WO2013145207A1 - Fire-extinguishing agent for throwing fire-extinguisher - Google Patents
Fire-extinguishing agent for throwing fire-extinguisher Download PDFInfo
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- WO2013145207A1 WO2013145207A1 PCT/JP2012/058349 JP2012058349W WO2013145207A1 WO 2013145207 A1 WO2013145207 A1 WO 2013145207A1 JP 2012058349 W JP2012058349 W JP 2012058349W WO 2013145207 A1 WO2013145207 A1 WO 2013145207A1
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- fire
- extinguisher
- throwing
- extinguishing
- foam
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Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C19/00—Hand fire-extinguishers in which the extinguishing substance is expelled by an explosion; Exploding containers thrown into the fire
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C99/00—Subject matter not provided for in other groups of this subclass
- A62C99/0009—Methods of extinguishing or preventing the spread of fire by cooling down or suffocating the flames
- A62C99/0036—Methods of extinguishing or preventing the spread of fire by cooling down or suffocating the flames using foam
Definitions
- the present invention relates to, for example, a throwing fire extinguisher, and more particularly to a fire extinguishing agent used for a throwing fire extinguisher.
- Patent Document 1 discloses a fire extinguishing agent mainly composed of anhydrous sodium carbonate, ammonium sulfate, and urea
- Patent Document 2 discloses a fire extinguishing agent mainly composed of diammonium hydrogen phosphate and ammonium bicarbonate.
- Patent Document 3 proposes a throwing fire extinguisher in which a fire extinguishing agent is sealed in a container that bursts by impact.
- the throwing fire extinguisher of Patent Document 3 is an excellent instrument in that it can be extinguished away from the source of the fire, but it is difficult to extinguish unless the fire extinguisher used can cover the flame instantly.
- JP 2001-379015 A Japanese Patent No. 4437053 Japanese Patent No. 3081531
- the generation of non-combustible gas which is an important factor for the oxygen-blocking fire extinguishing, is instantaneous in the fire extinguishing mechanism, and when used as a throwing fire extinguisher, the container breaks at any part of the flame.
- the fire extinguishes inadequately without the extinguishing agent or suffocating gas generated from the extinguishing agent covering the entire flame.
- the present invention is intended to solve such problems in the prior art, and an object of the present invention is to provide a fire extinguishing agent that uses generated suffocating gas without waste.
- the fire extinguisher according to claim 1 of the present application is a foam which spreads so as to cover the combustion surface without letting out the inorganic salt which decomposes and generates carbon dioxide gas and ammonia gas by the heat of the flame upon extinguishing the fire. It is made by mixing the agent.
- hydrolyzed protein foam extinguishing agent Is generated even if 10-20% (wt%) of foam extinguishing agent or a plurality of foam extinguishing agents are mixed with agitation, hydrocarbon surface active foam, fluorine surface active foam It was set as the range which does not have big influence on.
- a normal foam extinguisher or water film foam extinguisher is used by adjusting the concentration to 3 to 6% at the time of use, but the extinguisher of the present invention has a foaming component of 10 to 20% (wt%).
- the point is a feature and an essential configuration.
- the foam extinguisher is usually mixed with water, foamed by a fire extinguishing agent spray nozzle, and supplied to the fire part in a foamed state, a high-pressure spray device is required when there is a distance from the fire part.
- the fire extinguisher of the present invention When used as a throw-out type fire extinguisher, the fire extinguisher is thrown into the fire part in the entire container and destroyed, so it is possible to extinguish the fire within the reach of throwing, and it is superior to a normal foam fire extinguisher It becomes a characteristic.
- the fire extinguishing agent of the present invention having such a configuration has improved the sealing performance of the entire flame due to the high incombustible gas generation rate and the foaming agent that does not escape the derived gas.
- ammonium bicarbonate, potassium carbonate, diammonium hydrogen phosphate and ammonium sulfate are dissolved as basic materials for generating carbon dioxide gas and ammonia gas by thermal decomposition.
- thermal decomposition hardly occurs in the range of 70 ° C. to 90 ° C. of the claim 1, but when the acid side or the alkaline side is touched on the acidic side or alkaline side during the dissolution process, carbon dioxide gas is present on the strongly acidic side. However, since ammonia gas is generated on the strong alkali side, it is prepared so that the solution is always kept near neutrality.
- this fire extinguisher When using this fire extinguisher as a throw-out type fire extinguisher, select and fill a container that has no problem in transportation and storage and can be destroyed by throwing during actual fire extinguishing use.
- the container is made up of only resin that does not use a filler or other binder so that it can be destroyed relatively easily when thrown, and the thickness of the container should be controlled for the purpose of obtaining strength during transportation.
- a fire extinguisher with a different amount of foaming agent added was prepared, and the appropriate amount of foaming agent added was determined by a simple fire fighting experiment using gasoline as the fire source.
- Alpha foam 310R manufactured by Yamato Protech Co., Ltd. was used as the foaming agent.
- the fire extinguishing experiment was conducted once with the foaming agent as 1% (weight%, the same applies hereinafter). In this case, the fire could not be extinguished and the remaining area was 40% or more.
- the fire extinguishing experiment was conducted 3 times with 3% foaming agent. In this case, the fire could not be extinguished three times, and the remaining area was 27-36%.
- the fire extinguishing experiment was conducted twice with 5% foaming agent. In this case, the fire could be extinguished in less than 5 seconds and there was no recurrence, but the remaining fire could not be extinguished and the remaining area was 35%.
- the fire extinguishing experiment was conducted twice with the foaming agent at 6%. In this case, the fire could be extinguished in less than 5 seconds and there was no recurrence, but the remaining fire could not be extinguished and the remaining area was 40%.
- the fire extinguishing experiment was conducted 3 times with 8% foaming agent. In this case, the fire could be extinguished twice in less than 5 seconds and there was no recurrence, but the remaining one could not be extinguished and the remaining area was 30%.
- the fire extinguishing experiment was conducted 3 times with 10% foaming agent. All three fires could be extinguished in less than 5 seconds and there was no recurrence.
- the fire extinguishing experiment was conducted twice with the foaming agent at 12%. Both could be extinguished in less than 5 seconds and there was no recurrence.
- the fire extinguishing experiment was conducted twice with the foaming agent at 14%. Both could be extinguished in less than 5 seconds and there was no recurrence.
- the fire extinguishing experiment was conducted twice with 18% foaming agent. Both could be extinguished in less than 5 seconds and there was no recurrence.
- the fire extinguishing experiment was conducted 3 times with a foaming agent of 22%. In this case, the fire could be extinguished in less than 5 seconds and there was no recurrence, but the remaining one could not be extinguished and the remaining area was 20%.
- the use of the fire extinguisher for a throwing fire extinguisher of the present invention makes it possible to provide a fire extinguishing extinguisher for initial fire fighting that does not select the fire site by enclosing the fire extinguisher in a small capacity throwing container.
Abstract
Due to some fire causes or in some fire sites, conventional throwing fire-extinguishers to be used in first-aid fire fighting fail to completely extinguish fire.
A fire-extinguishing agent for a throwing fire-extinguisher having an improved fire-extinguishing performance, said fire-extinguishing agent having been prepared by examining the additive amount of individual foaming agents and, as a result, containing a foaming agent in an increased amount so as to be able to generate an increased amount of carbon dioxide gas and an increased amount of ammonia gas and block the escape of the thus generated gases in fire-extinguishing.
Description
本発明は、たとえば投てき消火具に係り、特に投てき消火具に使用する消火剤に関する。
The present invention relates to, for example, a throwing fire extinguisher, and more particularly to a fire extinguishing agent used for a throwing fire extinguisher.
取り扱いが簡便で初期消火能力に優れた投てき消火具が一般家庭、病院、学校などで簡便な初期消火用具として要請されている。この要請に応える一法として、たとえば特許文献１では無水炭酸ソーダや硫酸アンモニウム、尿素などを主剤とする消火剤、特許文献２にはリン酸水素二アンモニウム、重炭酸アンモニウムを主剤とする消火剤が開示されている。また、特許文献３では衝撃により破裂する容器に消火剤を封入した投てき消火具が提案されている。
A throwing fire extinguisher that is easy to handle and has excellent initial fire extinguishing ability is required as a simple initial fire extinguishing tool in general homes, hospitals, and schools. For example, Patent Document 1 discloses a fire extinguishing agent mainly composed of anhydrous sodium carbonate, ammonium sulfate, and urea, and Patent Document 2 discloses a fire extinguishing agent mainly composed of diammonium hydrogen phosphate and ammonium bicarbonate. Has been. Patent Document 3 proposes a throwing fire extinguisher in which a fire extinguishing agent is sealed in a container that bursts by impact.
しかし、特許文献１および特許文献２の方法では火災を消し止める不燃性ガスである炭酸ガスあるいはアンモニアガスが火災の熱によって発生しても、瞬間的発生のため、ガスは瞬時に拡散してしまい火災を起こしている空間中にガスが充満しないかぎり、完全な消火は困難である。
However, in the methods of Patent Document 1 and Patent Document 2, even if carbon dioxide or ammonia gas, which is an incombustible gas that extinguishes the fire, is generated by the heat of the fire, the gas is instantly diffused, so the gas diffuses instantaneously. Complete extinguishing is difficult unless the fire-laden space is filled with gas.
特許文献３の投てき消火具は、火元から離れて消火できるという点で優れた器具であるが、使用する消火剤によって瞬時に火炎を覆うことができなければ消火は困難である。
The throwing fire extinguisher of Patent Document 3 is an excellent instrument in that it can be extinguished away from the source of the fire, but it is difficult to extinguish unless the fire extinguisher used can cover the flame instantly.
上述のように、これまでの投てき消火具技術では消火剤性能が不十分であった。
As described above, the fire extinguishing agent performance was insufficient with the conventional fire extinguishing extinguisher technology.
すなわち、従来技術では消火機構のうち特に酸素遮断型消火の重要な因子となる不燃性ガスの発生が瞬間的であり、特に投てき消火具として使用した場合には火炎のどの部分で容器が破壊するかによっては火炎全体を消火剤、または消火剤から発生した窒息性ガスが覆うことなく消火は不十分に終わる。
That is, in the prior art, the generation of non-combustible gas, which is an important factor for the oxygen-blocking fire extinguishing, is instantaneous in the fire extinguishing mechanism, and when used as a throwing fire extinguisher, the container breaks at any part of the flame. Depending on how the fire extinguishes, the fire extinguishes inadequately without the extinguishing agent or suffocating gas generated from the extinguishing agent covering the entire flame.
本発明はこうした従来技術上の問題点を解決することを企図したものであり、発生した窒息性ガスを無駄なく利用する消火剤を提供することを目的とするものである。
The present invention is intended to solve such problems in the prior art, and an object of the present invention is to provide a fire extinguishing agent that uses generated suffocating gas without waste.
かかる課題を解決するために、本願の請求項１に係る消火剤は、消火にあたり火炎の熱によって炭酸ガス、アンモニアガスを分解発生する無機塩類とそのガスを逃がさず燃焼面を覆うように広がる発泡剤とを混合してなる。
In order to solve such a problem, the fire extinguisher according to claim 1 of the present application is a foam which spreads so as to cover the combustion surface without letting out the inorganic salt which decomposes and generates carbon dioxide gas and ammonia gas by the heat of the flame upon extinguishing the fire. It is made by mixing the agent.
無機塩類は不燃ガス発生により発泡源となることから消火剤が水溶液として成立する範囲で高濃度であるほど望ましいが、水成膜性を考慮して調製するため、加水分解したたん白質泡消火剤、炭化水素系界面活性泡消火剤、フッ素系界面活性泡消火剤のうちのいずれか一の泡消火剤または複数の泡消火剤を１０～２０％（重量％）撹拌混入しても泡の発生に大きく影響を与えない範囲とした。
Since inorganic salts become a foaming source due to the generation of non-combustible gas, it is desirable that the concentration of the extinguishing agent is high as long as it is an aqueous solution. However, in order to prepare water film-forming properties, hydrolyzed protein foam extinguishing agent Is generated even if 10-20% (wt%) of foam extinguishing agent or a plurality of foam extinguishing agents are mixed with agitation, hydrocarbon surface active foam, fluorine surface active foam It was set as the range which does not have big influence on.
通常の泡消火剤または水成膜泡消火剤は使用時に３％から６％の濃度に調整して使用されるが、本発明の消火剤は発泡成分が１０～２０％（重量％）である点が特徴であり、必須の構成である。
A normal foam extinguisher or water film foam extinguisher is used by adjusting the concentration to 3 to 6% at the time of use, but the extinguisher of the present invention has a foaming component of 10 to 20% (wt%). The point is a feature and an essential configuration.
泡消火剤は通常、水と混合し、消火剤噴霧ノズル部で発泡させられ、泡状態で火災部に供給することから、火災部と距離がある場合には高圧の噴射装置が必要となる。
Since the foam extinguisher is usually mixed with water, foamed by a fire extinguishing agent spray nozzle, and supplied to the fire part in a foamed state, a high-pressure spray device is required when there is a distance from the fire part.
本発明の消火剤を投てき型消火具として用いる場合には消火剤は容器全体で火災部に投入、破壊されるため、投てきで届く範囲の消火が可能であり、通常の泡消火器よりも優れた特徴となる。
When the fire extinguisher of the present invention is used as a throw-out type fire extinguisher, the fire extinguisher is thrown into the fire part in the entire container and destroyed, so it is possible to extinguish the fire within the reach of throwing, and it is superior to a normal foam fire extinguisher It becomes a characteristic.
こうした構成を備える本発明の消火剤は高い不燃ガス発生率と派生したガスを逃がさない発泡剤により火炎全体の封鎖性が向上した。
The fire extinguishing agent of the present invention having such a configuration has improved the sealing performance of the entire flame due to the high incombustible gas generation rate and the foaming agent that does not escape the derived gas.
以下、本発明を実施するための形態について説明する。なお、以下では、本発明の説明に必要な範囲を主に説明することとし、説明を省略する箇所については公知技術によるものとする。
Hereinafter, modes for carrying out the present invention will be described. In the following description, the scope necessary for the description of the present invention will be mainly described, and portions that will not be described are based on known techniques.
本発明は基本的な構成として、熱分解により炭酸ガスおよびアンモニアガスを発生する基本材料として重炭酸アンモニウム、炭酸カリウム、リン酸水素二アンモニウムおよび硫酸アンモニウムを溶解する。
In the present invention, ammonium bicarbonate, potassium carbonate, diammonium hydrogen phosphate and ammonium sulfate are dissolved as basic materials for generating carbon dioxide gas and ammonia gas by thermal decomposition.
これらの無機塩類の溶解では請求項１の７０℃～９０℃の範囲ではほとんど熱分解は起こらないが、溶解過程でｐＨが大きく酸性側、あるいはアルカリ性側に触れると、それぞれ強酸性側では炭酸ガスが、強アルカリ側ではアンモニアガスが発生するので、中性付近に常時溶解液を保つように調製していく。
In the dissolution of these inorganic salts, thermal decomposition hardly occurs in the range of 70 ° C. to 90 ° C. of the claim 1, but when the acid side or the alkaline side is touched on the acidic side or alkaline side during the dissolution process, carbon dioxide gas is present on the strongly acidic side. However, since ammonia gas is generated on the strong alkali side, it is prepared so that the solution is always kept near neutrality.
無機塩類の溶解完了後、最後に発泡剤を添加する。
After the inorganic salt is completely dissolved, add a foaming agent.
すべての材料を溶解調製後、２０℃における比重およびｐＨを測定し、比重１．１０～１．１４、ｐＨ８．０～８．８の範囲であることを確認する。
After dissolving and preparing all the materials, measure the specific gravity and pH at 20 ° C., and confirm that the specific gravity is in the range of 1.10 to 1.14 and pH 8.0 to 8.8.
本消火剤を投てき型消火具として用いる場合には、運搬および保管に問題がなく、実際の消火使用時には投てきにより破壊されるような容器を選び充填する。
When using this fire extinguisher as a throw-out type fire extinguisher, select and fill a container that has no problem in transportation and storage and can be destroyed by throwing during actual fire extinguishing use.
投てき型消火具としては火災発生まで長期間安定して保存することが必要になり、消火剤の塩濃度が高いことを考えるとプラスチック容器を選択することになる。
As throwing-type fire extinguishers, it is necessary to store them stably for a long time until a fire breaks out, and considering the high salt concentration of fire extinguishing agents, plastic containers will be selected.
さらに投てき時に比較的簡単に破壊するよう容器はフィラーなどのつなぎ剤を使用しない樹脂のみの構成により、運搬時の強度を得る目的では容器肉厚等の制御によるのがよい。
In addition, the container is made up of only resin that does not use a filler or other binder so that it can be destroyed relatively easily when thrown, and the thickness of the container should be controlled for the purpose of obtaining strength during transportation.
以下に、無機塩類調整後の発泡剤添加量の決定の実験例を示す。
The following is an experimental example of determining the amount of foaming agent added after adjusting inorganic salts.
無機塩類溶液を調製後、発泡剤添加量を変えた消火液を用意し、ガソリンを火災源とした簡易消火実験により、発泡剤の適正添加量を決定した。発泡剤としてはヤマトプロテック社製アルファフォーム３１０Ｒを用いた。
After preparing the inorganic salt solution, a fire extinguisher with a different amount of foaming agent added was prepared, and the appropriate amount of foaming agent added was determined by a simple fire fighting experiment using gasoline as the fire source. Alpha foam 310R manufactured by Yamato Protech Co., Ltd. was used as the foaming agent.
簡易消火実験用には２００リットルのドラム缶の背面を残し底面から６０ｃｍの所で上部を切断したものに、水を１０リットル入れ、ガソリンを１リットル投入、着火後３０秒して、火勢が一定となったところで、試験液６００ｍＬを入れた塩化ビニル製投てき容器をドラム缶の残った背面に距離３ｍから投げ入れることにした。５秒以下で消火でき、そのまま待機して再発火のない薬剤を合格とした。消火できなかった場合にはドラム缶上部面を写真撮影し、消火できないで残っている面積を算出し、残面積％とした。
For a simple fire-fighting experiment, leave the back of a 200-liter drum can and cut the top at 60 cm from the bottom. Put 10 liters of water, 1 liter of gasoline, and 30 seconds after ignition. At that point, it was decided that a vinyl chloride throwing container containing 600 mL of the test solution was thrown into the rear surface of the drum can from a distance of 3 m. A drug that can be extinguished in less than 5 seconds and waited for no recurrence was accepted. When the fire could not be extinguished, a photo was taken of the upper surface of the drum, and the remaining area that could not be extinguished was calculated as the remaining area%.
発泡剤を１％（重量％、以下同じ）として消火実験を１回行った。この場合、消火できず、残面積は４０％以上だった。
The fire extinguishing experiment was conducted once with the foaming agent as 1% (weight%, the same applies hereinafter). In this case, the fire could not be extinguished and the remaining area was 40% or more.
発泡剤を３％として消火実験を３回行った。この場合、３回とも消火できず、残面積は２７～３６％だった。
The fire extinguishing experiment was conducted 3 times with 3% foaming agent. In this case, the fire could not be extinguished three times, and the remaining area was 27-36%.
発泡剤を５％として消火実験を２回行った。この場合、１回は５秒以下で消火でき再発火もなかったが、残りの１回は消火できず、残面積は３５％だった。
The fire extinguishing experiment was conducted twice with 5% foaming agent. In this case, the fire could be extinguished in less than 5 seconds and there was no recurrence, but the remaining fire could not be extinguished and the remaining area was 35%.
発泡剤を６％として消火実験を２回行った。この場合、１回は５秒以下で消火でき再発火もなかったが、残りの１回は消火できず、残面積は４０％だった。
The fire extinguishing experiment was conducted twice with the foaming agent at 6%. In this case, the fire could be extinguished in less than 5 seconds and there was no recurrence, but the remaining fire could not be extinguished and the remaining area was 40%.
発泡剤を８％として消火実験を３回行った。この場合、２回は５秒以下で消火でき再発火もなかったが、残りの１回は消火できず、残面積は３０％だった。
The fire extinguishing experiment was conducted 3 times with 8% foaming agent. In this case, the fire could be extinguished twice in less than 5 seconds and there was no recurrence, but the remaining one could not be extinguished and the remaining area was 30%.
発泡剤を１０％として消火実験を３回行った。３回とも５秒以下で消火でき再発火もなかった。
The fire extinguishing experiment was conducted 3 times with 10% foaming agent. All three fires could be extinguished in less than 5 seconds and there was no recurrence.
発泡剤を１２％として消火実験を２回行った。２回とも５秒以下で消火でき再発火もなかった。
The fire extinguishing experiment was conducted twice with the foaming agent at 12%. Both could be extinguished in less than 5 seconds and there was no recurrence.
発泡剤を１４％として消火実験を２回行った。２回とも５秒以下で消火でき再発火もなかった。
The fire extinguishing experiment was conducted twice with the foaming agent at 14%. Both could be extinguished in less than 5 seconds and there was no recurrence.
発泡剤を１６％として消火実験を２回行った。２回とも５秒以下で消火でき再発火もなかった。
消 Fire extinguishing experiment was conducted twice with 16% foaming agent. Both could be extinguished in less than 5 seconds and there was no recurrence.
発泡剤を１８％として消火実験を２回行った。２回とも５秒以下で消火でき再発火もなかった。
The fire extinguishing experiment was conducted twice with 18% foaming agent. Both could be extinguished in less than 5 seconds and there was no recurrence.
発泡剤を２０％として消火実験を２回行った。２回とも５秒以下で消火でき再発火もなかった。
消 Fire extinguishing experiment was conducted twice with 20% foaming agent. Both could be extinguished in less than 5 seconds and there was no recurrence.
発泡剤を２２％として消火実験を３回行った。この場合、２回は５秒以下で消火でき再発火もなかったが、残りの１回は消火できず、残面積は２０％だった。
The fire extinguishing experiment was conducted 3 times with a foaming agent of 22%. In this case, the fire could be extinguished in less than 5 seconds and there was no recurrence, but the remaining one could not be extinguished and the remaining area was 20%.
本発明の投てき消火具用消火剤の使用により、小容量の投てき容器に当該消火剤を封入することで火災現場を選ばない初期消火用投てき型消火具が可能になる。
The use of the fire extinguisher for a throwing fire extinguisher of the present invention makes it possible to provide a fire extinguishing extinguisher for initial fire fighting that does not select the fire site by enclosing the fire extinguisher in a small capacity throwing container.
Claims (2)
- ７０℃～９０℃の湯４００～５５０ｍｌに、リン酸水素二アンモニウム１０～８０ｇ、重炭酸アンモニウム１０～８０ｇ、硫酸アンモニウム１０～１００ｇ、炭酸カリウム５０～２２０ｇを順次溶解し、加水分解したたん白質泡消火剤、炭化水素系界面活性泡消火剤、フッ素系界面活性泡消火剤のうちのいずれか一の泡消火剤または複数の泡消火剤を１００～２００ｇ撹拌混入し水で１０００ｍｌに希釈したことを特徴とする投てき消火具用消火剤。 A hydrolyzed protein foam fire extinguisher is dissolved in 400 to 550 ml of hot water at 70 ° C. to 90 ° C. by dissolving 10 to 80 g of diammonium hydrogen phosphate, 10 to 80 g of ammonium bicarbonate, 10 to 100 g of ammonium sulfate, and 50 to 220 g of potassium carbonate. 100 to 200 g of a foam extinguisher or a hydrocarbon-based surfactant foam extinguisher, a fluorosurfactant foam extinguisher, or a plurality of foam extinguishing agents, and diluted to 1000 ml with water Extinguishing agent for throwing fire extinguishing equipment.
- 比重が液温摂氏２０度において１．１０～１．１４であり、ＰＨ値が液温摂氏２０度において８．０～８．８であることを特徴とする請求項１に記載の投てき消火具用消火剤。 The throwing fire extinguisher according to claim 1, wherein the specific gravity is 1.10 to 1.14 at a liquid temperature of 20 degrees Celsius, and the PH value is 8.0 to 8.8 at a liquid temperature of 20 degrees Celsius. Fire extinguishing agent.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014507173A JP5928919B2 (en) | 2012-03-29 | 2012-03-29 | Manufacturing method of fire extinguishing agent for throwing fire extinguishing equipment |
| RU2014143538A RU2014143538A (en) | 2012-03-29 | 2012-03-29 | EXTINGUISHING SUBSTANCE FOR THROWING FIRE EXTINGUISHER |
| PCT/JP2012/058349 WO2013145207A1 (en) | 2012-03-29 | 2012-03-29 | Fire-extinguishing agent for throwing fire-extinguisher |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2012/058349 WO2013145207A1 (en) | 2012-03-29 | 2012-03-29 | Fire-extinguishing agent for throwing fire-extinguisher |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2013145207A1 true WO2013145207A1 (en) | 2013-10-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2012/058349 WO2013145207A1 (en) | 2012-03-29 | 2012-03-29 | Fire-extinguishing agent for throwing fire-extinguisher |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5928919B2 (en) |
| RU (1) | RU2014143538A (en) |
| WO (1) | WO2013145207A1 (en) |
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| CN104474659A (en) * | 2014-12-17 | 2015-04-01 | 刘树民 | Liquid extinguishing agent and water-based expendable fire extinguisher |
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| US9586070B2 (en) | 2013-01-22 | 2017-03-07 | Miraculum, Inc. | Flame retardant and fire extinguishing product for fires in solid materials |
| US9597538B2 (en) | 2013-01-22 | 2017-03-21 | Miraculum, Inc. | Flame retardant and fire extinguishing product for fires in liquids |
| WO2017163401A1 (en) * | 2016-03-25 | 2017-09-28 | 株式会社Ｊ－Ｓｔｙｌｅ | Method for producing fire extinguishing agent |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005288059A (en) * | 2004-03-31 | 2005-10-20 | Bonex:Kk | Manufacturing method of fire extinguishing agent |
| JP2007020965A (en) * | 2005-07-19 | 2007-02-01 | Bonex:Kk | Fire-extinguishing composition and fire extinguishing method |
| JP2007020966A (en) * | 2005-07-19 | 2007-02-01 | Bonex:Kk | Fire-extinguishing agent and fire extinguishing method |
| JP2010119754A (en) * | 2008-11-21 | 2010-06-03 | Kazuo Takase | Method of manufacturing fire extinguishing agent |
| WO2011158340A1 (en) * | 2010-06-16 | 2011-12-22 | 日本ファイヤープロテクト株式会社 | Method for producing fire-extinguishing agent and hand-thrown fire-extinguishing equipment |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5707585B2 (en) * | 2010-07-22 | 2015-04-30 | 株式会社Ｊ−Ｓｔｙｌｅ | Extinguishing agent manufacturing method |
-
2012
- 2012-03-29 WO PCT/JP2012/058349 patent/WO2013145207A1/en active Application Filing
- 2012-03-29 RU RU2014143538A patent/RU2014143538A/en not_active Application Discontinuation
- 2012-03-29 JP JP2014507173A patent/JP5928919B2/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005288059A (en) * | 2004-03-31 | 2005-10-20 | Bonex:Kk | Manufacturing method of fire extinguishing agent |
| JP2007020965A (en) * | 2005-07-19 | 2007-02-01 | Bonex:Kk | Fire-extinguishing composition and fire extinguishing method |
| JP2007020966A (en) * | 2005-07-19 | 2007-02-01 | Bonex:Kk | Fire-extinguishing agent and fire extinguishing method |
| JP2010119754A (en) * | 2008-11-21 | 2010-06-03 | Kazuo Takase | Method of manufacturing fire extinguishing agent |
| WO2011158340A1 (en) * | 2010-06-16 | 2011-12-22 | 日本ファイヤープロテクト株式会社 | Method for producing fire-extinguishing agent and hand-thrown fire-extinguishing equipment |
Cited By (27)
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| US9586070B2 (en) | 2013-01-22 | 2017-03-07 | Miraculum, Inc. | Flame retardant and fire extinguishing product for fires in solid materials |
| US9597538B2 (en) | 2013-01-22 | 2017-03-21 | Miraculum, Inc. | Flame retardant and fire extinguishing product for fires in liquids |
| US9878190B2 (en) | 2013-01-22 | 2018-01-30 | Miraculum, Inc. | Flame retardant and fire extinguishing product for fires in solid materials |
| CN104474659A (en) * | 2014-12-17 | 2015-04-01 | 刘树民 | Liquid extinguishing agent and water-based expendable fire extinguisher |
| WO2017015585A1 (en) * | 2015-07-22 | 2017-01-26 | Miraculum Applications, Inc. | Flame retardant and fire extinguishing product |
| WO2017163401A1 (en) * | 2016-03-25 | 2017-09-28 | 株式会社Ｊ－Ｓｔｙｌｅ | Method for producing fire extinguishing agent |
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| WO2020254869A1 (en) * | 2019-06-21 | 2020-12-24 | Kha Luan Trading Production Company Limited | Improved fire-extinguishing mixture |
| CN114100050A (en) * | 2020-08-27 | 2022-03-01 | 洪福安 | Fire extinguishing agent composition and method for producing the same |
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Also Published As
| Publication number | Publication date |
|---|---|
| RU2014143538A (en) | 2016-05-20 |
| JP5928919B2 (en) | 2016-06-01 |
| JPWO2013145207A1 (en) | 2015-08-03 |
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