WO2013097087A1 - Ultrasonic emulsification method and apparatus for replacing clouding agents - Google Patents

Ultrasonic emulsification method and apparatus for replacing clouding agents Download PDF

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Publication number
WO2013097087A1
WO2013097087A1 PCT/CN2011/084721 CN2011084721W WO2013097087A1 WO 2013097087 A1 WO2013097087 A1 WO 2013097087A1 CN 2011084721 W CN2011084721 W CN 2011084721W WO 2013097087 A1 WO2013097087 A1 WO 2013097087A1
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khz
frequency
ultrasonic
energy
ultrasonic emulsification
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PCT/CN2011/084721
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French (fr)
Chinese (zh)
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黄育斌
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Huang Yubin
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Priority to PCT/CN2011/084721 priority Critical patent/WO2013097087A1/en
Publication of WO2013097087A1 publication Critical patent/WO2013097087A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/41Emulsifying
    • B01F23/411Emulsifying using electrical or magnetic fields, heat or vibrations
    • B01F23/4111Emulsifying using electrical or magnetic fields, heat or vibrations using vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F31/00Mixers with shaking, oscillating, or vibrating mechanisms
    • B01F31/80Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations
    • B01F31/85Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations with a vibrating element inside the receptacle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2215/00Auxiliary or complementary information in relation with mixing
    • B01F2215/04Technical information in relation with mixing
    • B01F2215/0413Numerical information
    • B01F2215/0436Operational information
    • B01F2215/0454Numerical frequency values

Definitions

  • the present invention relates to a water and oil mixed product processing method and processing apparatus, and more particularly to a method of ultrasonic emulsification of a product in which water and oil are mixed, and a processing apparatus for carrying out the method.
  • a clouding agent also known as a turbidity agent, an opacifier or a turbidity agent
  • a turbidity agent is a food additive commonly used in beverages. It is mainly used in beverages and dairy products, as well as in ice cream, juice, jam, and concentrated fructose. It is also used in products such as healthy foods and probiotics. Its main purpose is to emulsify the water and oil mixed products, avoid the oil moisture layer, and make the skin feel more uniform and improve the taste of the food.
  • the clouding agent is generally prepared by adding and mixing various substances such as water, palm oil, emulsifier, and emulsion stabilizer.
  • plasticizers are a toxic chemical that is strictly prohibited for use in food. If it is eaten for a long time, it may cause abnormalities in the reproductive system and even cause teratogenicity and cancer. The above incidents have caused people to worry about products that use clouding agents.
  • the real clouding agent is a legal food additive
  • the main components of the emulsifier and emulsion stabilizer are also chemical compounds. When the intake is excessive, it may cause metabolic disorders, causing diarrhea, dizziness, etc. Caused by chronic diseases, this kind of harm is especially serious for the elderly, children, pregnant women and other special people.
  • the present invention provides a method for ultrasonically emulsifying a product in which water and oil are mixed without adding a clouding agent to avoid an oil moisture layer, more uniform perception, and improved food taste. Method and equipment.
  • a method of ultrasonic emulsification instead of a clouding agent comprising the following steps:
  • the transducer element converts electrical energy at a frequency of 15 kHz to 1000 kHz into mechanical vibrational energy
  • An ultrasonic emulsification apparatus for replacing a clouding agent, comprising: a power converter, a transducing element, a coupling element, and a transmitting head, wherein the power converter converts the power source into a power source having a frequency of 15 kHz to 1000 kHz
  • a transducing element is provided that converts electrical energy into mechanical vibration energy that is transmitted to the transmitting head through the coupling element.
  • the ultrasonic emulsification method instead of the clouding agent
  • the ultrasonic emulsification device instead of the clouding agent to treat the water and oil mixed products
  • the average droplet size of the emulsion is small, and the minimum is 0.5-0.2 ⁇ , even up to ⁇ . ⁇ , corresponding to the droplets floating 2cm for about 2000-5000 hours, the liquid emulsification stability time can reach Instruction manual
  • FIG. 1 is a schematic structural view of an ultrasonic emulsification apparatus of the present invention.
  • Ultrasonic emulsification technology is one of the methods.
  • the phacoemulsification technology realizes the mixing effect of "oil-in-water” emulsification, “water-oil-in-oil” emulsification, “dispersed phase” and “continuous” phase by the “cavitation effect” of ultrasonic waves to achieve the effect of producing emulsion.
  • the conventional ultrasonic emulsification technique results in an emulsion having an average droplet size of 1 ⁇ , which is inferior in stability and sometimes requires an external emulsion stabilizer to be stabilized.
  • the time for the droplet to float 2cm is extended by one hundred times to 100. hour. Therefore, in order to achieve the effect without using an emulsifier, an emulsion stabilizer or the like as an active ingredient in the clouding agent, it is necessary to treat the average size of the emulsion droplets obtained by the phacoemulsification method as small as possible, and the smaller the stable.
  • the device is provided with a plurality of gear positions of different power levels.
  • the lower frequency (below 20 kHz) can be used to make the droplet size of the prepared emulsified product less than 5 ⁇ , and the stability is guaranteed for more than 4 hours. It can be used for filling beverages or other products that need to be stored for a long time (such as cosmetics), and can use higher frequency (100kHz - 1000 kHz), so that the droplets are less than 0.2 ⁇ , which can make emulsion stability Guaranteed for more than 8000 hours, meet the shelf life requirements of the general product for half a year to one year. Thereby, the effect of adding a clouding agent to the food in an ultrasonic physical manner is achieved.
  • Embodiment An ultrasonic emulsification device for filling a beverage, using an ultrasonic vibration source, converting a power supply of a power supply of 50 Hz to a high-frequency 100 kHz power supply 1 through a power converter 2, and supplying the ultrasonic transducer element 3; through the transducer element 3, the high-frequency electrical energy is converted into mechanical vibration energy, and through the coupling element 4, the transducer element 3 and the emitter head 5 are coupled, and the mechanical vibration energy of the transducer element is transmitted to the emitter head 5, and finally
  • the ultrasonic energy is emitted by the emitter 5 to the oil (or flavor, sesame oil, etc.) and the water mixed (1: 50) of liquid (250 ml) 6 for 60-120 seconds (if the volume of the liquid increases, the time is appropriately extended) Ultrasonic emulsification, the droplet size of the emulsified product made of liquid is smaller than Instruction manual
  • stability can be guaranteed for more than 8000 hours, to meet the shelf life of the product for half a year to one year, to replace the role of clouding agent.

Abstract

Disclosed are an ultrasonic emulsification method for a product (6) formed by mixing water and oil and a processing apparatus for realizing the method. The method comprises the following steps: converting a power supply (1) into a power supply with a frequency of 15-1000 kHz; supplying electric energy with the frequency to a transducer element (3); the transducer element (3) converting the electric energy with the frequency of 15-1000 kHz into mechanical vibration energy; transmitting through a coupling element (4) the mechanical vibration energy to a transmitting head (5); and transmitting ultrasonic energy to the product (6) formed by mixing water and oil using the transmitting head (5). The apparatus comprises a power supply converter (2), a transducer element (3), a coupling element (4) and a transmitting head (5).

Description

说明书 一种代替起云剂作用的超声波乳化方法及设备 技术领域  Ultrasonic emulsification method and equipment instead of clouding agent
[0001] 本发明涉及一种水和油混合的产品加工方法以及加工设备, 尤其是一种水和油混合 的产品的超声波乳化方法以及实现该方法的加工设备。  [0001] The present invention relates to a water and oil mixed product processing method and processing apparatus, and more particularly to a method of ultrasonic emulsification of a product in which water and oil are mixed, and a processing apparatus for carrying out the method.
背景技术 Background technique
[0002] 起云剂又称浑浊剂、 乳浊剂或增浊剂, 是饮料中常用的一种食物添加剂, 主要应用 于饮料和奶类制品中, 同时在冰淇淋, 果汁、 果酱、 浓縮果糖、 健康食品、 益生菌等产品中 也有运用。 其主要目的是使水和油混合的产品乳化, 避免油水分层, 观感更为均匀, 改善食 品口感。 起云剂一般由水、 棕榈油、 乳化剂、 乳化稳定剂等多种物质添加混合制成。 由于起 云剂价格较高, 台湾一些不法商人用塑化剂代替起云剂中的棕榈油, 以牟取暴利。 塑化剂是 一种严禁用于食品的毒性化学物质, 若长期食用可能引起生殖系统异常、 甚至造成畸胎、 癌 症的危险。 以上事件, 造成了人们对使用了起云剂的产品的担心。 另外, 虽然真正的起云剂 是一种合法的食物添加剂, 但其中的主要成分乳化剂、 乳化稳定剂多也为化学合成物, 摄入 过量后, 容易引起代谢紊乱, 造成腹泻、 头晕等或引起慢性疾病, 这种危害对老人、 小孩、 孕妇等特感人群尤为严重。  [0002] A clouding agent, also known as a turbidity agent, an opacifier or a turbidity agent, is a food additive commonly used in beverages. It is mainly used in beverages and dairy products, as well as in ice cream, juice, jam, and concentrated fructose. It is also used in products such as healthy foods and probiotics. Its main purpose is to emulsify the water and oil mixed products, avoid the oil moisture layer, and make the skin feel more uniform and improve the taste of the food. The clouding agent is generally prepared by adding and mixing various substances such as water, palm oil, emulsifier, and emulsion stabilizer. Due to the high price of cloud-forming agents, some unscrupulous businessmen in Taiwan used plasticizers instead of palm oil in cloud-based agents to make huge profits. A plasticizer is a toxic chemical that is strictly prohibited for use in food. If it is eaten for a long time, it may cause abnormalities in the reproductive system and even cause teratogenicity and cancer. The above incidents have caused people to worry about products that use clouding agents. In addition, although the real clouding agent is a legal food additive, the main components of the emulsifier and emulsion stabilizer are also chemical compounds. When the intake is excessive, it may cause metabolic disorders, causing diarrhea, dizziness, etc. Caused by chronic diseases, this kind of harm is especially serious for the elderly, children, pregnant women and other special people.
发明内容 Summary of the invention
[0003] 针对现有技术中存在的不足, 本发明提供一种不需要添加起云剂就能使水和油混合 的产品达到避免油水分层、 观感更为均匀、 改善食品口感效果的超声波乳化方法及其设备。  [0003] In view of the deficiencies in the prior art, the present invention provides a method for ultrasonically emulsifying a product in which water and oil are mixed without adding a clouding agent to avoid an oil moisture layer, more uniform perception, and improved food taste. Method and equipment.
[0004] 一种代替起云剂作用的超声波乳化方法, 包括下列步骤: [0004] A method of ultrasonic emulsification instead of a clouding agent, comprising the following steps:
( A ) 将电源转化为频率为 15kHz— 1000kHz的电源, 并将该频率的电能提供给换能元件; (A) converting the power source into a power source with a frequency of 15 kHz to 1000 kHz, and supplying the power of the frequency to the transducer element;
( B ) 换能元件将频率为 15kHz— 1000kHz的电能转化为机械振动能; (B) The transducer element converts electrical energy at a frequency of 15 kHz to 1000 kHz into mechanical vibrational energy;
( C ) 通过联接元件将机械振动能传送至发射头;  (C) transmitting mechanical vibration energy to the transmitting head through the coupling element;
( D ) 通过发射头把超声波能量发射到水和油混合的产品中。  (D) The ultrasonic energy is emitted into the product of water and oil mixing through the emitter.
[0005] 一种代替起云剂作用的超声波乳化设备, 其特征是: 包括电源转换器、 换能元件、 联接元件和发射头, 所述电源转换器将电源转化为频率为 15kHz— 1000kHz的电源供给换能 元件, 所述换能元件将电能转化为机械振动能通过联接元件传送至发射头。  [0005] An ultrasonic emulsification apparatus for replacing a clouding agent, comprising: a power converter, a transducing element, a coupling element, and a transmitting head, wherein the power converter converts the power source into a power source having a frequency of 15 kHz to 1000 kHz A transducing element is provided that converts electrical energy into mechanical vibration energy that is transmitted to the transmitting head through the coupling element.
[0006] 运用所述的代替起云剂作用的超声波乳化方法, 结合代替起云剂作用的超声波乳化 设备对水和油混合的产品进行处理, 制成乳化液的平均液滴尺寸小, 最小可为 0.5— 0.2μηι、 甚至达 Ο.ΐμηι, 对应液滴上浮 2cm的时间约为 2000— 5000小时, 液体乳化的稳定时间可达 说明书 [0006] using the ultrasonic emulsification method instead of the clouding agent, combined with the ultrasonic emulsification device instead of the clouding agent to treat the water and oil mixed products, the average droplet size of the emulsion is small, and the minimum is 0.5-0.2μηι, even up to Ο.ΐμηι, corresponding to the droplets floating 2cm for about 2000-5000 hours, the liquid emulsification stability time can reach Instruction manual
4000—8000 小时, 这样就达到不添加起云剂却又满足一般乳化饮料半年至一年保质期的要 求和效果。  4000-8000 hours, this will meet the requirements and effects of not adding the clouding agent but satisfying the shelf life of the general emulsified beverage for half a year to one year.
附图说明 DRAWINGS
[0007] 图 1是本发明超声波乳化设备结构示意图。  1 is a schematic structural view of an ultrasonic emulsification apparatus of the present invention.
[0008] 其中图中 1.电源、 2.电源转换器、 3.换能元件、 4.联接元件、 5.发射头、 6. 水和油混 合的产品。  [0008] In the figure, 1. Power supply, 2. Power converter, 3. Transducing element, 4. Coupling element, 5. Transmitter, 6. Water and oil mixed product.
具体实施方式 detailed description
[0009] 超声波乳化技术正是其中一种方法。 超声乳化技术是以超声波的 "空化效应" 实现 "油掺水"乳化、 "水掺油"乳化、 "分散相"与 "连续"相的混合匀化, 以达到产生乳液的 效果。 但是, 普通的超声波乳化技术得到乳液平均液滴尺寸为 1一 ΙΟμηι, 稳定性较差, 有时 还需要外加乳化稳定剂加以稳定。 运用斯脱克斯方程式 (乳化液液滴的沉降速度公式) V=2r2( p 2- P l)g/9 n可知 (这里 v为液滴的沉降速度, r为分散相液滴的半径, P 2、 p i 为 分散相和分散介质的密度, n为分散介质的粘度), 沉浮速度与液滴的半径之平方成正比, 为了提高乳状液的稳定性, 必须要使分散相液滴充分小。 通过实验可得, 当常用饮料乳化液 平均液滴尺寸 ΙΟμηι时, 液滴上浮 2cm的时间约为 1小时, 当液滴尺寸为 Ιμηι时, 液滴上 浮 2cm的时间延长了一百倍, 为 100小时。) 因此, 为了可不用乳化剂、 乳化稳定剂等起云 剂中的有效成分, 却能达到效果, 就必须将超声乳化方法得到的乳液液滴的平均尺寸处理得 越小越好, 越小越稳定。 [0009] Ultrasonic emulsification technology is one of the methods. The phacoemulsification technology realizes the mixing effect of "oil-in-water" emulsification, "water-oil-in-oil" emulsification, "dispersed phase" and "continuous" phase by the "cavitation effect" of ultrasonic waves to achieve the effect of producing emulsion. However, the conventional ultrasonic emulsification technique results in an emulsion having an average droplet size of 1 ΙΟμηι, which is inferior in stability and sometimes requires an external emulsion stabilizer to be stabilized. Using the Stokes equation (the formula for the sedimentation velocity of emulsion droplets) V = 2r2( p 2- P l)g/9 n (where v is the sedimentation velocity of the droplet, r is the radius of the droplet of the dispersed phase, P 2, pi is the density of the dispersed phase and the dispersion medium, n is the viscosity of the dispersion medium), and the speed of the sedimentation is proportional to the square of the radius of the droplet. In order to improve the stability of the emulsion, the droplets of the dispersed phase must be sufficiently small. . Through experiments, when the average droplet size of the common beverage emulsion is ΙΟμηι, the time for the droplet to float 2cm is about 1 hour. When the droplet size is Ιμηι, the time for the droplet to float 2cm is extended by one hundred times to 100. hour. Therefore, in order to achieve the effect without using an emulsifier, an emulsion stabilizer or the like as an active ingredient in the clouding agent, it is necessary to treat the average size of the emulsion droplets obtained by the phacoemulsification method as small as possible, and the smaller the stable.
[0010] 本设备设置有多种不同功率级别的档位。 当在快餐店、 咖啡屋、 冷热饮料店等速食 店使用时, 可采用较低的频率 (20kHz 以下), 使制成的乳化产品的液滴尺寸小于 5μηι, 稳 定性保证在 4 小时以上即可; 而对运用于灌装饮料或其它需较长期保存的产品 (如化妆品 等), 可使用较高的频率 (100kHz— 1000 kHz), 使液滴小于 0.2μηι, 对应可使乳化稳定性保 证在 8000 小时以上, 满足一般产品半年至一年的保质期的要求。 从而达到以超声波物理的 方式代替在食品中添加起云剂的作用。  [0010] The device is provided with a plurality of gear positions of different power levels. When used in fast food restaurants such as fast food restaurants, coffee houses, hot and cold drinks shops, etc., the lower frequency (below 20 kHz) can be used to make the droplet size of the prepared emulsified product less than 5μηι, and the stability is guaranteed for more than 4 hours. It can be used for filling beverages or other products that need to be stored for a long time (such as cosmetics), and can use higher frequency (100kHz - 1000 kHz), so that the droplets are less than 0.2μηι, which can make emulsion stability Guaranteed for more than 8000 hours, meet the shelf life requirements of the general product for half a year to one year. Thereby, the effect of adding a clouding agent to the food in an ultrasonic physical manner is achieved.
[0011] 实施例: 一种运用于灌装饮料的超声波乳化设备,运用超声波振动源, 把供电局民用 供电 50Hz的电能通过电源转换器 2转化为高频率 100kHz 电源 1, 提供给超声波换能元件 3; 通过换能元件 3, 把高频率电能转化为机械振动能, 并通过联接元件 4, 联接好换能元件 3和发射头 5, 将换能元件之机械振动能传送到发射头 5, 最后由发射头 5把超声波能量发 射到油 (或香精、 香油等)和水混合 (1 : 50) 的液体 (250 毫升) 6 中去, 经过 60 -120 秒 (如液体体积增加, 时间适当延长) 的超声波乳化, 使液体制成的乳化产品的液滴尺寸小于 说明书 [0011] Embodiment: An ultrasonic emulsification device for filling a beverage, using an ultrasonic vibration source, converting a power supply of a power supply of 50 Hz to a high-frequency 100 kHz power supply 1 through a power converter 2, and supplying the ultrasonic transducer element 3; through the transducer element 3, the high-frequency electrical energy is converted into mechanical vibration energy, and through the coupling element 4, the transducer element 3 and the emitter head 5 are coupled, and the mechanical vibration energy of the transducer element is transmitted to the emitter head 5, and finally The ultrasonic energy is emitted by the emitter 5 to the oil (or flavor, sesame oil, etc.) and the water mixed (1: 50) of liquid (250 ml) 6 for 60-120 seconds (if the volume of the liquid increases, the time is appropriately extended) Ultrasonic emulsification, the droplet size of the emulsified product made of liquid is smaller than Instruction manual
0.2μηι, 稳定性可保证在 8000小时以上, 满足产品半年至一年的保质期的要求, 起到代替起 云剂的作用。  0.2μηι, stability can be guaranteed for more than 8000 hours, to meet the shelf life of the product for half a year to one year, to replace the role of clouding agent.

Claims

权利要求书 Claim
1. 一种代替起云剂作用的超声波乳化方法, 包括下列步骤:  1. A method of ultrasonic emulsification instead of a clouding agent, comprising the following steps:
( A ) 将电源转化为频率为 15kHz— 1000kHz的电源, 并将该频率的电能提供给换能元件; ( B ) 换能元件将频率为 15kHz— 1000kHz的电能转化为机械振动能;  (A) converting the power source into a power source with a frequency of 15 kHz to 1000 kHz, and supplying the power of the frequency to the transducer element; (B) the transducer element converting electrical energy having a frequency of 15 kHz to 1000 kHz into mechanical vibration energy;
( C ) 通过联接元件将机械振动能传送至发射头;  (C) transmitting mechanical vibration energy to the transmitting head through the coupling element;
( D ) 通过发射头把超声波能量发射到水和油混合的产品中。  (D) The ultrasonic energy is emitted into the product of water and oil mixing through the emitter.
2. 一种代替起云剂作用的超声波乳化设备, 其特征是: 包括电源转换器、 换能元件、 联接 元件和发射头, 所述电源转换器将电源转化为频率为 15kHz— 1000kHz 的电源供给换能元 件, 所述换能元件将电能转化为机械振动能通过联接元件传送至发射头。  2. An ultrasonic emulsification apparatus instead of a clouding agent, comprising: a power converter, a transducing element, a coupling element and a transmitting head, wherein the power converter converts the power source into a power supply with a frequency of 15 kHz to 1000 kHz A transducer element that converts electrical energy into mechanical vibration energy that is transmitted to the emitter through the coupling element.
PCT/CN2011/084721 2011-12-27 2011-12-27 Ultrasonic emulsification method and apparatus for replacing clouding agents WO2013097087A1 (en)

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CN2636980Y (en) * 2003-08-28 2004-09-01 金仲民 Supersonic reactor
JP2005103530A (en) * 2003-10-01 2005-04-21 Shinka Sangyo Kk Apparatus for processing liquid
CN101543740A (en) * 2009-04-09 2009-09-30 姚明勤 Emulsifier for supersonic ferromagnetic cavity effect control
CN101837256A (en) * 2010-05-26 2010-09-22 昆明理工大学 Method for preparing high-quality emulsified heavy oil
CN102246996A (en) * 2011-08-16 2011-11-23 黄育斌 Ultrasonic emulsifying method and equipment for replacing role of clouding agent

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