WO2014001436A1 - Double-cone pumping device - Google Patents

Double-cone pumping device Download PDF

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Publication number
WO2014001436A1
WO2014001436A1 PCT/EP2013/063478 EP2013063478W WO2014001436A1 WO 2014001436 A1 WO2014001436 A1 WO 2014001436A1 EP 2013063478 W EP2013063478 W EP 2013063478W WO 2014001436 A1 WO2014001436 A1 WO 2014001436A1
Authority
WO
WIPO (PCT)
Prior art keywords
double
pumping device
cones
cone
cone pumping
Prior art date
Application number
PCT/EP2013/063478
Other languages
French (fr)
Inventor
Constantine Sandu
Original Assignee
Nestec S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nestec S.A. filed Critical Nestec S.A.
Priority to EP13732150.1A priority Critical patent/EP2866924B1/en
Priority to CA2875639A priority patent/CA2875639A1/en
Priority to CN201380033451.9A priority patent/CN104379246B/en
Priority to ES13732150.1T priority patent/ES2600484T3/en
Priority to US14/407,149 priority patent/US9744504B2/en
Publication of WO2014001436A1 publication Critical patent/WO2014001436A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05Stirrers
    • B01F27/11Stirrers characterised by the configuration of the stirrers
    • B01F27/111Centrifugal stirrers, i.e. stirrers with radial outlets; Stirrers of the turbine type, e.g. with means to guide the flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05Stirrers
    • B01F27/11Stirrers characterised by the configuration of the stirrers
    • B01F27/117Stirrers provided with conical-shaped elements, e.g. funnel-shaped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/50Mixing liquids with solids
    • B01F23/53Mixing liquids with solids using driven stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/81Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis the stirrers having central axial inflow and substantially radial outflow
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D7/00Pumps adapted for handling specific fluids, e.g. by selection of specific materials for pumps or pump parts
    • F04D7/02Pumps adapted for handling specific fluids, e.g. by selection of specific materials for pumps or pump parts of centrifugal type
    • F04D7/04Pumps adapted for handling specific fluids, e.g. by selection of specific materials for pumps or pump parts of centrifugal type the fluids being viscous or non-homogenous
    • F04D7/045Pumps adapted for handling specific fluids, e.g. by selection of specific materials for pumps or pump parts of centrifugal type the fluids being viscous or non-homogenous with means for comminuting, mixing stirring or otherwise treating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/06Mixing of food ingredients

Definitions

  • the present invention generally refers to a pumping device.
  • the invention relates to a double-cone pumping device for food-processing mixing and agitation of liquid products, including particulate-containing liquid products. More particular, the invention relates to double-cone pumping device for mixing and agitation inside processing vessels.
  • the periphery of the disc may be slotted or formed with a plurality of extended teeth; or even the teeth may be serrated in the nature of a rotary saw blade.
  • vanes pitched at an angle are installed inside the hollow cones to increases the pumping capacity of the device.
  • the feeding elements include a plurality of openings formed at acute angles relative to the longitudinal axis such that, when rotated, the feeding elements induce liquid flow in an axial direction, inside the rotating screen.
  • the mixing devices described by the Jorgensen and Korstvedt patents feature entirely internal flow, incompatible with handling of particulates. In fact, these devices are tools mostly intended for comminution or micronization; instead of pumping alone.
  • the invention in a first aspect, relates to double-cone pumping device, comprising two cones that are axially symmetrically arranged with their large bases abutting, and rotatable around the axis, and an axial shaft that connects to driving means.
  • the double-cone pumping device comprises a flat disc and at least two rotating vanes and wherein the two cones are arranged so that their large bases lay on the opposite faces of the flat disc; and the vanes are located symmetrically onto the opposite sides of the flat disc; the flat disc and the vanes are rotatable with the two cones. It has been found that this design can generate a surprisingly large pumping action when rotating inside of a processing vessel.
  • the invention relates to a use of the double-cone pumping device for processing liquid food.
  • the double-cone pumping device in this invention both allows pumping of fluids containing particulates of any size while ensuring a large pumping capacity.
  • the double-cone pumping device is preferably made of two rotating cones that are substantially full bodies (as opposed to hollow).
  • the rotating cones are preferably directly connected to a rotating disc that additionally displays rotating vanes on each one of its sides, in order to enhance the pumping capacity of the device.
  • the combined physical body made of the two cones can be empty or can have an internal closed cavity, in order to reduce the total weight of the device. This does not change any of the external geometry of the double-cone pumping device, while the flow remains strictly external, and particulate- containing liquid products can be processed.
  • FIG. 1 illustrates a full view of a double-cone pumping device in accordance with an embodiment of the invention.
  • FIG. 2 illustrates a geometry of a double-cone pumping device in accordance with an embodiment of the invention.
  • the double-cone pumping device 1200 in Fig. 1 illustrates an embodiment of the invention both allows pumping of fluids containing particulates of any size and ensures a large pumping capacity.
  • Pumping device 1200 is made of rotating cones 1220 that are full bodies (as opposed to hollow). Rotating cones 1220 are directly connected to a rotating disc 1230 that additionally displays rotating vanes 1240 on each one of its sides.
  • rotating double-cone devices foreaturing hollow cones
  • the pumping device 1200 is solely designed for an efficient pumping that generates a strong internal motion inside a processing vessel.
  • rotating cones 1220 are full physical bodies.
  • rotating cones are directly connected to a rotating disc 1230.
  • rotating disc 1230 displays rotating vanes 1240 or blades on each side of the rotating disc.
  • the flow induced by the pumping device 1200 is entirely external to the rotating device, allowing for handling of particulates of any size.
  • the two cones and the flat disc may be separate part or made out of one piece.
  • the combined physical body made of the two cones can be empty or can have an internal closed cavity, in order to reduce the total weight of the device. This does not change any of the external geometry of the double-cone pumping device, while the flow remains strictly on the outside of the device.
  • the vanes on the rotating flat disc 1230 extend entirely along the rotating cones 1220, in a spiral configuration, to further increase the pumping capacity of the double-cone pumping device.
  • Fig. 2 is an illustration to the geometry of the double-cone pumping device, whereby the range within which the dimensions can vary is limited only by the intended purpose of the pumping device, the design power of the device, the mechanical resistance of construction materials, etc.
  • the rotating cones have a large base diameter A and a small base diameter B; the rotating disc has a diameter C; and an overall height of the double-cone pumping device is D.
  • A is in the range from 5 to 35 cm
  • B is from 1 to 15 cm
  • C is from 10 to 40 cm
  • D is from 15 to 55 cm.
  • A/D 0.4.
  • the double-cone pumping device is installed within a processing vessel by means of a shaft, eventually associated with driving means such as a gear box and a motor drive to transfer the torque from the motor to the pumping device.
  • driving means such as a gear box and a motor drive to transfer the torque from the motor to the pumping device.
  • the motor drive can have a variable frequency drive to allow rotational speeds in the range from 10 RPM to thousands RPM.
  • the location of the pump shaft can be axially in the processing vessel, or sidewise, coming from the top end of the processing vessel, from the bottom end of the processing, or from any side of the processing vessel.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)

Abstract

The invention relates to a double-cone pumping device, designed to provide for flow of the liquid product only on the outer side of the rotating cones, making it compatible with mixing of particulate-containing liquid products; and specifically advanced for high pumping capacity in mixing-agitation applications in food processing. The double-cone pumping device comprises two cones that are axially symmetrically arranged with their large bases abutting, and rotatable around the axis, and an axial shaft that connects to driving means. The invention also relates to a use of this pump in processing of liquid food.

Description

TITLE
"DOUBLE CONE PUMPING DEVICE"
[0001] The present invention generally refers to a pumping device. In particular, the invention relates to a double-cone pumping device for food-processing mixing and agitation of liquid products, including particulate-containing liquid products. More particular, the invention relates to double-cone pumping device for mixing and agitation inside processing vessels.
BACKGROUND
[0002] It is known in the food processing industry to use mixing-agitation devices built on the concept of rotating hollow cones, where the liquid is accelerated on the outer and inner sides of the hollow cones. However, since a flow of the liquid product on the inner side of the hollow cones is involved, there is a particle-size limitation that restricts the practical application of these mixing-agitation devices. In fact, these types of mixing-agitation devices are mainly utilized for comminution or micronization.
[0003] The subject of rotating cones or conical-surfaces is well known in the literature. For instance, Bruin, S., Velocity Distribution in a Liquid Film Flowing over a Rotating Conical Surface, Chemical Engineering Science 24, pp. 1647-1654, 1969. Under the influence of the centrifugal force, the flow along the surface of a rotating cone causes the liquid to accelerate; essentially, the liquid does flow from the small base towards the large base of the truncated cone. The acceleration of the liquid along the conical surface is a function of the geometry of the conical surface, rotational speed, and flow properties of the liquid. Equally known are the industrial applications of the rotating cones as pumps, degassing devices, level controllers, such as described by Henderson, M.H., Hollow Cone Degassing, US Patent Application 2011/0219853 Al, Sep. 15, 2011.
[0004] Commercially available mixing devices operate on the physics of the rotating cones. For instance, in US Patent 3170638 and US Patent 3170639 by Burton, L., a Mixing and Disintegration Head is described. The patents describe a double-cone geometry, where both cones are hollow bodies; that is, the liquid is accelerated on both faces of the hollow cone, the outer face and the inner face. One embodiment discloses a distance piece (i.e. a cage) interposed between the large bases of the two cones, which features elongated openings extending the height of the piece. In another embodiment, there is a flat disc interposed between the large bases of the two cones; the periphery of the disc may be slotted or formed with a plurality of extended teeth; or even the teeth may be serrated in the nature of a rotary saw blade. And then there is another embodiment in which vanes pitched at an angle are installed inside the hollow cones to increases the pumping capacity of the device.
[0005] From the point of view of pumping capability, the rotating double-cone devices currently offered on the market have limitations in terms of the particulate size that can pass through the hollow cones; particulates entrained along the outer face of the cones are not limited by the size.
[0006] In US Patent 5407271 by Jorgensen, P.J. et al, an Integrated Rotary Mixer and Disperser Head is described. It has a rotating mixing chamber of cylindrical geometry fitted with impeller blades that have ends located outside the mixing chamber to direct the liquid into the mixing chamber and out through some vertical elongated openings made in the wall of the mixing chamber. Similarly, in US Patent Application 2002/0118597 Al by Korstvedt, H.O., a Mixing Head with axial flow is disclosed. It has a rotating mixing screen of cylindrical geometry that can be fitted with a variety of feeding elements installed at the ends of the screen; these feeding elements may be of different shapes, including flat and conical. The feeding elements include a plurality of openings formed at acute angles relative to the longitudinal axis such that, when rotated, the feeding elements induce liquid flow in an axial direction, inside the rotating screen. The mixing devices described by the Jorgensen and Korstvedt patents feature entirely internal flow, incompatible with handling of particulates. In fact, these devices are tools mostly intended for comminution or micronization; instead of pumping alone.
[0007] Accordingly, there exists a need for a double-cone pumping device that is designed to provide for flow of the liquid product, and making them compatible with mixing of particulate-containing liquid products. Further, there is a need for a double- cone pumping device with large pumping action in mixing-agitation, instead of specific comminution-micronization action. It is therefore an object of the invention to provide a double-cone pumping device aimed at solving these problems, or to at least provide a useful alternative which addresses these needs.
SUMMARY
[0008] In a first aspect, the invention relates to double-cone pumping device, comprising two cones that are axially symmetrically arranged with their large bases abutting, and rotatable around the axis, and an axial shaft that connects to driving means. In a particular preferred design the double-cone pumping device comprises a flat disc and at least two rotating vanes and wherein the two cones are arranged so that their large bases lay on the opposite faces of the flat disc; and the vanes are located symmetrically onto the opposite sides of the flat disc; the flat disc and the vanes are rotatable with the two cones. It has been found that this design can generate a surprisingly large pumping action when rotating inside of a processing vessel.
[0009] In a second aspect, the invention relates to a use of the double-cone pumping device for processing liquid food.
[0010] The double-cone pumping device in this invention both allows pumping of fluids containing particulates of any size while ensuring a large pumping capacity. In a preferred embodiment, the double-cone pumping device is preferably made of two rotating cones that are substantially full bodies (as opposed to hollow). The rotating cones are preferably directly connected to a rotating disc that additionally displays rotating vanes on each one of its sides, in order to enhance the pumping capacity of the device.
[0011] In another embodiment, while substantially preserving the external flow feature of the double-cone pumping device, the combined physical body made of the two cones can be empty or can have an internal closed cavity, in order to reduce the total weight of the device. This does not change any of the external geometry of the double-cone pumping device, while the flow remains strictly external, and particulate- containing liquid products can be processed.
[0012] These and additional features and advantages are described herein, and will be apparent from the following Figures and Detailed Description of the device in this invention. The description of the invention in relation to the drawings is not intended to limit the invention. BRIEF DESCRIPTION OF THE FIGURES
[0013] FIG. 1 illustrates a full view of a double-cone pumping device in accordance with an embodiment of the invention.
[0014] FIG. 2 illustrates a geometry of a double-cone pumping device in accordance with an embodiment of the invention.
DETAILED DESCRIPTION
[0015] By comparison, the double-cone pumping device 1200 in Fig. 1 illustrates an embodiment of the invention both allows pumping of fluids containing particulates of any size and ensures a large pumping capacity. Pumping device 1200 is made of rotating cones 1220 that are full bodies (as opposed to hollow). Rotating cones 1220 are directly connected to a rotating disc 1230 that additionally displays rotating vanes 1240 on each one of its sides. Unlike rotating double-cone devices (featuring hollow cones) on the market, which are mainly intended for comminution or micronization, the pumping device 1200 is solely designed for an efficient pumping that generates a strong internal motion inside a processing vessel.
[0016] Referenced to the state-of-the-art, there are four major points of differentiation characterizing the pumping device in Fig. 1 : First, rotating cones 1220 are full physical bodies. Second, rotating cones are directly connected to a rotating disc 1230. Third, rotating disc 1230 displays rotating vanes 1240 or blades on each side of the rotating disc. And fourth, as a result, the flow induced by the pumping device 1200 is entirely external to the rotating device, allowing for handling of particulates of any size. The two cones and the flat disc may be separate part or made out of one piece.
[0017] In another embodiment, while entirely preserving the external flow feature of the double-cone pumping device 1200, the combined physical body made of the two cones can be empty or can have an internal closed cavity, in order to reduce the total weight of the device. This does not change any of the external geometry of the double-cone pumping device, while the flow remains strictly on the outside of the device.
[0018] In yet another embodiment, the vanes on the rotating flat disc 1230 extend entirely along the rotating cones 1220, in a spiral configuration, to further increase the pumping capacity of the double-cone pumping device. [0019] Fig. 2 is an illustration to the geometry of the double-cone pumping device, whereby the range within which the dimensions can vary is limited only by the intended purpose of the pumping device, the design power of the device, the mechanical resistance of construction materials, etc. In the particular example of Fig.2, the rotating cones have a large base diameter A and a small base diameter B; the rotating disc has a diameter C; and an overall height of the double-cone pumping device is D. It is preferred that A is in the range from 5 to 35 cm, B is from 1 to 15 cm, C is from 10 to 40 cm, and D is from 15 to 55 cm. In a particular preferred embodiment the A/B = 5, A/C = 0.5, and A/D = 0.4.
[0020] The double-cone pumping device is installed within a processing vessel by means of a shaft, eventually associated with driving means such as a gear box and a motor drive to transfer the torque from the motor to the pumping device. Furthermore, the motor drive can have a variable frequency drive to allow rotational speeds in the range from 10 RPM to thousands RPM. The location of the pump shaft can be axially in the processing vessel, or sidewise, coming from the top end of the processing vessel, from the bottom end of the processing, or from any side of the processing vessel.
[0021] Any reference to prior art documents in this specification is not to be considered an admission that such prior art is widely known or forms part of the common general knowledge in the field.
[0022] Although the invention has been described by way of example, it should be appreciated that variations and modifications may be made without departing from the scope of the invention as defined in the claims. Furthermore, where known equivalents exist to specific features, such equivalents are incorporated as if specifically referred in this specification.

Claims

CLAIMS The invention is claimed as follows:
1. A double-cone pumping device, comprising two cones that are axially symmetrically arranged with their large bases abutting, and rotatable around the axis, and an axial shaft that connects to driving means.
2. A double-cone pumping device according to Claim 1, wherein the double-cone pumping device further comprises a flat disc and at least two rotating vanes and wherein the two cones are arranged so that their large bases lay on the opposite faces of the flat disc; and the vanes are located symmetrically onto the opposite sides of the flat disc; the flat disc and the vanes are rotatable with the two cones.
3. A double-cone pumping device according to Claims 1 or 2, wherein the physical body made of the combined two cones can be empty or can have an internal closed cavity.
4. A double-cone pumping device according to any of Claims 1 to 3, wherein the physical body of the cones are substantially full bodies.
5. A double-cone pumping device according to any of Claims 1 to 4, wherein the flat disc features a plurality of vanes located symmetrically on the opposite faces of the flat disc.
6. A double-cone pumping device according to any of Claims 1 to 5, wherein the vanes on the flat disc extend entirely along the rotating cones, in a spiral configuration.
7. A double-cone pumping device according to any of Claims 1 to 6, wherein the two cones and the flat disc are made out of one piece.
8. Use of a double-cone pumping device according to any of the preceding claims for the processing of liquid food.
PCT/EP2013/063478 2012-06-29 2013-06-27 Double-cone pumping device WO2014001436A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP13732150.1A EP2866924B1 (en) 2012-06-29 2013-06-27 Double-cone pumping device
CA2875639A CA2875639A1 (en) 2012-06-29 2013-06-27 Double cone pumping device
CN201380033451.9A CN104379246B (en) 2012-06-29 2013-06-27 Double-cone type pumping installations
ES13732150.1T ES2600484T3 (en) 2012-06-29 2013-06-27 Double cone pumping device
US14/407,149 US9744504B2 (en) 2012-06-29 2013-06-27 Double-cone pumping device

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261666176P 2012-06-29 2012-06-29
US61/666,176 2012-06-29

Publications (1)

Publication Number Publication Date
WO2014001436A1 true WO2014001436A1 (en) 2014-01-03

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2013/063478 WO2014001436A1 (en) 2012-06-29 2013-06-27 Double-cone pumping device

Country Status (7)

Country Link
US (1) US9744504B2 (en)
EP (1) EP2866924B1 (en)
CN (1) CN104379246B (en)
CA (1) CA2875639A1 (en)
ES (1) ES2600484T3 (en)
PT (1) PT2866924T (en)
WO (1) WO2014001436A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107126902A (en) * 2016-02-26 2017-09-05 上海弗鲁克科技发展有限公司 Universal mixer

Citations (8)

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US3170638A (en) 1963-04-12 1965-02-23 Linwood P Burton Mixing and disintegrating head
US3170639A (en) 1963-04-12 1965-02-23 Linwood P Burton Mixing and disintegrating head
JPS5567318A (en) * 1978-11-14 1980-05-21 Kaoru Aoki Contact apparatus for gas and liquid
US4938899A (en) * 1988-09-30 1990-07-03 Oros Leo J Gas diffusion system
US5407271A (en) 1993-10-07 1995-04-18 Jorgen Jorgensen Maskinfabrik A/S Integrated rotary mixer and disperser head
US20020118597A1 (en) 2000-10-30 2002-08-29 Silverson Machines Inc. Mixing head with axial flow
KR20090061616A (en) * 2009-05-18 2009-06-16 주식회사 그린기술산업 Mixer with a double conical impeller
US20110219853A1 (en) 2008-12-01 2011-09-15 Matthew Hay Henderson Hollow Cone Degassing

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US3252690A (en) * 1964-06-15 1966-05-24 Warner J Cooper Liquid mixing device
US4720360A (en) * 1986-02-10 1988-01-19 Enviroquip, Inc. Diffused aeration system
CN2473365Y (en) * 2001-04-02 2002-01-23 江庆元 New structure of motor blade group
CN201288694Y (en) * 2008-10-07 2009-08-12 石家庄工业水泵有限公司 Highly efficient slurry pump
JP5378857B2 (en) * 2009-03-27 2013-12-25 株式会社山田製作所 Manufacturing method of closed impeller
JP5567318B2 (en) 2009-11-20 2014-08-06 株式会社国際電気セミコンダクターサービス Power supply system, substrate processing apparatus, semiconductor manufacturing apparatus, and deterioration diagnosis method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3170638A (en) 1963-04-12 1965-02-23 Linwood P Burton Mixing and disintegrating head
US3170639A (en) 1963-04-12 1965-02-23 Linwood P Burton Mixing and disintegrating head
JPS5567318A (en) * 1978-11-14 1980-05-21 Kaoru Aoki Contact apparatus for gas and liquid
US4938899A (en) * 1988-09-30 1990-07-03 Oros Leo J Gas diffusion system
US5407271A (en) 1993-10-07 1995-04-18 Jorgen Jorgensen Maskinfabrik A/S Integrated rotary mixer and disperser head
US20020118597A1 (en) 2000-10-30 2002-08-29 Silverson Machines Inc. Mixing head with axial flow
US20110219853A1 (en) 2008-12-01 2011-09-15 Matthew Hay Henderson Hollow Cone Degassing
KR20090061616A (en) * 2009-05-18 2009-06-16 주식회사 그린기술산업 Mixer with a double conical impeller

Non-Patent Citations (1)

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Title
BRUIN, S.: "Velocity Distribution in a Liquid Film Flowing over a Rotating Conical Surface", CHEMICAL ENGINEERING SCIENCE, vol. 24, 1969, pages 1647 - 1654

Also Published As

Publication number Publication date
US20150174538A1 (en) 2015-06-25
CA2875639A1 (en) 2014-01-03
EP2866924A1 (en) 2015-05-06
ES2600484T3 (en) 2017-02-09
US9744504B2 (en) 2017-08-29
EP2866924B1 (en) 2016-08-24
CN104379246B (en) 2016-09-07
CN104379246A (en) 2015-02-25
PT2866924T (en) 2016-11-29

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