WO2013170547A1 - Fibre chauffante et à accumulation de chaleur et procédé de préparation ainsi que textile l'utilisant - Google Patents

Fibre chauffante et à accumulation de chaleur et procédé de préparation ainsi que textile l'utilisant Download PDF

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Publication number
WO2013170547A1
WO2013170547A1 PCT/CN2012/080105 CN2012080105W WO2013170547A1 WO 2013170547 A1 WO2013170547 A1 WO 2013170547A1 CN 2012080105 W CN2012080105 W CN 2012080105W WO 2013170547 A1 WO2013170547 A1 WO 2013170547A1
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WO
WIPO (PCT)
Prior art keywords
fiber
textile
nano
heat
preparation
Prior art date
Application number
PCT/CN2012/080105
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English (en)
Chinese (zh)
Inventor
毛盈军
Original Assignee
Mao Yingjun
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mao Yingjun filed Critical Mao Yingjun
Publication of WO2013170547A1 publication Critical patent/WO2013170547A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08—Composition of the spinning solution or the bath

Definitions

  • the invention relates to a textile fiber and a preparation method thereof, in particular to a fiber for heating and storing heat, a preparation method thereof and a textile. Background technique
  • a kind of thermal insulation garment material produced in Japan is a composite fiber composed of electrothermal materials.
  • the principle is like an electric blanket.
  • the conductive fiber is used to heat the fiber to achieve heating effect.
  • the garment made of this fiber looks like a thin single coat. It is actually an electric heating suit.
  • the energy comes from a rechargeable battery that is carried around. In the cold winter, its constant heat is enough to withstand the cold.
  • Sun velvet is a new generation of representative materials made according to the principle of space cotton. It fully fluffs the traditional 100% wool fiber and fluffs it between the two soft mirrors to form a thin and controllable thermal convection barrier (gas enthalpy) with extremely low thermal conductivity and at the same time
  • the heat ray has a reflection effect, achieving double warming effect. Because the gas content in the gas is 90%, the sun velvet is light, soft and warm. Its fiber volume per unit volume is 2 / 3 less than cotton, 4 / 5 less than down, and the finished garment is beautiful and not bloated.
  • the clo value was 3.062.
  • the two-layer mirror has openable and closed micropores, like the pores of the skin. It can be opened for heat when it is hot. It can be turned off when it is cold, and the temperature is adjustable and breathable. It is the ideal material for autumn and winter.
  • Such a velvet material also has defects such as complicated manufacturing processes, high cost, and difficulty in industrialization.
  • An object of the present invention is to provide a heat-storing heat-storing fiber which is easy to manufacture, low in cost, and easy to industrially implement, a preparation method thereof and a textile.
  • the present invention provides a fiber for heating and heat storage, the fiber comprising a conventional textile fiber and a nano unit comprising 0.13% by weight of the total weight, the nano unit comprising 300 8000 nm of microparticles,
  • the microparticles include strontium, potassium, tin or a mixture of at least two of them.
  • the conventional textile fibers comprise chemical fibers, and the chemical fibers comprise rayon and/or synthetic fibers.
  • the microparticles comprise 50 to 500 weight units of lanthanum and 50 to 100 weight units of potassium.
  • the microparticles comprise ⁇ of 50 to 500 weight units and a clock of 50 100 weight units.
  • the microparticles further comprise 100 500 weight units of tin.
  • Another object of the present invention is to provide a method for preparing a textile fiber which is rapidly heated and stored in the presence of light, and the preparation method comprises the following steps: A. A natural high molecular substance or an inorganic substance or a synthetic high molecular substance Or the inorganic material is made into a spinning refining body or a solution; B. adding the above-mentioned nano unit to the spinning refining body or solution; C, extruding through a spinning mechanism to form a bismuth dimension.
  • Another object of the present invention is to provide a method for preparing a textile fabric which is rapidly heated and stored in the light, wherein the preparation method comprises the steps of preparing a textile fiber masterbatch, and in the preparation process of the chemical fiber masterbatch, adding the above Nanocells.
  • the present invention adds a certain proportion of microparticle nano-units of 300 to 8000 nm in the conventional textile ⁇ dimension, the ⁇ dimension of the invention has an unexpected rapid temperature-increasing effect under the same illumination time and illumination intensity, and at the same time
  • the invention has better heat storage performance than the conventional chemical enthalpy after the cessation of illumination, and the invention has lower manufacturing cost, simple manufacturing process and easy comparison with the existing heating fiber.
  • the advantages of industrial production and so on are better new heat-generating fiber materials in low temperature environments. The additional aspects and advantages of the invention will be set forth in part in the description which follows.
  • Figure 1 is a detection device of the technical effect of the present invention
  • Fig. 2 is a temperature-time curve of the measurement method in Example 1. Detailed description of the invention
  • FIG. 1 there is shown a detection embodiment of the heat-generating effect of the temperature-increasing heat storage of the present invention.
  • Testing unit Japan General Consortium BO E Quality Evaluation Structure Kinki Office Quality Test 4 Notice Number: 11604789 - 1
  • Test items Temperature measurement, the test method is as follows:
  • the fiber of the present invention In order to add about 2,9% by weight of the total weight in the conventional textile a textile fiber of a rice unit having a particle size of about 300 nm; the microparticles comprising 480 weight units of lanthanum and 90 weight units of potassium (may also be added to only one of them), and other trace elements, the present invention
  • the nanocells can be added in the process of manufacturing in the Uyghur process using any of the prior art.
  • Control group fiber Conventional textiles without nano-units.
  • weight unit described in the present invention preferably has a weight ratio of "micrograms/kg", and may be weighed according to other weight units according to actual needs.
  • thermocouple thermometer B is placed inside the central portion of the fabric S (15 cm X 15 cm) to be tested, and each of the following conditions is obtained.
  • the temperature change of the fabric S to be tested under illumination was measured every 20 minutes:
  • PRF-500WB reflector lamp produced by Panasonic Corporation A;
  • Measurement conditions Firstly, the reflector lamp A is irradiated for 10 minutes, the reflector lamp is turned off immediately, and it is measured for 10 minutes without being irradiated;
  • Determination method Firstly, the two fabrics to be tested are measured together, and then the positions of the two fabrics to be tested are exchanged and measured again. Finally, the average value of the two determinations is calculated to obtain the test result.
  • the temperature-time relationship curve of the above detection result is shown in FIG. 2, wherein the fabric with a higher upper position corresponds to the fiber of the present invention corresponding to the fabric to be tested, and the lower fabric of the lower position corresponds to the fabric to be tested.
  • the middle is a conventional textile fabric that does not contain the fibers of the present invention.
  • the temperature-sensing fiber of the present invention is more remarkable and unexpected than the conventional chemical fiber under the same light intensity and illumination time.
  • the rapid heating effect is obtained, and at the same time, after the light is stopped, it has better heat storage performance than the conventional chemical enthalpy, as shown in Fig. 2.
  • Example 2
  • the present embodiment is different from the above embodiment in that the test sample is a textile fiber in which about 0.2% by weight of the nano unit is added to the conventional textile fiber, and the nano cell has a particle size of about 8000 nm; Including a 55 weight unit of tantalum, and 110 weight units of tin, the nanocell of the present invention can be added in a fiber manufacturing process using any of the prior art.
  • This embodiment adopts a preparation method of textile fiber which is rapidly heated and stored in the light, and includes the following steps: A. A natural high molecular substance or an inorganic substance (such as viscose fiber), or a synthetic high a molecular substance or an inorganic substance (such as nylon or acrylic) is made into a spinning melt or a solution; B. adding the above-mentioned nano unit to the spinning body or solution; C, extruding through a spinning mechanism to form a crucible dimension.
  • the other process steps are the same as those of the prior art fiber preparation method, and will not be described herein.
  • Example 3 The temperature-time relationship curve of the detection result of this embodiment is omitted.
  • test sample is a textile fiber comprising about 1.5% by weight of the total weight of the nano unit in the conventional textile, the nanometer having a particle size of about 4000 nm;
  • the microparticles comprise 300 weight units of rhodium, 50 weight units of potassium, and 500 weight units of tin, and the nanocells of the present invention can be fabricated in fibers using any of the prior art. Add in the process.
  • This embodiment adopts a preparation method of textile woven fabric which is rapidly heated and stored in the light, and includes a preparation step of the textile fiber chemical fiber masterbatch.
  • the preparation process of the chemical fiber masterbatch the above nano unit is added, and then Produce fiber.
  • the other process steps of the preparation method of the present embodiment are the same as those of the prior art, and will not be described herein.
  • the temperature-time relationship curve of the detection result of this embodiment is omitted.
  • the present invention employs 0.1 to 3% by weight of nano-units of 300 to 8000 nm to conventional chemical fibers, so that the new chemical fibers are expected to rapidly heat up and store heat.
  • the benefits can be understood that more nanometers of nanometers and/or smaller nanoparticles can be added under the premise of the textile process, and the chemical vapor formed by the textiles will have better heat and storage. Thermal effect.
  • another object of the present invention is to provide a textile which is rapidly heated and stored in the presence of light, such as a knitted or woven product, in which at least part of the above-mentioned fibers are included, and of course, the present invention can also be used in its entirety. Made of fiber that heats up and stores heat.
  • the heat-up and heat-storing fiber of the invention and the preparation method thereof can be effectively used for preparing high-quality new heat-storing heat-storage fiber fabric, and can be effectively applied in a low-temperature environment, thereby achieving an unexpected rapid temperature-increasing effect of light. And excellent heat storage performance. Further, the temperature-increasing heat storage of the present invention has advantages such as lower manufacturing cost, simple manufacturing process, and ease of industrial production, compared with the conventional chemical vapor.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)

Abstract

La présente invention concerne une fibre chauffante et à accumulation de chaleur, un procédé de préparation d'une fibre textile qui se réchauffe rapidement et qui accumule de la chaleur lorsqu'elle est exposée à de la lumière et un textile qui se réchauffe rapidement et qui accumule de la chaleur lorsqu'il est exposé à de la lumière. Selon l'invention, la fibre chauffante et à accumulation de chaleur comprend : une fibre textile classique et une unité nanométrique comptant pour 0,1 à 3 % (partie en poids) d'un poids total. L'unité nanométrique comprend des microparticules dont la taille de particule est de 300 à 8 000 nanomètres. Les microparticules comprennent du cérium, du potassium, de l'étain, ou un mélange d'au moins deux du cérium, du potassium et de l'étain.
PCT/CN2012/080105 2012-05-14 2012-08-14 Fibre chauffante et à accumulation de chaleur et procédé de préparation ainsi que textile l'utilisant WO2013170547A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201210148272.7A CN102912466B (zh) 2012-05-14 2012-05-14 一种升温蓄热的纤维及其制备方法和纺织品
CN201210148272.7 2012-05-14

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WO2013170547A1 true WO2013170547A1 (fr) 2013-11-21

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CN (1) CN102912466B (fr)
WO (1) WO2013170547A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103147143B (zh) * 2013-03-05 2014-12-17 毛盈军 一种保温隔热纤维及由该纤维制成的纺织品
CN105671732B (zh) * 2016-01-06 2017-10-24 浙江朗莎尔维迪制衣有限公司 一种新型功能性面料
CN105648625B (zh) * 2016-01-06 2017-10-27 章俊杰 一种新型面料
CN106319662A (zh) * 2016-11-15 2017-01-11 李光武 一种隔热保温纤维及其制备方法、用途
CN106757439A (zh) * 2016-12-19 2017-05-31 武汉纺织大学 一种吸湿排汗、发热和保温多功能纤维及其制备方法

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JPH11279830A (ja) * 1998-03-26 1999-10-12 Kuraray Co Ltd 熱線放射性に優れる繊維
JP2004316029A (ja) * 2003-04-17 2004-11-11 Kanebo Ltd 導電性繊維の製法およびそれによって得られる導電性繊維、並びにそれを用いた導電性繊維構造体
CN1804160A (zh) * 2005-01-13 2006-07-19 李官奇 一种功能性纤维
US20080299160A1 (en) * 2004-01-28 2008-12-04 Agboh Ochayi C Method of Manufacture of Polymer Composites
US20080305377A1 (en) * 2007-03-15 2008-12-11 University Of Rochester Long metallic nanowires, methods of making, and use thereof in proton exchange membrane fuel cell
CN102392327A (zh) * 2011-11-24 2012-03-28 长春理工大学 一种掺铈钇铝石榴石纳米带的制备方法
CN102677204A (zh) * 2012-05-14 2012-09-19 毛盈军 在潮湿条件下自然升温发热的纤维、制备方法和纺织品
CN102747441A (zh) * 2012-05-14 2012-10-24 毛盈军 一种降温发冷的纤维、制备方法及纺织品

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CN1401831A (zh) * 2001-08-27 2003-03-12 武汉纳宝新技术有限责任公司 含有纳米粉末材料的功能性人造棉
CN1190546C (zh) * 2003-07-25 2005-02-23 东华大学 纳米粒子改性化学纤维的制备方法
CN101709511B (zh) * 2009-11-26 2012-05-23 毛盈军 遇光快速升温发热的化学纤维及包含该纤维的纺织品

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11279830A (ja) * 1998-03-26 1999-10-12 Kuraray Co Ltd 熱線放射性に優れる繊維
JP2004316029A (ja) * 2003-04-17 2004-11-11 Kanebo Ltd 導電性繊維の製法およびそれによって得られる導電性繊維、並びにそれを用いた導電性繊維構造体
US20080299160A1 (en) * 2004-01-28 2008-12-04 Agboh Ochayi C Method of Manufacture of Polymer Composites
CN1804160A (zh) * 2005-01-13 2006-07-19 李官奇 一种功能性纤维
US20080305377A1 (en) * 2007-03-15 2008-12-11 University Of Rochester Long metallic nanowires, methods of making, and use thereof in proton exchange membrane fuel cell
CN102392327A (zh) * 2011-11-24 2012-03-28 长春理工大学 一种掺铈钇铝石榴石纳米带的制备方法
CN102677204A (zh) * 2012-05-14 2012-09-19 毛盈军 在潮湿条件下自然升温发热的纤维、制备方法和纺织品
CN102747441A (zh) * 2012-05-14 2012-10-24 毛盈军 一种降温发冷的纤维、制备方法及纺织品

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CN102912466B (zh) 2014-12-17
CN102912466A (zh) 2013-02-06

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