WO2013101299A1 - Batterie à circulation comprenant une membrane de séparation en polymère composite - Google Patents

Batterie à circulation comprenant une membrane de séparation en polymère composite Download PDF

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Publication number
WO2013101299A1
WO2013101299A1 PCT/US2012/042788 US2012042788W WO2013101299A1 WO 2013101299 A1 WO2013101299 A1 WO 2013101299A1 US 2012042788 W US2012042788 W US 2012042788W WO 2013101299 A1 WO2013101299 A1 WO 2013101299A1
Authority
WO
WIPO (PCT)
Prior art keywords
membrane
flow battery
ionomer
eptfe
separator membrane
Prior art date
Application number
PCT/US2012/042788
Other languages
English (en)
Inventor
Ralph Birchard Lloyd
Biswajit Choudhury
Murat ÜNLÜ
Original Assignee
E. I. Du Pont De Nemours And Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by E. I. Du Pont De Nemours And Company filed Critical E. I. Du Pont De Nemours And Company
Publication of WO2013101299A1 publication Critical patent/WO2013101299A1/fr

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H01M12/085—Zinc-halogen cells or batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0289—Means for holding the electrolyte
    • H01M8/0293—Matrices for immobilising electrolyte solutions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Fuel Cell (AREA)

Abstract

La présente invention se rapporte à des batteries à circulation qui présentent une meilleure résistance au croisement avec des espèces électroactives, une excellente efficacité de Coulomb et de tension et une excellente durabilité, lesdites batteries comprenant une couche de membre de séparation en polymère renforcé composite pour obtenir ces avantages en termes de performance. La membrane de séparation en polymère composite comprend un ionomère renforcé par ePTFE. L'ionomère est un ionomère d'acide perfluorosulfonique qui comprend sensiblement tous les groupes fonctionnels qui sont représentés par la formule SO3X dans laquelle X est l'hydrogène (H), le lithium (Li), le sodium (Na), le potassium (K) ou N(R1)(R2)(R3)(R4) et R1, R2, R3 et R4 sont identiques ou différents et sont l'hydrogène (H), CH3 ou C2H5. De préférence, sensiblement tous les groupes fonctionnels sont représentés par la formule SO3X dans laquelle X est l'hydrogène (H).
PCT/US2012/042788 2011-12-29 2012-06-15 Batterie à circulation comprenant une membrane de séparation en polymère composite WO2013101299A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161581165P 2011-12-29 2011-12-29
US61/581,165 2011-12-29

Publications (1)

Publication Number Publication Date
WO2013101299A1 true WO2013101299A1 (fr) 2013-07-04

Family

ID=46397642

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/042788 WO2013101299A1 (fr) 2011-12-29 2012-06-15 Batterie à circulation comprenant une membrane de séparation en polymère composite

Country Status (1)

Country Link
WO (1) WO2013101299A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014099874A1 (fr) * 2012-12-17 2014-06-26 E. I. Du Pont De Nemours And Company Batterie à circulation pourvue d'une membrane de séparation comprenant un ionomère
WO2015065102A1 (fr) * 2013-10-31 2015-05-07 주식회사 엘지화학 Batterie rechargeable au lithium
US20190214557A1 (en) * 2018-01-11 2019-07-11 Xergy Inc. Organic memristor
WO2021263065A1 (fr) * 2020-06-25 2021-12-30 The Chemours Company Fc, Llc Membranes échangeuses de cations étirées et hautement uniformes et leurs procédés de formation
WO2022038543A1 (fr) * 2020-08-19 2022-02-24 W. L. Gore & Associates, Inc. Membrane électrolyte composite

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3593566A (en) 1968-01-31 1971-07-20 African Explosives & Chem Means for and method of gauging articles
US3953566A (en) 1970-05-21 1976-04-27 W. L. Gore & Associates, Inc. Process for producing porous products
US3962153A (en) 1970-05-21 1976-06-08 W. L. Gore & Associates, Inc. Very highly stretched polytetrafluoroethylene and process therefor
US4180623A (en) 1977-12-19 1979-12-25 Lockheed Missiles & Space Company, Inc. Electrically rechargeable battery
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4552631A (en) 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US5082472A (en) * 1990-11-05 1992-01-21 Mallouk Robert S Composite membrane for facilitated transport processes
US5547551A (en) 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US6475661B1 (en) 1998-01-28 2002-11-05 Squirrel Holdings Ltd Redox flow battery system and cell stack
US20060183016A1 (en) * 2003-04-14 2006-08-17 Michael Kazacos Novel vanadium halide redox flow battery
WO2012109359A1 (fr) * 2011-02-08 2012-08-16 United Technologies Corporation Batterie en flux continu comportant une membrane de faible résistance

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3593566A (en) 1968-01-31 1971-07-20 African Explosives & Chem Means for and method of gauging articles
US3953566A (en) 1970-05-21 1976-04-27 W. L. Gore & Associates, Inc. Process for producing porous products
US3962153A (en) 1970-05-21 1976-06-08 W. L. Gore & Associates, Inc. Very highly stretched polytetrafluoroethylene and process therefor
US4187390A (en) 1970-05-21 1980-02-05 W. L. Gore & Associates, Inc. Porous products and process therefor
US4180623A (en) 1977-12-19 1979-12-25 Lockheed Missiles & Space Company, Inc. Electrically rechargeable battery
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4552631A (en) 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US5082472A (en) * 1990-11-05 1992-01-21 Mallouk Robert S Composite membrane for facilitated transport processes
US5547551A (en) 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US6475661B1 (en) 1998-01-28 2002-11-05 Squirrel Holdings Ltd Redox flow battery system and cell stack
US20060183016A1 (en) * 2003-04-14 2006-08-17 Michael Kazacos Novel vanadium halide redox flow battery
WO2012109359A1 (fr) * 2011-02-08 2012-08-16 United Technologies Corporation Batterie en flux continu comportant une membrane de faible résistance

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
JEE-AE SHIMA ET AL: "Nafion/e-PTFE Composite Membrane for Polymer Electrolyte Fuel Cells", vol. MA2005-03, 1 June 2005 (2005-06-01), pages 1, XP008156313, ISSN: 2151-2043, Retrieved from the Internet <URL:http://ma.ecsdl.org/content/MA2005-03/1/71.full.pdf> *
JOURNAL OF MEMBRANE SCIENCE, vol. 234, 2004, pages 51 - 54
WENPING WEI ET AL: "Poly(tetrafluoroethylene) reinforced sulfonated poly(ether ether ketone) membranes for vanadium redox flow battery application", JOURNAL OF POWER SOURCES, vol. 208, 1 June 2012 (2012-06-01), pages 421 - 425, XP055038391, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2012.02.047 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014099874A1 (fr) * 2012-12-17 2014-06-26 E. I. Du Pont De Nemours And Company Batterie à circulation pourvue d'une membrane de séparation comprenant un ionomère
JP2019216111A (ja) * 2012-12-17 2019-12-19 ザ ケマーズ カンパニー エフシーリミテッド ライアビリティ カンパニー アイオノマーを含むセパレータ膜を有するフロー電池
US10868324B2 (en) 2012-12-17 2020-12-15 The Chemours Company Fc, Llc Flow battery having a separator membrane comprising an ionomer
WO2015065102A1 (fr) * 2013-10-31 2015-05-07 주식회사 엘지화학 Batterie rechargeable au lithium
US9553338B2 (en) 2013-10-31 2017-01-24 Lg Chem, Ltd. Lithium secondary battery
US20190214557A1 (en) * 2018-01-11 2019-07-11 Xergy Inc. Organic memristor
WO2021263065A1 (fr) * 2020-06-25 2021-12-30 The Chemours Company Fc, Llc Membranes échangeuses de cations étirées et hautement uniformes et leurs procédés de formation
WO2022038543A1 (fr) * 2020-08-19 2022-02-24 W. L. Gore & Associates, Inc. Membrane électrolyte composite

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