WO2012175152A1 - Installation de production de biogaz et procédé de fonctionnement d'une telle installation - Google Patents
Installation de production de biogaz et procédé de fonctionnement d'une telle installation Download PDFInfo
- Publication number
- WO2012175152A1 WO2012175152A1 PCT/EP2012/001548 EP2012001548W WO2012175152A1 WO 2012175152 A1 WO2012175152 A1 WO 2012175152A1 EP 2012001548 W EP2012001548 W EP 2012001548W WO 2012175152 A1 WO2012175152 A1 WO 2012175152A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- biogas
- fermenter
- biomass
- liquid medium
- gas
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M21/00—Bioreactors or fermenters specially adapted for specific uses
- C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M23/00—Constructional details, e.g. recesses, hinges
- C12M23/02—Form or structure of the vessel
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M23/00—Constructional details, e.g. recesses, hinges
- C12M23/36—Means for collection or storage of gas; Gas holders
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M23/00—Constructional details, e.g. recesses, hinges
- C12M23/58—Reaction vessels connected in series or in parallel
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M27/00—Means for mixing, agitating or circulating fluids in the vessel
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
- C12M29/02—Percolation
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
- C12M29/18—External loop; Means for reintroduction of fermented biomass or liquid percolate
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
- C12M29/24—Recirculation of gas
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
- C12M29/26—Conditioning fluids entering or exiting the reaction vessel
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
- C12P5/02—Preparation of hydrocarbons or halogenated hydrocarbons acyclic
- C12P5/023—Methane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Definitions
- the invention relates to a plant for the production of biogas according to the preamble of claim 1 and a method for operating a plant for the production of biogas according to the preamble of claim 9.
- Biogas is understood as meaning a methane-rich gas which is produced during the anaerobic digestion of biomass. Anaerobic digestion is also referred to as fermentation or fermentation in this context.
- plants for the fermentation of solid biomass have essentially a generally gas-tight fermenter for receiving the solid biomass. This may be a garage or tunnel-shaped structure into which the biomass is introduced, for example in the form of a heap.
- fermenters according to the prior art generally have a device for charging the biomass with a liquid medium.
- the liquid medium is usually so-called percolate, which by the biomass, which is normally in the form of a Batch or as a debris and thus has a certain porosity, is passed.
- the percolate is used in particular as a carrier for the anaerobic biology, which is responsible for the fermentation process and usually allows only the fermentation of solid biomass, which is wetted by the percolate and moistened with it.
- the fermenters of the type in question usually have a gas outlet for the removal of biogas from the fermenter and a gas inlet for the supply of gases in the fermenter.
- the gas outlet serves at least primarily to remove the biogas from the fermenter, while the gas inlet is usually used to rinse the fermenter, for example, to displace the oxygen from the fermenter with a carbon dioxide-containing gas to the transition from aerobic During the anaerobic phase, among other things, to reduce the risk of explosion by removing explosive gas mixtures or gases which can lead to the formation of such mixtures.
- Such rinses which are made in particular when starting and stopping the fermenter and the associated switching between aerobic and anaerobic processes have the problem with it, that during rinsing a large amount of gas is formed with a no longer technically useful composition, which must be supplied to a disposal, for example, in special Fkelig or filter systems usually.
- a considerable amount of biogas is lost in this way, making the process inefficient.
- the invention has for its object to provide a plant for the production of biogas and a method for operating a plant for the production of biogas, which allow more efficient biogas production, in particular with regard to the prevention of gas losses by rinsing processes and a higher potential content of dry substrate.
- the object is achieved by a system having the features of claim 1 and a method having the features of claim 9.
- Advantageous embodiments can be found in the subclaims.
- the object is achieved in that biogas is introduced into the fermenter.
- the gas inlet of the fermenter with a biogas source preferably the gas outlet of the same and / or another fermenter, a biogas line or a biogas storage connectable.
- the fermenters operated on the common biogas line are operated such that the various process steps of the fermenter operation, in particular start-up and shut-down, are carried out in different fermenters with a time delay, so that in the desired case always at least one fermenter in a biogas generating phase is located.
- the fermentor or fermenters have a further gas outlet next to the biogas outlet or the biogas outlet has a switchable or closable branch, the device to a suitable Gasentsor- supply device, such as a torch, in particular low-gas torch, or a biofilter or another exhaust treatment leads. If gases accumulate during start-up or shut-down processes or purging processes that can not be supplied to the biogas system for recovery, they may overflow the other gas outlets or branches of the biogas lines are disposed of and / or treated accordingly.
- a suitable Gasentsor- supply device such as a torch, in particular low-gas torch, or a biofilter or another exhaust treatment leads. If gases accumulate during start-up or shut-down processes or purging processes that can not be supplied to the biogas system for recovery, they may overflow the other gas outlets or branches of the biogas lines are disposed of and / or treated accordingly.
- the plant preferably has a delivery device for conveying the biogas in the direction of the gas inlet.
- This conveyor may be, for example, a compressor or compressor which is capable of conveying the biogas in the direction of the fermenter.
- the advantage of this is that the correct directions of flow in the biogas line system can be ensured, and, on the other hand, the biogas can also be conveyed against pressure resistances in the fermenter, which is particularly advantageous if the biogas is conducted into the fermenter in such a way a flow of biomass through the biogas is enforced.
- the biomass heap or the biomass bed has an internal porosity or cavities in the interior, in which gas collects, and in particular can be air inclusions, which are present in the biomass after the introduction of the biomass into the fermenter are.
- gas collects and in particular can be air inclusions, which are present in the biomass after the introduction of the biomass into the fermenter are.
- the biogas makes sense for the biogas to be conducted into the fermenter in such a way that a throughflow of the biomass is forced by the biogas.
- Another advantage of this approach is that in this way drainage channels can be created in the heap.
- the biogas also during the fermentation phase, ie during the supply of the liquid medium in the fermenter and the Beauf- slagging the solid biomass with the liquid medium to introduce biogas into the fermenter.
- the creation of the drainage channels is advantageous in the case, even if no other gas is displaced by the biogas in the biogas introduction in this phase of the process. In particular, in this phase, it may also be useful to drive the biogas of a single fermenter in the circulation.
- This forced flow through the biomass is preferably carried out starting from the bottom of the fermenter in a predominantly vertical direction.
- the gas inlet is designed as a gas distribution device, in particular as Spigotteil, a drainage channel network in the heap or the bed of solid biomass are created, which allows a very homogeneous flow through the solid biomass with the liquid medium.
- the gas inlet is therefore preferably arranged below the biomass to be introduced into the fermenter, preferably in the bottom of the fermenter.
- a device for the lateral support of the solid biomass is provided inside the fermenter, preferably permeable to liquid media.
- the provision of such a support is advantageous in order to allow a high height of the heap and at the same time the outflow of the liquid medium from the side of the heap. plant or the bed of biomass.
- this design is prone to the emergence of a dead volume in the lower central region of the heap, which is unsatisfactorily flows through the liquid medium, which can be effectively prevented by the advantageous arrangement of the gas inlet below the biomass.
- the admission of the gas or biogas and the removal of the liquid medium thus takes place through the same gas inlet. This makes it possible that the drainage channels created by the injected biogas always lead to drainage.
- the biogas can be passed into the fermenter after the completion of the supply of the liquid medium to support the dehydration of the biomass. This makes it possible to maintain the fermentation process until reaching the desired for the removal of biomass from the fermenter water or dry substrate content. Between the fermentation phase under biogas atmosphere to produce the biogas and the removal of the fermented biomass, which is forcibly accompanied by aeration of the fermenter, so only a minimal brief flushing of the fermenter is necessary.
- biogas for rinsing the fermenter during startup of the fermenter, advantageously for displacing gases, in particular oxygen. material and nitrogen, from the fermenter and in particular from the porosities and / or cavities of the biomass in the fermenter use. It can already be started after a short rinse with the anaerobic fermentation and usable biogas can be generated. The formation of technically unavailable gas mixtures during startup operation is thereby avoided.
- the system has a plurality of fermenters and the gas inlet and gas outlet of different fermenters can be connected to one another. This can be done for example via the interconnection with a common biogas line.
- a biogas storage device can also be provided, which is preferably connectable to the gas outlet and / or gas inlet, preferably to all existing fermenters, and serves to ensure the availability of the biogas.
- FIG. 1 shows a flow chart of an exemplary system according to the invention
- FIG. 2 shows schematically the flow paths of the percolate and the formation of a dead volume without biogas feed according to the invention
- FIG. 3 shows schematically the flow paths of supplied biogas through the biomass in an exemplary fermenter according to the invention
- FIG. 4 shows diagrammatically exemplary flow paths of the liquid medium through the biomass after creation of additional drainage channels with an exemplary advantageous flushing method according to the invention.
- the exemplary system has a plurality of fermenters 1, the gas outlets 2 can be connected via the shut-off valves 9 with the common biogas line 4. Furthermore, it is possible to connect the gas outlets 2 with the additional exhaust pipe 22 by means of the shut-off valves 10.
- the exemplary system also has an additional protective gas line 24, which can be connected by means of the shut-off valves 25 with the fermenters 1.
- the gas inlets 3 of the individual fermenters can be connected to the common biogas line 4 via the shut-off valve 8 and the line 5.
- the gas inlets 3 can be individually connected with their respective shut-off valves 7 with the line 5 or separated from it.
- a conveyor 6, for example, a compressor is provided to ensure the promotion of the biogas to the gas inlets.
- the Plant according to the invention via a further purge gas supply line 23, with the example, air can be promoted to the gas inlets in the bottoms of the fermenter 1 and / or other gas inlets 26 in the headspace of the fermenter 1.
- a further conveyor 12 is provided.
- the individual gas inlets 3 can be connected by the shut-off valves 11 with this line.
- the exemplary fermenters 1 have gas inlets 3 in their floor designed as a spigot floor.
- a device 16 for exposing the biomass 13 is further arranged with a liquid medium.
- the biomass 13 in the case of the exemplary plant is laterally supported by the means 14 which is permeable to the liquid medium.
- the container also has collecting channels 15 for the removal of the liquid medium. Without the use of the flushing according to the invention for creating additional drainage channels in the heap of biomass 13, the liquid medium takes in the penetration of the heap the indicated in Figure 2 preferred flow paths 18. This creates a dead volume 19 in the lower middle region of the heap of biomass 13, which is not sufficiently flowed through with the liquid medium.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Genetics & Genomics (AREA)
- General Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
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- Clinical Laboratory Science (AREA)
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- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Processing Of Solid Wastes (AREA)
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- Apparatus Associated With Microorganisms And Enzymes (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201280031074.0A CN103649296A (zh) | 2011-06-24 | 2012-04-07 | 产生生物气体的设备和操作这样的设备的方法 |
BR112013032858-4A BR112013032858B1 (pt) | 2011-06-24 | 2012-04-07 | sistema para a geração de biogás e método para operar o sistema |
CA2840465A CA2840465A1 (fr) | 2011-06-24 | 2012-04-07 | Installation de production de biogaz et procede de fonctionnement d'une telle installation |
US14/128,215 US20150031104A1 (en) | 2011-06-24 | 2012-04-07 | System For Generating Biogas And Method For Operating Such A System |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11005135.6 | 2011-06-24 | ||
EP11005135A EP2537919A1 (fr) | 2011-06-24 | 2011-06-24 | Installation de production de biogaz et procédé de fonctionnement de celle-ci |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012175152A1 true WO2012175152A1 (fr) | 2012-12-27 |
Family
ID=45937223
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2012/001548 WO2012175152A1 (fr) | 2011-06-24 | 2012-04-07 | Installation de production de biogaz et procédé de fonctionnement d'une telle installation |
Country Status (6)
Country | Link |
---|---|
US (1) | US20150031104A1 (fr) |
EP (1) | EP2537919A1 (fr) |
CN (1) | CN103649296A (fr) |
BR (1) | BR112013032858B1 (fr) |
CA (1) | CA2840465A1 (fr) |
WO (1) | WO2012175152A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102013107432B4 (de) * | 2013-07-12 | 2017-11-16 | Peter Lutz | Fermenter zur Erzeugung von Biogas aus Biomasse |
US11230689B2 (en) * | 2017-06-07 | 2022-01-25 | Native American Construction Service, Inc. | System and method for generating and storing methane gas using renewable sources |
WO2023147625A1 (fr) * | 2022-02-01 | 2023-08-10 | The University Of Sydney | Système et procédé de pompage d'un fluide à travers une unité cible |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19719323A1 (de) * | 1997-05-08 | 1998-11-12 | Rudolf Dipl Ing Loock | Tunnelfermentationsverfahren zur einstufigen anaeroben und aeroben Behandlung von festen und flüssigen biogenen Abfällen |
EP1428868A1 (fr) * | 2002-12-11 | 2004-06-16 | Ludwig Schiedermeier | Dispositive pour fermentation anearobic de biomasse |
EP2103681A2 (fr) * | 2008-03-20 | 2009-09-23 | Bekon Energy Technologies GmbH & Co.Kg | Installation combinée de production de biogaz et de compost et procédé de commutation d'un fermenteur dans une telle installation entre production de biogaz et compostage |
EP2251408A1 (fr) * | 2009-05-11 | 2010-11-17 | KOMPOFERM GmbH | Procédé et dispositif destinés au fonctionnement d'une installation de fermentation |
DE102009050867A1 (de) * | 2009-10-27 | 2011-04-28 | Vsr Industrietechnik Gmbh | Verfahren zur Erzeugung von Biogas durch Trockenfermentation sowie Biogasanlage zur Gewinnung von Biogas durch Trockenfermentation |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4237693A (en) * | 1977-08-09 | 1980-12-09 | Imperial Chemical Industries Limited | Energy recovery system |
US5269634A (en) * | 1992-08-31 | 1993-12-14 | University Of Florida | Apparatus and method for sequential batch anaerobic composting of high-solids organic feedstocks |
US7422393B2 (en) * | 2005-04-05 | 2008-09-09 | Casella Waste Systems, Inc. | Aerobic and anaerobic waste management systems and methods for landfills |
-
2011
- 2011-06-24 EP EP11005135A patent/EP2537919A1/fr not_active Ceased
-
2012
- 2012-04-07 CA CA2840465A patent/CA2840465A1/fr not_active Abandoned
- 2012-04-07 WO PCT/EP2012/001548 patent/WO2012175152A1/fr active Application Filing
- 2012-04-07 CN CN201280031074.0A patent/CN103649296A/zh active Pending
- 2012-04-07 BR BR112013032858-4A patent/BR112013032858B1/pt active IP Right Grant
- 2012-04-07 US US14/128,215 patent/US20150031104A1/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19719323A1 (de) * | 1997-05-08 | 1998-11-12 | Rudolf Dipl Ing Loock | Tunnelfermentationsverfahren zur einstufigen anaeroben und aeroben Behandlung von festen und flüssigen biogenen Abfällen |
EP1428868A1 (fr) * | 2002-12-11 | 2004-06-16 | Ludwig Schiedermeier | Dispositive pour fermentation anearobic de biomasse |
EP2103681A2 (fr) * | 2008-03-20 | 2009-09-23 | Bekon Energy Technologies GmbH & Co.Kg | Installation combinée de production de biogaz et de compost et procédé de commutation d'un fermenteur dans une telle installation entre production de biogaz et compostage |
EP2251408A1 (fr) * | 2009-05-11 | 2010-11-17 | KOMPOFERM GmbH | Procédé et dispositif destinés au fonctionnement d'une installation de fermentation |
DE102009050867A1 (de) * | 2009-10-27 | 2011-04-28 | Vsr Industrietechnik Gmbh | Verfahren zur Erzeugung von Biogas durch Trockenfermentation sowie Biogasanlage zur Gewinnung von Biogas durch Trockenfermentation |
Also Published As
Publication number | Publication date |
---|---|
BR112013032858B1 (pt) | 2018-12-04 |
US20150031104A1 (en) | 2015-01-29 |
BR112013032858A2 (pt) | 2017-01-24 |
EP2537919A1 (fr) | 2012-12-26 |
CA2840465A1 (fr) | 2012-12-27 |
CN103649296A (zh) | 2014-03-19 |
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