WO2013033298A3 - Use of supercritical fluid in hydroprocessing heavy hydrocarbons - Google Patents

Use of supercritical fluid in hydroprocessing heavy hydrocarbons Download PDF

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Publication number
WO2013033298A3
WO2013033298A3 PCT/US2012/052991 US2012052991W WO2013033298A3 WO 2013033298 A3 WO2013033298 A3 WO 2013033298A3 US 2012052991 W US2012052991 W US 2012052991W WO 2013033298 A3 WO2013033298 A3 WO 2013033298A3
Authority
WO
WIPO (PCT)
Prior art keywords
supercritical fluid
heavy hydrocarbons
hydroprocessing heavy
solvent
hydroprocessing
Prior art date
Application number
PCT/US2012/052991
Other languages
French (fr)
Other versions
WO2013033298A2 (en
Inventor
Stephen Harold Brown
Teh C. Ho
Jane Chi-Ya Cheng
Hyung Suk Woo
Original Assignee
Exxonmobil Research And Engineering Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Research And Engineering Company filed Critical Exxonmobil Research And Engineering Company
Priority to SG2014008882A priority Critical patent/SG2014008882A/en
Priority to CA2844394A priority patent/CA2844394A1/en
Priority to EP12762124.1A priority patent/EP2751230A2/en
Publication of WO2013033298A2 publication Critical patent/WO2013033298A2/en
Publication of WO2013033298A3 publication Critical patent/WO2013033298A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/32—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions in the presence of hydrogen-generating compounds
    • C10G47/34—Organic compounds, e.g. hydrogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C10G2300/206—Asphaltenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/308—Gravity, density, e.g. API
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/44—Solvents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially longer run length can be attained relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component, particular, the solvent component is comprised of at least one or more supercritical solvent compounds.
PCT/US2012/052991 2011-08-31 2012-08-30 Use of supercritical fluid in hydroprocessing heavy hydrocarbons WO2013033298A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SG2014008882A SG2014008882A (en) 2011-08-31 2012-08-30 Use of supercritical fluid in hydroprocessing heavy hydrocarbons
CA2844394A CA2844394A1 (en) 2011-08-31 2012-08-30 Use of supercritical fluid in hydroprocessing heavy hydrocarbons
EP12762124.1A EP2751230A2 (en) 2011-08-31 2012-08-30 Use of supercritical fluid in hydroprocessing heavy hydrocarbons

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201161529588P 2011-08-31 2011-08-31
US61/529,588 2011-08-31
US13/597,616 2012-08-29
US13/597,616 US20130081979A1 (en) 2011-08-31 2012-08-29 Use of supercritical fluid in hydroprocessing heavy hydrocarbons

Publications (2)

Publication Number Publication Date
WO2013033298A2 WO2013033298A2 (en) 2013-03-07
WO2013033298A3 true WO2013033298A3 (en) 2013-04-25

Family

ID=46888661

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/052991 WO2013033298A2 (en) 2011-08-31 2012-08-30 Use of supercritical fluid in hydroprocessing heavy hydrocarbons

Country Status (5)

Country Link
US (1) US20130081979A1 (en)
EP (1) EP2751230A2 (en)
CA (1) CA2844394A1 (en)
SG (1) SG2014008882A (en)
WO (1) WO2013033298A2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9243193B2 (en) 2013-03-14 2016-01-26 Exxonmobil Research And Engineering Company Fixed bed hydrovisbreaking of heavy hydrocarbon oils
CN110072974B (en) 2016-12-16 2021-11-30 埃克森美孚化学专利公司 Pyrolysis tar pretreatment
WO2018111573A1 (en) 2016-12-16 2018-06-21 Exxonmobil Chemical Patents Inc. Pyrolysis tar conversion
US10072218B2 (en) 2016-12-16 2018-09-11 Exxon Mobil Chemical Patents Inc. Pyrolysis tar conversion
CN110072980B (en) 2016-12-16 2021-11-30 埃克森美孚化学专利公司 Pyrolysis tar conversion
EP3652278B1 (en) 2017-07-14 2022-04-20 ExxonMobil Research and Engineering Company Multi-stage upgrading pyrolysis tar products
US10894924B2 (en) 2017-07-14 2021-01-19 Exxonmobil Chemical Patents Inc. Multi-stage upgrading of hydrocarbon pyrolysis tar using recycled interstage product
WO2020123374A1 (en) 2018-12-10 2020-06-18 Exxonmobil Research And Engineeringcompany Upgrading polynucleararomatic hydrocarbon-rich feeds
CN113214862A (en) * 2020-07-10 2021-08-06 中国石油大学(北京) Heavy oil supercritical/subcritical fluid enhanced hydrogenation method
CN113214864A (en) * 2020-07-10 2021-08-06 中国石油大学(北京) Distillate oil supercritical/subcritical fluid enhanced hydrogenation combination method
CN113214865A (en) * 2020-07-10 2021-08-06 中国石油大学(北京) Heavy oil supercritical/subcritical fluid enhanced hydrogenation combination method
CN113214863A (en) * 2020-07-10 2021-08-06 中国石油大学(北京) Distillate oil supercritical/subcritical fluid enhanced hydrogenation method

Citations (4)

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Publication number Priority date Publication date Assignee Title
US4363717A (en) * 1981-01-15 1982-12-14 Mobil Oil Corporation Conversion of heavy hydrocarbon oils
US4548709A (en) * 1983-04-29 1985-10-22 Mobil Oil Corporation Hydrotreating petroleum heavy ends in aromatic solvents with dual pore size distribution alumina catalyst
US4585546A (en) * 1983-04-29 1986-04-29 Mobil Oil Corporation Hydrotreating petroleum heavy ends in aromatic solvents with large pore size alumina
US5496464A (en) * 1993-01-04 1996-03-05 Natural Resources Canada Hydrotreating of heavy hydrocarbon oils in supercritical fluids

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US2958643A (en) * 1956-08-29 1960-11-01 Sinclair Refining Co Two-stage catalytic conversion process for producing naphthalene and an aromatic gasoline from cycle oils
US3150196A (en) * 1961-07-27 1964-09-22 Sun Oil Co Production of naphthalene and benzene
US3617525A (en) 1969-04-03 1971-11-02 Exxon Research Engineering Co Residuum hydrodesulfurization
US3830731A (en) * 1972-03-20 1974-08-20 Chevron Res Vacuum residuum and vacuum gas oil desulfurization
US4302323A (en) 1980-05-12 1981-11-24 Mobil Oil Corporation Catalytic hydroconversion of residual stocks
US4421633A (en) 1981-03-13 1983-12-20 Mobil Oil Corporation Low pressure cyclic hydrocracking process using multi-catalyst bed reactor for heavy liquids
US4397736A (en) * 1981-04-01 1983-08-09 Phillips Petroleum Company Hydrotreating supercritical solvent extracts in the presence of alkane extractants
US4521293A (en) * 1983-01-11 1985-06-04 James Scinta Oil recovery
US4483761A (en) 1983-07-05 1984-11-20 The Standard Oil Company Upgrading heavy hydrocarbons with supercritical water and light olefins
US4727165A (en) * 1983-11-18 1988-02-23 Phillips Petroleum Company Catalytically hydrogenated decomposible molybdenum compounds as oil hydrofining agents
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Publication number Priority date Publication date Assignee Title
US4363717A (en) * 1981-01-15 1982-12-14 Mobil Oil Corporation Conversion of heavy hydrocarbon oils
US4548709A (en) * 1983-04-29 1985-10-22 Mobil Oil Corporation Hydrotreating petroleum heavy ends in aromatic solvents with dual pore size distribution alumina catalyst
US4585546A (en) * 1983-04-29 1986-04-29 Mobil Oil Corporation Hydrotreating petroleum heavy ends in aromatic solvents with large pore size alumina
US5496464A (en) * 1993-01-04 1996-03-05 Natural Resources Canada Hydrotreating of heavy hydrocarbon oils in supercritical fluids

Non-Patent Citations (1)

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Also Published As

Publication number Publication date
EP2751230A2 (en) 2014-07-09
SG2014008882A (en) 2014-03-28
WO2013033298A2 (en) 2013-03-07
US20130081979A1 (en) 2013-04-04
CA2844394A1 (en) 2013-03-07

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