WO2013159868A3 - Transportable package having a cold box, low-temperature air separation plant and method for producing a low-temperature air separation plant - Google Patents

Transportable package having a cold box, low-temperature air separation plant and method for producing a low-temperature air separation plant Download PDF

Info

Publication number
WO2013159868A3
WO2013159868A3 PCT/EP2013/001046 EP2013001046W WO2013159868A3 WO 2013159868 A3 WO2013159868 A3 WO 2013159868A3 EP 2013001046 W EP2013001046 W EP 2013001046W WO 2013159868 A3 WO2013159868 A3 WO 2013159868A3
Authority
WO
WIPO (PCT)
Prior art keywords
low
temperature air
air separation
separation plant
transportable package
Prior art date
Application number
PCT/EP2013/001046
Other languages
German (de)
French (fr)
Other versions
WO2013159868A2 (en
Inventor
Stefan Lochner
Augustin Rampp
Original Assignee
Linde Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde Aktiengesellschaft filed Critical Linde Aktiengesellschaft
Priority to EP13716961.1A priority Critical patent/EP2841858A2/en
Priority to US14/396,408 priority patent/US20150096327A1/en
Priority to CN201380022149.3A priority patent/CN104272046A/en
Publication of WO2013159868A2 publication Critical patent/WO2013159868A2/en
Publication of WO2013159868A3 publication Critical patent/WO2013159868A3/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04975Construction and layout of air fractionation equipments, e.g. valves, machines adapted for special use of the air fractionation unit, e.g. transportable devices by truck or small scale use
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/0489Modularity and arrangement of parts of the air fractionation unit, in particular of the cold box, e.g. pre-fabrication, assembling and erection, dimensions, horizontal layout "plot"
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04406Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
    • F25J3/04412Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04642Recovering noble gases from air
    • F25J3/04648Recovering noble gases from air argon
    • F25J3/04654Producing crude argon in a crude argon column
    • F25J3/04666Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system
    • F25J3/04672Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system having a top condenser
    • F25J3/04678Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system having a top condenser cooled by oxygen enriched liquid from high pressure column bottoms
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04642Recovering noble gases from air
    • F25J3/04648Recovering noble gases from air argon
    • F25J3/04721Producing pure argon, e.g. recovered from a crude argon column
    • F25J3/04727Producing pure argon, e.g. recovered from a crude argon column using an auxiliary pure argon column for nitrogen rejection
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04872Vertical layout of cold equipments within in the cold box, e.g. columns, heat exchangers etc.
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04945Details of internal structure; insulation and housing of the cold box
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/40Vertical layout or arrangement of cold equipments within in the cold box, e.g. columns, condensers, heat exchangers etc.
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/42Modularity, pre-fabrication of modules, assembling and erection, horizontal layout, i.e. plot plan, and vertical arrangement of parts of the cryogenic unit, e.g. of the cold box

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

The invention relates to a transportable package for a low-temperature air separation plant which has a main heat exchanger (2a, 2b, 2c) for cooling feed air (1) and a double column (5) for separating the cooled feed air, wherein the double column (5) has a high-pressure column and a low-pressure column that are arranged above one another. The transportable package has a cold box (20, 400), in the interior of which accessories of the double column (5), in particular pipelines (7, 11, 12) and valves, are arranged, but not the double column and not the main heat exchanger, wherein the transportable package has connections for joining the pipelines to the double column and to the main heat exchanger. Moreover the invention relates to a low-temperature air separation plant and to a method for producing a low-temperature air separation plant using this transportable package.
PCT/EP2013/001046 2012-04-27 2013-04-09 Transportable package having a cold box, low-temperature air separation plant and method for producing a low-temperature air separation plant WO2013159868A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP13716961.1A EP2841858A2 (en) 2012-04-27 2013-04-09 Transportable package having a cold box, low-temperature air separation plant and method for producing a low-temperature air separation plant
US14/396,408 US20150096327A1 (en) 2012-04-27 2013-04-09 Transportable package having a cold box, low-temperature air separation plant and method for producing a low-temperature air separation plant
CN201380022149.3A CN104272046A (en) 2012-04-27 2013-04-09 Transportable package having a cold box, low-temperature air separation plant and method for producing a low-temperature air separation plant

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012008415A DE102012008415A1 (en) 2012-04-27 2012-04-27 Transportable package comprising a cold box, cryogenic air separation plant and method of manufacturing a cryogenic air separation plant
DE102012008415.3 2012-04-27

Publications (2)

Publication Number Publication Date
WO2013159868A2 WO2013159868A2 (en) 2013-10-31
WO2013159868A3 true WO2013159868A3 (en) 2014-05-08

Family

ID=48139878

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2013/001046 WO2013159868A2 (en) 2012-04-27 2013-04-09 Transportable package having a cold box, low-temperature air separation plant and method for producing a low-temperature air separation plant

Country Status (5)

Country Link
US (1) US20150096327A1 (en)
EP (1) EP2841858A2 (en)
CN (1) CN104272046A (en)
DE (1) DE102012008415A1 (en)
WO (1) WO2013159868A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3052243B1 (en) * 2016-06-06 2019-06-28 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude ASSEMBLY OF MODULAR CONSTRUCTION ELEMENTS OF A MASS AND / OR HEAT EXCHANGE APPARATUS AND EXCHANGE METHOD USING AN ASSEMBLY
DE102016125350A1 (en) 2016-12-22 2018-06-28 Endress+Hauser SE+Co. KG Connecting element and transmitter housing with inserted therein connecting element
WO2018130157A1 (en) * 2017-01-10 2018-07-19 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Enclosure for an apparatus for the separation of a gaseous mixture by distillation, and separation apparatus comprising such an enclosure
US20180209727A1 (en) 2017-01-25 2018-07-26 Kevin J. Saboda Structual support assembly for cold box structures in an air separation unit
EP3614083A1 (en) 2018-08-22 2020-02-26 Linde Aktiengesellschaft Air separation system, method for cryogenic decomposition of air using air separation system and method for creating an air separation system
EP3614084A1 (en) * 2018-08-22 2020-02-26 Linde Aktiengesellschaft Method and installation for cryogenic decomposition of air
EP3614082A1 (en) 2018-08-22 2020-02-26 Linde Aktiengesellschaft Air separation plant, method for cryogenic decomposition of air and method for creating an air separation system
CN109676367A (en) 2018-12-28 2019-04-26 乔治洛德方法研究和开发液化空气有限公司 A kind of method of heat exchanger assemblies and the assembly heat exchanger assemblies
FR3095217B1 (en) * 2019-04-17 2021-03-19 Air Liquide Frame panel intended to be part of a cold box of a separation device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0605262A1 (en) * 1992-12-30 1994-07-06 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process and apparatus for the production of gaseous oxygen under pressure
US5412954A (en) * 1992-09-16 1995-05-09 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Precedes Georges Claude Apparatus for cryogenic treatment, such as air distillation
JPH11101576A (en) * 1997-09-29 1999-04-13 Daido Hoxan Inc Air separator
FR2778234A1 (en) * 1998-04-30 1999-11-05 Air Liquide AIR DISTILLATION SYSTEM AND CORRESPONDING COLD BOX
EP1180655A1 (en) * 2000-08-18 2002-02-20 Linde Aktiengesellschaft Plant for cryogenic air separation

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3840506A1 (en) 1988-12-01 1990-06-07 Linde Ag METHOD AND DEVICE FOR AIR DISASSEMBLY
DE4317916A1 (en) 1993-05-28 1994-12-01 Linde Ag Process and apparatus for the isolation of argon
FR2706025B1 (en) 1993-06-03 1995-07-28 Air Liquide Air distillation installation.
US7621152B2 (en) 2006-02-24 2009-11-24 Praxair Technology, Inc. Compact cryogenic plant

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5412954A (en) * 1992-09-16 1995-05-09 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Precedes Georges Claude Apparatus for cryogenic treatment, such as air distillation
EP0605262A1 (en) * 1992-12-30 1994-07-06 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process and apparatus for the production of gaseous oxygen under pressure
JPH11101576A (en) * 1997-09-29 1999-04-13 Daido Hoxan Inc Air separator
FR2778234A1 (en) * 1998-04-30 1999-11-05 Air Liquide AIR DISTILLATION SYSTEM AND CORRESPONDING COLD BOX
EP1180655A1 (en) * 2000-08-18 2002-02-20 Linde Aktiengesellschaft Plant for cryogenic air separation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CASTLE W F: "THE USE OF PRE-PACKAGED COLDBOX TECHNIQUES IN ENGINEERING AND CONSTRUCTION OF A 1500 METRIC TONNE PER DAY OXYGEN PLANT USING THE LOW PRESSURE CYCLE", INTERNATIONAL CONGRESS OF REFRIGERATION. PROCEEDINGS - CONGRESINTERNATIONAL DU FROID. COMPTES RENDUS, XX, XX, vol. 1, 1 January 1979 (1979-01-01), pages 399 - 404, XP001182791 *

Also Published As

Publication number Publication date
WO2013159868A2 (en) 2013-10-31
DE102012008415A1 (en) 2013-10-31
CN104272046A (en) 2015-01-07
US20150096327A1 (en) 2015-04-09
EP2841858A2 (en) 2015-03-04

Similar Documents

Publication Publication Date Title
WO2013159868A3 (en) Transportable package having a cold box, low-temperature air separation plant and method for producing a low-temperature air separation plant
MY176364A (en) Integrated nitrogen removal in the production of liquefied natural gas using refrigerated heat pump
EA201890251A1 (en) SYSTEM AND METHODS OF OBTAINING LIQUEFIED NITROGEN USING LIQUEFIED NATURAL GAS
BR112015012441A2 (en) liquefied natural gas production
WO2011117655A3 (en) Refrigeration process
WO2011135335A3 (en) Process and apparatus for the liquefaction of natural gas
MY178749A (en) Liquefied gas producing facility and liquefied gas producing method
MX2023003745A (en) Configurations and methods for small scale lng production.
WO2012175889A3 (en) Method for liquefying natural gas with a triple closed circuit of coolant gas
WO2013020775A3 (en) Liquid-cryogen injection cooling devices and methods for using same
WO2013148799A3 (en) Process for the separation of air by cryogenic distillation
WO2015110779A3 (en) Lng production process
WO2015140197A3 (en) A method for liquefaction of a pre-processed natural gas
GB201113681D0 (en) High efficiency air cooling apparatus
WO2015136182A3 (en) Method and facility for transporting and liquefying gas
WO2011116871A3 (en) Device for the cryogenic separation of air
WO2014154361A3 (en) Method and device for producing gaseous compressed oxygen having variable power consumption
WO2015060930A3 (en) Air separation method and apparatus
WO2012140369A3 (en) Method and apparatus for liquefying a gas or cooling a feed gas at supercritical pressure
MY161644A (en) Process for liquefying a hydrocarbon-rich fraction
WO2013052288A3 (en) Air separation method and apparatus
WO2014154339A3 (en) Method for air separation and air separation plant
WO2015003808A3 (en) Method for producing at least one air product, air separation system, method and device for producing electrical energy
WO2011010049A3 (en) Method and apparatus for separating air by cryogenic distillation
WO2015014460A3 (en) Method for separating undesired components from a helium flow

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13716961

Country of ref document: EP

Kind code of ref document: A2

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2013716961

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 14396408

Country of ref document: US