WO2013054105A2 - Combustion method - Google Patents
Combustion method Download PDFInfo
- Publication number
- WO2013054105A2 WO2013054105A2 PCT/GB2012/052504 GB2012052504W WO2013054105A2 WO 2013054105 A2 WO2013054105 A2 WO 2013054105A2 GB 2012052504 W GB2012052504 W GB 2012052504W WO 2013054105 A2 WO2013054105 A2 WO 2013054105A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- air
- cetane number
- engine
- materials
- combustion
- Prior art date
Links
- 238000009841 combustion method Methods 0.000 title description 2
- 238000002485 combustion reaction Methods 0.000 claims abstract description 32
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 27
- 238000007906 compression Methods 0.000 claims abstract description 16
- 230000006835 compression Effects 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 8
- 239000000446 fuel Substances 0.000 claims description 27
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 239000012530 fluid Substances 0.000 claims description 13
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 230000003247 decreasing effect Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 description 8
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/0025—Controlling engines characterised by use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M31/00—Apparatus for thermally treating combustion-air, fuel, or fuel-air mixture
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D19/00—Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
- F02D19/06—Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed
- F02D19/0639—Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed characterised by the type of fuels
- F02D19/0649—Liquid fuels having different boiling temperatures, volatilities, densities, viscosities, cetane or octane numbers
- F02D19/0652—Biofuels, e.g. plant oils
- F02D19/0655—Biofuels, e.g. plant oils at least one fuel being an alcohol, e.g. ethanol
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02N—STARTING OF COMBUSTION ENGINES; STARTING AIDS FOR SUCH ENGINES, NOT OTHERWISE PROVIDED FOR
- F02N19/00—Starting aids for combustion engines, not otherwise provided for
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02N—STARTING OF COMBUSTION ENGINES; STARTING AIDS FOR SUCH ENGINES, NOT OTHERWISE PROVIDED FOR
- F02N19/00—Starting aids for combustion engines, not otherwise provided for
- F02N19/02—Aiding engine start by thermal means, e.g. using lighted wicks
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02N—STARTING OF COMBUSTION ENGINES; STARTING AIDS FOR SUCH ENGINES, NOT OTHERWISE PROVIDED FOR
- F02N99/00—Subject matter not provided for in other groups of this subclass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/307—Cetane number, cetane index
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D2200/00—Input parameters for engine control
- F02D2200/02—Input parameters for engine control the parameters being related to the engine
- F02D2200/06—Fuel or fuel supply system parameters
- F02D2200/0611—Fuel type, fuel composition or fuel quality
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/30—Use of alternative fuels, e.g. biofuels
Definitions
- the present invention relates to a method of combustion, notably combustion in a compression ignition internal combustion engine.
- 'diesel engine' is used herein to refer to a compression ignition internal combustion engine in which compression initiates combustion when fuel is injected.
- a heterogeneous charge of fuel and air ignites in a combustion chamber because of the heat generated in the compression process. This differs from Otto-cycle engines, wherein fuel and air are mixed together before entering the combustion chamber, and then ignited by a spark plug.
- a diesel engine differs from a Homogeneous Charge Compression Ignition (HCCI) engine, which uses compression ignition but with pre-mixing of fuel and air to produce a homogeneous charge. When the fuel/air mixture is compressed sufficiently it ignites spontaneously.
- HCCI is suitable for lean burn operation and hence can have higher efficiency than a conventional Otto-cycle engine, and lower peak temperatures which reduces NOx formation.
- HCCI is more difficult to control than combustion in conventional engines, which can cause timing problems.
- HCCI there is no well-defined combustion initiator that can be directly controlled.
- the control system must be able to change operating conditions such as compression ratio and fuel-air ratio, which can add complexity and cost.
- the fuel employed in HCCI should have a relatively low boiling point.
- CN Cetane Number
- CN Cetane Number
- Fuels with high CN values have low ignition delay and are suitable for use in diesel engines.
- Commercial diesel engine fuels typically have CN values in the range 40-55. Fuels with high CN values are typically unsuitable for Otto-cycle engines, where resistance to autoignition is desirable.
- Liquids with low or zero cetane numbers include aromatic hydrocarbons such as toluene, and alcohols such as glycerol. Ethanol, for example, has a cetane number of about 8 and methanol has a cetane number of about 3.
- the term 'very low CN material' is used herein to refer to materials having a cetane number between 0 and 30. For some very low CN number materials the CN is determined by calculation and or extrapolations and sometimes negative CN are obtained. For the purpose of this invention it is assumed that materials with calculated or extrapolated negative CN have cetane number zero.
- Very low CN materials are not regarded as suitable for use in diesel engines unless modified by admixing with a higher cetane number fuel or by the addition of cetane improvers such as polynitrate esters and amines. See, for example, US 4,746,326 and WO 85/002194. Cetane improvers are expensive, and polynitrate esters have the drawback of being explosive.
- US 5,117,800 describes a method of operating a diesel or spark ignited engine which includes enriching the combustion air supply with oxygen while simultaneously adjusting the fuel injection or ignition timing of the engine to compensate for advanced combustion caused by an increased oxygen content in the combustion air.
- a turbocharger is used as a pump to separate air through an oxygen-producing membrane.
- the oxygen-enriched air is at a lower pressure, and hence is cooler, than conventionally turbocharged combustion air, so the need for an intercooler is reduced or eliminated.
- US 3,794,007 describes the use of fuel from an engine's fuel supply to heat up combustion air for a cold start. Air in a suction line or intake manifold is heated by burning fuel in a flame-suction air heater during startup operation of the engine under load when a poorly ignitable fuel such as gasoline is used.
- GB 2460996 describes method of combustion and igniting very low cetane number materials by supplying to the inlet port combustion air or working fluid at a temperatures at least 90 ° C (60 ° C in case of glycerine) for substantially the entire time that the engine is running, the combustible part of the working fluid containing only very low cetane number components.
- it does not teach how to start the engine on a very low cetane number materials.
- the engine was started on gas oil or dimethyl ether (DME), i.e. high cetane number materials.
- DME dimethyl ether
- a compression ignition engine could be successfully cold started and run on very low cetane number materials for the entire time the engine is running without using conventional diesel fuels for starting the engine by supplying combustion air to the engine so that the product of inlet temperature of combustion air (or working fluid, (WF)) expressed in degrees Kelvin to the power of 2.00336 and ratio of air (WF) densities under operating conditions and under standard conditions (1 atm,20 ° C) is in the range from 130000 to 190000.
- WF working fluid
- T inlet is the inlet temperature of combustion air or WF, degrees K
- d op is the air (WF)density under operating conditions
- d st is the air (WF) density under standard conditions (1 atm,20 ° C).
- ⁇ is individual for each very low cetane number material. Thus for glycerine it lies in the range of 134000 to 174000, for gasoline it is in the range from 145000 to 177000.
- the invention involves keeping ⁇ within certain operational limits. This invention enables the cold start and operation of a compression ignition engine on very low CN materials without using high CN fuels.
- working fluid' is used herein to denote a fluid (gas or liquid) used as the medium for the transfer of energy from one part of a system to another part.
- the working fluid could comprise air mixed with a gas or vapour which is combustible or supports combustion.
- the invention may in principle be used with solid or fluid materials; however, fluid materials are preferred for the ease of injection.
- the invention is suitable for application in internal combustion engines such as power generation engines, marine engines, aircraft engines and automotive engines, gas turbines.
- the invention is also particularly well suited to engine driven power generation systems and engine driven Combined Heat and Power systems as the majority of the energy used to increase the intake charge temperature is recycled back to the heat recovery system via the engine exhaust.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Output Control And Ontrol Of Special Type Engine (AREA)
Abstract
A method of starting a compression ignition engine on a very low cetane number materials, igniting and combusting very low cetane number materials comprises delivering said materials into a combustion chamber and supplying to the chamber combustion air so that 130000 ≤ Π ≤ 190000 where Π = T
2.00336
Inlet ×(d
op /d
st
), where T
inlet
is the inlet temperature of combustion air or WF, degrees K; d
op
is the air (WF)density under operating conditions, d
st
is the air (WF) density under standard conditions (1 atm,20 ° C).
Description
The present invention relates to a method of
combustion, notably combustion in a compression ignition internal combustion
engine.
The term 'diesel engine' is used herein to refer to a
compression ignition internal combustion engine in which compression initiates
combustion when fuel is injected. A heterogeneous charge of fuel and air
ignites in a combustion chamber because of the heat generated in the
compression process. This differs from Otto-cycle engines, wherein fuel and air
are mixed together before entering the combustion chamber, and then ignited by
a spark plug.
A diesel engine differs from a Homogeneous Charge
Compression Ignition (HCCI) engine, which uses compression ignition but with
pre-mixing of fuel and air to produce a homogeneous charge. When the fuel/air
mixture is compressed sufficiently it ignites spontaneously. HCCI is suitable
for lean burn operation and hence can have higher efficiency than a
conventional Otto-cycle engine, and lower peak temperatures which reduces NOx
formation. However, HCCI is more difficult to control than combustion in
conventional engines, which can cause timing problems. In contrast to a diesel
engine, where ignition is controlled by the time when fuel is injected into the
compressed air, or an Otto-cycle engine, where ignition is controlled by the
time when a spark is generated, with HCCI there is no well-defined combustion
initiator that can be directly controlled. Moreover, to achieve dynamic
operation with variable work output, the control system must be able to change
operating conditions such as compression ratio and fuel-air ratio, which can
add complexity and cost.
To ensure ignition and to avoid cylinder wall wetting
by fuel droplet condensation the fuel employed in HCCI should have a relatively
low boiling point.
The combustion quality of a diesel engine fuel is
expressed as a Cetane Number (CN), which is defined as the percentage by volume
of normal cetane (n-hexadecane) in a mixture of normal cetane and 1-methyl
naphthalene which has the same ignition characteristics (ignition delay) as the
test fuel when combusted in a standard engine under specified test conditions.
Fuels with high CN values have low ignition delay and are suitable for use in
diesel engines. Commercial diesel engine fuels typically have CN values in the
range 40-55. Fuels with high CN values are typically unsuitable for Otto-cycle
engines, where resistance to autoignition is desirable.
The combustion quality of Otto-cycle engine fuels is
expressed as an Octane Number (ON), with high ON fuels being suitable.
Typically, high CN fuels have low ON values and vice versa.
Liquids with low or zero cetane numbers include
aromatic hydrocarbons such as toluene, and alcohols such as glycerol. Ethanol,
for example, has a cetane number of about 8 and methanol has a cetane number of
about 3. The term 'very low CN material' is used herein to refer to materials
having a cetane number between 0 and 30. For some very low CN number materials
the CN is determined by calculation and or extrapolations and sometimes
negative CN are obtained. For the purpose of this invention it is assumed that
materials with calculated or extrapolated negative CN have cetane number zero.
Very low CN materials are not regarded as suitable for use in diesel engines
unless modified by admixing with a higher cetane number fuel or by the addition
of cetane improvers such as polynitrate esters and amines. See, for example, US
4,746,326 and WO 85/002194. Cetane improvers are expensive, and polynitrate
esters have the drawback of being explosive.
US 5,117,800 describes a method of operating a diesel
or spark ignited engine which includes enriching the combustion air supply with
oxygen while simultaneously adjusting the fuel injection or ignition timing of
the engine to compensate for advanced combustion caused by an increased oxygen
content in the combustion air. A turbocharger is used as a pump to separate air
through an oxygen-producing membrane. The oxygen-enriched air is at a lower
pressure, and hence is cooler, than conventionally turbocharged combustion air,
so the need for an intercooler is reduced or eliminated.
US 3,794,007 describes the use of fuel from an
engine's fuel supply to heat up combustion air for a cold start. Air in a
suction line or intake manifold is heated by burning fuel in a flame-suction
air heater during startup operation of the engine under load when a poorly
ignitable fuel such as gasoline is used.
GB 2460996 describes method of combustion and
igniting very low cetane number materials by supplying to the inlet port
combustion air or working fluid at a temperatures at least 90 ° C (60 ° C in
case of glycerine) for substantially the entire time that the engine is
running, the combustible part of the working fluid containing only very low
cetane number components. However, it does not teach how to start the engine on
a very low cetane number materials. In all listed examples the engine was
started on gas oil or dimethyl ether (DME), i.e. high cetane number materials.
Thus attempts to date to cold start the engine using only very low cetane
number materials including glycerol have proved unsatisfactory.
It is not possible to start the ignition
compression engine on low cetane number fuels, also the emissions while running
even on high cetane number fule are very high.
Aspects of the invention are specified in
independent claims. Preferred features are specified in dependent claims..
We have surprisingly found that a compression
ignition engine could be successfully cold started and run on very low cetane
number materials for the entire time the engine is running without using
conventional diesel fuels for starting the engine by supplying combustion air
to the engine so that the product of inlet temperature of combustion air (or
working fluid, (WF)) expressed in degrees Kelvin to the power of 2.00336 and
ratio of air (WF) densities under operating conditions and under standard
conditions (1 atm,20 ° C) is in the range from 130000 to 190000.
130000 ≤
T
2.00336
Inlet
×(d
op /d
st ) ≤ 190000
Where T
inlet is the
inlet temperature of combustion air or WF, degrees K;
d
op is the air (WF)density under operating conditions,
d
st is the air (WF) density under standard conditions
(1 atm,20 ° C).
For the sake of brevity the product T
2.00336
Inlet ×(d
op /d
st ) will be further designated as Π
.
We have also found that the quality of exhaust
emissions as characterised by CO level in the exhaust gases of the engine
running on very low CN materials is significantly improved when Π is in
the above-mentioned range.
The exact numerical value of Π is
individual for each very low cetane number material. Thus for glycerine it lies
in the range of 134000 to 174000, for gasoline it is in the range from 145000
to 177000.
We have also found that the quality of exhaust
emissions as characterised by CO level in the exhaust gases of the engine
running on conventional diesel fuels during the cold start is significantly
improved when Π is in the same range.
In broad terms the invention involves keeping
Π within certain operational limits. This invention enables the cold start
and operation of a compression ignition engine on very low CN materials without
using high CN fuels.
A person skilled in the art would be aware that
increased mass flow during engine starting cranking may reduce the cranking
speed and therefore a higher power starting system may be required to ensure a
normal rated cranking speed for any chosen engine type
The term 'working fluid' is used herein to denote
a fluid (gas or liquid) used as the medium for the transfer of energy from one
part of a system to another part. The working fluid could comprise air mixed
with a gas or vapour which is combustible or supports combustion.
The invention may in principle be used with solid
or fluid materials; however, fluid materials are preferred for the ease of
injection.
EXPERIMENTAL RESULTS
Various very low cetane number materials were
combusted in an experimental apparatus comprising a 4 cylinder Deutz direct
injected turbocharged engine and the set with a continuous power rating of
43KWe at 1,500 rpm. No modifications were made to the engine or the fuel system
injection components. The engine was run at different loads. The compression
ratio was 18 : 1. No high cetane number materials were used to initiate the
combustion. The obtained results are listed in the table below.
The other experiments were devoted to cold start
of the engine on a conventional diesel fuel such as a standard gas oil. The
results are also listed in the table.
Table 1. Experimental results
Fuel | Inlet air temperature T inlet | (d op /d st ) | Π | CO in the exhaust, ppm |
Glycerine | ||||
96% load | 368 | 1.09 | 150612 | 116 |
75% load | 396 | 0.92 | 146763 | 71 |
53% load | 429 | 0.78 | 145959 | 87 |
31% load | 463 | 0.68 | 149340 | 106 |
Engine cold start on glycerine | ||||
383 | 1.71 | 149650 | 284 | |
363 | 1.81 | 134404 | 212 | |
Comparative examples according to GB2460996 (engine stalls) | ||||
333 | 0.88 | 99452 | ||
509 | 0.49 | 129214 | 781 | |
417 | 0.70 | 124540 | 389 | |
Gasoline, 95 octane | ||||
65% load | 434 | 0.84 | 160855 | 380 |
65% load | 427 | 0.85 | 158775 | 346 |
65% load | 418.4 | 0.87 | 155860 | 318 |
65% load | 409.6 | 0.9 | 153401 | 309 |
75% load | 408.8 | 0.94 | 160549 | 418 |
75% load | 401.6 | 0.96 | 157842 | 387 |
75% load | 390.2 | 0.99 | 156508 | 391 |
Comparative example according to GB2460996 (engine stalls) | ||||
363 | 0.81 | 108412 | ||
373 | 0.78 | 111399 | ||
Gas oil, 75% load. Engine cold start according to the current invention | ||||
348.2 | 1.09 | 134566 | 162 | |
293 | 1.5 | 131260 | 400 | |
Engine cold start under standard conditions (comparative) | 273 | 1.07 | 81533 | 2400 |
It is appreciated that certain features of the
invention, which are, for clarity, described in the context of separate
embodiments, may also be provided in combination in a single embodiment.
Conversely, various features of the invention which are, for brevity, described
in the context of a single embodiment, may also be provided separately, or in
any suitable combination.
While the invention has, for purposes of
illustration, been described with reference to specific examples, it will be
understood that the invention is not limited to those examples. Various
alterations, modifications, and/or additions may be introduced into the
constructions and arrangements described above without departing from the ambit
of the present invention set forth in the claims.
The articles 'a' and 'an' are used herein to mean
'at least one' unless the context otherwise requires.
The invention is suitable for application in
internal combustion engines such as power generation engines, marine engines,
aircraft engines and automotive engines, gas turbines. The invention is also
particularly well suited to engine driven power generation systems and engine
driven Combined Heat and Power systems as the majority of the energy used to
increase the intake charge temperature is recycled back to the heat recovery
system via the engine exhaust.
Claims (1)
- A method of starting a compression ignition engine on very low cetane number materials, igniting and combusting very low cetane number materials comprising delivering said materials into a combustion chamber of a compression ignition engine and supplying to the combustion chamber air or working fluid, the combustible part of the working fluid having weighted average cetane number below 30, for the entire time that the engine is running so that the product of an inlet temperature of air or working fluid expressed in degrees Kelvin to the power of 2.00336 and ratio of air (WF) densities under operating conditions and under standard conditions (1 atm,20 °C) is in the range from 130000 to 190000 according to the equation130000 ≤ Π ≤ 190000 where Π = T 2.00336 Inlet ×(d op /d st ), where T inlet is the inlet temperature of combustion air or WF, degrees K; d op is the air (WF)density under operating conditions, d st is the air (WF) density under standard conditions (1 atm,20 ° C).2. A method according to claim 1 where the very low cetane number material is glycerine and Π is in the range from 134000 to 174000.3.A method according to claim 1 where the very low cetane number material is a fuel for Otto engines and Π is in the range from 145000 to 1770004.A method of decreasing emissions during the cold start of a compression ignition engine running on high cetane number materials comprising delivering said materials into a combustion chamber of a compression ignition engine and supplying to the combustion chamber air or working fluid so that during the start up period the product of an inlet temperature of air or working fluid expressed in degrees Kelvin o the power of 2.00336 and ratio of air (WF) densities under operating conditions and under standard conditions (1 atm,20 °C) is in the range from 130000 to 190000 according to the equation 130000 ≤ Π ≤ 190000
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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GB1117779.7 | 2011-10-14 | ||
GB1117779.7A GB2495549A (en) | 2011-10-14 | 2011-10-14 | Method of starting a compression ignition engine |
Publications (2)
Publication Number | Publication Date |
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WO2013054105A2 true WO2013054105A2 (en) | 2013-04-18 |
WO2013054105A9 WO2013054105A9 (en) | 2013-07-18 |
Family
ID=45219732
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/GB2012/052504 WO2013054105A2 (en) | 2011-10-14 | 2012-10-10 | Combustion method |
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GB (1) | GB2495549A (en) |
WO (1) | WO2013054105A2 (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US3794007A (en) | 1971-03-27 | 1974-02-26 | Daimler Benz Ag | Process and apparatus for multi-fuel operation of an air-compressing and auto-igniting injection internal combustion engine |
WO1985002194A1 (en) | 1983-11-07 | 1985-05-23 | Ethyl Corporation | Diesel fuel cetane improver |
US4746326A (en) | 1985-11-15 | 1988-05-24 | Mobil Oil Corporation | Cetane number of diesel fuel by incorporating polynitrate esters and stabilizers |
US5117800A (en) | 1988-02-10 | 1992-06-02 | The Broken Hill Proprietary Company Limited | Oxygen enrichment of fuels |
GB2460996A (en) | 2008-03-20 | 2009-12-23 | Aquafuel Res Ltd | Combustion method and apparatus |
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JPH05126019A (en) * | 1991-10-30 | 1993-05-21 | Tonen Corp | Alcohol engine starting property improving device and starting property improving method |
CN2883692Y (en) * | 2006-03-14 | 2007-03-28 | 郑国璋 | Low pollusion methyl alcohol engine |
US7461628B2 (en) * | 2006-12-01 | 2008-12-09 | Ford Global Technologies, Llc | Multiple combustion mode engine using direct alcohol injection |
BRPI0805484A2 (en) * | 2008-12-02 | 2010-08-24 | Magneti Marelli Sist Ltda | fuel gallery with axially mounted heating system for ethanol cold start system |
JP2010265774A (en) * | 2009-05-12 | 2010-11-25 | Nippon Soken Inc | Starter and starting method for internal combustion engine |
CN201902275U (en) * | 2010-12-11 | 2011-07-20 | 广东高奇能源工程有限公司 | Methanol fuel using device for motorcycle |
CN201963449U (en) * | 2011-04-01 | 2011-09-07 | 山西华顿实业有限公司 | Auxiliary device for cold starting of methanol-fueled automobile |
-
2011
- 2011-10-14 GB GB1117779.7A patent/GB2495549A/en not_active Withdrawn
-
2012
- 2012-10-10 WO PCT/GB2012/052504 patent/WO2013054105A2/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3794007A (en) | 1971-03-27 | 1974-02-26 | Daimler Benz Ag | Process and apparatus for multi-fuel operation of an air-compressing and auto-igniting injection internal combustion engine |
WO1985002194A1 (en) | 1983-11-07 | 1985-05-23 | Ethyl Corporation | Diesel fuel cetane improver |
US4746326A (en) | 1985-11-15 | 1988-05-24 | Mobil Oil Corporation | Cetane number of diesel fuel by incorporating polynitrate esters and stabilizers |
US5117800A (en) | 1988-02-10 | 1992-06-02 | The Broken Hill Proprietary Company Limited | Oxygen enrichment of fuels |
GB2460996A (en) | 2008-03-20 | 2009-12-23 | Aquafuel Res Ltd | Combustion method and apparatus |
Also Published As
Publication number | Publication date |
---|---|
GB2495549A (en) | 2013-04-17 |
GB201117779D0 (en) | 2011-11-30 |
WO2013054105A9 (en) | 2013-07-18 |
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