JP2022031416A - Plant disease control method and bactericidal composition for agricultural and horticultural use - Google Patents

Abstract

To provide a plant disease control method that shows excellent control effect on a plant disease even at a low dosage, and causes no risk of chemical damage to useful plants, and a bactericide for agricultural and horticultural use.SOLUTION: A bactericide for agricultural and horticultural use contains ipflufenoquin, and at least one component B selected from a group consisting of biological pesticides/biological agrochemicals, a phosphorous acid or salts thereof.SELECTED DRAWING: None

Description

The present invention relates to a plant disease control method and a fungicide composition for agriculture and horticulture. More specifically, the present invention relates to a plant disease control method and an agricultural and horticultural bactericidal composition, which show an excellent control effect on plant diseases even at a low dose and do not have to worry about drug damage to useful plants.

Many chemicals for controlling crop diseases are used in the cultivation of agricultural and horticultural crops. However, its use is restricted due to insufficient control effect, the emergence of drug-resistant pathogens, it causes phytotoxicity and contamination of plants, and it is highly toxic to humans, livestock and fish. Many of them are far from being fully satisfactory control agents.

Against this background, various fungicide compositions and mixtures thereof containing a nitrogen-containing heterocyclic compound and / or a salt thereof as an active ingredient have been proposed (see, for example, Patent Documents 1 to 4).

WO2011 / 081174 WO2013 / 047441 WO2017 / 061483 WO2019 / 163868

An object of the present invention is to provide a plant disease control method and an agricultural and horticultural bactericidal composition, which show an excellent control effect on plant diseases even at a low dose and do not have to worry about drug damage to useful plants. ..

We have been diligently researching to solve the above problems. As a result, the present invention including the following forms has been completed.

That is, the present invention is as follows.
(1)
Ipfluphenokin and biological pesticides or pesticides derived from living organisms, phosphite or salts thereof, mineral oils, organic oils, material of biological origin, potassium hydrogen carbonate (Potassium) bicarbonate), sodium hydrogen carbonate, Calcium carbonate, Calcium hydroxide, Potassium iodide, Potassium phosphonates, Chitosan hydrochloride , D-Limonene, Orange Oil, Urea, and an agricultural and horticultural bactericide composition containing at least one component B selected from the group consisting of elicitor.
(2)
Biopesticide of component B or pesticide derived from organism
Extract from the cotyledons of lupine plantlets, extract from Swinglea glutinosa, extract from Melaleuca alternifolia (tea tree oil) ), Α-pinene (Alpha-pinene), α-terpinene (Alpha-terpinene), α-terpineol (Alpha-terpineol), α-terpinene (Alpha-terpinoline), γ-terpinene (Gamma-terpinene),
Vegetable oils (mixtures), eugenol, geraniol, thymol;
Trichoderma atroviride strain I-1237, Trichoderma atroviride strain LU132, Trichoderma atroviride strain SC1 and Trichoderma atroviride strain SC1 strain SKT-1), Trichoderma atroviride strain 77B,
Trichoderma asperellum strain T34, Trichoderma asperellum strain kd,
Trichoderma harzianum strain T-22,
Trichoderma, including Trichoderma virens strain G-41;
Gliocladium, including the Gliocladium catenulatum strain J1446;
Clonostachys rosea strain CR-7, including Clonostachys rosea strain CR-7;
Coniothyrium, including Coniothyrium minitans strain CON / M / 91-08;
Talaromyces, including the Talaromyces flavus strain SAY-Y-94-01;
Saccharomyces, including Saccharomyces cerevisae strain LAS02;
Bacillus amyloliquefaciens strain QST713 (Bacillus amyloliquefaciens strain QST713), Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain MBI600 Bacillus amyloliquefaciens strain D747, Bacillus amyloliquefaciens strain F727, Bacillus amyloliquefaciens strain AT-332,
Bacillus subtilis strain AFS032321 strain (Bacillus subtilis strain AFS032321), Bacillus subtilis strain Y1336 strain (Bacillus subtilis strain Y1336), Bacillus subtilis strain HAI-0404 strain (Bacillus subtilis strain HAI-0404), including Bacillus subtilis strain HAI-0404, Bacillus simplex Bacillus;
Paenibacillus;
Burkholderia;
Pseudomonas fluoraphis strain AFS009, Pseudomonas fluorescens, Pseudomonas rhodesiae, Pseudomonas rhodesiae, Pseudomonas rhodesiae
Streptomyces, including Streptomyces griseovirides strain K61, Streptomyces lydicus strain WYEC108;
Agrobacterium, including Agrobacterium radiobacter;
Non-pathogenic Erwinia, including Erwinia carotovora subsp. Carotovora;
Variovorax paradoxus, variovorax; and Lactobacillus plantarum, Lactobacillus;
The fungicide composition for agriculture and horticulture according to (1), which is at least one selected from the group consisting of.
(3)
Phosphorous acid salts are potassium phosphite (Potassium phosphite), ammonium phosphite (Ammonium phosphite), calcium phosphite (Calcium phosphite), aluminum phosphite (Aluminum phosphite) and sodium phosphite (Disodium phosphonate), The bactericidal composition for agriculture and gardening according to (1) or (2), which is at least one selected from the group consisting of.
(4)
The elicitor is yeast or its extract, β-glucan, chitin or chitosan or fragments thereof, β-aminobutyric acid, 2,6-dichloroisonicotinic acid, salicylic acid or its derivatives, algae extract, algae extract (hydrogenated). Degradants), jasmine flower extract, sodium alginate, oligosaccharides, laminarin (β-1,3-glucooligosaccharide), trehalose, polysaccharides, lipids, lipopolysaccharides, fatty acids, glycolipids, glycoproteins, glycopeptides, plants and / or The agricultural and horticultural bactericidal composition according to any one of (1) to (3), which is at least one selected from the group consisting of proteins or peptides derived from pathogenic microorganisms and ergosterol.
(5)
Ipfluphenokin and biological pesticides or pesticides derived from living organisms, phosphite or salts thereof, mineral oils, organic oils, material of biological origin, potassium hydrogen carbonate (Potassium) bicarbonate, sodium hydrogen carbonate, Calcium carbonate, Calcium hydroxide, Potassium iodide, Potassium phosphonates, Chitosan hydrochloride , D-Limonene, Orange Oil, Urea, and at least one ingredient B selected from the group consisting of elicitor, used simultaneously, separately or at intervals of time. How to control plant diseases.
(6)
Biopesticide of component B or pesticide derived from organism
Extract from the cotyledons of lupine plantlets, extract from Swinglea glutinosa, extract from Melaleuca alternifolia (tea tree oil) ), Α-pinene (Alpha-pinene), α-terpinene (Alpha-terpinene), α-terpineol (Alpha-terpineol), α-terpinene (Alpha-terpinoline), γ-terpinene (Gamma-terpinene), vegetable oils ( Mixtures (plant oils (mixtures)), eugenol, geraniol, thymol;
Trichoderma atroviride strain I-1237, Trichoderma atroviride strain LU132, Trichoderma atroviride strain SC1 and Trichoderma atroviride strain SC1 strain SKT-1), Trichoderma atroviride strain 77B,
Trichoderma asperellum strain T34, Trichoderma asperellum strain kd,
Trichoderma harzianum strain T-22,
Trichoderma, including Trichoderma virens strain G-41;
Gliocladium, including the Gliocladium catenulatum strain J1446;
Clonostachys rosea strain CR-7, including Clonostachys rosea strain CR-7;
Coniothyrium, including Coniothyrium minitans strain CON / M / 91-08;
Talaromyces, including the Talaromyces flavus strain SAY-Y-94-01;
Saccharomyces, including Saccharomyces cerevisae strain LAS02;
Bacillus amyloliquefaciens strain QST713 (Bacillus amyloliquefaciens strain QST713), Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain MBI600 Bacillus amyloliquefaciens strain D747, Bacillus amyloliquefaciens strain F727, Bacillus amyloliquefaciens strain AT-332,
Bacillus subtilis strain AFS032321 strain (Bacillus subtilis strain AFS032321), Bacillus subtilis strain Y1336 strain (Bacillus subtilis strain Y1336), Bacillus subtilis strain HAI-0404 strain (Bacillus subtilis strain HAI-0404), Bacillus simplex Bacillus;
Paenibacillus;
Burkholderia;
Pseudomonas genus; Pseudomonas chlororaphis strain AFS009, Pseudomonas fluorescens, Pseudomonas rhodesiae, Pseudomonas genus Pseudomonas
Streptomyces, including Streptomyces griseovirides strain K61, Streptomyces lydicus strain WYEC108;
Agrobacterium, including agrobacterium radiobacter;
Non-pathogenic Erwinia genus (erwinia), including erwinia carotovora subsp. Carotovora;
Variovorax, including the variovorax paradoxus;
Lactobacillus plantarum, including Lactobacillus plantarum;
The plant disease control method according to claim 5, which is at least one selected from the group consisting of.
(7)
Phosphorous acid salts are potassium phosphite (Potassium phosphite), ammonium phosphite (Ammonium phosphite), calcium phosphite (Calcium phosphite), aluminum phosphite (Aluminum phosphite) and sodium phosphite (Disodium phosphonate), The method for controlling plant diseases according to (5) or (6), which is at least one selected from the group consisting of.
(8)
The elicitor is yeast or its extract, β-glucan, chitin or chitosan or fragments thereof, β-aminobutyric acid, 2,6-dichloroisonicotinic acid, salicylic acid or its derivative, algae extract, algae extract (hydrogenated). Degradants), jasmine flower extract, sodium alginate, oligosaccharides, laminarin (β-1,3-glucooligosaccharides), trehalose, polysaccharides, lipids, lipopolysaccharides, fatty acids, glycolipids, glycoproteins, glycopeptides, plants and / or The method for controlling plant diseases according to any one of (5) to (7), which is at least one selected from the group consisting of proteins or peptides derived from pathogenic microorganisms and ergosterol.

The plant disease control method and the horticultural bactericidal composition of the present invention show an excellent control effect against plant diseases even at a very low dose, and there is no concern about phytotoxicity to useful plants. The plant disease control method and the horticultural bactericidal composition of the present invention have a remarkable synergistic plant disease control effect that cannot be predicted from the plant disease control effect obtained by using only ipfluphenokin or only component B. Play.

In the plant disease control method of the present invention, ipfluphenokin can be mixed or used in combination with one or more components selected from the group consisting of component B (hereinafter referred to as this component).
The above-mentioned mixed use or combined use means that ipfluphenokine and this ingredient are used at the same time, separately or at intervals of time.
When the ipfluphenokin and the present ingredient are used at the same time, the ipflufenokin and the present ingredient may be contained in separate formulations or may be contained in one formulation.
That is, the agricultural and horticultural fungicide composition of the present invention contains ipfluphenokin and the present component.
When using ipflufenokin and this ingredient separately or at intervals of time, ipflufenokin may be applied first, then this ingredient may be applied, or this ingredient may be applied first. , Then Ipfluphenokin may be applied.

[Ipflufenoquin]
Ipfluphenokine: 2- {2-[(7,8-difluoro-2-methylquinoline-3-yl) oxy] -6-fluorophenyl} propane-2-ol is a known compound (CAS. 1314008-27-9). The ipfluphenokin is represented by the formula (a) and can be produced by a known method, for example, the method described in WO2011 / 081174A1, or can be obtained from a commercially available product.

The ipfluphenokin used in the present invention can also be used in a salt state, and is a concept including this. In this case, the salt is not particularly limited as long as it is acceptable in terms of agriculture and horticulture. For example, salts of inorganic acids such as hydrochlorides, nitrates, sulfates and phosphates; salts of organic acids such as acetates, lactates, propionates and benzoates can be mentioned.

[Component B]
Specifically, the components selected from the following groups can be exemplified.
It is preferably at least one selected from the following.
(B1) Extract from the cotyledons of lupine plantlets; Extract from Swinglea glutinosa; Gosei Kayupte (tea tree) Extract from Melaleuca alternifolia (tea tree oil); plant oils (mixtures): eugenol, geraniol, thymol.
Alpha-pinene, Alpha-terpinene, Alpha-terpineol, Alpha-terpineol, which are also tea tree oil extracts. -terpinoline), γ-terpinene (Gamma-terpinene).
(B2) Biopesticide with multiple mechanisms of action (microbial pesticide)
Trichoderma atroviride strain I-1237, Trichoderma atroviride strain LU132, Trichoderma atroviride strain SC1 and Trichoderma atroviride strain SC1 strain SKT-1), Trichoderma atroviride strain 77B;
Trichoderma asperellum strain T34, Trichoderma asperellum strain kd;
Trichoderma harzianum strain T-22;
Trichoderma virens strain G-41;
Trichoderma, such as.
Gliocladium, such as Gliocladium catenulatum strain J1446;
Clonostachys rosea strain CR-7; such as Clonostachys rosea strain CR-7;
Coniothyrium strains such as Coniothyrium minitans strain CON / M / 91-08; Coniothyrium.
Talaromyces flavus strain SAY-Y-94-01; etc., Talaromyces spp.
Saccharomyces, such as Saccharomyces cerevisae strain LAS02;
Bacillus amyloliquefaciens strain QST713 (Bacillus amyloliquefaciens strain QST713), Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain MBI600 Bacillus amyloliquefaciens strain D747, Bacillus amyloliquefaciens strain F727, Bacillus amyloliquefaciens strain AT-332;
Bacillus subtilis strain AFS032321 (Bacillus subtilis strain AFS032321), Bacillus subtilis strain Y1336 (Bacillus subtilis strain Y1336), Bacillus subtilis strain HAI-0404 (Bacillus subtilis strain HAI-0404); Bacillus.
Paenibacillus.
Burkholderia.
Fusarium.
Pseudomonas fluoraphis strain AFS009; Pseudomonas fluorescens, Pseudomonas rhodesiae; Pseudomonas spp.
Streptomyces griseovirides strain K61;
Streptomyces, such as Streptomyces lydicus strain WYEC108;
Agrobacterium, such as Agrobacterium radiobacter;
Non-pathogenic Erwinia carotovora (Erwinia carotovora subsp. Carotovora); Erwinia spp.
Variovorax, such as Variovorax paradoxus;
Lactobacillus, such as Lactobacillus plantarum;
(B3) Phosphorous acid or a salt thereof.
(B4) Mineral oils, organic oils, material of biological origin, inorganic salts: Potassium bicarbonate, Sodium hydrogen carbonate , Calcium carbonate, Calcium hydroxide, Potassium iodide, Potassium phosphonates, etc .; Chitosan hydrochloride, d-Limonene, Orange Oil, Urea.
(B5) Elicitor.

A salt of phosphorous acid means a salt of phosphorous acid itself. At least selected from the group consisting of potassium phosphite (Potassium phosphite), ammonium phosphite (Ammonium phosphite), calcium phosphite (Calcium phosphite), aluminum phosphite (Aluminum phosphite) and sodium phosphite (Disodium phosphonate). It is preferably one.

Elicitor refers to a substance that induces an immune response of a plant, that is, a substance that induces a defensive response.
Examples of elicitors include yeast or its extract, β-glucan, chitin or chitosan or fragments thereof, β-aminobutyric acid, 2,6-dichloroisonicotinic acid, salicylic acid or its derivative, algae extract, algae extract (hydrogenated). Degradants), jasmine flower extract, sodium alginate, oligosaccharides, laminarin (β-1,3-glucooligosaccharides), trehalose, polysaccharides, lipids (sphingolipids, etc.), lipopolysaccharides, fatty acids, glycolipids, glycoproteins (elicitin, etc.) ), Glycopeptides, proteins derived from plants and / or pathogenic microorganisms or peptides thereof (eg, xylanase, harpin, INF1, flaggerin, translation elongation factor, etc.), preferably at least one selected from the group consisting of ergosterol. ..

The agricultural and horticultural bactericide composition of the present invention may have a compounding ratio that produces a synergistic effect, and the weight ratio of ipflufenokin to component B (ipfluphenokin: component B) is usually 1: 1. , Million to 1,000,000: 1, preferably 1: 100,000 to 100,000: 1, more preferably 1: 10000 to 10,000: 1, and even more preferably 1: 1. It is 000 to 1,000: 1, even more preferably 100: 1 to 1: 100, and particularly preferably 1:10 to 10: 1. In particular, it is preferable to apply at a mass ratio that exhibits a synergistic effect. The synergistic effect can be confirmed by the Colby formula described later.

Ingredient B is microbial pesticide, tea tree extract, α-pinene, α-terpinene, α-terpinene, α-terpinene, γ-terpinene, potassium hydrogencarbonate, sodium hydrogencarbonate, calcium carbonate, calcium hydroxide, iodide. A group consisting of potassium, potassium phosphonate, chitosan hydrochloride, phosphite, potassium phosphite, calcium phosphite, aluminum phosphite, sodium phosphite, ammonium phosphite, d-limonene, orange oil, urea, and elicitor. It is preferable that it is at least one selected from.

When component B is a microbial pesticide, d-limonene, orange oil, elicitor, the mass ratio of ipflufenokin to component B used in the method and composition of the present invention (ipflufenokin: component B) is particularly high. Although not limited, it is preferably 1000: 1 to 1: 1000, more preferably 500: 1 to 1: 500, still more preferably 250: 1 to 1: 250, and particularly preferably 200: 1 to 1: 200.

Table 1 shows an example of a specific combination of ipfluphenokin and component B and an example of the mass ratio.

Ingredient B is tea tree extract, α-pinene, α-terpinene, α-terpineol, α-terpinolene, γ-terpinene, inorganic salts, potassium hydrogencarbonate, sodium hydrogencarbonate, calcium carbonate, calcium hydroxide, iodide. In the case of potassium, potassium phosphonate, chitosan hydrochloride, phosphorous acid, potassium phosphite, calcium phosphite, aluminum phosphite, sodium phosphite, ammonium phosphite, urea, used in the method and composition of the present invention. The mass ratio of ipflufenokin to the component B (ipfluphenokin: component B) is not particularly limited, but is preferably 1: 1 to 1: 1000, more preferably 1: 2 to 1: 500, and even more preferably. Is 1: 5 to 1: 250, particularly preferably 1:10 to 1: 200.

Table 2 shows an example of a specific combination of ipfluphenokin and component B and an example of the mass ratio.

The agricultural and horticultural bactericide composition of the present invention contains fertilizers, solid carriers, thickeners, surfactants, spreading agents, additives, solvents and the like to the extent that the effects of the present invention are not affected. May be.

Fertilizers include compost, oil cake, fish flour, cow manure, chicken manure, etc. or organic materials obtained by processing these; nitrogen fertilizers such as ammonium sulfate, ammonium nitrate, lime nitrate, urea; Phosphoric acid fertilizer such as phosphorus fertilizer; Potassium fertilizer such as potassium chloride, potassium sulfate, potassium nitrate; ; Examples include chemical fertilizers containing various inorganic fertilizers.

Examples of the solid carrier include vegetable powders such as soybean grains and wheat flour; and mineral fine powders such as silicon dioxide, diatomaceous earth, phosphoric stone, gypsum, talc, bentonite, pyrophyllite, clay, and soil.

Additives include organic or inorganic compounds such as sodium benzoate, urea, and sardine; rapeseed oil, soybean oil, sunflower oil, sunflower oil, pine oil, cottonseed oil, derivatives of these oils, and their derivatives. Examples include oil concentrates.
Examples of the solvent include petroleum distillates such as kerosine and xylene; solvent naphtha; cyclohexane, cyclohexanone, dimethylformamide, dimethyl sulfoxide, alcohol, acetone, methyl isobutyl ketone, mineral oil, vegetable oil, water and the like.

Examples of the surfactant include an alkylphenyl ether added with polyoxyethylene, an alkyl ether added with polyoxyethylene, a higher fatty acid ester added with polyoxyethylene, a sorbitan higher fatty acid ester added with polyoxyethylene, and polyoxy. Nonionic surfactants such as tristyrylphenyl ether added with ethylene, sulfate ester salts of alkylphenyl ethers added with polyoxyethylene, alkylbenzene sulfonates, sulfate esters of higher alcohols, alkylnaphthalene sulfonates, poly Examples thereof include carboxylates, lignin sulfonates, formaldehyde condensates of alkylnaphthalene sulfonates, isobutylene-maleic anhydride copolymers and the like.

The agricultural and horticultural fungicide composition of the present invention includes other fungicides, insecticides, acaricides, nematodes, soil pesticides, anthelmintics, etc., as long as the effects of the present invention are not reduced. It can contain an anthelmintic or the like.
Representative examples of other fungicides, insecticides, acaricides, nematodes, soil pesticides, anthelmintics, and plant growth regulators are shown below.

Fungicide:
(A) Agents that act on nucleic acid synthesis and metabolism A1) RNA polymerase I inhibitor Benalaxyl, benalaxyl-M, furalaxyl, metalaxyl, metalaxyl-M; oxadixyl (metalaxyl-M) oxadixyl); ofurace.
A2) Adenosine deaminase inhibitor bupirimate, dimethirimol, ethirimol.
A3) DNA / RNA biosynthesis inhibitor hymexazole, octhilinone.
A4) DNA topoisomerase type II inhibitor oxolinic acid.

(B) Cell skeleton and motor proteins B1) to B3) β-tubulin polymerization inhibition Benomyl, carbendazim, fuberidazole, thiabendazole, thiophanate, thiophanate-methyl ), Diethofencarb, zoxamide, ethaboxam.
Chlorfenazole, debacarb, trichlamide, zarilamid.
B4) Cell division (point of action unknown)
Pencientcuron.
B5) Delocalization of spectrin-like protein Fluopicolide, fluopimomide.
B6) Actin / myosin / fimbrin function Phenamacril, metrafenone, pyriofenone.

(C) Respiration C1) Complex I: NADH oxidoreductase diflumetorim, tolfenpyrad, fenazaquin.
C2) Complex II: Succinate dehydrogenase benodanil, flutolanil, mepronil; isofetamid; fluopyram; cyclobutrifluram; fenfuram; carboxy Carboxin, oxycarboxin; thifluzamide; benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, furametpyr, impil Inpyrfluxam, isopyrazam, penflufen, penthiopyrad, sedaxane; isoflucypram; pydiflumetofen; boscalid; pyraziflumid; Flubeneteram. Furmecyclox.
C3) Complex III: Cytochrome bc1 (ubiquinol oxidase) Qo site (cyt b gene)
Azoxystrobin, coumoxystrobin, enoxastrobin, flufenoxystrobin, picoxystrobin, pyraoxystrobin; mandestrobin (Mandestrobin); pyraclostrobin, pyrametostrobin, trilopyricarb; kresoxim-methyl, trifloxystrobin; dimoxystrobin, phenaminest Robin (fenaminstrobin), metminostrobin (metominostrobin), orysastrobin (orysastrobin); famoxadone; fluoxastrobin (fluoxastrobin); fenamidone (pyribencarb); methyltetraprole (metyltetraprole).
C4) Complex III: Ubiquinone reductase Qi site cyazofamid; amisulbrom; fenpicoxamid; florylpicoxamid; metarylpicoxamid.
C5) Oxidative phosphorylation uncoupled binapacryl, dinocap, meptyldinocap; fluazinam.
C6) Oxidative phosphorylation, inhibition of ATP synthase Triphenyltin acetate (fentin acetate), triphenyltin chloride (fentin chloride), triphenyltin hydroxide (fentin hydroxide).
C7) ATP transport silthiofam.
C8) Complex III: Ubiquinone reductase (Qo site, stigmaterin binding subsite)
Ametoctradin (ametoctradin).

(D) Amino acid and protein synthesis D1) Methionine biosynthesis (cgs gene)
Cyprodinil, mepanipyrim, pyrimethanil.
D2) Protein synthesis (end stage of ribosome translation)
Blasticidin S (blasticidin-S)
D3), D4) Protein synthesis (ribosome translation initiation stage)
Kasugamycin, kasugamycin hydrochloride, streptomycin.
D5) Protein synthesis (ribosome polypeptide elongation stage)
Oxytetracycline.

(E) Signal transduction E1) Signal transduction (mechanism of action unknown)
Kinoxyfen, proquinazid.
E2) MAP / histidine kinase (os-2, HOG1) in osmotic signaling
Fenpiclonil, fludioxonil.
E3) MAP / histidine kinase (os-1, Daf1) in osmotic signaling
Chlozolinate, dimethachlone, iprodione, procymidone, vinclozolin.

(F) Lipid biosynthesis or transport / structure or function of cell membrane F2) Phospholipid biosynthesis, methyltransferase edifenphos, iprobenfos, pyrazophos; isoprothiolane.
F3) Cell peroxides biphenyl, chloroneb, dichloran, quintozene, tecnazene, tolclofos-methyl; etridiazole.
F4) Cell membrane permeability, fatty acid iodocarb, propamocarb, propamocarb hydrochloride, prothiocarb.
F8) Ergosterol-bound natamycin.
F9) Lipid homeostasis and transport / storage Oxathiapiprolin, fluoxapiprolin.

(G) Cell membrane sterol biosynthesis (inhibitor)
G1) Demethylase at position C14 in sterol biosynthesis (erg11 / cyp51)
Triforine; pyrifenox, pyrisoxazole; fenarimol, nuarimol; imazalil, oxpoconazole, pefurazoate, prochloraz, prochloraz Triflumizole; azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, etaconazole, epoxiconazole. etaconazole), fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, mephen Trifluconazole (mefentrifluconazole), metconazole (metconazole), microbutanil (myclobutanil), penconazole (penconazole), propiconazole (propiconazole), simeconazole (simeconazole), tebuconazole (tebuconazole), tetraconazole (tetraconazole), triazimephone (tetraconazole) Triadimenol, triticonazole, prothioconazole, Fluoxytioconazole.
Fluconazole (furconazole), fluconazole-cis (furconazole-cis), diniconazole M (diniconazole-M).
G2) Δ14 reductase and Δ8 → Δ7-isomerase in sterol biosynthesis (erg24, erg2)
Aldimorph, dodemorph, dodemorph acetate, fenpropimorph, tridemorph; fenpropidin, piperalin; spiroxamine.
Buthiobate.
G3) 3-keto reductase (erg27) in C4 demethylation of sterol biosynthesis system
Fenhexamid; fenpyrazamine.
G4) Sterol biosynthetic squalene epoxydase (erg1)
Pyributicarb; naftifine, terbinafine.

(H) Cell wall biosynthesis (inhibitor)
H4) Chitin synthase polyoxin.
Polyoxorim.
H5) Cellulose synthase dimethomorph, flumorph, pyrimorph; benthiavalicarb, iprovalicarb, valifenalate; mandipropamid, benthiavacarb Isopropyl).

(I) Melanin synthesis of cell wall I1) Reductase of melanin biosynthesis fthalide; pyroquilon; tricyclazole.
I2) Melanin biosynthetic dehydratase carpropamid; diclocymet; fenoxanil.
I3) Polyquetide synthase for melanin biosynthesis tolprocarb.

(P) Host plant resistance induction P1-P3) Salicylic acid signaling Acibenzolar-S-methyl; probenazole; tiadinil, isotianil.
P4) Polysaccharide elicitor laminarin.
P5) Anthraquinone elicitor Reynoutria sachalinensis extract from Reynoutria sachalinensis.
P6) Microbial elicitor Bacillus mycoides isolate J; cell walls of Saccharomyces cerevisiae strain LAS117.
P7) Phosphorous acid and salts: Phosphorous acid and salts: Potassium phosphite, Calcium phosphite, Aluminum phosphite, Phosphorous acid Sodium (Disodium phosphonate).
P8) Salicylic acid-related dichlobentiazox
(U) Mechanism of action unknown cymoxanil; tecloftalam; triazoxide; flusulfamide; diclomezine; cyflufenamid; dodine, dodine free base; Flutianil; ferimzone; tebufloquin; picarbutrazox; validamycin.
Bethoxazin, cyprofuram, flumetover, nitrothal-isopropyl, propamidine.
Ipflufenoquin, pyridachlometyl, pyrapropoyne, aminopyrifen, ipfentrifluconazole, quinofumelin, dipymetitrone; cloinconazide; ); Seboctylamine; Flumetylsulforim; Flufenoxadiazam.
(M) Multi-point contact active copper (different salts), basic copper sulfate, Bordeaux mixture, copper hydroxide, copper naphthalate (copper) naphthenate), copper oxychloride, copper sulfate, cuprous oxide, oxine-copper; sulfur, Lime sulfur; ambam ), Ferbam, mancozeb, maneb, metiram, propineb, thiram, zinc thiazole, zineb, ziram; captan (Captan), captafol, folpet; chlorothalonil; dichlofluanid, tolylfluanid; guazatine, guazatine acetates, iminoctadine , Iminoctadine triacetate, iminoctadine trialbesilate; anilazine; dithianon; chinomethionat; fluoroimide; methasulfocarb.
Dazomet, cufraneb, mancopper, polycarbamate.
(BM01) Biopesticide with multiple action mechanisms / Pesticide derived from organisms Extract from the cotyledons of lupine plantlets; Extract from Swinglea glutinosa; Gosei Kayupte (extract from Swinglea glutinosa) Extract from Melaleuca alternifolia (tea tree oil); plant oils (mixtures): eugenol, geraniol, thymol.
(BM02) Biological pesticide / biological pesticide having multiple action mechanisms Trichoderma atroviride strain I-1237, Trichoderma atroviride strain LU132, Trichoderma atroviride strain LU132, Trichoderma atroviride strain LU132 (Trichoderma atroviride strain LU132) Trichoderma atroviride strain SC1), Trichoderma atroviride strain SKT-1; Trichoderma atroviride strain 77B;
Trichoderma asperellum strain T34, Trichoderma asperellum strain kd;
Trichoderma harzianum strain T-22;
Trichoderma, such as Trichoderma virens strain G-41;
Gliocladium, such as Gliocladium catenulatum strain J1446;
Clonostachys rosea strain CR-7; such as Clonostachys rosea strain CR-7;
Coniothyrium strains such as Coniothyrium minitans strain CON / M / 91-08; Coniothyrium.
Talaromyces flavus strain SAY-Y-94-01; etc., Talaromyces spp.
Saccharomyces, such as Saccharomyces cerevisae strain LAS02;
Bacillus amyloliquefaciens strain QST713 (Bacillus amyloliquefaciens strain QST713), Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain MBI600 Bacillus amyloliquefaciens strain D747, Bacillus amyloliquefaciens strain F727, Bacillus amyloliquefaciens strain AT-332;
Bacillus subtilis strain AFS032321 (Bacillus subtilis strain AFS032321), Bacillus subtilis strain Y1336 (Bacillus subtilis strain Y1336), Bacillus subtilis strain HAI-0404 (Bacillus subtilis strain HAI-0404); Bacillus.
Pseudomonas chlororaphis strain AFS009; Pseudomonas fluorescens, pseudomonas rhodesiae; Pseudomonas strain Kseudomonas Streptomyces strain K61); Streptomyces lydicus strain WYEC108; etc., Streptomyces.
Agrobacterium, such as Agrobacterium radiobacter;
Non-pathogenic Erwinia carotovora (erwinia carotovora subsp. Carotovora); Erwinia spp.
Variovorax paradoxus; etc., Variovorax spp.
Lactobacillus plantarum; such as Lactobacillus spp.
(NC) Uncategorized mineral oils, organic oils, inorganic salts, material of biological origin, potassium hydrogen carbonate, sodium hydrogen carbonate.

Insecticides, acaricides, etc .:
(1) Acetylcholinesterase inhibitor:
(a) Carbamate: Aranicarb, Aldicarb, Bengiocarb, Benfracarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Ethiophencarb, Fenocarb, Holmethanate, Frathiocarb, Isoprocarb, Methiocarb, Methomyl, Oxamil, Pyrimicarb, Propoxul Thiodicarb, thiofanox, triazamate, trimetacarb, XMC, xylylcarb, phenothiocarb, MIPC, MPMC, MTMC, aldicarb, alixcarb, aminocarb, butofancarb, chloretcarb, metam sodium, promecarb;

(b) Organophosphorus: acephate, azamethiphos, azinephos-ethyl, azinephos-methyl, kazusaphos, chlorethoxyphos, chlorfenbinphos, chlormephos, chlorpyriphos, chlorpyriphos-methyl, bearphos, cyanophos, demethon-S-methyl, diazinone, Dichlorvos / DDVP, Diclotophos, Dimethate, Dimethylbinphos, Disulfoton, EPN, Ethion, Etoprophos, Famfur, Fenamiphos, Fenitrothione, Fention, Hostiazeto, Heptenophos, Imiciaphos, Isophenphos, Isocarbhos, Isoxathion, Malathion, Methamidophos, Methamidophos Monochrometophos, Naredo, Ometoate, Oxydimethone-Methyl, Parathion, Parathion-Methyl, Fentate, Holate, Hosalon, Hosmet, Phosphamiden, Hoxim, Pyrimiphos-Methyl, Prophenofus, Propetumphos, Prothiophos, Pyraclophos, Pyridafenthion, Kinalphos, Sulfonep, Temefos Temefos, Telbuphos, Tetrachlorbinphos, Thiometon, Triazophos, Trichlorfon, Bamidethione, Bromophos-ethyl, BRP, Carbophenothione, Cyanophenphos, CYAP, Demeton-S-Methylsulfone, Diariphos, Diclofenthion, Dioxabenzophos, Ethriphos , Fensulfothion, flupyrazophos, honophos, formotion, phosmethylan, isazophos, iodophenphos, methamiphos, pyrimiphos-ethyl, phosphocarb, propaphos, protoate, sulprophos.

(2) GABA-Operating Chloride Channel Antagonists: acetoprol, chlordane, endosulfan, ethiprol, fipronil, pilafulfrol, pyriprol, campechlor, heptachlor, dienochlor.
(3) Sodium channel modulators: acrinathrin, d-cis-trans-allethrin, d-trans-allethrin, bifentrin, bio-allethrin, bio-allethrin s-cyclopentyl isomer, bioresmethrin, cycloprothrin, cypermethrin, beta-cypermethrin, cypermethrin, lambda- Cypermethrin, gamma-cypermethrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cypermethrin [(1R) -trans isomer], deltamethrin, empentrin [(EZ)-( 1R)-isomer], esphenvalerate, etofenprox, phenpropathrin, fenvalerate, flucitrinate, flumethrin, tau-fluvalinate, halphenprox, imiprothrin, cadestrin, permethrin, phenothrin [(1R) -trans Heterogeneous], prarethrin, pyresram, lesmethrin, cypermethrin, tefluthrin, tetramethrin [(1R) -isomer], allethrin, transfluthrin, allethrin, pyrethrin, pyrethrin I, pyrethrin II, profluthrin, dimefluthrin, bioetanomethrin Permethrin, transpermethrin, fenfluthrin, fenpyritrin, flubrocitrinate, flufenprox, methfurthrin, protrifenbut, allethrin, terarethrin.

(4) Nicotinic acetylcholine receptor agonists: acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, nithiadin, thiacloprid, thiamethoxam, sulfoxaflor, nicotine, flupyraziflon, flupyrimin, triflumesopirim.
(5) Nicotinic acetylcholine receptor allosteric modulator: spinetram, spinosad.
(6) Chloride channel activator: abamectin, emamectin benzoate, repimectin, milbemectin, ivermectin, selamectin, doramectin, eprinomectin, moxidectin, milbemycin, milbemycin oxime, nemadetin.
(7) Juvenile hormone-like substances: hydroprene, quinoprene, methoprene, phenoxycarb, pyriproxyfen, diophenolan, epophenonan, triprene.
(8) Other non-specific inhibitors: Methyl bromide, chloropicrin, sulfuryl fluoride, borax, antimony stone.
(9) Hemiptera Selective Eating Inhibitors: Flonicamid, Pymetrodin, Pyrifluquinazone.

(10) Tick growth inhibitor: clofentezine, difluorovidazine, hexitiazox, etoxazole.
(11) Microbial-derived insect mid-intestinal intestinal destructive agent: Bacillus thuringiensis subspecies Isla Elenshi, Bacillus thuringiensis subspecies Aisawai, Bacillus thuringiensis subspecies Kurstaki, Bacillus thuringiensis subspecies Tenebrionis, Bt Crop protein: Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb, Cry34Ab1 / Cry35Ab1.
(12) Mitochondrial ATP biosynthetic enzyme inhibitor: diafentiurone, azocyclotin, cyhexatin, fenbutatin oxide, propargite, tetradiphon.
(13) Oxidative phosphorylation uncoupler: chlorfenapyr, sulfurulamide, DNOC, binapacryl, dinobutone, dinocup.
(14) Nicotinic Acetylcholine Receptor Channel Blocker: Bensultap, Cartap Hydrochloride, Neristoxin, Thiosultap-Sodium Salt, Nereistoxin.
(15) Chitin synthesis inhibitors: bistrifluron, chlorflubenzuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumron, lufenuron, novallon, nobiflumron, teflubenzuron, triflumron, buprofezin, fluazuron.
(16) Diptera molting disturber: Cyromazine.
(17) Moulting hormone receptor agonists: chromaphenozide, halophenozide, methoxyphenozide, tebufenozide.
(18) Octopamine receptor agonists: amitraz, demiditras, chlordimeholm.
(19) Mitochondrial electron transport chain complex III inhibitor: acequinosyl, fluaclipirim, hydramethylnon.
(20) Mitochondrial electron transport chain complex I inhibitor: phenazakin, phenpyroximate, pyrimidiphen, pyridaben, tebufenpyrado, tolfenpyrado, rotenone.

(21) Voltage-gated sodium channel blocker: Indoxacarb, Metaflumison.
(22) Acetyl-CoA carboxylase inhibitors: spirodiclofen, spiromesiphen, spirotetramato.
(23) Mitochondrial electron transport chain complex IV inhibitor: aluminum phosphide, calcium phosphide, phosphine, zinc phosphide, cyanide.
(24) Mitochondrial electron transport chain complex II inhibitor: sienopyraphen, siflumethofen, piflubumid.
(25) Ryanodine receptor modulator: chloranthraniliprole, cyantraniliprole, flubendiamide, cyclaniliprole, tetraniliprole.
(26) Mixing function Oxidase inhibitor compound: piperonyl butoxide.
(27) Latrophilin receptor agonists: depsipeptide, cyclic depsipeptide, 24-membered cyclic depsipeptide, modepside.
(28) Other agents (mechanism of action unknown): azadilactin, benzoximate, biphenazate, bromopropylate, quinomethionate, cryolite, dicoform, pyridalyl, bencrothias, sulfur, amide flumet, 1,3-dichloropropene, DCIP, Phenisobromolate, benzomate, metaaldehyde, chlorbendilate, clothiazoben, disicranyl, phenoxacrim, fentrifanyl, flubenzimine, flufenazine, gossiplua, japonyla, methoxadiazone, petroleum, potassium oleate, tetrasul, triazolesen, afidopyropen. ), Fromotkin, flufiprole, fluene sulfone, meperfluthrin, tetramethylfluthrin, traropyryl, dimefluthrin, methylneodecanamide, flularanel, afoxolanel, fluxametamid, 5- [5- (3,5-dichlorophenyl) -5-trifluoro Methyl-4,5-dihydroisoxazole-3-yl] -2- (1H-1,2,4-triazole-1-yl) benzonitrile (CAS: 943137-49-3), brofuranilide, and other metadiamidides , Steiner Nema Capocapsae, Steiner Nema Gracerai, Pasturia Penetrans, Pekiromyces Tenuipes, Pekiromyces Fumosoroseus, Beauveria Bassiana, Beauveria Bronniati, Metallidium Anisoprier, Verticillium Lecani, Asinonapil, Benzpirimoxane.

(29) Anthelmintic:
(a) benzimidazole system: fenbendazole, albendazole, triclabendazole, oxybendazole, mebendazole, oxfendazole, perbendazole, flubendazole, fevantel, netobimin, thiophanate, thiabendazole, cambendazole;
(b) Salicylanilide system: closantel, oxyclozanide, lafoxanide, niclosamide;
(c) Substituted phenolic system: nitroxynyl, nitroscanate;
(d) Pyrimidines: Pyrantel, Morantel;
(e) Imidazothiazole system: levamisole, tetramisole;
(f) Tetrahydropyrimidines: Praziquantel, Epsiprantel;
(g) Other anthelmintics: cyclodiene, liania, chlorthrone, metronidazole, demiditraz, piperazine, diethylcarbamazine, dichlorophen, monepantel, tribendimidine, amidantel, thiacetalsamide, melarsomine, arsenamide.

Plant growth regulator:
Absidic acid, kinetin, benzylaminopurine, 1,3-diphenylurea, forchlorphenuron, tidiazulone, chlorphenuron, dihydrozeatin, gibberellin A, gibberellin A4, gibberellin A7, gibberellin A3, 1-methylcyclopropane, N -Acetylaminoethoxyvinylglycine (also known as abiglycin), aminooxyacetic acid, silver nitrate, cobalt chloride, IAA, 4-CPA, cloxyp, 2,4-D, MCPB, indol-3-butyric acid, gibberellin, phenothiol , 1-naphthylacetamide, ethicrozeto, cloxyfonac, hydrazide maleate, 2,3,5-triiodobenzoic acid, salicylic acid, methyl salicylate, (-)-jasmonic acid, methyl jasmonate, (+)-strigol, ( +)-Deoxystrigor, (+)-Orobancol, (+)-Solgolactone, 4-oxo-4- (2-phenylethyl) aminobutyric acid, ethephon, cloxyfonac, mepicort chloride, benzyladenin, 5-aminoleverellin Acid, daminozid.

The agricultural and horticultural fungicide composition of the present invention is not particularly limited by the production method thereof. As a method for producing the agricultural and horticultural bactericidal composition of the present invention, for example, (a) a method comprising separately formulating ipfluphenokin and component B and mixing these formulations, (b). () A method comprising formulating an ipfluphenokine and mixing the component B with the formulation, (c) a method comprising formulating the component B and mixing the ipfluphenokin with the formulation, (d) ip. There is a method including mixing fluphenokine and component B and formulating the mixture as needed.

The formulation can be in the form of a normal horticultural drug. Examples of the dosage form include powder (DP, Dustable Powder), wettable powder (WP, Wattable Powder), emulsion (EC, Emulsifiable Concentrate), flowable agent (FL, flowable), suspension agent (SC, Suspension Concentrate). , Water solvent (SP, Water Soluble Powder), Granule wettable powder (WG, Water Dispersible Granule), Tablet (Tablet), Granule (GR, Granule), SE agent (Suspo Emulsion), OD agent (Oil Dispersion), EW agent (Emulsion oil in water) and the like can be mentioned.

The concentration of the active ingredient (total concentration of ipfluphenokine and component B) in the formulated composition of the fungicide for agriculture and horticulture of the present invention is not particularly limited, and various concentrations can be taken depending on the form of the above-mentioned formulation. For example, in wettable powders, usually 5 to 90% by weight, preferably 10 to 85% by weight; in emulsions, usually 3 to 70% by weight, preferably 5 to 60% by weight; in granules. It can be usually 0.01 to 50% by weight, preferably 0.05 to 40% by weight.

The following are some examples of the pharmaceutical product. It should be noted that the pharmaceutical formulation shown below is merely an example and can be modified to the extent that it does not contradict the gist of the present invention, and the present invention is not limited by the following pharmaceutical examples. "Part" means "part by weight" unless otherwise specified.

(Formation 1: Wettable powder)
Ipfluphenokin + component B 40 parts diatomaceous earth 53 parts higher alcohol sulfate ester 4 parts alkylnaphthalene sulfonate 3 parts or more are uniformly mixed and finely pulverized to obtain a wettable powder having 40% of the active ingredient.

(Formation 2: Emulsion)
Ipfluphenokine + component B 30 parts xylene 33 parts dimethylformamide 30 parts polyoxyethylene alkyl allyl ether 7 parts or more are mixed and dissolved to obtain an emulsion containing 30% of the active ingredient.

(Formation 3: Powder)
Ipfluphenokin + 10 parts of ingredient B 10 parts of clay 90 parts or more of clay are uniformly mixed and finely pulverized to obtain a powder containing 10% of the active ingredient.

(Formation 4: Granules)
Ipfluphenokin + Ingredient B 5 parts Clay 73 parts Bentnite 20 parts Dioctylsulfosuccinate sodium salt 1 part Potassium phosphate 1 part After crushing and mixing well, add water and knead well, then granulate and dry. Obtain granules with 5% active ingredient.

(Formula 5: Suspension)
Ipfluphenokin + ingredient B 10 parts polyoxyethylene alkyl allyl ether 4 parts polycarboxylic acid sodium salt 2 parts glycerin 10 parts xanthan gum 0.2 parts water 73.8 parts or more are mixed until the particle size becomes 3 microns or less. Wet grind to obtain a suspension of 10% active ingredient.

(Formation 6: Granule wettable powder)
Ipfluphenokin + component B 40 parts clay 36 parts potassium chloride 10 parts alkylbenzene sulfonic acid sodium salt 1 part lignin sulfonic acid sodium salt 8 parts alkylbenzene sulfonic acid sodium salt formaldehyde condensate 5 parts or more are mixed uniformly and finely After crushing, add an appropriate amount of water and knead to make it clay-like. The clay-like material is granulated and then dried to obtain a granule wettable powder having 40% of the active ingredient.

The agricultural and horticultural fungicide composition of the present invention may bring about effects such as labor saving when used in combination with known insecticides, acaricides, herbicides, plant growth regulators and the like.

The agricultural and horticultural bactericide composition of the present invention can be sprayed on plants or irrigated with soil as it is, diluted with water to a predetermined concentration, or in the form of a lysate, suspension or emulsion. It can be used by mixing or spraying. The agricultural and horticultural fungicide composition of the present invention is usually applied to a field in an appropriate amount of 0.1 g or more of the active ingredient (total amount of ipfluphenokine and component B) per hectare.
The agricultural and horticultural fungicide composition of the present invention can also be used as a seed treatment agent. It can also be used by applying it to the surface of the water.

Examples of useful plants to be treated with the agricultural and horticultural fungicide composition of the present invention include cereals, vegetables, root vegetables, potatoes, fruit trees, trees, grasses, turf and the like. can. Here, each part of these plants can be treated as a target. Examples of each part of the plant include leaves, stems, stalks, flowers, buds, fruits, seeds, sprouts, roots, tubers, tubers, shoots, cuttings and the like. In addition, improved varieties / varieties of these plants, cultivars, mutants, hybrids, and genetically modified organisms (GMOs) can be treated as targets.
The following are specific examples of useful plants.
(1) Malvaceae plants, such as okra (Abelmoschus esculentus) and cotton (Gossypium hirsutum);
(2) Sterculiaceae plants, such as Theobroma cacao;
(3) Chenopodiaceae plants, such as sugar beet (Beta vulgaris), Swiss chard (Swiss chard) (Beta vulgaris var. Cicla L.), spinach (Spinacia oleracea);
(4) Rubiaceae plants, such as coffee (Coffea spp);
(5) Cannabaceae plants, such as hops (Humulus lupulus)
(6) Cruciferae plants, such as Brassica cempestris, Brassica juncea, Brassica juncea var. Integrifolia, Brassica napus, Brassica oleracea var. Botrytis. , Cabbage (Brassica oleracea var. Capitata), Broccary (Brassica oleracea var. Italica), Hakusai (Brassica rapa), Chingensai (Brassica rapa var. Chinensis), Cub (Brassica rapa var. Glabra), Nozawana (Brassica rapa) ), Mizuna (Brassica rapa var. Lancinifolia), Nazuna (Capsella bursa-pastoris), Cresson (Nasturtium spp.), Daikon (Raphanus sativus), Wasabi (Wasabia japonica);
(7) Flaxaceae (Linaceae) plants, such as flax (Linaceae usitatissimum);
(8) Gramineae plants, such as Avena sativa, Coix lacryma-jobi var. Ma-yuen, Dactylis glomerata, Hordeum vulgare, Oryza sativa. , Timothy (TPhleum pratense), Saccharum officinarum, Limegi (Secale cereale), Awa (Setaria italica), Pancomgi (Triticum aestivum), Corn (Zea meys), Shiva (Zoysia spp.);
(9) Cucurbitaceae plants, such as togan (Benincasa hispida), watermelon (Citrulus lanatus), western squash (Cucurbita maxima), oriental pumpkin (Cucurbita moschata), pepo pumpkin (Zucchini) (Cucurbita pepo), leopard. Lagenaria siceraria), Hechima (Luffa cylindrica);
(10) Plants of the family Rhus (Anacardiaceae), such as cashew nut tree (Anacardium), mango (Mangifera);
(11) Ebenaceae plants, such as Diospyros kaki;
(12) Betulaceae plants, such as the hazel (Corylus avellana);
(13) Asteraceae (Compositae) plants, such as yomogi (Artemisia indica var. Maximowiczii), burdock (Arctium lappa L.), chicory (Cichorium intybus), artichoke (Cynara scolymus), garland chrysanthemum (Glebionis coronaria), garland chrysanthemum (Glebionis coronaria). Helianthus annuus), lettuce (Lactuca sativa);
(14) Asparagus family (Asparagaceae) plants, such as Asparagus officinalis L.;
(15) Moraceae plants, such as figs (Ficus carica L.);
(16) Walnut family (Juglandaceae) plants, such as walnuts (Juglans spp.);
(17) Pedaliaceae plants, such as Sesamum indicum;
(18) Piperaceae plants, such as Piper nigrum;
(19) Araceae plants, such as konjac (Amorphophallus rivieri var.konjac), taro (Colocasia esculenta);
(20) Labiatae (Lamiaceae) plants, such as mint (Mentha spp.), Basilico (Ocimum basilicum), perilla (Perilla frutescens var. Crispa), sage (Salvia officinalis);
(21) Plants of the family Zingiberaceae, such as turmeric (Curcuma longa), ginger (Hedychium spp.), Japanese ginger (Zingiber mioga);
(22) Umbelliferae plants, such as celery (Apium graveolens L.), carrot (Daucus carota var. Sativa), auction (Oenanthe javanica), royal fern (Osmunda japonica Thunb), parsley (Petroselium crispum);
(23) Grossulariaceae plants, such as the European Gooseberry (Ribes uva-crispa);
(24) Polygonaceae plants, such as buckwheat (Fagopyrum esculentum);
(25) Ericaceae plants, such as blueberries (Vaccinium spp);
(26) Theaceae plants, such as tea plant (Camellia sinensis);
(27) Solanaceae plants such as capsicum annuum, capsicum annuum var.'Grossum', tomato (Lycopersicon esculentum), tobacco (Nicotiana tabacum), eggplant (Solanum melongena), potato ( Solanum tuberosum);
(28) Bromeliaceae plants, such as Bromeliace (Ananas comosus);
(29) Plants of the Musaceae family, such as bananas (Musa spp.);
(30) Nelumbo nucifera plants, such as Nelumbo nucifera.
(31) A plant of the Caricaceae family, for example, Carica papaya.
(32) Rosaceae plants such as Karin (Chaenomeles sinensis), Biwa (Eriobotrya japonica Lindl.), Strawberry (Fragaria spp.), Apple (Malus pumila), Anzu (Prunus armeniaca), Plum (Plumus armeniaca) Prunus avium, Prunus cerasus, Prunus dulcis, Prunus mume, Prunus persica, Prunus salicina, Pear (Pyrus pyrifolia var. Culta), Pyrus communis Blackberry (Rubus spp.);
(33) Convolvulaceae plants, such as sweet potatoes (Ipomoea batatas Lam.var. Edulis Makino);
(34) Vitaceae plants, such as grapes (Vitis spp.);
(35) Fagaceae plants, such as chestnuts (Castanea crenata Sieb. Et Zucc.);
(36) Actinidiaceae plants, such as kiwi (Actinidia deliciosa);
(37) Leguminosae plants such as Arachis hypogaea, soybean (Glycine max subsp. Max), Glycine max subsp. Soja, Lens culinaris, Medicago sativa, pea. Beans (Pisum sativum L.), green beans (Phaseolus vulgaris), yahazu pea (Vicia angustifolia), soybeans (Vicia faba), azuki (Vigna angularis);
(38) Rutaceae plants, such as Citrus junos, Citrus kinokuni, Citrus limon, Citrus sinensis, Citrus unshiu, Grapefruit (Citrus unshiu). Citrus X paradisi), Kinkan (Fortunella japonica), Sansho (Zanthoxylum piperitum);
(39) Oleaceae plants, such as Jasminum spp., Olea europaea;
(40) Dioscorea (Dioscoreaceae) plants, such as yam (Dioscorea japonica Thunb.), Dioscorea (Dioscorea batatas);
(41) Liliaceae plants, such as onions (Allium cepa), allium (Allium fistulosum), garlic (Allium sativum), chives (Allium schoenoprasum), garlic (Allium tuberosum), tulips (Tulipa gesneriana);

The agricultural and horticultural bactericidal composition of the present invention comprises a wide variety of filamentous fungi, such as Phycomycetes, Ascomycetes, Deuteromycetes, and Basidiomycetes. , Can be used to control plant diseases derived from fungi belonging to basidiomycetes (Zygomycetes).

Examples of plant diseases and pathogens to be controlled are shown below.
Cercospora beticola, Aphanomyces cochloides, Thanatephorus cucumeris, Thanatephorus cucumeris, Uromyces betae, Oidium sp., Spots Diseases (Ramularia beticola), seedling blight (Aphanomyces cochlioides, Pythium ultimum), etc. ), Cercospora beetle (Alternaria alternata), White silk disease (Sclerotium rolfsii) Black astringent disease (Mycosphaerella berkeleyi), etc. , Fusarium oxysporum, Sclerotinia sclerotiorum, Botrytis cinerea, Colletotrichum orbiculare, Cladosporium cucumerinum, Corynespora cassiicola, seedlings Blight (Pythium debaryanum, Rhizoctonia solani Kuhn), Homopsis sp., Pseudomonas syringae pv. Lachrymans, etc. Tomatoes: Botrytis cinerea, Cladosporium fulvum (Phytophthora infestans), Half-body wilt (Verticillium albo-atrum, Verticillium dahliae), Oidium neolycopersici, Alternaria solani, Pseudocercospora Fuligena, etc. Botrytis cinerea, Corynespora melongenae, Erysiphe cichoracearum, Mycovellosiella nattrassii, Sclerotinia sclerotiorum, half-body wilt dahliae), brown spot disease (Phomopsis vexans), etc. Botrytis cinerea (Botrytis cinerea), downy mildew (Sphaerotheca humuli), charcoal sickness (Colletotrichum acutatum, Colletotrichum fragariae), plague (Phytophthora cactorum), soft rot (Rhipus) stolonifer), chlorosis (Fusarium oxysporum), wilt (Verticillium dahliae), etc. Onion: Botrytis allii, Botrytis cinerea, Botrytis cinerea, Downy mildew (Peronospora destructor) ), White plague (Phytophthora porri), Botrytis cinerea (Ciborinia allii), etc. cepivorum), rust (Puccinia allii), Botrytis cinerea (Botrytis squamosa), etc. Disease (Pseudomonas syringae pv. Maculicola, Pseudomonas syringae pv. Alisalensis), Downy mildew (Peronospora parasitica), Botrytis cinerea (Sclerotinia sclerotiorum), Botrytis cinerea (Alternaria brass) icicola), Botrytis cinerea, etc. Green beans: Sclerotinia sclerotiorum, Botrytis cinerea, Colletotrichum lindemuthianum, Phaeosariopsis griseola, etc.

Ringo: Udonko disease (Podosphaera leucotricha), scab (Venturia inaequalis), Monilinia mali, black spot disease (Mycosphaerella pomi), rotten disease (Valsa mali), spot foliar disease (Alternaria mali), red spot disease (Gymnosporangium) yamadae), botryosphaeria berengeriana, charcoal disease (Glomerella cingulata, Colletotrichum acutatum), brown spot disease (Diplocarpon mali), soot spot disease (Zygophiala jamaicensis), soot spot disease (Gloeodes pomigena) (Helicobasidium mompa), Gray mold (Botrytis cinerea), Burn disease (Erwinia amylovora), etc. sp.), etc. Kaki: Udonko disease (Phyllactinia kakicola), Charcoal disease (Gloeosporium kaki), Horn spot foliar disease (Cercospora kaki), Circular foliage disease (Mycosphaerella nawae), etc. Momo: Monilinia fructicola, Cladosporium carpophilum, Phomopsis sp., Xanthomonas campestris pv. Pruni, Taphrina deformans, Colletotrichum gloeosporioides
Almonds: Monilinia laxa, Stigmina carpophila, Cladosporium carpophilum, Polystigma rubrum, Alternaria alternata, Colletotrichum gloeospoides, etc. Elsinoë (Monilinia fructicola), Colletotrichum acutatum, Black rot (Alternaria sp.), Lactobacillus nucleus disease (Monilinia kusanoi), Brown pit disease (Mycosphaerella cerasella), etc. Grape: Gray mold (Botrytis) cinerea, Uncinula necator, Glomerella cingulata, Colletotrichum acutatum, Plasmopara viticola, Elsinoe ampelina, Pseudocercospora vitis, Black rot (Pseudocercospora vitis) Guignardia bidwellii), white rot (Coniella castaneicola), rust (Phakopsora ampelopsidis), white cotton snow disease, etc. (Botryosphaeria berengeriana), Udonko disease (Phyllactinia mali), Body blight (Phomopsis fukushii), Brown spot disease (Stemphylium vesicarium), Colletotrichum (Glomerella cingulata), etc. Cha: Ring spot disease (Pestalotiopsis longiseta, P. theae) , Colletotrichum theae-sinensis, Exobasidium reticulatum, etc. Kankitsu: Elsinoe fawcettii, Penicillium italicum, Green mold (Penicillium digitatum), Gray mold Disease (Botrytis cinerea), Black spot disease (Diaporthe citri), Canker disease (Xanthomonas campestris pv.Citri), Powdery mildew (Oidium sp.), Epidemic (Phytophthora citrophthora), Charcoal disease (Colletotrichum fioriniae), etc.

Wheat: Udonko disease (Erysiphe graminis f.sp.tritici, Blumeriagraminis f.sp. Tritici), Fusarium head blight (Gibberella zeae), Fusarium head blight (Puccinia recondita), brown snow rot (Pythium iwayamai), red snow rot (Monographella nivalis), Pseudocercosporella herpotrichoides, Leaf blight (Septoria tritici), Fusarium (Leptosphaeria nodorum), Typhula incarnata, Myriosclerotinia borealis , Gaeumannomyces graminis, Claviceps purpurea, Tilletia caries, Ustilago nuda, Pyricularia grisea, etc. Omugi: Pyrenophora graminea, net Pyrenophora teres, cloud-shaped disease (Rhynchosporium secalis), naked black spike disease (Ustilago tritici, U.nuda), etc. Rice: blast (Pyricularia oryzae), blight (Rhizoctonia solani), bakanae (Gibberella fujikuroi) , Sesame leaf blight (Cochliobolus miyabeanus), Sapling blight (Pythium graminicola), White leaf blight (Xanthomonas oryzae), Sapling blight (Burkholderia plantarii), Brown streak disease (Acidovorax avenae) Burkholderia glumae), streak leaf blight (Cercospora oryzae), rice scab (Ustilaginoidea virens), brown rice (Alternaria alternata, Curvularia intermedia), belly black rice (Alternaria padwickii), red metamorphic rice (Epicoccum purpurascens), etc. Disease (Sclerotinia sclerotiorum), Udonko disease (Erysiphe cichoracearum), plague (Phytophthora nicotianae), etc. Tulip: Gray mold disease (Botrytis cinerea) Sunflower: Botrytis cinerea (Plasmopara halstedii), Botrytis cinerea Bentgrass: Sclerotinia borealis, Rhizoctonia solani, Rhizoctonia solani, Sclerotinia homoeocarpa, Pyricularia sp., Pythium aphanidermatum, etc. Orchardgrass: Erysiphe graminis, etc. Soy: Cercospora kikuchii, Peronospora manshurica, Phytophthora sojae, Phytophthora pachyr, etc. , Sclerotinia sclerotiorum, Collettrichum truncatum, Botrytis cinerea, Elsinoe glycines, Diaporthe phaseolorum var. Sojae, etc. Potatophthora infestans , Summer plague (Alternaria solani), Botrytis cinerea (Thanatephorus cucumeris), Half-body wilt (Verticillium albo-atrum, V. dahliae, V. nigrescens), Botrytis cinerea (Pectobacterium atrosepticum), Soft rot (Pectobacterium carotovorum), etc. : Panama disease (Fusarium oxysporum), Shigatoka disease (Mycosphaerella fijiensis, M. musicola), etc. Rapeseed: Mycosphaerella sclerotiorum , Phoma lingam, Alternaria brassicae, etc. Coffee: rust (Hemileia vastatrix), Colletotrichum coffeanum, Brown eye disease (Cercospora coffeicola), etc. Corn: Gloeocercospora sorghi, Puccinia sorghi, Puccinia polysora, Ustilago maydis, Cochliobolus heterostrophus, Setosphaeria turcica, etc. : Can be used to control seedling blight (Pythium sp), rust (Phakopsora gossypii), white mold (Mycosphaerella areola), charcoal scab (Glomerella gossypii), etc.

In addition, the agricultural and horticultural fungicide composition of the present invention has an excellent bactericidal effect against resistant bacteria. Furthermore, since it is effective when applied at a very low dose, it has the effect of preventing the emergence of new resistant bacteria.

The present invention will be described in more detail with reference to test examples. However, the present invention is not limited to test examples.

(Cucumber gray mold control test)
Emulsion is obtained by dissolving ipfluphenokin and component B in an organic solvent and a surfactant. The emulsion is diluted with water to a predetermined concentration. The emulsion diluted solution is sprayed on the cotyledons of cucumber and naturally dried at room temperature. Then, a suspension of spores of Botrytis cinerea cucumber is inoculated by dropping and placed in a dark place, 20 ° C., and a room with high humidity for several days. The appearance of lesions on the leaves is compared with that without treatment, and the control rate is calculated. Emulsion diluents and ingredients using ipfluphenokin alone, based on S.R.Colby, Calculating synergistic and antagonistic responses of herbicide combinations, Weeds, 15, 20-22pp (1967). From each of the measured control rates in the emulsion diluent using B alone, the theoretical control rate in the emulsion diluent consisting of ipfluphenokin and component B in combination is calculated. Colby's formula: E = M + N-MN / 100M: Measured control rate in emulsion diluted solution using ipfluphenokin alone (%) N: Measured control in emulsion diluted solution using component B alone Rate (%) E: The theoretical control rate (%) control rate of 0% in the emulsion diluted solution consisting of ipfluphenokin and component B in combination means that lesions similar to those in the untreated group were observed. However, a control rate of 100% means that no lesion was found.
A synergistic effect is confirmed when the value of the measured control rate exceeds the theoretical control rate E calculated according to the above Colby's formula.

The plant disease control method and the horticultural bactericidal composition of the present invention show an excellent control effect against plant diseases even at a very low dose, and there is no concern about phytotoxicity to useful plants. In addition, the agricultural and horticultural fungicide composition of the present invention exhibits a remarkable synergistic plant disease control effect that cannot be predicted from the plant disease control effect obtained by using only ipfluphenokin or only the component B. Therefore, the present invention is industrially useful.

Claims (8)

Ipfluphenokin and biological pesticides or pesticides derived from living organisms, phosphite or salts thereof, mineral oils, organic oils, material of biological origin, potassium hydrogen carbonate (Potassium) bicarbonate), sodium hydrogen carbonate, Calcium carbonate, Calcium hydroxide, Potassium iodide, Potassium phosphonates, Chitosan hydrochloride , D-Limonene, Orange Oil, Urea, and an agricultural and horticultural bactericide composition containing at least one component B selected from the group consisting of elicitor. Biopesticide of component B or pesticide derived from organism
Extract from the cotyledons of lupine plantlets, extract from Swinglea glutinosa, extract from Melaleuca alternifolia (tea tree oil) ), Α-pinene (Alpha-pinene), α-terpinene (Alpha-terpinene), α-terpineol (Alpha-terpineol), α-terpinene (Alpha-terpinoline), γ-terpinene (Gamma-terpinene),
Vegetable oils (mixtures), eugenol, geraniol, thymol;
Trichoderma atroviride strain I-1237, Trichoderma atroviride strain LU132, Trichoderma atroviride strain SC1 and Trichoderma atroviride strain SC1 strain SKT-1), Trichoderma atroviride strain 77B,
Trichoderma asperellum strain T34, Trichoderma asperellum strain kd,
Trichoderma harzianum strain T-22,
Trichoderma, including Trichoderma virens strain G-41;
Gliocladium, including the Gliocladium catenulatum strain J1446;
Clonostachys rosea strain CR-7, including Clonostachys rosea strain CR-7;
Coniothyrium, including Coniothyrium minitans strain CON / M / 91-08;
Talaromyces, including the Talaromyces flavus strain SAY-Y-94-01;
Saccharomyces, including Saccharomyces cerevisae strain LAS02;
Bacillus amyloliquefaciens strain QST713 (Bacillus amyloliquefaciens strain QST713), Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain MBI600 Bacillus amyloliquefaciens strain D747, Bacillus amyloliquefaciens strain F727, Bacillus amyloliquefaciens strain AT-332,
Bacillus subtilis strain AFS032321 strain (Bacillus subtilis strain AFS032321), Bacillus subtilis strain Y1336 strain (Bacillus subtilis strain Y1336), Bacillus subtilis strain HAI-0404 strain (Bacillus subtilis strain HAI-0404), including Bacillus subtilis strain HAI-0404, Bacillus simplex Bacillus;
Paenibacillus;
Burkholderia;
Pseudomonas fluoraphis strain AFS009, Pseudomonas fluorescens, Pseudomonas rhodesiae, Pseudomonas rhodesiae, Pseudomonas rhodesiae
Streptomyces, including Streptomyces griseovirides strain K61, Streptomyces lydicus strain WYEC108;
Agrobacterium, including Agrobacterium radiobacter;
Non-pathogenic Erwinia, including Erwinia carotovora subsp. Carotovora;
Variovorax paradoxus, variovorax; and Lactobacillus plantarum, Lactobacillus;
The fungicide composition for agriculture and horticulture according to claim 1, which is at least one selected from the group consisting of. Phosphorous acid salts are potassium phosphite (Potassium phosphite), ammonium phosphite (Ammonium phosphite), calcium phosphite (Calcium phosphite), aluminum phosphite (Aluminum phosphite) and sodium phosphite (Disodium phosphonate), The agricultural and horticultural bactericide composition according to claim 1 or 2, which is at least one selected from the group consisting of. The elicitor is yeast or its extract, β-glucan, chitin or chitosan or fragments thereof, β-aminobutyric acid, 2,6-dichloroisonicotinic acid, salicylic acid or its derivative, algae extract, algae extract (hydrogenated). Degradants), jasmine flower extract, sodium alginate, oligosaccharides, laminarin (β-1,3-glucooligosaccharides), trehalose, polysaccharides, lipids, lipopolysaccharides, fatty acids, glycolipids, glycoproteins, glycopeptides, plants and / or The agricultural and horticultural bactericidal composition according to any one of claims 1 to 3, which is at least one selected from the group consisting of proteins or peptides derived from pathogenic microorganisms and ergosterol. Ipfluphenokin and biological pesticides or pesticides derived from living organisms, phosphite or salts thereof, mineral oils, organic oils, material of biological origin, potassium hydrogen carbonate (Potassium) bicarbonate, sodium hydrogen carbonate, Calcium carbonate, Calcium hydroxide, Potassium iodide, Potassium phosphonates, Chitosan hydrochloride , D-Limonene, Orange Oil, Urea, and at least one ingredient B selected from the group consisting of elicitor, used simultaneously, separately or at intervals of time. How to control plant diseases. Biopesticide of component B or pesticide derived from organism
Extract from the cotyledons of lupine plantlets, extract from Swinglea glutinosa, extract from Melaleuca alternifolia (tea tree oil) ), Α-pinene (Alpha-pinene), α-terpinene (Alpha-terpinene), α-terpineol (Alpha-terpineol), α-terpinene (Alpha-terpinoline), γ-terpinene (Gamma-terpinene), vegetable oils ( Mixtures (plant oils (mixtures)), eugenol, geraniol, thymol;
Trichoderma atroviride strain I-1237, Trichoderma atroviride strain LU132, Trichoderma atroviride strain SC1 and Trichoderma atroviride strain SC1 strain SKT-1), Trichoderma atroviride strain 77B,
Trichoderma asperellum strain T34, Trichoderma asperellum strain kd,
Trichoderma harzianum strain T-22,
Trichoderma, including Trichoderma virens strain G-41;
Gliocladium, including the Gliocladium catenulatum strain J1446;
Clonostachys rosea strain CR-7, including Clonostachys rosea strain CR-7;
Coniothyrium, including Coniothyrium minitans strain CON / M / 91-08;
Talaromyces, including the Talaromyces flavus strain SAY-Y-94-01;
Saccharomyces, including Saccharomyces cerevisae strain LAS02;
Bacillus amyloliquefaciens strain QST713 (Bacillus amyloliquefaciens strain QST713), Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain FZB24, Bacillus amyloliquefaciens strain MBI600 Bacillus amyloliquefaciens strain D747, Bacillus amyloliquefaciens strain F727, Bacillus amyloliquefaciens strain AT-332,
Bacillus subtilis strain AFS032321 strain (Bacillus subtilis strain AFS032321), Bacillus subtilis strain Y1336 strain (Bacillus subtilis strain Y1336), Bacillus subtilis strain HAI-0404 strain (Bacillus subtilis strain HAI-0404), Bacillus simplex Bacillus;
Paenibacillus;
Burkholderia;
Pseudomonas genus; Pseudomonas chlororaphis strain AFS009, Pseudomonas fluorescens, Pseudomonas rhodesiae, Pseudomonas genus Pseudomonas
Streptomyces, including Streptomyces griseovirides strain K61, Streptomyces lydicus strain WYEC108;
Agrobacterium, including agrobacterium radiobacter;
Non-pathogenic Erwinia genus (erwinia), including erwinia carotovora subsp. Carotovora;
Variovorax, including the variovorax paradoxus;
Lactobacillus plantarum, including Lactobacillus plantarum;
The plant disease control method according to claim 5, which is at least one selected from the group consisting of. Phosphorous acid salts are potassium phosphite (Potassium phosphite), ammonium phosphite (Ammonium phosphite), calcium phosphite (Calcium phosphite), aluminum phosphite (Aluminum phosphite) and sodium phosphite (Disodium phosphonate), The method for controlling plant diseases according to claim 5 or 6, which is at least one selected from the group consisting of. The elicitor is yeast or its extract, β-glucan, chitin or chitosan or fragments thereof, β-aminobutyric acid, 2,6-dichloroisonicotinic acid, salicylic acid or its derivative, algae extract, algae extract (hydrogenated). Degradants), jasmine flower extract, sodium alginate, oligosaccharides, laminarin (β-1,3-glucooligosaccharides), trehalose, polysaccharides, lipids, lipopolysaccharides, fatty acids, glycolipids, glycoproteins, glycopeptides, plants and / or The method for controlling plant diseases according to any one of claims 5 to 7, which is at least one selected from the group consisting of proteins or peptides derived from pathogenic microorganisms and ergosterol.