WO2013083783A3 - Procédé de synthèse de copolymères à blocs comprenant des monomères vinyliques polaires et apolaires - Google Patents

Procédé de synthèse de copolymères à blocs comprenant des monomères vinyliques polaires et apolaires Download PDF

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Publication number
WO2013083783A3
WO2013083783A3 PCT/EP2012/074808 EP2012074808W WO2013083783A3 WO 2013083783 A3 WO2013083783 A3 WO 2013083783A3 EP 2012074808 W EP2012074808 W EP 2012074808W WO 2013083783 A3 WO2013083783 A3 WO 2013083783A3
Authority
WO
WIPO (PCT)
Prior art keywords
polar
vinyl monomers
block copolymers
copolymers including
synthesizing block
Prior art date
Application number
PCT/EP2012/074808
Other languages
English (en)
Other versions
WO2013083783A2 (fr
Inventor
Vincent Monteil
Christophe Boisson
Roger Spitz
Etienne GRAU
Jean-Pierre Broyer
Original Assignee
Centre National De La Recherche Scientifique (C.N.R.S)
Université Claude Bernard Lyon 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National De La Recherche Scientifique (C.N.R.S), Université Claude Bernard Lyon 1 filed Critical Centre National De La Recherche Scientifique (C.N.R.S)
Publication of WO2013083783A2 publication Critical patent/WO2013083783A2/fr
Publication of WO2013083783A3 publication Critical patent/WO2013083783A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Procédé de synthèse de copolymères à blocs comprenant des monomères vinyliques polaires et apolaires en présence: (a) d'un catalyseur comprenant un métal, au moins un ligand oxydant et au moins un ligand complexant, électrodonneur et monodentate, et (b) d'un composé générateur de radicaux libres. L'invention concerne un procédé de synthèse de copolymères à blocs comprenant des monomères vinyliques polaires et apolaires, ainsi que les copolymères issus dudit procédé.
PCT/EP2012/074808 2011-12-09 2012-12-07 Procédé de synthèse de copolymères à blocs comprenant des monomères vinyliques polaires et apolaires WO2013083783A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1161409 2011-12-09
FR1161409A FR2983860A1 (fr) 2011-12-09 2011-12-09 Procede de synthese de copolymeres a blocs comprenant des monomeres vinyliques polaires et apolaires

Publications (2)

Publication Number Publication Date
WO2013083783A2 WO2013083783A2 (fr) 2013-06-13
WO2013083783A3 true WO2013083783A3 (fr) 2013-08-01

Family

ID=47356038

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2012/074808 WO2013083783A2 (fr) 2011-12-09 2012-12-07 Procédé de synthèse de copolymères à blocs comprenant des monomères vinyliques polaires et apolaires

Country Status (2)

Country Link
FR (1) FR2983860A1 (fr)
WO (1) WO2013083783A2 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3502153A1 (fr) 2017-12-19 2019-06-26 Université de Liège Copolymérisation de blocs d'éthylène par polymérisation radicalaire de cobalt
CN112358585B (zh) * 2020-10-30 2023-03-14 内蒙古工业大学 一种极性单体与非极性单体分散共聚制备聚合物纳米微球的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2377249A1 (fr) * 1999-06-25 2001-01-04 Bayer Aktiengesellschaft Procede de copolymerisation de monomeres polaires et non polaires
FR2937643A1 (fr) * 2008-10-27 2010-04-30 Arkema France Nouveaux copolymeres a blocs d'olefines polaires et apolaires

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2377249A1 (fr) * 1999-06-25 2001-01-04 Bayer Aktiengesellschaft Procede de copolymerisation de monomeres polaires et non polaires
FR2937643A1 (fr) * 2008-10-27 2010-04-30 Arkema France Nouveaux copolymeres a blocs d'olefines polaires et apolaires

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
DAMIEN GUIRONNET ET AL: "Insertion Polymerization of Acrylate", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 131, no. 2, 21 January 2009 (2009-01-21), pages 422 - 423, XP055023527, ISSN: 0002-7863, DOI: 10.1021/ja808017n *
ENDRE SZUROMI ET AL: "Polymerization of Norbornene and Methyl Acrylate by a Bimetallic Palladium(II) Allyl Complex", ORGANOMETALLICS, vol. 27, no. 3, 1 February 2008 (2008-02-01), pages 402 - 409, XP055023531, ISSN: 0276-7333, DOI: 10.1021/om700921f *
HAJIME YASUDA ET AL: "NEW APPROACH TO BLOCK COPOLYMERIZATIONS OF ETHYLENE WITH ALKYL METHACRYLATES AND LACTONES BY UNIQUE CATALYSIS WITH ORGANOLANTHANIDE COMPLEXES", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC; US, vol. 25, no. 19, 14 September 1992 (1992-09-14), pages 5115 - 5116, XP000298710, ISSN: 0024-9297, DOI: 10.1021/MA00045A045 *
KOCHI TAKUYA ET AL: "Formation of Linear Copolymers of Ethylene and Acrylonitrile Catalyzed by Phosphine Sulfonate Palladium Complexes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC; US, vol. 129, no. 29, 25 July 2007 (2007-07-25), pages 8948 - 8949, XP008132604, ISSN: 0002-7863, [retrieved on 20070627], DOI: 10.1021/JA0725504 *
RAJESH CHITTA ET AL: "Characterization of Ethylene methyl methacrylate and Ethylene butylacrylate Copolymers with Interactive Liquid Chromatography", MACROMOLECULAR SYMPOSIA, WILEY VCH VERLAG, WEINHEIM, DE, vol. 298, no. 1, 1 December 2010 (2010-12-01), pages 191 - 199, XP009157491, ISSN: 1022-1360, [retrieved on 20110107] *

Also Published As

Publication number Publication date
FR2983860A1 (fr) 2013-06-14
WO2013083783A2 (fr) 2013-06-13

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