WO2013020395A1 - Stainless steel product having non-stick surface and treatment process thereof - Google Patents

Stainless steel product having non-stick surface and treatment process thereof Download PDF

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Publication number
WO2013020395A1
WO2013020395A1 PCT/CN2012/074876 CN2012074876W WO2013020395A1 WO 2013020395 A1 WO2013020395 A1 WO 2013020395A1 CN 2012074876 W CN2012074876 W CN 2012074876W WO 2013020395 A1 WO2013020395 A1 WO 2013020395A1
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WO
WIPO (PCT)
Prior art keywords
stainless steel
stick
cleaning
sintering
trichloroethylene
Prior art date
Application number
PCT/CN2012/074876
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French (fr)
Chinese (zh)
Inventor
胡金高
汪宇洋
胡骏超
Original Assignee
缙云县太极科技有限公司
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Publication of WO2013020395A1 publication Critical patent/WO2013020395A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18After-treatment

Definitions

  • the invention relates to a stainless steel product having a non-stick surface and a treatment process thereof, and is particularly suitable for non-stick surface treatment of stainless steel products such as stainless steel decorative materials, stainless steel security doors and stainless steel kitchen appliances.
  • stainless steel products have been widely used in stainless steel decorative materials, stainless steel security doors and stainless steel kitchen appliances.
  • the surface treatment methods of the existing stainless steel cookware are: polishing, sanding, and surface coating non-stick layer.
  • polishing, sanding, and surface coating non-stick layer When cooking utensils using stainless steel polishing and sanding surface treatment, there is a sticking or burning phenomenon.
  • the stainless steel cookware with non-stick layer treatment on the surface can avoid the sticking and burning of the cookware when processing food, which brings convenience and fun to people's cooking.
  • some cookwares with non-stick layers on the open field when the non-stick layer is processed, the surface of the body is sprayed with gold steel sand to form irregular four pits, and then sprayed on the cookware by washing with water. The gold steel sand on the surface of the body is washed away.
  • the non-stick material solution is sprayed, and the non-stick material solution is adhered to the body of the cookware by the temperature baking, and the production process can be reduced to some extent.
  • the water contains many mineral components, especially calcium and magnesium, and the body of the cookware is washed with water to make the cookware
  • the surface of the body is easy to scale, so that when the non-stick layer is sprayed, the adhesion of the non-stick layer to the cookware body is affected; 3. Processing according to the existing process
  • the surface of the stainless steel cookware has different pits and irregular shapes, so the non-stick layer of the spray needs to be relatively thick. Even if a transparent non-stick layer is used, the presence of the coating is obvious, so the surface has lost the stainless steel metal texture. Affects the overall aesthetics of the cookware.
  • the surface treatment of the existing stainless steel security door mainly has two processes of polishing and drawing.
  • the disadvantages are mainly that the pollution resistance is not good, such as being easily removed by sweat stains and dust, and it is easy to be scratched by hard objects and difficult to repair. . Summary of the invention
  • One of the objects of the present invention is to provide a stainless steel article having a surface that is easy to clean and suitable for sintering a non-stick layer.
  • the stainless steel member of the present invention has a stainless steel body, and at least one surface of the stainless steel body is evenly distributed with circular arc-shaped pits, and the surface roughness thereof is Ral ⁇ 2 m.
  • the stainless steel member according to the present invention may be a member made of a single stainless steel material, or may be a member having a surface layer of stainless steel and a core layer of other materials.
  • the material of the sintered non-stick layer contains silicon oxide.
  • the sintered non-stick layer is formed by spraying a transparent non-stick material solution onto the surface of the stainless steel body and then sintering.
  • the stainless steel article of the present invention may be a stainless steel decorative material, a stainless steel security door, and a stainless steel kitchen article.
  • a further object of the present invention is to provide a non-stick surface treatment process for a stainless steel product, by which the non-stick layer on the surface of the stainless steel product is processed, which not only ensures that the surface of the stainless steel body is thoroughly cleaned, and the sintered non-stick layer and stainless steel The body is bonded more firmly, and the texture of the stainless steel can be maintained to ensure the overall beauty of the stainless steel.
  • the technical solution drawn by the present invention is a treatment process for a non-stick surface of a stainless steel product, which comprises the following steps: polishing ⁇ shot blasting ⁇ cleaning ⁇ spraying ⁇ sintering, wherein:
  • polishing Polishing the surface of the stainless steel first
  • Sintering Sintering stainless steel sprayed with a transparent non-stick material solution in an oven for more than 10 minutes, The stainless steel non-stick layer is formed, and the sintering temperature is controlled at 20 (TC or more.
  • the polishing treatment makes the surface roughness of the stainless steel between RaO.05 ⁇ 1 ⁇ .
  • the shot blasting is performed by spraying the glass beads on the surface of the stainless steel to form a circular arc-shaped pit, and the surface roughness of the polished stainless steel is Ra 1 ⁇ 2 ⁇ .
  • the glass beads In the treatment process of the non-stick surface of the stainless steel product, the glass beads have a particle diameter of 60 to 160 mesh.
  • the volatile organic solvent used in the cleaning is trichloroethylene.
  • the cleaning agent used for cleaning is trichloroethylene heated to 50 to 70 °c.
  • the cleaning is performed in an ultrasonic cleaner.
  • the cleaning process is divided into three steps: The first step is rough washing, the stainless steel to be cleaned is immersed in trichloroethylene at 50-70 ° C, and the ultrasonic wave of 28 KHz is activated at the same time. The generator is cleaned by trichloroethylene and ultrasonic cleaning for 2 minutes.
  • the second step is fine washing. The pre-washed stainless steel is immersed in trichloroethylene at 60-70 ° C, and the 68 KHz ultrasonic generator is started at the same time. The cleaning is continued for 2 minutes.
  • the third step is steam drying. The stainless steel is blown with trichloroethylene vapor at 80-90 ° C for 2 minutes to volatilize the trichloroethylene adhered to the stainless steel surface.
  • the spraying amount of the non-stick material solution is preferably 1 to 5 ⁇ , which is formed by sintering.
  • the sintering time is 10 to 25 minutes
  • the sintering temperature is 200 ⁇ 280 ° C o
  • the invention has the beneficial effects of replacing the gold steel sand with glass beads, forming a uniform arc-shaped four pits on the surface of the stainless steel, and cleaning the surface of the stainless steel with a volatile solvent as a cleaning agent to ensure the cleanliness of the stainless steel surface and avoiding Scale is generated on the surface of the stainless steel.
  • the invention can improve the surface strength of the stainless steel non-stick product, increase the adhesion of the stainless steel non-stick product surface and the non-stick layer, and enhance the surface corrosion resistance of the stainless steel non-stick product. Highlights the metallic texture of stainless steel non-stick products. Extend the service life of stainless steel non-stick products. The technical solution of the present invention will be further described below in conjunction with the embodiments.
  • 1 is a schematic view showing the structure of a wok-shaped stainless steel body of the first embodiment
  • FIG. 2 is a schematic structural view of a stainless steel non-stick pan of the second embodiment.
  • FIG. 3 is a schematic structural view of a flat-plate stainless steel member according to Embodiment 3;
  • FIG. 4 is a schematic structural view of a stainless steel security door having a non-stick surface according to Embodiment 4.
  • Embodiment 1 is a diagrammatic representation of Embodiment 1:
  • the stainless steel body 1 of the present embodiment is in the shape of a wok.
  • the inner surface of the stainless steel body 1 is evenly covered with a circular arc shape, and the surface roughness of the inner surface of the stainless steel body 1 is ⁇ 1 ⁇ 2 ⁇ m.
  • the stainless steel member described in this embodiment may be a body made of a single stainless steel material, or a pot body whose surface layer is made of stainless steel and whose core layer is made of a composite material of aluminum or copper.
  • the processing of the stainless steel body is carried out by the following steps:
  • Polishing - shot peening - cleaning - where:
  • Polishing The inner surface of the stainless steel body 1 is mirror-polished to make the surface roughness of the stainless steel body between RaO. 05 ⁇ 1 ⁇ ⁇ . By mirror-polishing the inner surface of the stainless steel body 1, the oxide layer and other impurities on the surface can be removed to ensure the cleanliness of the surface.
  • the inner surface of the stainless steel body 1 can be made to have a certain roughness, and the inner surface of the stainless steel body 1 can be strengthened, thereby improving the mechanical properties of the stainless steel pot and effectively improving the fatigue resistance of the stainless steel pot. Moreover, since the surface of the glass beads is even and smooth, the surface of the stainless steel body 1 is not damaged during the shot peening, and the metal texture of the surface of the stainless steel pot is not damaged.
  • the circular arc-shaped four pits having the same depth of four depressions formed on the surface thereof are favorable for thoroughly cleaning the surface of the stainless steel body 1 in the subsequent cleaning process, thereby ensuring the cleanliness of the surface of the stainless steel body 1 and facilitating the increase of the stainless steel body 1 and The adhesion and bonding force between the coatings make the non-stick layer 2 adhere to the stainless steel body 1 more firmly, prolonging the durability of the non-stick layer.
  • the blasted stainless steel body 1 is cleaned with a heated volatile organic solvent as a cleaning agent to remove dirt on the surface, and not only can heat be used to decompose some oil adhering to the surface thereof.
  • the surface of the cookware is cleaned, and the organic solvent is quickly volatilized after the cleaning is completed, so that the surface thereof is not scaled, and the bonding strength between the non-stick layer 2 and the stainless steel body 1 is improved to ensure the appearance of the pot surface.
  • the organic solvent used in this embodiment is trichloroethylene.
  • the specific cleaning process is divided into three steps: The first step is rough washing, and the stainless steel pot body to be cleaned is immersed in trichloroethylene at 50 ⁇ 70 °C, and simultaneously started.
  • the 28 kHz ultrasonic generator was cleaned with an organic solvent and ultrasonic for 2 minutes.
  • the second step is fine washing.
  • the rough-washed stainless steel body is immersed in trichloroethylene at 60 ⁇ 70 °C, and the 68KHz ultrasonic generator is started at the same time for 2 minutes.
  • the third step is steam drying, which is purged with trichloroethylene vapor at 80 to 90 °C for 2 minutes to volatilize the trichloroethylene adhered to the stainless steel body.
  • the surface of the stainless steel cookware is cleaned with untreated hard water. After the cleaning is completed, the surface of the stainless steel pot body is prone to scale, thereby affecting the bonding strength between the non-stick layer and the stainless steel pot body.
  • the stainless steel pot body is cleaned by using an organic solvent. Since the organic solvent has a large volatility, after the cleaning is completed, the cleaning liquid remaining on the surface of the stainless steel pot body can be quickly volatilized and no knot is formed. The scale phenomenon ensures the surface cleanliness of the stainless steel body.
  • a volatile solvent having similar chemical properties such as trichloroethane can also be used as a cleaning agent.
  • the stainless steel cookware is made of a metal material and trichloroethylene has a strong metal degreasing effect, the embodiment of the present embodiment is Preferred embodiment.
  • the cleaning is performed in the ultrasonic cleaning machine. Because the prior art is used for cleaning with a water pressure gun, it is easy to leave a cleaning corner and easy to leave. Affected by artificial factors, the cleaning effect can not meet the technical requirements, and the process is cleaned with an ultrasonic cleaning machine, which not only avoids the influence of artificial factors on the cleaning effect, but also does not leave a cleaning dead angle, and protects the cleaning of the stainless steel body. Clean.
  • the ultrasonic cleaning machine obviously improves the cleaning quality of the product and makes the product quality more reliable.
  • Embodiment 2 is a diagrammatic representation of Embodiment 1:
  • the embodiment relates to a stainless steel non-stick pan having the stainless steel pot body of the first embodiment, and a sintered non-stick layer 2 is attached to the inner surface of the wok-shaped stainless steel body 1.
  • the thickness of the sintered non-stick layer 2 is 1 to 5 ⁇ ⁇ .
  • the material of the sintered non-stick layer 2 contains silicon oxide, and the sintered non-stick layer 2 is formed by bonding a surface of the stainless steel body 1 by sintering after spraying a transparent non-stick material solution.
  • the processing method of the stainless steel non-stick pan described in this embodiment is performed by spraying and sintering on the basis of the first step.
  • the stainless steel pot with non-stick surface made by the above process has a strong surface strength, and the non-stick layer 2 and the stainless steel body 1 are firmly combined, which increases the corrosion resistance and scratch resistance of the stainless steel pot surface, and prolongs the use of the stainless steel non-stick pan. It has a long life and a non-stick layer. It is only 1 ⁇ 5 ⁇ ⁇ thick, which highlights the metal texture and overall aesthetics of the stainless steel pot surface.
  • the stainless steel non-stick pan according to the present invention may be a cooker such as a wok, a steamer, a soup pot, a frying pan, a milk pot, a pressure cooker, a rice cooker, an electric pot, and the like.
  • Embodiment 3 Embodiment 3:
  • the flat-plate stainless steel member of the embodiment has a stainless steel body 1, and a surface of the stainless steel body 1 is evenly distributed with a circular arc-shaped four pits, and the surface roughness thereof is ⁇ 1 ⁇ 2 ⁇ .
  • polishing First, the surface to be treated of the stainless steel body 1 is mirror-polished so that the surface roughness of the stainless steel body is between RaO.05 ⁇ 1 ⁇ . By mirror-polishing the surface of the stainless steel body 1, the oxide layer and other impurities on the surface can be removed to ensure the cleanliness of the surface.
  • the blasted stainless steel body 1 is cleaned with a heated volatile organic solvent as a cleaning agent to remove dirt on the surface, and not only can heat be used to decompose some oil adhering to the surface.
  • the surface is cleaned, and the organic solvent is quickly volatilized after the cleaning is completed, so that the surface does not scale, and the bonding strength between the non-stick layer and the stainless steel body is improved, and the surface of the product is ensured.
  • the organic solvent used in this embodiment is trichloroethylene.
  • the specific cleaning process is divided into three steps: The first step is rough washing, and the stainless steel body to be cleaned is immersed in trichloroethylene at 50-70 ° C, and 28 KHz is started at the same time.
  • the ultrasonic generator was cleaned with an organic solvent and ultrasonic for 3 minutes.
  • the second step is fine washing.
  • the rough-washed stainless steel body is immersed in trichloroethylene at 60-70 ° C, and a 68 KHz ultrasonic generator is started at the same time, and the cleaning is continued for 3 minutes.
  • the third step is steam drying, which is purged with trichloroethylene vapor at 80 to 90 ° C for 3 minutes to volatilize the trichloroethylene adhered to the stainless steel body.
  • a volatile solvent having similar chemical properties such as trichloroethane can also be used as a cleaning agent.
  • the stainless steel product is made of a metal material and trichloroethylene has a strong metal degreasing effect, the embodiment of the present embodiment is Preferred embodiment.
  • the cleaning is performed in ultrasonic cleaning.
  • Cleaning in the washing machine because the prior art is washed with a water pressure gun, it is easy to leave a cleaning dead angle and is susceptible to artificial factors, so that the cleaning effect cannot meet the technical requirements, and the process is cleaned by an ultrasonic cleaning machine. It not only avoids the influence of artificial factors on the cleaning effect, but also leaves no cleaning corners and protects the cleanliness of stainless steel parts.
  • the ultrasonic cleaning machine obviously improves the cleaning quality of the product and makes the product quality more reliable.
  • Embodiment 4 is a diagrammatic representation of Embodiment 4:
  • the embodiment is a stainless steel security door having a non-stick surface
  • the stainless steel security door having a non-stick surface includes the stainless steel member of the first embodiment
  • the workpiece is a security door.
  • the stainless steel body 1 having a circular arc-shaped four-pit evenly distributed on the surface thereof has a sintered non-stick layer 2 attached thereto, and the sintered non-stick layer 2 has a thickness of 1 to 5 ⁇ m.
  • the material of the sintered non-stick layer 2 contains silicon oxide, and the sintered non-stick layer 2 is formed by spraying a solution of a transparent non-stick material onto the surface of a stainless steel door and then sintering.
  • the processing method of the stainless steel anti-theft door having the non-adhesive surface exemplified in the embodiment is sprayed and sintered on the basis of the first step.
  • the stainless steel anti-theft door made of the above process has a non-stick surface, the surface strength is ⁇ , the non-stick layer 2 and the stainless steel door are firmly combined, the corrosion resistance and scratch resistance of the stainless steel door surface are enhanced, and the service life of the stainless steel anti-theft door is prolonged.
  • the non-stick layer is uniform and transparent, and the thickness is only 1 ⁇ 5 ⁇ ⁇ , highlighting the stainless steel security door surface Metal texture and overall aesthetics.
  • Embodiment 5 is a diagrammatic representation of Embodiment 5:
  • the embodiment provides a treatment process for a non-stick surface of a stainless steel product, and is suitable for processing stainless steel decorative materials, stainless steel security doors, stainless steel kitchen appliances, and the like.
  • the process comprises the following steps: polishing ⁇ shot blasting ⁇ washing ⁇ spraying ⁇ sintering, wherein:
  • polishing The surface of the stainless steel body of the stainless steel product is mirror-polished to make the surface roughness of the stainless steel body between RaO. 05 ⁇ 1 ⁇ ⁇ . Through the mirror polishing of the stainless steel body surface, the oxide layer and other impurities on the stainless steel surface can be removed to ensure the cleanliness of the stainless steel surface.
  • 60 ⁇ 160 mesh is more suitable.
  • 100 to 120 mesh glass beads are used for shot peening, and the surface roughness of the stainless steel body after shot blasting is Ral. 2 ⁇ 1. 3 ⁇ ⁇ .
  • the depth of the circular arc-shaped pit on the surface of the stainless steel body is uniform, and the metal texture of the stainless steel surface is highlighted.
  • the surface of the stainless steel body can be obtained with a certain roughness, and the surface of the stainless steel body can be strengthened, thereby improving the mechanical properties of the stainless steel body and effectively improving the fatigue resistance of the stainless steel body.
  • the surface of the stainless steel body forms a circular arc-shaped four pits, which is beneficial to thoroughly clean the surface of the stainless steel body in the subsequent cleaning process, thereby ensuring the cleanliness of the surface of the stainless steel body, and is beneficial to increasing the adhesion and bonding between the stainless steel body and the coating.
  • the force makes the non-stick layer adhere to the stainless steel body more firmly, prolonging the durability of the non-stick layer.
  • the surface of the glass bead is even and smooth, when the shot peening is performed, scratches on the surface of the stainless steel body are not caused, and the arc-shaped four pits having the same depth of four pits formed on the surface thereof are easily cleaned. The cleanliness of the stainless steel body surface is ensured, thereby improving the bonding strength between the non-stick layer and the stainless steel body, and prolonging the service life of the stainless steel product.
  • the blasted stainless steel body is cleaned with a heated volatile organic solvent as a cleaning agent to remove dirt on the surface, which not only can be used to decompose some oil adhering to the surface, ensuring The surface of the stainless steel body is cleaned, and the organic solvent is quickly volatilized after the cleaning is completed, so that the surface thereof is not scaled, and the bonding strength between the non-stick layer and the stainless steel body is improved, and the surface is beautiful.
  • Ben The organic solvent used in the embodiment is trichloroethylene.
  • the specific cleaning process is divided into three steps: The first step is rough washing, and the stainless steel body to be cleaned is immersed in trichloroethylene at 50-70 ° C, and 28 KHz is started at the same time.
  • the ultrasonic generator is cleaned by an organic solvent and ultrasonic cleaning for 2 to 3 minutes.
  • the second step is fine washing.
  • the pre-cleaned stainless steel body is immersed in trichloroethylene at 60 ⁇ 70 ° C, and the 68 KHz ultrasonic generator is started at the same time, and the cleaning is continued for 2 to 3 minutes.
  • the third step is steam drying, which is purged with trichloroethylene vapor at 80 to 90 °C for 2-3 minutes to volatilize the trichloroethylene adhered to the stainless steel body.
  • the existing process uses the untreated hard water to clean the surface of the stainless steel cookware, after the cleaning is completed, the surface of the stainless steel cookware is prone to scale, thereby affecting the bonding strength between the non-stick layer and the stainless steel cookware;
  • the organic solvent is used to clean the stainless steel body, and since the organic solvent has a large volatility, after the cleaning is completed, the cleaning liquid remaining on the surface of the stainless steel body can be quickly volatilized without scaling, thereby effectively ensuring The surface cleanliness of the stainless steel body.
  • a volatile solvent having similar chemical properties such as trichloroethane can also be used as a cleaning agent.
  • the stainless steel product is made of a metal material and trichloroethylene has a strong metal degreasing effect, the embodiment of the present embodiment is Preferred embodiment.
  • the cleaning is performed in the ultrasonic cleaning machine. Because the prior art is cleaned with a water pressure gun, it is easy to leave a cleaning corner and is susceptible to labor. The influence of the factors makes the cleaning effect not meet the technical requirements, and the process is cleaned by the ultrasonic cleaning machine, which not only avoids the influence of the artificial factors on the cleaning effect, but also does not leave a cleaning dead angle, and protects the cleaning of the stainless steel body.
  • the ultrasonic cleaning machine clearly improves the cleaning quality of the product and makes the product quality more reliable.
  • Spraying Spray the transparent non-stick material solution evenly on the surface of the stainless steel body, and spray the transparent non-stick material solution evenly on the arc-shaped four pits on the surface of the stainless steel body by spraying, and spray the non-stick material solution.
  • the thickness of the non-stick layer formed after sintering should be 1 ⁇ 5 ⁇ ⁇ . Since the silicon oxide has a three-dimensional network structure, silicon oxide is doped into the non-stick material solution, so that the non-stick material solution can form a network structure on the surface of the stainless steel body when dried, thereby enhancing the non-stick layer and the stainless steel body. Bond strength and non-stick layer finish.
  • the above embodiments are only preferred embodiments of the present invention, and are not intended to limit the scope of protection and application of the present invention.
  • the stainless steel articles having a non-stick surface may be stainless steel decorative materials, stainless steel security doors, kitchen cabinets, cooktops, Stainless steel kitchen utensils such as non-stick pans, gas stoves, sinks or range hoods. Products made by equivalent technical means employed in accordance with the design concept of the present invention are within the scope of protection of the present invention.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
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Abstract

A stainless steel product having a non-stick surface and a treatment process thereof. The stainless steel product has a stainless steel body, wherein at least one surface of the body is uniformly distributed with arc-shaped pits, and the surface roughness thereof is Ra1 to 2 μm. A sintering non-stick layer having a thickness of 1 to 5μm is attached to the surface of the stainless steel body. The treatment process of the stainless steel product comprises the steps of polishing, shot blasting, washing, spray coating, and sintering etc., wherein, by shot blasting, the stainless steel surface forms arc-shaped pits uniformly, and then a volatile solvent is used to wash the stainless steel surface. This treatment process can improve the surface strength of the non-stick stainless steel product, increase the adhesion between the surface of the non-stick stainless steel product and the non-stick layer, enhance the corrosion resistance of the surface, distinguish the metal texture of the surface, and extend the service life of the non-stick stainless steel product.

Description

一种具有不粘表面的不锈钢制品及其处理工艺  Stainless steel product with non-stick surface and treatment process thereof
技术领域 Technical field
本发明涉及一种具有不粘表面的不锈钢制品及其处理工艺, 尤其适用于不锈 钢装饰材料、 不锈钢防盗门和不锈钢厨房用品等不锈钢制品的不粘表面处理。 目前, 不锈钢制品已经不锈钢装饰材料、 不锈钢防盗门和不锈钢厨房用品等 领域得到普遍应用。  The invention relates to a stainless steel product having a non-stick surface and a treatment process thereof, and is particularly suitable for non-stick surface treatment of stainless steel products such as stainless steel decorative materials, stainless steel security doors and stainless steel kitchen appliances. At present, stainless steel products have been widely used in stainless steel decorative materials, stainless steel security doors and stainless steel kitchen appliances.
现有不锈钢炊具的表面处理方法有: 抛光、 砂光、 及表面喷涂不粘层。 在使 用不锈钢抛光、 砂光表面处理工艺的炊具加工食物时, 会出现粘锅或烧糊的现象。 用表面喷涂不粘层处理工艺的不锈钢炊具, 可以避免炊具在加工食物时出现粘锅 和烧糊现象, 给人们烹饪带来方便和乐趣。 但是目前巿场上一些带不粘层的炊具, 这类炊具在加工不粘层时, 利用对炊具本体表面喷射金钢砂使本体表面形成不规 则的四坑, 然后再通过水洗将喷射在炊具本体表面上的金钢砂清洗掉, 最后, 再 喷涂不粘材料溶液, 并使不粘材料溶液经髙温烘烤与炊具本体相粘连, 釆用这种 生产工艺, 在一定程度上是可以减少食物粘锅或糊锅现象, 但是现有工艺存在如 下不足之处: 1、 通过金钢砂对炊具本体表面进行处理后, 无法通过水将附着在炊 具本体表面上的金钢砂彻底清洗干净, 不能达到清洁要求, 使在加工不粘层时, 不粘层易变色及脱落; 2、 众所周之, 水中含有矿物质成分多, 尤其是钙和镁, 用 水对炊具本体进行清洗, 使炊具本体表面易结水垢, 这样在喷涂不粘层时, 影响 不粘层与炊具本体粘接的牢固度; 3、 按照现有工艺加工的不锈钢炊具表面的凹坑 深浅不同, 形状不规则, 因此喷涂的不粘层需要比较厚, 即使使用透明的不粘层, 也会明显看出涂层的存在, 所以其表面已经失去不锈钢金属质感, 影响了炊具的 整体美观。  The surface treatment methods of the existing stainless steel cookware are: polishing, sanding, and surface coating non-stick layer. When cooking utensils using stainless steel polishing and sanding surface treatment, there is a sticking or burning phenomenon. The stainless steel cookware with non-stick layer treatment on the surface can avoid the sticking and burning of the cookware when processing food, which brings convenience and fun to people's cooking. However, at present, some cookwares with non-stick layers on the open field, when the non-stick layer is processed, the surface of the body is sprayed with gold steel sand to form irregular four pits, and then sprayed on the cookware by washing with water. The gold steel sand on the surface of the body is washed away. Finally, the non-stick material solution is sprayed, and the non-stick material solution is adhered to the body of the cookware by the temperature baking, and the production process can be reduced to some extent. The food sticks to the pan or the paste pot phenomenon, but the existing process has the following deficiencies: 1. After the surface of the cooker body is treated by the gold steel sand, the gold steel sand attached to the surface of the cookware body cannot be thoroughly cleaned by water. Can not meet the cleaning requirements, so that when the non-stick layer is processed, the non-stick layer is easy to change color and fall off; 2. As everyone knows, the water contains many mineral components, especially calcium and magnesium, and the body of the cookware is washed with water to make the cookware The surface of the body is easy to scale, so that when the non-stick layer is sprayed, the adhesion of the non-stick layer to the cookware body is affected; 3. Processing according to the existing process The surface of the stainless steel cookware has different pits and irregular shapes, so the non-stick layer of the spray needs to be relatively thick. Even if a transparent non-stick layer is used, the presence of the coating is obvious, so the surface has lost the stainless steel metal texture. Affects the overall aesthetics of the cookware.
目前不锈钢防盗门及装饰材料已经得到广泛应用, 其具有良好的实用性和装 饰性。 现有不锈钢防盗门的表面处理主要有抛光与拉丝两种工艺, 其不足之处主 要在于抗污染性不好, 比如被汗渍、 灰尘污染后不易清除, 并且容易被硬物划出 伤痕且不易修复。 发明内容 At present, stainless steel security doors and decorative materials have been widely used, and they have good practicability and decoration. The surface treatment of the existing stainless steel security door mainly has two processes of polishing and drawing. The disadvantages are mainly that the pollution resistance is not good, such as being easily removed by sweat stains and dust, and it is easy to be scratched by hard objects and difficult to repair. . Summary of the invention
本发明的目的之一在于提供一种不锈钢制件, 该不锈钢制件上具有易于清洗 并适于烧结不粘层的表面。  One of the objects of the present invention is to provide a stainless steel article having a surface that is easy to clean and suitable for sintering a non-stick layer.
本发明所述的不锈钢制件, 具有一不锈钢本体, 所述不锈钢本体的至少一表 面均匀分布有圆弧形凹坑, 其表面粗糙度为 Ral~2 m。  The stainless steel member of the present invention has a stainless steel body, and at least one surface of the stainless steel body is evenly distributed with circular arc-shaped pits, and the surface roughness thereof is Ral~2 m.
本发明所述的不锈钢制件, 可以是由单一不锈钢材料制成的制件, 也可以是 表面层为不锈钢材料, 芯层为其他材料的制件。  The stainless steel member according to the present invention may be a member made of a single stainless steel material, or may be a member having a surface layer of stainless steel and a core layer of other materials.
本发明的又一目的在于提供一种具有不粘性表面的不锈钢制品, 所述的具有 不粘性表面的不锈钢制品包括有上述的不锈钢制件, 在其均匀分布有圆弧形四坑 的不锈钢本体表面上附着有一烧结不粘层, 所述烧结不粘层的厚度为 1~5μηι。 作为优选方案, 所述烧结不粘层的材料含有氧化硅。  It is still another object of the present invention to provide a stainless steel article having a non-stick surface, the stainless steel article having a non-stick surface comprising the above-described stainless steel member having a stainless steel body surface uniformly distributed with arc-shaped four pits A sintered non-stick layer is attached thereon, and the sintered non-stick layer has a thickness of 1 to 5 μm. Preferably, the material of the sintered non-stick layer contains silicon oxide.
作为优选方案, 所述烧结不粘层由喷涂透明不粘材料溶液到不锈钢本体表面 再经烧结形成。  Preferably, the sintered non-stick layer is formed by spraying a transparent non-stick material solution onto the surface of the stainless steel body and then sintering.
本发明所述的不锈钢制品可以是不锈钢装饰材料、 不锈钢防盗门以及不锈钢 厨房用品。  The stainless steel article of the present invention may be a stainless steel decorative material, a stainless steel security door, and a stainless steel kitchen article.
本发明的再一目的在于提供一种不锈钢制品不粘表面的处理工艺, 通过该工 艺来加工不锈钢制品表面的不粘层, 不仅可保证不锈钢本体表面彻底清洗干净, 使烧结的不粘层与不锈钢本体粘接更牢固, 而且可以保持不锈钢的质感, 保证不 锈钢的整体美观。  A further object of the present invention is to provide a non-stick surface treatment process for a stainless steel product, by which the non-stick layer on the surface of the stainless steel product is processed, which not only ensures that the surface of the stainless steel body is thoroughly cleaned, and the sintered non-stick layer and stainless steel The body is bonded more firmly, and the texture of the stainless steel can be maintained to ensure the overall beauty of the stainless steel.
为解决现有技术存在的问题, 本发明釆取的技术方案是一种不锈钢制品不粘 表面的处理工艺, 其包括以下步骤: 抛光→喷丸→清洗→喷涂→烧结, 其中: In order to solve the problems existing in the prior art, the technical solution drawn by the present invention is a treatment process for a non-stick surface of a stainless steel product, which comprises the following steps: polishing→shot blasting→cleaning→spraying→sintering, wherein:
(1 )抛光: 先对不锈钢表面抛光处理; (1) Polishing: Polishing the surface of the stainless steel first;
(2) 喷丸: 对不锈钢表面进行喷丸, 使不锈钢表面形成均匀的圆弧形凹坑; (2) Shot peening: blasting the surface of the stainless steel to form a uniform circular arc-shaped pit on the surface of the stainless steel;
( 3)清洗: 将经过喷丸处理的不锈钢表面用挥发性有机溶剂清洗剂进行清洗, 清除不锈钢表面的喷料; (3) Cleaning: The surface of the blasted stainless steel is cleaned with a volatile organic solvent cleaning agent to remove the spray material on the surface of the stainless steel;
(4) 喷涂: 将透明不粘材料溶液均匀的喷涂于不锈钢表面上;  (4) Spraying: Spray the transparent non-stick material solution evenly on the stainless steel surface;
(5)烧结: 将喷涂有透明不粘材料溶液的不锈钢放入烤炉内烧结 10分钟以上, 形成不锈钢不粘层, 烧结温度控制在 20(TC以上。 (5) Sintering: Sintering stainless steel sprayed with a transparent non-stick material solution in an oven for more than 10 minutes, The stainless steel non-stick layer is formed, and the sintering temperature is controlled at 20 (TC or more.
所述的不锈钢制品不粘表面的处理工艺中, 抛光处理使不锈钢表面的粗糙度 在 RaO.05 ~ 1 μηι之间。  In the treatment process of the non-stick surface of the stainless steel product, the polishing treatment makes the surface roughness of the stainless steel between RaO.05 ~ 1 μηι.
该不锈钢制品不粘表面的处理工艺中, 所述喷丸是将玻璃珠喷射在不锈钢的 表面形成圆弧形的凹坑, 经喷丸后的不锈钢表面粗糙度为 Ra 1 ~2μηι。  In the treatment process of the non-stick surface of the stainless steel product, the shot blasting is performed by spraying the glass beads on the surface of the stainless steel to form a circular arc-shaped pit, and the surface roughness of the polished stainless steel is Ra 1 ~ 2 μη.
该不锈钢制品不粘表面的处理工艺中, 所述的玻璃珠粒径为 60~160目。  In the treatment process of the non-stick surface of the stainless steel product, the glass beads have a particle diameter of 60 to 160 mesh.
该不锈钢制品不粘表面的处理工艺中, 清洗时釆用的挥发性有机溶剂为三氯 乙烯。  In the treatment process of the non-stick surface of the stainless steel product, the volatile organic solvent used in the cleaning is trichloroethylene.
该不锈钢制品不粘表面的处理工艺中, 清洗时釆用的清洗剂是加热到 50~70 °c的三氯乙烯。  In the non-stick surface treatment process of the stainless steel product, the cleaning agent used for cleaning is trichloroethylene heated to 50 to 70 °c.
该不锈钢制品不粘表面的处理工艺中, 所述清洗是在超声波清洗机内进行清 洗。  In the treatment process of the non-stick surface of the stainless steel product, the cleaning is performed in an ultrasonic cleaner.
该不锈钢制品不粘表面的处理工艺中, 所述的清洗过程分为三步: 第一步为 粗洗, 将待清洗的不锈钢浸入 50~70°C的三氯乙烯中, 同时启动 28KHz的超声波 发生器, 由三氯乙烯和超声波清洗配合进行 2分钟的清洗; 第二步为精洗, 将经 过预清洗的不锈钢浸入 60~70°C的三氯乙烯中, 同时启动 68KHz的超声波发生 器, 持续清洗 2分钟; 第三步为蒸汽干燥, 利用 80~90°C的三氯乙烯蒸汽吹不锈 钢 2分钟, 使沾附在不锈钢表面的三氯乙烯挥发干净。  In the treatment process of the non-stick surface of the stainless steel product, the cleaning process is divided into three steps: The first step is rough washing, the stainless steel to be cleaned is immersed in trichloroethylene at 50-70 ° C, and the ultrasonic wave of 28 KHz is activated at the same time. The generator is cleaned by trichloroethylene and ultrasonic cleaning for 2 minutes. The second step is fine washing. The pre-washed stainless steel is immersed in trichloroethylene at 60-70 ° C, and the 68 KHz ultrasonic generator is started at the same time. The cleaning is continued for 2 minutes. The third step is steam drying. The stainless steel is blown with trichloroethylene vapor at 80-90 ° C for 2 minutes to volatilize the trichloroethylene adhered to the stainless steel surface.
该不锈钢制品不粘表面的处理工艺中, 所述的不粘材料溶液的喷涂量, 以烧 结后形成的不粘层厚度为 1~5μηι为宜。  In the treatment process of the non-stick surface of the stainless steel product, the spraying amount of the non-stick material solution is preferably 1 to 5 μηι, which is formed by sintering.
该不锈钢制品不粘表面的处理工艺中, 所述烧结的时间为 10~25分钟, 烧结 温度为 200 ~ 280°Co Process non-stick surface of the stainless steel products, the sintering time is 10 to 25 minutes, the sintering temperature is 200 ~ 280 ° C o
本发明的有益效果是用玻璃珠代替金钢砂, 使不锈钢表面形成均匀的圆弧形 四坑, 并釆用挥发性溶剂做为清洗剂对不锈钢表面进行清洗, 保证不锈钢表面的 清洁度, 避免不锈钢表面产生水垢。 同时, 本发明可以提髙不锈钢不粘制品的表 面强度, 增加不锈钢不粘制品表面与不粘层的附着力, 增强不锈钢不粘制品表面 耐蚀性。 突出不锈钢不粘制品表面的金属质感。 延长不锈钢不粘制品的使用寿命。 下面结合实施例对本发明的技术方案做进一步描述。 The invention has the beneficial effects of replacing the gold steel sand with glass beads, forming a uniform arc-shaped four pits on the surface of the stainless steel, and cleaning the surface of the stainless steel with a volatile solvent as a cleaning agent to ensure the cleanliness of the stainless steel surface and avoiding Scale is generated on the surface of the stainless steel. At the same time, the invention can improve the surface strength of the stainless steel non-stick product, increase the adhesion of the stainless steel non-stick product surface and the non-stick layer, and enhance the surface corrosion resistance of the stainless steel non-stick product. Highlights the metallic texture of stainless steel non-stick products. Extend the service life of stainless steel non-stick products. The technical solution of the present invention will be further described below in conjunction with the embodiments.
附图说明 DRAWINGS
图 1为实施例一的一种炒锅形不锈钢本体结构示意图; 1 is a schematic view showing the structure of a wok-shaped stainless steel body of the first embodiment;
图 2为实施例二的一种不锈钢不粘锅的结构示意图。 2 is a schematic structural view of a stainless steel non-stick pan of the second embodiment.
图 3为实施例三的一种平板形不锈钢制件的结构示意图; 3 is a schematic structural view of a flat-plate stainless steel member according to Embodiment 3;
图 4为实施例四的一种具有不粘性表面的不锈钢防盗门的结构示意图。 4 is a schematic structural view of a stainless steel security door having a non-stick surface according to Embodiment 4.
具体实施方式 detailed description
实施例一: Embodiment 1:
参见图 1所示, 本实施例所述的不锈钢本体 1为炒锅形, 所述不锈钢本体 1 的内表面均匀布满了圆弧形 ffl坑, 不锈钢本体 1 内表面的表面粗糙度为 Ι^1 ~ 2 μ m。  Referring to Fig. 1, the stainless steel body 1 of the present embodiment is in the shape of a wok. The inner surface of the stainless steel body 1 is evenly covered with a circular arc shape, and the surface roughness of the inner surface of the stainless steel body 1 is Ι^ 1 ~ 2 μ m.
本实施例所述的不锈钢制件, 可以是单一不锈钢材料制成的本体, 也可以是 表面层为不锈钢材料, 芯层为铝或铜的复合材料制成的锅体。  The stainless steel member described in this embodiment may be a body made of a single stainless steel material, or a pot body whose surface layer is made of stainless steel and whose core layer is made of a composite material of aluminum or copper.
本实施例对不锈钢本体的加工, 经过以下步骤:  In this embodiment, the processing of the stainless steel body is carried out by the following steps:
抛光—喷丸—清洗—, 其中:  Polishing - shot peening - cleaning - where:
( 1 ) 抛光: 先对不锈钢本体 1的内表面进行镜面抛光处理, 使不锈钢本体内 表面的粗糙度在 RaO. 05 ~ 1 μ ηι之间。 通过对不锈钢本体 1 内表面的镜面抛光处 理, 可去除表面的氧化层和其他杂质, 保证其表面的清洁度。  (1) Polishing: The inner surface of the stainless steel body 1 is mirror-polished to make the surface roughness of the stainless steel body between RaO. 05 ~ 1 μ ηι. By mirror-polishing the inner surface of the stainless steel body 1, the oxide layer and other impurities on the surface can be removed to ensure the cleanliness of the surface.
( 2 ) 喷丸: 釆用玻璃珠对不锈钢本体 1的镜面抛光面进行喷丸, 使锅内表面 布满均匀的圆弧形 ffl坑, 使不锈钢本体内表面粗糙度为 Ι^1 ~ 2 μ ηι。 通常上述玻 璃珠粒度为 60 ~ 160目比较适宜。 本实施例中釆用 100 目玻璃珠进行喷丸处理, 经喷丸后不锈钢本体 1的内表面粗糙度为 Ral. 3 μ ηι, 使不锈钢本体表面的圆弧形 四坑的深度均匀一致, 突出不锈钢表面的金属质感。  (2) Shot peening: 喷 blast the mirror polished surface of the stainless steel body 1 with glass beads, so that the inner surface of the pot is covered with a uniform arc-shaped ffl pit, so that the surface roughness of the stainless steel body is Ι^1 ~ 2 μ Ηι. Usually, the above glass beads have a particle size of 60 to 160 mesh. In this embodiment, the 100-mesh glass beads are used for shot peening. After the shot blasting, the inner surface roughness of the stainless steel body 1 is Ral. 3 μ ηι, so that the depth of the circular arc-shaped four pits on the surface of the stainless steel body is uniform and uniform. The metallic texture of the stainless steel surface.
由于以往工艺釆用的是金钢砂对不锈钢锅体进行表面粗糙化, 而金钢砂形状尖 锐而不规则, 在喷砂后, 使不锈钢锅体表面形成深浅不一的微小凹坑。 在清洗时, 无法彻底将微小四坑内的微颗粒杂质清除干净, 使后续喷涂不粘材料溶液后, 不 粘层无法与不锈钢锅体表面充分粘接, 造成不粘层易分层脱落。 而通过喷丸工序 可以使不锈钢本体 1的内表面获得一定的粗糙度, 进而可以使不锈钢体 1 内表面 得到强化, 从而可以改善不锈钢锅的机械性能, 有效提髙了不锈钢锅的抗疲劳性。 并且, 由于玻璃珠表面均匀光滑, 在进行喷丸处理时, 不会对不锈钢本体 1表面 造成损伤, 不会破坏不锈钢锅表面金属质感。 且使其表面上形成的四陷深度相同 的圆弧形四坑, 有利于在后续清洗工序中彻底清洗不锈钢本体 1表面, 从而可保 证不锈钢本体 1表面的清洁度, 有利于增加不锈钢本体 1与涂层之间的附着力和 结合力, 使不粘层 2与不锈钢本体 1粘接更牢固, 延长了不粘层的耐久性。 In the past, the process used to grind the surface of the stainless steel pot with gold steel sand, and the shape of the gold steel sand was sharp and irregular. After the sand blasting, the surface of the stainless steel pot body was formed into tiny pits of different depths. During cleaning, the micro-particle impurities in the tiny four pits cannot be completely removed, so that after the non-stick material solution is sprayed, the non-stick layer cannot be fully bonded to the surface of the stainless steel pot body, and the non-stick layer is easily separated and detached. Through the shot peening process The inner surface of the stainless steel body 1 can be made to have a certain roughness, and the inner surface of the stainless steel body 1 can be strengthened, thereby improving the mechanical properties of the stainless steel pot and effectively improving the fatigue resistance of the stainless steel pot. Moreover, since the surface of the glass beads is even and smooth, the surface of the stainless steel body 1 is not damaged during the shot peening, and the metal texture of the surface of the stainless steel pot is not damaged. Moreover, the circular arc-shaped four pits having the same depth of four depressions formed on the surface thereof are favorable for thoroughly cleaning the surface of the stainless steel body 1 in the subsequent cleaning process, thereby ensuring the cleanliness of the surface of the stainless steel body 1 and facilitating the increase of the stainless steel body 1 and The adhesion and bonding force between the coatings make the non-stick layer 2 adhere to the stainless steel body 1 more firmly, prolonging the durability of the non-stick layer.
( 3 ) 清洗: 将经过喷丸处理的不锈钢本体 1用加热的挥发性有机溶剂做为清 洗剂进行清洗, 以清除表面的污物, 不仅可利用热量分解一些附着在其表面上的 油质, 保证炊具表面的洁净, 同时还可使清洗完成后有机溶剂快速挥发, 使其表 面不会结垢, 提髙不粘层 2与不锈钢本体 1的粘接强度, 保证锅表面的美观。 本 实施例中釆用的有机溶剂为三氯乙烯, 具体清洗工艺分为三步: 第一步为粗洗, 将待清洗的不锈钢锅本体浸入 50 ~ 70 °C的三氯乙烯中, 同时启动 28KHz的超声波 发生器, 由有机溶剂和超声波配合进行 2分钟的清洗。 第二步为精洗, 将经过粗 洗的不锈钢本体浸入 60 ~ 70 °C的三氯乙烯中, 同时启动 68KHz的超声波发生器, 持续清洗 2分钟。 第三步为蒸汽烘干, 利用 80 ~ 90 °C的三氯乙烯蒸汽吹扫 2分钟, 使粘附在不锈钢本体上的三氯乙烯挥发干净。  (3) Cleaning: The blasted stainless steel body 1 is cleaned with a heated volatile organic solvent as a cleaning agent to remove dirt on the surface, and not only can heat be used to decompose some oil adhering to the surface thereof. The surface of the cookware is cleaned, and the organic solvent is quickly volatilized after the cleaning is completed, so that the surface thereof is not scaled, and the bonding strength between the non-stick layer 2 and the stainless steel body 1 is improved to ensure the appearance of the pot surface. The organic solvent used in this embodiment is trichloroethylene. The specific cleaning process is divided into three steps: The first step is rough washing, and the stainless steel pot body to be cleaned is immersed in trichloroethylene at 50 ~ 70 °C, and simultaneously started. The 28 kHz ultrasonic generator was cleaned with an organic solvent and ultrasonic for 2 minutes. The second step is fine washing. The rough-washed stainless steel body is immersed in trichloroethylene at 60 ~ 70 °C, and the 68KHz ultrasonic generator is started at the same time for 2 minutes. The third step is steam drying, which is purged with trichloroethylene vapor at 80 to 90 °C for 2 minutes to volatilize the trichloroethylene adhered to the stainless steel body.
由于现有工艺釆用没有经过处理的硬质水对不锈钢炊具表面进行清洗, 在清 洗完成后, 不锈钢锅体表面易产生水垢, 从而影响不粘层与不锈钢锅体的粘接强 度。 而在本实施例中, 利用有机溶剂对不锈钢锅本体进行清洗, 由于有机溶剂具 有较大的挥发性, 这样在清洗完成后, 残留在不锈钢锅本体表面的清洗液可迅速 挥发且不会产生结垢现象, 从而有效保证不锈钢本体的表面清洁度。  Due to the existing process, the surface of the stainless steel cookware is cleaned with untreated hard water. After the cleaning is completed, the surface of the stainless steel pot body is prone to scale, thereby affecting the bonding strength between the non-stick layer and the stainless steel pot body. In the present embodiment, the stainless steel pot body is cleaned by using an organic solvent. Since the organic solvent has a large volatility, after the cleaning is completed, the cleaning liquid remaining on the surface of the stainless steel pot body can be quickly volatilized and no knot is formed. The scale phenomenon ensures the surface cleanliness of the stainless steel body.
当然也可釆用三氯乙烷等化学性能相似的挥发性溶剂做为清洗剂, 但由于不 锈钢炊具为金属材质, 三氯乙烯具有较强的金属脱脂功效, 因此, 本实施例的实 施方案为优选实施方式。  Of course, a volatile solvent having similar chemical properties such as trichloroethane can also be used as a cleaning agent. However, since the stainless steel cookware is made of a metal material and trichloroethylene has a strong metal degreasing effect, the embodiment of the present embodiment is Preferred embodiment.
在本实施例中, 为降低清洗成本及提髙清洗效率, 所述的清洗是在超声波清 洗机内进行清洗, 由于现有技术釆用髙压水枪进行清洗, 容易留下清洗死角且易 受人工因素影响, 使清洗效果不能达到技术要求, 而本工艺釆用超声波清洗机进 行清洗, 这不仅可避免人工因素对清洗效果的影响, 且还不会留下清洗死角, 保 护不锈钢本体的清洗洁净。 超声波清洗机明显提髙了产品的清洗质量, 使产品品 质更加可靠。 In this embodiment, in order to reduce the cleaning cost and improve the cleaning efficiency, the cleaning is performed in the ultrasonic cleaning machine. Because the prior art is used for cleaning with a water pressure gun, it is easy to leave a cleaning corner and easy to leave. Affected by artificial factors, the cleaning effect can not meet the technical requirements, and the process is cleaned with an ultrasonic cleaning machine, which not only avoids the influence of artificial factors on the cleaning effect, but also does not leave a cleaning dead angle, and protects the cleaning of the stainless steel body. Clean. The ultrasonic cleaning machine obviously improves the cleaning quality of the product and makes the product quality more reliable.
实施例二: Embodiment 2:
参见图 2所示, 本实施例涉及一种不锈钢不粘锅, 该锅具有实施例一中的不 锈钢锅本体, 在其炒锅形不锈钢本体 1的内表面上附着有一烧结不粘层 2, 所述 烧结不粘层 2的厚度为 1 ~ 5 μ ηι。 该烧结不粘层 2的材料含有氧化硅, 该烧结不 粘层 2由喷涂透明不粘材料溶液之后通过烧结与不锈钢本体 1表面粘接形成。  Referring to FIG. 2, the embodiment relates to a stainless steel non-stick pan having the stainless steel pot body of the first embodiment, and a sintered non-stick layer 2 is attached to the inner surface of the wok-shaped stainless steel body 1. The thickness of the sintered non-stick layer 2 is 1 to 5 μ η. The material of the sintered non-stick layer 2 contains silicon oxide, and the sintered non-stick layer 2 is formed by bonding a surface of the stainless steel body 1 by sintering after spraying a transparent non-stick material solution.
本实施例所述的不锈钢不粘锅的加工工艺是在实施例一步骤的基础上再进行 喷涂、 烧结处理。  The processing method of the stainless steel non-stick pan described in this embodiment is performed by spraying and sintering on the basis of the first step.
( 4 )喷涂: 将透明不粘材料溶液均匀地喷涂于不锈钢本体 1的内表面上, 通 过喷涂使透明不粘材料溶液均匀地覆盖不锈钢本体表面的圆弧形四坑, 不粘材料 溶液的喷涂量, 应当以烧结后形成的不粘层的厚度 1 ~ 5 μ ηι为宜。 由于氧化硅具 有三维网状结构, 在不粘材料溶液中掺入氧化硅, 这样就可使不粘材料溶液干燥 时能在不锈钢本体 1表面形成网状结构, 从而提髙不粘层 2与不锈钢本体 1之间 的粘接强度和不粘层的光洁度。  (4) spraying: spraying the transparent non-stick material solution on the inner surface of the stainless steel body 1 uniformly, and spraying the transparent non-stick material solution to uniformly cover the arc-shaped four pits on the surface of the stainless steel body by spraying, spraying the non-stick material solution The amount should be 1 ~ 5 μ ηι of the thickness of the non-stick layer formed after sintering. Since the silicon oxide has a three-dimensional network structure, silicon oxide is doped into the non-stick material solution, so that the non-stick material solution can form a network structure on the surface of the stainless steel body 1 when dried, thereby lifting the non-stick layer 2 and the stainless steel. The bond strength between the bodies 1 and the finish of the non-stick layer.
( 5 ) 烧结: 将喷涂有透明不粘材料溶液的不锈钢锅放入烤炉内烧结 10 ~ 25分 钟, 烧结温度 200 ~ 28(TC, 通过烧结使喷涂于不锈钢本体 1表面上的不粘材料溶液 形成不粘层 2, 并完成具有不粘性表面的不锈钢锅的加工。 本实施例中, 烧结时间为 20分钟, 烧结温度控制在 230°C。  (5) Sintering: The stainless steel pot sprayed with the transparent non-stick material solution is placed in the oven for sintering for 10 to 25 minutes, and the sintering temperature is 200 ~ 28 (TC, the non-stick material solution sprayed on the surface of the stainless steel body 1 by sintering The non-stick layer 2 was formed, and processing of a stainless steel pot having a non-stick surface was completed. In this example, the sintering time was 20 minutes, and the sintering temperature was controlled at 230 °C.
由上述工艺制成的具有不粘性表面的不锈钢锅, 表面强度髙, 不粘层 2与不锈钢本 体 1的结合牢固, 增加不锈钢锅表面耐蚀性和耐划痕性, 延长不锈钢不粘锅的使 用寿命, 且不粘层均匀、 透明, 厚度仅为 1 ~ 5 μ ηι, 突出不锈钢锅表面的金属质 感和整体美观性。 本发明所述的不锈钢不粘锅可以是炒锅、 蒸锅、 汤锅、 煎锅、 奶锅、 髙压锅、 电饭锅、 电气锅等炊具。 实施例三: The stainless steel pot with non-stick surface made by the above process has a strong surface strength, and the non-stick layer 2 and the stainless steel body 1 are firmly combined, which increases the corrosion resistance and scratch resistance of the stainless steel pot surface, and prolongs the use of the stainless steel non-stick pan. It has a long life and a non-stick layer. It is only 1 ~ 5 μ ηι thick, which highlights the metal texture and overall aesthetics of the stainless steel pot surface. The stainless steel non-stick pan according to the present invention may be a cooker such as a wok, a steamer, a soup pot, a frying pan, a milk pot, a pressure cooker, a rice cooker, an electric pot, and the like. Embodiment 3:
参见图 3所示, 本实施例所述的平板形不锈钢制件, 具有一不锈钢本体 1, 所述不锈钢本体 1的一表面均匀分布有圆弧形四坑, 其表面粗糙度为 Ι^1~2μηι。  Referring to FIG. 3, the flat-plate stainless steel member of the embodiment has a stainless steel body 1, and a surface of the stainless steel body 1 is evenly distributed with a circular arc-shaped four pits, and the surface roughness thereof is Ι^1~ 2μηι.
本实施例所述的平板形不锈钢制件的加工, 经过的步骤与实施例一相同: 抛光—喷丸—清洗—, 其中:  The processing of the flat-shaped stainless steel parts described in this embodiment is the same as that of the first embodiment: polishing - shot peening - cleaning - wherein:
(1) 抛光: 先对不锈钢本体 1要处理的表面进行镜面抛光处理, 使不锈钢本 体表面的粗糙度在 RaO.05 ~ 1 μηι之间。 通过对不锈钢本体 1表面的镜面抛光处 理, 可去除表面的氧化层和其他杂质, 保证其表面的清洁度。  (1) Polishing: First, the surface to be treated of the stainless steel body 1 is mirror-polished so that the surface roughness of the stainless steel body is between RaO.05 ~ 1 μηι. By mirror-polishing the surface of the stainless steel body 1, the oxide layer and other impurities on the surface can be removed to ensure the cleanliness of the surface.
(2) 喷丸: 釆用玻璃珠对不锈钢本体 1的镜面抛光面进行喷丸, 使其表面布 满均匀的圆弧形 ffl坑, 使其达到表面粗糙度为 Ι^1~2μηι。 通常上述玻璃珠粒度 为 60~160目比较适宜。 本实施例中釆用 120目玻璃珠进行喷丸处理, 经喷丸后 不锈钢本体 1的表面粗糙度为 Ral.2μηι, 使不锈钢本体表面的圆弧形凹坑的深度 均匀一致, 突出不锈钢表面的金属质感。  (2) Shot peening: 喷 Use the glass beads to blast the mirror-polished surface of the stainless steel body 1 so that the surface is covered with a uniform arc-shaped ffl pit so that the surface roughness is Ι^1~2μηι. Generally, the above glass beads have a particle size of 60 to 160 mesh. In the embodiment, the 120-gauge glass beads are used for shot peening. After the shot blasting, the surface roughness of the stainless steel body 1 is Ral. 2μηι, so that the depth of the circular arc-shaped pits on the surface of the stainless steel body is uniform, and the surface of the stainless steel is protruded. metallic feel.
(3) 清洗: 将经过喷丸处理的不锈钢本体 1用加热的挥发性有机溶剂做为清 洗剂进行清洗, 以清除表面的污物, 不仅可利用热量分解一些附着在其表面上的 油质, 保证其表面的洁净, 同时还可使清洗完成后有机溶剂快速挥发, 使其表面 不会结垢, 提髙不粘层与不锈钢本体的粘接强度, 保证制品表面的美观。 本实施 例中釆用的有机溶剂为三氯乙烯, 具体清洗工艺分为三步: 第一步为粗洗, 将待 清洗的不锈钢本体浸入 50~70°C的三氯乙烯中, 同时启动 28KHz的超声波发生 器, 由有机溶剂和超声波配合进行 3分钟的清洗。 第二步为精洗, 将经过粗洗的 不锈钢本体浸入 60~70°C的三氯乙烯中, 同时启动 68KHz的超声波发生器, 持续 清洗 3分钟。 第三步为蒸汽烘干, 利用 80 ~90°C的三氯乙烯蒸汽吹扫 3分钟, 使 粘附在不锈钢本体上的三氯乙烯挥发干净。  (3) Cleaning: The blasted stainless steel body 1 is cleaned with a heated volatile organic solvent as a cleaning agent to remove dirt on the surface, and not only can heat be used to decompose some oil adhering to the surface. The surface is cleaned, and the organic solvent is quickly volatilized after the cleaning is completed, so that the surface does not scale, and the bonding strength between the non-stick layer and the stainless steel body is improved, and the surface of the product is ensured. The organic solvent used in this embodiment is trichloroethylene. The specific cleaning process is divided into three steps: The first step is rough washing, and the stainless steel body to be cleaned is immersed in trichloroethylene at 50-70 ° C, and 28 KHz is started at the same time. The ultrasonic generator was cleaned with an organic solvent and ultrasonic for 3 minutes. The second step is fine washing. The rough-washed stainless steel body is immersed in trichloroethylene at 60-70 ° C, and a 68 KHz ultrasonic generator is started at the same time, and the cleaning is continued for 3 minutes. The third step is steam drying, which is purged with trichloroethylene vapor at 80 to 90 ° C for 3 minutes to volatilize the trichloroethylene adhered to the stainless steel body.
当然也可釆用三氯乙烷等化学性能相似的挥发性溶剂做为清洗剂, 但由于不 锈钢制品为金属材质, 三氯乙烯具有较强的金属脱脂功效, 因此, 本实施例的实 施方案为优选实施方式。  Of course, a volatile solvent having similar chemical properties such as trichloroethane can also be used as a cleaning agent. However, since the stainless steel product is made of a metal material and trichloroethylene has a strong metal degreasing effect, the embodiment of the present embodiment is Preferred embodiment.
在本实施例中, 为降低清洗成本及提髙清洗效率, 所述的清洗是在超声波清 洗机内进行清洗, 由于现有技术釆用髙压水枪进行清洗, 容易留下清洗死角且易 受人工因素影响, 使清洗效果不能达到技术要求, 而本工艺釆用超声波清洗机进 行清洗, 这不仅可避免人工因素对清洗效果的影响, 且还不会留下清洗死角, 保 护不锈钢制件的清洗洁净。 超声波清洗机明显提髙了产品的清洗质量, 使产品品 质更加可靠。 In this embodiment, in order to reduce the cleaning cost and improve the cleaning efficiency, the cleaning is performed in ultrasonic cleaning. Cleaning in the washing machine, because the prior art is washed with a water pressure gun, it is easy to leave a cleaning dead angle and is susceptible to artificial factors, so that the cleaning effect cannot meet the technical requirements, and the process is cleaned by an ultrasonic cleaning machine. It not only avoids the influence of artificial factors on the cleaning effect, but also leaves no cleaning corners and protects the cleanliness of stainless steel parts. The ultrasonic cleaning machine obviously improves the cleaning quality of the product and makes the product quality more reliable.
实施例四: Embodiment 4:
参见图 4所示, 本实施例为一种具有不粘表面的不锈钢防盗门, 所述的具有 不粘性表面的不锈钢防盗门, 包括有上述实施例一的不锈钢制件, 该制件呈防盗 门形, 具有其表面均匀分布有圆弧形四坑的不锈钢本体 1, 其表面上还附着有一 烧结不粘层 2, 所述烧结不粘层 2的厚度为 1 ~ 5 μ ηι。 所述烧结不粘层 2的材料含 有氧化硅, 烧结不粘层 2是将透明不粘材料溶液喷涂到不锈钢门表面再经烧结形 成。  Referring to FIG. 4, the embodiment is a stainless steel security door having a non-stick surface, and the stainless steel security door having a non-stick surface includes the stainless steel member of the first embodiment, and the workpiece is a security door. The stainless steel body 1 having a circular arc-shaped four-pit evenly distributed on the surface thereof has a sintered non-stick layer 2 attached thereto, and the sintered non-stick layer 2 has a thickness of 1 to 5 μm. The material of the sintered non-stick layer 2 contains silicon oxide, and the sintered non-stick layer 2 is formed by spraying a solution of a transparent non-stick material onto the surface of a stainless steel door and then sintering.
本实施例所列举的具有不粘性表面的不锈钢防盗门的加工工艺是在实施例一 步骤的基础上再进行喷涂、 烧结处理。  The processing method of the stainless steel anti-theft door having the non-adhesive surface exemplified in the embodiment is sprayed and sintered on the basis of the first step.
( 4 ) 喷涂: 将透明不粘材料溶液均匀地喷涂于防盗门不锈钢本体 1的表面 上, 通过喷涂使透明不粘材料溶液均匀地覆盖不锈钢本体 1表面的圆弧形 ffl坑, 不粘材料溶液的喷涂量, 应当以烧结后形成的不粘层的厚度 1 ~ 5 μ ηι为宜。 由于 氧化硅具有三维网状结构, 在不粘材料溶液中掺入氧化硅, 这样就可使不粘材料 溶液干燥时能在不锈钢本体 1表面形成网状结构, 从而提髙不粘层 2与不锈钢本 体 1之间的粘接强度和不粘层的光洁度。  (4) Spraying: uniformly spray the transparent non-stick material solution on the surface of the stainless steel body 1 of the security door, and uniformly cover the arc-shaped ffl pit of the surface of the stainless steel body 1 by spraying, the non-stick material solution The amount of spray should be 1 ~ 5 μ ηι of the thickness of the non-stick layer formed after sintering. Since the silicon oxide has a three-dimensional network structure, silicon oxide is doped into the non-stick material solution, so that the non-stick material solution can form a network structure on the surface of the stainless steel body 1 when dried, thereby lifting the non-stick layer 2 and the stainless steel. The bond strength between the bodies 1 and the finish of the non-stick layer.
( 5 ) 烧结: 将喷涂有不粘材料溶液的不锈钢防盗门面放入烤炉内烧结 10 ~ 25 分钟, 烧结温度 200 ~ 28(TC, 通过烧结使喷涂于不锈钢本体 1表面上的不粘材料溶 液形成不粘层 2, 并完成具有不粘性表面的不锈钢防盗门的加工。 本实施例中, 烧结 时间为 20分钟, 烧结温度控制在 240 °C。  (5) Sintering: The stainless steel anti-theft facade sprayed with the non-stick material solution is placed in the oven for 10 to 25 minutes, and the sintering temperature is 200 ~ 28 (TC, the non-stick material solution sprayed on the surface of the stainless steel body 1 by sintering The non-stick layer 2 was formed, and the processing of the stainless steel security door having a non-stick surface was completed. In this embodiment, the sintering time was 20 minutes, and the sintering temperature was controlled at 240 °C.
由上述工艺制成的具有不粘性表面的不锈钢防盗门, 表面强度髙, 不粘层 2与 不锈钢门的结合牢固, 增强不锈钢门表面耐蚀性和耐划痕性, 延长不锈钢防盗门 的使用寿命, 且不粘层均匀、 透明, 厚度仅为 1 ~ 5 μ ηι, 突出不锈钢防盗门表面 的金属质感和整体美观性。 The stainless steel anti-theft door made of the above process has a non-stick surface, the surface strength is 髙, the non-stick layer 2 and the stainless steel door are firmly combined, the corrosion resistance and scratch resistance of the stainless steel door surface are enhanced, and the service life of the stainless steel anti-theft door is prolonged. , and the non-stick layer is uniform and transparent, and the thickness is only 1 ~ 5 μ ηι, highlighting the stainless steel security door surface Metal texture and overall aesthetics.
实施例五: Embodiment 5:
本实施例提供一种不锈钢制品不粘表面的处理工艺, 适用于加工不锈钢装饰 材料、 不锈钢防盗门以及不锈钢厨房用品等。 该工艺包括以下步骤: 抛光→喷丸 →清洗→喷涂→烧结, 其中:  The embodiment provides a treatment process for a non-stick surface of a stainless steel product, and is suitable for processing stainless steel decorative materials, stainless steel security doors, stainless steel kitchen appliances, and the like. The process comprises the following steps: polishing → shot blasting → washing → spraying → sintering, wherein:
( 1 ) 抛光: 先对不锈钢制品的不锈钢本体的表面进行镜面抛光处理, 使不锈 钢本体表面的粗糙度在 RaO. 05 ~ 1 μ ηι之间。 通过对不锈钢本体表面的镜面抛光处 理, 可去除不锈钢表面的氧化层和其他杂质, 保证不锈钢表面的清洁度。  (1) Polishing: The surface of the stainless steel body of the stainless steel product is mirror-polished to make the surface roughness of the stainless steel body between RaO. 05 ~ 1 μ ηι. Through the mirror polishing of the stainless steel body surface, the oxide layer and other impurities on the stainless steel surface can be removed to ensure the cleanliness of the stainless steel surface.
( 2 ) 喷丸: 釆用玻璃珠对不锈钢本体的镜面抛光面进行喷丸, 使不锈钢本体 表面形成均匀的圆弧形 ffl坑; 表面粗糙度 Ral ~ 2 m。 通常上述的玻璃珠粒度为 (2) Shot peening: 喷 The mirror polished surface of the stainless steel body is shot blasted with glass beads to form a uniform arc-shaped ffl pit on the surface of the stainless steel body; surface roughness Ral ~ 2 m. Usually the above glass beads have a particle size of
60 ~ 160 目比较适宜。 本实施例中釆用 100 ~ 120目玻璃珠进行喷丸处理, 经喷丸 后不锈钢本体的表面粗糙度为 Ral. 2 ~ 1. 3 μ ηι。 使不锈钢本体表面的圆弧形凹坑 的深度均匀一致, 突出不锈钢表面的金属质感。 60 ~ 160 mesh is more suitable. In this embodiment, 100 to 120 mesh glass beads are used for shot peening, and the surface roughness of the stainless steel body after shot blasting is Ral. 2 ~ 1. 3 μ ηι. The depth of the circular arc-shaped pit on the surface of the stainless steel body is uniform, and the metal texture of the stainless steel surface is highlighted.
通过喷丸工序可以使不锈钢本体的表面获得一定的粗糙度, 进而可以使不锈 钢本体表面得到强化, 从而可以改善不锈钢本体的机械性能, 有效提髙了不锈钢 本体的抗疲劳性。 并且, 不锈钢本体表面形成圆弧形四坑, 有利于在后续清洗工 序中彻底清洗不锈钢本体表面, 从而可保证不锈钢本体表面的清洁度, 有利于增 加不锈钢本体与涂层之间的附着力和结合力, 使不粘层与不锈钢本体粘接更牢 固, 延长了不粘层的耐久性。  Through the shot peening process, the surface of the stainless steel body can be obtained with a certain roughness, and the surface of the stainless steel body can be strengthened, thereby improving the mechanical properties of the stainless steel body and effectively improving the fatigue resistance of the stainless steel body. Moreover, the surface of the stainless steel body forms a circular arc-shaped four pits, which is beneficial to thoroughly clean the surface of the stainless steel body in the subsequent cleaning process, thereby ensuring the cleanliness of the surface of the stainless steel body, and is beneficial to increasing the adhesion and bonding between the stainless steel body and the coating. The force makes the non-stick layer adhere to the stainless steel body more firmly, prolonging the durability of the non-stick layer.
由于玻璃珠表面均匀光滑, 在进行喷丸处理时, 不会对不锈钢本体表面造成 损伤产生划痕, 且使其表面上形成的四坑深度相同的圆弧形四坑, 由此易于清洗, 以保证不锈钢本体表面的清洁度, 从而提髙不粘层与不锈钢本体的粘接强度, 延 长不锈钢制品的使用寿命。  Since the surface of the glass bead is even and smooth, when the shot peening is performed, scratches on the surface of the stainless steel body are not caused, and the arc-shaped four pits having the same depth of four pits formed on the surface thereof are easily cleaned. The cleanliness of the stainless steel body surface is ensured, thereby improving the bonding strength between the non-stick layer and the stainless steel body, and prolonging the service life of the stainless steel product.
( 3 ) 清洗: 将经过喷丸处理的不锈钢本体用加热的挥发性有机溶剂做为清洗 剂进行清洗, 以清除表面的污物, 不仅可利用热量分解一些附着在其表面上的油 质, 保证不锈钢本体表面的洁净, 同时还可使清洗完成后有机溶剂快速挥发, 使 其表面不会结垢, 提髙不粘层与不锈钢本体的粘接强度, 保证其表面的美观。 本 实施例中釆用的有机溶剂为三氯乙烯, 具体清洗工艺分为三步: 第一步为粗洗, 将待清洗的不锈钢本体浸入 50 ~ 70°C的三氯乙烯中, 同时启动 28KHz的超声波发 生器, 由有机溶剂和超声波清洗配合进行 2 ~ 3分钟的清洗。 第二步为精洗, 将经 过预清洗的不锈钢本体浸入 60 ~ 70°C的三氯乙烯中, 同时启动 68KHz的超声波发 生器, 持续清洗 2 ~ 3分钟。 第三步为蒸汽干燥, 利用 80 ~ 90 °C的三氯乙烯蒸汽 吹扫 2 - 3分钟, 使粘附在不锈钢本体上的三氯乙烯挥发干净。 (3) Cleaning: The blasted stainless steel body is cleaned with a heated volatile organic solvent as a cleaning agent to remove dirt on the surface, which not only can be used to decompose some oil adhering to the surface, ensuring The surface of the stainless steel body is cleaned, and the organic solvent is quickly volatilized after the cleaning is completed, so that the surface thereof is not scaled, and the bonding strength between the non-stick layer and the stainless steel body is improved, and the surface is beautiful. Ben The organic solvent used in the embodiment is trichloroethylene. The specific cleaning process is divided into three steps: The first step is rough washing, and the stainless steel body to be cleaned is immersed in trichloroethylene at 50-70 ° C, and 28 KHz is started at the same time. The ultrasonic generator is cleaned by an organic solvent and ultrasonic cleaning for 2 to 3 minutes. The second step is fine washing. The pre-cleaned stainless steel body is immersed in trichloroethylene at 60 ~ 70 ° C, and the 68 KHz ultrasonic generator is started at the same time, and the cleaning is continued for 2 to 3 minutes. The third step is steam drying, which is purged with trichloroethylene vapor at 80 to 90 °C for 2-3 minutes to volatilize the trichloroethylene adhered to the stainless steel body.
由于现有工艺釆用没有经过处理的硬质水对不锈钢炊具表面进行清洗, 在清 洗完成后, 不锈钢炊具表面易产生水垢, 从而影响不粘层与不锈钢炊具的粘接强 度; 而在本实施例中, 利用有机溶剂对不锈钢本体进行清洗, 而由于有机溶剂具 有较大的挥发性, 这样在清洗完成后, 残留在不锈钢本体表面的清洗液可迅速挥 发且不会产生结垢现象, 从而有效保证不锈钢本体的表面清洁度。  Because the existing process uses the untreated hard water to clean the surface of the stainless steel cookware, after the cleaning is completed, the surface of the stainless steel cookware is prone to scale, thereby affecting the bonding strength between the non-stick layer and the stainless steel cookware; The organic solvent is used to clean the stainless steel body, and since the organic solvent has a large volatility, after the cleaning is completed, the cleaning liquid remaining on the surface of the stainless steel body can be quickly volatilized without scaling, thereby effectively ensuring The surface cleanliness of the stainless steel body.
当然也可釆用三氯乙烷等化学性能相似的挥发性溶剂做为清洗剂, 但由于不 锈钢制品为金属材质, 三氯乙烯具有较强的金属脱脂功效, 因此, 本实施例的实 施方案为优选实施方式。  Of course, a volatile solvent having similar chemical properties such as trichloroethane can also be used as a cleaning agent. However, since the stainless steel product is made of a metal material and trichloroethylene has a strong metal degreasing effect, the embodiment of the present embodiment is Preferred embodiment.
在本实施例中, 为降低清洗成本及提髙清洗效率, 所述的清洗是在超声波清 洗机内进行清洗, 由于现有技术釆用髙压水枪进行清洗, 容易留下清洗死角且易 受人工因素影响, 使清洗效果不能达到技术要求, 而本工艺釆用超声波清洗机进 行清洗, 这不仅可避免人工因素对清洗效果的影响, 且还不会留下清洗死角, 保 护不锈钢本体的清洗洁净。 超声波清洗机明显提髙了产品的清洗质量, 使产品品 质更加可靠。  In this embodiment, in order to reduce the cleaning cost and improve the cleaning efficiency, the cleaning is performed in the ultrasonic cleaning machine. Because the prior art is cleaned with a water pressure gun, it is easy to leave a cleaning corner and is susceptible to labor. The influence of the factors makes the cleaning effect not meet the technical requirements, and the process is cleaned by the ultrasonic cleaning machine, which not only avoids the influence of the artificial factors on the cleaning effect, but also does not leave a cleaning dead angle, and protects the cleaning of the stainless steel body. The ultrasonic cleaning machine clearly improves the cleaning quality of the product and makes the product quality more reliable.
( 4 ) 喷涂: 将透明不粘材料溶液均匀地喷涂于不锈钢本体的表面上, 通过喷 涂使透明不粘材料溶液均匀地覆盖在不锈钢本体表面的圆弧形四坑内, 不粘材料 溶液的喷涂量, 应当以烧结后形成的不粘层的厚度为 1 ~ 5 μ ηι为宜。 由于氧化硅 具有三维网状结构, 在不粘材料溶液中掺入氧化硅, 这样就可使不粘材料溶液干 燥时能在不锈钢本体表面形成网状结构, 从而提髙不粘层与不锈钢本体粘接强度 及不粘层的光洁度。  (4) Spraying: Spray the transparent non-stick material solution evenly on the surface of the stainless steel body, and spray the transparent non-stick material solution evenly on the arc-shaped four pits on the surface of the stainless steel body by spraying, and spray the non-stick material solution. The thickness of the non-stick layer formed after sintering should be 1 ~ 5 μ ηι. Since the silicon oxide has a three-dimensional network structure, silicon oxide is doped into the non-stick material solution, so that the non-stick material solution can form a network structure on the surface of the stainless steel body when dried, thereby enhancing the non-stick layer and the stainless steel body. Bond strength and non-stick layer finish.
( 5 )烧结: 将喷涂有透明不粘材料溶液的不锈钢本体放入烤炉内烧结 10 ~ 25 分钟, 烧结温度 200 ~ 280°C, 通过烧结使喷涂于不锈钢本体表面上的透明不粘材 料溶液形成不粘层。 本实施例中, 烧结时间为 20分钟, 烧结温度控制在 230 ~ 250 。C。 (5) Sintering: The stainless steel body sprayed with the transparent non-stick material solution is placed in the oven for sintering 10 ~ 25 In minutes, the sintering temperature was 200 to 280 ° C, and the transparent non-stick material solution sprayed on the surface of the stainless steel body was formed into a non-stick layer by sintering. In this embodiment, the sintering time is 20 minutes, and the sintering temperature is controlled at 230 to 250. C.
以上实施例仅为本发明的较佳实施方式, 并非用以限定本发明的保护范围及 应用领域, 该具有不粘性表面的不锈钢制品可以是不锈钢装饰材料、 不锈钢防盗 门、 厨柜、 灶台、 不粘锅、 燃气灶、 洗菜池或抽油烟机等不锈钢厨房用品。 凡依 据本发明的设计思想而釆用的等同技术手段做出的产品, 均属于本发明的保护范 围。  The above embodiments are only preferred embodiments of the present invention, and are not intended to limit the scope of protection and application of the present invention. The stainless steel articles having a non-stick surface may be stainless steel decorative materials, stainless steel security doors, kitchen cabinets, cooktops, Stainless steel kitchen utensils such as non-stick pans, gas stoves, sinks or range hoods. Products made by equivalent technical means employed in accordance with the design concept of the present invention are within the scope of protection of the present invention.

Claims

权利要求书 Claim
1、 一种不锈钢制件, 具有一不锈钢本体, 其特征在于: 所述不锈钢本体的至少一 表面均匀分布有圆弧形凹坑, 其表面粗糙度为 Ral ~ 2 m。  A stainless steel member having a stainless steel body, characterized in that: at least one surface of the stainless steel body is uniformly distributed with arc-shaped pits, and the surface roughness thereof is Ral ~ 2 m.
2、 一种具有不粘性表面的不锈钢制品, 其特征在于: 包括有权利要求 1所述的不 锈钢制件,在其均匀分布有圆弧形四坑的不锈钢本体表面上附着有一烧结不粘层, 所述烧结不粘层的厚度为 1 ~ 5μηι。  2. A stainless steel article having a non-stick surface, comprising: the stainless steel member according to claim 1, wherein a sintered non-stick layer is adhered to a surface of the stainless steel body uniformly distributed with the arc-shaped four pits; The sintered non-stick layer has a thickness of 1 to 5 μm.
3、 根据权利要求 2所述的具有不粘性表面的不锈钢制品, 其特征在于: 所述烧结 不粘层的材料含有氧化硅。  3. A stainless steel article having a non-stick surface according to claim 2, wherein: the material of the sintered non-stick layer contains silicon oxide.
4、 根据权利要求 3所述的具有不粘性表面的不锈钢制品, 其特征在于: 所述烧结 不粘层由喷涂透明不粘材料溶液到不锈钢本体表面再经烧结形成。  4. The stainless steel article having a non-stick surface according to claim 3, wherein: the sintered non-stick layer is formed by spraying a transparent non-stick material solution onto the surface of the stainless steel body and then sintering.
5、 根据权利要求 2或 3或 4所述的具有不粘性表面的不锈钢制品, 其特征在于: 所述不锈钢制品是不锈钢装饰材料、 不锈钢防盗门、 厨柜、 灶台、 不粘锅、 燃气 灶、 洗菜池或抽油烟机等不锈钢厨房用品。  5. The stainless steel article having a non-stick surface according to claim 2 or 3 or 4, wherein: the stainless steel product is a stainless steel decorative material, a stainless steel security door, a kitchen cabinet, a cooktop, a non-stick pan, a gas stove Stainless steel kitchen supplies such as sinks or range hoods.
6、 一种不锈钢制品不粘表面的处理工艺, 其特征在于包括以下步骤: 抛光→喷丸 →清洗→喷涂→烧结, 其中:  6. A process for treating a non-stick surface of a stainless steel product, comprising the steps of: polishing→spraying→cleaning→spraying→sintering, wherein:
( 1 ) 抛光: 先对不锈钢表面抛光处理;  (1) Polishing: Polishing the surface of the stainless steel first;
( 2 ) 喷丸: 对不锈钢表面进行喷丸, 使不锈钢表面形成均匀的圆弧形凹坑; (2) Shot peening: shotting the surface of the stainless steel to form a uniform circular arc-shaped pit on the surface of the stainless steel;
( 3 )清洗: 将经过喷丸处理的不锈钢表面用挥发性有机溶剂清洗剂进行清洗, 清 除不锈钢表面的喷料; (3) Cleaning: The surface of the blasted stainless steel is cleaned with a volatile organic solvent cleaning agent to remove the spray on the stainless steel surface;
( 4 ) 喷涂: 将透明不粘材料溶液均匀的喷涂于不锈钢表面上;  (4) Spraying: Spray the transparent non-stick material solution evenly on the stainless steel surface;
( 5 ) 烧结: 将喷涂有透明不粘材料溶液的不锈钢放入烤炉内烧结 10分钟以上, 形成不锈钢不粘层, 烧结温度控制在 20(TC以上。  (5) Sintering: Sintering stainless steel sprayed with a transparent non-stick material solution in an oven for more than 10 minutes to form a stainless steel non-stick layer, and the sintering temperature is controlled at 20 (TC or more).
7、 根据权利要求 6所述的不锈钢制品不粘表面的处理工艺, 其特征在于: 所述抛 光处理使不锈钢表面的粗糙度在 RaO. 05 ~ Ιμηι之间。  7. The process for treating a non-stick surface of a stainless steel article according to claim 6, wherein: the polishing treatment causes a roughness of the surface of the stainless steel to be between RaO.05 and Ιμηι.
8、 根据权利要求 6所述的不锈钢制品不粘表面的处理工艺, 其特征在于: 所述喷 丸是将玻璃珠喷射在不锈钢的表面形成均匀的圆弧形四坑, 经喷丸后的不锈钢表 面粗糙度为 Ra 1 ~ 2μηι。 8. The process for treating a non-stick surface of a stainless steel product according to claim 6, wherein: the shot blasting is performed by spraying glass beads on the surface of the stainless steel to form a uniform arc-shaped four pits, and the blasted stainless steel. The surface roughness is Ra 1 ~ 2μηι.
9、 根据权利要求 8所述的不锈钢制品不粘表面的处理工艺, 其特征在于: 所述的 玻璃珠粒径为 60 ~ 160目。 9. The process for treating a non-stick surface of a stainless steel article according to claim 8, wherein: said glass beads have a particle size of 60 to 160 mesh.
10、 根据权利要求 6所述的不锈钢制品不粘表面的处理工艺, 其特征在于: 清洗 时釆用的挥发性有机溶剂为三氯乙烯。  10. The process for treating a non-stick surface of a stainless steel product according to claim 6, wherein the volatile organic solvent used for cleaning is trichloroethylene.
11、 根据权利要求 10所述的不锈钢制品不粘表面的处理工艺, 其特征在于: 清洗 时釆用的清洗剂是加热到 50~70°C的三氯乙烯。 11. The process for treating a non-stick surface of a stainless steel product according to claim 10, wherein: the cleaning agent used for cleaning is trichloroethylene heated to 50 to 70 °C.
12、 根据权利要求 11所述的不锈钢制品不粘表面的处理工艺, 其特征在于: 所述 清洗是在超声波清洗机内进行清洗。  A process for treating a non-stick surface of a stainless steel product according to claim 11, wherein: said cleaning is performed in an ultrasonic cleaner.
13、 根据权利要求 12所述的不锈钢制品不粘表面的处理工艺, 其特征在于: 所述 的清洗过程分为三步: 第一步为粗洗, 将待清洗的不锈钢浸入 50~ 70°C的三氯乙 烯中, 同时启动 28KHz的超声波发生器, 由三氯乙烯和超声波清洗配合进行 2 ~ 3 分钟的清洗; 第二步为精洗,将经过预清洗的不锈钢浸入 60 ~ 70°C的三氯乙烯中, 同时启动 68KHz的超声波发生器, 持续清洗 2 ~ 3分钟; 第三步为蒸汽干燥, 利用 80~ 90°C的三氯乙烯蒸汽吹不锈钢 2 ~ 3分钟,使沾附在不锈钢表面的三氯乙烯挥 发干净。  13. The process for treating a non-stick surface of a stainless steel product according to claim 12, wherein: the cleaning process is divided into three steps: the first step is rough washing, and the stainless steel to be cleaned is immersed in 50 to 70 ° C. In the trichloroethylene, the 28KHz ultrasonic generator is started at the same time, and the mixture is cleaned by trichloroethylene and ultrasonic cleaning for 2 to 3 minutes. The second step is fine washing, and the pre-cleaned stainless steel is immersed in 60 ~ 70 °C. In trichloroethylene, start the 68KHz ultrasonic generator at the same time and continue to clean for 2~3 minutes. The third step is steam drying. Boil the stainless steel with 80~90°C trichloroethylene vapor for 2~3 minutes to make it adhere to stainless steel. The surface of trichloroethylene is volatilized clean.
14、 根据权利要求 6所述的不锈钢制品不粘表面的处理工艺, 其特征在于: 所述 的不粘材料溶液的喷涂量, 以烧结后形成的不粘层厚度为 1 ~5μηι为宜。  The process for treating a non-stick surface of a stainless steel product according to claim 6, wherein the non-stick material solution is sprayed in a thickness of 1 to 5 μm.
15、 根据权利要求 6所述的不锈钢制品不粘表面的处理工艺, 其特征在于: 所述 烧结的时间为 10~25分钟, 烧结温度为 200 ~ 280°C。  15. The process for treating a non-stick surface of a stainless steel article according to claim 6, wherein: the sintering time is 10 to 25 minutes, and the sintering temperature is 200 to 280 °C.
PCT/CN2012/074876 2011-08-05 2012-04-28 Stainless steel product having non-stick surface and treatment process thereof WO2013020395A1 (en)

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