WO2014006154A1 - Improved filtration unit having a pressure voume adjusting body - Google Patents

Improved filtration unit having a pressure voume adjusting body Download PDF

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Publication number
WO2014006154A1
WO2014006154A1 PCT/EP2013/064182 EP2013064182W WO2014006154A1 WO 2014006154 A1 WO2014006154 A1 WO 2014006154A1 EP 2013064182 W EP2013064182 W EP 2013064182W WO 2014006154 A1 WO2014006154 A1 WO 2014006154A1
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WO
WIPO (PCT)
Prior art keywords
filter
filtration unit
unit
pressure
feed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2013/064182
Other languages
French (fr)
Inventor
Jeanette Lindau
Tomas Skoglund
Fredrik Innings
Jan Vos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tetra Laval Holdings and Finance SA
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Tetra Laval Holdings and Finance SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of WO2014006154A1 publication Critical patent/WO2014006154A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08Flat membrane modules
    • B01D63/082Flat membrane modules comprising a stack of flat membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; PREPARATION THEREOF
    • A23C2210/00Physical treatment of dairy products
    • A23C2210/20Treatment using membranes, including sterile filtration
    • A23C2210/208Removal of bacteria by membrane filtration; Sterile filtration of milk products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2311/00Details relating to membrane separation process operations and control
    • B01D2311/06Specific process operations in the permeate stream
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2311/00Details relating to membrane separation process operations and control
    • B01D2311/14Pressure control
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/24Specific pressurizing or depressurizing means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/24Specific pressurizing or depressurizing means
    • B01D2313/243Pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/02Forward flushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/04Backflushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/20By influencing the flow
    • B01D2321/2083By reversing the flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/147Microfiltration

Definitions

  • the present invention relates to an arrangement in a cross flow filtration unit, such as a microfiltration unit, having a feed inlet, a permeate outlet and retentate outlet, for improving washing action of the filter. More specifically, the present invention pertains to an arrangement in a cross flow filtration unit, such as a microfiltration unit, having a feed inlet, a permeate outlet and retentate outlet, such filtration unit comprising several membranes sandwiched between membrane support plates, which are arranged in stacks.
  • Cross flow membrane filtration technology has been used widely and globally in industry.
  • a feed is supplied to the cross flow membrane unit, wherein a permeate e its the unit on the other side of the filter while a retentate exits the unit on the same side of the filter as the feed enters.
  • Filtration membranes can be organic, such as polymeric, or inorganic, such as ceramic, depending upon the application.
  • the principles of cross-flow filtration are used in reverse osmosis, i.e. concentration of solutions by removing water, nanofiltration, i.e. concentration of organic components by removal of ions like sodium and chlorine, ultrafiltration, i.e. concentration of large and macromolecules, for example proteins, and microfiltration, i.e. removal of bacteria.
  • Filters in cross flow membrane filtration arc periodically cleaned/w ashed through backwash ing.
  • backw ashing the transmembrane pressure is periodically inverted by the use of a secondary pump, so that permeate flows back into the feed, lifting the foul ing layer from the surface of the membrane, which is disclosed in Figure. 2.
  • Backwashing results in a pressure increase on the feed/retentatc side of the filter, which affects the system negatively.
  • Microfiltration is a membrane technical filtration process which removes contaminants from a fluid ( l iquid or gas) by passage through a micro porous membrane.
  • a typical microfiltration membrane pore size range is 0. 1 to 1 0 micrometers ( iim).
  • the use of micro filters is widespread in food processing where the pore size is ideal for separating unwanted dissolved solids, such as pores for example.
  • One technique is to periodical ly block the forw ard feed short times periodically allowing the pores to be unclogged as the blocking of the permeate flow will cause a backwards flow that rinses the pores.
  • Another technique is to periodically push the permeate flow backw ards for a short time period for example using a piston
  • the present invention seeks to mitigate, alleviate, eliminate or circumvent one or more of the above-ident ified deficiencies in the art and disadvantages singly or in any combinat ion by providing a filtration unit for filtration of a liquid food product, said filtration unit comprising a feed inlet, a permeate outlet, arranged down streams the feed inlet, a filter, arranged in between the feed inlet and the permeate outlet to divide the filtration unit into at least a feed side and a permeate side, and a pressure volume adjust ing body, capable of varying in volume in response to pressure in the l iquid food product.
  • Figure 1 illustrates schematic view of a filter unit according to the prior art
  • Figure 2 illustrates schematic view of a filter unit according to the prior art during backwashing
  • Figure 3 illustrates schematic view of a filter unit according to one embodiment of the invent ion
  • Figure 4 illustrates schematic view of a filter unit according to one embodiment of the invent ion during backwashing
  • Figure 5a illustrates a perspective view of a filter unit according to one embodiment of the invent ion:
  • Figure 5b illustrates a cross-sectional view of a filter unit according to one embodiment of the inv ent ion
  • Figure 6 shows a schematic view of a filter apparatus according to one embodiment of the teachings of this application
  • Figure 7 shows a schematic, cross-sectional view of the general structure of a filter apparatus according to one embodiment of the teachings of this applicat ion
  • Figure 8 shows a partial view of a connect ing rod arrangement according to one embodiment of the teachings of this application.
  • the present invent ion relates to an arrangement in a cross flow filtration unit, such as a microfiltration unit, hav ing a feed inlet, a permeate outlet and retentate outlet, for improv ing performance washing act ion of the filter.
  • the filter is preferably inorganic, such as ceramic or silica-based, since organic, such as polymeric, membranes tend to delaminatc during backwash ing.
  • the present invention pertains to an arrangement in a cross flow filtration unit 30, such as a microfiltration unit, hav ing a feed inlet stream F, a permeate outlet stream P and retentate outlet stream R, in accordance with Figures. 3 and 4, in a dairy system.
  • the filtration unit 30 is posit ioned in the dairy system for removal of microorganisms and bacteria.
  • the filter unit 30 comprises at least one feed/ retentate channel, extending from the inlet to the retentate outlet, through which feed F gradually turns into retentate R, exit ing the filter unit 30.
  • the feed/retentate channel extends adjacent a filter 3 1 , such as a microfiltration filter, such that the feed/retentate channel not has to cross the filter 3 1 on its way from the feed inlet to the retentate outlet.
  • the filter unit 30 further comprises at least one permeate channel, extending from the filter 3 1 to the permeate outlet. Liquid passing from the feed F over the filter 3 1 will enter the permeate channel to become permeate P, which in turn exits the filter unit 30 at the permeate outlet.
  • the pressure volume adjusting body 37 may in one embodiment be a flexible membrane with hollow inner volume, such as a balloon or balloon- like body. Suitable materials for the balloon or balloon-like body 37 are thus plastics and rubbers. The plastics and rubbers are preferably of food-grade, due to the requirements on food production facilities.
  • the balloon or balloon l ike body 37 i.s inflated, such that the balloon or balloon like body 37, in production mode of the dairy system, has a first volume.
  • the first volume may be kept by inflat ing the balloon or balloon-like body 37 with a suitable gas or l iquid, such as ai , through a conduit outside the filter unit 30.
  • the pressure on the feed/retentate side of the filter unit 30 wants to increase.
  • the balloon or balloon-like body 37 will decrease in volume into a second volume to compensate for the pressure derivate, such that the backflow through the filter 31 and on the feed retentate side not is adversely affected by an increase in pressure.
  • the liquid volume on the feed F 'retentate R side of the filter will effect ively be increased.
  • the pressure on the feed/retentate side of the filter 3 1 in the filter unit 30 may be kept substantially constant.
  • the pressure volume adjusting body 37 may be a coated sponge-like body with a first volume.
  • the coating of the coated sponge-like body 37 is not permeable to the dairy product. Suitable materials for the coated spongel ike body 37 are thus plast ies and rubbers. The plastics and rubbers are preferably of food-grade, due to the requirements on food production facilities. Due to the spongelike and compressible core of the sponge-like body 37, the first volume may be kept without appl ication of a pressure through a separate conduit, connected to a pressure supply outside the filter unit 30.
  • the sponge- 1 ike body will be compressed during backwash in the same manner as the balloon or balloon-like body described above into a second volume, to compensate for the positive pressure derivate on the feed/retentate side of the filter 3 1 in the filter unit 30.
  • the structure of the core sponge should be selected such that it - under the circumstances - substantially holds the first volume during production mode, while it during baekwashing is compressed into the second volume as a result of positive pressure derivate on the feed, retentate side.
  • a filtration unit 50 in a dairy system comprises several membranes 5 1 sandwiched between membrane support plates 52, which are arranged in stacks.
  • the membranes may be microfiltration. membranes.
  • the feed F is forced through narrow channels 53.
  • the narrow channels 53 may be configured for parallel flow or as a combination o parallel and serial channels.
  • the filter unit 50 comprises at least one feed, retentate channel, extending from the inlet to the retentate outlet, through which feed F gradually turns into retentate R when exit ing the filter unit 50.
  • the fced/retentate channel extends adjacent the filter membrane 51 , such as a microfiltration filter, such that the fced/retentate channel not has to cross the filter on its way from the feed inlet to the retentate outlet.
  • the filter unit 50 further comprises at least one permeate channel, extending from the filter to the permeate outlet. Liquid passing from the feed F over the filter will enter the permeate channel to become permeate P, which in turn exits the filter unit 50 at the permeate outlet.
  • the filtration unit 50 may be divided into sections, in each of which the flow between pairs of membranes 5 1 is parallel .
  • the sections are separated by a special membrane support plate 52 in which one hole is closed with a stop disc to reverse the direction of flow, giving serial flow between successive sections.
  • the sizes of the modules may vary, depending on the size and capacity of the dairy system using the filtration unit 50.
  • Retentate channels 54 extend into the filtration unit 50 to intersect with the planes in which the membranes 5 1 are arranged, sandwiched between membrane support plates 52.
  • the retentate channels 54 may extend perpendicularly to the planes in which the membranes 5 1 are arranged. These retentate channels 54 provide close proximity to the membranes 51 , while simultaneously providing good volume for the retentate R on its way to leave the filter unit 50.
  • a top support plate 55 and a bottom support plate 56 are arranged. In at least one of these, but also possibly in both, feed inlets and retentate outlets are arranged. In at least one. but possibly two of the feed/retentate channels 54 a pressure volume adjusting body 57 is positioned.
  • the pressure volume adjusting body 57 may be a flexible membrane with hollow inner volume, such as the balloon or balloon-l ike body described above, or the pressure volume adjusting body 57 may be a coated sponge-like body in accordance with above. Suitable materials for the balloon or balloon-like body 31 and/or the coated sponge-like body are plastics and rubbers.
  • the pressure volume adjust ing body 57 extends into the filtrat ion unit 50, in said feed/retentate channel 54 to intersect with the planes in which the membranes 5 1 are arranged, sandw iched between membrane support plates 52.
  • the pressure volume adjusting body 57 may - just as the retentate channels 54 - extend
  • the pressure volume adjusting body 57 is then provided in close proximity to the membranes 5 1 , whereby it can adjust in volume in fast response and in good correlat ion with the increased pressure derivate caused by the baekwashing.
  • the pressure volume adjust ing body 57 is inflated, such that the pressure volume adjusting body 57, in production mode of the dairy system, has a first volume.
  • the first volume may be kept by inflating the pressure volume adjust ing body 57 with a suitable gas or liquid, such as air, through a conduit outside the filter unit 50.
  • a suitable gas or liquid such as air
  • the pressure volume adjust ing body 57 When the pressure on the feed/retentate side of the filter in the filter unit 50 wants to increase, the pressure volume adjust ing body 57 will decrease in volume into a second volume to compensate for the pressure derivate, such that the backflow through the filter membrane 5 1 and on the feed retentate side not is adversely affected by an increase in pressure. In this way, the pressure on the feed/retentate side of the filter in the filter unit 50 may be kept substant ially constant.
  • the present invent ion relates to a filter
  • FIG. 6 shows a filtration system 1 according to the teachings herein.
  • a filter unit 2 comprises a piston based pumping device which is controlled by a connect ing rod 3.
  • the filter unit 2 comprises a plurality of filters all connected to the same connect ing rod 3. This enables for controlling a plurality of filter membranes in an efficient manner.
  • the connecting rod 3 is driven by a motor 4 to move back and forth (up or down in the figure).
  • the connecting rod 3 moves back and forth (up or down in the figure), the flow through the filter membranes of the filter unit 2 is pushed or pumped backwards and forwards correspondingly through the filter unit 2.
  • TMP Trans Membrane Pressure
  • the TMP is kept at a high level. The level is dependent on the type of filtration as would be apparent to a skilled person.
  • the TMP is allowed to fall.
  • the filter is preferably a non-polymeric filter, even though tradit ional polymeric filter membranes commonly used in devices for ultra filtration, nano filtrat ion or reverse osmosis will also work within the context of the inv ent ion.
  • non-polymeric filters are less prone to be dclaminatcd by the two-way flow of the device according to embodiments of the inv ention.
  • the connecting rod 3 is arranged to allow a lev el of flow in a direction in relation to the distance of the connecting rod 3 from a midpoint of the connecting rod 3.
  • the connecting rod 3 controls the flow so that when the piston is in the bottom-most position the flow is at a maximum forwards flow. When the connecting rod 3 is in its top-most position the flow is at a maximum backwards flow.
  • the connect ing rod 3 is controlled to cause a slow forward flow being interrupted with a fast, periodical backward flow or backpuise for a repeated rinsing effect.
  • Figure 7 shows a cutout v iew of the piston arrangement of figure 6.
  • the arrangement is adapted to provide an improved control of a flow.
  • the connect ing rod 3 of figure 6 is springloaded by a spring 5 to push against a cam 6. This causes the mov ement of the connect ing rod 3 to be controlled by the shape of the cam 6.
  • the spring 5 is adapted to be suitable for a 15 to 30 Hz
  • the cam 6 is drivingly connected to the motor 4 of figure 6 through a spindle 7. As the spindle 7 revolves so does the cam 6 and based on the shape or profile of the cam 6 the connecting rod 3 is moved up and down (up and down di ections refer to the directions in the figures) causing the forwards and backwards flow accordingly.
  • the cam 6 is shaped to have low profile for most of its circumference enabling a slow fo ward flow.
  • the low profile is interrupted by a short peak.
  • the low profile causes the connecting rod 3 to drive the piston based pumping device slowly in a forwards direction, while the peak will cause the connecting rod 3 to be raised thereby causing the piston based pumping dev ice to pump the flow backwards for a short time period.
  • the piston based pumping device is solely arranged to generate the backpulse. When the piston is moved from a low position the raising the piston, the piston based pumping device causes a reverse or backwards flow. If the peak is short and rises quickly enough the reverse flow will be in the form of a short backpulse.
  • the uppermost (in the figure) surface portion of the cam 6 has a peak, whereas the bottommost (in the figure) surface portion of the cam 6 has a lower profile.
  • the speed and direction of the flow - in either direction - can be precisely controlled.
  • the period of the backward flow is determined by the length of the peak.
  • the speed of the flow is controlled by the height of the cam profile. The lower, the faster the forwards flow, the higher, the faster the backwards flow.
  • cam 6 which has a profile that enables a precise control of the connecting rod 3 and the piston based pumping device so that the flow through the filter membranes of the filter unit 2 can be precisely controlled. This allows for rinsing the pores of the filter membranes of the filter unit 2 and thereby extends the effective life time of the filters, which extends overall production time. This also leads to a decreased need for cleaning-in-place (CIP) and a decreased need for cleaning chemicals during operation.
  • CIP cleaning-in-place
  • the connecting rod 3 is supported by a first support 8 and a second support 9.
  • the connecting rod 3 is connected to the supports 8 and 9 by bearings 1 1 , 12, 13.
  • the bearings 11, 12, 13 supporting the connecting rod 3 arc adapted to cancel side forces, prevent rotation and limit bending forces on the connecting rod 3,
  • the spindle 7 is attached to a casing 1 0 by pendel bearings 14 ( in one specific embodiment the bending of the pendel bearing is 0.3 ) and to the cam 6 by a ial angle contact bearings 1 5.
  • the system comprising the connecting rod 3 and its drive system can be implemented as a micro-electromechanical system, as in figure 7.
  • the system comprising the connecting rod 3 and its driv e system can also be implemented as a pneumatic system.
  • the connect ing rod 3 is further arranged with a cam fol lower 16, see figure 8, which is adapted to operate being subjected to forces up to about 20 kN.
  • the force in the tube (not shown ) enclosing the connecting rod 3 is l imited to 7 k to prevent bending of the connecting rod 3.
  • the connecting rod 3 is arranged to drive a piston based pumping device to only cause a backpulse in the transmembrane flow.
  • the flow through the membrane of the filter would also be controlled by other, convent ional filter components (not shown ).
  • the connecting rod 3 is controllably driven by a hydraulics system. Be regulating the pressure in a hydraulic system operably connected to the connecting rod 3, the connecting rod 3 can be caused to move up and down according to the pressure changes. As the pressure increases in the hydraulic system, the connecting rod 3 is forced upwards and as the pressure decreases, the connect ing rod 3 is al lowed to retreat dow nwards, possibly biased by a spring 5.
  • the pressure in the hydraul ic system can be affected with a pump or by other means and such means can be controlled by a Programmable Logic Circuit or other control means to increase and decrease the pressure at specific interv als and at specific rates, thereby enabl ing an accurate and precise control of the mov ement of the connect ing rod 3.
  • a piston based pumping device based filter system is connected to a pipe system for providing the filter unit 2 with feed and for transporting the permeate from the filter unit 2.
  • the small volume of the flow from the piston based pumping device does not significantly affect the overall permeate flow.
  • Simulat ions have shown that when the pipes transporting the permeate are long, the piston displacement in the piston based pumping device is superimposed on the flow through a filter membrane in the filter unit 2 ithout a fleet ing the downstream flow in the permeate. This enables a steady del ivery of the permeate even though a backwards flow through the membrane is generated for short time periods.
  • the cam 6 is designed to cause a fall t ime for the TMP of 44 ms and a wait time of 1 7 ms.
  • the rise time is 6 ms.
  • the fall t ime is 61 ms and the wait time is 0 ms.
  • the rinsing caused by the backwards or reverse flow depends on at least two factors.
  • the first factor is the maximum negative flow length (s neg ) through the pores.
  • the second factor is the maximum negative flow velocity (v neg ) through the pores.
  • V' r and Q' r are determined through:
  • V ⁇ V,. * (1 - 1/T) - t r * Q aveperm (4)
  • a pUmp is 13 cm 2 and the stroke of the piston is about 0.15 cm.
  • the necessary setting for the piston and the piston based pumping device can thus be calculated through :
  • One benefit of the teachings herein is that a precise control of the reverse flow causing the rinsing effect can be achieved.
  • the control is provided through the use of a cam which is simple to design.
  • the lifespan of a filter is thereby effectively increased in a predictable manner.
  • a filtration unit such as the filtrat ion unit 30, 50 having been disclosed with reference to figures 1 to 5, can beneficially be arranged in a filter unit, such as the filter unit 2 in the filter apparatus 1 having been disclosed with reference to figures 6 to 8.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Description

IMPROVED FI LTRATION UNIT HAVING A PRESSURE VOUME
ADJUSTING BODY
Technical Field of the invention
The present invention relates to an arrangement in a cross flow filtration unit, such as a microfiltration unit, having a feed inlet, a permeate outlet and retentate outlet, for improving washing action of the filter. More specifically, the present invention pertains to an arrangement in a cross flow filtration unit, such as a microfiltration unit, having a feed inlet, a permeate outlet and retentate outlet, such filtration unit comprising several membranes sandwiched between membrane support plates, which are arranged in stacks.
Background
Cross flow membrane filtration technology has been used widely and globally in industry. A feed is supplied to the cross flow membrane unit, wherein a permeate e its the unit on the other side of the filter while a retentate exits the unit on the same side of the filter as the feed enters. Filtration membranes can be organic, such as polymeric, or inorganic, such as ceramic, depending upon the application. The principles of cross-flow filtration are used in reverse osmosis, i.e. concentration of solutions by removing water, nanofiltration, i.e. concentration of organic components by removal of ions like sodium and chlorine, ultrafiltration, i.e. concentration of large and macromolecules, for example proteins, and microfiltration, i.e. removal of bacteria.
Up to th is point, reverse osmosis is performed on a plate and frame design, tubular design with polymers, and spiral-wound; nanofiltration is performed in spiral wound; ultrafiltration is performed on plate and frame design, tubular design with polymers, tubular design with ceramics, spiral-wound, and hollow-fiber; and
microfiltration on tubular design w ith ceramics.
In the field of dairy industry, it has thus been common practice to remove bacteria through microfiltration on tubular design with ceramics. Normally, skim milk is treated in microfiltration, since otherwise also fat would be removed with bacteria.
Filters in cross flow membrane filtration arc periodically cleaned/w ashed through backwash ing. In backw ashing, the transmembrane pressure is periodically inverted by the use of a secondary pump, so that permeate flows back into the feed, lifting the foul ing layer from the surface of the membrane, which is disclosed in Figure. 2. Backwashing results in a pressure increase on the feed/retentatc side of the filter, which affects the system negatively.
It would thus be advantageous if maintenance of a micro filtrat ion system could be improved, while simultaneously obtaining higher cost efficiency. It would addit ionally be advantageous if these posit iv es could be obtained simultaneously as providing a system wherein backwashing is improved.
Microfiltration is a membrane technical filtration process which removes contaminants from a fluid ( l iquid or gas) by passage through a micro porous membrane. A typical microfiltration membrane pore size range is 0. 1 to 1 0 micrometers ( iim). The use of micro filters is widespread in food processing where the pore size is ideal for separating unwanted dissolved solids, such as pores for example.
In crossflow filtration, the feed is passed across the filter membrane
(tangent ially) at positive pressure relat ive to the permeate side. A proportion of the material which is smaller than the membrane pore size passes through the membrane as permeate or filtrate; everything else is retained on the feed side of the membrane as retentate.
Ov er time deposit ion of various components in the feed will build up and accumulate on, within and around the pores. The pores will then become clogged which will cause the flu through the filter to decl ine and eventual ly the filter will become blocked. Such membrane fouling thus shortens the time a filter can be actively used.
To prevent, or at least delay, such clogging and thereby increase the time a filter can actively be used, various techniques have been proposed. One technique is to periodical ly block the forw ard feed short times periodically allowing the pores to be unclogged as the blocking of the permeate flow will cause a backwards flow that rinses the pores. However, it is difficult to ascertain that the backw ards flow will actually occur and it is also hard to control it. Another technique is to periodically push the permeate flow backw ards for a short time period for example using a piston
basedpumping device. This will aid in unclogging the pores by causing a rinsing effect. However, such back-flow is di fficult to control. These problems are also present in Ultrafiltration. Nano filtration and Reverse Osmosis.
Summary of the invention
Consequently, the present invention seeks to mitigate, alleviate, eliminate or circumvent one or more of the above-ident ified deficiencies in the art and disadvantages singly or in any combinat ion by providing a filtration unit for filtration of a liquid food product, said filtration unit comprising a feed inlet, a permeate outlet, arranged down streams the feed inlet, a filter, arranged in between the feed inlet and the permeate outlet to divide the filtration unit into at least a feed side and a permeate side, and a pressure volume adjust ing body, capable of varying in volume in response to pressure in the l iquid food product.
Further advantageous features of the invention are defined in the dependent claims. In addit ion, advantageous features of the inv ent ion are elaborated in
embodiments disclosed herein.
Brief description of the drawings
The inv ent ion will below be described more in detail, hav ing reference to a preferred embodiment thereof shown on the accomplishing drawings, in which:
Figure 1 illustrates schematic view of a filter unit according to the prior art; Figure 2 illustrates schematic view of a filter unit according to the prior art during backwashing;
Figure 3 illustrates schematic view of a filter unit according to one embodiment of the invent ion;
Figure 4 illustrates schematic view of a filter unit according to one embodiment of the invent ion during backwashing;
Figure 5a illustrates a perspective view of a filter unit according to one embodiment of the invent ion:
Figure 5b illustrates a cross-sectional view of a filter unit according to one embodiment of the inv ent ion;
Figure 6 shows a schematic view of a filter apparatus according to one embodiment of the teachings of this application; Figure 7 shows a schematic, cross-sectional view of the general structure of a filter apparatus according to one embodiment of the teachings of this applicat ion; and
Figure 8 shows a partial view of a connect ing rod arrangement according to one embodiment of the teachings of this application.
Detailed descript ion of preferred embodiments
The disclosed embodiments will now be described more fully hereinafter with reference to the accompanying drawings, in which certain embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided by way of example so that this disclosure will be thorough and complete, and will ful ly convey the scope of the invent ion to those skilled in the art. Like numbers refer to l ike elements throughout.
According to one aspect, the present invent ion relates to an arrangement in a cross flow filtration unit, such as a microfiltration unit, hav ing a feed inlet, a permeate outlet and retentate outlet, for improv ing performance washing act ion of the filter. The filter is preferably inorganic, such as ceramic or silica-based, since organic, such as polymeric, membranes tend to delaminatc during backwash ing.
More specifically, the present invention pertains to an arrangement in a cross flow filtration unit 30, such as a microfiltration unit, hav ing a feed inlet stream F, a permeate outlet stream P and retentate outlet stream R, in accordance with Figures. 3 and 4, in a dairy system. The filtration unit 30 is posit ioned in the dairy system for removal of microorganisms and bacteria.
The filter unit 30 comprises at least one feed/ retentate channel, extending from the inlet to the retentate outlet, through which feed F gradually turns into retentate R, exit ing the filter unit 30. The feed/retentate channel extends adjacent a filter 3 1 , such as a microfiltration filter, such that the feed/retentate channel not has to cross the filter 3 1 on its way from the feed inlet to the retentate outlet. The filter unit 30 further comprises at least one permeate channel, extending from the filter 3 1 to the permeate outlet. Liquid passing from the feed F over the filter 3 1 will enter the permeate channel to become permeate P, which in turn exits the filter unit 30 at the permeate outlet. In the feed/retentate channel a pressure volume adjust ing body 37 is positioned. The pressure volume adjusting body 37 may in one embodiment be a flexible membrane with hollow inner volume, such as a balloon or balloon- like body. Suitable materials for the balloon or balloon-like body 37 are thus plastics and rubbers. The plastics and rubbers are preferably of food-grade, due to the requirements on food production facilities. In use, the balloon or balloon l ike body 37 i.s inflated, such that the balloon or balloon like body 37, in production mode of the dairy system, has a first volume. The first volume may be kept by inflat ing the balloon or balloon-like body 37 with a suitable gas or l iquid, such as ai , through a conduit outside the filter unit 30. When baekwashing of the dairy filter unit 30 of the dairy system is performed, the pressure on the feed/retentate side of the filter unit 30 wants to increase. When the pressure on the feed/retentate side of the filter 31 in the filter unit 30 wants to increase, the balloon or balloon-like body 37 will decrease in volume into a second volume to compensate for the pressure derivate, such that the backflow through the filter 31 and on the feed retentate side not is adversely affected by an increase in pressure. Thus, the liquid volume on the feed F 'retentate R side of the filter will effect ively be increased. In t h i.s way, the pressure on the feed/retentate side of the filter 3 1 in the filter unit 30 may be kept substantially constant.
In another embodiment, the pressure volume adjusting body 37 may be a coated sponge-like body with a first volume. The coating of the coated sponge-like body 37 is not permeable to the dairy product. Suitable materials for the coated spongel ike body 37 are thus plast ies and rubbers. The plastics and rubbers are preferably of food-grade, due to the requirements on food production facilities. Due to the spongelike and compressible core of the sponge-like body 37, the first volume may be kept without appl ication of a pressure through a separate conduit, connected to a pressure supply outside the filter unit 30. Simultaneously, the sponge- 1 ike body will be compressed during backwash in the same manner as the balloon or balloon-like body described above into a second volume, to compensate for the positive pressure derivate on the feed/retentate side of the filter 3 1 in the filter unit 30. Thus, the structure of the core sponge should be selected such that it - under the circumstances - substantially holds the first volume during production mode, while it during baekwashing is compressed into the second volume as a result of positive pressure derivate on the feed, retentate side.
In Figures. 5a and 5b a filtration unit 50 in a dairy system is disclosed. The filtrat ion unit 50 comprises several membranes 5 1 sandwiched between membrane support plates 52, which are arranged in stacks. The membranes may be microfiltration. membranes. The feed F is forced through narrow channels 53. The narrow channels 53 may be configured for parallel flow or as a combination o parallel and serial channels.
The filter unit 50 comprises at least one feed, retentate channel, extending from the inlet to the retentate outlet, through which feed F gradually turns into retentate R when exit ing the filter unit 50. The fced/retentate channel extends adjacent the filter membrane 51 , such as a microfiltration filter, such that the fced/retentate channel not has to cross the filter on its way from the feed inlet to the retentate outlet. The filter unit 50 further comprises at least one permeate channel, extending from the filter to the permeate outlet. Liquid passing from the feed F over the filter will enter the permeate channel to become permeate P, which in turn exits the filter unit 50 at the permeate outlet.
The filtration unit 50 may be divided into sections, in each of which the flow between pairs of membranes 5 1 is parallel . The sections are separated by a special membrane support plate 52 in which one hole is closed with a stop disc to reverse the direction of flow, giving serial flow between successive sections. The sizes of the modules may vary, depending on the size and capacity of the dairy system using the filtration unit 50.
Retentate channels 54 extend into the filtration unit 50 to intersect with the planes in which the membranes 5 1 are arranged, sandwiched between membrane support plates 52. The retentate channels 54 may extend perpendicularly to the planes in which the membranes 5 1 are arranged. These retentate channels 54 provide close proximity to the membranes 51 , while simultaneously providing good volume for the retentate R on its way to leave the filter unit 50.
At the top and the bottom, respectively, of the filtration unit 50, a top support plate 55 and a bottom support plate 56 are arranged. In at least one of these, but also possibly in both, feed inlets and retentate outlets are arranged. In at least one. but possibly two of the feed/retentate channels 54 a pressure volume adjusting body 57 is positioned. The pressure volume adjusting body 57 may be a flexible membrane with hollow inner volume, such as the balloon or balloon-l ike body described above, or the pressure volume adjusting body 57 may be a coated sponge-like body in accordance with above. Suitable materials for the balloon or balloon-like body 31 and/or the coated sponge-like body are plastics and rubbers.
The pressure volume adjust ing body 57 extends into the filtrat ion unit 50, in said feed/retentate channel 54 to intersect with the planes in which the membranes 5 1 are arranged, sandw iched between membrane support plates 52. Thus, the pressure volume adjusting body 57 may - just as the retentate channels 54 - extend
perpendicularly to the planes in which the membranes 51 are arranged. The pressure volume adjusting body 57 is then provided in close proximity to the membranes 5 1 , whereby it can adjust in volume in fast response and in good correlat ion with the increased pressure derivate caused by the baekwashing.
In use, the pressure volume adjust ing body 57 is inflated, such that the pressure volume adjusting body 57, in production mode of the dairy system, has a first volume. The first volume may be kept by inflating the pressure volume adjust ing body 57 with a suitable gas or liquid, such as air, through a conduit outside the filter unit 50. When baekwashing of the dairy filter unit 50 of the dairy system is performed, the pressure on t he feed/retentate side of the filter unit 50 wants to increase. When the pressure on the feed/retentate side of the filter in the filter unit 50 wants to increase, the pressure volume adjust ing body 57 will decrease in volume into a second volume to compensate for the pressure derivate, such that the backflow through the filter membrane 5 1 and on the feed retentate side not is adversely affected by an increase in pressure. In this way, the pressure on the feed/retentate side of the filter in the filter unit 50 may be kept substant ially constant.
According to another aspect the present invent ion relates to a filter
arrangement for generating a back-pulse of a flow through a membrane of said filter. The volume adjusting body according to the embodiments above can be combined w ith the embodiments of the filter arrangement for generating a back-pulse of a flow through a membrane of said filter according to the embodiments disclosed below. Figure 6 shows a filtration system 1 according to the teachings herein. A filter unit 2 comprises a piston based pumping device which is controlled by a connect ing rod 3. In the example embodiment of figure 6 the filter unit 2 comprises a plurality of filters all connected to the same connect ing rod 3. This enables for controlling a plurality of filter membranes in an efficient manner. The connecting rod 3 is driven by a motor 4 to move back and forth (up or down in the figure). As the connecting rod 3 moves back and forth (up or down in the figure), the flow through the filter membranes of the filter unit 2 is pushed or pumped backwards and forwards correspondingly through the filter unit 2. As the flow is pushed forwards the TMP (Trans Membrane Pressure) is kept at a high level. The level is dependent on the type of filtration as would be apparent to a skilled person. As the flow is pushed backwards the TMP is allowed to fall.
The filter is preferably a non-polymeric filter, even though tradit ional polymeric filter membranes commonly used in devices for ultra filtration, nano filtrat ion or reverse osmosis will also work within the context of the inv ent ion.
However, non-polymeric filters are less prone to be dclaminatcd by the two-way flow of the device according to embodiments of the inv ention.
In one embodiment the connecting rod 3 is arranged to allow a lev el of flow in a direction in relation to the distance of the connecting rod 3 from a midpoint of the connecting rod 3. In the exempl ifying embodiment of figure 6, the connecting rod 3 controls the flow so that when the piston is in the bottom-most position the flow is at a maximum forwards flow. When the connecting rod 3 is in its top-most position the flow is at a maximum backwards flow.
To enable an improved prevention of clogging the filter membranes of the filter unit 2, the connect ing rod 3 is controlled to cause a slow forward flow being interrupted with a fast, periodical backward flow or backpuise for a repeated rinsing effect.
Figure 7 shows a cutout v iew of the piston arrangement of figure 6. The arrangement is adapted to provide an improved control of a flow. The connect ing rod 3 of figure 6 is springloaded by a spring 5 to push against a cam 6. This causes the mov ement of the connect ing rod 3 to be controlled by the shape of the cam 6. In a specific embodiment, the spring 5 is adapted to be suitable for a 15 to 30 Hz
applicat ion. The cam 6 is drivingly connected to the motor 4 of figure 6 through a spindle 7. As the spindle 7 revolves so does the cam 6 and based on the shape or profile of the cam 6 the connecting rod 3 is moved up and down (up and down di ections refer to the directions in the figures) causing the forwards and backwards flow accordingly.
As can be seen in figure 7, the cam 6 is shaped to have low profile for most of its circumference enabling a slow fo ward flow. The low profile is interrupted by a short peak. The low profile causes the connecting rod 3 to drive the piston based pumping device slowly in a forwards direction, while the peak will cause the connecting rod 3 to be raised thereby causing the piston based pumping dev ice to pump the flow backwards for a short time period. In an alternative embodiment the piston based pumping device is solely arranged to generate the backpulse. When the piston is moved from a low position the raising the piston, the piston based pumping device causes a reverse or backwards flow. If the peak is short and rises quickly enough the reverse flow will be in the form of a short backpulse.
As can be seen in figure 7, the uppermost (in the figure) surface portion of the cam 6 has a peak, whereas the bottommost (in the figure) surface portion of the cam 6 has a lower profile.
By designing the cam profile the speed and direction of the flow - in either direction - can be precisely controlled. The period of the backward flow is determined by the length of the peak. The speed of the flow is controlled by the height of the cam profile. The lower, the faster the forwards flow, the higher, the faster the backwards flow.
It is thereby possible to design a cam 6 which has a profile that enables a precise control of the connecting rod 3 and the piston based pumping device so that the flow through the filter membranes of the filter unit 2 can be precisely controlled. This allows for rinsing the pores of the filter membranes of the filter unit 2 and thereby extends the effective life time of the filters, which extends overall production time. This also leads to a decreased need for cleaning-in-place (CIP) and a decreased need for cleaning chemicals during operation.
In figure 7 the connecting rod 3 is supported by a first support 8 and a second support 9. The connecting rod 3 is connected to the supports 8 and 9 by bearings 1 1 , 12, 13. The bearings 11, 12, 13 supporting the connecting rod 3 arc adapted to cancel side forces, prevent rotation and limit bending forces on the connecting rod 3, The spindle 7 is attached to a casing 1 0 by pendel bearings 14 ( in one specific embodiment the bending of the pendel bearing is 0.3 ) and to the cam 6 by a ial angle contact bearings 1 5.
The system comprising the connecting rod 3 and its drive system (spindle, motor) can be implemented as a micro-electromechanical system, as in figure 7. The system comprising the connecting rod 3 and its driv e system (spindle 7, motor 4 ) can also be implemented as a pneumatic system.
The connect ing rod 3 is further arranged with a cam fol lower 16, see figure 8, which is adapted to operate being subjected to forces up to about 20 kN. In one embodiment the force in the tube (not shown ) enclosing the connecting rod 3 is l imited to 7 k to prevent bending of the connecting rod 3.
In one embodiment, as mentioned abov e, the connecting rod 3 is arranged to drive a piston based pumping device to only cause a backpulse in the transmembrane flow. In such an embodiment the flow through the membrane of the filter would also be controlled by other, convent ional filter components (not shown ).
It should be noted that the up down movement of the connecting rod 3 and corresponding control of the flow can be rev ersed to down/up by a corresponding change in the shape of the cam 6.
In an alternative embodiment the connecting rod 3 is controllably driven by a hydraulics system. Be regulating the pressure in a hydraulic system operably connected to the connecting rod 3, the connecting rod 3 can be caused to move up and down according to the pressure changes. As the pressure increases in the hydraulic system, the connecting rod 3 is forced upwards and as the pressure decreases, the connect ing rod 3 is al lowed to retreat dow nwards, possibly biased by a spring 5. The pressure in the hydraul ic system can be affected with a pump or by other means and such means can be controlled by a Programmable Logic Circuit or other control means to increase and decrease the pressure at specific interv als and at specific rates, thereby enabl ing an accurate and precise control of the mov ement of the connect ing rod 3.
In one embodiment a piston based pumping device based filter system according to herein is connected to a pipe system for providing the filter unit 2 with feed and for transporting the permeate from the filter unit 2. As the permeate flow has an inertia and the time period for the reveres flow is kept short, the small volume of the flow from the piston based pumping device does not significantly affect the overall permeate flow. Simulat ions have shown that when the pipes transporting the permeate are long, the piston displacement in the piston based pumping device is superimposed on the flow through a filter membrane in the filter unit 2 ithout a fleet ing the downstream flow in the permeate. This enables a steady del ivery of the permeate even though a backwards flow through the membrane is generated for short time periods.
In one particular embodiment designed for a flux of 45 ml min with a 1 5 Hz cam cycle, the cam 6 is designed to cause a fall t ime for the TMP of 44 ms and a wait time of 1 7 ms. The rise time is 6 ms. In an alternative embodiment the fall t ime is 61 ms and the wait time is 0 ms.
The rinsing caused by the backwards or reverse flow depends on at least two factors. The first factor is the maximum negative flow length (sneg) through the pores. The second factor is the maximum negative flow velocity (vneg) through the pores. These can be determined through the following equations:
Figure imgf000013_0001
and
Vneg = Q 'r / Apores (2)
where Ap0res is the area of the pores, Q\ is the negativ e flow through the membrane and V\ is the negative volume of flow through the membrane. V'r and Q'r are determined through:
Q'r = Vr * ( l /tr 1 Π ) Qilv ) rm (3)
and
V\ = V,. * (1 - 1/T) - tr * Qaveperm (4)
where Qaveperm is the average flow of the permeate, V,· is the volume flow of the permeate, t, is the fall t ime and T is the cycle time. Through these equat ions it is possible to design the piston based pumping device. For the piston based pumping device driven by the connect ing rod 3 we have:
V* r ApUmp * Spump (5 where Vr =Apump is the area of the piston based pumping device, and Spump is the amplitude for the piston based pumping device.
In an embodiment, ApUmp is 13 cm2 and the stroke of the piston is about 0.15 cm.
The necessary setting for the piston and the piston based pumping device can thus be calculated through :
Spump = (V'r + tr * Qaveperm) / (Apump * ( 1 - tr/T)) (6).
One benefit of the teachings herein is that a precise control of the reverse flow causing the rinsing effect can be achieved. The control is provided through the use of a cam which is simple to design. The lifespan of a filter is thereby effectively increased in a predictable manner.
It should be noted that a filtration unit, such as the filtrat ion unit 30, 50 having been disclosed with reference to figures 1 to 5, can beneficially be arranged in a filter unit, such as the filter unit 2 in the filter apparatus 1 having been disclosed with reference to figures 6 to 8.
The invention has mainly been described above with reference to a few embodiments. However, without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invent ion to its fullest extent. The preferred specific embodiments described herein are, therefore, to be construed as merely illustrative and not limitat ive of the remainder of the descript ion in any way whatsoever. Further, although the present invent ion has been described above with reference to specific embodiments, it is not intended to be limited to the specific form set forth herein.
In the claims, the term "co m pr i ses/co m p i sing" does not exclude the presence of other elements or steps. Additionally, although individual features may be included in different claims, these may possibly advantageously be combined, and the inclusion in different claims does not im ly that a combinat ion of features is not feasible and/or advantageous. In addit ion, singular references do not exclude a plurality. The terms "a", "an", "first", "second" etc do not preclude a plurality.

Claims

1 . A filtration unit (2, 30, 50) for filtration of a liquid food product, said filtration unit (2, 30. 50 ) comprising:
a feed inlet (F);
a permeate outlet (P), arranged down streams the feed inlet (F);
a filter (3 1. 5 1 ), arranged in between the feed inlet (F) and the permeate outlet (P) to divide the filtration unit (2, 30, 50) into at least a feed side and a permeate side; and
a pressure volume adjusting body (37, 57 ), capable of varying in volume in response to pressure in the liquid food product.
2. The filtration unit (2, 30, 50) according to claim 1 , wherein said pressure volume adjusting body (37, 57) is positioned on the feed side of the filtration unit (30, 50).
3. The filtration unit (2, 30, 50) according to claim 1 or 2, wherein the filter (31 , 51) is a micro filtration filter.
4. The filtration unit (2, 30, 50) according to any of the preceding claims, wherein the pressure volume adjusting body (37, 57) is a flexible membrane with hollow inner volume or a coated sponge-like body.
5. The filtration unit ( 2, 30, 50) according to claim 4, wherein the flexible membrane with hollow inner volume is connected to a gas or l iquid supply.
6. The filtration unit (2, 30, 50) according to any of the preceding claims, wherein the filtration unit (2. 30, 50) is a cross flow filtration unit (2, 30, 50), such that the filtration unit (2, 30, 50) further comprises a retentate outlet (R), such that the filter unit (2, 30, 50 ) comprises at least one feed/retentate channel ( 54), extending from the feed inlet (F) to the retentate outlet (R ). through which feed gradually turns into retentate (R ). exit ing the filter unit (2, 30, 50).
7. The filtration unit (30. 50) according to claim 6, wherein the pressure volume adjusting body (3 1 , 5 1 ) is arranged in the feed, retentate channel (54 ).
8. The filtration unit (50 ) according to claim 6 or 7, wherein the filtration unit (50 ) comprises several membranes (5 1 ) sandwiched between membrane support plates ( 52 ), and the at least one retentate channel ( 54 ) extend into the filtration unit (50) to intersect with the planes in which the membranes (51) are arranged.
9. The filtration unit (50) according to claim 8, wherein at least one pressure volume adjusting body (57) extends in a retentate channel (54 ), respectively, such that the at least one pressure volume adjust ing body (57) intersects with the planes in which the membranes (51) are arranged.
10. The filtration unit (50) according to any of the preceding claims, further comprising an apparatus (1) to be attached to the filter unit (2, 30, 50) for generating a back-pulse of a flow through a membrane of said filter unit ( 2, 30, 50), said apparatus comprising means for causing a connect ing rod (3) to move in a first forward direct ion at a first speed and in a second backwards direction at a second speed, wherein the second speed is not the same as the first speed.
1 1 . A dairy system for producing a dairy food product, comprising the filtration unit (30, 50) according to any of claims 1 to 10, for removal of microorganisms and bacteria.
12. A method for washing a filter membrane (3 1 , 5 1 ) in a filter unit (2, 30, 50) for filtrat ion of a liquid food product, said filter unit ( 2, 30, 50) being arranged in a system with a first operational flow direction from a feed inlet (F) to a permeate outlet (P), comprising the steps of: (i) pushing a fluid through the filter membrane (31 , 51) from the permeate outlet (P) to the feed inlet (F) in an opposite direction to the operational flow direction; and
(ii) increasing the liquid volume of said filter unit (2, 30, 50) down streams said filter membrane (3 1 , 5 1 ) during step (i).
1 3. The method according to claim 12, wherein step (ii) is performed by decreasing the v olume of a pressure volume adjusting body (37, 57), capable of v arying in volume in response to pressure in the liquid food product, said pressure volume adjusting body (37, 57 ) being arranged in said filter unit (2, 30, 50).
14. The method according to claim 13, wherein the pressure volume adjusting body (37, 57 ) is positioned down streams said filter membrane (3 1 , 5 1 ) during step (i).
1 5. A filter apparatus (1) comprising a filter (2) where said filter comprises a filtrat ion unit (2, 30, 50) according to any of claims 1 to 10.
PCT/EP2013/064182 2012-07-05 2013-07-04 Improved filtration unit having a pressure voume adjusting body Ceased WO2014006154A1 (en)

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Citations (7)

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US4592848A (en) * 1984-12-11 1986-06-03 Pabst Richard E Flow through filter with backflush clearing capability
GB2273885A (en) * 1992-12-30 1994-07-06 Pall Corp Producing sterile milk using dynamic microfiltration
WO2000057997A1 (en) * 1999-03-25 2000-10-05 Technology Finance Corporation (Proprietary) Limited Filtration system suitable for microfiltration, ultrafiltration or reverse osmosis
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Title
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