WO2013122777A8 - Hydrolysis of used ionic liquid catalyst for disposal - Google Patents

Hydrolysis of used ionic liquid catalyst for disposal Download PDF

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Publication number
WO2013122777A8
WO2013122777A8 PCT/US2013/024728 US2013024728W WO2013122777A8 WO 2013122777 A8 WO2013122777 A8 WO 2013122777A8 US 2013024728 W US2013024728 W US 2013024728W WO 2013122777 A8 WO2013122777 A8 WO 2013122777A8
Authority
WO
WIPO (PCT)
Prior art keywords
disposal
ionic liquid
hydrolysis
liquid catalyst
phase
Prior art date
Application number
PCT/US2013/024728
Other languages
French (fr)
Other versions
WO2013122777A1 (en
Inventor
Hye-Kyung Cho Timken
Shawn Stephen HEALY
Shawn Shlomo Winter
Original Assignee
Chevron U.S.A. Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron U.S.A. Inc. filed Critical Chevron U.S.A. Inc.
Priority to CA2864081A priority Critical patent/CA2864081C/en
Priority to EP13749283.1A priority patent/EP2814515A4/en
Priority to KR1020147022535A priority patent/KR101497889B1/en
Priority to KR1020147031863A priority patent/KR101956064B1/en
Priority to CN201380009322.6A priority patent/CN104114193B/en
Priority to BR112014019696-6A priority patent/BR112014019696B1/en
Priority to AU2013219798A priority patent/AU2013219798B2/en
Priority to SG11201404453XA priority patent/SG11201404453XA/en
Priority to MX2014009535A priority patent/MX351851B/en
Publication of WO2013122777A1 publication Critical patent/WO2013122777A1/en
Publication of WO2013122777A8 publication Critical patent/WO2013122777A8/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
    • A62D3/35—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0298—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature the ionic liquids being characterised by the counter-anions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/006—Separating solid material from the gas/liquid stream by filtration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/007—Separating solid material from the gas/liquid stream by sedimentation
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
    • A62D2203/10—Apparatus specially adapted for treating harmful chemical agents; Details thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation

Abstract

We provide a process and apparatus for preparing a used catalyst for disposal, comprising: a. hydrolyzing a used ionic liquid catalyst comprising an anhydrous metal halide to produce a hydrolyzed product; and b. separating the hydrolyzed product into a liquid phase and a solid phase; wherein the liquid phase comprises a non-water-reactive aqueous phase and a hydrocarbon phase; and wherein the solid phase comprises a solid portion of the hydrolyzed product, that is not water reactive. A vessel is used for the hydrolyzing and a separator is used for the separating.
PCT/US2013/024728 2012-02-14 2013-02-05 Hydrolysis of used ionic liquid catalyst for disposal WO2013122777A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
CA2864081A CA2864081C (en) 2012-02-14 2013-02-05 Hydrolysis of used ionic liquid catalyst for disposal
EP13749283.1A EP2814515A4 (en) 2012-02-14 2013-02-05 Hydrolysis of used ionic liquid catalyst for disposal
KR1020147022535A KR101497889B1 (en) 2012-02-14 2013-02-05 Hydrolysis of used ionic liquid catalyst for disposal
KR1020147031863A KR101956064B1 (en) 2012-02-14 2013-02-05 Process and apparatus for safe disposal of used ionic liquid catalyst
CN201380009322.6A CN104114193B (en) 2012-02-14 2013-02-05 For disposing the ionic-liquid catalyst of hydrolysis
BR112014019696-6A BR112014019696B1 (en) 2012-02-14 2013-02-05 hydrolysis of a catalyst used for disposal
AU2013219798A AU2013219798B2 (en) 2012-02-14 2013-02-05 Hydrolysis of used ionic liquid catalyst for disposal
SG11201404453XA SG11201404453XA (en) 2012-02-14 2013-02-05 Hydrolysis of used ionic liquid catalyst for disposal
MX2014009535A MX351851B (en) 2012-02-14 2013-02-05 Hydrolysis of used ionic liquid catalyst for disposal.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/396,121 2012-02-14
US13/396,121 US8673800B2 (en) 2012-02-14 2012-02-14 Hydrolysis of used ionic liquid catalyst for disposal

Publications (2)

Publication Number Publication Date
WO2013122777A1 WO2013122777A1 (en) 2013-08-22
WO2013122777A8 true WO2013122777A8 (en) 2013-11-07

Family

ID=48945706

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/024728 WO2013122777A1 (en) 2012-02-14 2013-02-05 Hydrolysis of used ionic liquid catalyst for disposal

Country Status (10)

Country Link
US (3) US8673800B2 (en)
EP (1) EP2814515A4 (en)
KR (2) KR101956064B1 (en)
CN (2) CN104114193B (en)
AU (1) AU2013219798B2 (en)
BR (1) BR112014019696B1 (en)
CA (1) CA2864081C (en)
MX (1) MX351851B (en)
SG (2) SG10201505157SA (en)
WO (1) WO2013122777A1 (en)

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US9328296B2 (en) 2014-03-28 2016-05-03 Uop Llc Method for recovering entrained ionic liquid from an ionic liquid immiscible phase
US20160067668A1 (en) 2014-09-09 2016-03-10 Chevron U.S.A. Inc. Cost-effective materials for process units using acidic ionic liquids
US9580770B2 (en) * 2014-10-22 2017-02-28 Chevron U.S.A. Inc. Process for preparing a spent catalyst for precious metals recovery
US10017837B2 (en) 2014-10-22 2018-07-10 Chevron U.S.A. Inc. Metallurgical extraction technique to recover platinum group metals from a filter cake
US10052510B2 (en) * 2015-05-27 2018-08-21 Chevron U.S.A. Inc. Safe unloading and disposal of ionic liquid catalyst contaminated spent solids
US20170007993A1 (en) 2015-07-08 2017-01-12 Chevron U.S.A. Inc. Sulfur-contaminated ionic liquid catalyzed alklyation
US11602737B2 (en) * 2015-11-05 2023-03-14 Reliance Industries Limited Metal hydroxide based ionic liquid composition
WO2019113513A1 (en) 2017-12-08 2019-06-13 Baker Hughes, A Ge Company, Llc Ionic liquid based well asphaltene inhibitors and methods of using the same
CN109200978B (en) * 2018-03-01 2023-06-06 中国石油大学(北京) Method and system for treating waste catalyst of chloroaluminate ionic liquid and alkaline wastewater
WO2019202598A2 (en) * 2018-04-18 2019-10-24 Clairion Ltd. A process for separation of heavy metals and/or sulfur species from ionic liquids
EA202091413A1 (en) 2018-07-11 2020-09-24 Бейкер Хьюз Холдингз Ллк WELL ASPHALTEN INHIBITORS BASED ON IONIC LIQUID AND METHODS OF THEIR APPLICATION
CN111330651B (en) * 2018-12-19 2022-11-04 中国石油天然气集团有限公司 Waste ionic liquid catalyst treatment method and device
CN115869579A (en) * 2021-09-29 2023-03-31 中国石油化工股份有限公司 Curing method and curing device for aluminum chlorohydrate waste ionic liquid

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Also Published As

Publication number Publication date
MX2014009535A (en) 2014-09-12
US20130211175A1 (en) 2013-08-15
AU2013219798A1 (en) 2014-08-14
KR20140122246A (en) 2014-10-17
US20140350321A1 (en) 2014-11-27
CN105597630A (en) 2016-05-25
KR20140139136A (en) 2014-12-04
CN104114193B (en) 2016-02-03
CN104114193A (en) 2014-10-22
CA2864081C (en) 2017-04-25
BR112014019696B1 (en) 2019-11-12
CA2864081A1 (en) 2013-08-22
US8673800B2 (en) 2014-03-18
BR112014019696A8 (en) 2017-07-11
EP2814515A1 (en) 2014-12-24
WO2013122777A1 (en) 2013-08-22
CN105597630B (en) 2018-02-23
US9216393B2 (en) 2015-12-22
AU2013219798B2 (en) 2015-01-29
MX351851B (en) 2017-10-31
SG10201505157SA (en) 2015-07-30
KR101497889B1 (en) 2015-03-02
KR101956064B1 (en) 2019-03-11
BR112014019696A2 (en) 2017-06-20
EP2814515A4 (en) 2015-10-21
SG11201404453XA (en) 2014-08-28
US20130209324A1 (en) 2013-08-15

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