WO2013183213A1

WO2013183213A1 - Manufacturing method for piercing plug

Info

Publication number: WO2013183213A1
Application number: PCT/JP2013/002657
Authority: WO
Inventors: 建一斎藤; 日高　康善; 東田　泰斗
Original assignee: 新日鐵住金株式会社
Priority date: 2012-06-05
Filing date: 2013-04-19
Publication date: 2013-12-12
Also published as: CA2866802A1; MX2014012498A; RU2014153911A; CA2866802C; AR091250A1; US20150184276A1; CN104364413B; EP2857545A1; EP2857545B1; CN104364413A; RU2598414C2; EP2857545A4

Abstract

This manufacturing method for a piercing plug used in a piercing mill for manufacturing a seamless steel pipe includes a shot blasting step wherein shot blasting is applied to the plug surface and an arc spraying step wherein a thermal spraying wire is arc-sprayed onto the surface of base material of the shot-blasted plug in order to form a coating thereon. In the arc spraying step, the arc spraying is carried out by using a cored wire (1), which is produced by filling an iron tube (2) with iron particles (4) and at least low-thermal-conductivity material particles (3) that are selected from among low-thermal-conductivity material particles (3) having lower thermal conductivity characteristics than that of iron oxide(for example, ZrO₂ particles), in order to form a coating comprising iron oxide, Fe, and the low-thermal-conductivity material. Because a coating with high heat-insulating performance can be formed, a plug that allows the plug life to be improved for the piercing process can be manufactured.

Description

Manufacturing method of piercing and rolling plug

The present invention relates to a method for producing a piercing and rolling plug (hereinafter also simply referred to as “plug”) used in a piercing and rolling machine (hereinafter also simply referred to as “piercing machine”) used for the production of seamless steel pipes. In particular, the present invention relates to a method for manufacturing a piercing-rolling plug in which a coating is formed by arc spraying a thermal spray wire mainly composed of iron on the surface of a plug base material.

The seamless steel pipe can be manufactured by the Mannesmann pipe manufacturing method. This pipe making process consists of the following steps:
(1) A material (round billet) heated to a predetermined temperature is pierced and rolled by a piercing machine, and formed into a hollow shell (hollow shell);
(2) The hollow shell is stretch-rolled by a stretching mill (eg, mandrel mill);
(3) Using a constant diameter rolling mill (eg, stretch reducer), the stretched hollow shell is constant-rolled to a predetermined outer diameter and thickness.

In piercing and rolling with a piercing machine, a plug is used as a piercing tool. This plug is attached to the end of the core metal and pierces the billet heated to a high temperature of about 1200 ° C., so that it is exposed to a severe situation where high surface pressure is applied with high heat. Generally, a plug uses hot tool steel as a base material, and in order to protect the base material, an oxide scale film is previously formed on the surface of the base material by heat treatment, and then used for piercing and rolling. During piercing and rolling, the scale film on the plug surface plays a role of blocking heat transfer from the billet to the plug base material and preventing seizure between the billet and the plug.

Such a plug with a scale coating is gradually worn with repeated piercing and rolling. When the scale coating is worn, the heat shielding effect by the coating is reduced, so that the temperature of the plug rises during drilling, and the plug base material is easily melted and thermally deformed. Further, when the scale film disappears and the plug base material comes into direct contact with the billet, seizure occurs and wrinkles are generated on the inner surface of the steel pipe. For this reason, the plug becomes unusable at the time when the film is lost, and the life is reached.

In particular, when manufacturing seamless steel pipes made of high-Cr steels containing 9% or more of Cr, high-alloy steels such as Ni-base alloys and stainless steels, wear of the scale coating on the plug surface is noticeable during piercing and rolling. , Plug life is significantly reduced. For example, in the drilling of stainless steel, the scale film on the plug surface is worn in a few passes (number of continuous drilling), and the plug reaches the end of its life. For this reason, the situation where a plug is frequently replaced arises and the manufacturing efficiency of a steel pipe is low. Therefore, particularly when producing a seamless steel pipe of high alloy steel, it is required to improve the plug life during piercing and rolling, thereby increasing the production efficiency of the steel pipe.

In response to such a request, for example, in Patent Document 1, instead of a scale film formed by heat treatment as a film to be formed on the surface of the plug base material, an iron wire is arc sprayed on the surface of the plug base material and Fe oxide and A plug in which a film composed of Fe is formed is disclosed. This plug with arc sprayed coating is expected to improve the plug life because the coating on the plug surface is composed of Fe oxide and Fe, and is excellent in heat shielding properties and anti-seizure properties.

However, even the plug with an arc sprayed coating disclosed in the same document cannot be denied that if the piercing and rolling are repeated, wrinkles are generated in the coating due to repeated heat input, and the life is reached. In addition, if the time for piercing and rolling becomes longer, the load on the plug increases, and peeling of the film and wrinkling of the film occur, so that it cannot be denied that the service life is reached. These situations remarkably occur when the perforation length of the billet is long or when the billet has a high temperature strength. Here, in order to suppress the generation of wrinkles in the arc sprayed coating, it is effective to increase the thickness of the coating and improve the heat shielding property of the coating. However, if the coating is increased in thickness, the adhesion between the plug base material and the coating is effective. And the film peels off early. For this reason, there is room for improvement in terms of stably improving the plug life, and it is strongly required to produce a piercing-rolling plug that can improve this point.

Japanese Patent No. 4279350

The present invention has been made in view of the above problems, and presupposes that a coating is formed by arc spraying a thermal sprayed wire mainly composed of iron on the surface of a plug base material. It is to provide a method of manufacturing a piercing-rolling plug having properties:
The plug life can be improved stably.

The gist of the present invention is as follows.

A method of manufacturing a plug used in a piercing and rolling machine used for manufacturing a seamless steel pipe,
The manufacturing method of the piercing and rolling plug is as follows:
A shot blasting process for performing shot blasting on the surface of the plug;
An arc spraying step in which a sprayed wire is arc sprayed on the surface of the base material of the plug subjected to shot blasting to form a coating, and
In the arc spraying process, arc spraying is performed by using a cored wire in which at least a specific particle is filled in an iron tube among the iron particles and the specific particles contributing to the improvement of the plug life as a thermal spray wire, and iron oxide Forming a film composed of Fe and specific particles;
A manufacturing method of a plug for piercing and rolling characterized by the above.

In this manufacturing method, it is preferable that the specific particles are low thermal conductive material particles having characteristics of lower thermal conductivity than iron oxide. In this case, it is preferable that the low thermal conductive material particles are ZrO ₂ particles, it is preferable proportion in the cored wire of the ZrO ₂ particles is from 2.5 to 30.0% by volume.

In this manufacturing method, the specific particles are preferably solid lubricant particles. In this case, the solid lubricant particles are preferably BN particles, and the proportion of the BN particles in the cored wire is preferably 5.0 to 20.0% by volume.

The method for manufacturing a plug for piercing and rolling of the present invention has the following remarkable effects:
The plug life can be improved stably.

FIG. 1 is a cross-sectional view of a thermal spray wire used for arc spraying in the method for manufacturing a piercing-rolling plug according to the first embodiment of the present invention. FIG. 2 is a cross-sectional view of a thermal spray wire used for arc spraying in the method for manufacturing a piercing-rolling plug according to the second embodiment of the present invention. FIG. 3 is a diagram summarizing the relationship between the proportion of ZrO ₂ particles in the cored wire and the amount of deformation of the plug base material as the test results of Example 1. FIG. 4 is a graph summarizing the relationship between the proportion of BN particles in the cored wire and the plug life ratio as the test results of Example 2.

In order to achieve the above-mentioned object, the present inventor presupposes that a coating is formed by arc spraying a thermal spray wire mainly composed of iron on the surface of a plug base material, and various tests are conducted on the method of forming the coating. And conducted intensive studies. As a result, the following knowledge was obtained.

In arc spraying, for example, an arc is generated between the ends of two sprayed wires that serve as electrodes to melt the sprayed wire, and at the same time, a jet of compressed air, nitrogen gas, or the like is supplied between the ends of the sprayed wire to melt the material. This is a technique for forming a film by blowing a molten material onto an object. In the arc spraying disclosed in Patent Document 1, since an iron wire is used as the spray wire, the coating formed on the base material surface of the plug is composed of Fe oxide (iron oxide) and Fe. The Fe oxide in the coating is generated by the oxidation during the flight until the iron wire melts and the molten iron reaches the plug base metal surface during arc spraying. Fe in the film is the molten iron that has reached the plug base metal surface without being oxidized during flight.

(1) On the other hand, as a thermal spray wire, an iron tube of the same quality as an iron wire is used as an outer shell, and the iron tube is filled with low thermal conductive material particles having a lower thermal conductivity than iron oxide. Depending on the case, if a cored wire filled with iron particles is used and arc spraying is performed using this cored wire, the surface of the plug base material is composed of Fe oxide (iron oxide), Fe and a low thermal conductive material. A film can be formed. During the arc spraying, the iron oxide in the coating is oxidized during the flight until the iron tube constituting the cored wire and the iron particles are melted and the molten iron reaches the plug base metal surface. Generated. Fe in the film is the molten iron that has reached the plug base metal surface without being oxidized during flight. Further, the low thermal conductive material in the coating is a material in which the low thermal conductive particles constituting the cored wire reach the plug base material surface.

The coating formed by arc spraying using the cored wire in this way includes a low thermal conductive material having a lower thermal conductivity than Fe oxide, which is based on the low thermal conductive material particles constituting the cored wire. Even if it is not, the heat shielding property is increased. Therefore, such a plug with an arc sprayed coating has a high thermal barrier property during repeated piercing and rolling, so that the plug life is stably improved. That is, the low thermal conductive material particles are specific particles that contribute to the improvement of the plug life.

(2) As a thermal spray wire, an iron tube of the same quality as an iron wire is used as an outer shell, and a cored wire in which solid lubricant particles are filled in the iron tube and in some cases further filled with iron particles is adopted. When arc spraying is performed using a cored wire, a film composed of Fe oxide (iron oxide), Fe and a solid lubricant can be formed on the surface of the plug base material. During the arc spraying, the iron oxide in the coating is oxidized during the flight until the iron tube constituting the cored wire and the iron particles are melted and the molten iron reaches the plug base metal surface. Generated. Fe in the film is the molten iron that has reached the plug base metal surface without being oxidized during flight. Further, the solid lubricant in the film is one in which the solid lubricant particles constituting the cored wire reach the plug base material surface.

Since the coating formed by arc spraying using the cored wire in this manner contains a solid lubricant based on solid lubricant particles constituting the cored wire, the lubricity becomes high during piercing and rolling. Therefore, such a plug with an arc sprayed coating has a high lubricity of the coating during repeated piercing and rolling, so that the plug life is stably improved. That is, the solid lubricant particles are specific particles that contribute to the improvement of the plug life.

The present invention has been completed based on the findings shown in the above (1) and (2). Below, the preferable aspect of the manufacturing method of the plug of this invention is demonstrated.

<First Embodiment>
In the plug manufacturing method of the first embodiment of the present invention, shot blasting is performed on the surface of the plug prior to arc spraying. As a result, in the case where a plug that is repeatedly used for piercing and rolling and regenerated after reaching the end of its life is targeted, the piercing-rolled film remaining on the plug surface is removed and the base material surface of the plug is exposed. At the same time, the surface of the plug base material is roughened to moderate irregularities. Further, even when a newly manufactured plug is targeted, the surface of the plug base material is roughened to an appropriate unevenness. The reason why the shot blasting is performed in this way is that the adhesiveness between the plug base material and the coating is enhanced if arc spraying is performed on the surface of the plug base material having an appropriate unevenness without any remaining coating.

Subsequently, in the plug manufacturing method of the first embodiment, arc coating is performed on the base material surface of the plug subjected to shot blasting using a cored wire mainly composed of iron as a thermal spray wire to form a coating.

FIG. 1 is a cross-sectional view of a thermal spray wire used for arc spraying in the method for manufacturing a piercing-rolling plug according to the first embodiment of the present invention. As shown in the figure, in the first embodiment, a cored wire 1 is used as a thermal spray wire. The cored wire 1 has an outer shell made of an iron tube 2.

The iron tube 2 is filled with low thermal conductive material particles 3. The low thermal conductive material particle 3 has a characteristic that the thermal conductivity is lower than that of iron oxide, and does not disappear by burning during arc spraying. For example, metal particles and ceramic particles are applicable. Among these, zirconia (ZrO ₂ ) particles having extremely low thermal conductivity are preferable. Further, the low thermal conductive material particles 3 are not limited to granular particles, but also include those in powder form or short fiber form. The iron oxide here is iron oxide (II) (FeO), iron oxide (III) (Fe ₂ O ₃ ), iron oxide (II, III) (Fe ₃ O ₄ ), or the like.

The iron tube 2 may be filled with iron particles 4 in addition to the low thermal conductive material particles 3. The iron particles 4 are not limited to particles, but also include particles and short fibers.

By arc spraying using the cored wire (thermal spray wire) 1 having such a configuration, a coating composed of Fe oxide (iron oxide), Fe, and a low thermal conductive material can be formed on the surface of the plug base material. . The plug with arc sprayed coating manufactured in this way contains a low thermal conductivity material whose thermal conductivity is lower than that of Fe oxide in the coating, so that even if it is not thickened, it has high thermal barrier properties during repeated piercing and rolling. The plug life can be improved stably.

Here, when ZrO ₂ particles are applied as the low thermal conductive material particles 3, the proportion of the ZrO ₂ particles in the entire cored wire 1 including the iron tube 2, the low thermal conductive material particles 3, and the iron particles 4 is 2. It is preferably 5 to 30.0% by volume. As demonstrated in Example 1 to be described later, when the proportion of ZrO ₂ particles is less than 2.5% by volume, the amount of ZrO ₂ contained in the plug film is insufficient, so that it is blocked during piercing and rolling. This is because the thermal property cannot be sufficiently improved and the deformation of the plug base material becomes remarkable, so that it is not suitable for reuse, and the plug life is not stably improved. On the other hand, if the proportion of ZrO ₂ particles exceeds 30.0% by volume, the amount of ZrO ₂ contained in the plug film becomes excessive, resulting in a decrease in the adhesion between the plug base material and the film. This is because the film is peeled off early and the plug base material is melted, which makes it unsuitable for reuse. More preferably, it is 5.0 to 30.0% by volume.

<Second Embodiment>
In the plug manufacturing method according to the second embodiment of the present invention, shot blasting is performed on the surface of the plug prior to arc spraying, as in the first embodiment. Subsequently, a coating is formed on the surface of the base material of the plug subjected to shot blasting by arc spraying using a cored wire mainly composed of iron as a thermal spray wire. However, the cored wire used in the second embodiment is different from the cored wire of the first embodiment in the following points.

FIG. 2 is a cross-sectional view of a thermal spray wire used for arc spraying in the method for manufacturing a piercing-rolling plug according to the second embodiment of the present invention. As shown in the figure, in the second embodiment, a cored wire 1 is used as a thermal spray wire. The cored wire 1 has an outer shell made of an iron tube 2.

The inside of the iron tube 2 is filled with solid lubricant particles 5. The solid lubricant particles 5 have a characteristic of functioning as a solid lubricant during piercing and rolling, and are not burned and disappear during arc spraying. For example, metal particles and ceramic particles are applicable. Among these, boron nitride (BN) particles having extremely excellent solid lubricity are preferable. Further, the solid lubricant particles 5 are not limited to granular particles but also include powdery or short fiber particles.

The iron tube 2 may be filled with iron particles 4 in addition to the solid lubricant particles 5. The iron particles 4 are not limited to particles, but also include particles and short fibers.

A film composed of Fe oxide (iron oxide), Fe, and a solid lubricant can be formed on the surface of the base metal of the plug by arc spraying using the cored wire (thermal spray wire) 1 having such a configuration. . Since the plug with the arc sprayed coating manufactured in this way contains a solid lubricant in the coating, the lubricity becomes high during repeated piercing and rolling, and the plug life can be stably improved.

Here, when BN particles are applied as the solid lubricant particles 5, the proportion of BN particles in the entire cored wire 1 including the iron tube 2, the solid lubricant particles 5, and the iron particles 4 is 5.0 to It is preferable that it is 20.0 volume%. As demonstrated in Example 2 described later, if the proportion of BN particles is less than 5.0% by volume, the amount of BN contained in the plug film is insufficient, and lubricity during piercing and rolling is reduced. This is because the plug life is not stably improved because it cannot be sufficiently improved and the drilling efficiency cannot be sufficiently improved. On the other hand, if the proportion of BN particles exceeds 20.0% by volume, the amount of BN contained in the plug film becomes excessive, and the adhesiveness between the plug base material and the film is lowered early. This is because the film peels off and the plug base material melts, so that it is not suitable for reuse, and the plug life is not stably improved. More preferably, it is 7.5 to 20.0% by volume.

In addition, the drilling efficiency here means the following. During piercing and rolling, the speed at which the billet is transported in the axial direction (hereinafter referred to as “transport speed”) is determined by the number of rotations of the piercer roll, but the actual transport speed is the friction between the plug and billet that are in contact with each other. Due to the influence of resistance and the like, it becomes slower than the theoretical transport speed calculated from the set rotation speed of the piercer roll. Usually, the speed ratio (= (actual transport speed) / (theoretical transport speed) × 100 [%]) is referred to as “drilling efficiency”. The piercing efficiency is an index of lubricity, and if this is high, not only the manufacturing efficiency of the piercing mill is increased, but also the plug contact life with the billet is shortened, so that the life of the plug can be extended.

Further, in the plug manufacturing method of the present invention, when the coating is formed by arc spraying, arc spraying is performed while moving the spraying machine gradually away from the surface of the plug base material so that the spraying distance gradually increases. Can do. As a result, a film in which the ratio of the region occupied by the Fe oxide (hereinafter referred to as “oxide ratio”) gradually increases toward the surface layer side is formed on the plug base material. As described above, when a film having a low oxide ratio in the adjacent part to the plug base material and a high oxide ratio in the surface layer part is formed, the plug base material is secured while ensuring heat insulation and anti-seizure property in the surface layer part of the film. This is useful in that the adhesion can be secured at the adjacent portion with the material.

In order to confirm the effect of the present invention, a piercing and rolling plug was manufactured, and a test was conducted in which the manufactured plug was mounted on a piercing machine and pierced and rolled. The test conditions are as follows.

<Example 1>
[Test method]
(1) Manufacture of plugs A number of shell-shaped plugs having a maximum diameter of 147 mm using hot tool steel specified by JIS as a base material were prepared. After subjecting the surface of each plug to shot blasting, a coating was formed on the surface of the base material of each plug by arc spraying using the cored wire shown in FIG. 1 to produce a plug with an arc spray coating. When forming the arc sprayed coating, the arc spraying from the sprayer to the plug base material surface was initially performed with an arc spraying of 200 mm, while the thermal spraying machine was gradually moved away, and finally the spraying distance was increased to 1000 mm and arc spraying was performed. .

At that time, ZrO ₂ particles were employed as the low thermal conductive particles in the cored wire, and the ratio of the ZrO ₂ particles was changed as shown in Table 1 below. Note that in an iron tube cored wire, depending on the proportion of the ZrO ₂ particles was filled with iron particles together with ZrO ₂ particles.

(2) Drilling and rolling Using the above plugs, the following workpiece (material) heated to about 1200 ° C. was repeatedly punched and rolled to produce the following hollow shell.
・ Dimensions of work material: Round billet with a diameter of 191 mm and a length of 2200 mm ・ Material of work material: 13% Cr steel ・ Hollow shell: Outer diameter: 196 mm, wall thickness: 16.82 mm, length: 6520 mm

[Evaluation methods]
After repeatedly piercing and rolling 10 times continuously for each plug, the appearance of the plug was inspected, and the surface property, that is, the presence or absence of erosion of the plug base material accompanying peeling of the film was investigated. In addition, the surface of the plug is shot blasted to remove the remaining coating, and then the height (axial length) of the plug base material is measured to determine the amount of deformation before use, that is, the plug base before and after use. The difference in material height was investigated. Here, in actual operation, the amount of deformation of the plug base material is controlled to 2.0 mm or less. This is because if the amount of deformation of the plug base material exceeds 2.0 mm, it is not suitable for reuse. From these, in this test, the case where the deformation amount of the plug base material was 2.0 mm or less was evaluated as good without the plug base material being melted.

[Test results]
The test results are shown in Table 1 and FIG. FIG. 3 is a diagram summarizing the relationship between the proportion of ZrO ₂ particles in the cored wire and the amount of deformation of the plug base material as the test results of Example 1. These results show the following.

When ZrO ₂ particles were employed as the low thermal conductive particles in the cored wire and an arc sprayed coating was formed using this cored wire, As in 2 to 6, by making the ZrO ₂ particles 2.5 volume% or more in the cored wire, the deformation amount of the plug base material was suppressed to 2.0 mm or less. This is because a proper amount of ZrO ₂ is contained in the plug film, so that the heat shielding property is enhanced. Therefore, a plug in which an arc sprayed coating is formed using a cored wire having 2.5% by volume or more of ZrO ₂ particles can stably improve the plug life and be suitable for reuse. all right.

However, test no. When the arc sprayed coating was formed using a cored wire in which ZrO ₂ particles exceeded 30.0% by volume as in 7 and 8, the coating peeled off early and the plug base material was melted. This is because the adhesion between the plug base material and the film is lowered although the heat shielding property is increased because ZrO ₂ is excessively contained in the film of the plug. From this, it was found that the improvement of the plug life is not stable in the plug in which the arc sprayed coating is formed using the cored wire in which ZrO ₂ particles exceed 30.0% by volume.

On the other hand, test no. 1, when an arc sprayed coating is formed using a 0% by volume cored wire with ZrO ₂ particles (corresponding to the case where an arc sprayed coating is formed using an iron wire as disclosed in Patent Document 1) ), The amount of deformation of the plug base material far exceeded 2.0 mm. This is because the heat shielding property is not improved because ZrO ₂ having a low thermal conductivity is not contained in the plug film. From this, it was found that the improvement in the plug life was not stable even in the plug in which the arc sprayed coating was formed using the cored wire having less than 2.5 volume% of ZrO ₂ particles.

<Example 2>
[Test method]
(1) Manufacture of plugs A number of shell-shaped plugs having a maximum diameter of 147 mm using hot tool steel specified by JIS as a base material were prepared. After the surface of each plug was shot blasted, a coating was formed on the surface of the base material of each plug by arc spraying using the cored wire shown in FIG. 2 to produce a plug with an arc spray coating. When forming the arc sprayed coating, the arc spraying from the sprayer to the plug base material surface was initially performed with an arc spraying of 200 mm, while the thermal spraying machine was gradually moved away, and finally the spraying distance was increased to 1000 mm and arc spraying was performed. .

At that time, BN particles were employed as the solid lubricant in the cored wire, and the ratio of the BN particles was changed as shown in Table 2 below. The iron tube of the cored wire was filled with iron particles together with BN particles according to the proportion of BN particles.

[Evaluation methods]
The piercing efficiency when piercing and rolling each plug was investigated. The drilling efficiency is set to 70% or more in the actual operation, and in this test, the case where it exceeded the target was evaluated as good. Together with this, the appearance of the plug is inspected every time piercing and rolling is completed, and the number of passes when the plug peels off and the plug cannot be used, or when the plug tip is melted or deformed, that is, continuously. The number of billets that could be pierced and rolled (the number of continuous piercings) was investigated. This continuous drilling number was evaluated as the plug life. As disclosed in Patent Document 1, the evaluation of the plug life corresponds to a plug in which an arc sprayed coating is formed using an iron wire, that is, test No. in Table 2 above. 11, the life of a plug on which an arc sprayed coating is formed using a cored wire with 0% by volume of BN particles is defined as “1”, and the life ratio of each plug relative to this (hereinafter referred to as “plug life ratio”). )

[Test results]
The test results are shown in Table 2 and FIG. FIG. 4 is a graph summarizing the relationship between the proportion of BN particles in the cored wire and the plug life ratio as the test results of Example 2. These results show the following.

When BN particles are used as the solid lubricant in the cored wire and an arc sprayed coating is formed using this cored wire, test no. As in 13 to 17, by setting the BN particles in the cored wire to 5.0% by volume or more, the drilling efficiency was ensured to 70% or more, and an increase in the plug life ratio was recognized. This is because lubricity is improved because an appropriate amount of BN is contained in the plug film. From this, it was found that a plug in which an arc sprayed coating was formed using a cored wire having BN particles of 5.0% by volume or more stably improved the plug life.

However, test no. When an arc sprayed coating was formed using a cored wire with BN particles exceeding 20.0% by volume as in 18 to 20, the coating peeled off early and the plug base material melted. This is because BN is excessively contained in the plug film, and the adhesion between the plug base material and the film is lowered although the lubricity is increased. From this, it was found that the plug life improvement was not stable in the plug in which the arc sprayed coating was formed using the cored wire in which the BN particles exceeded 20.0% by volume.

On the other hand, test no. 11 and 12, when an arc sprayed coating is formed using a cored wire with BN particles less than 5.0% by volume (including 0% by volume), the drilling efficiency does not reach 70% and the plug life ratio increases. Was small. This is because the plug film does not contain BN functioning as a solid lubricant, or even if it is contained, the amount thereof is insufficient, so that the lubricity is not sufficiently improved. From this, it was found that the improvement of the plug life was not stable even in the plug in which the arc sprayed coating was formed using the cored wire having BN particles of less than 5.0% by volume.

The present invention can be effectively used for the production of high alloy steel seamless steel pipes.

1: Cored wire (sprayed wire), 2: Iron tube,
3: Low thermal conductive material particles, 4: Iron particles, 5: Solid lubricant particles

Claims

A method of manufacturing a plug used in a piercing and rolling machine used for manufacturing a seamless steel pipe,
The manufacturing method of the piercing and rolling plug is as follows:
A shot blasting process for performing shot blasting on the surface of the plug;
An arc spraying step in which a sprayed wire is arc sprayed on the surface of the base material of the plug subjected to shot blasting to form a coating, and
In the arc spraying process, arc spraying is performed by using a cored wire in which at least a specific particle is filled in an iron tube among the iron particles and the specific particles contributing to the improvement of the plug life as a thermal spray wire, and iron oxide Forming a film composed of Fe and specific particles;
A manufacturing method of a plug for piercing and rolling characterized by the above.
The specific particles are low thermal conductive material particles having a property of lower thermal conductivity than iron oxide,
The manufacturing method of the plug for piercing-rolling of Claim 1 characterized by these.
The low thermal conductive material particles are ZrO 2 particles;
The manufacturing method of the plug for piercing-rolling of Claim 2 characterized by these.
The proportion of the ZrO 2 particles in the cored wire is 2.5 to 30.0% by volume,
The manufacturing method of the plug for piercing-rolling of Claim 3 characterized by these.
The specific particles are solid lubricant particles;
The manufacturing method of the plug for piercing-rolling of Claim 1 characterized by these.
The solid lubricant particles are BN particles;
A method for manufacturing a piercing-rolling plug according to claim 5.
The proportion of the BN particles in the cored wire is 5.0 to 20.0% by volume;
A method for producing a piercing-rolling plug according to claim 6.