |
US9902707B2 (en) | 2013-11-01 | 2018-02-27 | Innospec Limited | Detergent compositions |
US9981933B2 (en) | 2013-11-01 | 2018-05-29 | Innospec Limited | Detergent compositions |
WO2016063896A1 (en) * | 2014-10-21 | 2016-04-28 | サントリーホールディングス株式会社 | Ascorbic acid derivative and glycoside production method using same |
JPWO2016063896A1 (en) * | 2014-10-21 | 2017-08-03 | サントリーホールディングス株式会社 | Ascorbic acid derivative and method for producing glycosides using this derivative |
Also Published As
Publication number | Publication date |
---|---|
US20150126368A1 (en) | 2015-05-07 |
CA2879519A1 (en) | 2014-01-23 |
BR112015001016A2 (en) | 2017-08-22 |
EP2875730A1 (en) | 2015-05-27 |
JP2014037407A (en) | 2014-02-27 |
EP2875730A4 (en) | 2016-03-09 |
AU2013291440A1 (en) | 2015-02-12 |
AU2013291440B2 (en) | 2015-08-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6212707B2 (en) | Pharmaceutical composition for reducing stress on plants | |
WO2014013744A1 (en) | Method for providing plants with resistance to stress | |
JP6752210B2 (en) | Agricultural and horticultural fungicide composition | |
BRPI0806771A2 (en) | pesticide combinations | |
WO2008062823A1 (en) | Plant disease control composition and method for the prevention and control of plant diseases | |
WO2018101223A1 (en) | Microorganism having ability to control plant disease | |
US20100144531A1 (en) | Method for enhancing intrinsic productivity of a plant | |
JP5091470B2 (en) | Agricultural and horticultural compositions | |
JPWO2019163868A1 (en) | Agricultural and horticultural fungicide composition | |
JP5719644B2 (en) | Bacterial disease control agent and bacterial disease control method for plants | |
US20210029995A1 (en) | Use of Volatile Organic Compounds as Pesticides | |
CN110087463B (en) | Solid composition for pest control containing cyclic bromodiamide or salt thereof | |
US20100173776A1 (en) | Method for enhancing plant tolerance | |
JP2017184738A (en) | Coated seed | |
JP5010204B2 (en) | Composition for controlling plant diseases | |
JP2022031416A (en) | Plant disease control method and bactericidal composition for agricultural and horticultural use | |
JPH0649039A (en) | Pyrimidine derivative, herbicide and fungicide for agricultural and horticultural use | |
JP2020097575A (en) | 1,3,5,6-TETRA SUBSTITUTED THIENO[2,3-d]PYRIMIDINE-2,4(1H,3H)DIONE COMPOUND AND HORTICULTURAL BACTERICIDE | |
KR102646989B1 (en) | Agricultural and horticultural compositions | |
JP2003137703A (en) | Pest-preventing agent for plant and method for preventing pest | |
WO2020225149A1 (en) | Use of volatile organic compounds as molluscides |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 13820583 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14415285 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 2879519 Country of ref document: CA |
|
REEP | Request for entry into the european phase |
Ref document number: 2013820583 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2013820583 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2013291440 Country of ref document: AU Date of ref document: 20130719 Kind code of ref document: A |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112015001016 Country of ref document: BR |
|
ENP | Entry into the national phase |
Ref document number: 112015001016 Country of ref document: BR Kind code of ref document: A2 Effective date: 20150115 |