WO2013033590A3 - Upgrading hydrocarbon pyrolysis products by hydroprocessing - Google Patents

Upgrading hydrocarbon pyrolysis products by hydroprocessing Download PDF

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Publication number
WO2013033590A3
WO2013033590A3 PCT/US2012/053433 US2012053433W WO2013033590A3 WO 2013033590 A3 WO2013033590 A3 WO 2013033590A3 US 2012053433 W US2012053433 W US 2012053433W WO 2013033590 A3 WO2013033590 A3 WO 2013033590A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydroprocessing
pyrolysis products
hydrocarbon pyrolysis
upgrading hydrocarbon
pyrolysis
Prior art date
Application number
PCT/US2012/053433
Other languages
French (fr)
Other versions
WO2013033590A2 (en
Inventor
Stephen H. Brown
Stephen M. Davis
John S. Buchanan
David T. Ferrughelli
Keith G. REED
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Priority to CN201280041820.4A priority Critical patent/CN103764799B/en
Priority to EP12762465.8A priority patent/EP2751234B1/en
Priority to PCT/US2012/053433 priority patent/WO2013033590A2/en
Priority to CA2843517A priority patent/CA2843517A1/en
Publication of WO2013033590A2 publication Critical patent/WO2013033590A2/en
Publication of WO2013033590A3 publication Critical patent/WO2013033590A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/18—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen-generating compounds, e.g. ammonia, water, hydrogen sulfide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention relates to processes for upgrading products obtained from hydrocarbon pyrolysis, equipment useful for such processes, and the use of upgraded pyrolysis products. A tar-containing stream recovered from the pyrolysis effluent is mixed with a utility fluid and subsequently hydroprocessed.
PCT/US2012/053433 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing WO2013033590A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201280041820.4A CN103764799B (en) 2011-08-31 2012-08-31 By hydrotreating upgrading hydrocarbon thermal decomposition product
EP12762465.8A EP2751234B1 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing
PCT/US2012/053433 WO2013033590A2 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing
CA2843517A CA2843517A1 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201161529565P 2011-08-31 2011-08-31
US201161529588P 2011-08-31 2011-08-31
US61/529,588 2011-08-31
US61/529,565 2011-08-31
US201261657299P 2012-06-08 2012-06-08
US61/657,299 2012-06-08
PCT/US2012/053433 WO2013033590A2 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing

Publications (2)

Publication Number Publication Date
WO2013033590A2 WO2013033590A2 (en) 2013-03-07
WO2013033590A3 true WO2013033590A3 (en) 2013-04-25

Family

ID=51862040

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/053433 WO2013033590A2 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing

Country Status (4)

Country Link
EP (1) EP2751234B1 (en)
CN (1) CN103764799B (en)
CA (1) CA2843517A1 (en)
WO (1) WO2013033590A2 (en)

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US9243193B2 (en) * 2013-03-14 2016-01-26 Exxonmobil Research And Engineering Company Fixed bed hydrovisbreaking of heavy hydrocarbon oils
US9777227B2 (en) 2014-04-30 2017-10-03 Exxonmobil Chemical Patents Inc. Upgrading hydrocarbon pyrolysis products
WO2015191236A1 (en) 2014-06-13 2015-12-17 Exxonmobil Chemical Patents Inc. Hydrocarbon upgrading
WO2015191148A1 (en) 2014-06-13 2015-12-17 Exxonmobil Chemical Patents Inc. Method and apparatus for improving a hydrocarbon feed
EP3158028B1 (en) 2014-06-20 2019-06-19 ExxonMobil Chemical Patents Inc. Pyrolysis tar upgrading using recycled product
WO2016069057A1 (en) * 2014-10-29 2016-05-06 Exonmobil Chemical Patents Inc. Upgrading hydrocarbon pyrolysis products
WO2016099787A1 (en) 2014-12-17 2016-06-23 Exxonmobil Chemical Patents Inc. Methods and systems for treating a hydrocarbon feed
US10597592B2 (en) * 2016-08-29 2020-03-24 Exxonmobil Chemical Patents Inc. Upgrading hydrocarbon pyrolysis tar
US11162037B2 (en) 2016-12-16 2021-11-02 Exxonmobil Chemical Patents Inc. Pyrolysis tar conversion
US11060039B2 (en) 2016-12-16 2021-07-13 Exxonmobil Chemical Patents Inc. Pyrolysis tar pretreatment
WO2018111574A1 (en) 2016-12-16 2018-06-21 Exxonmobil Chemical Patents Inc. Pyrolysis tar pretreatment
WO2018111572A1 (en) 2016-12-16 2018-06-21 Exxonmobil Chemical Patents Inc. Pyrolysis tar conversion
CN110753742A (en) 2017-05-17 2020-02-04 埃克森美孚化学专利公司 Upgrading hydrocarbon pyrolysis products
JP2020527182A (en) 2017-07-14 2020-09-03 エクソンモービル リサーチ アンド エンジニアリング カンパニーＥｘｘｏｎ Ｒｅｓｅａｒｃｈ Ａｎｄ Ｅｎｇｉｎｅｅｒｉｎｇ Ｃｏｍｐａｎｙ Multi-stage upgrading of pyrolysis tar products
US11401473B2 (en) 2018-08-30 2022-08-02 Exxonmobil Chemical Patents Inc. Process to maintain high solvency of recycle solvent during upgrading of steam cracked tar
WO2020086394A1 (en) 2018-10-25 2020-04-30 Exxonmobil Chemical Patents Inc. Solvent and temperature assisted dissolution of solids from steam cracked tar
US20220033716A1 (en) 2018-12-14 2022-02-03 Exxonmobil Chemical Patents Inc. Solvent Control for Centrifugation of Steam Cracked Tar
WO2020123634A1 (en) 2018-12-14 2020-06-18 Exxonmobil Chemical Patents Inc. Temperature control for centrifugation of steam cracked tar
CN113906118A (en) 2019-06-05 2022-01-07 埃克森美孚化学专利公司 Pyrolysis tar upgrading
US20230151283A1 (en) 2020-04-20 2023-05-18 Exxonmobil Chemical Patents Inc. Hydrocarbon pyrolysis of feeds containing nitrogen
WO2021236326A1 (en) 2020-05-22 2021-11-25 Exxonmobil Chemical Patents Inc. Fluid for tar hydroprocessing
US20230203386A1 (en) 2020-06-17 2023-06-29 Exxonmobil Chemical Patents Inc. Hydrocarbon Pyrolysis of Advantaged Feeds
WO2023107819A1 (en) 2021-12-09 2023-06-15 Exxonmobil Chemical Patents Inc. Steam cracking a hydrocarbon feed comprising arsenic

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1159843A (en) * 1967-05-24 1969-07-30 Exxon Research Engineering Co Process for manufacture of Heavy Aromatic Solvent
US4173529A (en) * 1978-05-30 1979-11-06 The Lummus Company Hydrotreating of pyrolysis gasoline
US5158668A (en) * 1988-10-13 1992-10-27 Conoco Inc. Preparation of recarburizer coke
US5215649A (en) * 1990-05-02 1993-06-01 Exxon Chemical Patents Inc. Method for upgrading steam cracker tars
WO2010144512A2 (en) * 2009-06-11 2010-12-16 Shell Oil Company A process for the selective hydrogenation and hydrodesulferization of a pyrolysis gasoline feedstock

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US6632351B1 (en) 2000-03-08 2003-10-14 Shell Oil Company Thermal cracking of crude oil and crude oil fractions containing pitch in an ethylene furnace
US7138047B2 (en) 2002-07-03 2006-11-21 Exxonmobil Chemical Patents Inc. Process for steam cracking heavy hydrocarbon feedstocks
US7097758B2 (en) 2002-07-03 2006-08-29 Exxonmobil Chemical Patents Inc. Converting mist flow to annular flow in thermal cracking application
US7090765B2 (en) 2002-07-03 2006-08-15 Exxonmobil Chemical Patents Inc. Process for cracking hydrocarbon feed with water substitution
EP1727877B1 (en) 2004-03-22 2012-04-04 ExxonMobil Chemical Patents Inc. Process for steam cracking heavy hydrocarbon feedstocks
US7311746B2 (en) 2004-05-21 2007-12-25 Exxonmobil Chemical Patents Inc. Vapor/liquid separation apparatus for use in cracking hydrocarbon feedstock containing resid
US7351872B2 (en) 2004-05-21 2008-04-01 Exxonmobil Chemical Patents Inc. Process and draft control system for use in cracking a heavy hydrocarbon feedstock in a pyrolysis furnace
US7312371B2 (en) 2004-05-21 2007-12-25 Exxonmobil Chemical Patents Inc. Steam cracking of hydrocarbon feedstocks containing non-volatile components and/or coke precursors
US7235705B2 (en) 2004-05-21 2007-06-26 Exxonmobil Chemical Patents Inc. Process for reducing vapor condensation in flash/separation apparatus overhead during steam cracking of hydrocarbon feedstocks
US7247765B2 (en) 2004-05-21 2007-07-24 Exxonmobil Chemical Patents Inc. Cracking hydrocarbon feedstock containing resid utilizing partial condensation of vapor phase from vapor/liquid separation to mitigate fouling in a flash/separation vessel
US7220887B2 (en) 2004-05-21 2007-05-22 Exxonmobil Chemical Patents Inc. Process and apparatus for cracking hydrocarbon feedstock containing resid
US7244871B2 (en) 2004-05-21 2007-07-17 Exxonmobil Chemical Patents, Inc. Process and apparatus for removing coke formed during steam cracking of hydrocarbon feedstocks containing resids
US7488459B2 (en) 2004-05-21 2009-02-10 Exxonmobil Chemical Patents Inc. Apparatus and process for controlling temperature of heated feed directed to a flash drum whose overhead provides feed for cracking
US7297833B2 (en) 2004-05-21 2007-11-20 Exxonmobil Chemical Patents Inc. Steam cracking of light hydrocarbon feedstocks containing non-volatile components and/or coke precursors
US8083931B2 (en) 2006-08-31 2011-12-27 Exxonmobil Chemical Patents Inc. Upgrading of tar using POX/coker
JP5339845B2 (en) * 2008-10-14 2013-11-13 Ｊｘ日鉱日石エネルギー株式会社 Fluid catalytic cracking method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1159843A (en) * 1967-05-24 1969-07-30 Exxon Research Engineering Co Process for manufacture of Heavy Aromatic Solvent
US4173529A (en) * 1978-05-30 1979-11-06 The Lummus Company Hydrotreating of pyrolysis gasoline
US5158668A (en) * 1988-10-13 1992-10-27 Conoco Inc. Preparation of recarburizer coke
US5215649A (en) * 1990-05-02 1993-06-01 Exxon Chemical Patents Inc. Method for upgrading steam cracker tars
WO2010144512A2 (en) * 2009-06-11 2010-12-16 Shell Oil Company A process for the selective hydrogenation and hydrodesulferization of a pyrolysis gasoline feedstock

Also Published As

Publication number Publication date
CN103764799B (en) 2016-08-24
CN103764799A (en) 2014-04-30
EP2751234A2 (en) 2014-07-09
CA2843517A1 (en) 2013-03-07
EP2751234B1 (en) 2016-11-16
WO2013033590A2 (en) 2013-03-07

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