WO2013012814A3 - Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide - Google Patents

Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide Download PDF

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Publication number
WO2013012814A3
WO2013012814A3 PCT/US2012/046944 US2012046944W WO2013012814A3 WO 2013012814 A3 WO2013012814 A3 WO 2013012814A3 US 2012046944 W US2012046944 W US 2012046944W WO 2013012814 A3 WO2013012814 A3 WO 2013012814A3
Authority
WO
WIPO (PCT)
Prior art keywords
gold
carbon monoxide
carbamates
carbonates
catalyzed synthesis
Prior art date
Application number
PCT/US2012/046944
Other languages
French (fr)
Other versions
WO2013012814A2 (en
Inventor
Cynthia M. Friend
Robert J. Madix
Bingjun Xu
Original Assignee
President And Fellows Of Harvard College
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by President And Fellows Of Harvard College filed Critical President And Fellows Of Harvard College
Priority to US14/233,041 priority Critical patent/US8937197B2/en
Publication of WO2013012814A2 publication Critical patent/WO2013012814A2/en
Publication of WO2013012814A3 publication Critical patent/WO2013012814A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/04—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups from amines with formation of carbamate groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/01—Preparation of esters of carbonic or haloformic acids from carbon monoxide and oxygen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention provides a method for producing organic carbonates via the reaction of alcohols and carbon monoxide with oxygen adsorbed on a metallic gold or gold alloy catalyst.
PCT/US2012/046944 2011-07-16 2012-07-16 Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide WO2013012814A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US14/233,041 US8937197B2 (en) 2011-07-16 2012-07-16 Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161572416P 2011-07-16 2011-07-16
US61/572,416 2011-07-16

Publications (2)

Publication Number Publication Date
WO2013012814A2 WO2013012814A2 (en) 2013-01-24
WO2013012814A3 true WO2013012814A3 (en) 2013-05-10

Family

ID=47558693

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/046944 WO2013012814A2 (en) 2011-07-16 2012-07-16 Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide

Country Status (2)

Country Link
US (1) US8937197B2 (en)
WO (1) WO2013012814A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2933245A1 (en) 2014-04-17 2015-10-21 Bayer Technology Services GmbH Oxidative carbonylation of amino aryl compounds by aryl formates
US10744488B2 (en) 2016-01-20 2020-08-18 President And Fellows Of Harvard College Ozone-activated nanoporous gold and methods of its use

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003016256A1 (en) * 2001-08-14 2003-02-27 General Electric Company Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates
EP2085375A1 (en) * 2007-12-20 2009-08-05 BP Chemicals Limited Process for the production of acetic acid and/or methyl acetate in the presence of a zeolite of structure type MOR

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT998309B (en) * 1973-08-01 1976-01-20 Snam Progetti CARBOXYLATION PROCESS OF ALCOHOLS IN HEROGENOUS PHASE

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003016256A1 (en) * 2001-08-14 2003-02-27 General Electric Company Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates
EP2085375A1 (en) * 2007-12-20 2009-08-05 BP Chemicals Limited Process for the production of acetic acid and/or methyl acetate in the presence of a zeolite of structure type MOR

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
A. WITTSTOCK ET AL., SCIENCE., vol. 327, 15 January 2010 (2010-01-15), pages 319 - 322 *
MA XINBIN ET AL., CATALYSIS TODAY., vol. 30, 1996, pages 201 - 206 *
RAQUEL JUAREZ ET AL., GREEN CHEM., vol. 11, 2009, pages 949 - 952 *
YONG CAO ET AL., APPLIED CATALYSIS A: GENERAL., vol. 272, 2004, pages 15 - 22 *

Also Published As

Publication number Publication date
WO2013012814A2 (en) 2013-01-24
US20140221679A1 (en) 2014-08-07
US8937197B2 (en) 2015-01-20

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