WO2013059193A1 - Micro channel heat exchanger alloy system - Google Patents

Micro channel heat exchanger alloy system Download PDF

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Publication number
WO2013059193A1
WO2013059193A1 PCT/US2012/060419 US2012060419W WO2013059193A1 WO 2013059193 A1 WO2013059193 A1 WO 2013059193A1 US 2012060419 W US2012060419 W US 2012060419W WO 2013059193 A1 WO2013059193 A1 WO 2013059193A1
Authority
WO
WIPO (PCT)
Prior art keywords
manifolds
tube
circular tubes
series aluminum
aluminum
Prior art date
Application number
PCT/US2012/060419
Other languages
French (fr)
Inventor
Thomas J. Garosshen
Mary Teresa LOMBARDO
Original Assignee
Carrier Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carrier Corporation filed Critical Carrier Corporation
Priority to CN201280051090.6A priority Critical patent/CN103857973A/en
Priority to EP12784390.2A priority patent/EP2769162A1/en
Priority to US14/352,510 priority patent/US20140262182A1/en
Publication of WO2013059193A1 publication Critical patent/WO2013059193A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00—Tubular elements; Assemblies of tubular elements
    • F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
    • F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
    • F28F1/126—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element consisting of zig-zag shaped fins
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/02—Alloys based on aluminium with silicon as the next major constituent
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
    • F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
    • F28D1/053—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being straight
    • F28D1/0535—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being straight the conduits having a non-circular cross-section
    • F28D1/05366—Assemblies of conduits connected to common headers, e.g. core type radiators
    • F28D1/05383—Assemblies of conduits connected to common headers, e.g. core type radiators with multiple rows of conduits or with multi-channel conduits
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00—Tubular elements; Assemblies of tubular elements
    • F28F1/02—Tubular elements of cross-section which is non-circular
    • F28F1/022—Tubular elements of cross-section which is non-circular with multiple channels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
    • F28F21/081—Heat exchange elements made from metals or metal alloys
    • F28F21/084—Heat exchange elements made from metals or metal alloys from aluminium or aluminium alloys

Definitions

  • Micro channel heat exchangers MCHXs and their alloys of construction were developed for automotive applications. Initial applications of these alloy systems resulted in poor corrosion performance, however, in heating, ventilation and air conditioning (HVAC) applications, such as roof top chillers. This problem is especially pronounced in coastal and/or industrial environments, where deterioration of the MCHX tubing can result in refrigerant leaks and system shutdown within a year. In addition, in coastal locations, fin disbonding due to corrosion effects may be a significant problem.
  • HVAC heating, ventilation and air conditioning
  • FIG. 4 is a perspective view of a manifold of the MCHX of FIG. 1.
  • This invention involves aluminum micro channel heat exchanger (MCHX) alloy systems including multi-channel (or multi-port) extruded tubes, with or without sacrificial anodic surface treatments, such as zinc, fin alloys cladded with a silicon rich lower melting point layer, a manifold (or header) alloy and a brazing flux.
  • MCHX micro channel heat exchanger
  • the tube 40 includes at least one of 31108 alloy material (especially with lithium flux), which includes 0.21-0.25 wt% silicon, 0.12 wt% iron, 0.01 wt% copper, 0.90-1.10 wt% manganese, 0.05 wt% magnesium, 0.02 wt% chromium, 0.03 wt% zinc and 0.14-0.20 wt% titanium, 31107 alloy material and 31104 alloy material, which includes 0.10 wt% silicon, 0.01 wt% copper, 0.05 wt% magnesium, 0.05 wt% zinc, 0.12 wt% iron, 1.10 wt% manganese (or magnesium), 0.05 wt% chromium and 0.05 wt% titanium, and extends from the first manifold 20 to the second manifold 30.
  • 31108 alloy material especially with lithium flux
  • the tube 40 may be plural in number with each of the plural tubes 40 extending from the first manifold 20 to the second manifold 30.
  • Each of the plural tubes 40 is also formed to define multiple channels 41.
  • the tube 40 may have a non-circular cross-section, such as an elongate cross-section, with the multiple channels 41 being arrayed along the non-circular cross-section.
  • the multiple channels 41 would be arrayed along the elongations of the tube 40.
  • the fin structure 50 may also be plural in number with each of the plural fin structures disposed in thermal communication with the tube(s) 40.
  • the fin structures 50 may include louvers 52 arranged along a longitudinal length of the tube(s) 40 to increase fin structure surface area and, therefore, heat transfer.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geometry (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Abstract

A micro channel heat exchanger alloy system is provided and includes first and second manifolds, including a 3000 series aluminum, each of the first and second manifolds being formed to define a respective interior therein, a tube, including at least one of 31108 and 31104 alloy material, extending from the first to the second manifold and being formed to define multiple channels by which the respective interiors of the first and the second manifolds fluidly communicate, a fin structure, including at least 3003 alloy material, disposed in thermal communication with the tube, the fin structure being cladded with a silicon rich layer, including a 4000 series aluminum and a flux material applied to surfaces of the first and second manifolds, the tube and the fin structure.

Description

MICRO CHANNEL HEAT EXCHANGER ALLOY SYSTEM
BACKGROUND OF THE INVENTION
[0001] Aspects of the present invention relate to micro channel heat exchangers
(MCHXs) and, more particularly, to an MCHX alloy system.
[0002] Micro channel heat exchangers (MCHXs) and their alloys of construction were developed for automotive applications. Initial applications of these alloy systems resulted in poor corrosion performance, however, in heating, ventilation and air conditioning (HVAC) applications, such as roof top chillers. This problem is especially pronounced in coastal and/or industrial environments, where deterioration of the MCHX tubing can result in refrigerant leaks and system shutdown within a year. In addition, in coastal locations, fin disbonding due to corrosion effects may be a significant problem.
BRIEF DESCRIPTION OF THE INVENTION
[0003] In accordance with an aspect of the invention, a micro channel heat exchanger alloy system is provided and includes first and second manifolds, including a 3000 series aluminum, each of the first and second manifolds being formed to define a respective interior therein; a tube, including at least one of 31108 and 31104 alloy material, extending from the first to the second manifold and being formed to define multiple channels by which the respective interiors of the first and the second manifolds fluidly communicate; a fin structure, including at least 3003 alloy material, disposed in thermal communication with the tube, the fin structure being cladded with a silicon rich layer, including a 4000 series aluminum; and a flux material applied to surfaces of the first and second manifolds, the tube and the fin structure.
[0004] In accordance with another aspect of the invention, a micro channel heat exchanger alloy system is provided and includes first and second manifolds, including a 3000 series aluminum, each of the first and second manifolds being formed to define a respective interior therein; a plurality of non-circular tubes, each of the non-circular tubes including at least one of 31108 and 31104 alloy material, and each of the non-circular tubes extending from the first to the second manifold and being formed to define multiple channels by which the respective interiors of the first and the second manifolds fluidly communicate; fin structures, including at least 3003 alloy material, disposed in thermal communication with each of the non-circular tubes, each of the fin structures being cladded with a silicon rich layer, including a 4000 series aluminum; and a flux material applied to surfaces of the first and second manifolds, each of the non-circular tubes, and each of the fin structures.
[0005] In accordance with yet another aspect of the invention, a micro channel heat exchanger alloy system is provided and includes first and second manifolds, including a 3003 series aluminum, each of the first and second manifolds being formed to define a respective interior therein; a plurality of non-circular tubes, each of the non-circular tubes including at least one of 31108 and 31104 alloy material, and each of the non-circular tubes extending from the first to the second manifold and being formed to define multiple channels by which the respective interiors of the first and the second manifolds fluidly communicate; fin structures, including at least 3003 alloy material, disposed in thermal communication with each of the non-circular tubes, each of the fin structures being cladded with a silicon rich layer, including a 4043 series aluminum; and a lithium modified flux material applied to surfaces of the first and second manifolds, each of the non-circular tubes and each of the fin structures.
BRIEF DESCRIPTION OF THE DRAWINGS
[0006] The subject matter which is regarded as the invention is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other features, and advantages of the invention are apparent from the following detailed description taken in conjunction with the accompanying drawings in which:
[0007] FIG. 1 is a side view of a micro channel heat exchanger (MCHX);
[0008] FIG. 2 is a perspective view of a tube of the MCHX of FIG. 1 ;
[0009] FIG. 3 is a perspective view of a fin structure of the MCHX of FIG. 1; and
[0010] FIG. 4 is a perspective view of a manifold of the MCHX of FIG. 1.
DETAILED DESCRIPTION OF THE INVENTION
[0011] This invention involves aluminum micro channel heat exchanger (MCHX) alloy systems including multi-channel (or multi-port) extruded tubes, with or without sacrificial anodic surface treatments, such as zinc, fin alloys cladded with a silicon rich lower melting point layer, a manifold (or header) alloy and a brazing flux.
[0012] With reference to FIGS. 1-4, a micro channel heat exchanger alloy system 10 is provided and includes first and second manifolds 20 and 30, a tube 40, a fin structure 50 and a flux material 60. The first and second manifolds 20 and 30 are volumetric features formed to define respective interiors 21 and 31 therein, as shown in FIG. 4, and are formed of a 3000 series aluminum, which is an aluminum alloy that normally includes about 1.0-1.5 weight per cent (wt%) manganese as well as magnesium. The 3000 series aluminum may be 3003 aluminum, which contains 1.2 wt% manganese and 0.12 wt% copper plus minor elements like iron and silicon as contaminants. The tube 40 includes at least one of 31108 alloy material (especially with lithium flux), which includes 0.21-0.25 wt% silicon, 0.12 wt% iron, 0.01 wt% copper, 0.90-1.10 wt% manganese, 0.05 wt% magnesium, 0.02 wt% chromium, 0.03 wt% zinc and 0.14-0.20 wt% titanium, 31107 alloy material and 31104 alloy material, which includes 0.10 wt% silicon, 0.01 wt% copper, 0.05 wt% magnesium, 0.05 wt% zinc, 0.12 wt% iron, 1.10 wt% manganese (or magnesium), 0.05 wt% chromium and 0.05 wt% titanium, and extends from the first manifold 20 to the second manifold 30. The tube 40 is formed to define multiple channels 41, as shown in FIG. 2, by which the respective interiors 21 and 31 of the first and the second manifolds 20 and 30 fluidly communicate with each other. The fin structure 50 includes at least one of X758, 6815 and 3003 alloy materials and is disposed in thermal communication with the tube 40. The fin structure 50 is further cladded with a silicon rich layer 51, including a 4000 series aluminum, which is an aluminum alloy that normally includes about 4.5-6.0 wt% silicon to form a low melting point alloy for joining or casting purposes, such as 4043 aluminum (5.2 wt% silicon). The flux material 60 is applied to surfaces of the first and second manifolds 20 and 30, the tube 40 and the fin structure 50 and may include lithium modified flux material.
[0013] As shown in FIG. 1, the tube 40 may be plural in number with each of the plural tubes 40 extending from the first manifold 20 to the second manifold 30. Each of the plural tubes 40 is also formed to define multiple channels 41. Whether the tube 40 is a single feature or plural features, the tube 40 may have a non-circular cross-section, such as an elongate cross-section, with the multiple channels 41 being arrayed along the non-circular cross-section. For the example of the elongate cross-section, the multiple channels 41 would be arrayed along the elongations of the tube 40. [0014] As shown in FIGS. 1 and 3, the fin structure 50 may also be plural in number with each of the plural fin structures disposed in thermal communication with the tube(s) 40. The fin structures 50 may include louvers 52 arranged along a longitudinal length of the tube(s) 40 to increase fin structure surface area and, therefore, heat transfer.
[0015] At least one or more of the first and second manifolds 20 and 30, the tube 40 and the fin structure(s) 50 may each further include a sacrificial anodic surface treatment 70, which may include zinc. In addition, the first and second manifolds 20 and 30 may include titanium.
[0016] While the invention has been described in detail in connection with only a limited number of embodiments, it should be readily understood that the invention is not limited to such disclosed embodiments. Rather, the invention can be modified to incorporate any number of variations, alterations, substitutions or equivalent arrangements not heretofore described, but which are commensurate with the spirit and scope of the invention. Additionally, while various embodiments of the invention have been described, it is to be understood that aspects of the invention may include only some of the described embodiments. Accordingly, the invention is not to be seen as limited by the foregoing description, but is only limited by the scope of the appended claims.

Claims

CLAIMS:
1. A micro channel heat exchanger alloy system, comprising: first and second manifolds, including a 3000 series aluminum, each of the first and second manifolds being formed to define a respective interior therein; a tube, including at least one of 31108 and 31104 alloy material, extending from the first to the second manifold and being formed to define multiple channels by which the respective interiors of the first and the second manifolds fluidly communicate; a fin structure, including at least 3003 alloy material, disposed in thermal communication with the tube, the fin structure being cladded with a silicon rich layer, including a 4000 series aluminum; and a flux material applied to surfaces of the first and second manifolds, the tube and the fin structure.
2. The system according to claim 1, wherein the tube is plural in number, each of the plural tubes extending from the first to the second manifold and being formed to define multiple channels.
3. The system according to claim 1, wherein the tube has a non-circular cross- section with the multiple channels being arrayed along the non-circular cross-section.
4. The system according to claim 1, wherein the fin structure comprises louvers arranged along a longitudinal length of the tube.
5. The system according to claim 1, wherein at least one or more of the first and second manifolds, the tube and the fin structure comprise a sacrificial anodic surface treatment.
6. The system according to claim 5, wherein the sacrificial anodic surface treatment comprises zinc.
7. The system according to claim 1, wherein the first and second manifolds comprise titanium.
8. The system according to claim 1, wherein the 3000 series aluminum comprises 3003 aluminum.
9. The system according to claim 1, wherein the 4000 series aluminum comprises 4043 aluminum.
10. The system according to claim 1, wherein the flux material comprises lithium modified flux.
11. A micro channel heat exchanger alloy system, comprising: first and second manifolds, including a 3000 series aluminum, each of the first and second manifolds being formed to define a respective interior therein; a plurality of non-circular tubes, each of the non-circular tubes including at least one of 31108 and 31104 alloy material, and each of the non-circular tubes extending from the first to the second manifold and being formed to define multiple channels by which the respective interiors of the first and the second manifolds fluidly communicate; fin structures, including at least 3003 alloy material, disposed in thermal communication with each of the non-circular tubes, each of the fin structures being cladded with a silicon rich layer, including a 4000 series aluminum; and a flux material applied to surfaces of the first and second manifolds, each of the non- circular tubes and each of the fin structures.
12. The system according to claim 11, wherein each of the non-circular tubes has a non-circular cross-section with the multiple channels being arrayed along the non-circular cross-section.
13. The system according to claim 11, wherein each of the fin structures comprises louvers arranged along a longitudinal length of each of the non-circular tubes.
14. The system according to claim 11, wherein at least one or more of the first and second manifolds, each of the non-circular tubes and the fin structures comprise a sacrificial anodic surface treatment.
15. The system according to claim 14, wherein the sacrificial anodic surface treatment comprises zinc.
16. The system according to claim 11, wherein the first and second manifolds comprise titanium.
17. The system according to claim 11, wherein the 3000 series aluminum comprises 3003 aluminum.
18. The system according to claim 11, wherein the 4000 series aluminum comprises 4043 aluminum.
19. The system according to claim 11, wherein the flux material comprises lithium modified flux.
20. A micro channel heat exchanger alloy system, comprising: first and second manifolds, including a 3003 series aluminum, each of the first and second manifolds being formed to define a respective interior therein; a plurality of non-circular tubes, each of the non-circular tubes including at least one of 31108 and 31104 alloy material, and each of the non-circular tubes extending from the first to the second manifold and being formed to define multiple channels by which the respective interiors of the first and the second manifolds fluidly communicate; fin structures, including at least 3003 alloy material, disposed in thermal communication with each of the non-circular tubes, each of the fin structures being cladded with a silicon rich layer, including a 4043 series aluminum; and a lithium modified flux material applied to surfaces of the first and second manifolds, each of the non-circular tubes and each of the fin structures.
PCT/US2012/060419 2011-10-18 2012-10-16 Micro channel heat exchanger alloy system WO2013059193A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201280051090.6A CN103857973A (en) 2011-10-18 2012-10-16 Micro channel heat exchanger alloy system
EP12784390.2A EP2769162A1 (en) 2011-10-18 2012-10-16 Micro channel heat exchanger alloy system
US14/352,510 US20140262182A1 (en) 2011-10-18 2012-10-16 Micro channel heat exchanger alloy system

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161548553P 2011-10-18 2011-10-18
US61/548,553 2011-10-18

Publications (1)

Publication Number Publication Date
WO2013059193A1 true WO2013059193A1 (en) 2013-04-25

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ID=47172890

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/060419 WO2013059193A1 (en) 2011-10-18 2012-10-16 Micro channel heat exchanger alloy system

Country Status (4)

Country Link
US (1) US20140262182A1 (en)
EP (1) EP2769162A1 (en)
CN (2) CN108917449A (en)
WO (1) WO2013059193A1 (en)

Cited By (1)

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US20160238262A1 (en) * 2013-09-30 2016-08-18 Arcelik Anonim Sirketi Forced convection heat exchanger for a refrigeration appliance

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US20060102696A1 (en) * 2001-11-21 2006-05-18 Graham Michael E Layered products for fluxless brazing of substrates
JP2009046704A (en) * 2007-08-14 2009-03-05 Mitsubishi Alum Co Ltd Extruded flat perforated pipe for heat exchanger having excellent corrosion resistance, and heat exchanger
US20100116472A1 (en) * 2003-05-06 2010-05-13 Mitsubishi Aluminum Co., Ltd. Heat exchanger tube

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Publication number Priority date Publication date Assignee Title
JPH10152767A (en) * 1996-11-22 1998-06-09 Calsonic Corp Corrosion protective treatment for internal surface of heat transfer tube made of aluminum alloy
US20060102696A1 (en) * 2001-11-21 2006-05-18 Graham Michael E Layered products for fluxless brazing of substrates
US20100116472A1 (en) * 2003-05-06 2010-05-13 Mitsubishi Aluminum Co., Ltd. Heat exchanger tube
JP2009046704A (en) * 2007-08-14 2009-03-05 Mitsubishi Alum Co Ltd Extruded flat perforated pipe for heat exchanger having excellent corrosion resistance, and heat exchanger

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160238262A1 (en) * 2013-09-30 2016-08-18 Arcelik Anonim Sirketi Forced convection heat exchanger for a refrigeration appliance
US9915437B2 (en) * 2013-09-30 2018-03-13 Arcelik Anonim Sirketi Forced convection heat exchanger for a refrigeration appliance

Also Published As

Publication number Publication date
EP2769162A1 (en) 2014-08-27
CN108917449A (en) 2018-11-30
CN103857973A (en) 2014-06-11
US20140262182A1 (en) 2014-09-18

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