WO2013185197A2 - Bronzina para motores de combustão interna - Google Patents
Bronzina para motores de combustão interna Download PDFInfo
- Publication number
- WO2013185197A2 WO2013185197A2 PCT/BR2013/000208 BR2013000208W WO2013185197A2 WO 2013185197 A2 WO2013185197 A2 WO 2013185197A2 BR 2013000208 W BR2013000208 W BR 2013000208W WO 2013185197 A2 WO2013185197 A2 WO 2013185197A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- bearing
- bronzine
- mpa
- sliding layer
- Prior art date
Links
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
- F16C33/20—Sliding surface consisting mainly of plastics
- F16C33/203—Multilayer structures, e.g. sleeves comprising a plastic lining
- F16C33/206—Multilayer structures, e.g. sleeves comprising a plastic lining with three layers
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/024—Deposition of sublayers, e.g. to promote adhesion of the coating
- C23C14/025—Metallic sublayers
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
- C23C14/165—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon by cathodic sputtering
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/584—Non-reactive treatment
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
- F16C33/20—Sliding surface consisting mainly of plastics
- F16C33/201—Composition of the plastic
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
- F16C33/20—Sliding surface consisting mainly of plastics
- F16C33/203—Multilayer structures, e.g. sleeves comprising a plastic lining
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2204/00—Metallic materials; Alloys
- F16C2204/10—Alloys based on copper
- F16C2204/12—Alloys based on copper with tin as the next major constituent
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2204/00—Metallic materials; Alloys
- F16C2204/20—Alloys based on aluminium
- F16C2204/22—Alloys based on aluminium with tin as the next major constituent
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2208/00—Plastics; Synthetic resins, e.g. rubbers
- F16C2208/02—Plastics; Synthetic resins, e.g. rubbers comprising fillers, fibres
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2208/00—Plastics; Synthetic resins, e.g. rubbers
- F16C2208/20—Thermoplastic resins
- F16C2208/58—Several materials as provided for in F16C2208/30 - F16C2208/54 mentioned as option
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2240/00—Specified values or numerical ranges of parameters; Relations between them
- F16C2240/40—Linear dimensions, e.g. length, radius, thickness, gap
- F16C2240/48—Particle sizes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2240/00—Specified values or numerical ranges of parameters; Relations between them
- F16C2240/40—Linear dimensions, e.g. length, radius, thickness, gap
- F16C2240/60—Thickness, e.g. thickness of coatings
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2326/00—Articles relating to transporting
- F16C2326/01—Parts of vehicles in general
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2360/00—Engines or pumps
- F16C2360/22—Internal combustion engines
Definitions
- the present invention relates to an internal combustion engine bearing, which is provided with a polymeric sliding layer to increase its longevity when working under high pressures and low lubrication conditions.
- the present invention relates to a bearing comprising a polymer wherein a ferrous base material is coated with a bronze alloy layer onto which a sputtering layer is deposited which in turn receives a layer of sputtering.
- the polymeric slider is provided, among other elements, with a soft metal alloy, the primary layer and the sputtering layer being joined by means of a bonding layer.
- the layered construction generally comprises sturdy base material such as steel coated with a soft metal alloy and at least one sliding layer which will maintain contact with the lubricating oil film. These layers are generally applied by a coating of a bearing material first adhered to the support and at least one additional layer of a bearing material adhered to the surface of the first bearing material. The outer surface of this latter rolling material forms the actual sliding surface that interacts with the shaft.
- the importance of layers is not restricted solely to the sliding layer.
- the function of the layers is rather found by the interaction between them, each having a specific role in the performance of the bearing, as well as a function with the adjacent layer.
- the bearings are usually provided with more than one layer for longevity.
- the applied layer on the base material aims to provide tack resistance and also to perform with reasonable performance as a sliding layer.
- the primary layer performs poorly both in accommodating minor misalignments between the bearing surfaces and the shaft surface, as well as in the ability to accommodate the particles present in the oil film that would cause scratching or scuffing. surfaces.
- One such solution may be exemplified by depositing aluminum and tin through the sputter process on a primary layer of bronzine material.
- Such bearings have as main feature the advantage of supporting high load capacity.
- the drawback is that the deposited layer has low sensitivity to large variations or discontinuities in the oil film, resulting in potential bearing degradation and compromising long-term performance, impairing engine operation, or even failure. .
- GB 2465852 describes a sliding polymeric layer for improving the performance of a bearing / bearing for use in an engine operating under heavy working conditions.
- the described polymeric layer contains friction reducing additives, consisting of a matrix containing 5% to 15% by volume of metal powder, preferably selected from a group containing aluminum, silver copper, tungsten and stainless steel; 1% to 15% by volume of fluoropolymer, preferably PTFE or FEP, the remainder being a polyamide imide resin.
- the chemical configuration of the polymer is not designed to last for the life of the bearing.
- the objective is that this polymeric layer will wear out during the first hours of operation, so that molybdenum disulphate releases from the polymer to be embedded in the deposited layer.
- the bearing described herein has a constructive configuration equivalent to those of the state of the art, ie it behaves like a bearing whose main performance element is its durability. the sliding layer of sputtering. As a result, this bearing cannot guarantee high carrying capacity, although it has good tack resistance.
- the carrying capacity value of a bearing having a sliding sputter layer usually ranges from 100 MPa to 120 MPa, with the usual gripping load being in the range of 50 MPa to 60 MPa.
- polymer bimetallic bearings can reach values in the range of 85 MPa to 90 MPa, however, the usual loading capacity is about 70 MPa to 80 MPa.
- an internal combustion engine bearing the bearing being provided with a ferrous base material onto which a primary layer of a bronze alloy and a deposited layer are applied sequentially, and over the A sliding layer is applied to the deposited layer comprising a polyamide-imide polymeric matrix provided with a soft metal, a fluoropolymer and a silane-based material, the bronzine being capable of withstanding a tackle load greater than 85 MPa.
- Figure 1 is a representation of the tanning layers of the present invention
- Figure 2 is a photograph of the bearing layers of the present invention.
- Figure 3 is a comparative graph of the prior art bearing with the bearing of the present invention.
- Figure 4 is a comparative photograph of the prior art bearing with the bearing of the present invention following a 1000 hour motor test.
- Figures 1 and 2 represent a cross-sectional view of a bearing of the present invention.
- the bearing 1 of the present invention is comprised of a ferrous base material 10 onto which a primary layer 2 of a bronze alloy is applied.
- the primary layer 2 further receives a sputtering deposited layer 4 which in turn receives a sliding layer 5 comprising a Polyamide-imide polymer matrix containing having a soft metal, a fluoropolymer and a silane based material.
- the bearing 1 is provided with a binding layer 3 which is applied over the primary layer 2, the binding layer 3 aims to promote a better association between the primary layer 2 and the deposited layer 4.
- the base material 10 is comprised of a ferrous alloy, preferably a low or medium carbon steel having a thickness between 1mm and 5mm.
- the primary layer 2 its composition is preferably 4% to 8% tin, 1% to 4% bismuth, 1% to 3% nickel with the remainder being copper.
- the copper alloy has a thickness between 150 to 400 microns. Note that this primary layer 2 may or may not contain lead.
- Binding layer 3 where present, is comprised of nickel and chromium having a thickness of between 1 and 5 microns.
- Sputtering deposited layer 4 comprises 1% to 40% tin, 1% silicon, 1% copper, 2% iron, the remainder being aluminum.
- the thickness of the deposited layer 4 ranges from 3 to 20 microns.
- the invention relates to depositing this polymeric sliding layer 5 onto a deposited layer 4 by sputtering. More specifically, the polymeric sliding layer 5 comprises a polymeric polyimideimide matrix having a soft metal, a fluoropolymer and a silane based material.
- sliding layer 5 has a concentration of 1 to 14% by volume of soft metal (in the form of powder or flakes), more preferably 11 to 14%, with an ideal concentration of 12.5%.
- Soft metal can be chosen from aluminum, copper, copper, silver, tungsten, and stainless alloys.
- the sliding layer comprises an aluminum powder with particles of less than 5 microns.
- the shape of the metal may be worked to result in a maximum area of less than better orientation of the soft metal in the polymer matrix and, consequently, a better particle absorption performance present in the thin oil film.
- sliding layer 5 has a concentration of 2 to 8% by volume of fluoropolymer.
- fluoropolymer may be chosen from polytetrafluoroethylene and fluorinated ethylene propylene, preferably the sliding layer fluoropolymer 5 is polytetrafluoroethylene (PTFE) whose amount is 5.7%. Note that the use of this fluoropolymer reduces the friction coefficient of the bearing and improves its lubricating properties.
- the polymeric matrix consisting of sliding layer 5 also contains a silane material. These materials promote matrix stability and promote adhesion of the material to the deposited layer 4 by sputtering.
- the silane material may be chosen from gamma-aminopropyltriethoxysilane or bis (gamma-trimethoxysilylpropyl) amine, preferably the silane material is of gamma-aminopropyltriethoxysilane.
- the sliding layer preferably has a concentration of 3 to 6% by volume of a material or mixture of silane materials, preferably being 4.8%.
- the polymeric matrix of the sliding layer 5 further comprises less than 0.1% of other elements, the remainder being polyimideimide, which will usually result in an amount of 77%.
- the thickness of the sliding layer 5 is from 5 to 20 microns, preferably from 7 to 20 microns.
- the novel concept of the present invention is the combined association of a deposited layer 4 by sputtering with a polymer matrix slip layer 5.
- the intention was to reconcile the best properties of each solution.
- the deposited layer 4 would guarantee good wear resistance and good loadability and, on the other hand, that the polymeric sliding layer 5 offers good clamping resistance. It would thus be expected that at best achieve a combination of the values found in the prior art, that is, achieve a bearing 1 having a loading capacity value of 120 MPa and a value for the tackling load of 85 MPa or greater.
- the constructive configuration of the present invention exceeded the initial expectation, completely justifying the new bearing 1 in terms of cost.
- the cost of a bearing 1 of the present invention is higher than those using only part of its layers.
- bronzine 1 of the present invention would be commercially unviable.
- the excellent tribological results achieved guarantee the longevity of a much higher than normal internal combustion engine, including those of the most modern engines with considerably higher demands.
- the result achieved by bearing 1 of the present invention is so superior to those of the prior art that it is anticipated to be a commercial success for being able to drive an engine beyond current limits and for longer even under poorly lubricated conditions.
- the state of the art notably the Miba patent, clearly states that soft metals should not be used in the polymeric layer as it decomposes, and will transfer these fine metal particulates to the oil and therefore a potential risk of bronzin, ie premature wear.
- the principle of the present invention has a distinct criterion in requiring the presence of a soft metal in the composition of the polymeric sliding layer 5.
- the constructive configuration of the bearing 1 of the present invention works so that the deposited layer 4 is able to absorb part of these harmful impacts. This effect comes from the fact that its chemical composition is also endowed with soft metals. Thus, the deposited layers 4 and sliding 5 work together, providing greater difficulty for bearing 1 to wear out.
- the bearing 1 of the present invention achieved a material index of more than 40% higher than the best values in the prior art, thus evidencing its notable advantage.
- This exam was performed using a heavy diesel engine.
- the applied capacity load was 85 MPa.
- Figure 3 represents a test performed between a bearing of the present invention and another of the prior art.
- the bronzine 1 disclosed in this invention has gone through all the steps without scraping on the bronzine.
- a prior art bearing failed four of the five tests, where three of the failures occurred early in the first stage. Of course this is a considerable difference at the very least.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Sliding-Contact Bearings (AREA)
- Shafts, Cranks, Connecting Bars, And Related Bearings (AREA)
- Physical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13742375.2A EP2863081B1 (en) | 2012-06-13 | 2013-06-12 | Bearing bushing for internal combustion engines |
US14/407,570 US9212696B2 (en) | 2012-06-13 | 2013-06-12 | Bearing for an internal combustion engine |
JP2015516387A JP6046809B2 (ja) | 2012-06-13 | 2013-06-12 | 内燃機関用ベアリング |
CN201380032338.9A CN104603483B (zh) | 2012-06-13 | 2013-06-12 | 用于内燃机的轴承 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRBR102012014337-2 | 2012-06-13 | ||
BR102012014337A BR102012014337A2 (pt) | 2012-06-13 | 2012-06-13 | bronzina para motores de combustão interna |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2013185197A2 true WO2013185197A2 (pt) | 2013-12-19 |
WO2013185197A3 WO2013185197A3 (pt) | 2014-02-27 |
Family
ID=48900712
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/BR2013/000208 WO2013185197A2 (pt) | 2012-06-13 | 2013-06-12 | Bronzina para motores de combustão interna |
Country Status (6)
Country | Link |
---|---|
US (1) | US9212696B2 (pt) |
EP (1) | EP2863081B1 (pt) |
JP (1) | JP6046809B2 (pt) |
CN (1) | CN104603483B (pt) |
BR (1) | BR102012014337A2 (pt) |
WO (1) | WO2013185197A2 (pt) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE112015003625T5 (de) * | 2014-08-05 | 2017-05-04 | Mahle International Gmbh | Lager für Verbrennungsmotoren und Verbrennungsmotor, Prozess und Verfahren zur Herstellung davon |
RU2671779C1 (ru) * | 2018-01-31 | 2018-11-06 | Туманов Александр Викторович | Способ нанесения антифрикционного слоя (варианты) |
CN110894856A (zh) * | 2019-09-29 | 2020-03-20 | 浙江中达精密部件股份有限公司 | 一种具有聚酰亚胺滑动层的滑动轴承 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7541086B2 (en) | 2005-09-16 | 2009-06-02 | Miba Gleitlager Gmbh | Bearing element |
GB2465852A (en) | 2008-12-08 | 2010-06-09 | Mahle Engine Systems Uk Ltd | Plastics polymer-based bearing material |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH671239A5 (pt) * | 1986-07-15 | 1989-08-15 | Balzers Hochvakuum | |
WO2004092602A1 (ja) * | 2003-04-17 | 2004-10-28 | Daido Metal Company Ltd. | 摺動部材 |
DE102005045701A1 (de) * | 2005-09-20 | 2007-03-22 | Ks Gleitlager Gmbh | Gleitlagerverbundwerkstoff |
DE102008037871A1 (de) * | 2008-08-15 | 2010-02-25 | Amg Coating Technologies Gmbh | Gleitelement mit Mehrfachschicht |
MX2012007502A (es) * | 2009-12-31 | 2012-08-07 | Saint Gobain Performance Plast | Fuente de energia renovable que incluye una extructura de conversion de energia y un componente de cojinete. |
GB2496587A (en) | 2011-11-09 | 2013-05-22 | Mahle Int Gmbh | A sliding bearing comprising three layers of material |
FR2985215B1 (fr) * | 2011-12-28 | 2014-09-19 | Saint Gobain Performance Plast | Revetements polymeres deposes sur des substrats par des techniques de projection thermique |
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2012
- 2012-06-13 BR BR102012014337A patent/BR102012014337A2/pt not_active Application Discontinuation
-
2013
- 2013-06-12 EP EP13742375.2A patent/EP2863081B1/en not_active Not-in-force
- 2013-06-12 CN CN201380032338.9A patent/CN104603483B/zh active Active
- 2013-06-12 WO PCT/BR2013/000208 patent/WO2013185197A2/pt active Application Filing
- 2013-06-12 US US14/407,570 patent/US9212696B2/en not_active Expired - Fee Related
- 2013-06-12 JP JP2015516387A patent/JP6046809B2/ja not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7541086B2 (en) | 2005-09-16 | 2009-06-02 | Miba Gleitlager Gmbh | Bearing element |
GB2465852A (en) | 2008-12-08 | 2010-06-09 | Mahle Engine Systems Uk Ltd | Plastics polymer-based bearing material |
Also Published As
Publication number | Publication date |
---|---|
US20150139579A1 (en) | 2015-05-21 |
CN104603483A (zh) | 2015-05-06 |
EP2863081B1 (en) | 2016-11-23 |
EP2863081A2 (en) | 2015-04-22 |
JP6046809B2 (ja) | 2016-12-21 |
WO2013185197A3 (pt) | 2014-02-27 |
JP2015527535A (ja) | 2015-09-17 |
BR102012014337A2 (pt) | 2015-09-15 |
US9212696B2 (en) | 2015-12-15 |
CN104603483B (zh) | 2017-03-08 |
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