WO2013077727A4 - Method of producing graphene, carbon nano-dendrites, nano-hexacones and nanostructured materials using waste tyres - Google Patents
Method of producing graphene, carbon nano-dendrites, nano-hexacones and nanostructured materials using waste tyres Download PDFInfo
- Publication number
- WO2013077727A4 WO2013077727A4 PCT/MY2012/000286 MY2012000286W WO2013077727A4 WO 2013077727 A4 WO2013077727 A4 WO 2013077727A4 MY 2012000286 W MY2012000286 W MY 2012000286W WO 2013077727 A4 WO2013077727 A4 WO 2013077727A4
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbon nanomaterials
- producing carbon
- particulates
- tyres
- tyres according
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/18—Nanoonions; Nanoscrolls; Nanohorns; Nanocones; Nanowalls
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/312—Preparation
- C01B32/318—Preparation characterised by the starting materials
- C01B32/324—Preparation characterised by the starting materials from waste materials, e.g. tyres or spent sulfite pulp liquor
Abstract
The present invention relates to a method of producing carbon nanomaterials using tyres, characterized by the steps of: thermal decomposition of the tyre to produce coal; grinding the coal to obtain particulates; mixing the particulates with transition metal–based catalyst; and heating the particulates to produce carbon nanomaterials; wherein said carbon nanomaterials comprises graphene, carbon nanostructures including nano-dendrites, nano-hexacones, nanospheres, nano-donuts, nanoparticles and nanorods, or combination thereof.
Claims
1. A method of producing carbon nanomaterials using tyres, characterized by
the steps of:
thermal decomposition of the tyre to produce coal;
grinding the coal to obtain particulates;
mixing the fine particulates with transition metal-based catalyst; and heating the fine particulates to produce carbon nanomaterials;
wherein the carbon nanomaterials comprises graphene, carbon nanostructures including nano-dendrites, nano-hexacones, nanospheres, nano-donuts, nanoparticles and nanorods, or combination thereof.
2. A method of producing carbon nanomaterials using tyres according to claim
1 , wherein the tyres are waste tyres.
3. A method of producing carbon nanomaterials using tyres according to claim
1, wherein the tyres is shredded and cut into pieces to the size of 1-4cm2 prior to thermal decomposition.
4. A method of producing carbon nanomaterials using tyres according to claim
1, wherein the step of thermal decomposition of the tyre is carried out for 2-4 hours at 400-800°C.
5. A method of producing carbon nanomaterials using tyres according to claim
1, wherein the method further comprises pre-treating the tyre by immersing said tyre in 30% (w/w) solution of zinc chloride, refluxing for 24 hours, and subsequently drying before thermal decomposition.
6. A method of producing carbon nanomaterials using tyres according to claim
1, wherein the fine particulates are mixed with the transition metal-based catalyst in a ratio of 2-5:1 by weight of the particulates to the transition metal-based catalyst.
7. A method of producing carbon nanomaterials using tyres according to claim 1 , wherein the transition metal-based catalyst is selected from a group consisting of chromium compound and iron compound.
8. A method of producing carbon nanomaterials using tyres according to claim 7, wherein the chromium compound is mixed with the particulates in a ratio of 1:2 by weight of the chromium compound to the particulates.
9. A method of producing carbon nanomaterials using tyres according to claim 7, wherein the chromium compound is chromium nitrate.
10. A method of producing carbon nanomaterials using tyres according to claim 1 and claim 8, wherein the particulates mixed with chromium compound are heated for 1-3 hours at 400-800°C.
11. A method of producing carbon nanomaterials using tyres according to claim 7, wherein the iron compound is mixed with the particulates in a ratio of 1 :4-5 by weight of the iron compound to the particulates.
12. A method of producing carbon nanomaterials using tyres according to claim 7, wherein the iron compound is selected from ferrocene and ferric chloride.
13. A method of producing carbon nanomaterials using tyres according to claim 1, claim 11 and claim 12, wherein the particulates mixed with ferrocene are heated for 1-3 hours at 500-700°C, followed by 30-90 minutes at 700-900°C.
14. A method of producing carbon nanomaterials using tyres according to claim 1, claim 11 and claim 12, wherein the particulates mixed with ferric chloride are heated for 1-3 hours at 500-700°C, followed by 30-90 minutes at 700-900°C.
A method of producing carbon nanomaterials using tyres according to claim 1 , claim 11 and claim 12, wherein the particulates mixed with ferric chloride are heated for 30-90 minutes at 500-700°C, followed by 1-3 hours at 700-900°C.
A method of producing carbon nanomaterials using tyres according to claim 1 , claim 11 and claim 12, wherein the particulates mixed with ferric chloride are heated for 30-90 minutes at 800-1200°C.
A method of producing carbon nanomaterials using tyres without any pre-treatment, characterized by the steps of:
mixing waste tyre pieces with transition metal-based catalyst, wherein the transition metal-based catalyst is ferric chloride; and
heating the mixture for 30-90 minutes at 800-1200°C to obtain graphene and carbon nanoparticles.
A method of producing carbon nanomaterials using tyres according to claim 17, wherein the feme chloride is mixed with the tyre pieces in a ratio of 1 :5 by weight.
Statement under Article 19(1) (Rule 46.4)
The International Search Report has cited one document (D2 - WO 2010-1 1 1624 Al, NORTFASTKRN UNIVERSITY et al.) that, in the opinion of the Examiner, has made claim 17 of the present application obvious over disclosure of D2. Accordingly, the following amendments have been made to narrow the scope of the claims and therefore exclude the subject matter that caused to be obvious by the prior art cited in the International Search Report and Written Opinion of the International Searching Authority.
1. Claim 17 has been amended to define the transition metal-based catalyst as ferric chloride.
2. Claim 18 has been cancelled followed by the amendment made to Claim 17 as above.
3. Claims 19 have been amended to clarify their appendancy to Claim 17 and have been assigned with number 18 followed by the amendment made to Claims 17 and 18.
The amended claims do not go beyond the disclosure in the international application as filed. The amendments do not have any impact on the drawings.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU92256A LU92256B1 (en) | 2011-11-24 | 2012-11-23 | Method of producing graphene, carbon nano-dendrites, nano-hexacones and nano-structured materials using waste tyres |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MYPI2011005712 | 2011-11-24 | ||
| MYPI2011005712 MY150618A (en) | 2011-11-24 | 2011-11-24 | Method of producing graphene, carbon nano-dendrites, nano-hexacones and nanostructured materials using waste tyres |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2013077727A1 WO2013077727A1 (en) | 2013-05-30 |
| WO2013077727A4 true WO2013077727A4 (en) | 2013-07-25 |
Family
ID=48470096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/MY2012/000286 WO2013077727A1 (en) | 2011-11-24 | 2012-11-23 | Method of producing graphene, carbon nano-dendrites, nano-hexacones and nanostructured materials using waste tyres |
Country Status (3)
| Country | Link |
|---|---|
| LU (1) | LU92256B1 (en) |
| MY (1) | MY150618A (en) |
| WO (1) | WO2013077727A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016184355A1 (en) * | 2015-05-19 | 2016-11-24 | 张雨虹 | Method for preparing graphene using coal as raw material |
| CN108163844B (en) * | 2018-03-19 | 2020-02-11 | 程贤甦 | Preparation method for preparing graphene by using waste tire rubber powder |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1544236A1 (en) * | 2003-12-15 | 2005-06-22 | Bio Watt Ibérica, S.L. | System for dissolving unuseable tires to obtain oils, coal and steel |
| JP4301410B2 (en) * | 2004-09-07 | 2009-07-22 | 株式会社北陸エコグラファイト | Method for producing dry distillation graphite from waste tires |
| US7842271B2 (en) * | 2004-12-07 | 2010-11-30 | Petrik Viktor I | Mass production of carbon nanostructures |
| JP5347191B2 (en) * | 2008-02-06 | 2013-11-20 | 株式会社Ｅ・Ｃ・Ｏ | Method for producing carbon nanotube |
| JP2009227561A (en) * | 2008-03-24 | 2009-10-08 | Korona:Kk | Method for producing nanocarbon using waste tire carbon |
| EP3584217B1 (en) * | 2009-03-26 | 2023-07-05 | Northeastern University | Carbon nanostructures from pyrolysis of organic materials |
| US8029759B2 (en) * | 2009-03-27 | 2011-10-04 | Ohio University | Pretreatment method for the synthesis of carbon nanotubes and carbon nanostructures from coal and carbon chars |
| US8257678B2 (en) * | 2009-07-31 | 2012-09-04 | Massachusetts Institute Of Technology | Systems and methods related to the formation of carbon-based nanostructures |
-
2011
- 2011-11-24 MY MYPI2011005712 patent/MY150618A/en unknown
-
2012
- 2012-11-23 LU LU92256A patent/LU92256B1/en active
- 2012-11-23 WO PCT/MY2012/000286 patent/WO2013077727A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013077727A1 (en) | 2013-05-30 |
| MY150618A (en) | 2014-02-05 |
| LU92256B1 (en) | 2013-11-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Xu et al. | One-step synthesis of Fe-doped surface-alkalinized g-C3N4 and their improved visible-light photocatalytic performance | |
| Dwivedi et al. | Recycling of waste tire by pyrolysis to recover carbon black: Alternative & environment-friendly reinforcing filler for natural rubber compounds | |
| Chen et al. | Designed nitrogen doping of few-layer graphene functionalized by selective oxygenic groups | |
| Zhou et al. | The influence of graphene based smoke suppression agents on reduced fire hazards of polystyrene composites | |
| Peng et al. | Synthesis of MoS2/g-C3N4 as a solar light-responsive photocatalyst for organic degradation | |
| Xu et al. | Coal-derived nitrogen, phosphorus and sulfur co-doped graphene quantum dots: A promising ion fluorescent probe | |
| CN102807720B (en) | Rubber formula and preparation method thereof | |
| AU2018260600A1 (en) | Process for regenerating a monolithic, macro-structural, inter-penetrating elastomer network morphology from ground tire rubber particles | |
| Zhang et al. | Microwave-aided synthesis of BiOI/g-C3N4 composites and their enhanced catalytic activities for Cr (VI) removal | |
| Shi et al. | Co-MOF@ MXene hybrids flame retardants for enhancing the fire safety of thermoplastic polyurethanes | |
| CN113896950B (en) | Monoatomic zinc material capable of replacing zinc oxide used in rubber field and preparation method thereof | |
| WO2013077727A4 (en) | Method of producing graphene, carbon nano-dendrites, nano-hexacones and nanostructured materials using waste tyres | |
| Oh et al. | Structural insights into photocatalytic performance of carbon nitrides for degradation of organic pollutants | |
| Wang et al. | Supramolecular engineered ultrathin MXene towards fire safe polylactic acid composites | |
| CN114832845A (en) | Composite catalyst prepared by utilizing recycled lithium battery material and preparation method thereof | |
| CN103710876A (en) | High-strength sound absorbing cotton and preparation method thereof | |
| Essawy et al. | Fabrication of single-walled carbon nanotubes from vulcanized scrap rubber via thermal chemical vapor deposition | |
| CN111675843A (en) | High-strength flame-retardant drain pipe and preparation method thereof | |
| CN101402744A (en) | Reutilization method for grinding material generated in brake flat production process | |
| Huang et al. | A comparison of surface morphology and chemistry of pyrolytic carbon blacks with commercial carbon blacks | |
| Gao et al. | Table tennis bat poplar baseplate-derived bismuth molybdate with efficient visible-light photocatalytic activity | |
| CN102372876A (en) | TPV material for highway isolation belt | |
| KR101449096B1 (en) | Biodegradable composites for shielding of electromagnetic wave containing carbon nanomaterials and biodegradable polymer and a fabrication process thereof | |
| CN106674777B (en) | Airtight layer adhesive and preparation method thereof | |
| CN107032346B (en) | The method for recycling carbon fiber enhancement resin base composite material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12851223 Country of ref document: EP Kind code of ref document: A1 |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 2014/04002 Country of ref document: TR |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 12851223 Country of ref document: EP Kind code of ref document: A1 |